In order to remove efficiently haled-particles emissions from coal combustions, a new way was used to put forward the process of agglomeration and the atomization was produced by the nozzle and then sprayed into the ...In order to remove efficiently haled-particles emissions from coal combustions, a new way was used to put forward the process of agglomeration and the atomization was produced by the nozzle and then sprayed into the flue before precipitation devices of power station boiler in order to make inhaled-particles agglomerate into bigger particles, which can be easily removed but not change existing running conditions of boiler. According to this idea, a model is set up to study agglomeration rate and effect forces between fly ash inhaled-particles and atomized agglomerator particles. The developed agglomeration rate was expressed by relative particle number decreasing speed per unit volume. The result showed that viscosity force and flow resistance force give main influences on agglomeration effect of inhaled-particles, while springiness force and gravity have little effect on agglomeration effect of theirs. Factors influencing the agglomeration rate and effect forces are studied, including agglomerator concentration, agglomerator flux and agglomerator density, atomized-particles diameters and inhaled-particles diameter and so on.展开更多
In older to collect fine particles more efficiently, a new-type electrostatic agglomerator with two zones was developed. The distinguishing feature of this electrostatic agglomerator is that the particles are bipolarl...In older to collect fine particles more efficiently, a new-type electrostatic agglomerator with two zones was developed. The distinguishing feature of this electrostatic agglomerator is that the particles are bipolarly charged and coagulated in the same alternating electric field simultaneously. The silica flour with 2 fun mass median diameter and the smoke from burning wood powder were used as test aerosol. The comparison experimental results have shown that when the mean electric field is 4 kV/cm the collection efficiency of the new electrostatic agglomerator was 98.2% for silica flour and 67.4% for wood powder smoke, Under the same experimental condition. the collection efficiency of the electrostatic agglomerator with three zones was 97.4% for collecting silica flour and the collection efficiency of the electrostatic precipitator was 56.3% for wood powder smoke.展开更多
The development of an efficient technology for removing fine particles in flue gas is essential as the haze is becoming more and more serious.To improve agglomeration effectiveness of fine particles,a dual zone electr...The development of an efficient technology for removing fine particles in flue gas is essential as the haze is becoming more and more serious.To improve agglomeration effectiveness of fine particles,a dual zone electric agglomeration device consisting of a charging chamber and an agglomeration chamber with bipolar barb electrodes was developed.The bipolar barb electric agglomerator with a polar distance of 200 mm demonstrates good agglomeration effectiveness for particles with a size less than 8.0μm under applied AC electric field.An optimal condition for achieving better agglomeration effectiveness was found to be as follows：flue gas flow velocity of3.00 m/s,particle concentration of 2.00 g/m^3,output voltage of 35 kV and length of the barb of16 ram.In addition,4.0-6.0μm particles haste the best effectiveness with the variation of particle volume occupancy of-3.2.展开更多
Interfacial interactions between rough mineral particles have garnered considerable attention as they directly determine particle agglomeration and floatability.This study comprehensively investigates the agglomeratio...Interfacial interactions between rough mineral particles have garnered considerable attention as they directly determine particle agglomeration and floatability.This study comprehensively investigates the agglomeration characteristics of siderite particles after argon(Ar)plasma surface modification through settling tests,flocs size measurements,and fractal dimension calculations.Ar plasma surface modification promotes the agglomeration of siderite particles,as evidenced by increased floc size and density.The agglomeration mechanism induced by Ar plasma surface modification is evaluated using a theoretical model combining the surface element integration(SEI)approach,differential geometry,and the composite Simpson's rule.Changes in surface roughness,wettability,and charge are considered in this model.Compared to the unpretreated siderite particles,the energy barrier for interaction of the 30-min Ar plasma-pretreated siderite particles decreases from 2.3×10-^(17)J to 1.6×10^(-17)J.This reduction provides strong evidence for the agglomeration behavior of siderite particles.Furthermore,flotation experiments confirm that Ar plasma surface modification is conducive to the aggregation flotation of siderite.These findings offer crucial insights into particle aggregation and dispersion behaviors,with notable application in mineral flotation.展开更多
Laser-induced aerosols,predominantly submicron in size,pose significant environmental and health risks during the decommissioning of nuclear reactors.This study experimentally investigated the removal of laser-generat...Laser-induced aerosols,predominantly submicron in size,pose significant environmental and health risks during the decommissioning of nuclear reactors.This study experimentally investigated the removal of laser-generated aerosol particles using a water spray system integrated with an innovative system for pre-injecting electrically charged mist in our facility.To simulate aerosol generation in reactor decommissioning,a high-power laser was used to irradiate various materials(including stainless steel,carbon steel,and concrete),generating aerosol particles that were agglomerated with injected water mist and subsequently scavenged by water spray.Experimental results demonstrate enhanced aerosol removal via aerosol-mist agglomeration,with charged mist significantly improving particle capture by increasing wettability and size.The average improvements for the stainless steel,carbon steel,and concrete were 40%,44%,and 21%,respectively.The results of experiments using charged mist with different polarities(both positive and negative)and different surface coatings reveal that the dominant polarity of aerosols varies with the irradiated materials,influenced by their crystal structure and electron emission properties.Notably,surface coatings such as ZrO_(2)and CeO_(2)were found to possibly alter aerosol charging characteristics,thereby affecting aerosol removal efficiency with charged mist configurations.The innovative aerosol-mist agglomeration approach shows promise in mitigating radiation exposure,ensuring environmental safety,and reducing contaminated water during reactor dismantling.This study contributes critical knowledge for the development of advanced aerosol management strategies for nuclear reactor decommissioning.The understanding obtained in this work is also expected to be useful for various environmental and chemical engineering applications such as gas decontamination,air purification,and pollution control.展开更多
In composite solid propellants with high aluminum(Al)content and low burning rate,incomplete combustion of the Al powder may occur.In this study,varying lithium(Li)content in Al-Li alloy powder was utilized instead of...In composite solid propellants with high aluminum(Al)content and low burning rate,incomplete combustion of the Al powder may occur.In this study,varying lithium(Li)content in Al-Li alloy powder was utilized instead of pure aluminum particles to mitigate agglomeration and enhance the combustion efficiency of solid propellants(Combustion efficiency herein refers to the completeness of metallic fuel oxidation,quantified as the ratio of actual-to-theoretical energy released during combustion)with high Al content and low burning rates.The impact of Al-Li alloy with different Li contents on combustion and agglomeration of solid propellant was investigated using explosion heat,combustion heat,differential thermal analysis(DTA),thermos-gravimetric analysis(TG),dynamic high-pressure combustion test,ignition experiment of small solid rocket motor(SRM)tests,condensation combustion product collection,and X-ray diffraction techniques(XRD).Compared with pure Al,Al-Li alloys exhibit higher combustion heat,which contributes to improved combustion efficiency in Al-Li alloy-containing propellants.DTA and TG analyses demonstrated higher reactivity and lower ignition temperatures for Al-Li alloys.High-pressure combustion experiments at 5 MPa showed that Al-Li alloy fuel significantly decreases combustion agglomeration.The results from theφ75 mm andφ165 mm SRM and XRD tests further support this finding.This study provides novel insights into the combustion and agglomeration behaviors of high-Al,low-burning-rate composite solid propellants and supports the potential application of Al-Li alloys in advanced propellant formulations.展开更多
