Mg-Li alloys hold significant potential for applications in aerospace,automotive manufacturing,military weaponry,and biomedical implants,due to their excellent recyclability,high specific strength,biocompatibility,and...Mg-Li alloys hold significant potential for applications in aerospace,automotive manufacturing,military weaponry,and biomedical implants,due to their excellent recyclability,high specific strength,biocompatibility,and superior electromagnetic shielding properties.However,their poor corrosion resistance and high susceptibility to environmentally assisted cracking(EAC)significantly limit broader application.In recent years,growing attention has been directed toward understanding the corrosion and EAC behavior of Mg-Li alloys,as localized corrosion areas and hydrogen generated during the corrosion process can serve as crack initiation points and promote crack propagation.A comprehensive understanding of these mechanisms is essential for enhancing the reliability and performance of Mg-Li alloys in practical environments.This paper presents a detailed review of corrosion and EAC in Mg-Li alloys,focusing on corrosion behavior,crack initiation and propagation mechanisms,and the key factors influencing these processes.It summarizes recent advances in alloying,heat treatment,mechanical processing,microstructural control,environmental influences,mechanical loading,and surface treatments.In addition,the paper explores future research directions,highlights emerging trends,and proposes strategies to improve the durability and service performance of Mg-Li alloys.展开更多
Coralline soils,specialized materials found extensively in the South China Sea,are playing an increasingly vital role in engineering projects.However,like most terrigenous soils,fine-grained coral soil is prone to shr...Coralline soils,specialized materials found extensively in the South China Sea,are playing an increasingly vital role in engineering projects.However,like most terrigenous soils,fine-grained coral soil is prone to shrinkage and cracking,which can significantly affect its engineering properties and ultimately jeopardize engineering safety.This paper presents a desiccation cracking test of fine-grained coral soil,with a particular focus on the thickness effect.The study involved measuring the water content and recording the evolution of desiccation cracking.Advanced image processing technology is employed to analyze the variations in crack parameters,clod parameters,fractal dimensions,frequency distributions,and desiccation cracking propagation velocities of fine-grained coral soil.Furthermore,the dynamic evolution of desiccation cracking under the influence of layer thickness is analyzed.A comprehensive crack evolution model is proposed,encompassing both top-down and bottom-up crack propagation,as well as internal tensile cracking.This work introduces novel metrics for the propagation velocity of the total crack area,the characteristic propagation velocities of desiccation cracks,and the acceleration of crack propagation.Through data fitting,theoretical formulas for soil water evaporation,propagation velocities of desiccation cracks,and crack propagation acceleration are derived,laying a foundation for future soil cracking theories.展开更多
Soil desiccation cracking is ubiquitous in nature and has significantpotential impacts on the engineering geological properties of soils.Previous studies have extensively examined various factors affecting soil cracki...Soil desiccation cracking is ubiquitous in nature and has significantpotential impacts on the engineering geological properties of soils.Previous studies have extensively examined various factors affecting soil cracking behavior through a numerous small-sample experiments.However,experimental studies alone cannot accurately describe soil cracking behavior.In this study,we firstly propose a modeling framework for predicting the surface crack ratio of soil desiccation cracking based on machine learning and interpretable analysis.The framework utilizes 1040 sets of soil cracking experimental data and employs random forest(RF),extreme gradient boosting(XGBoost),and artificialneural network(ANN)models to predict the surface crack ratio of soil desiccation cracking.To clarify the influenceof input features on soil cracking behavior,feature importance and Shapley additive explanations(SHAP)are applied for interpretability analysis.The results reveal that ensemble methods(RF and XGBoost)provide better predictive performance than the deep learning model(ANN).The feature importance analysis shows that soil desiccation cracking is primarily influencedby initial water content,plasticity index,finalwater content,liquid limit,sand content,clay content and thickness.Moreover,SHAP-based interpretability analysis further explores how soil cracking responds to various input variables.This study provides new insight into the evolution of soil cracking behavior,enhancing the understanding of its physical mechanisms and facilitating the assessment of potential regional development of soil desiccation cracking.展开更多
Peridynamics(PD)is an effective method for simulating the spontaneous initiation and propagation of tensile cracks in materials.However,it faces great challenges in simulating compression-shear cracking of geomaterial...Peridynamics(PD)is an effective method for simulating the spontaneous initiation and propagation of tensile cracks in materials.However,it faces great challenges in simulating compression-shear cracking of geomaterials due to the lack of efficient contact-friction models.This paper introduces an original contact-friction model that leverages twin mesh and potential function principles within PD to model rock cracking under tensile and compressive stresses.The contact detection algorithm,based on space segmentation axis-aligned bounding box(AABB)tree data structure,is used to address the significant challenge of highly efficient contact detection in compression and shear problems.In this method,the twin mesh and potential function are utilized to quantify contact detection and contact degree,as well as friction behavior.This is in contrast to the distance and circular contact area model,which lacks physical significance in the classical PD method.As demonstrated by the tests on specimens containing cracks,the proposed model can capture 8 types of secondary fractures,reduce the contact detection error by about 29%e56%,and increase the contact retrieval efficiency by over 1600 times compared to the classic PD models.This significantly enhances the capability of PD to simulate the initiation,expansion,and coalescence of intricate compression-shear cracks.展开更多
Cracking affected by wetting-drying cycles is a major cause of shallow failure of soft rock slopes.Knowledge of rock tensile properties and cracking behaviors helps better assess the stability of soft rock slopes.This...Cracking affected by wetting-drying cycles is a major cause of shallow failure of soft rock slopes.Knowledge of rock tensile properties and cracking behaviors helps better assess the stability of soft rock slopes.This study aims to examine the cracking behaviors and tensile strength of silty mudstone under wetting-drying cycles.The wetting-drying cycle and Brazilian splitting tests were performed on silty mudstone considering various cycle number and amplitude.The cracking behaviors of wetting-drying cycles were analyzed by digital image correlation,three-dimensional(3D)scanning technology,and scanning electron microscopy.The results reveal a spiral-like pattern of crack ratio escalation in silty mudstone,with a higher crack ratio observed during drying than wetting.Tensile strength and fracture energy correlate negatively with cycle number or amplitude,with cycle number exerting a more pronounced effect.The variance of the maximum principal strain reflects stages of initial deformation,linear deformation,strain localization,and stable deformation.The formation of strain localization zones reveals the physical process of crack propagation.Crack tip opening displacement progresses through stages of slow growth,exponential growth,and linear growth,delineating the process from crack initiation to stable extension.Failure modes of silty mudstone primarily involve tensile and tensile-shear failure,influenced by the geometric parameters of cracks induced by wetting-drying cycles.Fracture surface roughness and fractal dimension increase with cycle number due to mineral dissolution,physical erosion,and nondirectional crack propagation.Hydration-swelling and dehydration-shrinkage of clay minerals,along with absorption-drying cracking,initiate and merge cracks,leading to degradation of the rock mechanical properties.The findings could provide insights for mitigating shallow cracking of soft rock slopes under wetting-drying cycles.展开更多
