This study systematically investigated the effects of graphite nodule parameters,including count,average diameter,and nodularity,on microstructure and mechanical properties of austempered ductile irons(ADIs).The ADI s...This study systematically investigated the effects of graphite nodule parameters,including count,average diameter,and nodularity,on microstructure and mechanical properties of austempered ductile irons(ADIs).The ADI specimens with graphite nodule counts of 212±11 mm^(-2),308±9 mm^(-2),415±10 mm^(-2),and 589±13 mm^(-2) were designated as G-200,G-300,G-400,and G-600,respectively.Results indicate a progressive refinement of graphite with an increase in nodule counts.Specifically,the average nodule diameter decreases from 33.3±1.3μm for G-200 to 17.0±0.7μm for G-600.The nodularity of all samples is above 90%.Furthermore,the nodularity exhibits a corresponding increasing trend with the rise of graphite nodule count in ADIs.Additionally,the volume fraction of the austenite phase in ADIs decreases with an increase in graphite nodule count.The graphite nodule count changes the tensile strength and elongation of ADIs.The specimen G-400 exhibits the ultimate tensile strength of 897±11 MPa and an elongation of 9.8%±0.6%,representing 5.3%and 44.1%improvements respectively compared to G-200.To explore the wear resistance of ADIs with different graphite nodule counts,dry sliding friction and wear test of different samples was carried out at room temperature.At a high load of 25 N,G-400 exhibits superior wear resistance,achieving a 42%reduction in worn volume compared to G-200.Worn micromorphology identifies three primary wear mechanisms:microcutting-dominated abrasive wear,adhesive wear,and fatigue wear.展开更多
An alloyed cast iron was prepared by horizontal continuous casting.To study the salt bath temperature on microstructure and mechanical properties,the alloyed cast iron was firstly austenitized at 950℃for 3 h and then...An alloyed cast iron was prepared by horizontal continuous casting.To study the salt bath temperature on microstructure and mechanical properties,the alloyed cast iron was firstly austenitized at 950℃for 3 h and then austempered in salt bath at various temperatures(250℃,300℃and 350℃)for another 3 h.The scanning electron microscopy(SEM),electron backscattered diffraction(EBSD),and X-ray diffraction(XRD)were employed to observe the microstructure and test the mechanical properties of the alloyed cast iron.Results show that the microstructure of the alloyed cast iron is mainly composed of acicular or feathery ferrite(bainite),retained austenite,carbide,and graphite.When austempered in salt bath at 250℃,300℃and 350℃for 3 h,the volume fractions of retained austenite are 33.1%,41.7%,and 57.2%,the thickness of acicular ferrite are 0.25μm,0.3μm,and 0.8μm.As the salt bath austempering temperature increases,the mechanical properties decrease due to the increase of the volume fraction of retained austenite and the thickness of acicular ferrite.The highest tensile strength of the alloyed cast iron is achieved when it is austempered at 250℃in a salt bath.Under these conditions,the tensile strength of the alloyed cast iron can reach 1,429 MPa.Tensile test results indicate that the fracture mechanism is predominantly brittle fracture.展开更多
Austempered ductile iron(ADI) parts have a unique combination of high strength and toughness with excellent design flexibility and low cost. These excellent properties are directly related to its microstructure called...Austempered ductile iron(ADI) parts have a unique combination of high strength and toughness with excellent design flexibility and low cost. These excellent properties are directly related to its microstructure called "ausferrite" that is the result of austempering heat treatment applied to ductile irons. Alloying elements increase ADI austemperability and change speeds of austempering reactions. Thus, they can affect ADI resultant microstructure and mechanical properties. In this paper, the effects of alloying elements on ADI mechanical properties, microstructural changes, two-stage austempering reactions, processing windows, austemperability, and other aspects are reviewed.展开更多
The effect of sub-zero cooling on microstructure and mechanical properties of a low alloyed austempered ductile iron has been investigated. Austempering of samples was performed at 325℃and 400℃after austenitizing at...The effect of sub-zero cooling on microstructure and mechanical properties of a low alloyed austempered ductile iron has been investigated. Austempering of samples was performed at 325℃and 400℃after austenitizing at 875℃and 950℃. The sub-zero treatments were carried out by cooling down the samples to -30℃, -70℃and -196℃. The changes in volume fraction of austenite and mechanical properties were determined after cooling to each temperature. The austenite volume fraction of samples which were austenitized at 875℃and austempered at 325℃remained unchanged, whilst it reduced in samples austenitized at 950℃and 875℃for austempering temperature of 400℃. In these specimens, some austenite transformed to martensite after subzero cooling. Mechanical property measurements showed a slight increase in strength and hardness and decrease in elongation and toughness due to this transformation behavior.展开更多
Shot peening is one of the most common surface treatments to improve the fatigue behavior of metallic parts. In this study the effect of shot peening process on the fatigue behavior of an alloyed austempered ductile i...Shot peening is one of the most common surface treatments to improve the fatigue behavior of metallic parts. In this study the effect of shot peening process on the fatigue behavior of an alloyed austempered ductile iron (ADI) has been studied. Austempering heat treatment consisted of austenitizing at 875℃ for 90 min followed by austempering at three different temperatures of 320, 365 and 400℃. Rotating-bending fatigue test was carried out on samples after shot peening by 0.4-0.6 mm shots. XRD and SEM analysis, micro hardness and roughness tests were carried out to study the fatigue behavior of the samples. Results indicate that the fatigue strengths of samples austempered at 320, 365 and 400℃ are increased by 27.3%, 33.3% and 48.4%, respectively, after shot peening process.展开更多
