Atmospheric humidity is a sustainable low-value energy widely existing in natural environment,which is a promising candidate to solve the noncontinuous and low efficiency of low-value energy power generation.Here the ...Atmospheric humidity is a sustainable low-value energy widely existing in natural environment,which is a promising candidate to solve the noncontinuous and low efficiency of low-value energy power generation.Here the mono-substituted Dawson-type polyoxometalates are constructed to be highly dispersed organic ammonium-polyoxoanion clusters and are assembled into thin films power generators with micropores,working in atmospheric humidity.The optimal polyoxometalates generator with the thickness of 7.2μm and the area of 0.36 cm^(2) produces a voltage of 0.68 V and a current density of 19.5μA·cm^(-2) under simulated natural environment,and works continuously and stably under almost all-natural environments(humidity 10%–90%).The highly dispersed polyoxometalate nanoclusters can form microporous in polyoxometalate films to effectively absorb atmospheric humidity and spontaneously form distribution gradient of water,which is the structural basis of power generation.The continuous power generation may be maintained by the effective adsorption and utilization of H_(2)O,the huge electrostatic field of organic ammonium-polyoxoanion clusters,and the reasonably designed polyoxometalates containing inorganic small ions with high mobility.It is the first humidity generator designed with polyoxometalates,which may provide a new research direction for polyoxometalates in sustainable utilization of low-value energy.展开更多
Sexual reproduction is prevalent in eukaryotic organisms and plays a critical role in the evolution of new traits and in the generation of genetic diversity.Environmental factors often have a direct impact on the occu...Sexual reproduction is prevalent in eukaryotic organisms and plays a critical role in the evolution of new traits and in the generation of genetic diversity.Environmental factors often have a direct impact on the occurrence and frequency of sexual reproduction in fungi.The regulatory effects of atmospheric relative humidity(RH)on sexual reproduction and pathogenesis in plant fungal pathogens and in soil fungi have been extensively investigated.However,the knowledge of how RH regulates the lifecycles of human fungal pathogens is limited.In this study,we report that low atmospheric RH promotes the development of mating projections and same-sex(homothallic)mating in the human fungal pathogen Candida albicans.Low RH causes water loss in C.albicans cells,which results in osmotic stress and the generation of intracellular reactive oxygen species(ROS)and trehalose.The water transporting aquaporin Aqy1,and the G-protein coupled receptor Gpr1 function as cell surface sensors of changes in atmospheric humidity.Perturbation of the trehalose metabolic pathway by inactivating trehalose synthase or trehalase promotes same-sex mating in C.albicans by increasing osmotic or ROS stresses,respectively.Intracellular trehalose and ROS signal the Hog1-osmotic and Hsf1-Hsp90 signaling pathways to regulate the mating response.We,therefore,propose that the cell surface sensors Aqy1 and Gpr1,intracellular trehalose and ROS,and the Hog1-osmotic and Hsf1-Hsp90 signaling pathways function coordinately to regulate sexual mating in response to low atmospheric RH conditions in C.albicans.展开更多
In this study, we examined the key particles and chemical reactions that substantially influence plasma characteristics. In summarizing the chemical reaction model for the discharge process of N_(2)–O_(2)–H_(2)O(g)m...In this study, we examined the key particles and chemical reactions that substantially influence plasma characteristics. In summarizing the chemical reaction model for the discharge process of N_(2)–O_(2)–H_(2)O(g)mixed gases, 65 particle types and 673 chemical reactions were investigated. On this basis, a global model of atmospheric pressure humid air discharge plasma was developed, with a focus on the variation of charged particles densities and chemical reaction rates with time under the excitation of a 0–200 Td pulsed electric field. Particles with a density greater than 1% of the electron density were classified as key particles. For such particles, the top ranking generation or consumption reactions(i.e. where the sum of their rates was greater than 95% of the total rate of the generation or consumption reactions) were classified as key chemical reactions. On the basis of the key particles and reactions identified, a simplified global model was derived. A comparison of the global model with the simplified global model in terms of the model parameters, particle densities, reaction rates(with time), and calculation efficiencies demonstrated that both models can adequately identify the key particles and chemical reactions reflecting the chemical process of atmospheric pressure discharge plasma in humid air. Thus, by analyzing the key particles and chemical reaction pathways, the charge and substance transfer mechanism of atmospheric pressure pulse discharge plasma in humid air was revealed, and the mechanism underlying water vapor molecules’ influence on atmospheric pressure air discharge was elucidated.展开更多
