Using a recognition model of atmospheric gravity waves(AGWs),we identified 519 AGW events from the OH airglow images observed at the Dandong and Lhasa stations from 2015 to 2017.The 317 AGW events detected at the Dand...Using a recognition model of atmospheric gravity waves(AGWs),we identified 519 AGW events from the OH airglow images observed at the Dandong and Lhasa stations from 2015 to 2017.The 317 AGW events detected at the Dandong station have wavelengths ranging from 30 to 60 km,periods from 14 to 20 min,horizontal speeds from 30 to 60 m/s,and relative intensities from 0.4%to 0.6%,respectively.The parameters of 202 events recorded at the Lhasa station mainly vary within 15-35 km in horizontal wavelength,4-6 min in period,40-100 m/s in horizontal velocity,and 0.1%-0.3%in relative intensity.The occurrence rate peaks in winter and summer at Dandong and the peak in summer are absent at Lhasa because of the lack of convective weather.The seasonal propagation directions of the waves are influenced by both the wind field-filtering effect and the distribution of wave sources.In spring,because of the southeastward background wind field,fewer southeastward events are observed at the Dandong station.The situation at the Lhasa station is similar.In summer,both the Lhasa and Dandong stations are dominated by northeastward AGWs,which can be attributed to the southwestward wind.In autumn,ray-tracing results show that the events at Dandong mainly originate from wind shear,whereas the events at the Lhasa station are triggered by convective weather.The location of the wave sources determines the trend of the propagation directions at the Dandong and Lhasa stations in autumn.In winter,because of the eastward wind,more events are propagating to the southwest at the Dandong station.展开更多
A simple and convenient method, free of template, has been proposed to synthesize hollow carambolashaped Ag2 S microspheres with Ag NO3, thiourea（TU）, Na Cl and diethanolamine as reagents using a microwave-assisted ...A simple and convenient method, free of template, has been proposed to synthesize hollow carambolashaped Ag2 S microspheres with Ag NO3, thiourea（TU）, Na Cl and diethanolamine as reagents using a microwave-assisted method, at low temperatures of below 100 ℃. Powder X-ray diffraction（XRD）,scanning electron microscopy（FESEM） and high resolution transmission electron microscopy（HRTEM）were employed to characterize the morphology and composition of those microspheres. The results indicated that the hollow carambola-shaped silver sulfide microspheres（with high purity and homogeneous morphology） were prepared by an Ostwald ripening process. A possible formation mechanism of hollow carambola-shaped Ag2 S microspheres was proposed.展开更多
This paper presents a new method to estimate the height of the atmospheric boundary layer(ABL) by using COSMIC radio occultation bending angle(BA) data. Using the numerical differentiation method combined with the reg...This paper presents a new method to estimate the height of the atmospheric boundary layer(ABL) by using COSMIC radio occultation bending angle(BA) data. Using the numerical differentiation method combined with the regularization technique, the first derivative of BA profiles is retrieved, and the height at which the first derivative of BA has the global minimum is defined to be the ABL height. To reflect the reliability of estimated ABL heights, the sharpness parameter is introduced, according to the relative minimum of the BA derivative. Then, it is applied to four months of COSMIC BA data(January, April, July, and October in 2008), and the ABL heights estimated are compared with two kinds of ABL heights from COSMIC products and with the heights determined by the finite difference method upon the refractivity data. For sharp ABL tops(large sharpness parameters), there is little difference between the ABL heights determined by different methods, i.e.,the uncertainties are small; whereas, for non-sharp ABL tops(small sharpness parameters), big differences exist in the ABL heights obtained by different methods, which means large uncertainties for different methods. In addition, the new method can detect thin ABLs and provide a reference ABL height in the cases eliminated by other methods. Thus, the application of the numerical differentiation method combined with the regularization technique to COSMIC BA data is an appropriate choice and has further application value.展开更多
As more attention is being paid to the characteristics of atmospheric amines,there is also an increasing demand for reliable detection technologies.Herein,a method was developed for simultaneous detection of atmospher...As more attention is being paid to the characteristics of atmospheric amines,there is also an increasing demand for reliable detection technologies.Herein,a method was developed for simultaneous detection of atmospheric amines in both gaseous and particulate phases using gas chromatography-mass spectrometry(GC-MS).The amine samples were collected with and without phosphoric acid filters,followed by derivatization with benzenesulfonyl chloride under alkaline condition prior to GC-MS analysis.Furthermore,the method was optimized and validated for determining 14 standard amines.The detection limits ranged from0.0408-0.421μg/mL(for gaseous samples)and 0.163-1.69μg/mL(for particulate samples),respectively.The obtained recoveries ranged from 68.8%-180%and the relative standard deviation was less than 30%,indicating high precision and good reliability of the method.Seven amines were simultaneously detected in gaseous and particulate samples in an industrial park using the developed method successfully.Methylamine,dimethylamine and diethylamine together accounted for 76.7%and 75.6%of particulate and gaseous samples,respectively.By comparing the measured and predicted values of gas-particle partition fractions,it was found that absorption process of aqueous phase played a more important role in the gas-partition of amines than physical adsorption.Moreover,the reaction between unprotonated amines and acid(aq.)in water phase likely promoted water absorption.Higher measured partition fraction of dibutylamine was likely due to the reaction with gaseous HCl.The developed method would help provide a deeper understanding of gas-particle partitioning as well as atmospheric evolution of amines.展开更多