The wear resistances of austempered ductile iron （ADI） were improved through intxoduction of a new phase （carbide） into the ma- txix by addition of chromium. In the present investigation, low-caxbon-equivalent duc...The wear resistances of austempered ductile iron （ADI） were improved through intxoduction of a new phase （carbide） into the ma- txix by addition of chromium. In the present investigation, low-caxbon-equivalent ductile iron （LCEDI） （CE = 3.06%, and CE represents cax- bon-equivalent） with 2.42% chromium was selected. LCEDI was austeintized at two difl＇erent temperatures （900 and 975~C） a^ld soaked for 1 h and then quenched in a salt bath at 325~C for 0 to 10 h. Samples were analyzed using optical microscopy and X-ray diffraction. Wear tests were carded out on a pin-on-disk-type machine. The efl＇ect of austenization temperature on the wear resistance, impact strength, and the mi- crostructure was evaluated. A stxucture-property correlation based on the observations is established.展开更多
This paper presents the effects of chemical compositions of austempered ductile iron （ADI） on casting quality, heat treatment process parameters and mechanical properties of final products. Through experiment and pr...This paper presents the effects of chemical compositions of austempered ductile iron （ADI） on casting quality, heat treatment process parameters and mechanical properties of final products. Through experiment and production practice, the impacts of carbon equivalent on ADI and its mechanical properties have been studied. Proper content ranges for carbon and silicon have been obtained to avoid ADI casting shrinkage and graphite fioatation, as well as to achieve the optimal mechanical properties. According to the impact of silicon content on austenite phase transformation, the existing form of carbon in ADI has been analyzed, and also the formula and diagram showing the relationship between austenitizing temperature and carbon content in austenite have been deduced. The chemical composition range for high performance ADI and its control points have been recommended, to serve as a reference for production process.展开更多
Measurements of dry sliding wear are presented for ductile irons with composition Fe-3.56C-2.67Si- 0.25Mo-0.5Cu and Ni contents of 0.8 and 1.5 in wt.% with applied loads of 50, 100 and 150 N for austempering temperatu...Measurements of dry sliding wear are presented for ductile irons with composition Fe-3.56C-2.67Si- 0.25Mo-0.5Cu and Ni contents of 0.8 and 1.5 in wt.% with applied loads of 50, 100 and 150 N for austempering temperatures of 270, 320, and 370 ℃ after austenitizing at 870 ℃ for 120 min. The mechanical property measurements show that the grades of the ASTM 897M： 1990 Standard can be satisfied for the selected austempering conditions. The results show that wear resistance is independent of austempedng temperature with an applied load of 50 N, but there is a strong dependence at higher austempering temperatures with applied loads of 100 and 150 N. Observations indicate that wear is due to subsurface fatigue with cracks nucleated at deformed graphite nodules.展开更多
Effects of graphite nodule diameter on the water embrittlement of austempered ductile iron (ADI) is studied. The water embrittlement mechanism is discussed. Due to water adhesion, local embrittlement occurs on the sur...Effects of graphite nodule diameter on the water embrittlement of austempered ductile iron (ADI) is studied. The water embrittlement mechanism is discussed. Due to water adhesion, local embrittlement occurs on the surface of ADI specimen, resulting in early fracture and significant reduction in tensile strength and elongation. The water embrittlement is the cracking of stress induced martensite formed during tensile deformation caused by hydrogen diffusion decomposed from water and as a result tensile strength and elongation of ADI are remarkably reduced. The segregation of alloying elements in ductile iron is weakened with decreasing nodule diameter, reducing the residual austenite in grain boundaries, then decreasing the amount of stress induced martensite during tensile plastic deformation and finally restraining ADI water embrittlement.展开更多
The Impact toughness and fracture toughness of Austempered Ductile Iron (ADI) are described. The notched and un-notched Charpy impact toughness of ADI at room temperature are somewhat lower than that of steel castings...The Impact toughness and fracture toughness of Austempered Ductile Iron (ADI) are described. The notched and un-notched Charpy impact toughness of ADI at room temperature are somewhat lower than that of steel castings or forged steel pieces, however, they are approximately three times higher than that of normal pearlitic ductile iron. The impact toughness of ADI decreases with decreasing temperature; but at-40℃ it still maintains about 70% of the value at room temperature. The properties of fracture toughness are important in safety design and failure analysis. In this study all fracture toughness data of ADI are higher than that of conventional ductile iron, and are equivalent to or better than that of steel castings or forged steel pieces with the tensile strength equivalent to ADI.展开更多
The erosion behavior of austempered ductile irons austenized at different temperatures was studied. The results indicate that the erosion rate well correlates with the mechanical properties. At high impact angles, inc...The erosion behavior of austempered ductile irons austenized at different temperatures was studied. The results indicate that the erosion rate well correlates with the mechanical properties. At high impact angles, increasing ductility and mechanical energy density results in decreasing erosion rate, whereas increasing hardness reduces the erosion rate at low impact angles. 2008 University of Science and Technology Beijing. All rights reserved.展开更多
