Raman spectroscopy offers a great power to detect,analyze and identify molecules,and monitor their temporal dynamics and evolution when combined with single-molecule surface-enhanced Raman scattering(SM-SERS)substrate...Raman spectroscopy offers a great power to detect,analyze and identify molecules,and monitor their temporal dynamics and evolution when combined with single-molecule surface-enhanced Raman scattering(SM-SERS)substrates.Here we present a SM-SERS scheme that involves simultaneously giant chemical enhancement from WS22D materials,giant electromagnetic enhancement from plasmonic nanogap hot spot,and inhibition of molecular fluorescence influence under near-infrared laser illumination.Remarkably we find Coulomb attraction between analyte and gold nanoparticle can trigger spontaneous formation of molecule-hotspot pairing with high precision,stability and robustness.The scheme has enabled realization of universal,robust,fast,and large-scale uniform SM-SERS detection for three Raman molecules of rhodamine B,rhodamine 6G,and crystal violet with a very low detection limit of 10−16 M and at a very fast spectrum acquisition time of 50 ms.展开更多
The search for photoactive materials that are able to efficiently produce solar fuels is a growing research field to tackle the current energy crisis.Herein,we have prepared two ionic non-noble metallo-supramolecular ...The search for photoactive materials that are able to efficiently produce solar fuels is a growing research field to tackle the current energy crisis.Herein,we have prepared two ionic non-noble metallo-supramolecular polymers Se-MTpy(M=Co or Ni),and constructed their composites with single-walled carbon nanotubes(CNTs)via electrostatic attraction andπ-πinteractions for efficient and stable photocatalytic hydrogen evolution.In the photocatalytic system,the cationic Se-MTpy as host and anionic CNTs as vip are assembled into a binary composite,which exhibits superior photocatalytic activity under visible light irradiation(>420 nm).The optimized CNT@Se-CoTpy composite,containing 1.2 wt%metal loading,achieves 7 times higher hydrogen evolution rate(2.47 mmol g^(-1)h^(-1))than bare Se-CoTpy(0.35 mmol g^(-1)h^(-1)).This is attributed to the constructive formation of junctions between polymer and CNTs,facilitating interfacial charge transfer and transport for efficient proton reduction.The composite system also shows high photostability after continuous irradiation for~30 h.The combination of experimental and theoretical analysis demonstrates the higher activity for reducing H_(2)O to H_(2)of Se-CoTpy than Se-NiTpy.The feasible interfacial architecture proposed in this study represents an effective approach to achieve high photocatalytic performance.展开更多
Dynamical systems often exhibit multiple attractors representing significantly different functioning conditions.A global map of attraction basins can offer valuable guidance for stabilizing or transitioning system sta...Dynamical systems often exhibit multiple attractors representing significantly different functioning conditions.A global map of attraction basins can offer valuable guidance for stabilizing or transitioning system states.Such a map can be constructed without prior system knowledge by identifying attractors across a sufficient number of points in the state space.However,determining the attractor for each initial state can be a laborious task.Here,we tackle the challenge of reconstructing attraction basins using as few initial points as possible.In each iteration of our approach,informative points are selected through random seeding and are driven along the current classification boundary,promoting the eventual selection of points that are both diverse and enlightening.The results across various experimental dynamical systems demonstrate that our approach requires fewer points than baseline methods while achieving comparable mapping accuracy.Additionally,the reconstructed map allows us to accurately estimate the minimum escape distance required to transition the system state to a target basin.展开更多
In order to improve the competitiveness of smart tourist attractions in the tourism market,this paper selects a scenic spot in Shenyang and uses big data technology to predict the passenger flow of the scenic spot.Fir...In order to improve the competitiveness of smart tourist attractions in the tourism market,this paper selects a scenic spot in Shenyang and uses big data technology to predict the passenger flow of the scenic spot.Firstly,this paper introduces the big data-driven forecast model of scenic spot passenger flow.Based on the traditional autoregressive integral moving average model and artificial neural network model,it builds a big data analysis and forecast model.Through the analysis of data source,model building,scenic spot passenger flow accuracy,and modeling time comparison,it affirms the advantages of big data analysis in forecasting scenic spot passenger flow.Finally,it puts forward four commercial operation optimization strategies:adjusting the ticket pricing of scenic spots,upgrading the catering and accommodation services in scenic spots,planning and designing play projects,and formulating accurate scenic spot marketing strategies,in order to provide references for the optimization and upgrading of smart tourist attractions in the future.展开更多