By utilizing the data observed at Dunhuang during August and September 2000 in the 'Field Experiment on Interaction between Land and Atmosphere in the Arid Region of Northwest China (FEILARNC)', the characteri...By utilizing the data observed at Dunhuang during August and September 2000 in the 'Field Experiment on Interaction between Land and Atmosphere in the Arid Region of Northwest China (FEILARNC)', the characteristics of the soil moisture, temperature, and atmospheric humidity are analyzed. It is found that the thickness of the soil temperature active layer is about 5 cm and much thinner than is typical, that not only the atmospheric humidity gradient is often inverted but also the soil moisture gradient in the shallow layer in the Gobi near oasis, that the diurnal variation of soil moisture can be divided into the four stages that are called the wet stage, the losing-water stage, the dry stage, and the attaining-water stage. It is shown that in soil moisture profiles, the depth of the soil moisture active layer is about 10 cm and soil moisture inversion is the main feature in the shallow layer during the wet stage. Such a feature as soil moisture inversion indicates that soil in the shallow layer can inhale moisture from the air through condensation in the nighttime and exhale moisture to the air through evaporation in the daytime. The condensation and evaporation constitute together the full respiration process of moisture on the ground. The formation of soil moisture inversion is related with the state of soil temperature and moisture, the intensity of atmospheric humidity inversion, and the atmospheric thermodynamic stability.展开更多
The rechargeable Li-O_(2) battery endowed with high theoretical specific energy density has sparked intense research interest as a promising energy storage system. However, the intrinsic high activity of Li anode,espe...The rechargeable Li-O_(2) battery endowed with high theoretical specific energy density has sparked intense research interest as a promising energy storage system. However, the intrinsic high activity of Li anode,especially to moisture, usually leads to inferior electrochemical performance of Li-O_(2) battery in humid environments, hindering its widespread application. To settle the trouble of poor moisture tolerance, fabricating a water-proof layer on the Li-metal anode could be an effective tactic. Herein, a facile strategy for constructing an ibuprofen-based protective layer on the Li anode has been proposed to realize highly rechargeable Li-O_(2) battery in humid atmosphere. Due to the in-situ reaction between ibuprofen reagent and metallic Li, the protective layer with a thickness of ~30 μm has been uniformly deposited on the surface of Li anode. Particularly, the protective layer, consisting of a large amount of hydrophobic alkyl group and benzene ring, can significantly resist water ingress and enhance the electrochemical stability of Li anode. As a result, the Li-O_(2) battery based on the protected Li anode achieves a long cycle life of 210 h(21 cycles at 1000 m Ah/g, 200 m A/g) in highly moist atmosphere with relative humidity(RH) of68%. This convenient and efficient strategy offers novel design concept of water-resistant metal anode,and paves the way to the promising future prospect for the high-energy Li-O_(2) battery implementing in the ambient atmosphere.展开更多
Previous studies on haze formation focused mainly on the various chemical components in aerosol particles and their physicochemical effects on particle behaviour(e.g.,generation,growth,and agglomeration).This paper de...Previous studies on haze formation focused mainly on the various chemical components in aerosol particles and their physicochemical effects on particle behaviour(e.g.,generation,growth,and agglomeration).This paper describes the measurement of the charging state on atmospheric aerosol particles,which could be affected by meteorological conditions.A series of experiments on particle charging state and meteorological factors was undertaken on the roof of the west 4th building on the Qujiang Campus at Xi'an Jiaotong University(China).Measurements were conducted approximately 20 m above ground level,Our results showed that most atmospheric particles carried net negative or positive charge and that the electric charge on the particles varied diurnally and seasonally.The average amount of charge on particles was higher in winter than in summer.The number concentration of charged particles was higher during the day than overnight.Obvious difference in the average charge of aerosol particles was found between sand-dust days and haze days.A strong relationship was found between the PM2.s concentration,charge amount on particles,and humidity.Our findings show that particle formation and growth could partly be attributed to variation in particle charging state,which is related to meteorological conditions including atmospheric humidity.展开更多
基金supported by the National Natural Science Foundation of China(Nos.22271042 and 21871041)the Science and Technology Research Project of the Education Department of Jilin Province(No.JJKH20211286KJ)the Natural Science Foundation of Jilin Province(No.20180101298JC).