There remains debate on whether Mn is beneficial or detrimental to hydrogen embrittlement in stainless steel.In this work,a series of stainless steels were designed to study the change of hydrogen embrittlement sensit...There remains debate on whether Mn is beneficial or detrimental to hydrogen embrittlement in stainless steel.In this work,a series of stainless steels were designed to study the change of hydrogen embrittlement sensitivity,crack propagation,and hydrogen trapping behaviors upon Mn addition.The results suggest that adding 4 wt.% Mn increased hydrogen embrittlement susceptibility,whereas adding 8 wt.% Mn decreased hydrogen embrittlement sensitivity.Forming banded α’-martensite through austenitic grain is the main reason for the increased hydrogen embrittlement sensitivity when adding 4 wt.%Mn,by adsorbing hydrogen,promoting crack initiation,and accelerating crack propagation.展开更多
A comparative study of products of thermal and thermocatalytic cracking of polypropylene(PP) in the presence of potassium polytitanate(PPT) synthesized by treatment of TiO_(2)(rutile) powder with molten mixture of KOH...A comparative study of products of thermal and thermocatalytic cracking of polypropylene(PP) in the presence of potassium polytitanate(PPT) synthesized by treatment of TiO_(2)(rutile) powder with molten mixture of KOH and KNO_(3) taken in a weight ratio of 30∶30∶40 has been carried out.It was shown that the studied type of PPT powder exhibits catalytic properties in the reaction of thermal decomposition of PP,compared to the effect of commercial zeolite catalyst CBV-780 traditionally used for this purpose.Based on the analysis performed,the differences in the mechanism of catalytic action of PPT and the zeolite were considered.The reasons for the observed differences in the composition of PP cracking products and in the rate of coke formation on the surface of studied catalysts were analyzed.Considering the obtained results,it has been proposed that the CBV-780 catalyst promoted more intensive production of the gaseous hydrocarbons compared to PPT,due to higher specific surface area(internal surface) accessible for relatively light and small-sized hydrocarbon products of cracking.However,intensive coke formation on the outer surface of the microporous zeolite contributes to the blocking of transport channels and the rapid loss of catalytic action.At the same time,PPT,which initially has a smaller specific surface area,retains its catalytic activity significantly longer due to slit-shaped flat pores and higher transport accessibility of the inner surface.展开更多
By using fatigue crack propagation testing and microstructural characterization,the crack fracture and propagation mechanisms of K4169 superalloy under various loads were investigated.The results demonstrate that the ...By using fatigue crack propagation testing and microstructural characterization,the crack fracture and propagation mechanisms of K4169 superalloy under various loads were investigated.The results demonstrate that the grain sizes of K4169 superalloy significantly increase,and the precipitation of the needle-likeδphase and the Laves phase is observed.Voids and microcracks form at location of Laves phase enrichment,creating conditions for crack propagation.By the a−N(a is the crack length,and N is the number of cycles)relationship curve,the change in the fatigue crack growth rate with the increasing number of cycles progresses through three separate stages.The fracture process of K4169 superalloy under low-stress cyclic loading(3 kN)exhibits the ductile fracture.Subsequently,the fracture process starts to change from the ductile fracture to the brittle fracture as the stress increases to 4.5 kN.In the microstructures of fractures in both stress states,intergranular propagation is the mechanism responsible for crack propagation.Moreover,the Laves phase exists near the fracture crack,which is in line with the post-service structural phenomenon.展开更多
The edge crack behavior of copper foil in asymmetrical micro-rolling was studied.The effects of the speed ratio between rolls,grain size and stress state in the deformation zone on edge cracks of the rolled piece in a...The edge crack behavior of copper foil in asymmetrical micro-rolling was studied.The effects of the speed ratio between rolls,grain size and stress state in the deformation zone on edge cracks of the rolled piece in asymmetrical rolling were analyzed.Low plasticity,uneven deformation and longitudinal secondary tensile stress generated in the edge area of the rolled piece during the rolling process are the main causes of edge cracks.The larger the grain size of the rolled piece,the smaller the number of edge cracks and the deeper the expansion depth,and the larger the spacing between cracks under the same rolling reduction.Asymmetrical rolling can effectively increase the rolling reduction at when the copper foil fist shows edge cracks compared to symmetrical rolling.This enhancement is attributed to the shearing stress induced by asymmetrical rolling,which reduces the rolling force and longitudinal secondary tensile stress,and increases the residual compressive stress on the surface of the rolled piece.The edge crack defects of copper foil can be effectively reduced by increasing the speed ratio between the rolls in asymmetrical rolling.展开更多
This study leverages machine learning to perform high-throughput computational screening of n-hexane cracking initiators.Artificial neural networks are applied to predict the chemical performance of initiators,using s...This study leverages machine learning to perform high-throughput computational screening of n-hexane cracking initiators.Artificial neural networks are applied to predict the chemical performance of initiators,using simulated pyrolysis data as the training dataset.Various feature extraction methods are utilized,and five neural network architectures are developed to predict the co-cracking product distribution based on molecular structures.High-throughput screening of 12946 molecules outside the training dataset identifies the top 10 initiators for each target product—ethylene,propylene,and butadiene.The relative error between predicted and simulated values is less than 7%.Additionally,reaction pathway analysis elucidates the mechanisms by which initiators influence the distribution of cracking products.The proposed framework provides a practical and efficient approach for the rapid identification and evaluation of high-performance cracking initiators.展开更多
The 7075 aluminum alloy was subjected to power-modulated laser welding using a full-domain power modulation(FDPM)laser oscillating welding system.Three different power modes were utilized:constant power(CP),gradient p...The 7075 aluminum alloy was subjected to power-modulated laser welding using a full-domain power modulation(FDPM)laser oscillating welding system.Three different power modes were utilized:constant power(CP),gradient power(GP),and alternating power(AP)modes.The impact of different power modes on joint crack sensitivity,microstructure,and residual stress was assessed.The results demonstrate that joint welded with the AP mode exhibits the lowest sensitivity to solidification cracking(with mean crack sensitivity of 18.3%),and the smallest average grain size in the fusion zone of the weld seam(80μm).Additionally,it shows the highest microhardness(HV 113)and the narrowest softening region(3.5 cm).Furthermore,the joint displays the lowest residual stress and cooling rate,which is the reason for its minimal crack sensitivity.展开更多
