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Achieving colossal anisotropic thermal expansion via synergism of spin crossover and rhombus deformation
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作者 Shuai Liang Wen-Jing Jiang Ji-Xiang Hu 《Chinese Journal of Structural Chemistry》 2025年第2期5-6,共2页
Transducing thermal energy into mechanical movements via molecular reconfigurations offers a cutting-edge approach to thermal actuating materials,which could be applied to sensors,energy harvesting and storage devices... Transducing thermal energy into mechanical movements via molecular reconfigurations offers a cutting-edge approach to thermal actuating materials,which could be applied to sensors,energy harvesting and storage devices[1].Thermal expansion is a pivotal aspect in solid state chemistry,intricately intertwined with various factors such as crystal structure,chemical composition,electronic configuration,microstructure,and defects.Most materials undergo isotropic and positive thermal expansion(PTE)because of the disharmonic vibrational amplitudes of their chemical bonds.Moreover,anisotropic thermal expansion(ATE)and negative thermal expansion(NTE)are fascinating physical attributes of solids,which can originate from electronic or magnetic mechanisms,as well as through a transverse phonon mechanism in insulating lattice solids. 展开更多
关键词 transducing thermal energy Thermal actuating materials Spin crossover Rhombus deformation isotropic positive thermal expansion pte solid state chemistryintricately molecular reconfigurations crystal structurechemical
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Characterization and Microstructure of PLZT RAINBOW Ceramics 被引量:8
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作者 沈星 袁慎芳 陈勇 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2004年第2期124-128,共5页
A new type of large-displacement actuating materials called RAINBOW (Reduced and Internally Biased Oxide Wafer) ceramics is fabricated by a chemical reduction of PLZT piezoelectric ceramics. It is found that PLZT is e... A new type of large-displacement actuating materials called RAINBOW (Reduced and Internally Biased Oxide Wafer) ceramics is fabricated by a chemical reduction of PLZT piezoelectric ceramics. It is found that PLZT is easily reduced and the thickness of reduced layer has a linear relationship with the reduction time. The optimal conditions for producing RAINBOW samples from PLZT are determined to be 950℃ for 1-1.5 hours. SEM micrograph shows that the RAINBOW ceramics are composed of reduced and unreduced layer obviously. And the reduced layer is transgranularly fractured while the unreduced ceramic is intergranularly fractured. Metallic lead and refractor oxides (PbO, ZrO_2, ZrTiO_4, etc.) are found in the reduced layer by XRD analyses, however, the crystal structure of PLZT is not found. The analysis of the reduction mechanism is in good accordance with experimental data. 展开更多
关键词 actuating material RAINBOW chemical reduction piezoelectric ceramic reduction mechanism
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Preparation and Structure of Rainbow Piezoelectric Ceramics 被引量:1
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作者 沈星 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2003年第4期24-26,共3页
Rainbow piezoelectric ceramics are a new type of stress-biased,oxide-reduced composite ferroelectric ceramics,which have a special dome structure.The have shown excellent properties such as ultra-high displacement und... Rainbow piezoelectric ceramics are a new type of stress-biased,oxide-reduced composite ferroelectric ceramics,which have a special dome structure.The have shown excellent properties such as ultra-high displacement under an applied electric field and enhanced load-bearing capability.In this article,their manufacture,structures and properties were discussed in detail by combining experiments and theory analysis.The resuts show that the optimal conditions for producing Rainbow samples from PLZT ceramics were determined to be 900℃ for 1 to 1.5 hours.A number of different phases have been found in the reduced layer of Rainbow ceramics by XRD analyses.The phases found include metallic lead and other oxide phases,such as PbO,ZrO 2 and TiO 2.The original PLZT phase was not observed.The reduced layer was transgranularly fractured while the unreduced ceramic was intergranularly fractured.Two kinds of fracture types can be seen at the interface,which denotes the different degrees of reduction.It is shown that the Pb grains (about 0.2μm) constitute a continuous phase in the reduced layer,which accounts for the good electrical conductivity. 展开更多
关键词 RAINBOW piezoelectric ceramic stress-biased actuating materials
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The emerging technology of biohybrid micro-robots:a review 被引量:3
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作者 Zening Lin Tao Jiang Jianzhong Shang 《Bio-Design and Manufacturing》 SCIE EI CAS CSCD 2022年第1期107-132,共26页
