Sodium hexametaphosphate(SHMP)was used to minimize the adverse effect of serpentine for improving aschariterecovery.The effects of particle size and content of SHMP,and serpentine on ascharite flotation process were i...Sodium hexametaphosphate(SHMP)was used to minimize the adverse effect of serpentine for improving aschariterecovery.The effects of particle size and content of SHMP,and serpentine on ascharite flotation process were investigated throughflotation,zeta potential tests,FT-IR analysis,XPS analysis and DLVO theory.Particles interaction and mechanism of SHMP werealso discussed.It was found that aggregation between serpentine and ascharite particles easily happened,and the particle size ofserpentine had a profound impact on the ascharite recovery.In particular,the fine serpentine with size less than38μm had thegreatest contribution to the deterioration of ascharite flotation performance.After SHMP treatment,the adverse effect of serpentinewas significantly reduced.The mechanism of SHMP showed that it could alter the surface charges of serpentine and ascharite toprevent severe interparticle aggregation,which resulted in a well-dispersed pulp and benefited ascharite flotation process.Theadsorption of SHMP on serpentine was due to hydrogen bonding and chemical adsorption,resulting in the formation of complex onserpentine surface to decrease its floatability.展开更多
Boric acid and kieserite were prepared from low-grade ascharite by sulfuric acid method.This method results in the recovery of 71.06%and 45.03%for boric acid and kieserite,respectively.Meanwhile,the boric acid was pre...Boric acid and kieserite were prepared from low-grade ascharite by sulfuric acid method.This method results in the recovery of 71.06%and 45.03%for boric acid and kieserite,respectively.Meanwhile,the boric acid was precipitated from the filtrate at low temperature and the solution was recycled without discharging waste liquid in the whole process.The influence of amount of sulfuric acid,mass fraction of sulfuric acid,reaction temperature and reaction time on the leaching rate of boric acid were studied. The results show that the leaching rate of boric acid reaches 93.80%under the following conditions:the amount of sulfuric acid is 85%of theoretical dosage;the mass fraction of sulfuric acid is 25%;reaction temperature is 95℃;and the reaction time is 100 min. Meanwhile,the effects of mass fraction of magnesium sulfate,crystallization temperature and crystallization time on the crystallization of kieserite were investigated and the optimal crystallization conditions are obtained:the mass fraction of magnesium sulfate is 28%;the crystallization temperature is 180℃and the crystallization time is 4h.展开更多
Gaotaigou borate deposit in Ji'an area, southeastern Jilin, is located in the easten end of Liaoning-Jilin (Liaoji)Proterozoic paleo-rift, which is a medium-sized deposit and makes up 67% of the total borate reser...Gaotaigou borate deposit in Ji'an area, southeastern Jilin, is located in the easten end of Liaoning-Jilin (Liaoji)Proterozoic paleo-rift, which is a medium-sized deposit and makes up 67% of the total borate reserves in Jilin Province.The original borate ore bodies were formed by sedimentary exhalative process in Paleoproterozoic, but were activated and enriched by later metamorphism. In late stage of metamorphism, hydrothermal fluid of metamorphic origin made wallrocks be altered and the borate ore bodies be reformed. Ore bodies are strictly controlled by strata and their lithologies. In addition, the shape and spatial distribution of ore bodies are also defined by the Gaotaigou syncline. Combined with the ore-controlling factors and mineralizing features, it has been proposed that Gaotaigou borate deposit is a metamorphosed and hydrothermally altered sedimentary exhalative deposit.展开更多
基金Project(51204033) supported by the National Natural Science Foundation of ChinaProject(L2014088) supported by Liaoning Provincial Education Department of China
文摘Sodium hexametaphosphate(SHMP)was used to minimize the adverse effect of serpentine for improving aschariterecovery.The effects of particle size and content of SHMP,and serpentine on ascharite flotation process were investigated throughflotation,zeta potential tests,FT-IR analysis,XPS analysis and DLVO theory.Particles interaction and mechanism of SHMP werealso discussed.It was found that aggregation between serpentine and ascharite particles easily happened,and the particle size ofserpentine had a profound impact on the ascharite recovery.In particular,the fine serpentine with size less than38μm had thegreatest contribution to the deterioration of ascharite flotation performance.After SHMP treatment,the adverse effect of serpentinewas significantly reduced.The mechanism of SHMP showed that it could alter the surface charges of serpentine and ascharite toprevent severe interparticle aggregation,which resulted in a well-dispersed pulp and benefited ascharite flotation process.Theadsorption of SHMP on serpentine was due to hydrogen bonding and chemical adsorption,resulting in the formation of complex onserpentine surface to decrease its floatability.
基金Project(2006AA06Z368) supported by the National High-tech Research and Development Program of China
文摘Boric acid and kieserite were prepared from low-grade ascharite by sulfuric acid method.This method results in the recovery of 71.06%and 45.03%for boric acid and kieserite,respectively.Meanwhile,the boric acid was precipitated from the filtrate at low temperature and the solution was recycled without discharging waste liquid in the whole process.The influence of amount of sulfuric acid,mass fraction of sulfuric acid,reaction temperature and reaction time on the leaching rate of boric acid were studied. The results show that the leaching rate of boric acid reaches 93.80%under the following conditions:the amount of sulfuric acid is 85%of theoretical dosage;the mass fraction of sulfuric acid is 25%;reaction temperature is 95℃;and the reaction time is 100 min. Meanwhile,the effects of mass fraction of magnesium sulfate,crystallization temperature and crystallization time on the crystallization of kieserite were investigated and the optimal crystallization conditions are obtained:the mass fraction of magnesium sulfate is 28%;the crystallization temperature is 180℃and the crystallization time is 4h.
文摘Gaotaigou borate deposit in Ji'an area, southeastern Jilin, is located in the easten end of Liaoning-Jilin (Liaoji)Proterozoic paleo-rift, which is a medium-sized deposit and makes up 67% of the total borate reserves in Jilin Province.The original borate ore bodies were formed by sedimentary exhalative process in Paleoproterozoic, but were activated and enriched by later metamorphism. In late stage of metamorphism, hydrothermal fluid of metamorphic origin made wallrocks be altered and the borate ore bodies be reformed. Ore bodies are strictly controlled by strata and their lithologies. In addition, the shape and spatial distribution of ore bodies are also defined by the Gaotaigou syncline. Combined with the ore-controlling factors and mineralizing features, it has been proposed that Gaotaigou borate deposit is a metamorphosed and hydrothermally altered sedimentary exhalative deposit.