Majority of carbon emissions originate from fossil energy consumption,thus necessitating calculation and monitoring of carbon emissions from energy consumption.In this study,we utilized energy consumption data from Si...Majority of carbon emissions originate from fossil energy consumption,thus necessitating calculation and monitoring of carbon emissions from energy consumption.In this study,we utilized energy consumption data from Sichuan Province and Chongqing Municipality for the years 2000 to 2019 to estimate their statistical carbon emissions.We then employed nighttime light data to downscale and infer the spatial distribution of carbon emissions at the county level within the Chengdu-Chongqing urban agglomeration.Furthermore,we analyzed the spatial pattern of carbon emissions at the county level using the coefficient of variation and spatial autocorrelation,and we used the Geographically and Temporally Weighted Regression(GTWR)model to analyze the influencing factors of carbon emissions at this scale.The results of this study are as follows:(1)from 2000 to 2019,the overall carbon emissions in the Chengdu-Chongqing urban agglomeration showed an increasing trend followed by a decrease,with an average annual growth rate of 4.24%.However,in recent years,it has stabilized,and 2012 was the peak year for carbon emissions in the Chengdu-Chongqing urban agglomeration;(2)carbon emissions exhibited significant spatial clustering,with high-high clustering observed in the core urban areas of Chengdu and Chongqing and low-low clustering in the southern counties of the Chengdu-Chongqing urban agglomeration;(3)factors such as GDP,population(Pop),urbanization rate(Ur),and industrialization structure(Ic)all showed a significant influence on carbon emissions;(4)the spatial heterogeneity of each influencing factor was evident.展开更多
Gold ores in the Jiaozhou region of China are characterized by their abundant reserves,low grade,fine dissemination,and chal-lenges in upgrading.Froth flotation,with xanthate as the collector,is a commonly employed me...Gold ores in the Jiaozhou region of China are characterized by their abundant reserves,low grade,fine dissemination,and chal-lenges in upgrading.Froth flotation,with xanthate as the collector,is a commonly employed method for enriching auriferous pyrite from these ores.This study aimed to develop a more efficient flotation process by utilizing cavitation nanobubbles for a low-grade gold ore.Batch flotation tests demonstrated that nanobubbles significantly enhanced the flotation performance of auriferous pyrite,as evidenced by improved concentrate S and Au grades and their recoveries.The mechanisms underlying this enhancement were explored by investigat-ing surface nanobubble(SNB)formation,bulk nanobubble(BNB)attachment to hydrophobic pyrite surfaces,and nanobubble-induced agglomeration using atomic force microscopy(AFM)and focused beam reflectance measurement(FBRM).The results revealed that nan-obubble coverage on the pyrite surface is a critical factor influencing surface hydrophobicity and agglomeration.SNBs exhibited higher coverage on pyrite surfaces with increased surface hydrophobicity,flow rate,and cavitation time.Similarly,BNB attachment on pyrite surfaces was significantly increased with surface hydrophobicity and cavitation time.Enhanced surface hydrophobicity,along with higher flow rates and cavitation times,promoted pyrite particle agglomeration owing to the increased nanobubble coverage,ultimately leading to improved flotation performance.展开更多
Patna is among the cities high populated at risk of ecological and environmental deterioration due to a variety of human activities,such as poor land cover management.One of the most crucial elements of a successful l...Patna is among the cities high populated at risk of ecological and environmental deterioration due to a variety of human activities,such as poor land cover management.One of the most crucial elements of a successful land resource management plan is the evaluation of Land Use Land Cover(LULC).Over the past 20 years,our planet’s land cover resources have undergone substantial changes due to rapid development.The Land Use Land Cover(LULC)categories of the Patna Urban Agglomeration(PUA),including water bodies,agricultural land,barren land,built-up areas,and vegetation,were identified using Geographic Information System(GIS)techniques.Three multi-temporal images were analyzed and classified through supervised classification using the maximum likelihood method.By comparing three separately created LULC categorized maps from 1990 and 2024,temporal changes were analyzed.In order to update land cover or manage natural resources,it is vital to use change detection as a tool to identify changes in LULC over time in PUA,Patna between 1990,2010 and 2024.According to their respective Kappa coefficients,the accuracy rates for 1990,2010 and 2024 LULC are 91.66 and 94.93,respectively.An accuracy evaluation was conducted to determine the correctness of the classification system and to determine the efficacy of the LULC classification maps.One hundred reference test pixels were identified.There have been found significant changes in the LULC were built up area has increased doubled in last thirty-four years of timeline.展开更多
The horizontal ecological compensation plays an important role in balancing the interests of all parties and coordinating regional development in the basin.However,the mechanism of ecological compensation based on emb...The horizontal ecological compensation plays an important role in balancing the interests of all parties and coordinating regional development in the basin.However,the mechanism of ecological compensation based on embodied carbon emissions is still poorly understood.Here,taking the Yellow River Basin as the research area,we use the multi-regional input-output(MRIO)model to measure the embodied carbon transfers between its seven urban agglomerations in 2012 and 2017 from the viewpoint of value-added trade benefits.Further,for the first time,the green trade benefits and ecological compensation amounts are analyzed.The results indicate that:(1)The transfer of trade-embodied carbon among the urban agglomerations in the basin showed obvious spatial heterogeneity and geographic proximity effects,and trade-embodied carbon outflows(inflows)had a pattern of"highest in the midstream,second in the downstream,and lowest in the upstream".(2)The industry composition of the urban agglomerations in relation to embodied carbon outflows(inflows)was similar,mainly in the service and heavy manufacturing industries.(3)The spatial pattern of green trade benefits in the basin had shifted from"high in the north and low in the surrounding area"to"high in the east-central part and low in the west".(4)The pattern of ecological compensation in the basin had shifted from the upstream surplus,the middle and downstream deficit to the midstream deficit,and the upstream and downstream surplus.Therefore,we recommend improving energy structures in high-demand urban agglomerations by adopting clean energy,focusing on decarbonization and energy efficiency in resource-rich regions.Additionally,promoting low-carbon economies,especially in the service and heavy manufacturing industries,implementing differentiated emission reduction strategies,and optimizing carbon compensation mechanisms considering regional disparities and resource endowments are crucial.It is expected that the study can enrich the scientific basis of horizontal ecological compensation and increase the fairness of regional carbon emission rights allocation.展开更多