Austempered ductile iron(ADI)is composed of an ausferritic matrix with graphite nodules and has a wide range of applications because of its high mechanical strength,fatigue resistance,and wear resistance compared to o...Austempered ductile iron(ADI)is composed of an ausferritic matrix with graphite nodules and has a wide range of applications because of its high mechanical strength,fatigue resistance,and wear resistance compared to other cast irons.The amount and size of the nodules can be controlled by the chemical composition and austenitizing temperature.As the nodules have lower stiffness than the matrix and can act as stress concentrators,they influence crack propagation.However,the crack propagation mechanism in ADI is not yet fully understood.In this study,we describe a numerical investigation of crack propagation in ADIs subjected to cyclic loading.The numerical model used to calculate the stress intensity factors in the material under the given conditions is built with the aid of Abaqus commercial finite element code.The crack propagation routine,which is based on the Paris law,is implemented in Python.The results of the simulation show that the presence of a nodule generates a shear load on the crack tip.Consequently,even under uniaxial tensile loading,the presence of the nodule yields a non-zero stress intensity factor in mode II,resulting in a deviation in the crack propagation path.This is the primary factor responsible for changing the crack propagation direction towards the nodule.Modifying the parameters,for example,increasing the nodule size or decreasing the distance between the nodule and crack tip,can intensify this effect.In simulations comparing two different ADIs with the same graphite fraction area,the crack in the material with more nodules reaches another nodule in a shorter propagation time(or shorter number of cycles).This suggests that the high fatigue resistance observed in ADIs may be correlated with the number of nodules intercepted by a crack and the additional energy required to nucleate new cracks.In summary,these findings contribute to a better understanding of crack propagation in ADIs,provide insights into the relationship between the presence of nodules and the fatigue resistance of these materials,and support studies that associate the increased fatigue resistance with a higher number of graphite nodules.These results can also help justify the enhanced fatigue resistance of ADIs when compared to other cast irons.展开更多
Carbide formation in austempered ductile iron (ADI) alloyed with Ni and Cu has been studied by use of TEM. The results show that η carbide precipitates in the bainitic ferrite when austempered at 350℃.for 6h, but no...Carbide formation in austempered ductile iron (ADI) alloyed with Ni and Cu has been studied by use of TEM. The results show that η carbide precipitates in the bainitic ferrite when austempered at 350℃.for 6h, but no carbide was found at the austenite/.ferrite interfaces. When austempered at 300℃, two kinds of. s carbides appear in the bainitic ferrite when austempering time reached I h, and X carbide also precipitates at the austenite /ferrite interfaces when austempering time was extended up to 6h. The bainitic. ferrite and the retained austenite follow the Nishiyama- Wasserman relationship,展开更多
The aim of present work is to investigate the influencing factors on mechanical property stability of Cu-Mo-Ni alloyed austempered ductile iron （ADI）. The results show that after austenitized at 900℃ for 2 h follow...The aim of present work is to investigate the influencing factors on mechanical property stability of Cu-Mo-Ni alloyed austempered ductile iron （ADI）. The results show that after austenitized at 900℃ for 2 h followed by austempered at 370℃for another 2 h, the mechanical property of the alloyed ADI can reach the Germanite GGG-100 standard, i.e. σb≮1000 MPa,δ≮5%, at 95% confidence level. And the satisfactory mechanical properties were obtained when the alloyed ADI was austenitized at 850℃ to 1 000 ℃ for 1-4 h, and austempered at 355℃ to 400℃ for another 1 h to 4 h. The microstructures, including nodule number, white bright zone content （martensite-containing interdendritic segregation zone） and retained austenite content, can significantly influence the mechanical properties of the ADI. In order to obtain the good combinations of strength and ductility, the volume fraction of white bright zone should he less than 5%, and the retained austenite contents maintain hetween 30 % and 40%. The application of inoculation techniques to increase graphite nodule number can effectively reduce the white bright zone content in the structure.展开更多
In the present paper, a new type of austempered boron alloyed high silicon cast steel has been developed, and its microstructures and mechanical properties at different temperatures were investigated. The experimental...In the present paper, a new type of austempered boron alloyed high silicon cast steel has been developed, and its microstructures and mechanical properties at different temperatures were investigated. The experimental results indicate that the boron alloyed high silicon cast steel comprises a dendritic matrix and interdendritic eutectic borides in as-cast condition. The dendritic matrix is made up of pearlite, ferrite, and the interdendritic eutectic boride is with a chemical formula of M2B （M represents Fe, Cr, Mn or Mo） which is much like that of carbide in high chromium white cast iron. Pure ausferrite structure that consists of bainitic ferrite and retained austenite can be obtained in the matrix by austempering treatment to the cast steel. No carbides precipitate in the ausferrite structure and the morphology of borides remains almost unchanged after austempering treatments. Secondary boride particles precipitate during the course of austenitizing. The hardness and tensile strength of the austempered cast steel decrease with the increase of the austempering temperature, from 250℃ to 400 ℃. The impact toughness is 4-11 J.cm^-2 at room temperature and the impact fracture fractogragh indicates that the fracture is caused by the brittle fracture of the borides.展开更多