In subtropical regions,soil desiccation cracking often exerts a significant impact on the interactions between soil water and the atmosphere,making it a subject of great interest in the fields of geotechnical and geoe...In subtropical regions,soil desiccation cracking often exerts a significant impact on the interactions between soil water and the atmosphere,making it a subject of great interest in the fields of geotechnical and geoenvironmental engineering.Despite the growing utilization of biochar as a sustainable soil amendment,there remains a lack of in-depth understanding of biocharewateresoil interactions,as well as its impact on soil desiccation cracking behavior.To address this gap,this study investigated the influence and mechanism of woody biochar dosages and particle sizes on the cracking behavior of three typical clayey soils in subtropical regions in China,namely Pukou expansive soil(PKE),Xiashu soil(XS),and Zhongshan lateritic soil(ZSL).The quantitative analysis of crack images revealed that the use of biochar was not consistently effective in preventing soil cracking.The application of biochar reduced the crack ratio in PKE and XS by up to 24.03%and 53.89%,respectively.In contrast,ZSL exhibited a 74.57%increase in crack ratio with the addition of 10%biochar.This influence can be further enhanced by increasing the dosage and reducing the particle size of biochar.The microstructural analysis demonstrated that biochar exerts an inhibitory effect on PKE and XS primarily through direct replacement,direct barrier,and indirect physical mechanisms.Moreover,an indirect chemical effect between biochar and clay particles was proposed to explain the exacerbated cracking observed in biochar-amended ZSL.To effectively utilize biochar for soil cracking mitigation in subtropical regions,it is essential to evaluate the initial mineral composition and cation type of the soil.展开更多
Implants are inevitably subjected to stress corrosion,bringing serious challenges to the controlled degradation of biomedical Mg alloys.It is worth studying the stress corrosion cracking(SCC)behavior of Mg alloy and e...Implants are inevitably subjected to stress corrosion,bringing serious challenges to the controlled degradation of biomedical Mg alloys.It is worth studying the stress corrosion cracking(SCC)behavior of Mg alloy and exploring Mg alloy with good SCC resistance for wide biomedical applications.In this work,the as-cast and as-extruded Mg-3Gd-1Zn-0.4Zr(GZ31K)alloys with uniform corrosion were used to investigate SCC behavior.The as-extruded GZ31K alloy exhibited better corrosion resistance and mechanical properties than the as-cast one mainly owing to grain refinement and uniformly distributed fine precipitates,and possessed superior SCC resistance.To clarify the SCC mechanism,the slow strain rate tests were assisted with applied constant potentials via an electrochemical workstation.Accelerated anodic dissolution at anodic polarization deteriorated SCC resistance due to the initiation of corrosion pits and micro-cracks.However,cathodic polarization had no obvious effects on SCC resistance,along with both retarded corrosion and accelerated hydrogen evolution.Stacking faults in GZ31K alloy were hydrogen capture containers to reduce the effect of hydrogen on SCC resistance during cathodic polarization.These findings provide new insights into the evaluation of SCC mechanism,and offer more opportunities to explore Mg alloys with good SCC resistance by regulating anodic dissolution.展开更多
Surface soil cracking in alpine meadows signifies the transition of degradation from quantitative accumulation to qualitative deterioration.Quantitative research remains insufficient regarding changes in the mechanica...Surface soil cracking in alpine meadows signifies the transition of degradation from quantitative accumulation to qualitative deterioration.Quantitative research remains insufficient regarding changes in the mechanical properties of degraded meadow soils and the mechanical thresholds for cracking initiation.This study explored the relationships between surface cracking and the physical properties,tensile strength,and matrix suction of root-soil composites in alpine meadow sites with different stages of degradation(undegraded(UD),lightly degraded(LD),moderately degraded(MD),and heavily degraded(HD))under different water gradients(high water content(HWC),medium water content(MWC),and low water content(LWC))corresponding to different drying durations at a constant temperature of 40.0°C.The Huangcheng Mongolian Township in Menyuan Hui Autonomous County,Qinghai Province,China was chosen as the study area.The results indicated that as the degradation degree of alpine meadow intensified,both water content of rootsoil composite and the fine grain content of soil decreased.In contrast,the root-soil mass ratio and root area ratio initially increased and then decreased with progressive degradation.Under a consistent water content,the tensile strength of root-soil composite followed a pattern of MD>HD>LD>UD.The peak displacement of tensile strength also decreased as the degradation degree of alpine meadow increased.Both the tensile strength and matrix suction of root-soil composite increased as root-soil water content decreased.A root-soil water content of 30.00%-40.00%was found to be the critical threshold for soil cracking in alpine meadows.Within this range,the matrix suction of root-soil composite ranged from 50.00 to 100.00 kPa,resulting in the formation of linear cracks in the surface soil.As the root-soil water content continued to decrease,liner cracks evolved into branch-like and polygonal patterns.The findings of this study provide essential data for improving the mechanical understanding of grassland cracking and its development process.展开更多
Hydrogen-induced cracking (HIC) is one of the most complex material problems that hydrogen can diffuse into and interact with microstructure, degrading their mechanical properties. Microstructural modification is an e...Hydrogen-induced cracking (HIC) is one of the most complex material problems that hydrogen can diffuse into and interact with microstructure, degrading their mechanical properties. Microstructural modification is an effective way to enhance the resistance to HIC. The present study focused on the relationship between the retained austenite (RA) and HIC behavior in NiCrMoV/Nb multi-alloying ultra-strength steel. Results demonstrated that the maximum volume fraction of RA of 9.31% was obtained for QL30T specimen. After the deep cryogenic pretreatment, the volume fraction of RA reduced to 8.8%. RA could reduce the effective diffusion coefficient, while deep cryogenic pretreatment increased the susceptibility of the steel to HIC by a maxim of 14.8%. This was mainly due to the transformation of retained austenite into martensite, degrading the mechanical properties under hydrogen-charged condition. In addition, the deep cryogenic pretreatment had a significant effect on the crack initiation and propagation, with the intergranular (IG) fracture becoming the dominant fracture mode where an increase in the number of secondary cracks in the section. The interfaces of RA and matrix, as well as the grain boundaries, were the preferred sites for cracks initiation.展开更多
The effect of aging precipitation on the stress corrosion cracking(SCC)mechanism of Ni(Fe,Al)-maraging steel was studied through the comparative characterization and analyses of the microstructures and fracture featur...The effect of aging precipitation on the stress corrosion cracking(SCC)mechanism of Ni(Fe,Al)-maraging steel was studied through the comparative characterization and analyses of the microstructures and fracture features of solid–solution and peak-aged steels.Aging precipitation exerts a chain of impacts on the deformative compatibility and electrochemical difference between the matrix and oth-er phases or interfaces.The strength of the martensite matrix is enhanced by abundant and evenly dispersed Ni(Fe,Al)precipitates,thereby reducing the possibility of splitting across martensite laths.Meanwhile,the Volta potential difference(VPD)between the matrix and primary NbC particles increases from 11.43 to 18.60 mV.Given that most of the primary NbC particles tend to be distributed along high-angle grain boundaries(HAGBs),anodic dissolution along HAGBs accelerates.Therefore,mechanical and electrochemical factors triggered by aging precipitation are involved in the variation in SCC behavior and mechanism.The SCC susceptibility of the steel in-creases along with the increasing tendency for intergranular cracking.展开更多