Intercity mobility lays the foundation for capital flow,information flow,and knowledge flow,etc.,and is important for promoting regional integration.Although many scholars have studied intercity mobility in extensive ...Intercity mobility lays the foundation for capital flow,information flow,and knowledge flow,etc.,and is important for promoting regional integration.Although many scholars have studied intercity mobility in extensive well-developed urban agglomerations,few studies have examined the characteristics of intercity mobility at the county level and its impact on regionalization in western China.This study takes the Guanzhong Plain urban agglomeration(GPUA)as a case to study the geographical law of intercity mobility and then explore its impact on regionalization.The results obtained show that intercity mobility network exhibits a hub and spoke patterns focusing on major municipal districts at the county level.We also found a corridor effect that counties with higher travel volumes are mostly located along the trunk high speed railway(HSR)lines.Unlike previous studies,the distribution of intercity mobility is more concentrated than that of population and exhibits a super-linear behavior rule.There are the differences in gravity law for overall trips,weekday trips,weekend trips,and holiday trips.With the decrease of travel duration,the effect of attraction of destination is weakening,but the influence of distance decay is increasing.Finally,the spatial organization is still administrative-centric and is dominated by intraprefecture and intra-provincial development.Moreover,the coupled degree between network-based regionalization and attribute-based regionalization shows a decreasing trend from administrative via cultural to physical factors.These findings enrich the research on the intercity mobility and the regionalization in inland developing urban agglomerations.展开更多
Current mix design practices typically assume total blending and use the white curve of reclaimed asphalt pavement(RAP)to determine the gradation and optimum asphalt content(OAC)of recycled hot mix asphalt(HMA),often ...Current mix design practices typically assume total blending and use the white curve of reclaimed asphalt pavement(RAP)to determine the gradation and optimum asphalt content(OAC)of recycled hot mix asphalt(HMA),often overlooking the effects of RAP agglomeration and partial blending.This oversight can result in unsatisfactory performance,particularly when higher RAP content is used.Therefore,this paper reviews and discusses strategies for adjusting the mix design of recycled HMA to enhance its in-service performance.The discussion begins with RAP particle agglomeration,a significant phenomenon that significantly impacts the aggregate gradation of recycled HMA.Subsequently,detection methods to clarify the blending between virgin and RAP binders are described.Partial blending between RAP and virgin binders is common,and various indexes have been proposed to quantify the blending degree.Finally,the adjusted mix design method of recycled HMA is presented,emphasizing gradation optimization and corrected OAC.Gradation optimization should account for RAP agglomeration,while the corrected OAC should consider particle blending.Recycled HMA using the adjusted mix design exhibits improved crack resistance and fatigue life without substantially impairing rutting performance.This review aims to help both academics and highway agencies maximize the utilization of RAP materials within sustainable pavement frameworks.展开更多
This study focuses on urgent research on restoring and enhancing carbon storage capacity in the Beibu Gulf Urban Agglomer-ation of China,a key area in the‘Belt and Road’Initiative,which aligns with carbon peaking an...This study focuses on urgent research on restoring and enhancing carbon storage capacity in the Beibu Gulf Urban Agglomer-ation of China,a key area in the‘Belt and Road’Initiative,which aligns with carbon peaking and neutrality goals.This research ana-lyzes the spatial characteristics of carbon metabolism from 2000 to 2020 and uses models to identify stable carbon sink areas,positive carbon flow corridors,and carbon sequestration nodes.The goal is to construct a carbon metabolism spatial security pattern(CMSSP)and propose territorial ecological restoration strategies under different development demand scenarios.The results show the following:1)in 2020,the study area’s carbon sink decreased by 8.29×10^(4) t C/yr compared with that in 2010 and by 10.83×10^(4) t C/yr compared with that in 2000.High-carbon sinks were found mainly in mountainous areas,whereas low-carbon sinks are concentrated in urban con-struction land,rural residential areas,and land margins.2)From 2000 to 2020,the spatial security pattern of carbon metabolism tended to be‘high in the middle of the east and west and low in the gulf.’In 2000,2010,and 2020,16 stable carbon sinks were identified.The carbon energy flow density in Guangxi was greater than that in Guangdong and Hainan,with positive carbon flow corridors located primarily in Guangxi and Guangdong.The number of carbon sequestration nodes remained stable at approximately 15,mainly in Guangxi and Hainan.3)Scenario simulations revealed that under the Nature-based mild restoration scenario,the carbon sink rate will reach 611.85×10^(4) t C/yr by 2030 and increase to 612.45×10^(4) t C/yr by 2060,with stable carbon sinks increasing to 18.In the restora-tion scenario based on Anti-globalization,the carbon sink will decrease from 610.24×10^(4) t C/yr in 2030 to 605.19×10^(4) t C/yr in 2060,with the disappearance of some positive carbon flow corridors and stable carbon sinks.Under the Human-based sustainable restoration scenario,the carbon sink area will decrease from 607.00×10^(4) t C/yr in 2030 to 596.39×10^(4) t C/yr in 2060,with carbon sink areas frag-menting and positive carbon flow corridors becoming less dense.4)On the basis of the current and predicted CMSSPs,this study ex-plores spatial ecological restoration strategies for high-carbon storage areas in bay urban agglomerations at four levels:the land control region,urban agglomeration structure system,carbon sink structure and bay structure control region.展开更多
Farmland transfer is an important land policy for reducing agricultural fragmentation and improving land use efficiency.Many studies have investigated the driving forces of farmland transfer at the farmers’scale.Howe...Farmland transfer is an important land policy for reducing agricultural fragmentation and improving land use efficiency.Many studies have investigated the driving forces of farmland transfer at the farmers’scale.However,the overall spatial distribution and driving mechanisms of farmland transfer at the county scale has been less quantified.In this study,we evaluated farmland transfer and its spatial pattern in Central Yunnan Urban Agglomeration(CYUA)of China by using statistical data at the county scale in 2020.A so-cial-ecological indicator system,comprising natural endowment,social indicators,economic indicators,and landscape patterns,was es-tablished to explore the relationship between farmland transfer and its driving factors.Additionally,a heuristic structural equation mod-el(SEM)was employed to disentangle direct and indirect drivers of farmland transfer.The results indicated that significant spatial clusters of farmland transfer,with high transfer rates concentrated in highly urbanized areas and low transfer rates prevalent in tradition-al ethnic minority regions.Farmland transfer is primarily driven by soil quality,landscape patterns,terrain,and social-economic rurality.Specifically,higher soil quality and improved landscape connectivity facilitate farmland transfer directly,while gentler slopes promote farmland transfer indirectly by supporting better educational opportunities and fewer minority population.Improving rural vocational training and optimizing landscape patterns through land consolidation and redistribution are important in the mountainous areas.This study can provide valuable analytical framework for farmland management for other mountainous regions.展开更多
