Particle-to-particle dry graphene coatings on Ni-rich layered oxide materials are proposed for highenergy lithium-ion batteries(LIBs)to mitigate the inherent and engineering challenges related to the electrochemically...Particle-to-particle dry graphene coatings on Ni-rich layered oxide materials are proposed for highenergy lithium-ion batteries(LIBs)to mitigate the inherent and engineering challenges related to the electrochemically fragile surfaces,as well as limiting electrode thickness and density.Utilizing a shear stress-based coating process without supplementary solvent or heat treatment,graphene sheets derived from graphene powder are applied onto the surface of spherical LiNi_(0.89)Co_(0.055)Mn_(0.055)O_(2)(NCM)material.This process achieves a coating thickness equivalent to or fewer than 10 layers of graphene and exposes the basal plane.The graphene-coated material increases particle hardness and mitigates degradation caused by inter-particle pressure,enabling the formation of high-density electrodes without pulverization.In the absence of additional carbon-conducting agents for the high-density composite electrode with a density of 4.0 g cm^(-3),it significantly enhances rate capability,demonstrating more than 5 times improvement by achieving 149.4 mAh g^(-1)at 2 C compared to the bare sample(28.9 mAh g^(-1)).Furthermore,the dry graphene coating enables the high areal capacity of 6.98 mAh cm^(-2).By exposing the basal plane of the graphene coating,the process enhances chemical stability,effectively inhibiting side reactions at the interface and mitigating cycle degradation.展开更多
On October 25,2025,Bosideng,China's leading downwear brand,and British designer Kim Jones debuted AREAL worldwide.In Shanghai,the brand opened a dedicated pop-up and staged the global launch of the AREAL Fall/Wint...On October 25,2025,Bosideng,China's leading downwear brand,and British designer Kim Jones debuted AREAL worldwide.In Shanghai,the brand opened a dedicated pop-up and staged the global launch of the AREAL Fall/Winter 2025 Collection,followed by a gala dinner.Together,the events offered a comprehensive view of the new line and underscored the growing significance of partnerships between Chinese brands and the global fashion industry.Distinguished vips and industry leaders from across sectors at-tended to mark the milestone.展开更多
There is an urgent need to develop high-areal-capacity silicon(Si)anodes with good cycling stability and rate capability for high-energy-density lithium-ion batteries(LIBs).However,this remains a huge challenge due to...There is an urgent need to develop high-areal-capacity silicon(Si)anodes with good cycling stability and rate capability for high-energy-density lithium-ion batteries(LIBs).However,this remains a huge challenge due to large volume expansion-induced mechanical degradation and electrical connectivity loss in thick electrodes.Here,a three-in-one strategy is proposed to achieve high-areal-capacity silicon anodes by constructing a multi-level interconnected 3D porous and robust conductive network that carbon nanofibers and vertical carbon nanosheets tightly encapsulate on the surface of Si nanoparticles(Si NPs)anchored in porous carbon felts.This network accommodates large volume expansion of Si NPs to significantly improve electrode mechanical stability and creates excellent electrical connectivity to boost charge transport in thick electrodes,revealed through Multiphysics field simulations and in situ electrochemical techniques.Therefore,the designed Si anodes achieve superior long-term stability with a capacity of 8.13 mAh cm^(-2)after 500 cycles and an ultrahigh areal capacity of 45.8 mAh cm^(-2).In particular,Ah-level pouch cells demonstrate an impressive capacity retention of 79.34%after 500 cycles at 1 C.Our study offers novel insights and directions for understanding and optimizing high-areal-capacity silicon-carbon composite anodes.展开更多
The interface instability between composite solid electrolytes(CSEs)and lithium anode significantly shortens the lifespan of all-solid-state lithium batteries(ASSLBs)with high areal capacity.In this work,a CSE featuri...The interface instability between composite solid electrolytes(CSEs)and lithium anode significantly shortens the lifespan of all-solid-state lithium batteries(ASSLBs)with high areal capacity.In this work,a CSE featuring a trilayer architecture is developed by incorporating a thin polyethylene(PE)separator into a blending polymer matrix of poly(ethylene oxide)and poly(vinylidene fluoride)(PEO-PVDF)through a hot pressing technique.This structural design provides complementary functions:the flexible outer layers confine lithium deposition within a restricted area,while the robust interlayer prevents lithium dendrite penetration.Additionally,the incorporation of LiNO_(3) significantly enhances the stability of the CSE/Li interface by gradually forming a Li_(3)N-rich interfacial film,which promotes uniform lithium deposition.Consequently,the assembled Li||Li symmetrical cell demonstrates stable cycling for over 6000 h at a current density of 0.2 mA cm^(–2)with an areal capacity of 1.2 mAh cm^(–2).More attractively,ASSLBs constructed with the designed CSEs,high mass loading LFP/NCM811(LFP:LiFePO_(4);NCM811:LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2))cathodes(≥12 mg cm^(–2)),and lithium metal anodes deliver superior cycling performance without short-circuiting at current densities of 0.3/0.2 mA cm^(–2),respectively.This work offers critical insights for the design of high-performance ASSLBs with improved durability at high areal capacities.展开更多
Functional carbonaceous materials for supercapacitors(SCs)without using acid for post-treatment remain a substantial challenge.In this paper,we present a less harmful strategy for preparing three-dimensional(3D)N,O-co...Functional carbonaceous materials for supercapacitors(SCs)without using acid for post-treatment remain a substantial challenge.In this paper,we present a less harmful strategy for preparing three-dimensional(3D)N,O-codoped egg-box-like carbons(EBCs).The as-prepared EBCs with opened pores provide plentiful channels for ion fast transport,ensure the e ective contact of EBCs electrodes and electrolytes,and enhance the electron conduction.The nitrogen and oxygen atoms doped in EBCs improve the surface wettability of EBC electrodes and provide the pseudocapacitance.Consequently,the EBCs display a prominent areal capacitance of 39.8μF cm-2(340 F g-1)at 0.106 m A cm-2 in 6 M KOH electrolyte.The EBC-based symmetric SC manifests a high areal capacitance to 27.6μF cm-2(236 F g-1)at 0.1075 m A cm-2,a good rate capability of 18.8μF cm-2(160 F g-1)at 215 m A cm-2 and a long-term cycle stability with only 1.9%decay after 50,000 cycles in aqueous electrolyte.Impressively,even in all-solid-state SC,EBC electrode shows a high areal capacitance of 25.0μF cm-2(214 F g-1)and energy density of 0.0233 m Wh cm-2.This work provides an acid-free process to prepare electrode materials from industrial by-products for advanced energy storage devices.展开更多