The effects of austempering temperature on microstructure and surface residual stress of carbidic austempered ductile iron （CADI） grinding balls were systematically investigated in this work. The microstructures we...The effects of austempering temperature on microstructure and surface residual stress of carbidic austempered ductile iron （CADI） grinding balls were systematically investigated in this work. The microstructures were oberserved by optical metallography and analyized by X-ray diffraction. The surface residual stress measured by the cutting method is mainly composed of thermal stress and phase transformation stress.The thermal stress in grinding balls was determined by ANSYS simulation technique, and the surface phase transformation stress was obtained by subtracting the simulated surface thermal stress from the measured surface residual stress. Results show that all microstructures consist of ausferrite, white-bright zones （mixture of martensite and austenite）, nodular graphite, and carbides. The distribution of ausferrite shows uniform. With the increase of austempering temperature, the volume fraction and carbon content of austenite increase, whereas the amount of white-bright zone decreases. In addition, the surface residual stress increases with the increase of austempering temperature. Only the tension exists at the austempering temperature of 200 ℃, and the pressure exists at the austempering temperature of 220-260 °C. The thermal stress changes from the tension on the inside with the radius of 0-35 mm to the pressure on the outside with the radius of 35-62.5 mm, and the stress balance state presents at the radius of 35 mm. It is also found that the transformation stress is related to the content of carbon-rich austenite, and will reduce by 5.03 MPa accompanied with 1vol.% increase of the austenite.The thermal compressive stress and the transformation tensile stress on the surface both decrease with the increase of the austempering temperature.展开更多
The fracture characteristics of austempered spheroidal graphite aluminum cast iron had been investigated. The chemical content of the alloy was C3.2, Al2.2, Ni0.8 and Mg0.05 （in mass percent, %）. Impact test samples...The fracture characteristics of austempered spheroidal graphite aluminum cast iron had been investigated. The chemical content of the alloy was C3.2, Al2.2, Ni0.8 and Mg0.05 （in mass percent, %）. Impact test samples were produced from keel blocks cast in CO2 molding process. The oversized impact samples were austenitized at 850 and 950 ℃ for 2h followed by austempering at 300 and 400 ℃ for 30, 60, 120 and 180min. The austempered samples were machined and tested at room temperature. The impact strength values for those samples austempered at 400 ℃ varied between 90 and 110J. Lower bainitie structures showed impact strength values of 22 to 50J. The fractures of the samples were examined using SEM. The results showed that the upper bainitic fracture revealed a honey Comb-like topography, which confirmed the ductile fracture behavior. The lower bainitic fractures of those samples austempered for short times revealed brittle fracture.展开更多
Crack initiation, propagation and microfracture processes of austempered high silicon cast steel have been investigated by using an in-situ tensile stage installed inside a scanning electron microscope chamber. It is ...Crack initiation, propagation and microfracture processes of austempered high silicon cast steel have been investigated by using an in-situ tensile stage installed inside a scanning electron microscope chamber. It is revealed that micro cracks always nucleate at the yielding near imperfections and the boundary of matrix-inclusions due to the stress concentration. There are four types of crack propagations in the matrix: crack propagates along the boundary of two clusters of bainitic ferrite; crack propagates along the boundary of ferrite-austenite in bainitic ferrite laths; crack propagates into bainitic ferrite laths; crack nucleates and propagates in the high carbon brittle plate shape martensite which is transformed from some blocky retained austenite due to plastic deformation. Based on the observation and analysis of microfracture processes, a schematic diagram of the crack nucleation and propagation process of high silicon cast steel is proposed.展开更多
The effect of austempering temperature on the microstructure and properties of a high chromium white cast iron was investigated with the Rietveld refinement method. The result shows that the upper bainite exists in th...The effect of austempering temperature on the microstructure and properties of a high chromium white cast iron was investigated with the Rietveld refinement method. The result shows that the upper bainite exists in the sampie austempered at 623 K and the martensite, lower bainite, M7C3, and retained austenite exist in the samples austempered at 563 K and 593 K. The relative content of the retained austenite increases with increasing the austemper- ing temperature from 563 K to 623 K. The higher hardness, impact toughness and impact abrasive wear resistance can be obtained for the specimen austempered at 593 K.展开更多
This study aims to clarify the influence of external notch on impact characteristics of high toughness ductile cast irons prepared by austempering heat treatment. We produced ductile cast irons samples with various ma...This study aims to clarify the influence of external notch on impact characteristics of high toughness ductile cast irons prepared by austempering heat treatment. We produced ductile cast irons samples with various matrix microstructure tested by Charpy impact within five kinds of external notches whose stress concentration factors (α), with values taken from 1.0 (Un-notched) to 4.8. In addition, to clarify the initiation process of impact characteristics, we observed the evolution of microstructure surface during bending tests with a slow loading speed for the un-notched and the notched impact samples. The results showed that the impact fracture energy decreases strongly in the range of α from 1 to 2.3 but decreases slightly for α larger than 3. Moreover, the impact value of samples with austempered microstructure is sensitive to the external notch shape. The impact transition temperature increases with increasing the stress concentration factor. The fracture energy is decreasing with the external notch from the impact test since the crack initiation energy is directly affected by this later. This work contributes to get a better understanding in the basic theories of external notch effect on impact characteristics of austempered spheroidal graphite cast irons (ADI).展开更多
基金supported by the Science and Technology Project of Hebei Education Department(Grant No.BJK2023075)the Science and Technology Project of Tianjin Education Department(Grant No.2022K1087)the Chunhui Project Foundation of the Education Department of China(Grant No.HZKY20220264).