Manure slurry application to farmland reduces chemical fertilizer use,mitigates pollution,and improves soil fertility.However,researches on the role of anaerobically treated cow slurry applied to soil microorganisms i...Manure slurry application to farmland reduces chemical fertilizer use,mitigates pollution,and improves soil fertility.However,researches on the role of anaerobically treated cow slurry applied to soil microorganisms in Northeast China remain underexplored.Here,in laboratory incubation experiments,different treatments including various combinations of sterilized and non-sterilized soil and slurry,and different application rates were employed to examine the effects of indigenous microorganisms on soil microbial communities.Field-collected soil samples were employed to examine the responses and spatial variations of soil microbes under production conditions.The results indicated that indigenous soil microorganisms exerted a dominant influence in the microbial community variations,while the impact of cow slurry microbiota on community diversity was relatively minor.At the phylum level,Proteobacteria(P=0.031,R=0.969)showed a significant positive correlation with the slurry application,whereas Acidobacteriota(P=0.012,R=–0.988)and Basidiomycota(P=0.01,R=–0.99)showed significant negative correlations.In the field environment,the autumn slurry application effects on soil microbes in the following year were not significant.In contrast,under spring slurry application,the cow slurry-soil agglomerations led to significant spatial differences in soil microbial communities,with higher microbial diversity observed in the vicinity of agglomerations.The microbes in agglomerations,such as Actinomycetes,Bacteroides and Proteobacteria,were found to be beneficial for the crop residue decomposition.These microorganisms could decompose organic compounds including lignin,cellulose,hemicellulose,and xylan in crop straw.Overall,slurry application indeed influenced soil microbes and induced spatial variations,providing insights for sustainable agricultural practices.展开更多
Model calculations and laboratory experiments were conducted to investigate the influence of surface tension of the molten steel on the agglomeration trend of Al_(2)O_(3) inclusions.The agglomeration trends of inclusi...Model calculations and laboratory experiments were conducted to investigate the influence of surface tension of the molten steel on the agglomeration trend of Al_(2)O_(3) inclusions.The agglomeration trends of inclusions were compared using the calculated attractiveness.When the S content in the steel increased from 2.7×10^(-6) to 789×10^(-6),the surface tension of the molten steel decreased from 1.91 to 1.39 N/m,while the attractive force between inclusions increased from 5×10^(-18) to 5×10^(-16) N,and the critical collision distance of Al_(2)O_(3) inclusions gradually increased from 30 to 70μm.A model of the relationship between the capillary force of inclusions and S content in steel was established.It was found that the capillary force calculated by the model showed the same trend as the attractive force obtained from experiments,and an increase in the S content promoted the attraction between inclusions.展开更多
1.Introduction The strength-ductility trade-offdilemma has long been a per-sistent challenge in Al matrix composites(AMCs)[1,2].This is-sue primarily arises from the agglomeration of reinforcements at the grain bounda...1.Introduction The strength-ductility trade-offdilemma has long been a per-sistent challenge in Al matrix composites(AMCs)[1,2].This is-sue primarily arises from the agglomeration of reinforcements at the grain boundaries(GBs),which restricts local plastic flow dur-ing the plastic deformation and leads to stress concentration[3,4].Recently,the development of concepts aimed at achieving hetero-geneous grain has emerged as a promising approach for enhanc-ing comprehensive mechanical properties[5,6].展开更多
AP(Ammonium Perchlorate)and HMX(Octogen)are the two oxidizers most often used in Nitrate-Ester-Plasticized Polyether(NEPE)rocket propellants.How the AP–HMX ratio influences the agglomeration of NEPE propellants remai...AP(Ammonium Perchlorate)and HMX(Octogen)are the two oxidizers most often used in Nitrate-Ester-Plasticized Polyether(NEPE)rocket propellants.How the AP–HMX ratio influences the agglomeration of NEPE propellants remains unclear.We experimentally investigated the effect of the AP–HMX ratio on the combustion and agglomeration of NEPE propellants using burning rate test,quenched surface analysis,microscopic observations,and the collection of condensed combustion products.It was found that with the decrease in AP content from 40wt%to 10wt%,the burning rate decreased from 14.2 mm/s to 9.2 mm/s because the adiabatic flame temperature of NEPE propellants decreased from 3828 K to 3736 K.Pockets bounded by AP particles appeared on the surface when AP content was 40wt%;however,the accumulations grew and covered the burning surface eventually as the AP–HMX ratio decreased.The time required for the accumulation to coalesce into agglomerates increased with decreasing AP content.Even with similar agglomerate sizes,the coalescence time increased by 83%when the AP content decreased from 40wt%to 30wt%.The agglomerate size in the Condensed Combustion Products(CCPs)increased from 100μm to 200μm,and the fraction of large agglomerations increased from 6.4%to 24.7%when the AP content decreased from 40wt%to 10wt%.Overall,the high flame temperature of the AP particles enhanced the decomposition of the surrounding binder,resulting in the rapid ejection of the aluminum particles into the gas,which had a separating effect on the accumulation,thus weakening the agglomeration.展开更多
The formation of large-sized inclusions cluster severely impacts the continuous casting process and product quality of titanium-containing steel.Thermodynamic calculations were initially conducted to predict the forma...The formation of large-sized inclusions cluster severely impacts the continuous casting process and product quality of titanium-containing steel.Thermodynamic calculations were initially conducted to predict the formation of various complex oxide inclusions,namely Al_(2)O_(3),TiO_(x)and Al-Ti-O.Based on that,laboratory-scale experiments were designed to prepare samples with a single type of inclusions.Then,the scanning electron microscope-energy dispersive spectrometer was used for quantitative characterization.Subsequently,the agglomeration behavior of inclusions in Fe-Al-Ti-O melt was observed in situ by high-temperature confocal laser scanning microscopy.Furthermore,a quantitative analysis of the agglomeration characteristics of the various inclusions was conducted based on the attractive forces in accordance with Newton's second law and the capillary forces as described by the Kralchevsky-Paunov model.The results indicate that the size of Al_(2)O_(3)inclusions is larger than that of TiO_(x)and Al-Ti-O,but the number density of TiO_(x)is the highest.Based on the in situ observation and the theoretical calculation,Al_(2)O_(3),TiO_(x)and Al-Ti-O inclusions can all agglomerate into large-sized clusters without segregation,but the agglomeration tendency of Al_(2)O_(3)and TiO_(x)is stronger than that of Al-Ti-O.The attractive force between Al_(2)O_(3)inclusions’pair is the largest,ranging from 2.26×10^(-15)to 6.12×10^(-14)N,followed by TiO_(x)(7.13×10^(-16)to 3.56×10^(-14)N)and Al-Ti-O(1.16×10^(-17)to 3.77×10^(-16)N).展开更多
文摘In order to remove efficiently haled-particles emissions from coal combustions, a new way was used to put forward the process of agglomeration and the atomization was produced by the nozzle and then sprayed into the flue before precipitation devices of power station boiler in order to make inhaled-particles agglomerate into bigger particles, which can be easily removed but not change existing running conditions of boiler. According to this idea, a model is set up to study agglomeration rate and effect forces between fly ash inhaled-particles and atomized agglomerator particles. The developed agglomeration rate was expressed by relative particle number decreasing speed per unit volume. The result showed that viscosity force and flow resistance force give main influences on agglomeration effect of inhaled-particles, while springiness force and gravity have little effect on agglomeration effect of theirs. Factors influencing the agglomeration rate and effect forces are studied, including agglomerator concentration, agglomerator flux and agglomerator density, atomized-particles diameters and inhaled-particles diameter and so on.