Cracking of early-age concrete can occur in the track beds of high-speed railways due to changes in material properties,environmental effects,and construction processes.This is a multi-field,time-varying issue involvi...Cracking of early-age concrete can occur in the track beds of high-speed railways due to changes in material properties,environmental effects,and construction processes.This is a multi-field,time-varying issue involving hydro-thermo-chemo-mechanical coupling.However,to date,research has not adequately described the early-age cracking mechanisms in track beds,and few risk control measures have been proposed.To solve this problem,we incorporated the hydration degree of concrete into multi-field coupling equations for early-age concrete,and set boundary conditions that account for environmental influences and various stress factors that typically cause early creep of concrete.A four-field coupled risk prediction model was built based on hydro-thermo-chemo-mechanical properties,and was used to calculate and analyze various time-varying behavior(including the risk and form of cracking)in the hydro,thermo,chemo,and mechanical fields of early-age concrete.Finally,we focused on material-related factors(maximum heat of hydration and peak heat release time),environmental factors(temperature difference between day and night,average daily cooling rate,and intensity of solar radiation),and construction technique factors(molding temperature,pouring time,and thermal insulation coefficient).The influence of these factors on the early-age cracking risk of the track bed was analyzed,and risk control measures against early cracking were proposed accordingly.展开更多
Fruit cracking is a persistent challenge for table grape growing.To investigate the mechanism of this disorder,a comprehensive two-year investigation was conducted to assess the fruit cracking percentage of 15 table g...Fruit cracking is a persistent challenge for table grape growing.To investigate the mechanism of this disorder,a comprehensive two-year investigation was conducted to assess the fruit cracking percentage of 15 table grape(Vitis vinifera L.)varieties.Based on the findings,the cracking-susceptible variety‘Xiangfei'and the cracking-resistant variety‘Zuijinxiang'were selected for further study.Fruit growth curves for‘Zuijinxiang'and‘Xiangfei'were plotted based on fruit diameter and total soluble solids content,revealing that both varieties exhibited typical double-sigmoidal patterns that were highly similar.The period between 48 and 53 days after full bloom(DAFB)was identified as the critical phase for fruit cracking incidence.Furthermore,during the fruit cracking period,‘Xiangfei'fruit exhibited significantly higher water content and mesocarp cell area compared with those of‘Zuijinxiang'.Applying aquaporin inhibitors(nano-silver)to‘Xiangfei'berries reduced fruit water uptake and cracking percentage,whereas applying aquaporin activators(forskolin)to‘Zuijinxiang'berries increased fruit water uptake and cracking percentage.Additionally,expression analysis of six genes associated with plasma membrane intrinsic proteins(PIPs)synthesis(VvPIP1;1,VvPIP1;2,VvPIP1;3,VvPIP2;1,VvPIP2;2,and VvPIP2;3)revealed that only the expression level of VvPIP1;1 was higher in‘Zuijinxiang'than in‘Xiangfei'during the fruit cracking period,whereas the expression levels of the other genes exhibited no significant difference between the two varieties.Transgenic overexpression of VvPIP1;1 in tomato resulted in increased fruit water content,enlarged mesocarp cell size,and enhanced fruit cracking percentage.These findings indicate that VvPIP1;1 plays a pivotal role in controlling grape berry cracking.展开更多
In this work,a new process for achieving the recovery of elemental sulfur by utilizing a fluidized catalytic cracking(FCC) riser reactor for SOxtreatment(FCC-DeSOx) is proposed.The process leverages the high temperatu...In this work,a new process for achieving the recovery of elemental sulfur by utilizing a fluidized catalytic cracking(FCC) riser reactor for SOxtreatment(FCC-DeSOx) is proposed.The process leverages the high temperatures and hydrocarbon concentrations in the FCC riser reactor to convert SOxinto H_(2)S.Subsequently,H_(2)S,along with the cracked gas,is processed downstream to produce sulfur.Thermodynamic analysis of the key reduction reactions in the FCC-DeSOxprocess revealed that complete conversion of SOxto H_(2)S is feasible in the dry gas(hydrogen-rich) prelift zone,as well as the upper and lower zones of the riser,upon achieving thermodynamic equilibrium.Experimental studies were conducted to replicate the conditions of these reaction zones using a low concentration of hydrogen gas as the reducing agent.Through process optimization,investigation of the minimum reaction time,and kinetic studies,the potential of this method for the complete reduction of SOxwas further confirmed.展开更多
Coking at the fractionating tower bottom and the decant oil circulation system disrupts the heat balance,leading to unplanned shutdown and destroying the long period stable operation of the Fluid Catalytic Cracking Un...Coking at the fractionating tower bottom and the decant oil circulation system disrupts the heat balance,leading to unplanned shutdown and destroying the long period stable operation of the Fluid Catalytic Cracking Unit(FCCU).The FCCU operates through interconnected subsystems,generating high-dimensional,nonlinear,and non-stationary data characterized by spatiotemporally correlated.The decant oil solid content is the crucial indicator for monitoring catalyst loss from the reactor-regenerator system and coking risk tendency at the fractionating tower bottom that relies on sampling and laboratory testing,which is lagging responsiveness and labor-intensive.Developing the online decant oil solid content soft sensor using industrial data to support operators in conducting predictive maintenance is essential.Therefore,this paper proposes a hybrid deep learning framework for soft sensor development that combines spatiotemporal pattern extraction with interpretability,enabling accurate risk identification in dynamic operational conditions.This framework employs a Filter-Wrapper method for dimensionality reduction,followed by a 2D Convolutional Neural Network(2DCNN)for extracting spatial patterns,and a Bidirectional Gated Recurrent Unit(BiGRU)for capturing long-term temporal dependencies,with an Attention Mechanism(AM)to highlight critical features adaptively.The integration of SHapley Additive exPlanations(SHAP),Complementary Ensemble Empirical Mode Decomposition with Adaptive Noise(CEEMDAN),2DCNN,and expert knowledge precisely quantifies feature contributions and decomposes signals,significantly enhancing the practicality of risk identification.Applied to a China refinery with processing capacity of 2.80×10^(6) t/a,the soft sensor achieved the R^(2) value of 0.93 and five-level risk identification accuracy of 96.42%.These results demonstrate the framework's accuracy,robustness,and suitability for complex industrial scenarios,advancing risk visualization and management.展开更多
基金supported by the National Natural Science Foundation of China Projects under Grant(nos.52301112,52331004,U21A2049,and 51871211)Guangdong Basic and Applied Basic Research Foundation(Grant no.2024A1515030065)+4 种基金Basic and Applied Basic Research Project of Guangzhou(Grant no.2024A04J6299)LiaoNing Revitalization Talents Program(XLYC1907062,and XLYC2403026)Shenyang Young and Middle-aged Science and Technology Innovation Talent Support Program(RC231178)the Fundamental Research Funds for the Central Universities(N25GFY002)the Innovation Fund of Institute of Metal Research(IMR),Chinese Academy of Sciences(CAS).