In the past few decades,robotics research has witnessed an increasingly high interest in miniaturized,intelligent,and integrated robots.The imperative component of a robot is the actuator that determines its performan... In the past few decades,robotics research has witnessed an increasingly high interest in miniaturized,intelligent,and integrated robots.The imperative component of a robot is the actuator that determines its performance.Although traditional rigid drives such as motors and gas engines have shown great prevalence in most macroscale circumstances,the reduction of these drives to the millimeter or even lower scale results in a significant increase in manufacturing difficulty accompanied by a remarkable performance decline.Biohybrid robots driven by living cells can be a potential solution to overcome these drawbacks by benefiting from the intrinsic microscale self-assembly of living tissues and high energy efficiency,which,among other unprecedented properties,also feature flexibility,self-repair,and even multiple degrees of freedom.This paper systematically reviews the development of biohybrid robots.First,the development of biological flexible drivers is introduced while emphasizing on their advantages over traditional drivers.Second,up-to-date works regarding biohybrid robots are reviewed in detail from three aspects:biological driving sources,actuator materials,and structures with associated control methodologies.Finally,the potential future applications and major challenges of biohybrid robots are explored. 展开更多
关键词 Biohybrid robots Living cells Actuator materials Structure Control methodologies
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An analytical model for electrode-ceramic interaction in multilayer piezoelectric actuators
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作者 B.L.Wang J.C.Han 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2007年第2期199-208,共10页
The present paper develops an analytical model for multi-electrodes in multi-layered piezoelectric actuators, in which the electrodes are vertical to and terminated at the edges of the medium and electroelastic field ... The present paper develops an analytical model for multi-electrodes in multi-layered piezoelectric actuators, in which the electrodes are vertical to and terminated at the edges of the medium and electroelastic field concentrations ahead of the electrodes in the multilayer piezoelectric actuators are examined. By considering a representative unit in realistic multilayers, the problem is formulated in terms of electric potential between the electrode tips and results in a system of singular integral equations in which the electric potential is taken as unknown function. Effects are investigated of electrode spacing and piezoelectric coupling on the singular electroelastic fields at the electrode tips, and closed-form expressions are given for the electromechanical field near the electrode tips. Exact solution for un-coupled dielectrics is provided, where no piezoelectric coupling is present. 展开更多
关键词 Actuators . Piezoelectric materials . Electrodes. Multilayer. Fracture mechanics
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Advanced Design of Fibrous Flexible Actuators for Smart Wearable Applications 被引量:5
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作者 Cuiqin Fang Bingang Xu +3 位作者 Meiqi Li Jing Han Yujue Yang Xinlong Liu 《Advanced Fiber Materials》 SCIE EI CAS 2024年第3期622-657,共36页
Smart wearables equipped with integrated flexible actuators possess the ability to autonomously respond and adapt to changes in the environment.Fibrous textiles have been recognised as promising platforms for integrat... Smart wearables equipped with integrated flexible actuators possess the ability to autonomously respond and adapt to changes in the environment.Fibrous textiles have been recognised as promising platforms for integrating flexible actuators and wearables owing to their superior body compliance,lightweight nature,and programmable architectures.Various studies related to textile actuators in smart wearables have been recently reported.However,the review focusing on the advanced design of these textile actuator technologies for smart wearables is lacking.Herein,a timely and thorough review of the progress achieved in this field over the past five years is presented.This review focuses on the advanced design concepts for textile actuators in smart wearables,covering functional materials,innovative architecture configurations,external stimuli,and their applications in smart wearables.The primary aspects focus on actuating materials,formation techniques of textile architecture,actuating behaviour and performance metrics of textile actuators,various applications in smart wearables,and the design challenges for next-generation smart wearables.Ultimately,conclusive perspectives are highlighted. 展开更多
关键词 Flexible textile actuators Advanced design Smart wearables actuating behaviours actuating materials
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