文摘In older to collect fine particles more efficiently, a new-type electrostatic agglomerator with two zones was developed. The distinguishing feature of this electrostatic agglomerator is that the particles are bipolarly charged and coagulated in the same alternating electric field simultaneously. The silica flour with 2 fun mass median diameter and the smoke from burning wood powder were used as test aerosol. The comparison experimental results have shown that when the mean electric field is 4 kV/cm the collection efficiency of the new electrostatic agglomerator was 98.2% for silica flour and 67.4% for wood powder smoke, Under the same experimental condition. the collection efficiency of the electrostatic agglomerator with three zones was 97.4% for collecting silica flour and the collection efficiency of the electrostatic precipitator was 56.3% for wood powder smoke.
基金supported by the Key Technology R&D Program of Hebei,China(No.13211207D)
文摘The development of an efficient technology for removing fine particles in flue gas is essential as the haze is becoming more and more serious.To improve agglomeration effectiveness of fine particles,a dual zone electric agglomeration device consisting of a charging chamber and an agglomeration chamber with bipolar barb electrodes was developed.The bipolar barb electric agglomerator with a polar distance of 200 mm demonstrates good agglomeration effectiveness for particles with a size less than 8.0μm under applied AC electric field.An optimal condition for achieving better agglomeration effectiveness was found to be as follows：flue gas flow velocity of3.00 m/s,particle concentration of 2.00 g/m^3,output voltage of 35 kV and length of the barb of16 ram.In addition,4.0-6.0μm particles haste the best effectiveness with the variation of particle volume occupancy of-3.2.
基金financially supported by the National Natural Science Foundation of China(No.52204284)the China Postdoctoral Science Foundation(No.2025MD784125)+2 种基金the Natural Science Foundation of Shaanxi Province,China(No.2024JC-YBQN-0365)the Shaanxi Province Postdoctoral Science Foundation,China(No.2025BSHSDZZ363)Outstanding Youth Science Fund of Xi’an University of Science and Technology,China(No.202308)。
文摘Interfacial interactions between rough mineral particles have garnered considerable attention as they directly determine particle agglomeration and floatability.This study comprehensively investigates the agglomeration characteristics of siderite particles after argon(Ar)plasma surface modification through settling tests,flocs size measurements,and fractal dimension calculations.Ar plasma surface modification promotes the agglomeration of siderite particles,as evidenced by increased floc size and density.The agglomeration mechanism induced by Ar plasma surface modification is evaluated using a theoretical model combining the surface element integration(SEI)approach,differential geometry,and the composite Simpson's rule.Changes in surface roughness,wettability,and charge are considered in this model.Compared to the unpretreated siderite particles,the energy barrier for interaction of the 30-min Ar plasma-pretreated siderite particles decreases from 2.3×10-^(17)J to 1.6×10^(-17)J.This reduction provides strong evidence for the agglomeration behavior of siderite particles.Furthermore,flotation experiments confirm that Ar plasma surface modification is conducive to the aggregation flotation of siderite.These findings offer crucial insights into particle aggregation and dispersion behaviors,with notable application in mineral flotation.
基金financial support from the Nuclear Energy Science&Technology and Human Resource Development Project of the Japan Atomic Energy Agency/Collaborative Laboratories for Advanced Decommissioning Science(No.R04I034)The author Ruicong Xu appreciates the scholarship(financial support)from the China Scholarship Council(CSC,No.202106380073).
文摘Laser-induced aerosols,predominantly submicron in size,pose significant environmental and health risks during the decommissioning of nuclear reactors.This study experimentally investigated the removal of laser-generated aerosol particles using a water spray system integrated with an innovative system for pre-injecting electrically charged mist in our facility.To simulate aerosol generation in reactor decommissioning,a high-power laser was used to irradiate various materials(including stainless steel,carbon steel,and concrete),generating aerosol particles that were agglomerated with injected water mist and subsequently scavenged by water spray.Experimental results demonstrate enhanced aerosol removal via aerosol-mist agglomeration,with charged mist significantly improving particle capture by increasing wettability and size.The average improvements for the stainless steel,carbon steel,and concrete were 40%,44%,and 21%,respectively.The results of experiments using charged mist with different polarities(both positive and negative)and different surface coatings reveal that the dominant polarity of aerosols varies with the irradiated materials,influenced by their crystal structure and electron emission properties.Notably,surface coatings such as ZrO_(2)and CeO_(2)were found to possibly alter aerosol charging characteristics,thereby affecting aerosol removal efficiency with charged mist configurations.The innovative aerosol-mist agglomeration approach shows promise in mitigating radiation exposure,ensuring environmental safety,and reducing contaminated water during reactor dismantling.This study contributes critical knowledge for the development of advanced aerosol management strategies for nuclear reactor decommissioning.The understanding obtained in this work is also expected to be useful for various environmental and chemical engineering applications such as gas decontamination,air purification,and pollution control.
基金the National Natural Science Foundation of China(Grant No.U2441263)for financial support of this work。
文摘In composite solid propellants with high aluminum(Al)content and low burning rate,incomplete combustion of the Al powder may occur.In this study,varying lithium(Li)content in Al-Li alloy powder was utilized instead of pure aluminum particles to mitigate agglomeration and enhance the combustion efficiency of solid propellants(Combustion efficiency herein refers to the completeness of metallic fuel oxidation,quantified as the ratio of actual-to-theoretical energy released during combustion)with high Al content and low burning rates.The impact of Al-Li alloy with different Li contents on combustion and agglomeration of solid propellant was investigated using explosion heat,combustion heat,differential thermal analysis(DTA),thermos-gravimetric analysis(TG),dynamic high-pressure combustion test,ignition experiment of small solid rocket motor(SRM)tests,condensation combustion product collection,and X-ray diffraction techniques(XRD).Compared with pure Al,Al-Li alloys exhibit higher combustion heat,which contributes to improved combustion efficiency in Al-Li alloy-containing propellants.DTA and TG analyses demonstrated higher reactivity and lower ignition temperatures for Al-Li alloys.High-pressure combustion experiments at 5 MPa showed that Al-Li alloy fuel significantly decreases combustion agglomeration.The results from theφ75 mm andφ165 mm SRM and XRD tests further support this finding.This study provides novel insights into the combustion and agglomeration behaviors of high-Al,low-burning-rate composite solid propellants and supports the potential application of Al-Li alloys in advanced propellant formulations.