The research on the rock burst prediction was made on the basis of seismology,rock mechanics and the data from Dongguashan Copper Mine(DCM) ,the deepest metal mine in China.The seismic responses to mining in DCM were ...The research on the rock burst prediction was made on the basis of seismology,rock mechanics and the data from Dongguashan Copper Mine(DCM) ,the deepest metal mine in China.The seismic responses to mining in DCM were investigated through the analyses of the spatio-temporal distribution of hypocenters,apparent stress and displacement of seismic events,and the process of the generation of hazardous seismicity in DCM was studied in the framework of the theory of asperity in the seismic source mechanism.A method of locating areas with hazardous seismicity and a conceptual model of hazardous seismic nucleation in DCM were proposed.A criterion of rockburst prediction was analyzed theoretically in the framework of unstable failure theories,and consequently,the rate of change in the ratio of the seismic stiffness of rock in a seismic nucleation area to that in surrounding area,dS/dt,is defined as an index of the rockburst prediction.The possibility of a rockburst will increase if dS/dt>0,and the possibility of rock burst will decrease if dS/dt<0.The correctness of these methods is demonstrated by analyses of rock failure cases in DCM.展开更多
Lithium–sulfur(Li–S)batteries have been recognized as promising substitutes for current energy-storage technologies owing to their exceptional advantages in very high-energy density and excellent material sustainabi...Lithium–sulfur(Li–S)batteries have been recognized as promising substitutes for current energy-storage technologies owing to their exceptional advantages in very high-energy density and excellent material sustainability.The cathode with high sulfur areal loading is vital for the practical applications of Li–S batteries with very high energy density.However,the high sulfur loading in an electrode results in poor rate and cycling performances of batteries in most cases.Herein,we used diameters of 5.0(D5)and 13.0(D13)mm to probe the effect of electrodes with different sizes on the rate and cycling performances under a high sulfur loading(4.5 mg cm^-2).The cell with D5 sulfur cathode exhibits better rate and cycling performances comparing with a large(D13)cathode.Both the high concentration of lithium polysulfides and corrosion of lithium metal anode impede rapid kinetics of sulfur redox reactions,which results in inferior battery performance of the Li–S cell with large diameter cathode.This work highlights the importance of rational matching of the large sulfur cathode with a high areal sulfur loading,carbon modified separators,organic electrolyte,and Li metal anode in a pouch cell,wherein the sulfur redox kinetics and lithium metal protection should be carefully considered under the flooded lithium polysulfide conditions in a working Li–S battery.展开更多
Pore structure of hard carbon has a fundamental influence on the electrochemical properties in sodium-ion batteries(SIBs).Ultra-micropores(<0.5 nm)of hard carbon can function as ionic sieves to reduce the diffusion...Pore structure of hard carbon has a fundamental influence on the electrochemical properties in sodium-ion batteries(SIBs).Ultra-micropores(<0.5 nm)of hard carbon can function as ionic sieves to reduce the diffusion of slovated Na+but allow the entrance of naked Na^(+) into the pores,which can reduce the interficial contact between the electrolyte and the inner pores without sacrificing the fast diffusion kinetics.Herein,a molten diffusion-carbonization method is proposed to transform the micropores(>1 nm)inside carbon into ultra-micropores(<0.5 nm).Consequently,the designed carbon anode displays an enhanced capacity of 346 mAh g^(−1) at 30 mA g^(−1) with a high ICE value of~80.6%and most of the capacity(~90%)is below 1 V.Moreover,the high-loading electrode(~19 mg cm^(−2))exhibits a good temperature endurance with a high areal capacity of 6.14 mAh cm^(−2) at 25℃ and 5.32 mAh cm^(−2) at −20℃.Based on the in situ X-ray diffraction and ex situ solid-state nuclear magnetic resonance results,the designed ultra-micropores provide the extra Na+storage sites,which mainly contributes to the enhanced capacity.This proposed strategy shows a good potential for the development of high-performance SIBs.展开更多
Silicon monoxide(SiO)is an attractive anode material for next-generation lithium-ion batteries for its ultra-high theoretical capacity of 2680 mAh g−1.The studies to date have been limited to electrodes with a rela-ti...Silicon monoxide(SiO)is an attractive anode material for next-generation lithium-ion batteries for its ultra-high theoretical capacity of 2680 mAh g−1.The studies to date have been limited to electrodes with a rela-tively low mass loading(<3.5 mg cm^(−2)),which has seriously restricted the areal capacity and its potential in practical devices.Maximizing areal capacity with such high-capacity materials is critical for capitalizing their potential in practi-cal technologies.Herein,we report a monolithic three-dimensional(3D)large-sheet holey gra-phene framework/SiO(LHGF/SiO)composite for high-mass-loading electrode.By specifically using large-sheet holey graphene building blocks,we construct LHGF with super-elasticity and exceptional mechanical robustness,which is essential for accommodating the large volume change of SiO and ensuring the structure integrity even at ultrahigh mass loading.Additionally,the 3D porous graphene network structure in LHGF ensures excellent electron and ion transport.By systematically tailoring microstructure design,we show the LHGF/SiO anode with a mass loading of 44 mg cm^(−2)delivers a high areal capacity of 35.4 mAh cm^(−2)at a current of 8.8 mA cm^(−2)and retains a capacity of 10.6 mAh cm^(−2)at 17.6 mA cm^(−2),greatly exceeding those of the state-of-the-art commercial or research devices.Furthermore,we show an LHGF/SiO anode with an ultra-high mass loading of 94 mg cm^(−2)delivers an unprecedented areal capacity up to 140.8 mAh cm^(−2).The achievement of such high areal capacities marks a critical step toward realizing the full potential of high-capacity alloy-type electrode materials in practical lithium-ion batteries.展开更多
