The organic-inorganic hybrid complex with formula [（CuL）2Cu3（μ-1,1-N3）4（ClO4）2], complex 1, {CuL, [5,6：14,l5-dibenzo-1,4,8,12-tetraazacyclopentadeca-7,3-diene-2,3-dione（2-）]copper（Ⅱ）}, has been synthesize...The organic-inorganic hybrid complex with formula [（CuL）2Cu3（μ-1,1-N3）4（ClO4）2], complex 1, {CuL, [5,6：14,l5-dibenzo-1,4,8,12-tetraazacyclopentadeca-7,3-diene-2,3-dione（2-）]copper（Ⅱ）}, has been synthesized and structurally determined. The crystals of complex 1 crystallize in the triclinic system with space group P1, a=0.92983（12） nm, b=1.09644（14） nm, c=1.27396（16） nm, α=70.782（2）°β=86.266（2）°,γ=78.284（2）°. In this complex, the five copper ions are bridged by macrocyclic oxamide groups and azido. Furthermore, C-H…O hydrogen bond interactions link the pentanuclear fragments to form a 2D supramolecular architecture.展开更多
A new thiolate-bridged diiron complex with two mono-coordinated azido ligands, [Cp＊Fe（kt-SMe）N3]2 （Cp^＊ = η^5-C5Me5）, was synthesized from [Cp＊Fe（η-SMe）MeCNMPF6]2 and NaN3 in a bi-solvent system of acetone ...A new thiolate-bridged diiron complex with two mono-coordinated azido ligands, [Cp＊Fe（kt-SMe）N3]2 （Cp^＊ = η^5-C5Me5）, was synthesized from [Cp＊Fe（η-SMe）MeCNMPF6]2 and NaN3 in a bi-solvent system of acetone and methanol. X-ray crystal structural analysis shows that the compound belongs to the orthorhombic Fdd2 space group, with a = 14.3771（15）, b = 71.424（8）, c = 9.7010（10）A, V = 9961.7（18） A3, C22H36Fe2N6S2, Mr = 560.39, Dc = 1.495 g/cm^3, F（000） = 4704,μ（MoKa） = 1.355 mm-I and Z = 16. The compound consists ofa di（u-thiolate）diiron unit {Cp＊Fe（p-SMe）}2, in which each iron is coordinated by a terminal azido ligand. Magnetic characterizations show spin canting behavior for the title compound.展开更多
The complex [Ni(L)(N3)2](H_2O (L=N,N(-Bis(2-pyridylaldehyde) condensation 1,3-diaminopropane) was synthesized by the reaction of NiCl2(6H_2O with 2-pyridylaldehyde and 1,3-diaminopropane and sodium azide in the ethan...The complex [Ni(L)(N3)2](H_2O (L=N,N(-Bis(2-pyridylaldehyde) condensation 1,3-diaminopropane) was synthesized by the reaction of NiCl2(6H_2O with 2-pyridylaldehyde and 1,3-diaminopropane and sodium azide in the ethanol. A single-crystal X-ray study shows that the complex is a six-coordinated nickel (II) with an octahedral environment compound (C15H18N10NiO). The crystal is orthogonal, space group Pbca, with unit cell parameters: a = 13.577(3), b = 15.261(3), c = 17.554(4) ?, V= 3637(1) ?3, Z=8, Mr=413.10, Dc=1.509 g/cm3, ( = 1.096 mm－1, F(000) = 1712, T = 293(2)K, R = 0.0411, wR = 0.1048 for 2888 reflections with I >2( (I). The distances between Ni and N atoms (N(1), N(2), N(3), N(4)) range from 2.050(2) to 2.140(2)?. The distances of Ni-N(5) and Ni-N(8) are 2.115(3) and 2.133(3)?, respectively. The solvent molecule H_2O(O(1)) is linked by hydrogen bonds with O(1) and N(5) and N(8) atoms. Their distances are 2.881(+x, +y, +z) and 2.893(0.5+x, y, 0.5+z)?, respectively.展开更多