This article proposes the hybrid method to inverse the equivalent electric charge of thunder cloud based on the data of multi-station atmospheric electric field. Firstly,the method combines the genetic algorithm( GA) ...This article proposes the hybrid method to inverse the equivalent electric charge of thunder cloud based on the data of multi-station atmospheric electric field. Firstly,the method combines the genetic algorithm( GA) and New ton method through the mosaic hybrid structure. In addition,the thunder cloud equivalent charge is inversed based on the forw ard modeling results by giving the parameters of the thunder cloud charge structure. Then an ideal model is built to examine the performance compared to the nonlinear least squares method. Finally,a typical thunderstorms process in Nanjing is analyzed by Genetic-New ton algorithm with the help of weather radar. The results show the proposed method has the strong global searching capability so that the problem of initial value selection can be solved effectively,as well as gets the better inversion results. Furthermore,the mosaic hybrid structure can absorb the advantages of tw o algorithms better,and the inversion position is consistent with the strongest radar echo.The inversion results find the upper negative charge is small and can be ignored,w hich means the triple-polarity charge structure is relatively scientific,w hich could give some references to the research like lightning forecasting,location tracking.展开更多
Matching optimization of resonant parameters among the high power inverters,low power transformers and plasma reactors have significant effects on the performance and output of the reactor array when applying the part...Matching optimization of resonant parameters among the high power inverters,low power transformers and plasma reactors have significant effects on the performance and output of the reactor array when applying the partitioned operation method.In this paper,the Matlab/Simulink electrical model was established based on the method of partitioned operation.The matching relation between resonant parameters is analyzed on the basis of experimental result.As a consequence,transformer leakage inductance and working frequency are the important parameters influencing the operational efficiency of system,leakage inductance of transformer should be adjusted based on the equivalent capacitance of plasma reactor to realize the matching optimization of resonant parameters.展开更多
A three-dimensional variational method is proposed to simultaneously retrieve the 3-D atmospheric temperature and moisture profiles from satellite radiance measurements. To include both vertical structure and the hori...A three-dimensional variational method is proposed to simultaneously retrieve the 3-D atmospheric temperature and moisture profiles from satellite radiance measurements. To include both vertical structure and the horizontal patterns of the atmospheric temperature and moisture, an EOF technique is used to decompose the temperature and moisture field in a 3-D space. A number of numerical simulations are conducted and they demonstrate that the 3-D method is less sensitive to the observation errors compared to the 1-D method. When the observation error is more than 2.0 K, to get the best results, the truncation number for the EOF＇s expansion have to be restricted to 2 in the 1-D method, while it can be set as large as 40 in a 3-D method. This results in the truncation error being reduced and the retrieval accuracy being improved in the 3-D method. Compared to the 1-D method, the rms errors of the 3-D method are reduced by 48% and 36% for the temperature and moisture retrievals, respectively. Using the real satellite measured brightness temperatures at 0557 UTC 31 July 2002, the temperature and moisture profiles are retrieved over a region （20°-45°N, 100°- 125°E） and compared with 37 collocated radiosonde observations. The results show that the retrieval accuracy with a 3-D method is significantly higher than those with the 1-D method.展开更多
Characteristics of studies on the spatial distribution of atmospheric pollutants are shown as follows: the main object of the studies in China is a single city instead of a region and the country; studying the spatial...Characteristics of studies on the spatial distribution of atmospheric pollutants are shown as follows: the main object of the studies in China is a single city instead of a region and the country; studying the spatial distribution of fine particulate matter becomes a hot spot presently;research methods have developed from traditional techniques into modernized techniques. Current methods of studying the spatial distribution of atmospheric pollutants mainly include spatial interpolation model,remote sensing method,land use regression model and BP neural network approach,etc. Each method has both advantages and disadvantages,and combining various methods to study the spatial distribution of atmospheric pollutants becomes a new problem that needs to be solved urgently.展开更多
The atmospheric scattering optical transfer function （OTF） is solved by applying the multi-coupled single scattering （MCSS） method to the three-dimensional radiative transfer equation （RTE） under the periodic gr...The atmospheric scattering optical transfer function （OTF） is solved by applying the multi-coupled single scattering （MCSS） method to the three-dimensional radiative transfer equation （RTE） under the periodic ground condition. This approach is a direct hit to the atmospheric scattering OTF using the same original context of modulation transfer function （MTF） measurement, i.e., images of sinusoidal grating at different spatial frequencies. Both the amplitude and phase shift of the OTF at various zenith and azimuth angles can be obtained at an arbitrary spatial frequency.展开更多
Tweek atmospherics are extremely low frequency and very low frequency pulse signals with frequency dispersion characteristics that originate from lightning discharges and that propagate in the Earth–ionosphere wavegu...Tweek atmospherics are extremely low frequency and very low frequency pulse signals with frequency dispersion characteristics that originate from lightning discharges and that propagate in the Earth–ionosphere waveguide over long distances.In this study,we developed an automatic method to recognize tweek atmospherics and diagnose the lower ionosphere based on the machine learning method.The differences(automatic−manual)in each ionosphere parameter between the automatic method and the manual method were−0.07±2.73 km,0.03±0.92 cm^(−3),and 91±1,068 km for the ionospheric reflection height(h),equivalent electron densities at reflection heights(Ne),and propagation distance(d),respectively.Moreover,the automatic method is capable of recognizing higher harmonic tweek sferics.The evaluation results of the model suggest that the automatic method is a powerful tool for investigating the long-term variations in the lower ionosphere.展开更多