Viscous fingering is one of the main challenges that could reduce areal sweep efficiency during waterflooding in oil reservoirs. A series of waterflooding experiments were carried out in a Hele-Shaw cell at ambient te...Viscous fingering is one of the main challenges that could reduce areal sweep efficiency during waterflooding in oil reservoirs. A series of waterflooding experiments were carried out in a Hele-Shaw cell at ambient temperature during which areal sweep efficiency was estimated and techniques to ease the fingering problem were examined. The onset and propagation of viscous fingers were monitored as a function of both injection rate and injection/production positions. Image processing techniques were utilized to quantitatively investigate the propagation of fingers. The experimental results show that, under specific conditions, increasing the number of finger branches could improve the areal sweep efficiency, whereas growth of a single narrow finger has a negative impact on oil displacement efficiency. According to the obtained results,increasing the injection rate improves the areal sweep efficiency up to a critical rate at which viscous fingers start to grow.The impact of heterogeneity of the medium on distributing the viscous fingers was also investigated by introducing two different arrangements of fractures in the model. The results show that fractures perpendicular to the direction of flow would distribute the displacing water more uniformly, while fractures in the direction of flow would amplify the unfavorable sweep efficiency.展开更多
Lithium-sulfur(Li-S)battery is regarded as one of the most promising next-generation energy storage systems due to the ultra-high theoretical energy density of 2600 Wh kg^(-1).To address the insulation nature of sulfu...Lithium-sulfur(Li-S)battery is regarded as one of the most promising next-generation energy storage systems due to the ultra-high theoretical energy density of 2600 Wh kg^(-1).To address the insulation nature of sulfur,nanocarbon composition is essential to afford acceptable cycling capacity but inevitably sacrifices the actual energy density under working conditions.Therefore,rational structural design of the carbon/sulfur composite cathode is of great significance to realize satisfactory electrochemical performances with limited carbon content.Herein,the cathode carbon distribution is rationally regulated to construct high-sulfur-content and high-performance Li-S batteries.Concretely,a double-layer carbon(DLC)cathode is prepared by fabricating a surface carbon layer on the carbon/sulfur composite.The surface carbon layer not only provides more electrochemically active surfaces,but also blocks the polysulfide shuttle.Consequently,the DLC configuration with an increased sulfur content by nearly 10 wt%renders an initial areal capacity of 3.40 mAh cm^(-2) and capacity retention of 83.8%during 50 cycles,which is about two times than that of the low-sulfur-content cathode.The strategy of carbon distribution regulation affords an effective pathway to construct advanced high-sulfur-content cathodes for practical high-energy-density Li-S batteries.展开更多
The lithium-sulfur battery is the subject of much recent attention due to the high theoretical energy density,but practical applications are challenged by fast decay owing to polysulfide shuttle and electrode architec...The lithium-sulfur battery is the subject of much recent attention due to the high theoretical energy density,but practical applications are challenged by fast decay owing to polysulfide shuttle and electrode architecture degradation.A comprehensive study of the sulfur host microstructure design and the cell architecture construction based on the MXene phase(Ti3C2Tx nanosheets) is performed,aiming at realize stable cycling performance of Li-S battery with high sulfur areal loading.The interwoven KB@Ti3C2Tx composite formed by self-assembly of MXene and Ktej en black,not only provides superior conductivity and maintains the electrode integrality bearing the volume expansion/shrinkage when used as the sulfur host,but also functions as an interlayer on separator to further retard the polysulfide cross-diffusion that possibly escaped from the cathode.The KB@Ti3C2Tx interlayer is only 0.28 mg cm-2 in areal loading and 3 μm in thickness,which accounts a little contribution to the thick sulfur electrode;thus,the impacts on the energy density is minimal.By coupling the robust KB@Ti3C2Tx cathode and the effective KB@Ti3C2Tx modified separator,a stable Li-S battery with high sulfur areal loading(5.6 mg cm-2) and high areal capacity(6.4 mAh cm-2) at relatively lean electrolyte is achieved.展开更多
The lithium sulfur batteries(LSBs) are considered as one of the promising next generation energy storage devices due to the high theoretical specific capacity of sulfur(1675 m Ah g-1), naturally available, low cost.Ho...The lithium sulfur batteries(LSBs) are considered as one of the promising next generation energy storage devices due to the high theoretical specific capacity of sulfur(1675 m Ah g-1), naturally available, low cost.However, the practical LSBs are impeded by the well-known "shuttle effect" combined with other technical drawbacks. The "shuttle effect" causes rapid capacity decay, severe self-discharging and low active material utilization. The polysulfide(PS) which has lone pair electrons in each sulfur atom is considered as Lewis base and shows strong affinity to various polar, Lewis acid and catenation interactive materials but very weakly interacts with the non-polar conductive carbons. The "shuttle effect" occurs due to the diffusion of high order PS from the cathode to the anode and then low-order PS back to the cathode. The PS is polar and, due to a lone pair of electrons associated with the sulfur atom, is considered a Lewis base. As such, the PS shows a strong affinity with various polar and Lewis acid materials. In addition, a more novel trapping can be performance through a catenation reaction. For LSBs to compete with the state-of-the-art lithium ion batteries(LIBs), the LSB areal capacity need to be ~6 m Ah cm-2(which is proportional to sulfur loading). To achieve this target the PS shuttling needs to mitigate, which can be achieved through using functional materials. This review addresses the aforementioned phenomena by considering the PS phase interacts with the various functional materials and how this impacts areal capacity and cycling stability of LSBs.展开更多