Azide-containing coordination polymers have received considerable attention for the construction of new molecule-based magnets.A three dimensional heteronuclear Mn-Na compound [MnNa(N3)4(C5H5N)4] was obtained by react...Azide-containing coordination polymers have received considerable attention for the construction of new molecule-based magnets.A three dimensional heteronuclear Mn-Na compound [MnNa(N3)4(C5H5N)4] was obtained by reaction of [Mn3O(O2CCH3)6(py)3]ClO4 and NaN3 in pyridine solvents.The title compound crystallizes in monoclinic space group C2/c,a=1.536 6(2),b=1.045 3(2),c=1.576 3(2) nm,β=90.309(3)°,V=2.531 8(6) nm3,Z=4.In the structure,each Mn3+ and Na+ ion coordinated with four N atoms from four N3-and two N atoms from two pyridine molecules.Each pair of Mn3+ and Na+ ion are linked by N3-bridges into a 3D polymer with PtS topology.CCDC:706250.展开更多
Two new mononuclear Mn ￡"complexes Mn ￡¨phen￡(c)￡2￡¨N￡3￡(c)￡2￡¨￡±￡(c)andMn ￡¨phen￡(c)￡2￡¨N￡3￡(c)￡¨H￡2O￡(c)ClO4·H2 O￡¨￡2￡(c)have been synthesized...Two new mononuclear Mn ￡"complexes Mn ￡¨phen￡(c)￡2￡¨N￡3￡(c)￡2￡¨￡±￡(c)andMn ￡¨phen￡(c)￡2￡¨N￡3￡(c)￡¨H￡2O￡(c)ClO4·H2 O￡¨￡2￡(c)have been synthesized and structura lly characterized,where phen is ￡±￡?￡±￡°￡-phenanthroline￡(r)Complex1crystallizes in theP1pace group,with lattice parameters a￡1/2￡?￡(r)￡±￡?￡?￡?￡¨￡2￡(c)|!￡?b￡1/2￡±￡±￡(r)￡±￡2￡±￡?￡¨￡2￡(c)|!￡?c￡1/2￡±￡2￡(r)6￡?￡?￡±￡¨￡2￡(c)|!￡?|á￡1/2￡?￡3￡(r)￡μ￡μ￡?￡¨￡3￡(c)??￡?|?￡1/2￡?￡2￡(r)28￡*￡¨￡3￡(c)??￡?|?￡1/2￡*￡3￡(r)6￡¨￡3￡(c)??￡?V￡1/2￡±￡°￡1￡2￡(r)￡*￡¨￡′￡(c)|!￡3￡?Dc￡1/2￡±￡(r)￡μ￡±￡?Mg ?¤m￡-￡3￡?Z ￡1/22,F(000￡(c)￡1/2￡μ￡±￡°￡?R￡±￡1/2￡°￡(r)￡°￡?￡2￡°￡?w R￡2￡1/2￡°￡(r)0958(based on F￡2 ￡(c)￡?S￡1/2￡°￡(r)￡1￡?￡±￡(r)Complex2crystallizes in theP1space group,with lattice parameters a￡1/2￡?￡(r)￡?￡μ￡′￡3￡¨￡2￡(c)|!￡?b￡1/2￡?￡(r)￡1￡*￡?￡*￡¨￡2￡(c)|!￡?c￡1/2￡±￡*￡(r)5915￡¨￡′￡(c)|!￡?|á￡1/2￡1￡3￡(r)￡3￡1￡1￡¨￡3￡(c)??￡?|?￡1/2￡±￡°￡2￡(r)￡?￡°￡?￡¨￡3￡(c)??￡?|?￡1/2￡±￡°￡?￡(r)23￡′￡¨￡3￡(c)??￡?V￡1/2￡±￡2￡?￡?￡(r)￡*￡¨￡′￡(c)? ￡3 ￡?Dc￡1/2￡±￡(r)￡μ￡μ￡2Mg ?¤m￡-￡3￡?Z ￡1/2￡2￡?F￡¨￡°￡°￡°￡(c)￡1/2606,R!? ￡1/2￡°￡(r)067￡2￡?w R ￡2 ￡1/2￡°￡(r)1781(based on F2 ￡(c)￡?S￡1/2￡±￡(r)￡°￡′￡*￡(r)In complex1,the Mn atom is coordinated by six nit rogen atoms of two phen molecules and two N 3- ions with the Mn￡-N distances ranging from ￡2￡(r)￡±￡′￡2￡¨￡′￡(c)to ￡2￡(r)318(4￡(c)|!￡(r)The coordinated phen molecules of the adjacent Mn ￡¨phen￡(c) ￡2 ￡¨N ￡3 ￡(c) 2 moieties experienceπ-πstacking which is responsible for th e crystal packing￡(r)In complex2,the Mn atom is coordinated by five ni trogen atoms of two phen molecules an d one N 3- ion with the Mn￡-N distances ranging from ￡2￡(r)￡±￡μ￡2￡¨￡μ￡(c)to ￡2￡(r)291(5￡(c)|!￡(r)The approximately octahedral environment was completed by the oxygen atom of the coordinated water molecule with the Mn?O distance of ￡2￡(r)￡±￡?￡°￡¨￡μ￡(c)?￡(r)The hydrate water molecule is hydrogen-bonded to one of the O ato ms of free ClO ￡′￡- anion￡(r)展开更多
A new one-dimensional chain complex [Cu(N3)2(C6H8N2)]n (C6H8N2=(2-aminomethyl)pyridine) has been synth-esized and characterized by EA, FTIR and X-ray single-crystal structure analysis. The complex crystallizes in tric...A new one-dimensional chain complex [Cu(N3)2(C6H8N2)]n (C6H8N2=(2-aminomethyl)pyridine) has been synth-esized and characterized by EA, FTIR and X-ray single-crystal structure analysis. The complex crystallizes in triclinic space group P1, with a=0.690 1(2) nm, b=0.825 1(3) nm, c=0.995 3(3) nm, α=67.154(5)°, β=72.898 (5)°, γ=65.462 (5)°, V=0.469 1 (3) nm3, Z=2. Magnetic susceptibility measurement indicates that there is a weak ferro-magnetic exchange coupling between Cu(Ⅱ) ions. CCDC: 686151.展开更多