The water level in a deep well instantly responds to the earth’s tide and atmospheric pressure, and varies accordingly, not only in terms of amplitude but also in the phase lag. Therefore, phase lag correction is use...The water level in a deep well instantly responds to the earth’s tide and atmospheric pressure, and varies accordingly, not only in terms of amplitude but also in the phase lag. Therefore, phase lag correction is used in analyzing digital groundwater observation data in eastern China. Calculation results presented by the authors in this paper show that the correction method is effective in the identification of anomalous changes for short-term seismic precursors. The correction method can also be applied to the processing of observed deformation and tilt data.展开更多
During discharge, appropriately changing the development paths of electron avalanches and increasing the number of initial electrons can effectively inhibit the formation of filamentary discharge. Based on the aforeme...During discharge, appropriately changing the development paths of electron avalanches and increasing the number of initial electrons can effectively inhibit the formation of filamentary discharge. Based on the aforementioned phenomenon, we propose a method of using microdischarge electrodes to produce a macroscopic discharge phenomenon. In the form of an asymmetric structure composed of a carbon fiber electrode, an electrode structure of carbon fiber spiral-contact type is designed to achieve an atmospheric pressure glow discharge in air, which is characterized by low discharge voltage, low energy consumption, good diffusion and less ozone generation.展开更多
This article deals with generation and application of three-dimensional (3D) atmospheric turbulence field in large aircraft real-time flight simulation. The modeling requirements for the turbulence field of large airc...This article deals with generation and application of three-dimensional (3D) atmospheric turbulence field in large aircraft real-time flight simulation. The modeling requirements for the turbulence field of large aircraft flight simulation are analyzed here. The spatial turbulence field is generated in the frequency domain by using the Monte Carlo method,and then transformed back to the time domain with the 3D inverse Fourier transform. The von Karman model is adopted for an accurate description of the turb...展开更多
The total emission control method based on atmospheric environmental capacity is the most effective in air pollution mitigation. The atmospheric environmental capacities of SO2 on representative days over Lanzhou are ...The total emission control method based on atmospheric environmental capacity is the most effective in air pollution mitigation. The atmospheric environmental capacities of SO2 on representative days over Lanzhou are estimated using the numerical models RAMS, HYPACT and a linear programming model, according to the national ambient air quality standard of China （NAAQSCHN）. The results show that the fields of meteorological elements and SO2 simulated by the models agree reasonably well with observations. The atmospheric environmental capacity of SO2 over Lanzhou is around 111.7 × 10^3 kg d^-1, and in order to meet the air quality level Ⅱ of the NAAQSCHN, SO2 emissions need to be reduced by 20%.展开更多
Atmospheric humic-like substances （HULIS） are not only an unresolved mixture of macro- organic compounds but also powerful chelating agents in atmospheric particulate matters （PMs）; impacting on both the propertie...Atmospheric humic-like substances （HULIS） are not only an unresolved mixture of macro- organic compounds but also powerful chelating agents in atmospheric particulate matters （PMs）; impacting on both the properties of aerosol particles and health effects by generating reactive oxygen spedes （ROS）. Currently, the interests of HULIS are intensively shifting to the investigations of HULIS-metal synergic effects and kinetics modeling studies, as well as the development of HULIS quantification, findings of possible HULIS sources and generation of ROS from HULIS. In light of HULIS studies, we comprehensively review the current knowledge of isolation and physicochemical characterization of HULIS from atmospheric samples as well as HULIS properties （hygroscopic, surface activity, and colloidal） and possible sources of HULIS. This review mainly highlights the generation of reactive oxygen species （ROS） from PMs, HULIS and transition metals, especially iron. This review also summarized the mechanism of iron-organic complexation and recent findings of OH formation from HULIS-metal complexes. This review will be helpful to carry out the modeling studies that concern with HULIS-transition metals and for further studies in the generation of ROS from HULIS-metal complexes,展开更多
The operational cloud-motion tracking technique fails to retrieve atmospheric motion vectors （AMVs） in areas lacking cloud; and while water vapor shown in water vapor imagery can be used, the heights assigned to the...The operational cloud-motion tracking technique fails to retrieve atmospheric motion vectors （AMVs） in areas lacking cloud; and while water vapor shown in water vapor imagery can be used, the heights assigned to the retrieved AMVs are mostly in the upper troposphere. As the noise-equivalent temperature difference （NEdT） performance of FY-2E split win- dow （10.3-11.5 μm, 11.6-12.8 μm） channels has been improved, the weak signals representing the spatial texture of water vapor and aerosols in cloud-free areas can be strengthened with algorithms based on the difference principle, and applied in calculating AMVs in the lower troposphere. This paper is a preliminary summary for this purpose, in which the principles and algorithm schemes for the temporal difference, split window difference and second-order difference （SD） methods are introduced. Results from simulation and cases experiments are reported in order to verify and evaluate the methods, based on comparison among retrievals and the ＂truth＂. The results show that all three algorithms, though not perfect in some cases, generally work well. Moreover, the SD method appears to be the best in suppressing the surface temperature influence and clarifying the spatial texture of water vapor and aerosols. The accuracy with respect to NCEP 800 hPa reanalysis data was found to be acceptable, as compared with the accuracy of the cloud motion vectors.展开更多