文摘This study systematically investigated the effects of graphite nodule parameters,including count,average diameter,and nodularity,on microstructure and mechanical properties of austempered ductile irons(ADIs).The ADI specimens with graphite nodule counts of 212±11 mm^(-2),308±9 mm^(-2),415±10 mm^(-2),and 589±13 mm^(-2) were designated as G-200,G-300,G-400,and G-600,respectively.Results indicate a progressive refinement of graphite with an increase in nodule counts.Specifically,the average nodule diameter decreases from 33.3±1.3μm for G-200 to 17.0±0.7μm for G-600.The nodularity of all samples is above 90%.Furthermore,the nodularity exhibits a corresponding increasing trend with the rise of graphite nodule count in ADIs.Additionally,the volume fraction of the austenite phase in ADIs decreases with an increase in graphite nodule count.The graphite nodule count changes the tensile strength and elongation of ADIs.The specimen G-400 exhibits the ultimate tensile strength of 897±11 MPa and an elongation of 9.8%±0.6%,representing 5.3%and 44.1%improvements respectively compared to G-200.To explore the wear resistance of ADIs with different graphite nodule counts,dry sliding friction and wear test of different samples was carried out at room temperature.At a high load of 25 N,G-400 exhibits superior wear resistance,achieving a 42%reduction in worn volume compared to G-200.Worn micromorphology identifies three primary wear mechanisms:microcutting-dominated abrasive wear,adhesive wear,and fatigue wear.
基金financially supported by the National Natural Science Foundation of China(Nos.U20A20235,52171127)Guangdong East Northwest New R&D Institution Construction(No.2019B090905009)Guangdong Aluminum Strip and Foil Processing Enterprise Research Institute(No.2014B090903012).
文摘An alloyed cast iron was prepared by horizontal continuous casting.To study the salt bath temperature on microstructure and mechanical properties,the alloyed cast iron was firstly austenitized at 950℃for 3 h and then austempered in salt bath at various temperatures(250℃,300℃and 350℃)for another 3 h.The scanning electron microscopy(SEM),electron backscattered diffraction(EBSD),and X-ray diffraction(XRD)were employed to observe the microstructure and test the mechanical properties of the alloyed cast iron.Results show that the microstructure of the alloyed cast iron is mainly composed of acicular or feathery ferrite(bainite),retained austenite,carbide,and graphite.When austempered in salt bath at 250℃,300℃and 350℃for 3 h,the volume fractions of retained austenite are 33.1%,41.7%,and 57.2%,the thickness of acicular ferrite are 0.25μm,0.3μm,and 0.8μm.As the salt bath austempering temperature increases,the mechanical properties decrease due to the increase of the volume fraction of retained austenite and the thickness of acicular ferrite.The highest tensile strength of the alloyed cast iron is achieved when it is austempered at 250℃in a salt bath.Under these conditions,the tensile strength of the alloyed cast iron can reach 1,429 MPa.Tensile test results indicate that the fracture mechanism is predominantly brittle fracture.
文摘Austempered ductile iron(ADI) parts have a unique combination of high strength and toughness with excellent design flexibility and low cost. These excellent properties are directly related to its microstructure called "ausferrite" that is the result of austempering heat treatment applied to ductile irons. Alloying elements increase ADI austemperability and change speeds of austempering reactions. Thus, they can affect ADI resultant microstructure and mechanical properties. In this paper, the effects of alloying elements on ADI mechanical properties, microstructural changes, two-stage austempering reactions, processing windows, austemperability, and other aspects are reviewed.
