In order to improve the anti-explosion performance ofρ-Al_(2)O_(3) bonded corundum castables,H_(2)O_(2) was added(0,0.025%,0.050%,0.075%,0.100%and 0.125%,by mass)as the anti-explosion agent.After mixing and casting,s...In order to improve the anti-explosion performance ofρ-Al_(2)O_(3) bonded corundum castables,H_(2)O_(2) was added(0,0.025%,0.050%,0.075%,0.100%and 0.125%,by mass)as the anti-explosion agent.After mixing and casting,specimens were prepared.Some specimens were cured at room temperature for 12 h and demoulded for the anti-explosion performance test at different temperatures(450,500,550,600,650,700,750 and 800℃);the other specimens were cured,dried and fired,and tested in terms of the apparent porosity,the density,the cold mechanical properties,the air permeability and the pore size distribution.The results show that:(1)with the increase of the H_(2)O_(2) addition,the anti-explosion performance of castables increases gradually,the average pore size increases gradually,and the density and the strength decrease gradually;(2)by comprehensive consideration,the appropriate addition of H_(2)O_(2) shall be within 0.075%.展开更多
An innovative multi-layer composite explosion containment vessel(CECV)utilizing a sliding steel platealuminum honeycomb-fiber cloth sandwich is put forward to improve the anti-explosion capacity of a conventional sing...An innovative multi-layer composite explosion containment vessel(CECV)utilizing a sliding steel platealuminum honeycomb-fiber cloth sandwich is put forward to improve the anti-explosion capacity of a conventional single-layer explosion containment vessel(SECV).Firstly,a series of experiments and finite element(FE)simulations of internal explosions are implemented to understand the basic anti-explosion characteristics of a SECV and the rationality of the computational models and methods is verified by the comparison between the experimental results and simulation results.Based on this,the CECV is designed in detail and a variety of FE simulations are carried out to investigate effects of the sandwich structure,the explosive quantity and the laying mode of the fiber cloth on anti-explosion performance and dynamic response of the CECV under internal explosions.Simulation results indicate that the end cover is the critical position for both the SECV and CECV.The maximum pressure of the explosion shock wave and the maximum strain of the CECV can be extremely declined compared to those of the SECV.As a result,the explosive quantity the CECV can sustain is up to 20 times of that the SECV can sustain.Besides,as the explosive quantity increases,the internal pressure of the CECV keeps growing and the plastic deformation and failure of the sandwich structure become more and more severe,yielding plastic strain of the CECV in addition to elastic strain.The results also reveal that the laying angles of the fiber cloth's five layers have an impact on the anti-explosion performance of the CECV.For example,the CECV with fiber cloth layered in 0°/45°/90°/45°/0°mode has the optimal anti-capacity,compared to 0°/0°/0°/0°/0°and 0°/30°/60°/30°/0°modes.Overall,owing to remarkable anti-explosion capacity,this CECV can be regarded as a promising candidate for explosion resistance.展开更多
Multi-protection is a principle in security management, and the use of anti-explosion and fireproof agents is a crucial part of it. In this paper, the properties of nano-oxide particles in the field of anti-explosion ...Multi-protection is a principle in security management, and the use of anti-explosion and fireproof agents is a crucial part of it. In this paper, the properties of nano-oxide particles in the field of anti-explosion and fireproof were analyzed. The sedimentation velocity of nanometer particles was calculated. CH4 was taken as an example, and its combustion mechanism of the initial stages was concluded. The effects of 15 oxides on molecular energies of the reaction system were calculated with program Hyperchem 6, and the possible contact manner between radi- cals and oxides was got. It was concluded that oxides, such as ZrO2, could combine with radicals, and thus prevent the combustion reaction. It was found that the nano-ZrO2 eruptively generated aerosol is superior to other counterparts in serving as the anti-explosion and fireproof agent, and therefore, will play an increasingly important role in the security management.展开更多
The explosivity experiment of anti-explosive ammonium nitrate (AEAN) shows that the explosive characteristic of AEAN is eliminated. The adiabatic decompositions of ammonium nitrate and AEAN were investigated with an a...The explosivity experiment of anti-explosive ammonium nitrate (AEAN) shows that the explosive characteristic of AEAN is eliminated. The adiabatic decompositions of ammonium nitrate and AEAN were investigated with an accelerating rate calorimeter (ARC). The curves of thermal decomposition temperature and pressure versus time, self-heating rate and pressure versus temperature for two systems were obtained. The kinetic parameters such as apparent activation energy and pre-exponential factor were calculated. The safety of AEAN was analyzed. It was indicated that AEAN has a higher thermal stability than AN. At the same time, it can be shown that the elimination of its explosive characteristic is due to the improvement on the thermal stability of AEAN.展开更多
Experimental investigation into impact-resistant behavior of reactive powder concrete (RPC)-filled steel tubular columns was conducted,and dynamic response of the columns under axial impact loading was studied by mean...Experimental investigation into impact-resistant behavior of reactive powder concrete (RPC)-filled steel tubular columns was conducted,and dynamic response of the columns under axial impact loading was studied by means of numerical simulation method.Increase coefficient of load carrying capacity and ratio of load carrying capacity between steel tube and RPC core of col-umns were obtained.展开更多
文摘In order to improve the anti-explosion performance ofρ-Al_(2)O_(3) bonded corundum castables,H_(2)O_(2) was added(0,0.025%,0.050%,0.075%,0.100%and 0.125%,by mass)as the anti-explosion agent.After mixing and casting,specimens were prepared.Some specimens were cured at room temperature for 12 h and demoulded for the anti-explosion performance test at different temperatures(450,500,550,600,650,700,750 and 800℃);the other specimens were cured,dried and fired,and tested in terms of the apparent porosity,the density,the cold mechanical properties,the air permeability and the pore size distribution.The results show that:(1)with the increase of the H_(2)O_(2) addition,the anti-explosion performance of castables increases gradually,the average pore size increases gradually,and the density and the strength decrease gradually;(2)by comprehensive consideration,the appropriate addition of H_(2)O_(2) shall be within 0.075%.
