Based on dynamic triaxial test results of saturated soft clay, similarities of variations between accumulated pore water pressure and accumulated deformation were analyzed. The Parr＇s equation on accumulated deformat...Based on dynamic triaxial test results of saturated soft clay, similarities of variations between accumulated pore water pressure and accumulated deformation were analyzed. The Parr＇s equation on accumulated deformation was modified to create an attenuation-type curve model on accumulated pore water pressure in saturated normal consolidation clay. In this model, dynamic strength was introduced and a new parameter called equivalent dynamic stress level was added. Besides, based on comparative analysis on variations between failure-type and attenuatiun-type curves, a failure-type curve model was created on accumulated pore water pressure in saturated normal consolidation clay. Two models can take cycle number, coupling of static and dynamic deviator stress, and consolidation way into consideration. The models are verified by test results. The correlation coefficients are more than 0.98 for optimization of test results based on the two models, and there is good agreement between the optimized and test curves, which shows that the two models are suitable to predict variations of accumulated pore water pressure under different loading cases and consolidation ways. In order to improve prediction accuracy, it is suggested that loading cases and consolidation ways should be consistent with in-situ conditions when dynamic triaxial tests are used to determine the constants in the models.展开更多
The photoinduced bulk polymerization of a reactive-hindered amine light stabilizers (r-HALS), 4-acryloyl-2, 2, 6,6-tetramethylpiperidinyl (ATMP), was performed at 80 C by using a DPC technique. An unique periodic expo...The photoinduced bulk polymerization of a reactive-hindered amine light stabilizers (r-HALS), 4-acryloyl-2, 2, 6,6-tetramethylpiperidinyl (ATMP), was performed at 80 C by using a DPC technique. An unique periodic exponential attenuation-type oscillating curve was found when the polymerization was carried out in air, but this phenomenon was not found in nitrogen. It is supposed that this unique kinetic performance may be attributed to nitroxyl radicals that are produced in situ from the oxidation of ATMP. ATMP polymer with narrow polydispersity (d = 1.03) can be obtained by photoinduced solution polymerization of ATMP. The signal detected in ESR may be assigned to the nitroxyl radicals in the matrix of ATMP polymer. Since this kind of recycling of nitroxyl radicals is well documented for the photostabilizing mechanism of HALS, the present results may serve as a kinetic evidence for this mechanism.展开更多
基金Project(2009AA11Z101) supported by National High Technology Research and Development Program of ChinaProject supported by Postdoctoral Science Foundation of Central South University,China+1 种基金Project(2012QNZT045) supported by Fundamental Research Funds for Central Universities of ChinaProject(2011CB710601) supported by the National Basic Research Program of China
文摘Based on dynamic triaxial test results of saturated soft clay, similarities of variations between accumulated pore water pressure and accumulated deformation were analyzed. The Parr＇s equation on accumulated deformation was modified to create an attenuation-type curve model on accumulated pore water pressure in saturated normal consolidation clay. In this model, dynamic strength was introduced and a new parameter called equivalent dynamic stress level was added. Besides, based on comparative analysis on variations between failure-type and attenuatiun-type curves, a failure-type curve model was created on accumulated pore water pressure in saturated normal consolidation clay. Two models can take cycle number, coupling of static and dynamic deviator stress, and consolidation way into consideration. The models are verified by test results. The correlation coefficients are more than 0.98 for optimization of test results based on the two models, and there is good agreement between the optimized and test curves, which shows that the two models are suitable to predict variations of accumulated pore water pressure under different loading cases and consolidation ways. In order to improve prediction accuracy, it is suggested that loading cases and consolidation ways should be consistent with in-situ conditions when dynamic triaxial tests are used to determine the constants in the models.
基金the National Natural Science Foundation of China(No.20274023)key project foundation of National Ministry of Education(No.02114)Guangdong Province Natural Science Foundation of China(No.021241)for supporting this work.
文摘The photoinduced bulk polymerization of a reactive-hindered amine light stabilizers (r-HALS), 4-acryloyl-2, 2, 6,6-tetramethylpiperidinyl (ATMP), was performed at 80 C by using a DPC technique. An unique periodic exponential attenuation-type oscillating curve was found when the polymerization was carried out in air, but this phenomenon was not found in nitrogen. It is supposed that this unique kinetic performance may be attributed to nitroxyl radicals that are produced in situ from the oxidation of ATMP. ATMP polymer with narrow polydispersity (d = 1.03) can be obtained by photoinduced solution polymerization of ATMP. The signal detected in ESR may be assigned to the nitroxyl radicals in the matrix of ATMP polymer. Since this kind of recycling of nitroxyl radicals is well documented for the photostabilizing mechanism of HALS, the present results may serve as a kinetic evidence for this mechanism.