文摘The effect of sub-zero cooling on microstructure and mechanical properties of a low alloyed austempered ductile iron has been investigated. Austempering of samples was performed at 325℃and 400℃after austenitizing at 875℃and 950℃. The sub-zero treatments were carried out by cooling down the samples to -30℃, -70℃and -196℃. The changes in volume fraction of austenite and mechanical properties were determined after cooling to each temperature. The austenite volume fraction of samples which were austenitized at 875℃and austempered at 325℃remained unchanged, whilst it reduced in samples austenitized at 950℃and 875℃for austempering temperature of 400℃. In these specimens, some austenite transformed to martensite after subzero cooling. Mechanical property measurements showed a slight increase in strength and hardness and decrease in elongation and toughness due to this transformation behavior.
基金supported financially by the research council of Sahand University of Technology
文摘Shot peening is one of the most common surface treatments to improve the fatigue behavior of metallic parts. In this study the effect of shot peening process on the fatigue behavior of an alloyed austempered ductile iron (ADI) has been studied. Austempering heat treatment consisted of austenitizing at 875℃ for 90 min followed by austempering at three different temperatures of 320, 365 and 400℃. Rotating-bending fatigue test was carried out on samples after shot peening by 0.4-0.6 mm shots. XRD and SEM analysis, micro hardness and roughness tests were carried out to study the fatigue behavior of the samples. Results indicate that the fatigue strengths of samples austempered at 320, 365 and 400℃ are increased by 27.3%, 33.3% and 48.4%, respectively, after shot peening process.
文摘The wear resistances of austempered ductile iron （ADI） were improved through intxoduction of a new phase （carbide） into the ma- txix by addition of chromium. In the present investigation, low-caxbon-equivalent ductile iron （LCEDI） （CE = 3.06%, and CE represents cax- bon-equivalent） with 2.42% chromium was selected. LCEDI was austeintized at two difl＇erent temperatures （900 and 975~C） a^ld soaked for 1 h and then quenched in a salt bath at 325~C for 0 to 10 h. Samples were analyzed using optical microscopy and X-ray diffraction. Wear tests were carded out on a pin-on-disk-type machine. The efl＇ect of austenization temperature on the wear resistance, impact strength, and the mi- crostructure was evaluated. A stxucture-property correlation based on the observations is established.
基金supported by the key project for Science and Technology of Hubei Provincial Department of Education(No.D20101606)the Scientific and Technological Project of China Textile Industry Association(No.2008085)
文摘This paper presents the effects of chemical compositions of austempered ductile iron （ADI） on casting quality, heat treatment process parameters and mechanical properties of final products. Through experiment and production practice, the impacts of carbon equivalent on ADI and its mechanical properties have been studied. Proper content ranges for carbon and silicon have been obtained to avoid ADI casting shrinkage and graphite fioatation, as well as to achieve the optimal mechanical properties. According to the impact of silicon content on austenite phase transformation, the existing form of carbon in ADI has been analyzed, and also the formula and diagram showing the relationship between austenitizing temperature and carbon content in austenite have been deduced. The chemical composition range for high performance ADI and its control points have been recommended, to serve as a reference for production process.
基金the Sahand University of Technology for providing the research facilities and financial support
文摘Measurements of dry sliding wear are presented for ductile irons with composition Fe-3.56C-2.67Si- 0.25Mo-0.5Cu and Ni contents of 0.8 and 1.5 in wt.% with applied loads of 50, 100 and 150 N for austempering temperatures of 270, 320, and 370 ℃ after austenitizing at 870 ℃ for 120 min. The mechanical property measurements show that the grades of the ASTM 897M： 1990 Standard can be satisfied for the selected austempering conditions. The results show that wear resistance is independent of austempedng temperature with an applied load of 50 N, but there is a strong dependence at higher austempering temperatures with applied loads of 100 and 150 N. Observations indicate that wear is due to subsurface fatigue with cracks nucleated at deformed graphite nodules.
文摘Effects of graphite nodule diameter on the water embrittlement of austempered ductile iron (ADI) is studied. The water embrittlement mechanism is discussed. Due to water adhesion, local embrittlement occurs on the surface of ADI specimen, resulting in early fracture and significant reduction in tensile strength and elongation. The water embrittlement is the cracking of stress induced martensite formed during tensile deformation caused by hydrogen diffusion decomposed from water and as a result tensile strength and elongation of ADI are remarkably reduced. The segregation of alloying elements in ductile iron is weakened with decreasing nodule diameter, reducing the residual austenite in grain boundaries, then decreasing the amount of stress induced martensite during tensile plastic deformation and finally restraining ADI water embrittlement.
文摘The Impact toughness and fracture toughness of Austempered Ductile Iron (ADI) are described. The notched and un-notched Charpy impact toughness of ADI at room temperature are somewhat lower than that of steel castings or forged steel pieces, however, they are approximately three times higher than that of normal pearlitic ductile iron. The impact toughness of ADI decreases with decreasing temperature; but at-40℃ it still maintains about 70% of the value at room temperature. The properties of fracture toughness are important in safety design and failure analysis. In this study all fracture toughness data of ADI are higher than that of conventional ductile iron, and are equivalent to or better than that of steel castings or forged steel pieces with the tensile strength equivalent to ADI.