A novel one-dimensional manganese(II) complex containing nitronyl nitroxide radical [Mn2(IM2-py)2(Ac)2(μ1,1-N3)(μ1,3-N3)·EtOH]n was synthesized and characterized structurally and magnetically. It crystallizes i...A novel one-dimensional manganese(II) complex containing nitronyl nitroxide radical [Mn2(IM2-py)2(Ac)2(μ1,1-N3)(μ1,3-N3)·EtOH]n was synthesized and characterized structurally and magnetically. It crystallizes in the monoclinic space group p21/n. Each Mn(II) ion is six-coordinated in a distorted octahedral environment. The two N atoms of the nitronyl nitroxide radical and the two O atoms of acetate ligands are in the equatorial plane, whereas the two different azido bridging ligands are in trans axial position. Mn(II) ions are linked by nitrogen atom of μ1,1-azido and oxygen atoms of two carboxy groups to form a Mn-Mn unit. Mn-Mn units are linked by azido ligands through μ1,3 bridging style to form a one-dimensional chain. The compound is connected by the coordination bonds, π-π interactions and hydrogen bonds as a three-dimensional structure. Magnetic susceptibility data support that there are stronger antiferromagnetic interactions between the radical and Mn(II) ion, weak antiferromagnetic interactions between the Mn-R units, and very weak antiferromagnetic interactions between the R-Mn-Mn-R units.展开更多
A novel azide-bridged copper（Ⅱ） coordination polymer, [Cu3（NITpPy）4（N3）6]n （NITpPy = 4-pyridyl-4,4,5,5-tetramethylimidazline-3-oxide-1-oxyl）, was structurally and magnetically characterized. It crystallizes i...A novel azide-bridged copper（Ⅱ） coordination polymer, [Cu3（NITpPy）4（N3）6]n （NITpPy = 4-pyridyl-4,4,5,5-tetramethylimidazline-3-oxide-1-oxyl）, was structurally and magnetically characterized. It crystallizes in the triclinic space group P with a = 7.6932（10）, b = 14.5556（19）, c = 16.122（2） , α = 108.443（2）, β = 95.251（2）, γ = 104.236（2）°, V = 1631.7（4） 3, C48H64Cu3N30O8, Mr = 1379.87, Z = 1, Dc = 1.404 g/cm3, μ（MoKα） = 1.041 mm-1, F（000） = 713, the R = 0.0510 and wR = 0.1185 for 4285 observed reflections with I 2σ（I）. X-ray analysis reveals that the Cu（Ⅱ） ions are linked by nitrogen atom of μ1,1 azido ligands to form a Cu-Cu-Cu unit. The units are linked by μ1,3 azido ligands through a bridging style to form a one-dimensional coordination polymer. The variable-temperature magnetic susceptibility data of the complex show ferromagnetic interactions in the complex.展开更多
基金Supported by the National Natural Science Foundation of China(No.20771083)
文摘The organic-inorganic hybrid complex with formula [（CuL）2Cu3（μ-1,1-N3）4（ClO4）2], complex 1, {CuL, [5,6：14,l5-dibenzo-1,4,8,12-tetraazacyclopentadeca-7,3-diene-2,3-dione（2-）]copper（Ⅱ）}, has been synthesized and structurally determined. The crystals of complex 1 crystallize in the triclinic system with space group P1, a=0.92983（12） nm, b=1.09644（14） nm, c=1.27396（16） nm, α=70.782（2）°β=86.266（2）°,γ=78.284（2）°. In this complex, the five copper ions are bridged by macrocyclic oxamide groups and azido. Furthermore, C-H…O hydrogen bond interactions link the pentanuclear fragments to form a 2D supramolecular architecture.