The hydroxyl radical(·OH)has a crucial function in the oxidation and removal of many atmospheric compounds that are harmful to health.Nevertheless,high reactivity,low atmospheric abundance,determination of hydrox...The hydroxyl radical(·OH)has a crucial function in the oxidation and removal of many atmospheric compounds that are harmful to health.Nevertheless,high reactivity,low atmospheric abundance,determination of hydroxyl,and hydroperoxyl radical’s quantity is very difficult.In the atmosphere and troposphere,hydroperoxyl radicals(HO_(2))are closely demanded in the chemical oxidation of the troposphere.But advances in technology have allowed researchers to improve the determination methods on the research of free radicals through some spectroscopic techniques.So far,several methods such as laser-induced fluorescence(LIF),high-performance liquid chromatography(HPLC),and chemical ionization mass spectroscopy have been identified and mostly used in determining the quantity of hydroxyl and hydroperoxyl radicals.In this systematic review,we have advised the use of scavenger as an advance for further researchers to circumvent some of these problems caused by free radicals.The primary goal of this review is to deepen our understanding of the functions of the most critical free radical(·OH,HO_(2))and also understand the currently used methods to quantify them in the atmosphere and troposphere.展开更多
Side-refraction is the main error source of horizontal angle surveying, but it has little influence on the sides by analyzing the influence of atmospheric-infraction on the ultrahigh-precision side and angle surveying...Side-refraction is the main error source of horizontal angle surveying, but it has little influence on the sides by analyzing the influence of atmospheric-infraction on the ultrahigh-precision side and angle surveying. Choosing oriented direction is crucial to distance and angle measurement in triangulateration network. How to select the oriented direction during angle measurement is presented, and the means to check the quality of auto-surveying with Georobot is brought forward as well. At last some solutions to reduce the influence of side-refraction while disposing and surveying ultrahigh-precision triangulateration network are put forward.展开更多
We report atmospheric turbulence parameters, namely atmospheric seeing, tilt-anisoplanatic angle(θ_0) and coherence time(Τ_0), measured under various sky conditions, at Vainu Bappu Observatory in Kavalur. Bursts of ...We report atmospheric turbulence parameters, namely atmospheric seeing, tilt-anisoplanatic angle(θ_0) and coherence time(Τ_0), measured under various sky conditions, at Vainu Bappu Observatory in Kavalur. Bursts of short exposure images of selected stars were recorded with a high-speed, frame-transfer CCD mounted on the Cassegrain focus of a newly commissioned 1.3 m telescope. The estimated median seeing is ≈ 1.85 " at wavelength of ～ 600 nm, the image motion correlation between different pairs of stars is ～44% for θ0≈ 36" and mean Τ_0 is ≈ 2.4 ms. This work was motivated by the design considerations and expected performance of an adaptive optics system that is currently being planned for the telescope.展开更多
Ce^(3+)as the active site on the CeO_(2)abrasive surface is the key to enhancing the material removal rate(MRR).The CeO_(2)abrasives with high chemical activity were prepared by the molten salt method under a reducing...Ce^(3+)as the active site on the CeO_(2)abrasive surface is the key to enhancing the material removal rate(MRR).The CeO_(2)abrasives with high chemical activity were prepared by the molten salt method under a reducing atmosphere.The crystal structure and morphology of CeO_(2)abrasive s were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),Fourier transform infrared spectroscopy(FT-IR),ultraviolet—visible diffuse reflectance spectroscopy(UV-Vis DRS),and X-ray photoelectron spectroscopy(XPS).The CeO_(2)abrasives were obtained under different atmospheres(Air,Ar,and Ar/H_(2)).With the enhancement of the reducing atmosphere,the morphology of the abrasives transforms from spherical to octahedral,while more oxygen vacancies and Ce^(3+)are generated on the surface of CeO_(2)abrasives.The CMP experiments show that the MRRs of the CeO_(2)-Air,CeO_(2)-Ar,and CeO_(2)-Ar/H_(2)abrasives on SiO_(2)substrates are 337.60,578.74,and 691.28 nm/min,respectively.Moreover,as confirmed by atomic force microscopy(AFM),the substrate surfaces exhibit low roughness(20.5 nm)after being polished using all of the prepared samples.Especially,the MRR of CeO_(2)-Ar/H_(2)abrasives is increased by 104.76%compared with CeO_(2)-air abrasives.The improved CMP performance is attributed to the increased Ce^(3+)concentration and the octahedral morphology of the abrasives enhancing the chemical reaction and mechanical removal at the abrasive-substrate interface.展开更多
基金supported by the National Key Research and Development Program of China(Grant No.2022YFF0711402)the Specialized Research Fund for State Key Laboratories。
文摘Using a recognition model of atmospheric gravity waves(AGWs),we identified 519 AGW events from the OH airglow images observed at the Dandong and Lhasa stations from 2015 to 2017.The 317 AGW events detected at the Dandong station have wavelengths ranging from 30 to 60 km,periods from 14 to 20 min,horizontal speeds from 30 to 60 m/s,and relative intensities from 0.4%to 0.6%,respectively.The parameters of 202 events recorded at the Lhasa station mainly vary within 15-35 km in horizontal wavelength,4-6 min in period,40-100 m/s in horizontal velocity,and 0.1%-0.3%in relative intensity.The occurrence rate peaks in winter and summer at Dandong and the peak in summer are absent at Lhasa because of the lack of convective weather.The seasonal propagation directions of the waves are influenced by both the wind field-filtering effect and the distribution of wave sources.In spring,because of the southeastward background wind field,fewer southeastward events are observed at the Dandong station.The situation at the Lhasa station is similar.In summer,both the Lhasa and Dandong stations are dominated by northeastward AGWs,which can be attributed to the southwestward wind.In autumn,ray-tracing results show that the events at Dandong mainly originate from wind shear,whereas the events at the Lhasa station are triggered by convective weather.The location of the wave sources determines the trend of the propagation directions at the Dandong and Lhasa stations in autumn.In winter,because of the eastward wind,more events are propagating to the southwest at the Dandong station.