基金the National Science Council(No.NSC 93-2216-E-006-034).
文摘The erosion behavior of austempered ductile irons austenized at different temperatures was studied. The results indicate that the erosion rate well correlates with the mechanical properties. At high impact angles, increasing ductility and mechanical energy density results in decreasing erosion rate, whereas increasing hardness reduces the erosion rate at low impact angles. 2008 University of Science and Technology Beijing. All rights reserved.
文摘Austempered ductile iron(ADI)is composed of an ausferritic matrix with graphite nodules and has a wide range of applications because of its high mechanical strength,fatigue resistance,and wear resistance compared to other cast irons.The amount and size of the nodules can be controlled by the chemical composition and austenitizing temperature.As the nodules have lower stiffness than the matrix and can act as stress concentrators,they influence crack propagation.However,the crack propagation mechanism in ADI is not yet fully understood.In this study,we describe a numerical investigation of crack propagation in ADIs subjected to cyclic loading.The numerical model used to calculate the stress intensity factors in the material under the given conditions is built with the aid of Abaqus commercial finite element code.The crack propagation routine,which is based on the Paris law,is implemented in Python.The results of the simulation show that the presence of a nodule generates a shear load on the crack tip.Consequently,even under uniaxial tensile loading,the presence of the nodule yields a non-zero stress intensity factor in mode II,resulting in a deviation in the crack propagation path.This is the primary factor responsible for changing the crack propagation direction towards the nodule.Modifying the parameters,for example,increasing the nodule size or decreasing the distance between the nodule and crack tip,can intensify this effect.In simulations comparing two different ADIs with the same graphite fraction area,the crack in the material with more nodules reaches another nodule in a shorter propagation time(or shorter number of cycles).This suggests that the high fatigue resistance observed in ADIs may be correlated with the number of nodules intercepted by a crack and the additional energy required to nucleate new cracks.In summary,these findings contribute to a better understanding of crack propagation in ADIs,provide insights into the relationship between the presence of nodules and the fatigue resistance of these materials,and support studies that associate the increased fatigue resistance with a higher number of graphite nodules.These results can also help justify the enhanced fatigue resistance of ADIs when compared to other cast irons.
文摘Carbide formation in austempered ductile iron (ADI) alloyed with Ni and Cu has been studied by use of TEM. The results show that η carbide precipitates in the bainitic ferrite when austempered at 350℃.for 6h, but no carbide was found at the austenite/.ferrite interfaces. When austempered at 300℃, two kinds of. s carbides appear in the bainitic ferrite when austempering time reached I h, and X carbide also precipitates at the austenite /ferrite interfaces when austempering time was extended up to 6h. The bainitic. ferrite and the retained austenite follow the Nishiyama- Wasserman relationship,
文摘The aim of present work is to investigate the influencing factors on mechanical property stability of Cu-Mo-Ni alloyed austempered ductile iron （ADI）. The results show that after austenitized at 900℃ for 2 h followed by austempered at 370℃for another 2 h, the mechanical property of the alloyed ADI can reach the Germanite GGG-100 standard, i.e. σb≮1000 MPa,δ≮5%, at 95% confidence level. And the satisfactory mechanical properties were obtained when the alloyed ADI was austenitized at 850℃ to 1 000 ℃ for 1-4 h, and austempered at 355℃ to 400℃ for another 1 h to 4 h. The microstructures, including nodule number, white bright zone content （martensite-containing interdendritic segregation zone） and retained austenite content, can significantly influence the mechanical properties of the ADI. In order to obtain the good combinations of strength and ductility, the volume fraction of white bright zone should he less than 5%, and the retained austenite contents maintain hetween 30 % and 40%. The application of inoculation techniques to increase graphite nodule number can effectively reduce the white bright zone content in the structure.
基金supported by the National Natural Science Foundation of China(No.50974080)
文摘In the present paper, a new type of austempered boron alloyed high silicon cast steel has been developed, and its microstructures and mechanical properties at different temperatures were investigated. The experimental results indicate that the boron alloyed high silicon cast steel comprises a dendritic matrix and interdendritic eutectic borides in as-cast condition. The dendritic matrix is made up of pearlite, ferrite, and the interdendritic eutectic boride is with a chemical formula of M2B （M represents Fe, Cr, Mn or Mo） which is much like that of carbide in high chromium white cast iron. Pure ausferrite structure that consists of bainitic ferrite and retained austenite can be obtained in the matrix by austempering treatment to the cast steel. No carbides precipitate in the ausferrite structure and the morphology of borides remains almost unchanged after austempering treatments. Secondary boride particles precipitate during the course of austenitizing. The hardness and tensile strength of the austempered cast steel decrease with the increase of the austempering temperature, from 250℃ to 400 ℃. The impact toughness is 4-11 J.cm^-2 at room temperature and the impact fracture fractogragh indicates that the fracture is caused by the brittle fracture of the borides.