文摘Atmospheric humidity is a sustainable low-value energy widely existing in natural environment,which is a promising candidate to solve the noncontinuous and low efficiency of low-value energy power generation.Here the mono-substituted Dawson-type polyoxometalates are constructed to be highly dispersed organic ammonium-polyoxoanion clusters and are assembled into thin films power generators with micropores,working in atmospheric humidity.The optimal polyoxometalates generator with the thickness of 7.2μm and the area of 0.36 cm^(2) produces a voltage of 0.68 V and a current density of 19.5μA·cm^(-2) under simulated natural environment,and works continuously and stably under almost all-natural environments(humidity 10%–90%).The highly dispersed polyoxometalate nanoclusters can form microporous in polyoxometalate films to effectively absorb atmospheric humidity and spontaneously form distribution gradient of water,which is the structural basis of power generation.The continuous power generation may be maintained by the effective adsorption and utilization of H_(2)O,the huge electrostatic field of organic ammonium-polyoxoanion clusters,and the reasonably designed polyoxometalates containing inorganic small ions with high mobility.It is the first humidity generator designed with polyoxometalates,which may provide a new research direction for polyoxometalates in sustainable utilization of low-value energy.
基金supported by the National Key Research and Development Program of China(2021YFC2300400)the National Natural Science Foundation of China(31930005 and 32170194)+2 种基金Shanghai Municipal Science and Technology Major Project(HS2021SHZX001)supported by the National Institutes of Health(NIH)National Institute of General Medical Sciences(NIGMS)award R35GM124594by the Kamangar family in the form of an endowed chair to C.J.N.
文摘Sexual reproduction is prevalent in eukaryotic organisms and plays a critical role in the evolution of new traits and in the generation of genetic diversity.Environmental factors often have a direct impact on the occurrence and frequency of sexual reproduction in fungi.The regulatory effects of atmospheric relative humidity(RH)on sexual reproduction and pathogenesis in plant fungal pathogens and in soil fungi have been extensively investigated.However,the knowledge of how RH regulates the lifecycles of human fungal pathogens is limited.In this study,we report that low atmospheric RH promotes the development of mating projections and same-sex(homothallic)mating in the human fungal pathogen Candida albicans.Low RH causes water loss in C.albicans cells,which results in osmotic stress and the generation of intracellular reactive oxygen species(ROS)and trehalose.The water transporting aquaporin Aqy1,and the G-protein coupled receptor Gpr1 function as cell surface sensors of changes in atmospheric humidity.Perturbation of the trehalose metabolic pathway by inactivating trehalose synthase or trehalase promotes same-sex mating in C.albicans by increasing osmotic or ROS stresses,respectively.Intracellular trehalose and ROS signal the Hog1-osmotic and Hsf1-Hsp90 signaling pathways to regulate the mating response.We,therefore,propose that the cell surface sensors Aqy1 and Gpr1,intracellular trehalose and ROS,and the Hog1-osmotic and Hsf1-Hsp90 signaling pathways function coordinately to regulate sexual mating in response to low atmospheric RH conditions in C.albicans.
基金supported by National Natural Science Foundation of China(No.51907145)。
文摘In this study, we examined the key particles and chemical reactions that substantially influence plasma characteristics. In summarizing the chemical reaction model for the discharge process of N_(2)–O_(2)–H_(2)O(g)mixed gases, 65 particle types and 673 chemical reactions were investigated. On this basis, a global model of atmospheric pressure humid air discharge plasma was developed, with a focus on the variation of charged particles densities and chemical reaction rates with time under the excitation of a 0–200 Td pulsed electric field. Particles with a density greater than 1% of the electron density were classified as key particles. For such particles, the top ranking generation or consumption reactions(i.e. where the sum of their rates was greater than 95% of the total rate of the generation or consumption reactions) were classified as key chemical reactions. On the basis of the key particles and reactions identified, a simplified global model was derived. A comparison of the global model with the simplified global model in terms of the model parameters, particle densities, reaction rates(with time), and calculation efficiencies demonstrated that both models can adequately identify the key particles and chemical reactions reflecting the chemical process of atmospheric pressure discharge plasma in humid air. Thus, by analyzing the key particles and chemical reaction pathways, the charge and substance transfer mechanism of atmospheric pressure pulse discharge plasma in humid air was revealed, and the mechanism underlying water vapor molecules’ influence on atmospheric pressure air discharge was elucidated.