Inland lakes are important water resources in arid and semiarid regions. Understanding climate effects on these lakes is critical to accurately evaluate the dynamic changes of water resources. This study focused on th...Inland lakes are important water resources in arid and semiarid regions. Understanding climate effects on these lakes is critical to accurately evaluate the dynamic changes of water resources. This study focused on the changes in Sayram Lake of Xinjiang, China, and addressed the effects of climate fluctuations on the inland lake based on long-term sequenced remote sensing images and meteorological data from the past 40 years. A geo- graphic information system （GIS） method was used to obtain the hypsometry of the basin area of Sayram Lake, and estimation methods for evaporation from rising temperature and water levels from increasing precipitation were proposed. Results showed that： （1）Areal values of Sayram Lake have increased over the past 40 years. （2） Both temperature and precipitation have increased with average increases of more than 1.8~C and 82 mm, respectively. Variation of the water levels in the lake was consistent with local climate changes, and the areal values show linear relationships with local temperature and precipitation data. （3） According to the hypsometry data of the basin area, the estimated lake water levels increased by 2.8 m, and the water volume increased by 12.9×108 m3 over the past 40 years. The increasing area of Sayram Lake correlated with local and regional climatic changes because it is hardly affected by human activities.展开更多
Thick electrodes can substantially enhance the overall energy density of batteries.However,insufficient wettability of aqueous electrolytes toward electrodes with conventional hydrophobic binders severely limits utili...Thick electrodes can substantially enhance the overall energy density of batteries.However,insufficient wettability of aqueous electrolytes toward electrodes with conventional hydrophobic binders severely limits utilization of active materials with increasing the thickness of electrodes for aqueous batteries,resulting in battery performance deterioration with a reduced capacity.Here,we demonstrate that controlling the hydrophilicity of the thicker electrodes is critical to enhancing the overall energy density of batteries.Hydrophilic binders are synthesized via a simple sulfonation process of conventional polyvinylidene fluoride binders,considering physicochemical properties such as mechanical properties and adhesion.The introduction of abundant sulfonate groups of binders(i)allows fast and sufficient electrolyte wetting,and(ii)improves ionic conduction in thick electrodes,enabling a significant increase in reversible capacities under various current densities.Further,the sulfonated binder effectively inhibits the dissolution of cathode materials in reactive aqueous electrolytes.Overall,our findings significantly enhance the energy density and contribute to the development of practical zinc-ion batteries.展开更多
Ganga river basins exposed to active erosional and deformational processes. The recurrence of landslides, floods, and seismic activities makes it more susceptible to deformational activities. The tectonic analysis usi...Ganga river basins exposed to active erosional and deformational processes. The recurrence of landslides, floods, and seismic activities makes it more susceptible to deformational activities. The tectonic analysis using geomorphic indices and morphometric parameters will help in determining the hazard-prone area of the river basin. Geomorphic indices and morphometric parameters are calculated to investigate the role of neotectonic activities, as it acts as a controlling factor in the development of landforms in the tectonically active terrains. Neotectonic activities influence the terrain topography, which significantly affects the drainage system and geomorphological setup of the area. In this study, the assessment of active tectonics of study area was determined using Advanced Spaceborne Thermal Emission and Reflection Radiometer(ASTER) Global Digital Elevation Model(GDEM) based on Geomorphic Indices(Stream Length Gradient index, Hypsometric integral, Asymmetry factor, Basin shape, Valley floor width to Valley height ratio, Mountain front sinuosity index) cumulatively with Linear, Areal and Relief morphometric parameters on 27 delineated basins of the study area. The combined classification of Relative Tectonic Activity Index(Iat) and morphometric parameters of 27 basins categorized all the zones into four different classes:Class 1 – Very High(<1.97;410 km^2);Class 2 – High(1.97 – 2.05;275 km^2);Class 3 – Moderate(2.05 – 2.21;273 km^2),and Class 4 – Low(>2.21;299 km^2). The basins with tectonic activities have a consistent relationship with structural disturbances, basin geometry, and field studies. The tectonically active zonation of a part of Ganga basin using geomorphic indices and morphometric parameters suggest that it has significant influence of neotectonic activities in a part of Ganga basin.展开更多
基金supported by the Hyundai NGV and Technology Innovation Program(20010900)funded by the Ministry of Trade,Industry&Energy(MOTIE,Korea)+1 种基金the support by BK21 FOUR(Human Tech Materials-based Global Elite Cultivation Center for Student Success)funded by the Ministry of Education(MOE,Korea)supported by the Technology Innovation Program Development Program(Grant No.20017477)funded by the Ministry of Trade,Industry&Energy(MOTIE,Korea)。
文摘Particle-to-particle dry graphene coatings on Ni-rich layered oxide materials are proposed for highenergy lithium-ion batteries(LIBs)to mitigate the inherent and engineering challenges related to the electrochemically fragile surfaces,as well as limiting electrode thickness and density.Utilizing a shear stress-based coating process without supplementary solvent or heat treatment,graphene sheets derived from graphene powder are applied onto the surface of spherical LiNi_(0.89)Co_(0.055)Mn_(0.055)O_(2)(NCM)material.This process achieves a coating thickness equivalent to or fewer than 10 layers of graphene and exposes the basal plane.The graphene-coated material increases particle hardness and mitigates degradation caused by inter-particle pressure,enabling the formation of high-density electrodes without pulverization.In the absence of additional carbon-conducting agents for the high-density composite electrode with a density of 4.0 g cm^(-3),it significantly enhances rate capability,demonstrating more than 5 times improvement by achieving 149.4 mAh g^(-1)at 2 C compared to the bare sample(28.9 mAh g^(-1)).Furthermore,the dry graphene coating enables the high areal capacity of 6.98 mAh cm^(-2).By exposing the basal plane of the graphene coating,the process enhances chemical stability,effectively inhibiting side reactions at the interface and mitigating cycle degradation.