基金financially supported by the National Natural Science Foundation of China(NSFC)(Grant No.51601054)the Natural Science Foundation of Hebei Province of China(Grant Nos.E2017202095 and E2016202100)+1 种基金the Plan Program for International S&T Cooperation Projects of Hebei Province of China(Grant No.17391004D)the Tianjin Science and Technology Support Program(Grant No.16YFZCGX00140)
文摘The effects of austempering temperature on microstructure and surface residual stress of carbidic austempered ductile iron （CADI） grinding balls were systematically investigated in this work. The microstructures were oberserved by optical metallography and analyized by X-ray diffraction. The surface residual stress measured by the cutting method is mainly composed of thermal stress and phase transformation stress.The thermal stress in grinding balls was determined by ANSYS simulation technique, and the surface phase transformation stress was obtained by subtracting the simulated surface thermal stress from the measured surface residual stress. Results show that all microstructures consist of ausferrite, white-bright zones （mixture of martensite and austenite）, nodular graphite, and carbides. The distribution of ausferrite shows uniform. With the increase of austempering temperature, the volume fraction and carbon content of austenite increase, whereas the amount of white-bright zone decreases. In addition, the surface residual stress increases with the increase of austempering temperature. Only the tension exists at the austempering temperature of 200 ℃, and the pressure exists at the austempering temperature of 220-260 °C. The thermal stress changes from the tension on the inside with the radius of 0-35 mm to the pressure on the outside with the radius of 35-62.5 mm, and the stress balance state presents at the radius of 35 mm. It is also found that the transformation stress is related to the content of carbon-rich austenite, and will reduce by 5.03 MPa accompanied with 1vol.% increase of the austenite.The thermal compressive stress and the transformation tensile stress on the surface both decrease with the increase of the austempering temperature.
文摘The fracture characteristics of austempered spheroidal graphite aluminum cast iron had been investigated. The chemical content of the alloy was C3.2, Al2.2, Ni0.8 and Mg0.05 （in mass percent, %）. Impact test samples were produced from keel blocks cast in CO2 molding process. The oversized impact samples were austenitized at 850 and 950 ℃ for 2h followed by austempering at 300 and 400 ℃ for 30, 60, 120 and 180min. The austempered samples were machined and tested at room temperature. The impact strength values for those samples austempered at 400 ℃ varied between 90 and 110J. Lower bainitie structures showed impact strength values of 22 to 50J. The fractures of the samples were examined using SEM. The results showed that the upper bainitic fracture revealed a honey Comb-like topography, which confirmed the ductile fracture behavior. The lower bainitic fractures of those samples austempered for short times revealed brittle fracture.
基金supported by Swedish Institute of Sweden (No. 200/01954/2007/China Bilateral programme)
文摘Crack initiation, propagation and microfracture processes of austempered high silicon cast steel have been investigated by using an in-situ tensile stage installed inside a scanning electron microscope chamber. It is revealed that micro cracks always nucleate at the yielding near imperfections and the boundary of matrix-inclusions due to the stress concentration. There are four types of crack propagations in the matrix: crack propagates along the boundary of two clusters of bainitic ferrite; crack propagates along the boundary of ferrite-austenite in bainitic ferrite laths; crack propagates into bainitic ferrite laths; crack nucleates and propagates in the high carbon brittle plate shape martensite which is transformed from some blocky retained austenite due to plastic deformation. Based on the observation and analysis of microfracture processes, a schematic diagram of the crack nucleation and propagation process of high silicon cast steel is proposed.
基金Item Sponsored by Key Project on Natural Science for the Education Department of Anhui Province (2006KJ080A)
文摘The effect of austempering temperature on the microstructure and properties of a high chromium white cast iron was investigated with the Rietveld refinement method. The result shows that the upper bainite exists in the sampie austempered at 623 K and the martensite, lower bainite, M7C3, and retained austenite exist in the samples austempered at 563 K and 593 K. The relative content of the retained austenite increases with increasing the austemper- ing temperature from 563 K to 623 K. The higher hardness, impact toughness and impact abrasive wear resistance can be obtained for the specimen austempered at 593 K.
文摘This study aims to clarify the influence of external notch on impact characteristics of high toughness ductile cast irons prepared by austempering heat treatment. We produced ductile cast irons samples with various matrix microstructure tested by Charpy impact within five kinds of external notches whose stress concentration factors (α), with values taken from 1.0 (Un-notched) to 4.8. In addition, to clarify the initiation process of impact characteristics, we observed the evolution of microstructure surface during bending tests with a slow loading speed for the un-notched and the notched impact samples. The results showed that the impact fracture energy decreases strongly in the range of α from 1 to 2.3 but decreases slightly for α larger than 3. Moreover, the impact value of samples with austempered microstructure is sensitive to the external notch shape. The impact transition temperature increases with increasing the stress concentration factor. The fracture energy is decreasing with the external notch from the impact test since the crack initiation energy is directly affected by this later. This work contributes to get a better understanding in the basic theories of external notch effect on impact characteristics of austempered spheroidal graphite cast irons (ADI).