基金supported by the Fundamental Research Funds for the Central Universities(No.2232013A3-05)the National Science and Technology Ministry(No.ID 2012BAK30B03)
文摘A simple and convenient method, free of template, has been proposed to synthesize hollow carambolashaped Ag2 S microspheres with Ag NO3, thiourea（TU）, Na Cl and diethanolamine as reagents using a microwave-assisted method, at low temperatures of below 100 ℃. Powder X-ray diffraction（XRD）,scanning electron microscopy（FESEM） and high resolution transmission electron microscopy（HRTEM）were employed to characterize the morphology and composition of those microspheres. The results indicated that the hollow carambola-shaped silver sulfide microspheres（with high purity and homogeneous morphology） were prepared by an Ostwald ripening process. A possible formation mechanism of hollow carambola-shaped Ag2 S microspheres was proposed.
基金supported by the National Natural Science Foundation of China (Grant No. 41475021)
文摘This paper presents a new method to estimate the height of the atmospheric boundary layer(ABL) by using COSMIC radio occultation bending angle(BA) data. Using the numerical differentiation method combined with the regularization technique, the first derivative of BA profiles is retrieved, and the height at which the first derivative of BA has the global minimum is defined to be the ABL height. To reflect the reliability of estimated ABL heights, the sharpness parameter is introduced, according to the relative minimum of the BA derivative. Then, it is applied to four months of COSMIC BA data(January, April, July, and October in 2008), and the ABL heights estimated are compared with two kinds of ABL heights from COSMIC products and with the heights determined by the finite difference method upon the refractivity data. For sharp ABL tops(large sharpness parameters), there is little difference between the ABL heights determined by different methods, i.e.,the uncertainties are small; whereas, for non-sharp ABL tops(small sharpness parameters), big differences exist in the ABL heights obtained by different methods, which means large uncertainties for different methods. In addition, the new method can detect thin ABLs and provide a reference ABL height in the cases eliminated by other methods. Thus, the application of the numerical differentiation method combined with the regularization technique to COSMIC BA data is an appropriate choice and has further application value.
基金supported from the National Natural Science Foundation of China(Nos.42020104001 and 41805103)Local Innovative and Research Team Project of Guangdong Pearl River Talents Program(No.2017BT01Z032)the Fund from Chemistry and Chemical Engineering Guangdong Laboratory(No.1922009)
文摘As more attention is being paid to the characteristics of atmospheric amines,there is also an increasing demand for reliable detection technologies.Herein,a method was developed for simultaneous detection of atmospheric amines in both gaseous and particulate phases using gas chromatography-mass spectrometry(GC-MS).The amine samples were collected with and without phosphoric acid filters,followed by derivatization with benzenesulfonyl chloride under alkaline condition prior to GC-MS analysis.Furthermore,the method was optimized and validated for determining 14 standard amines.The detection limits ranged from0.0408-0.421μg/mL(for gaseous samples)and 0.163-1.69μg/mL(for particulate samples),respectively.The obtained recoveries ranged from 68.8%-180%and the relative standard deviation was less than 30%,indicating high precision and good reliability of the method.Seven amines were simultaneously detected in gaseous and particulate samples in an industrial park using the developed method successfully.Methylamine,dimethylamine and diethylamine together accounted for 76.7%and 75.6%of particulate and gaseous samples,respectively.By comparing the measured and predicted values of gas-particle partition fractions,it was found that absorption process of aqueous phase played a more important role in the gas-partition of amines than physical adsorption.Moreover,the reaction between unprotonated amines and acid(aq.)in water phase likely promoted water absorption.Higher measured partition fraction of dibutylamine was likely due to the reaction with gaseous HCl.The developed method would help provide a deeper understanding of gas-particle partitioning as well as atmospheric evolution of amines.