文摘On October 25,2025,Bosideng,China's leading downwear brand,and British designer Kim Jones debuted AREAL worldwide.In Shanghai,the brand opened a dedicated pop-up and staged the global launch of the AREAL Fall/Winter 2025 Collection,followed by a gala dinner.Together,the events offered a comprehensive view of the new line and underscored the growing significance of partnerships between Chinese brands and the global fashion industry.Distinguished vips and industry leaders from across sectors at-tended to mark the milestone.
基金supported by the Jiangyin-SUSTech Innovation Fundthe National Natural Science Foundation of China (No. 22309078 and 52302261)+3 种基金the Shenzhen Key Laboratory of Advanced Energy Storage (ZDSYS20220401141000001)the Shenzhen Science and Technology Plan Project(No. SGDX20230116091644003)the Guangdong Basic and Applied Basic Research Foundation (2023B1515120069)the Pico Center at SUSTech Core Research Facilities,which is supported by the Presidential Fund and the Development and Reform Commission of Shenzhen Municipality
文摘There is an urgent need to develop high-areal-capacity silicon(Si)anodes with good cycling stability and rate capability for high-energy-density lithium-ion batteries(LIBs).However,this remains a huge challenge due to large volume expansion-induced mechanical degradation and electrical connectivity loss in thick electrodes.Here,a three-in-one strategy is proposed to achieve high-areal-capacity silicon anodes by constructing a multi-level interconnected 3D porous and robust conductive network that carbon nanofibers and vertical carbon nanosheets tightly encapsulate on the surface of Si nanoparticles(Si NPs)anchored in porous carbon felts.This network accommodates large volume expansion of Si NPs to significantly improve electrode mechanical stability and creates excellent electrical connectivity to boost charge transport in thick electrodes,revealed through Multiphysics field simulations and in situ electrochemical techniques.Therefore,the designed Si anodes achieve superior long-term stability with a capacity of 8.13 mAh cm^(-2)after 500 cycles and an ultrahigh areal capacity of 45.8 mAh cm^(-2).In particular,Ah-level pouch cells demonstrate an impressive capacity retention of 79.34%after 500 cycles at 1 C.Our study offers novel insights and directions for understanding and optimizing high-areal-capacity silicon-carbon composite anodes.
基金financially supported by the National Natural Science Foundation of China(Nos.22178125 and 22478130).
文摘The interface instability between composite solid electrolytes(CSEs)and lithium anode significantly shortens the lifespan of all-solid-state lithium batteries(ASSLBs)with high areal capacity.In this work,a CSE featuring a trilayer architecture is developed by incorporating a thin polyethylene(PE)separator into a blending polymer matrix of poly(ethylene oxide)and poly(vinylidene fluoride)(PEO-PVDF)through a hot pressing technique.This structural design provides complementary functions:the flexible outer layers confine lithium deposition within a restricted area,while the robust interlayer prevents lithium dendrite penetration.Additionally,the incorporation of LiNO_(3) significantly enhances the stability of the CSE/Li interface by gradually forming a Li_(3)N-rich interfacial film,which promotes uniform lithium deposition.Consequently,the assembled Li||Li symmetrical cell demonstrates stable cycling for over 6000 h at a current density of 0.2 mA cm^(–2)with an areal capacity of 1.2 mAh cm^(–2).More attractively,ASSLBs constructed with the designed CSEs,high mass loading LFP/NCM811(LFP:LiFePO_(4);NCM811:LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2))cathodes(≥12 mg cm^(–2)),and lithium metal anodes deliver superior cycling performance without short-circuiting at current densities of 0.3/0.2 mA cm^(–2),respectively.This work offers critical insights for the design of high-performance ASSLBs with improved durability at high areal capacities.
基金the funding support of this work by the National Natural Science Foundation of China(Nos.U1710116,U1508201 and 51872005).