文摘Mg-Li alloys hold significant potential for applications in aerospace,automotive manufacturing,military weaponry,and biomedical implants,due to their excellent recyclability,high specific strength,biocompatibility,and superior electromagnetic shielding properties.However,their poor corrosion resistance and high susceptibility to environmentally assisted cracking(EAC)significantly limit broader application.In recent years,growing attention has been directed toward understanding the corrosion and EAC behavior of Mg-Li alloys,as localized corrosion areas and hydrogen generated during the corrosion process can serve as crack initiation points and promote crack propagation.A comprehensive understanding of these mechanisms is essential for enhancing the reliability and performance of Mg-Li alloys in practical environments.This paper presents a detailed review of corrosion and EAC in Mg-Li alloys,focusing on corrosion behavior,crack initiation and propagation mechanisms,and the key factors influencing these processes.It summarizes recent advances in alloying,heat treatment,mechanical processing,microstructural control,environmental influences,mechanical loading,and surface treatments.In addition,the paper explores future research directions,highlights emerging trends,and proposes strategies to improve the durability and service performance of Mg-Li alloys.
基金supported by the Fundamental Research Funds for the Central Universities(Grant No.2022CDJQY-012)the Innovation Group Science Foundation of the Natural Science Foundation of Chongqing,China(Grant No.cstc2020jcyj-cxttX0003).
文摘Coralline soils,specialized materials found extensively in the South China Sea,are playing an increasingly vital role in engineering projects.However,like most terrigenous soils,fine-grained coral soil is prone to shrinkage and cracking,which can significantly affect its engineering properties and ultimately jeopardize engineering safety.This paper presents a desiccation cracking test of fine-grained coral soil,with a particular focus on the thickness effect.The study involved measuring the water content and recording the evolution of desiccation cracking.Advanced image processing technology is employed to analyze the variations in crack parameters,clod parameters,fractal dimensions,frequency distributions,and desiccation cracking propagation velocities of fine-grained coral soil.Furthermore,the dynamic evolution of desiccation cracking under the influence of layer thickness is analyzed.A comprehensive crack evolution model is proposed,encompassing both top-down and bottom-up crack propagation,as well as internal tensile cracking.This work introduces novel metrics for the propagation velocity of the total crack area,the characteristic propagation velocities of desiccation cracks,and the acceleration of crack propagation.Through data fitting,theoretical formulas for soil water evaporation,propagation velocities of desiccation cracks,and crack propagation acceleration are derived,laying a foundation for future soil cracking theories.
基金supported by the National Key Research and Development Program of China(Grant Nos.2023YFC3707900 and 2024YFC3012700)the National Natural Science Foundation of China(Grant No.42230710).
文摘Soil desiccation cracking is ubiquitous in nature and has significantpotential impacts on the engineering geological properties of soils.Previous studies have extensively examined various factors affecting soil cracking behavior through a numerous small-sample experiments.However,experimental studies alone cannot accurately describe soil cracking behavior.In this study,we firstly propose a modeling framework for predicting the surface crack ratio of soil desiccation cracking based on machine learning and interpretable analysis.The framework utilizes 1040 sets of soil cracking experimental data and employs random forest(RF),extreme gradient boosting(XGBoost),and artificialneural network(ANN)models to predict the surface crack ratio of soil desiccation cracking.To clarify the influenceof input features on soil cracking behavior,feature importance and Shapley additive explanations(SHAP)are applied for interpretability analysis.The results reveal that ensemble methods(RF and XGBoost)provide better predictive performance than the deep learning model(ANN).The feature importance analysis shows that soil desiccation cracking is primarily influencedby initial water content,plasticity index,finalwater content,liquid limit,sand content,clay content and thickness.Moreover,SHAP-based interpretability analysis further explores how soil cracking responds to various input variables.This study provides new insight into the evolution of soil cracking behavior,enhancing the understanding of its physical mechanisms and facilitating the assessment of potential regional development of soil desiccation cracking.
基金supported by the National Natural Science Foundation of China(Grant No.52278333)the China Scholarship Council(CSC)and the Science and Technology Department of Liaoning Province(Grant No.2024JH2/102500069).
文摘Peridynamics(PD)is an effective method for simulating the spontaneous initiation and propagation of tensile cracks in materials.However,it faces great challenges in simulating compression-shear cracking of geomaterials due to the lack of efficient contact-friction models.This paper introduces an original contact-friction model that leverages twin mesh and potential function principles within PD to model rock cracking under tensile and compressive stresses.The contact detection algorithm,based on space segmentation axis-aligned bounding box(AABB)tree data structure,is used to address the significant challenge of highly efficient contact detection in compression and shear problems.In this method,the twin mesh and potential function are utilized to quantify contact detection and contact degree,as well as friction behavior.This is in contrast to the distance and circular contact area model,which lacks physical significance in the classical PD method.As demonstrated by the tests on specimens containing cracks,the proposed model can capture 8 types of secondary fractures,reduce the contact detection error by about 29%e56%,and increase the contact retrieval efficiency by over 1600 times compared to the classic PD models.This significantly enhances the capability of PD to simulate the initiation,expansion,and coalescence of intricate compression-shear cracks.
基金the financial support by the National Natural Science Foundation of China(Grant No.52108397)“Xiaohe”Science and Technology Talent Special Project(Grant No.2024 TJ-X06)Water Resources Science and Technology Project of Hunan Province(Grant No.XSKJ2023059-41).
文摘Cracking affected by wetting-drying cycles is a major cause of shallow failure of soft rock slopes.Knowledge of rock tensile properties and cracking behaviors helps better assess the stability of soft rock slopes.This study aims to examine the cracking behaviors and tensile strength of silty mudstone under wetting-drying cycles.The wetting-drying cycle and Brazilian splitting tests were performed on silty mudstone considering various cycle number and amplitude.The cracking behaviors of wetting-drying cycles were analyzed by digital image correlation,three-dimensional(3D)scanning technology,and scanning electron microscopy.The results reveal a spiral-like pattern of crack ratio escalation in silty mudstone,with a higher crack ratio observed during drying than wetting.Tensile strength and fracture energy correlate negatively with cycle number or amplitude,with cycle number exerting a more pronounced effect.The variance of the maximum principal strain reflects stages of initial deformation,linear deformation,strain localization,and stable deformation.The formation of strain localization zones reveals the physical process of crack propagation.Crack tip opening displacement progresses through stages of slow growth,exponential growth,and linear growth,delineating the process from crack initiation to stable extension.Failure modes of silty mudstone primarily involve tensile and tensile-shear failure,influenced by the geometric parameters of cracks induced by wetting-drying cycles.Fracture surface roughness and fractal dimension increase with cycle number due to mineral dissolution,physical erosion,and nondirectional crack propagation.Hydration-swelling and dehydration-shrinkage of clay minerals,along with absorption-drying cracking,initiate and merge cracks,leading to degradation of the rock mechanical properties.The findings could provide insights for mitigating shallow cracking of soft rock slopes under wetting-drying cycles.
