Nitrile hydrogenation represents an atom-economical and green approach to yield the highly valueadded primary amines,which suffers from harsh conditions and serious selectivity challenges.Herein,we demonstrated Pd nan...Nitrile hydrogenation represents an atom-economical and green approach to yield the highly valueadded primary amines,which suffers from harsh conditions and serious selectivity challenges.Herein,we demonstrated Pd nanoparticles anchored on ultrathin plate-like porous magnesium hydrate(Mg(OH)_(2))supports for the highly selective synthesis of benzylamine from benzonitrile hydrogenation in the absence of additives at 30℃.展开更多
基金supported by the National Natural Science Foundation of China(21872109 and 22002115)the Fundamental Research Funds for the Central Universities(D5000210283,D5000210601 and D5000210829)+2 种基金S.Zhang is also supported by the Guangdong Basic and Applied Basic Research Foundation(2022B1515020092)the Young Elite Scientists Sponsorship Program by CAST(2019QNRC001)Technology and the support of the National Natural Science Foundation of China(Grant No:22038011).
文摘Nitrile hydrogenation represents an atom-economical and green approach to yield the highly valueadded primary amines,which suffers from harsh conditions and serious selectivity challenges.Herein,we demonstrated Pd nanoparticles anchored on ultrathin plate-like porous magnesium hydrate(Mg(OH)_(2))supports for the highly selective synthesis of benzylamine from benzonitrile hydrogenation in the absence of additives at 30℃.