文摘Functional carbonaceous materials for supercapacitors(SCs)without using acid for post-treatment remain a substantial challenge.In this paper,we present a less harmful strategy for preparing three-dimensional(3D)N,O-codoped egg-box-like carbons(EBCs).The as-prepared EBCs with opened pores provide plentiful channels for ion fast transport,ensure the e ective contact of EBCs electrodes and electrolytes,and enhance the electron conduction.The nitrogen and oxygen atoms doped in EBCs improve the surface wettability of EBC electrodes and provide the pseudocapacitance.Consequently,the EBCs display a prominent areal capacitance of 39.8μF cm-2(340 F g-1)at 0.106 m A cm-2 in 6 M KOH electrolyte.The EBC-based symmetric SC manifests a high areal capacitance to 27.6μF cm-2(236 F g-1)at 0.1075 m A cm-2,a good rate capability of 18.8μF cm-2(160 F g-1)at 215 m A cm-2 and a long-term cycle stability with only 1.9%decay after 50,000 cycles in aqueous electrolyte.Impressively,even in all-solid-state SC,EBC electrode shows a high areal capacitance of 25.0μF cm-2(214 F g-1)and energy density of 0.0233 m Wh cm-2.This work provides an acid-free process to prepare electrode materials from industrial by-products for advanced energy storage devices.
基金Project(2010CB732004) supported by the National Basic Research Program of ChinaProject(50490274) supported by the National Natural Science Foundation of China
文摘The research on the rock burst prediction was made on the basis of seismology,rock mechanics and the data from Dongguashan Copper Mine(DCM) ,the deepest metal mine in China.The seismic responses to mining in DCM were investigated through the analyses of the spatio-temporal distribution of hypocenters,apparent stress and displacement of seismic events,and the process of the generation of hazardous seismicity in DCM was studied in the framework of the theory of asperity in the seismic source mechanism.A method of locating areas with hazardous seismicity and a conceptual model of hazardous seismic nucleation in DCM were proposed.A criterion of rockburst prediction was analyzed theoretically in the framework of unstable failure theories,and consequently,the rate of change in the ratio of the seismic stiffness of rock in a seismic nucleation area to that in surrounding area,dS/dt,is defined as an index of the rockburst prediction.The possibility of a rockburst will increase if dS/dt>0,and the possibility of rock burst will decrease if dS/dt<0.The correctness of these methods is demonstrated by analyses of rock failure cases in DCM.
基金supported by the National Key Research and Development Program(2016YFA0202500 and 2016YFA0200102)the National Natural Science Foundation of China(21776019,21805162,51772069,and U1801257)+1 种基金China Postdoctoral Science Foundation(2018M630165)Beijing Key Research and Development Plan(Z181100004518001)
文摘Lithium–sulfur(Li–S)batteries have been recognized as promising substitutes for current energy-storage technologies owing to their exceptional advantages in very high-energy density and excellent material sustainability.The cathode with high sulfur areal loading is vital for the practical applications of Li–S batteries with very high energy density.However,the high sulfur loading in an electrode results in poor rate and cycling performances of batteries in most cases.Herein,we used diameters of 5.0(D5)and 13.0(D13)mm to probe the effect of electrodes with different sizes on the rate and cycling performances under a high sulfur loading(4.5 mg cm^-2).The cell with D5 sulfur cathode exhibits better rate and cycling performances comparing with a large(D13)cathode.Both the high concentration of lithium polysulfides and corrosion of lithium metal anode impede rapid kinetics of sulfur redox reactions,which results in inferior battery performance of the Li–S cell with large diameter cathode.This work highlights the importance of rational matching of the large sulfur cathode with a high areal sulfur loading,carbon modified separators,organic electrolyte,and Li metal anode in a pouch cell,wherein the sulfur redox kinetics and lithium metal protection should be carefully considered under the flooded lithium polysulfide conditions in a working Li–S battery.
基金Singapore MOE Tier Ⅱ grant R143-000-A29-112the National Research Foundation under the Grant of NRF2017NRF-NSFC001-007.
文摘Pore structure of hard carbon has a fundamental influence on the electrochemical properties in sodium-ion batteries(SIBs).Ultra-micropores(<0.5 nm)of hard carbon can function as ionic sieves to reduce the diffusion of slovated Na+but allow the entrance of naked Na^(+) into the pores,which can reduce the interficial contact between the electrolyte and the inner pores without sacrificing the fast diffusion kinetics.Herein,a molten diffusion-carbonization method is proposed to transform the micropores(>1 nm)inside carbon into ultra-micropores(<0.5 nm).Consequently,the designed carbon anode displays an enhanced capacity of 346 mAh g^(−1) at 30 mA g^(−1) with a high ICE value of~80.6%and most of the capacity(~90%)is below 1 V.Moreover,the high-loading electrode(~19 mg cm^(−2))exhibits a good temperature endurance with a high areal capacity of 6.14 mAh cm^(−2) at 25℃ and 5.32 mAh cm^(−2) at −20℃.Based on the in situ X-ray diffraction and ex situ solid-state nuclear magnetic resonance results,the designed ultra-micropores provide the extra Na+storage sites,which mainly contributes to the enhanced capacity.This proposed strategy shows a good potential for the development of high-performance SIBs.
基金support by the National Natural Science Foundation of China(Nos.52074113,22005091)the Fundamental Research Funds of the Central Universities(No.531107051048)+6 种基金the Changsha Municipal Natural Science Foundantion(Grant No.43184)the CITIC Metals Ningbo Energy Co.Ltd.(No.H202191380246)Xidong Duan acknowledges support by the National Natural Science Foundation of China(Nos.51991343,51991340,61804050 and 51872086)the Hunan Key Laboratory of Two-Dimensional Materials(No.2018TP1010)Junfei Liang acknowledges support by the National Natural Science Foundation of China(No.U1910208)the National Natural Science Foundation of Shanxi Province(No.201901D111137)Tao Wang acknowledges support by the National Natural Science Foundation of China(No.22005092).
