The SmBaCuMO5+δ (M=Fe, Co, Ni) (SBCM) powders were synthesized by the citrate sol-gel method and the powders were sintered to ceramic pellets. The powders and sintered ceramic pellets were characterized with XRD, TEM...The SmBaCuMO5+δ (M=Fe, Co, Ni) (SBCM) powders were synthesized by the citrate sol-gel method and the powders were sintered to ceramic pellets. The powders and sintered ceramic pellets were characterized with XRD, TEM and SEM measurements. The cathode catalytic performances of SBCM ceramic pellets for ammonia synthesis were studied from wet hydrogen and dry nitrogen at atmospheric pressure and low temperature, using SBCM ceramic pellets as cathode, Nafion proton exchange membrane as electrolyte, Ni-Ce0.8Sm0....展开更多
To explore the reaction behavior of trace oxygen during the flash combustion process of falling FeSi75 powder in a nitrogen flow, a flash-combustion-synthesized Fe-Si;N;sample was heat-treated to remove SiO;. The samp...To explore the reaction behavior of trace oxygen during the flash combustion process of falling FeSi75 powder in a nitrogen flow, a flash-combustion-synthesized Fe-Si;N;sample was heat-treated to remove SiO;. The samples before and after the treatment were investigated by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy, and the formation mechanism of SiO;was investigated. The results show that SiO;in the Fe-Si;N;is mainly located on the surface or around the Si;N;particles in dense areas, existing in both crystalline and amorphous states; when the FeSi75 particles, which are less than 0.074 mm in size, fell in up-flowing hot N;stream, trace oxygen in the N;stream did not significantly hinder the nitridation of FeSi75 particles as it was consumed by the surface oxidation of the generated Si;N;particles to form SiO;. At the reaction zone, the oxidation of Si;N;particles decreased the oxygen partial pressure in the N;stream and greatly reduced the opportunity for FeSi75 particles to be oxidized into SiO;; by virtue of the SiO;film developed on the surface, the Si;N;particles adhered to each other and formed dense areas in the material.展开更多
The method for synthesis of corrected three-wavelengths spectrometers for trace gas components of atmo- sphere on the basis of development of mathematical model has been suggested. The classification table for possibl...The method for synthesis of corrected three-wavelengths spectrometers for trace gas components of atmo- sphere on the basis of development of mathematical model has been suggested. The classification table for possible structures of corrected spectrometers is considered. The synthesis allows to reveal some new variants for development of three-wavelength spectrometers for trace gas components of atmosphere. For experimental checkup of achieved theoretical results, a laboratory pattern of three-wavelength spectrome- ter is developed and tested.展开更多
基金Project supported by the National Natural Science Foundation of China (20863007)
文摘The SmBaCuMO5+δ (M=Fe, Co, Ni) (SBCM) powders were synthesized by the citrate sol-gel method and the powders were sintered to ceramic pellets. The powders and sintered ceramic pellets were characterized with XRD, TEM and SEM measurements. The cathode catalytic performances of SBCM ceramic pellets for ammonia synthesis were studied from wet hydrogen and dry nitrogen at atmospheric pressure and low temperature, using SBCM ceramic pellets as cathode, Nafion proton exchange membrane as electrolyte, Ni-Ce0.8Sm0....
基金financially supported by the National Nature Science Foundation of China (No.51572019)
文摘To explore the reaction behavior of trace oxygen during the flash combustion process of falling FeSi75 powder in a nitrogen flow, a flash-combustion-synthesized Fe-Si;N;sample was heat-treated to remove SiO;. The samples before and after the treatment were investigated by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy, and the formation mechanism of SiO;was investigated. The results show that SiO;in the Fe-Si;N;is mainly located on the surface or around the Si;N;particles in dense areas, existing in both crystalline and amorphous states; when the FeSi75 particles, which are less than 0.074 mm in size, fell in up-flowing hot N;stream, trace oxygen in the N;stream did not significantly hinder the nitridation of FeSi75 particles as it was consumed by the surface oxidation of the generated Si;N;particles to form SiO;. At the reaction zone, the oxidation of Si;N;particles decreased the oxygen partial pressure in the N;stream and greatly reduced the opportunity for FeSi75 particles to be oxidized into SiO;; by virtue of the SiO;film developed on the surface, the Si;N;particles adhered to each other and formed dense areas in the material.
文摘The method for synthesis of corrected three-wavelengths spectrometers for trace gas components of atmo- sphere on the basis of development of mathematical model has been suggested. The classification table for possible structures of corrected spectrometers is considered. The synthesis allows to reveal some new variants for development of three-wavelength spectrometers for trace gas components of atmosphere. For experimental checkup of achieved theoretical results, a laboratory pattern of three-wavelength spectrome- ter is developed and tested.