基金supported by NNSFC (21231003, 20972023, 21076037)
文摘A new thiolate-bridged diiron complex with two mono-coordinated azido ligands, [Cp＊Fe（kt-SMe）N3]2 （Cp^＊ = η^5-C5Me5）, was synthesized from [Cp＊Fe（η-SMe）MeCNMPF6]2 and NaN3 in a bi-solvent system of acetone and methanol. X-ray crystal structural analysis shows that the compound belongs to the orthorhombic Fdd2 space group, with a = 14.3771（15）, b = 71.424（8）, c = 9.7010（10）A, V = 9961.7（18） A3, C22H36Fe2N6S2, Mr = 560.39, Dc = 1.495 g/cm^3, F（000） = 4704,μ（MoKa） = 1.355 mm-I and Z = 16. The compound consists ofa di（u-thiolate）diiron unit {Cp＊Fe（p-SMe）}2, in which each iron is coordinated by a terminal azido ligand. Magnetic characterizations show spin canting behavior for the title compound.
文摘The complex [Ni(L)(N3)2](H_2O (L=N,N(-Bis(2-pyridylaldehyde) condensation 1,3-diaminopropane) was synthesized by the reaction of NiCl2(6H_2O with 2-pyridylaldehyde and 1,3-diaminopropane and sodium azide in the ethanol. A single-crystal X-ray study shows that the complex is a six-coordinated nickel (II) with an octahedral environment compound (C15H18N10NiO). The crystal is orthogonal, space group Pbca, with unit cell parameters: a = 13.577(3), b = 15.261(3), c = 17.554(4) ?, V= 3637(1) ?3, Z=8, Mr=413.10, Dc=1.509 g/cm3, ( = 1.096 mm－1, F(000) = 1712, T = 293(2)K, R = 0.0411, wR = 0.1048 for 2888 reflections with I >2( (I). The distances between Ni and N atoms (N(1), N(2), N(3), N(4)) range from 2.050(2) to 2.140(2)?. The distances of Ni-N(5) and Ni-N(8) are 2.115(3) and 2.133(3)?, respectively. The solvent molecule H_2O(O(1)) is linked by hydrogen bonds with O(1) and N(5) and N(8) atoms. Their distances are 2.881(+x, +y, +z) and 2.893(0.5+x, y, 0.5+z)?, respectively.
文摘结合对称性破损(BS)方法,采用不同的密度泛函理论(DFT)对反铁磁性μ-1,3-N3-Ni(II)叠氮配合物[LNi2(N3)](Cl O4)2(L=pyrazolate)的磁特性进行了研究.结果显示,杂化密度泛函理论(HDFT)的计算结果与实验数据非常吻合,能够准确描述配合物的磁特性.磁轨道研究结果表明,配合物表现出较大的单占据轨道能量劈裂(0.93-0.99 e V),显示配合物的单占据轨道去简并化程度较大,且配合物中的2个磁通道(叠氮基、配体pyrazolate)中都分别存在有氮原子之间的p轨道重叠,这些都使得体系表现为反铁磁耦合作用.另外,配合物的磁性与叠氮桥和两金属离子间形成的二面角(τ,Ni-N-N-N-Ni)密切相关,τ从-55.38°逐渐变化到-1.5°的过程中,其反铁磁性逐渐增强,交换耦合常数(Jab)的绝对值逐渐增大,并在-11.95°处达到最大值(Jab=-151.02 cm-1).在此过程中,配合物中叠氮桥及其所连接的2个Ni离子与pyrazolate基配体L-中的2个桥原子N(4)、N(5)形成的七元环共平面性不断增强,即共平面性会诱导增强体系的反铁磁相互作用.