基金supported by the Humanities and Social Sciences Project of the Ministry of Education of the Peoples Republic(No.21YJCZH099)the National Natural Science Foundation of China(Nos.41401089 and 41741014)the Science and Technology Project of Sichuan Province(No.2023NSFSC1979).
文摘Majority of carbon emissions originate from fossil energy consumption,thus necessitating calculation and monitoring of carbon emissions from energy consumption.In this study,we utilized energy consumption data from Sichuan Province and Chongqing Municipality for the years 2000 to 2019 to estimate their statistical carbon emissions.We then employed nighttime light data to downscale and infer the spatial distribution of carbon emissions at the county level within the Chengdu-Chongqing urban agglomeration.Furthermore,we analyzed the spatial pattern of carbon emissions at the county level using the coefficient of variation and spatial autocorrelation,and we used the Geographically and Temporally Weighted Regression(GTWR)model to analyze the influencing factors of carbon emissions at this scale.The results of this study are as follows:(1)from 2000 to 2019,the overall carbon emissions in the Chengdu-Chongqing urban agglomeration showed an increasing trend followed by a decrease,with an average annual growth rate of 4.24%.However,in recent years,it has stabilized,and 2012 was the peak year for carbon emissions in the Chengdu-Chongqing urban agglomeration;(2)carbon emissions exhibited significant spatial clustering,with high-high clustering observed in the core urban areas of Chengdu and Chongqing and low-low clustering in the southern counties of the Chengdu-Chongqing urban agglomeration;(3)factors such as GDP,population(Pop),urbanization rate(Ur),and industrialization structure(Ic)all showed a significant influence on carbon emissions;(4)the spatial heterogeneity of each influencing factor was evident.
基金support from the National Natural Science Foundation of China(No.52204274)the Shandong Provincial Natural Science Foundation,China(No.ZR2021QE122)+1 种基金Shandong Provincial Department of Science and Technology Key Project,China(No.2023TZXD021)Shandong Provincial Department of Science and Technology,China(No.ZTYJY-KY-2033-11).
文摘Gold ores in the Jiaozhou region of China are characterized by their abundant reserves,low grade,fine dissemination,and chal-lenges in upgrading.Froth flotation,with xanthate as the collector,is a commonly employed method for enriching auriferous pyrite from these ores.This study aimed to develop a more efficient flotation process by utilizing cavitation nanobubbles for a low-grade gold ore.Batch flotation tests demonstrated that nanobubbles significantly enhanced the flotation performance of auriferous pyrite,as evidenced by improved concentrate S and Au grades and their recoveries.The mechanisms underlying this enhancement were explored by investigat-ing surface nanobubble(SNB)formation,bulk nanobubble(BNB)attachment to hydrophobic pyrite surfaces,and nanobubble-induced agglomeration using atomic force microscopy(AFM)and focused beam reflectance measurement(FBRM).The results revealed that nan-obubble coverage on the pyrite surface is a critical factor influencing surface hydrophobicity and agglomeration.SNBs exhibited higher coverage on pyrite surfaces with increased surface hydrophobicity,flow rate,and cavitation time.Similarly,BNB attachment on pyrite surfaces was significantly increased with surface hydrophobicity and cavitation time.Enhanced surface hydrophobicity,along with higher flow rates and cavitation times,promoted pyrite particle agglomeration owing to the increased nanobubble coverage,ultimately leading to improved flotation performance.
文摘Patna is among the cities high populated at risk of ecological and environmental deterioration due to a variety of human activities,such as poor land cover management.One of the most crucial elements of a successful land resource management plan is the evaluation of Land Use Land Cover(LULC).Over the past 20 years,our planet’s land cover resources have undergone substantial changes due to rapid development.The Land Use Land Cover(LULC)categories of the Patna Urban Agglomeration(PUA),including water bodies,agricultural land,barren land,built-up areas,and vegetation,were identified using Geographic Information System(GIS)techniques.Three multi-temporal images were analyzed and classified through supervised classification using the maximum likelihood method.By comparing three separately created LULC categorized maps from 1990 and 2024,temporal changes were analyzed.In order to update land cover or manage natural resources,it is vital to use change detection as a tool to identify changes in LULC over time in PUA,Patna between 1990,2010 and 2024.According to their respective Kappa coefficients,the accuracy rates for 1990,2010 and 2024 LULC are 91.66 and 94.93,respectively.An accuracy evaluation was conducted to determine the correctness of the classification system and to determine the efficacy of the LULC classification maps.One hundred reference test pixels were identified.There have been found significant changes in the LULC were built up area has increased doubled in last thirty-four years of timeline.
基金supported by the National Natural Science Foundation of China(Grant number 42201302)the"Double First-Class"University Construction Project of Lanzhou University(Grant number:561120213)。
文摘The horizontal ecological compensation plays an important role in balancing the interests of all parties and coordinating regional development in the basin.However,the mechanism of ecological compensation based on embodied carbon emissions is still poorly understood.Here,taking the Yellow River Basin as the research area,we use the multi-regional input-output(MRIO)model to measure the embodied carbon transfers between its seven urban agglomerations in 2012 and 2017 from the viewpoint of value-added trade benefits.Further,for the first time,the green trade benefits and ecological compensation amounts are analyzed.The results indicate that:(1)The transfer of trade-embodied carbon among the urban agglomerations in the basin showed obvious spatial heterogeneity and geographic proximity effects,and trade-embodied carbon outflows(inflows)had a pattern of"highest in the midstream,second in the downstream,and lowest in the upstream".(2)The industry composition of the urban agglomerations in relation to embodied carbon outflows(inflows)was similar,mainly in the service and heavy manufacturing industries.(3)The spatial pattern of green trade benefits in the basin had shifted from"high in the north and low in the surrounding area"to"high in the east-central part and low in the west".(4)The pattern of ecological compensation in the basin had shifted from the upstream surplus,the middle and downstream deficit to the midstream deficit,and the upstream and downstream surplus.Therefore,we recommend improving energy structures in high-demand urban agglomerations by adopting clean energy,focusing on decarbonization and energy efficiency in resource-rich regions.Additionally,promoting low-carbon economies,especially in the service and heavy manufacturing industries,implementing differentiated emission reduction strategies,and optimizing carbon compensation mechanisms considering regional disparities and resource endowments are crucial.It is expected that the study can enrich the scientific basis of horizontal ecological compensation and increase the fairness of regional carbon emission rights allocation.