基金the National Nat-ural Science Foundation of China(No.40175004)and theNational Key Program for Developing Basic Sciences ofChina(No.G1998040904-2).
文摘By utilizing the data observed at Dunhuang during August and September 2000 in the 'Field Experiment on Interaction between Land and Atmosphere in the Arid Region of Northwest China (FEILARNC)', the characteristics of the soil moisture, temperature, and atmospheric humidity are analyzed. It is found that the thickness of the soil temperature active layer is about 5 cm and much thinner than is typical, that not only the atmospheric humidity gradient is often inverted but also the soil moisture gradient in the shallow layer in the Gobi near oasis, that the diurnal variation of soil moisture can be divided into the four stages that are called the wet stage, the losing-water stage, the dry stage, and the attaining-water stage. It is shown that in soil moisture profiles, the depth of the soil moisture active layer is about 10 cm and soil moisture inversion is the main feature in the shallow layer during the wet stage. Such a feature as soil moisture inversion indicates that soil in the shallow layer can inhale moisture from the air through condensation in the nighttime and exhale moisture to the air through evaporation in the daytime. The condensation and evaporation constitute together the full respiration process of moisture on the ground. The formation of soil moisture inversion is related with the state of soil temperature and moisture, the intensity of atmospheric humidity inversion, and the atmospheric thermodynamic stability.
基金financially supported by National Natural Science Foundation of China(No.22075171)。
文摘The rechargeable Li-O_(2) battery endowed with high theoretical specific energy density has sparked intense research interest as a promising energy storage system. However, the intrinsic high activity of Li anode,especially to moisture, usually leads to inferior electrochemical performance of Li-O_(2) battery in humid environments, hindering its widespread application. To settle the trouble of poor moisture tolerance, fabricating a water-proof layer on the Li-metal anode could be an effective tactic. Herein, a facile strategy for constructing an ibuprofen-based protective layer on the Li anode has been proposed to realize highly rechargeable Li-O_(2) battery in humid atmosphere. Due to the in-situ reaction between ibuprofen reagent and metallic Li, the protective layer with a thickness of ~30 μm has been uniformly deposited on the surface of Li anode. Particularly, the protective layer, consisting of a large amount of hydrophobic alkyl group and benzene ring, can significantly resist water ingress and enhance the electrochemical stability of Li anode. As a result, the Li-O_(2) battery based on the protected Li anode achieves a long cycle life of 210 h(21 cycles at 1000 m Ah/g, 200 m A/g) in highly moist atmosphere with relative humidity(RH) of68%. This convenient and efficient strategy offers novel design concept of water-resistant metal anode,and paves the way to the promising future prospect for the high-energy Li-O_(2) battery implementing in the ambient atmosphere.
基金supported by the Natural Science Foundation of China(Grant No.11872295)the Strategic Research Grant,City University of Hong Kong(Grant No.Cityli-SRG 7004867)the State Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment,CAS(Grant No.SKLLQG1807),China。
文摘Previous studies on haze formation focused mainly on the various chemical components in aerosol particles and their physicochemical effects on particle behaviour(e.g.,generation,growth,and agglomeration).This paper describes the measurement of the charging state on atmospheric aerosol particles,which could be affected by meteorological conditions.A series of experiments on particle charging state and meteorological factors was undertaken on the roof of the west 4th building on the Qujiang Campus at Xi'an Jiaotong University(China).Measurements were conducted approximately 20 m above ground level,Our results showed that most atmospheric particles carried net negative or positive charge and that the electric charge on the particles varied diurnally and seasonally.The average amount of charge on particles was higher in winter than in summer.The number concentration of charged particles was higher during the day than overnight.Obvious difference in the average charge of aerosol particles was found between sand-dust days and haze days.A strong relationship was found between the PM2.s concentration,charge amount on particles,and humidity.Our findings show that particle formation and growth could partly be attributed to variation in particle charging state,which is related to meteorological conditions including atmospheric humidity.