基金supported by the National Natural Science Foundation of China ( Grant No. 61072133 )the Production,Learning and Research Joint Innovation Program of Jiangsu Province, China ( Grant Nos. BY2013007-02, SBY201120033)+2 种基金the Major Project Plan for Natural science Research in Colleges and Universities of Jiangsu Province, China( Grant No. 15KJA460008)the Open Topic of Atmospheric Sounding Key Open Laboratory of China Meteorological Administration ( Grant No. KLAS201407)the advantage discipline platform " Information and Communication Engineering" of Jiangsu Province,China
文摘This article proposes the hybrid method to inverse the equivalent electric charge of thunder cloud based on the data of multi-station atmospheric electric field. Firstly,the method combines the genetic algorithm( GA) and New ton method through the mosaic hybrid structure. In addition,the thunder cloud equivalent charge is inversed based on the forw ard modeling results by giving the parameters of the thunder cloud charge structure. Then an ideal model is built to examine the performance compared to the nonlinear least squares method. Finally,a typical thunderstorms process in Nanjing is analyzed by Genetic-New ton algorithm with the help of weather radar. The results show the proposed method has the strong global searching capability so that the problem of initial value selection can be solved effectively,as well as gets the better inversion results. Furthermore,the mosaic hybrid structure can absorb the advantages of tw o algorithms better,and the inversion position is consistent with the strongest radar echo.The inversion results find the upper negative charge is small and can be ignored,w hich means the triple-polarity charge structure is relatively scientific,w hich could give some references to the research like lightning forecasting,location tracking.
基金supported by National Key Technology Research and Development Program of the Ministry of Science and Technology of China(No.2013BAC06B02)Public Science and Technology Research Funds Projects of Ocean (No.201305027)+2 种基金National Natural Science Foundation of China(No.51877024)Liaoning Scientific Research Project of Department of Education of Liaoning Province(No.LZ2015007)High Level Talent Innovation Project of Dalian(No.2016RQ040)
文摘Matching optimization of resonant parameters among the high power inverters,low power transformers and plasma reactors have significant effects on the performance and output of the reactor array when applying the partitioned operation method.In this paper,the Matlab/Simulink electrical model was established based on the method of partitioned operation.The matching relation between resonant parameters is analyzed on the basis of experimental result.As a consequence,transformer leakage inductance and working frequency are the important parameters influencing the operational efficiency of system,leakage inductance of transformer should be adjusted based on the equivalent capacitance of plasma reactor to realize the matching optimization of resonant parameters.
基金the 973 Program (Grant No. 2004CB418305)the National Natural Science Foundation of China(Grant No. 40575049).
文摘A three-dimensional variational method is proposed to simultaneously retrieve the 3-D atmospheric temperature and moisture profiles from satellite radiance measurements. To include both vertical structure and the horizontal patterns of the atmospheric temperature and moisture, an EOF technique is used to decompose the temperature and moisture field in a 3-D space. A number of numerical simulations are conducted and they demonstrate that the 3-D method is less sensitive to the observation errors compared to the 1-D method. When the observation error is more than 2.0 K, to get the best results, the truncation number for the EOF＇s expansion have to be restricted to 2 in the 1-D method, while it can be set as large as 40 in a 3-D method. This results in the truncation error being reduced and the retrieval accuracy being improved in the 3-D method. Compared to the 1-D method, the rms errors of the 3-D method are reduced by 48% and 36% for the temperature and moisture retrievals, respectively. Using the real satellite measured brightness temperatures at 0557 UTC 31 July 2002, the temperature and moisture profiles are retrieved over a region （20°-45°N, 100°- 125°E） and compared with 37 collocated radiosonde observations. The results show that the retrieval accuracy with a 3-D method is significantly higher than those with the 1-D method.
基金Supported by the Major Research and Development Plan of Shandong Province,China(2015GSF117032)Scientific Research Foundation of Binzhou University(BZXY1501)Major Subject of Binzhou University(2015ZDL03)
文摘Characteristics of studies on the spatial distribution of atmospheric pollutants are shown as follows: the main object of the studies in China is a single city instead of a region and the country; studying the spatial distribution of fine particulate matter becomes a hot spot presently;research methods have developed from traditional techniques into modernized techniques. Current methods of studying the spatial distribution of atmospheric pollutants mainly include spatial interpolation model,remote sensing method,land use regression model and BP neural network approach,etc. Each method has both advantages and disadvantages,and combining various methods to study the spatial distribution of atmospheric pollutants becomes a new problem that needs to be solved urgently.
基金supported by the Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences(Grant No.KGFZD-125-13-006)
文摘The atmospheric scattering optical transfer function （OTF） is solved by applying the multi-coupled single scattering （MCSS） method to the three-dimensional radiative transfer equation （RTE） under the periodic ground condition. This approach is a direct hit to the atmospheric scattering OTF using the same original context of modulation transfer function （MTF） measurement, i.e., images of sinusoidal grating at different spatial frequencies. Both the amplitude and phase shift of the OTF at various zenith and azimuth angles can be obtained at an arbitrary spatial frequency.