基金Under the auspices of National Natural Science Foundation of China(No.42371189)Central University Basic Research Fund of China(No.24ZYYB017)。
文摘Intercity mobility lays the foundation for capital flow,information flow,and knowledge flow,etc.,and is important for promoting regional integration.Although many scholars have studied intercity mobility in extensive well-developed urban agglomerations,few studies have examined the characteristics of intercity mobility at the county level and its impact on regionalization in western China.This study takes the Guanzhong Plain urban agglomeration(GPUA)as a case to study the geographical law of intercity mobility and then explore its impact on regionalization.The results obtained show that intercity mobility network exhibits a hub and spoke patterns focusing on major municipal districts at the county level.We also found a corridor effect that counties with higher travel volumes are mostly located along the trunk high speed railway(HSR)lines.Unlike previous studies,the distribution of intercity mobility is more concentrated than that of population and exhibits a super-linear behavior rule.There are the differences in gravity law for overall trips,weekday trips,weekend trips,and holiday trips.With the decrease of travel duration,the effect of attraction of destination is weakening,but the influence of distance decay is increasing.Finally,the spatial organization is still administrative-centric and is dominated by intraprefecture and intra-provincial development.Moreover,the coupled degree between network-based regionalization and attribute-based regionalization shows a decreasing trend from administrative via cultural to physical factors.These findings enrich the research on the intercity mobility and the regionalization in inland developing urban agglomerations.
基金sponsored by the National Natural Science Foundation of China(52178420,52408476)Special subsidy from Heilongjiang Provincial People's Government(HITTY-20190028)+1 种基金Postdoctoral Fellowship Program of CPSF(GZC20242207)the Fundamental Research Funds for the Central Universities(HIT.DZJJ.2023086).
文摘Current mix design practices typically assume total blending and use the white curve of reclaimed asphalt pavement(RAP)to determine the gradation and optimum asphalt content(OAC)of recycled hot mix asphalt(HMA),often overlooking the effects of RAP agglomeration and partial blending.This oversight can result in unsatisfactory performance,particularly when higher RAP content is used.Therefore,this paper reviews and discusses strategies for adjusting the mix design of recycled HMA to enhance its in-service performance.The discussion begins with RAP particle agglomeration,a significant phenomenon that significantly impacts the aggregate gradation of recycled HMA.Subsequently,detection methods to clarify the blending between virgin and RAP binders are described.Partial blending between RAP and virgin binders is common,and various indexes have been proposed to quantify the blending degree.Finally,the adjusted mix design method of recycled HMA is presented,emphasizing gradation optimization and corrected OAC.Gradation optimization should account for RAP agglomeration,while the corrected OAC should consider particle blending.Recycled HMA using the adjusted mix design exhibits improved crack resistance and fatigue life without substantially impairing rutting performance.This review aims to help both academics and highway agencies maximize the utilization of RAP materials within sustainable pavement frameworks.
基金Under the auspices of the National Natural Science Foundation of China(No.52268008)。
文摘This study focuses on urgent research on restoring and enhancing carbon storage capacity in the Beibu Gulf Urban Agglomer-ation of China,a key area in the‘Belt and Road’Initiative,which aligns with carbon peaking and neutrality goals.This research ana-lyzes the spatial characteristics of carbon metabolism from 2000 to 2020 and uses models to identify stable carbon sink areas,positive carbon flow corridors,and carbon sequestration nodes.The goal is to construct a carbon metabolism spatial security pattern(CMSSP)and propose territorial ecological restoration strategies under different development demand scenarios.The results show the following:1)in 2020,the study area’s carbon sink decreased by 8.29×10^(4) t C/yr compared with that in 2010 and by 10.83×10^(4) t C/yr compared with that in 2000.High-carbon sinks were found mainly in mountainous areas,whereas low-carbon sinks are concentrated in urban con-struction land,rural residential areas,and land margins.2)From 2000 to 2020,the spatial security pattern of carbon metabolism tended to be‘high in the middle of the east and west and low in the gulf.’In 2000,2010,and 2020,16 stable carbon sinks were identified.The carbon energy flow density in Guangxi was greater than that in Guangdong and Hainan,with positive carbon flow corridors located primarily in Guangxi and Guangdong.The number of carbon sequestration nodes remained stable at approximately 15,mainly in Guangxi and Hainan.3)Scenario simulations revealed that under the Nature-based mild restoration scenario,the carbon sink rate will reach 611.85×10^(4) t C/yr by 2030 and increase to 612.45×10^(4) t C/yr by 2060,with stable carbon sinks increasing to 18.In the restora-tion scenario based on Anti-globalization,the carbon sink will decrease from 610.24×10^(4) t C/yr in 2030 to 605.19×10^(4) t C/yr in 2060,with the disappearance of some positive carbon flow corridors and stable carbon sinks.Under the Human-based sustainable restoration scenario,the carbon sink area will decrease from 607.00×10^(4) t C/yr in 2030 to 596.39×10^(4) t C/yr in 2060,with carbon sink areas frag-menting and positive carbon flow corridors becoming less dense.4)On the basis of the current and predicted CMSSPs,this study ex-plores spatial ecological restoration strategies for high-carbon storage areas in bay urban agglomerations at four levels:the land control region,urban agglomeration structure system,carbon sink structure and bay structure control region.
基金Under the auspices of Yunnan Provincial Science and Technology Project at Southwest United Graduate School(No.202302AO370012)National Natural Science Foundation of China(No.42201290)+1 种基金Talent Introduction Fund of Yunnan University(No.CZ22623101)the Fourteenth Program of Research Innovation Fund for Graduate Students of Yunnan University(No.KC-22221099)。
文摘Farmland transfer is an important land policy for reducing agricultural fragmentation and improving land use efficiency.Many studies have investigated the driving forces of farmland transfer at the farmers’scale.However,the overall spatial distribution and driving mechanisms of farmland transfer at the county scale has been less quantified.In this study,we evaluated farmland transfer and its spatial pattern in Central Yunnan Urban Agglomeration(CYUA)of China by using statistical data at the county scale in 2020.A so-cial-ecological indicator system,comprising natural endowment,social indicators,economic indicators,and landscape patterns,was es-tablished to explore the relationship between farmland transfer and its driving factors.Additionally,a heuristic structural equation mod-el(SEM)was employed to disentangle direct and indirect drivers of farmland transfer.The results indicated that significant spatial clusters of farmland transfer,with high transfer rates concentrated in highly urbanized areas and low transfer rates prevalent in tradition-al ethnic minority regions.Farmland transfer is primarily driven by soil quality,landscape patterns,terrain,and social-economic rurality.Specifically,higher soil quality and improved landscape connectivity facilitate farmland transfer directly,while gentler slopes promote farmland transfer indirectly by supporting better educational opportunities and fewer minority population.Improving rural vocational training and optimizing landscape patterns through land consolidation and redistribution are important in the mountainous areas.This study can provide valuable analytical framework for farmland management for other mountainous regions.