Modeling research and empirical study on the attraction of tourism destinations were conducted from 6 aspects,i.e.quality and scale of tourism resources,economic environment of tourism destinations,policy environment,...Modeling research and empirical study on the attraction of tourism destinations were conducted from 6 aspects,i.e.quality and scale of tourism resources,economic environment of tourism destinations,policy environment,accessibility,income level of tourist source areas as well as distance between tourist source area and tourism destination.展开更多
In order to improve the management level of heritage tourist attractions and achieve their sustainable development,a comparative study has been conducted on the management mode of heritage tourist attractions in China...In order to improve the management level of heritage tourist attractions and achieve their sustainable development,a comparative study has been conducted on the management mode of heritage tourist attractions in China and foreign countries from the perspective of management foundation,management objects and management resources.Then,suggestions have been proposed from the ideology and supervision mechanism,including improving ideology,upgrading management system,completing supervision mechanism and adopting international management mode.Particularly,the paper has pointed out that it should find the best management mode based on different social and economic backgrounds of the countries of heritage tourist attractions.展开更多
What is special about the sky bridge near Qingjing Farm?Qingjing Farm in Nantou is a popular place to visit.Every year,it has a Sheep Run Festival!Thousands of visitors go each year to cheer on their favorite sheep an...What is special about the sky bridge near Qingjing Farm?Qingjing Farm in Nantou is a popular place to visit.Every year,it has a Sheep Run Festival!Thousands of visitors go each year to cheer on their favorite sheep and take pictures as they run down the mountain roads.People can enjoy many performances,games and activities during the festival,too.展开更多
Salzburg is a beautiful city in Austria.It has old buildings,pretty streets and big mountains all around.The scenery is amazing!The famous movie The Sound of Music was filmed there.Many people visit Salzburg to see th...Salzburg is a beautiful city in Austria.It has old buildings,pretty streets and big mountains all around.The scenery is amazing!The famous movie The Sound of Music was filmed there.Many people visit Salzburg to see the locations from the movie.Some even do interviews there to ask people their feelings about the movie.One famous location from the movie is the Mirabell Gardens.The actors sang the song"Do-Re-Mi"there.The gardens have colorful flowers,statues and fountains.Salzburg is a fun and exciting place to visit and explore.展开更多
基金financial support from Science and Technology Project of Guangdong(2020B010190001)National Natural Science Foundation(12434016).
文摘Raman spectroscopy offers a great power to detect,analyze and identify molecules,and monitor their temporal dynamics and evolution when combined with single-molecule surface-enhanced Raman scattering(SM-SERS)substrates.Here we present a SM-SERS scheme that involves simultaneously giant chemical enhancement from WS22D materials,giant electromagnetic enhancement from plasmonic nanogap hot spot,and inhibition of molecular fluorescence influence under near-infrared laser illumination.Remarkably we find Coulomb attraction between analyte and gold nanoparticle can trigger spontaneous formation of molecule-hotspot pairing with high precision,stability and robustness.The scheme has enabled realization of universal,robust,fast,and large-scale uniform SM-SERS detection for three Raman molecules of rhodamine B,rhodamine 6G,and crystal violet with a very low detection limit of 10−16 M and at a very fast spectrum acquisition time of 50 ms.
基金supported by the RGC Senior Research Fellowship Scheme(Grant No.SRFS2021-5S01)the Hong Kong Research Grants Council(Grant No.PolyU 15307321)+2 种基金Research Institute for Smart Energy(CDAQ),Research Centre for Nanoscience and Nanotechnology(CE2H),Research Centre for Carbon-Strategic Catalysis(CE2L)Miss Clarea Au for the Endowed Professorship in Energy(Grant No.847S)National Natural Science Foundation of China(Grant No.62205277).
