A novel organic-inorganic hybrid arsenatomolybdate based on infrequent[AsMoO(OH)]unit,[Cu ~I(phen)][AsMoO(OH)]·3HO(1,phen=1,10-phenanthroline),has been hydrothermally synthe-sized.This structure was determined by...A novel organic-inorganic hybrid arsenatomolybdate based on infrequent[AsMoO(OH)]unit,[Cu ~I(phen)][AsMoO(OH)]·3HO(1,phen=1,10-phenanthroline),has been hydrothermally synthe-sized.This structure was determined by single-crystal X-ray diffraction analysis,and further characterized by elemental analysis,and IR and UV spectra.To the best of our knowledge,it is the first report of a novel arsenatomolybdate subunit[AsMoO(OH)].Photoluminescence of 1 is ascribed to???*emission of the aromatic rings derived from the phen ligand.展开更多
基金supported by the Foundation of Education Department of Henan Province(15A150037)
文摘A novel organic-inorganic hybrid arsenatomolybdate based on infrequent[AsMoO(OH)]unit,[Cu ~I(phen)][AsMoO(OH)]·3HO(1,phen=1,10-phenanthroline),has been hydrothermally synthe-sized.This structure was determined by single-crystal X-ray diffraction analysis,and further characterized by elemental analysis,and IR and UV spectra.To the best of our knowledge,it is the first report of a novel arsenatomolybdate subunit[AsMoO(OH)].Photoluminescence of 1 is ascribed to???*emission of the aromatic rings derived from the phen ligand.