基金supported by the National Science and Technology Resources Investigation Program of China(Grant No.2021FY100604).
文摘There remains debate on whether Mn is beneficial or detrimental to hydrogen embrittlement in stainless steel.In this work,a series of stainless steels were designed to study the change of hydrogen embrittlement sensitivity,crack propagation,and hydrogen trapping behaviors upon Mn addition.The results suggest that adding 4 wt.% Mn increased hydrogen embrittlement susceptibility,whereas adding 8 wt.% Mn decreased hydrogen embrittlement sensitivity.Forming banded α’-martensite through austenitic grain is the main reason for the increased hydrogen embrittlement sensitivity when adding 4 wt.%Mn,by adsorbing hydrogen,promoting crack initiation,and accelerating crack propagation.
文摘A comparative study of products of thermal and thermocatalytic cracking of polypropylene(PP) in the presence of potassium polytitanate(PPT) synthesized by treatment of TiO_(2)(rutile) powder with molten mixture of KOH and KNO_(3) taken in a weight ratio of 30∶30∶40 has been carried out.It was shown that the studied type of PPT powder exhibits catalytic properties in the reaction of thermal decomposition of PP,compared to the effect of commercial zeolite catalyst CBV-780 traditionally used for this purpose.Based on the analysis performed,the differences in the mechanism of catalytic action of PPT and the zeolite were considered.The reasons for the observed differences in the composition of PP cracking products and in the rate of coke formation on the surface of studied catalysts were analyzed.Considering the obtained results,it has been proposed that the CBV-780 catalyst promoted more intensive production of the gaseous hydrocarbons compared to PPT,due to higher specific surface area(internal surface) accessible for relatively light and small-sized hydrocarbon products of cracking.However,intensive coke formation on the outer surface of the microporous zeolite contributes to the blocking of transport channels and the rapid loss of catalytic action.At the same time,PPT,which initially has a smaller specific surface area,retains its catalytic activity significantly longer due to slit-shaped flat pores and higher transport accessibility of the inner surface.
基金National Natural Science Foundation of China (No. 51975200)Hunan Provincial Innovation Foundation for Postgraduate,China (No. QL20220201)。
文摘By using fatigue crack propagation testing and microstructural characterization,the crack fracture and propagation mechanisms of K4169 superalloy under various loads were investigated.The results demonstrate that the grain sizes of K4169 superalloy significantly increase,and the precipitation of the needle-likeδphase and the Laves phase is observed.Voids and microcracks form at location of Laves phase enrichment,creating conditions for crack propagation.By the a−N(a is the crack length,and N is the number of cycles)relationship curve,the change in the fatigue crack growth rate with the increasing number of cycles progresses through three separate stages.The fracture process of K4169 superalloy under low-stress cyclic loading(3 kN)exhibits the ductile fracture.Subsequently,the fracture process starts to change from the ductile fracture to the brittle fracture as the stress increases to 4.5 kN.In the microstructures of fractures in both stress states,intergranular propagation is the mechanism responsible for crack propagation.Moreover,the Laves phase exists near the fracture crack,which is in line with the post-service structural phenomenon.
基金supported by the National Natural Science Foundation of China(Nos.52204401,52005432)Hebei Natural Science Foundation of China(No.E2021203179),Excellent Young Talents Program of University of Anhui Province,China(No.gxyq2022093)Excellent Youth Research Projects in Universities of Anhui Province,China(No.2022AH030153).
文摘The edge crack behavior of copper foil in asymmetrical micro-rolling was studied.The effects of the speed ratio between rolls,grain size and stress state in the deformation zone on edge cracks of the rolled piece in asymmetrical rolling were analyzed.Low plasticity,uneven deformation and longitudinal secondary tensile stress generated in the edge area of the rolled piece during the rolling process are the main causes of edge cracks.The larger the grain size of the rolled piece,the smaller the number of edge cracks and the deeper the expansion depth,and the larger the spacing between cracks under the same rolling reduction.Asymmetrical rolling can effectively increase the rolling reduction at when the copper foil fist shows edge cracks compared to symmetrical rolling.This enhancement is attributed to the shearing stress induced by asymmetrical rolling,which reduces the rolling force and longitudinal secondary tensile stress,and increases the residual compressive stress on the surface of the rolled piece.The edge crack defects of copper foil can be effectively reduced by increasing the speed ratio between the rolls in asymmetrical rolling.
基金The financial support provided by the Project of the National Natural Science Foundation of China (22308314,U22A20415)the Natural Science Foundation of Zhejiang Province (LQ24B060001)+1 种基金the "Pioneer" and "Leading Goose" Research & Development Program of Zhejiang (2022C01SA442617)the SINOPEC Technology Development Project (224244)
文摘This study leverages machine learning to perform high-throughput computational screening of n-hexane cracking initiators.Artificial neural networks are applied to predict the chemical performance of initiators,using simulated pyrolysis data as the training dataset.Various feature extraction methods are utilized,and five neural network architectures are developed to predict the co-cracking product distribution based on molecular structures.High-throughput screening of 12946 molecules outside the training dataset identifies the top 10 initiators for each target product—ethylene,propylene,and butadiene.The relative error between predicted and simulated values is less than 7%.Additionally,reaction pathway analysis elucidates the mechanisms by which initiators influence the distribution of cracking products.The proposed framework provides a practical and efficient approach for the rapid identification and evaluation of high-performance cracking initiators.
基金supported by the National Natural Science Foundation of China(No.52075235)the Major Science and Technology Project of Gansu Province,China(No.22ZD6GA008)+2 种基金the Key Research and Development Program of Gansu Province,China(No.20YF3WA017)the Natural Science Foundation of Gansu Province,China(No.21JR7RA233)the Scientific and Technological Projects of Jiayuguan,China(No.22-16)。
文摘The 7075 aluminum alloy was subjected to power-modulated laser welding using a full-domain power modulation(FDPM)laser oscillating welding system.Three different power modes were utilized:constant power(CP),gradient power(GP),and alternating power(AP)modes.The impact of different power modes on joint crack sensitivity,microstructure,and residual stress was assessed.The results demonstrate that joint welded with the AP mode exhibits the lowest sensitivity to solidification cracking(with mean crack sensitivity of 18.3%),and the smallest average grain size in the fusion zone of the weld seam(80μm).Additionally,it shows the highest microhardness(HV 113)and the narrowest softening region(3.5 cm).Furthermore,the joint displays the lowest residual stress and cooling rate,which is the reason for its minimal crack sensitivity.