基金supported by the Chinese Academy of Sciences(CAS)Project of Stable Support for Youth Team in Basic Research Field(Grant No.YSRR-018)the National Key R&D Program of China(Grant No.2019YFC1510103)+1 种基金the National Natural Science Foundation of China(Grant Nos.41875006 and U1938115)the Chinese Meridian Project,and the International Partnership Program of CAS(Grant No.183311KYSB20200003).
文摘Tweek atmospherics are extremely low frequency and very low frequency pulse signals with frequency dispersion characteristics that originate from lightning discharges and that propagate in the Earth–ionosphere waveguide over long distances.In this study,we developed an automatic method to recognize tweek atmospherics and diagnose the lower ionosphere based on the machine learning method.The differences(automatic−manual)in each ionosphere parameter between the automatic method and the manual method were−0.07±2.73 km,0.03±0.92 cm^(−3),and 91±1,068 km for the ionospheric reflection height(h),equivalent electron densities at reflection heights(Ne),and propagation distance(d),respectively.Moreover,the automatic method is capable of recognizing higher harmonic tweek sferics.The evaluation results of the model suggest that the automatic method is a powerful tool for investigating the long-term variations in the lower ionosphere.
基金This project was sponsored by the Science and Technology Development Program(031060107) ,Shandong Province .
文摘The water level in a deep well instantly responds to the earth’s tide and atmospheric pressure, and varies accordingly, not only in terms of amplitude but also in the phase lag. Therefore, phase lag correction is used in analyzing digital groundwater observation data in eastern China. Calculation results presented by the authors in this paper show that the correction method is effective in the identification of anomalous changes for short-term seismic precursors. The correction method can also be applied to the processing of observed deformation and tilt data.
基金Supported by the National Natural Science Foundation of China under Grant No 51577011
文摘During discharge, appropriately changing the development paths of electron avalanches and increasing the number of initial electrons can effectively inhibit the formation of filamentary discharge. Based on the aforementioned phenomenon, we propose a method of using microdischarge electrodes to produce a macroscopic discharge phenomenon. In the form of an asymmetric structure composed of a carbon fiber electrode, an electrode structure of carbon fiber spiral-contact type is designed to achieve an atmospheric pressure glow discharge in air, which is characterized by low discharge voltage, low energy consumption, good diffusion and less ozone generation.
文摘This article deals with generation and application of three-dimensional (3D) atmospheric turbulence field in large aircraft real-time flight simulation. The modeling requirements for the turbulence field of large aircraft flight simulation are analyzed here. The spatial turbulence field is generated in the frequency domain by using the Monte Carlo method,and then transformed back to the time domain with the 3D inverse Fourier transform. The von Karman model is adopted for an accurate description of the turb...
基金the National Natural Science Foundation of China （Grant No. 40305020）.
文摘The total emission control method based on atmospheric environmental capacity is the most effective in air pollution mitigation. The atmospheric environmental capacities of SO2 on representative days over Lanzhou are estimated using the numerical models RAMS, HYPACT and a linear programming model, according to the national ambient air quality standard of China （NAAQSCHN）. The results show that the fields of meteorological elements and SO2 simulated by the models agree reasonably well with observations. The atmospheric environmental capacity of SO2 over Lanzhou is around 111.7 × 10^3 kg d^-1, and in order to meet the air quality level Ⅱ of the NAAQSCHN, SO2 emissions need to be reduced by 20%.
基金the Natural Science Foundation of China under NSFC Grant No. 21477073, 41273127 for support to conduct this research
文摘Atmospheric humic-like substances （HULIS） are not only an unresolved mixture of macro- organic compounds but also powerful chelating agents in atmospheric particulate matters （PMs）; impacting on both the properties of aerosol particles and health effects by generating reactive oxygen spedes （ROS）. Currently, the interests of HULIS are intensively shifting to the investigations of HULIS-metal synergic effects and kinetics modeling studies, as well as the development of HULIS quantification, findings of possible HULIS sources and generation of ROS from HULIS. In light of HULIS studies, we comprehensively review the current knowledge of isolation and physicochemical characterization of HULIS from atmospheric samples as well as HULIS properties （hygroscopic, surface activity, and colloidal） and possible sources of HULIS. This review mainly highlights the generation of reactive oxygen species （ROS） from PMs, HULIS and transition metals, especially iron. This review also summarized the mechanism of iron-organic complexation and recent findings of OH formation from HULIS-metal complexes. This review will be helpful to carry out the modeling studies that concern with HULIS-transition metals and for further studies in the generation of ROS from HULIS-metal complexes,
基金supported by the National Natural Science Foundation of China(Grant Nos.41175035 and 40475018)the National Basic Research Program of China(Grant No.2009CB421502)a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘The operational cloud-motion tracking technique fails to retrieve atmospheric motion vectors （AMVs） in areas lacking cloud; and while water vapor shown in water vapor imagery can be used, the heights assigned to the retrieved AMVs are mostly in the upper troposphere. As the noise-equivalent temperature difference （NEdT） performance of FY-2E split win- dow （10.3-11.5 μm, 11.6-12.8 μm） channels has been improved, the weak signals representing the spatial texture of water vapor and aerosols in cloud-free areas can be strengthened with algorithms based on the difference principle, and applied in calculating AMVs in the lower troposphere. This paper is a preliminary summary for this purpose, in which the principles and algorithm schemes for the temporal difference, split window difference and second-order difference （SD） methods are introduced. Results from simulation and cases experiments are reported in order to verify and evaluate the methods, based on comparison among retrievals and the ＂truth＂. The results show that all three algorithms, though not perfect in some cases, generally work well. Moreover, the SD method appears to be the best in suppressing the surface temperature influence and clarifying the spatial texture of water vapor and aerosols. The accuracy with respect to NCEP 800 hPa reanalysis data was found to be acceptable, as compared with the accuracy of the cloud motion vectors.