文摘Azide-containing coordination polymers have received considerable attention for the construction of new molecule-based magnets.A three dimensional heteronuclear Mn-Na compound [MnNa(N3)4(C5H5N)4] was obtained by reaction of [Mn3O(O2CCH3)6(py)3]ClO4 and NaN3 in pyridine solvents.The title compound crystallizes in monoclinic space group C2/c,a=1.536 6(2),b=1.045 3(2),c=1.576 3(2) nm,β=90.309(3)°,V=2.531 8(6) nm3,Z=4.In the structure,each Mn3+ and Na+ ion coordinated with four N atoms from four N3-and two N atoms from two pyridine molecules.Each pair of Mn3+ and Na+ ion are linked by N3-bridges into a 3D polymer with PtS topology.CCDC:706250.
文摘Two new mononuclear Mn ￡"complexes Mn ￡¨phen￡(c)￡2￡¨N￡3￡(c)￡2￡¨￡±￡(c)andMn ￡¨phen￡(c)￡2￡¨N￡3￡(c)￡¨H￡2O￡(c)ClO4·H2 O￡¨￡2￡(c)have been synthesized and structura lly characterized,where phen is ￡±￡?￡±￡°￡-phenanthroline￡(r)Complex1crystallizes in theP1pace group,with lattice parameters a￡1/2￡?￡(r)￡±￡?￡?￡?￡¨￡2￡(c)|!￡?b￡1/2￡±￡±￡(r)￡±￡2￡±￡?￡¨￡2￡(c)|!￡?c￡1/2￡±￡2￡(r)6￡?￡?￡±￡¨￡2￡(c)|!￡?|á￡1/2￡?￡3￡(r)￡μ￡μ￡?￡¨￡3￡(c)??￡?|?￡1/2￡?￡2￡(r)28￡*￡¨￡3￡(c)??￡?|?￡1/2￡*￡3￡(r)6￡¨￡3￡(c)??￡?V￡1/2￡±￡°￡1￡2￡(r)￡*￡¨￡′￡(c)|!￡3￡?Dc￡1/2￡±￡(r)￡μ￡±￡?Mg ?¤m￡-￡3￡?Z ￡1/22,F(000￡(c)￡1/2￡μ￡±￡°￡?R￡±￡1/2￡°￡(r)￡°￡?￡2￡°￡?w R￡2￡1/2￡°￡(r)0958(based on F￡2 ￡(c)￡?S￡1/2￡°￡(r)￡1￡?￡±￡(r)Complex2crystallizes in theP1space group,with lattice parameters a￡1/2￡?￡(r)￡?￡μ￡′￡3￡¨￡2￡(c)|!￡?b￡1/2￡?￡(r)￡1￡*￡?￡*￡¨￡2￡(c)|!￡?c￡1/2￡±￡*￡(r)5915￡¨￡′￡(c)|!￡?|á￡1/2￡1￡3￡(r)￡3￡1￡1￡¨￡3￡(c)??￡?|?￡1/2￡±￡°￡2￡(r)￡?￡°￡?￡¨￡3￡(c)??￡?|?￡1/2￡±￡°￡?￡(r)23￡′￡¨￡3￡(c)??￡?V￡1/2￡±￡2￡?￡?￡(r)￡*￡¨￡′￡(c)? ￡3 ￡?Dc￡1/2￡±￡(r)￡μ￡μ￡2Mg ?¤m￡-￡3￡?Z ￡1/2￡2￡?F￡¨￡°￡°￡°￡(c)￡1/2606,R!? ￡1/2￡°￡(r)067￡2￡?w R ￡2 ￡1/2￡°￡(r)1781(based on F2 ￡(c)￡?S￡1/2￡±￡(r)￡°￡′￡*￡(r)In complex1,the Mn atom is coordinated by six nit rogen atoms of two phen molecules and two N 3- ions with the Mn￡-N distances ranging from ￡2￡(r)￡±￡′￡2￡¨￡′￡(c)to ￡2￡(r)318(4￡(c)|!￡(r)The coordinated phen molecules of the adjacent Mn ￡¨phen￡(c) ￡2 ￡¨N ￡3 ￡(c) 2 moieties experienceπ-πstacking which is responsible for th e crystal packing￡(r)In complex2,the Mn atom is coordinated by five ni trogen atoms of two phen molecules an d one N 3- ion with the Mn￡-N distances ranging from ￡2￡(r)￡±￡μ￡2￡¨￡μ￡(c)to ￡2￡(r)291(5￡(c)|!￡(r)The approximately octahedral environment was completed by the oxygen atom of the coordinated water molecule with the Mn?O distance of ￡2￡(r)￡±￡?￡°￡¨￡μ￡(c)?￡(r)The hydrate water molecule is hydrogen-bonded to one of the O ato ms of free ClO ￡′￡- anion￡(r)
基金supported by the National Natural Science Foundation of China(20471008)Program for New Century Excellent Talents in Universities of the Ministry of Education of China(NCET-09-0051)~~