文摘Silicon monoxide(SiO)is an attractive anode material for next-generation lithium-ion batteries for its ultra-high theoretical capacity of 2680 mAh g−1.The studies to date have been limited to electrodes with a rela-tively low mass loading(<3.5 mg cm^(−2)),which has seriously restricted the areal capacity and its potential in practical devices.Maximizing areal capacity with such high-capacity materials is critical for capitalizing their potential in practi-cal technologies.Herein,we report a monolithic three-dimensional(3D)large-sheet holey gra-phene framework/SiO(LHGF/SiO)composite for high-mass-loading electrode.By specifically using large-sheet holey graphene building blocks,we construct LHGF with super-elasticity and exceptional mechanical robustness,which is essential for accommodating the large volume change of SiO and ensuring the structure integrity even at ultrahigh mass loading.Additionally,the 3D porous graphene network structure in LHGF ensures excellent electron and ion transport.By systematically tailoring microstructure design,we show the LHGF/SiO anode with a mass loading of 44 mg cm^(−2)delivers a high areal capacity of 35.4 mAh cm^(−2)at a current of 8.8 mA cm^(−2)and retains a capacity of 10.6 mAh cm^(−2)at 17.6 mA cm^(−2),greatly exceeding those of the state-of-the-art commercial or research devices.Furthermore,we show an LHGF/SiO anode with an ultra-high mass loading of 94 mg cm^(−2)delivers an unprecedented areal capacity up to 140.8 mAh cm^(−2).The achievement of such high areal capacities marks a critical step toward realizing the full potential of high-capacity alloy-type electrode materials in practical lithium-ion batteries.
基金Shiraz University Enhanced Oil Recovery(EOR)Research Center for the support
文摘Viscous fingering is one of the main challenges that could reduce areal sweep efficiency during waterflooding in oil reservoirs. A series of waterflooding experiments were carried out in a Hele-Shaw cell at ambient temperature during which areal sweep efficiency was estimated and techniques to ease the fingering problem were examined. The onset and propagation of viscous fingers were monitored as a function of both injection rate and injection/production positions. Image processing techniques were utilized to quantitatively investigate the propagation of fingers. The experimental results show that, under specific conditions, increasing the number of finger branches could improve the areal sweep efficiency, whereas growth of a single narrow finger has a negative impact on oil displacement efficiency. According to the obtained results,increasing the injection rate improves the areal sweep efficiency up to a critical rate at which viscous fingers start to grow.The impact of heterogeneity of the medium on distributing the viscous fingers was also investigated by introducing two different arrangements of fractures in the model. The results show that fractures perpendicular to the direction of flow would distribute the displacing water more uniformly, while fractures in the direction of flow would amplify the unfavorable sweep efficiency.
基金supported by Scientific and Technological Key Project of Shanxi Province(20191102003)National Key Research and Development Program(2016YFA0202500)+1 种基金the National Natural Science Foundation of China(21776019)Beijing Natural Science Foundation(L182021)。
文摘Lithium-sulfur(Li-S)battery is regarded as one of the most promising next-generation energy storage systems due to the ultra-high theoretical energy density of 2600 Wh kg^(-1).To address the insulation nature of sulfur,nanocarbon composition is essential to afford acceptable cycling capacity but inevitably sacrifices the actual energy density under working conditions.Therefore,rational structural design of the carbon/sulfur composite cathode is of great significance to realize satisfactory electrochemical performances with limited carbon content.Herein,the cathode carbon distribution is rationally regulated to construct high-sulfur-content and high-performance Li-S batteries.Concretely,a double-layer carbon(DLC)cathode is prepared by fabricating a surface carbon layer on the carbon/sulfur composite.The surface carbon layer not only provides more electrochemically active surfaces,but also blocks the polysulfide shuttle.Consequently,the DLC configuration with an increased sulfur content by nearly 10 wt%renders an initial areal capacity of 3.40 mAh cm^(-2) and capacity retention of 83.8%during 50 cycles,which is about two times than that of the low-sulfur-content cathode.The strategy of carbon distribution regulation affords an effective pathway to construct advanced high-sulfur-content cathodes for practical high-energy-density Li-S batteries.
基金financially supported by National Key Research and Development Program(No.2019YFA0210600)the Major Technological Innovation Project of Hubei Science and Technology Department(No.2019AAA164)+1 种基金the National Natural Science Foundation of China(No.51972107)the Innovative Research Groups of Hunan Province(No.2019JJ10001)。
文摘The lithium-sulfur battery is the subject of much recent attention due to the high theoretical energy density,but practical applications are challenged by fast decay owing to polysulfide shuttle and electrode architecture degradation.A comprehensive study of the sulfur host microstructure design and the cell architecture construction based on the MXene phase(Ti3C2Tx nanosheets) is performed,aiming at realize stable cycling performance of Li-S battery with high sulfur areal loading.The interwoven KB@Ti3C2Tx composite formed by self-assembly of MXene and Ktej en black,not only provides superior conductivity and maintains the electrode integrality bearing the volume expansion/shrinkage when used as the sulfur host,but also functions as an interlayer on separator to further retard the polysulfide cross-diffusion that possibly escaped from the cathode.The KB@Ti3C2Tx interlayer is only 0.28 mg cm-2 in areal loading and 3 μm in thickness,which accounts a little contribution to the thick sulfur electrode;thus,the impacts on the energy density is minimal.By coupling the robust KB@Ti3C2Tx cathode and the effective KB@Ti3C2Tx modified separator,a stable Li-S battery with high sulfur areal loading(5.6 mg cm-2) and high areal capacity(6.4 mAh cm-2) at relatively lean electrolyte is achieved.