基金supported by the National Natural Science Foundation of China(Grant No.42277124)the National Key Research&Development Program of China(Grant No.2020YFC1808004)the Jiangsu Province 333 Talents Youth Talent Support Project.
文摘In subtropical regions,soil desiccation cracking often exerts a significant impact on the interactions between soil water and the atmosphere,making it a subject of great interest in the fields of geotechnical and geoenvironmental engineering.Despite the growing utilization of biochar as a sustainable soil amendment,there remains a lack of in-depth understanding of biocharewateresoil interactions,as well as its impact on soil desiccation cracking behavior.To address this gap,this study investigated the influence and mechanism of woody biochar dosages and particle sizes on the cracking behavior of three typical clayey soils in subtropical regions in China,namely Pukou expansive soil(PKE),Xiashu soil(XS),and Zhongshan lateritic soil(ZSL).The quantitative analysis of crack images revealed that the use of biochar was not consistently effective in preventing soil cracking.The application of biochar reduced the crack ratio in PKE and XS by up to 24.03%and 53.89%,respectively.In contrast,ZSL exhibited a 74.57%increase in crack ratio with the addition of 10%biochar.This influence can be further enhanced by increasing the dosage and reducing the particle size of biochar.The microstructural analysis demonstrated that biochar exerts an inhibitory effect on PKE and XS primarily through direct replacement,direct barrier,and indirect physical mechanisms.Moreover,an indirect chemical effect between biochar and clay particles was proposed to explain the exacerbated cracking observed in biochar-amended ZSL.To effectively utilize biochar for soil cracking mitigation in subtropical regions,it is essential to evaluate the initial mineral composition and cation type of the soil.
基金supported by the National Natural Science Foundation of China(52071175,52301304)the Natural Science Foundation of Jiangsu Province(BK20230704)+3 种基金the China Postdoctoral Science Foundation Funded Project(2023M731742)the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province(23KJB430019)the Research Fund of Nanjing Institute of Technology(YKJ202402)the Open Research Fund of Jiangsu Key Laboratory for Light Metal Alloys(LMA202401).
文摘Implants are inevitably subjected to stress corrosion,bringing serious challenges to the controlled degradation of biomedical Mg alloys.It is worth studying the stress corrosion cracking(SCC)behavior of Mg alloy and exploring Mg alloy with good SCC resistance for wide biomedical applications.In this work,the as-cast and as-extruded Mg-3Gd-1Zn-0.4Zr(GZ31K)alloys with uniform corrosion were used to investigate SCC behavior.The as-extruded GZ31K alloy exhibited better corrosion resistance and mechanical properties than the as-cast one mainly owing to grain refinement and uniformly distributed fine precipitates,and possessed superior SCC resistance.To clarify the SCC mechanism,the slow strain rate tests were assisted with applied constant potentials via an electrochemical workstation.Accelerated anodic dissolution at anodic polarization deteriorated SCC resistance due to the initiation of corrosion pits and micro-cracks.However,cathodic polarization had no obvious effects on SCC resistance,along with both retarded corrosion and accelerated hydrogen evolution.Stacking faults in GZ31K alloy were hydrogen capture containers to reduce the effect of hydrogen on SCC resistance during cathodic polarization.These findings provide new insights into the evaluation of SCC mechanism,and offer more opportunities to explore Mg alloys with good SCC resistance by regulating anodic dissolution.
基金funded by the National Natural Science Foundation of China(42062019,42002283)。
文摘Surface soil cracking in alpine meadows signifies the transition of degradation from quantitative accumulation to qualitative deterioration.Quantitative research remains insufficient regarding changes in the mechanical properties of degraded meadow soils and the mechanical thresholds for cracking initiation.This study explored the relationships between surface cracking and the physical properties,tensile strength,and matrix suction of root-soil composites in alpine meadow sites with different stages of degradation(undegraded(UD),lightly degraded(LD),moderately degraded(MD),and heavily degraded(HD))under different water gradients(high water content(HWC),medium water content(MWC),and low water content(LWC))corresponding to different drying durations at a constant temperature of 40.0°C.The Huangcheng Mongolian Township in Menyuan Hui Autonomous County,Qinghai Province,China was chosen as the study area.The results indicated that as the degradation degree of alpine meadow intensified,both water content of rootsoil composite and the fine grain content of soil decreased.In contrast,the root-soil mass ratio and root area ratio initially increased and then decreased with progressive degradation.Under a consistent water content,the tensile strength of root-soil composite followed a pattern of MD>HD>LD>UD.The peak displacement of tensile strength also decreased as the degradation degree of alpine meadow increased.Both the tensile strength and matrix suction of root-soil composite increased as root-soil water content decreased.A root-soil water content of 30.00%-40.00%was found to be the critical threshold for soil cracking in alpine meadows.Within this range,the matrix suction of root-soil composite ranged from 50.00 to 100.00 kPa,resulting in the formation of linear cracks in the surface soil.As the root-soil water content continued to decrease,liner cracks evolved into branch-like and polygonal patterns.The findings of this study provide essential data for improving the mechanical understanding of grassland cracking and its development process.
文摘Hydrogen-induced cracking (HIC) is one of the most complex material problems that hydrogen can diffuse into and interact with microstructure, degrading their mechanical properties. Microstructural modification is an effective way to enhance the resistance to HIC. The present study focused on the relationship between the retained austenite (RA) and HIC behavior in NiCrMoV/Nb multi-alloying ultra-strength steel. Results demonstrated that the maximum volume fraction of RA of 9.31% was obtained for QL30T specimen. After the deep cryogenic pretreatment, the volume fraction of RA reduced to 8.8%. RA could reduce the effective diffusion coefficient, while deep cryogenic pretreatment increased the susceptibility of the steel to HIC by a maxim of 14.8%. This was mainly due to the transformation of retained austenite into martensite, degrading the mechanical properties under hydrogen-charged condition. In addition, the deep cryogenic pretreatment had a significant effect on the crack initiation and propagation, with the intergranular (IG) fracture becoming the dominant fracture mode where an increase in the number of secondary cracks in the section. The interfaces of RA and matrix, as well as the grain boundaries, were the preferred sites for cracks initiation.
基金support from the National Key Research and Development Program of China(No.2023YFB3710300)National Natural Science Foundation of China(Nos.12174296 and 52101088)+1 种基金Major Program(JD)of Hubei Province,China(No.2023BAA019-5)Numerical calculation is supported by the High-Performance Computing Center of Wuhan University of Science and Technology,China.