文摘A new one-dimensional chain complex [Cu(N3)2(C6H8N2)]n (C6H8N2=(2-aminomethyl)pyridine) has been synth-esized and characterized by EA, FTIR and X-ray single-crystal structure analysis. The complex crystallizes in triclinic space group P1, with a=0.690 1(2) nm, b=0.825 1(3) nm, c=0.995 3(3) nm, α=67.154(5)°, β=72.898 (5)°, γ=65.462 (5)°, V=0.469 1 (3) nm3, Z=2. Magnetic susceptibility measurement indicates that there is a weak ferro-magnetic exchange coupling between Cu(Ⅱ) ions. CCDC: 686151.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.20071019 and 90101028).
文摘A novel one-dimensional manganese(II) complex containing nitronyl nitroxide radical [Mn2(IM2-py)2(Ac)2(μ1,1-N3)(μ1,3-N3)·EtOH]n was synthesized and characterized structurally and magnetically. It crystallizes in the monoclinic space group p21/n. Each Mn(II) ion is six-coordinated in a distorted octahedral environment. The two N atoms of the nitronyl nitroxide radical and the two O atoms of acetate ligands are in the equatorial plane, whereas the two different azido bridging ligands are in trans axial position. Mn(II) ions are linked by nitrogen atom of μ1,1-azido and oxygen atoms of two carboxy groups to form a Mn-Mn unit. Mn-Mn units are linked by azido ligands through μ1,3 bridging style to form a one-dimensional chain. The compound is connected by the coordination bonds, π-π interactions and hydrogen bonds as a three-dimensional structure. Magnetic susceptibility data support that there are stronger antiferromagnetic interactions between the radical and Mn(II) ion, weak antiferromagnetic interactions between the Mn-R units, and very weak antiferromagnetic interactions between the R-Mn-Mn-R units.
基金supported by the National Natural Science Foundations of China (Nos. 20771054 and 21071074)
文摘A novel azide-bridged copper（Ⅱ） coordination polymer, [Cu3（NITpPy）4（N3）6]n （NITpPy = 4-pyridyl-4,4,5,5-tetramethylimidazline-3-oxide-1-oxyl）, was structurally and magnetically characterized. It crystallizes in the triclinic space group P with a = 7.6932（10）, b = 14.5556（19）, c = 16.122（2） , α = 108.443（2）, β = 95.251（2）, γ = 104.236（2）°, V = 1631.7（4） 3, C48H64Cu3N30O8, Mr = 1379.87, Z = 1, Dc = 1.404 g/cm3, μ（MoKα） = 1.041 mm-1, F（000） = 713, the R = 0.0510 and wR = 0.1185 for 4285 observed reflections with I 2σ（I）. X-ray analysis reveals that the Cu（Ⅱ） ions are linked by nitrogen atom of μ1,1 azido ligands to form a Cu-Cu-Cu unit. The units are linked by μ1,3 azido ligands through a bridging style to form a one-dimensional coordination polymer. The variable-temperature magnetic susceptibility data of the complex show ferromagnetic interactions in the complex.