基金the National Key R&D Program of China(No.2016YFC0202900)the National Natural Science Foundation of China(Nos.21567015 and 21407072)+5 种基金the West Light Foundation of The Chinese Academy of Sciences(2019)special fund of State Key Joint Laboratory of Environment Simulation and Pollution Control(No.20K03ESPCP)the Natural Science Foundation of Gansu Province(Nos.18JR3RA079 and 17JR5RA109)the Project of Food and Drug Administration of Gansu Province(No.2018GSFDA014)the Gansu Provincial Party Committee Young Creative Talents(No.Ganzutongzi[2017]121)the Hongliu Science Fund for Distinguished Young Scholars(2018)。
文摘The hydroxyl radical(·OH)has a crucial function in the oxidation and removal of many atmospheric compounds that are harmful to health.Nevertheless,high reactivity,low atmospheric abundance,determination of hydroxyl,and hydroperoxyl radical’s quantity is very difficult.In the atmosphere and troposphere,hydroperoxyl radicals(HO_(2))are closely demanded in the chemical oxidation of the troposphere.But advances in technology have allowed researchers to improve the determination methods on the research of free radicals through some spectroscopic techniques.So far,several methods such as laser-induced fluorescence(LIF),high-performance liquid chromatography(HPLC),and chemical ionization mass spectroscopy have been identified and mostly used in determining the quantity of hydroxyl and hydroperoxyl radicals.In this systematic review,we have advised the use of scavenger as an advance for further researchers to circumvent some of these problems caused by free radicals.The primary goal of this review is to deepen our understanding of the functions of the most critical free radical(·OH,HO_(2))and also understand the currently used methods to quantify them in the atmosphere and troposphere.
文摘Side-refraction is the main error source of horizontal angle surveying, but it has little influence on the sides by analyzing the influence of atmospheric-infraction on the ultrahigh-precision side and angle surveying. Choosing oriented direction is crucial to distance and angle measurement in triangulateration network. How to select the oriented direction during angle measurement is presented, and the means to check the quality of auto-surveying with Georobot is brought forward as well. At last some solutions to reduce the influence of side-refraction while disposing and surveying ultrahigh-precision triangulateration network are put forward.
文摘We report atmospheric turbulence parameters, namely atmospheric seeing, tilt-anisoplanatic angle(θ_0) and coherence time(Τ_0), measured under various sky conditions, at Vainu Bappu Observatory in Kavalur. Bursts of short exposure images of selected stars were recorded with a high-speed, frame-transfer CCD mounted on the Cassegrain focus of a newly commissioned 1.3 m telescope. The estimated median seeing is ≈ 1.85 " at wavelength of ～ 600 nm, the image motion correlation between different pairs of stars is ～44% for θ0≈ 36" and mean Τ_0 is ≈ 2.4 ms. This work was motivated by the design considerations and expected performance of an adaptive optics system that is currently being planned for the telescope.
基金the National Natural Science Foundation of China(51905324)the Scientific Research Program Funded by Shaanxi Provincial Education Department(20JK0545)the Doctoral Scientific Research Startup Foundation of Shaanxi University of Science and Technology(2018BJ-14)。
文摘Ce^(3+)as the active site on the CeO_(2)abrasive surface is the key to enhancing the material removal rate(MRR).The CeO_(2)abrasives with high chemical activity were prepared by the molten salt method under a reducing atmosphere.The crystal structure and morphology of CeO_(2)abrasive s were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),Fourier transform infrared spectroscopy(FT-IR),ultraviolet—visible diffuse reflectance spectroscopy(UV-Vis DRS),and X-ray photoelectron spectroscopy(XPS).The CeO_(2)abrasives were obtained under different atmospheres(Air,Ar,and Ar/H_(2)).With the enhancement of the reducing atmosphere,the morphology of the abrasives transforms from spherical to octahedral,while more oxygen vacancies and Ce^(3+)are generated on the surface of CeO_(2)abrasives.The CMP experiments show that the MRRs of the CeO_(2)-Air,CeO_(2)-Ar,and CeO_(2)-Ar/H_(2)abrasives on SiO_(2)substrates are 337.60,578.74,and 691.28 nm/min,respectively.Moreover,as confirmed by atomic force microscopy(AFM),the substrate surfaces exhibit low roughness(20.5 nm)after being polished using all of the prepared samples.Especially,the MRR of CeO_(2)-Ar/H_(2)abrasives is increased by 104.76%compared with CeO_(2)-air abrasives.The improved CMP performance is attributed to the increased Ce^(3+)concentration and the octahedral morphology of the abrasives enhancing the chemical reaction and mechanical removal at the abrasive-substrate interface.