文摘The effect of aging precipitation on the stress corrosion cracking(SCC)mechanism of Ni(Fe,Al)-maraging steel was studied through the comparative characterization and analyses of the microstructures and fracture features of solid–solution and peak-aged steels.Aging precipitation exerts a chain of impacts on the deformative compatibility and electrochemical difference between the matrix and oth-er phases or interfaces.The strength of the martensite matrix is enhanced by abundant and evenly dispersed Ni(Fe,Al)precipitates,thereby reducing the possibility of splitting across martensite laths.Meanwhile,the Volta potential difference(VPD)between the matrix and primary NbC particles increases from 11.43 to 18.60 mV.Given that most of the primary NbC particles tend to be distributed along high-angle grain boundaries(HAGBs),anodic dissolution along HAGBs accelerates.Therefore,mechanical and electrochemical factors triggered by aging precipitation are involved in the variation in SCC behavior and mechanism.The SCC susceptibility of the steel in-creases along with the increasing tendency for intergranular cracking.
基金supported by the National Key R&D Program of China(No.2021YFF0502100)the National Natural Science Foundation of China(Nos.52278461 and 52308467).
文摘Cracking of early-age concrete can occur in the track beds of high-speed railways due to changes in material properties,environmental effects,and construction processes.This is a multi-field,time-varying issue involving hydro-thermo-chemo-mechanical coupling.However,to date,research has not adequately described the early-age cracking mechanisms in track beds,and few risk control measures have been proposed.To solve this problem,we incorporated the hydration degree of concrete into multi-field coupling equations for early-age concrete,and set boundary conditions that account for environmental influences and various stress factors that typically cause early creep of concrete.A four-field coupled risk prediction model was built based on hydro-thermo-chemo-mechanical properties,and was used to calculate and analyze various time-varying behavior(including the risk and form of cracking)in the hydro,thermo,chemo,and mechanical fields of early-age concrete.Finally,we focused on material-related factors(maximum heat of hydration and peak heat release time),environmental factors(temperature difference between day and night,average daily cooling rate,and intensity of solar radiation),and construction technique factors(molding temperature,pouring time,and thermal insulation coefficient).The influence of these factors on the early-age cracking risk of the track bed was analyzed,and risk control measures against early cracking were proposed accordingly.
基金supported by Hunan Provincial Natural Science Foundation of China(Grant No.2022JJ40194)National Natural Science Foundation of China(Grant No.32102322)National Technology System for Grape Industry(Grant No.CARS-29-ZP-9)。
文摘Fruit cracking is a persistent challenge for table grape growing.To investigate the mechanism of this disorder,a comprehensive two-year investigation was conducted to assess the fruit cracking percentage of 15 table grape(Vitis vinifera L.)varieties.Based on the findings,the cracking-susceptible variety‘Xiangfei'and the cracking-resistant variety‘Zuijinxiang'were selected for further study.Fruit growth curves for‘Zuijinxiang'and‘Xiangfei'were plotted based on fruit diameter and total soluble solids content,revealing that both varieties exhibited typical double-sigmoidal patterns that were highly similar.The period between 48 and 53 days after full bloom(DAFB)was identified as the critical phase for fruit cracking incidence.Furthermore,during the fruit cracking period,‘Xiangfei'fruit exhibited significantly higher water content and mesocarp cell area compared with those of‘Zuijinxiang'.Applying aquaporin inhibitors(nano-silver)to‘Xiangfei'berries reduced fruit water uptake and cracking percentage,whereas applying aquaporin activators(forskolin)to‘Zuijinxiang'berries increased fruit water uptake and cracking percentage.Additionally,expression analysis of six genes associated with plasma membrane intrinsic proteins(PIPs)synthesis(VvPIP1;1,VvPIP1;2,VvPIP1;3,VvPIP2;1,VvPIP2;2,and VvPIP2;3)revealed that only the expression level of VvPIP1;1 was higher in‘Zuijinxiang'than in‘Xiangfei'during the fruit cracking period,whereas the expression levels of the other genes exhibited no significant difference between the two varieties.Transgenic overexpression of VvPIP1;1 in tomato resulted in increased fruit water content,enlarged mesocarp cell size,and enhanced fruit cracking percentage.These findings indicate that VvPIP1;1 plays a pivotal role in controlling grape berry cracking.
基金supported by General Program of National Natural Science Foundation of China (22178385)。
文摘In this work,a new process for achieving the recovery of elemental sulfur by utilizing a fluidized catalytic cracking(FCC) riser reactor for SOxtreatment(FCC-DeSOx) is proposed.The process leverages the high temperatures and hydrocarbon concentrations in the FCC riser reactor to convert SOxinto H_(2)S.Subsequently,H_(2)S,along with the cracked gas,is processed downstream to produce sulfur.Thermodynamic analysis of the key reduction reactions in the FCC-DeSOxprocess revealed that complete conversion of SOxto H_(2)S is feasible in the dry gas(hydrogen-rich) prelift zone,as well as the upper and lower zones of the riser,upon achieving thermodynamic equilibrium.Experimental studies were conducted to replicate the conditions of these reaction zones using a low concentration of hydrogen gas as the reducing agent.Through process optimization,investigation of the minimum reaction time,and kinetic studies,the potential of this method for the complete reduction of SOxwas further confirmed.
基金supported by the Innovative Research Group Project of the National Natural Science Foundation of China(22021004)Sinopec Major Science and Technology Projects(321123-1)。
文摘Coking at the fractionating tower bottom and the decant oil circulation system disrupts the heat balance,leading to unplanned shutdown and destroying the long period stable operation of the Fluid Catalytic Cracking Unit(FCCU).The FCCU operates through interconnected subsystems,generating high-dimensional,nonlinear,and non-stationary data characterized by spatiotemporally correlated.The decant oil solid content is the crucial indicator for monitoring catalyst loss from the reactor-regenerator system and coking risk tendency at the fractionating tower bottom that relies on sampling and laboratory testing,which is lagging responsiveness and labor-intensive.Developing the online decant oil solid content soft sensor using industrial data to support operators in conducting predictive maintenance is essential.Therefore,this paper proposes a hybrid deep learning framework for soft sensor development that combines spatiotemporal pattern extraction with interpretability,enabling accurate risk identification in dynamic operational conditions.This framework employs a Filter-Wrapper method for dimensionality reduction,followed by a 2D Convolutional Neural Network(2DCNN)for extracting spatial patterns,and a Bidirectional Gated Recurrent Unit(BiGRU)for capturing long-term temporal dependencies,with an Attention Mechanism(AM)to highlight critical features adaptively.The integration of SHapley Additive exPlanations(SHAP),Complementary Ensemble Empirical Mode Decomposition with Adaptive Noise(CEEMDAN),2DCNN,and expert knowledge precisely quantifies feature contributions and decomposes signals,significantly enhancing the practicality of risk identification.Applied to a China refinery with processing capacity of 2.80×10^(6) t/a,the soft sensor achieved the R^(2) value of 0.93 and five-level risk identification accuracy of 96.42%.These results demonstrate the framework's accuracy,robustness,and suitability for complex industrial scenarios,advancing risk visualization and management.