文摘The lithium sulfur batteries(LSBs) are considered as one of the promising next generation energy storage devices due to the high theoretical specific capacity of sulfur(1675 m Ah g-1), naturally available, low cost.However, the practical LSBs are impeded by the well-known "shuttle effect" combined with other technical drawbacks. The "shuttle effect" causes rapid capacity decay, severe self-discharging and low active material utilization. The polysulfide(PS) which has lone pair electrons in each sulfur atom is considered as Lewis base and shows strong affinity to various polar, Lewis acid and catenation interactive materials but very weakly interacts with the non-polar conductive carbons. The "shuttle effect" occurs due to the diffusion of high order PS from the cathode to the anode and then low-order PS back to the cathode. The PS is polar and, due to a lone pair of electrons associated with the sulfur atom, is considered a Lewis base. As such, the PS shows a strong affinity with various polar and Lewis acid materials. In addition, a more novel trapping can be performance through a catenation reaction. For LSBs to compete with the state-of-the-art lithium ion batteries(LIBs), the LSB areal capacity need to be ~6 m Ah cm-2(which is proportional to sulfur loading). To achieve this target the PS shuttling needs to mitigate, which can be achieved through using functional materials. This review addresses the aforementioned phenomena by considering the PS phase interacts with the various functional materials and how this impacts areal capacity and cycling stability of LSBs.
基金financially supported by the National Science Technology Support Plan Project (2012BAH28B01-03)the National Natural Science Foundation of China(41171332)+1 种基金the National Science Technology Basic Special Project (2011FY110400-2)the China Postdoctoral Science Foundation (2012M510526)
文摘Inland lakes are important water resources in arid and semiarid regions. Understanding climate effects on these lakes is critical to accurately evaluate the dynamic changes of water resources. This study focused on the changes in Sayram Lake of Xinjiang, China, and addressed the effects of climate fluctuations on the inland lake based on long-term sequenced remote sensing images and meteorological data from the past 40 years. A geo- graphic information system （GIS） method was used to obtain the hypsometry of the basin area of Sayram Lake, and estimation methods for evaporation from rising temperature and water levels from increasing precipitation were proposed. Results showed that： （1）Areal values of Sayram Lake have increased over the past 40 years. （2） Both temperature and precipitation have increased with average increases of more than 1.8~C and 82 mm, respectively. Variation of the water levels in the lake was consistent with local climate changes, and the areal values show linear relationships with local temperature and precipitation data. （3） According to the hypsometry data of the basin area, the estimated lake water levels increased by 2.8 m, and the water volume increased by 12.9×108 m3 over the past 40 years. The increasing area of Sayram Lake correlated with local and regional climatic changes because it is hardly affected by human activities.
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(No.2022R1F1A1070168,2020R1C1C1004322)the Korea Institute of Industrial Technology as Development of core technology for smart wellness care based on cleaner production process technology(KITECH-PEH23030)+1 种基金supported by the Renewable Surplus Sector Coupling Technology Program of the Korea Institute of Energy Technology Evaluation and Planning(KETEP)granted financial resource from the Ministry of Trade,Industry&Energy,Republic of Korea(No.20226210100050)the National Research Council of Science&Technology(NST)grant by the Korea government(MSIT)(No.CPS21141-100)。
文摘Thick electrodes can substantially enhance the overall energy density of batteries.However,insufficient wettability of aqueous electrolytes toward electrodes with conventional hydrophobic binders severely limits utilization of active materials with increasing the thickness of electrodes for aqueous batteries,resulting in battery performance deterioration with a reduced capacity.Here,we demonstrate that controlling the hydrophilicity of the thicker electrodes is critical to enhancing the overall energy density of batteries.Hydrophilic binders are synthesized via a simple sulfonation process of conventional polyvinylidene fluoride binders,considering physicochemical properties such as mechanical properties and adhesion.The introduction of abundant sulfonate groups of binders(i)allows fast and sufficient electrolyte wetting,and(ii)improves ionic conduction in thick electrodes,enabling a significant increase in reversible capacities under various current densities.Further,the sulfonated binder effectively inhibits the dissolution of cathode materials in reactive aqueous electrolytes.Overall,our findings significantly enhance the energy density and contribute to the development of practical zinc-ion batteries.
文摘Ganga river basins exposed to active erosional and deformational processes. The recurrence of landslides, floods, and seismic activities makes it more susceptible to deformational activities. The tectonic analysis using geomorphic indices and morphometric parameters will help in determining the hazard-prone area of the river basin. Geomorphic indices and morphometric parameters are calculated to investigate the role of neotectonic activities, as it acts as a controlling factor in the development of landforms in the tectonically active terrains. Neotectonic activities influence the terrain topography, which significantly affects the drainage system and geomorphological setup of the area. In this study, the assessment of active tectonics of study area was determined using Advanced Spaceborne Thermal Emission and Reflection Radiometer(ASTER) Global Digital Elevation Model(GDEM) based on Geomorphic Indices(Stream Length Gradient index, Hypsometric integral, Asymmetry factor, Basin shape, Valley floor width to Valley height ratio, Mountain front sinuosity index) cumulatively with Linear, Areal and Relief morphometric parameters on 27 delineated basins of the study area. The combined classification of Relative Tectonic Activity Index(Iat) and morphometric parameters of 27 basins categorized all the zones into four different classes:Class 1 – Very High(<1.97;410 km^2);Class 2 – High(1.97 – 2.05;275 km^2);Class 3 – Moderate(2.05 – 2.21;273 km^2),and Class 4 – Low(>2.21;299 km^2). The basins with tectonic activities have a consistent relationship with structural disturbances, basin geometry, and field studies. The tectonically active zonation of a part of Ganga basin using geomorphic indices and morphometric parameters suggest that it has significant influence of neotectonic activities in a part of Ganga basin.
