Transition metals(TMs)are widely recognized for their valuable catalytic properties in various fields,from environmental protection to industrial application[1].Recently,there has been increasing interest in catalysts...Transition metals(TMs)are widely recognized for their valuable catalytic properties in various fields,from environmental protection to industrial application[1].Recently,there has been increasing interest in catalysts containing late TMs,particularly noble metals such as osmium,iridium and platinum.For instance,some studies have demonstrated that the Os atom serves as metal centers that coordinates alkanes,enabling the activation of C-H bonds in the first step[2].Characterization of the geometric and electronic structures of TM catalysts is essential for exploring the structure-reactivity relationship and elucidating complex mechanisms.展开更多
基金supported by the National Natural Science Foundation of China(22273101,22125303,92361302,22373102,21327901,and 22288201)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(2020187)+3 种基金the Innovation Program for Quantum Science and Technology(2021Z D0303304)the International Partnership Program of the Chinese Academy of Sciences(121421KYSB20170012)the Scientific Instrument Developing Project of the Chinese Academy of Sciences(GJJS TD20220001)Dalian Institute of Chemical Physics(DICP I202437).
文摘Transition metals(TMs)are widely recognized for their valuable catalytic properties in various fields,from environmental protection to industrial application[1].Recently,there has been increasing interest in catalysts containing late TMs,particularly noble metals such as osmium,iridium and platinum.For instance,some studies have demonstrated that the Os atom serves as metal centers that coordinates alkanes,enabling the activation of C-H bonds in the first step[2].Characterization of the geometric and electronic structures of TM catalysts is essential for exploring the structure-reactivity relationship and elucidating complex mechanisms.