基金Supported by the China Postdoctoral Science Foundation(2021M700742)Heilongjiang Postdoctoral Fund(LBH–Z21109)。
文摘Manure slurry application to farmland reduces chemical fertilizer use,mitigates pollution,and improves soil fertility.However,researches on the role of anaerobically treated cow slurry applied to soil microorganisms in Northeast China remain underexplored.Here,in laboratory incubation experiments,different treatments including various combinations of sterilized and non-sterilized soil and slurry,and different application rates were employed to examine the effects of indigenous microorganisms on soil microbial communities.Field-collected soil samples were employed to examine the responses and spatial variations of soil microbes under production conditions.The results indicated that indigenous soil microorganisms exerted a dominant influence in the microbial community variations,while the impact of cow slurry microbiota on community diversity was relatively minor.At the phylum level,Proteobacteria(P=0.031,R=0.969)showed a significant positive correlation with the slurry application,whereas Acidobacteriota(P=0.012,R=–0.988)and Basidiomycota(P=0.01,R=–0.99)showed significant negative correlations.In the field environment,the autumn slurry application effects on soil microbes in the following year were not significant.In contrast,under spring slurry application,the cow slurry-soil agglomerations led to significant spatial differences in soil microbial communities,with higher microbial diversity observed in the vicinity of agglomerations.The microbes in agglomerations,such as Actinomycetes,Bacteroides and Proteobacteria,were found to be beneficial for the crop residue decomposition.These microorganisms could decompose organic compounds including lignin,cellulose,hemicellulose,and xylan in crop straw.Overall,slurry application indeed influenced soil microbes and induced spatial variations,providing insights for sustainable agricultural practices.
基金the National Natural Science Foundation of China(Grant No.U22A20171)the National Key Research and Development Program Project of China(2023YFB3709900)+1 种基金the China Baowu Low Carbon Metallurgical Innovation Fund(BWLCF202315)the Pangang-USTB Vanadium and Titanium Research Institute Research Project,the High Steel Center(HSC)at North China University of Technology,Yanshan University and University of Science and Technology Beijing,China.
文摘Model calculations and laboratory experiments were conducted to investigate the influence of surface tension of the molten steel on the agglomeration trend of Al_(2)O_(3) inclusions.The agglomeration trends of inclusions were compared using the calculated attractiveness.When the S content in the steel increased from 2.7×10^(-6) to 789×10^(-6),the surface tension of the molten steel decreased from 1.91 to 1.39 N/m,while the attractive force between inclusions increased from 5×10^(-18) to 5×10^(-16) N,and the critical collision distance of Al_(2)O_(3) inclusions gradually increased from 30 to 70μm.A model of the relationship between the capillary force of inclusions and S content in steel was established.It was found that the capillary force calculated by the model showed the same trend as the attractive force obtained from experiments,and an increase in the S content promoted the attraction between inclusions.
基金support by the National Natural Science Foundation of China(Grant Nos.U23A20546 and 52271010)the Chinese National Natural Science Fund for Distinguished Young Scholars(Grant No.52025015)the Natural Science Foundation of Tianjin City(No.21JCZDJC00510).
文摘1.Introduction The strength-ductility trade-offdilemma has long been a per-sistent challenge in Al matrix composites(AMCs)[1,2].This is-sue primarily arises from the agglomeration of reinforcements at the grain boundaries(GBs),which restricts local plastic flow dur-ing the plastic deformation and leads to stress concentration[3,4].Recently,the development of concepts aimed at achieving hetero-geneous grain has emerged as a promising approach for enhanc-ing comprehensive mechanical properties[5,6].
基金supported by the National Natural Science Foundation of China(Nos.U2241250 and U2441284)。
文摘AP(Ammonium Perchlorate)and HMX(Octogen)are the two oxidizers most often used in Nitrate-Ester-Plasticized Polyether(NEPE)rocket propellants.How the AP–HMX ratio influences the agglomeration of NEPE propellants remains unclear.We experimentally investigated the effect of the AP–HMX ratio on the combustion and agglomeration of NEPE propellants using burning rate test,quenched surface analysis,microscopic observations,and the collection of condensed combustion products.It was found that with the decrease in AP content from 40wt%to 10wt%,the burning rate decreased from 14.2 mm/s to 9.2 mm/s because the adiabatic flame temperature of NEPE propellants decreased from 3828 K to 3736 K.Pockets bounded by AP particles appeared on the surface when AP content was 40wt%;however,the accumulations grew and covered the burning surface eventually as the AP–HMX ratio decreased.The time required for the accumulation to coalesce into agglomerates increased with decreasing AP content.Even with similar agglomerate sizes,the coalescence time increased by 83%when the AP content decreased from 40wt%to 30wt%.The agglomerate size in the Condensed Combustion Products(CCPs)increased from 100μm to 200μm,and the fraction of large agglomerations increased from 6.4%to 24.7%when the AP content decreased from 40wt%to 10wt%.Overall,the high flame temperature of the AP particles enhanced the decomposition of the surrounding binder,resulting in the rapid ejection of the aluminum particles into the gas,which had a separating effect on the accumulation,thus weakening the agglomeration.
基金support of Postdoctoral Fellowship Program of CPSF(GZC20230393)Natural Science Foundation of Liaoning Province in China(2023-BSBA-112)Fundamental Research Funds for the Central Universities(N2425032).
文摘The formation of large-sized inclusions cluster severely impacts the continuous casting process and product quality of titanium-containing steel.Thermodynamic calculations were initially conducted to predict the formation of various complex oxide inclusions,namely Al_(2)O_(3),TiO_(x)and Al-Ti-O.Based on that,laboratory-scale experiments were designed to prepare samples with a single type of inclusions.Then,the scanning electron microscope-energy dispersive spectrometer was used for quantitative characterization.Subsequently,the agglomeration behavior of inclusions in Fe-Al-Ti-O melt was observed in situ by high-temperature confocal laser scanning microscopy.Furthermore,a quantitative analysis of the agglomeration characteristics of the various inclusions was conducted based on the attractive forces in accordance with Newton's second law and the capillary forces as described by the Kralchevsky-Paunov model.The results indicate that the size of Al_(2)O_(3)inclusions is larger than that of TiO_(x)and Al-Ti-O,but the number density of TiO_(x)is the highest.Based on the in situ observation and the theoretical calculation,Al_(2)O_(3),TiO_(x)and Al-Ti-O inclusions can all agglomerate into large-sized clusters without segregation,but the agglomeration tendency of Al_(2)O_(3)and TiO_(x)is stronger than that of Al-Ti-O.The attractive force between Al_(2)O_(3)inclusions’pair is the largest,ranging from 2.26×10^(-15)to 6.12×10^(-14)N,followed by TiO_(x)(7.13×10^(-16)to 3.56×10^(-14)N)and Al-Ti-O(1.16×10^(-17)to 3.77×10^(-16)N).