基金supported by the National Natural Science Foundation of China (Grant No.11902157)Natural Science Foundation of Jiangsu Province (Grant No.BK20180417)the Scientific and Technological Innovation Project of Army Engineering Univeristy of PLA (Grant No.KYGYZXJK150025)。
文摘An innovative multi-layer composite explosion containment vessel(CECV)utilizing a sliding steel platealuminum honeycomb-fiber cloth sandwich is put forward to improve the anti-explosion capacity of a conventional single-layer explosion containment vessel(SECV).Firstly,a series of experiments and finite element(FE)simulations of internal explosions are implemented to understand the basic anti-explosion characteristics of a SECV and the rationality of the computational models and methods is verified by the comparison between the experimental results and simulation results.Based on this,the CECV is designed in detail and a variety of FE simulations are carried out to investigate effects of the sandwich structure,the explosive quantity and the laying mode of the fiber cloth on anti-explosion performance and dynamic response of the CECV under internal explosions.Simulation results indicate that the end cover is the critical position for both the SECV and CECV.The maximum pressure of the explosion shock wave and the maximum strain of the CECV can be extremely declined compared to those of the SECV.As a result,the explosive quantity the CECV can sustain is up to 20 times of that the SECV can sustain.Besides,as the explosive quantity increases,the internal pressure of the CECV keeps growing and the plastic deformation and failure of the sandwich structure become more and more severe,yielding plastic strain of the CECV in addition to elastic strain.The results also reveal that the laying angles of the fiber cloth's five layers have an impact on the anti-explosion performance of the CECV.For example,the CECV with fiber cloth layered in 0°/45°/90°/45°/0°mode has the optimal anti-capacity,compared to 0°/0°/0°/0°/0°and 0°/30°/60°/30°/0°modes.Overall,owing to remarkable anti-explosion capacity,this CECV can be regarded as a promising candidate for explosion resistance.
基金Project supported by the National Natural Science Foundation of China （No. 50372028） and the Natural Science Foundation of Jiangsu Province （No. BK2005130）.
文摘Multi-protection is a principle in security management, and the use of anti-explosion and fireproof agents is a crucial part of it. In this paper, the properties of nano-oxide particles in the field of anti-explosion and fireproof were analyzed. The sedimentation velocity of nanometer particles was calculated. CH4 was taken as an example, and its combustion mechanism of the initial stages was concluded. The effects of 15 oxides on molecular energies of the reaction system were calculated with program Hyperchem 6, and the possible contact manner between radi- cals and oxides was got. It was concluded that oxides, such as ZrO2, could combine with radicals, and thus prevent the combustion reaction. It was found that the nano-ZrO2 eruptively generated aerosol is superior to other counterparts in serving as the anti-explosion and fireproof agent, and therefore, will play an increasingly important role in the security management.
文摘The explosivity experiment of anti-explosive ammonium nitrate (AEAN) shows that the explosive characteristic of AEAN is eliminated. The adiabatic decompositions of ammonium nitrate and AEAN were investigated with an accelerating rate calorimeter (ARC). The curves of thermal decomposition temperature and pressure versus time, self-heating rate and pressure versus temperature for two systems were obtained. The kinetic parameters such as apparent activation energy and pre-exponential factor were calculated. The safety of AEAN was analyzed. It was indicated that AEAN has a higher thermal stability than AN. At the same time, it can be shown that the elimination of its explosive characteristic is due to the improvement on the thermal stability of AEAN.
基金Supported by National Natural Science Foundation of China(No.50778174).
文摘Experimental investigation into impact-resistant behavior of reactive powder concrete (RPC)-filled steel tubular columns was conducted,and dynamic response of the columns under axial impact loading was studied by means of numerical simulation method.Increase coefficient of load carrying capacity and ratio of load carrying capacity between steel tube and RPC core of col-umns were obtained.