文摘The search for photoactive materials that are able to efficiently produce solar fuels is a growing research field to tackle the current energy crisis.Herein,we have prepared two ionic non-noble metallo-supramolecular polymers Se-MTpy(M=Co or Ni),and constructed their composites with single-walled carbon nanotubes(CNTs)via electrostatic attraction andπ-πinteractions for efficient and stable photocatalytic hydrogen evolution.In the photocatalytic system,the cationic Se-MTpy as host and anionic CNTs as vip are assembled into a binary composite,which exhibits superior photocatalytic activity under visible light irradiation(>420 nm).The optimized CNT@Se-CoTpy composite,containing 1.2 wt%metal loading,achieves 7 times higher hydrogen evolution rate(2.47 mmol g^(-1)h^(-1))than bare Se-CoTpy(0.35 mmol g^(-1)h^(-1)).This is attributed to the constructive formation of junctions between polymer and CNTs,facilitating interfacial charge transfer and transport for efficient proton reduction.The composite system also shows high photostability after continuous irradiation for~30 h.The combination of experimental and theoretical analysis demonstrates the higher activity for reducing H_(2)O to H_(2)of Se-CoTpy than Se-NiTpy.The feasible interfacial architecture proposed in this study represents an effective approach to achieve high photocatalytic performance.
基金supported by the National Natural Science Foundation of China(Grant Nos.T2225022,12350710786,62088101,and 12161141016)Shuguang Program of Shanghai Education Development Foundation(Grant No.22SG21)Shanghai Municipal Education Commission,and the Fundamental Research Funds for the Central Universities。
文摘Dynamical systems often exhibit multiple attractors representing significantly different functioning conditions.A global map of attraction basins can offer valuable guidance for stabilizing or transitioning system states.Such a map can be constructed without prior system knowledge by identifying attractors across a sufficient number of points in the state space.However,determining the attractor for each initial state can be a laborious task.Here,we tackle the challenge of reconstructing attraction basins using as few initial points as possible.In each iteration of our approach,informative points are selected through random seeding and are driven along the current classification boundary,promoting the eventual selection of points that are both diverse and enlightening.The results across various experimental dynamical systems demonstrate that our approach requires fewer points than baseline methods while achieving comparable mapping accuracy.Additionally,the reconstructed map allows us to accurately estimate the minimum escape distance required to transition the system state to a target basin.
文摘In order to improve the competitiveness of smart tourist attractions in the tourism market,this paper selects a scenic spot in Shenyang and uses big data technology to predict the passenger flow of the scenic spot.Firstly,this paper introduces the big data-driven forecast model of scenic spot passenger flow.Based on the traditional autoregressive integral moving average model and artificial neural network model,it builds a big data analysis and forecast model.Through the analysis of data source,model building,scenic spot passenger flow accuracy,and modeling time comparison,it affirms the advantages of big data analysis in forecasting scenic spot passenger flow.Finally,it puts forward four commercial operation optimization strategies:adjusting the ticket pricing of scenic spots,upgrading the catering and accommodation services in scenic spots,planning and designing play projects,and formulating accurate scenic spot marketing strategies,in order to provide references for the optimization and upgrading of smart tourist attractions in the future.
文摘Modeling research and empirical study on the attraction of tourism destinations were conducted from 6 aspects,i.e.quality and scale of tourism resources,economic environment of tourism destinations,policy environment,accessibility,income level of tourist source areas as well as distance between tourist source area and tourism destination.
文摘In order to improve the management level of heritage tourist attractions and achieve their sustainable development,a comparative study has been conducted on the management mode of heritage tourist attractions in China and foreign countries from the perspective of management foundation,management objects and management resources.Then,suggestions have been proposed from the ideology and supervision mechanism,including improving ideology,upgrading management system,completing supervision mechanism and adopting international management mode.Particularly,the paper has pointed out that it should find the best management mode based on different social and economic backgrounds of the countries of heritage tourist attractions.
文摘What is special about the sky bridge near Qingjing Farm?Qingjing Farm in Nantou is a popular place to visit.Every year,it has a Sheep Run Festival!Thousands of visitors go each year to cheer on their favorite sheep and take pictures as they run down the mountain roads.People can enjoy many performances,games and activities during the festival,too.
文摘Salzburg is a beautiful city in Austria.It has old buildings,pretty streets and big mountains all around.The scenery is amazing!The famous movie The Sound of Music was filmed there.Many people visit Salzburg to see the locations from the movie.Some even do interviews there to ask people their feelings about the movie.One famous location from the movie is the Mirabell Gardens.The actors sang the song"Do-Re-Mi"there.The gardens have colorful flowers,statues and fountains.Salzburg is a fun and exciting place to visit and explore.
