Herein,we proposed a green synthetic route based on coordination chemistry to produce nanostructured layered double hydroxides(LDHs).The synthesized NiAl-,NiFe-and ZnAl-LDHs exhibited similar morphologies and crystal ...Herein,we proposed a green synthetic route based on coordination chemistry to produce nanostructured layered double hydroxides(LDHs).The synthesized NiAl-,NiFe-and ZnAl-LDHs exhibited similar morphologies and crystal structures.A possible mechanism for LDH formation was proposed based on pHpotentiometric titrations.Extensive electronic spectroscopy analyses,interpreted through the lens of ligand field theory,provided key insights into the formation mechanism of NiFe-LDH.展开更多
基金the Italian Ministry of University and Research for funding through the LEGACY(healing wide-gap chalcopyrite,grant no.20223ZP4WP)project of national relevance(PRIN 2022),under the ERC PE3 Condensed Matter Physics sector。
文摘Herein,we proposed a green synthetic route based on coordination chemistry to produce nanostructured layered double hydroxides(LDHs).The synthesized NiAl-,NiFe-and ZnAl-LDHs exhibited similar morphologies and crystal structures.A possible mechanism for LDH formation was proposed based on pHpotentiometric titrations.Extensive electronic spectroscopy analyses,interpreted through the lens of ligand field theory,provided key insights into the formation mechanism of NiFe-LDH.
