Based on the historical documents and measured data from the active-layer temperature （ALT） at A, B and C locations （4 670, 4 720 and 4 770 m a.s.l.） on Baishui Glacier No. 1, southeastern Tibetan Plateau, this pa...Based on the historical documents and measured data from the active-layer temperature （ALT） at A, B and C locations （4 670, 4 720 and 4 770 m a.s.l.） on Baishui Glacier No. 1, southeastern Tibetan Plateau, this paper analyzed spatial-temporal characteristics of ALT and its relationship with air temperature, and revealed the response of the active layer ice temperature towards climate change in the monitoring period. The results showed that the influence of air temperature on the active-layer ice temperature had a hysteresis characteristic on the upper of ablation zone and the lag period in- creased gradually with the altitude elevating. The decrease amplitude of ALT in the accumulation pe- riod was far below its increase magnitude in the ablation period. At the same time, the mean glacier ice temperatures at 10 m depth （T10） in A, B and C profile were obviously higher than most of glaciers previously studied. Measured data also showed that the mean ALT increased by 0.24℃ in 0.5-8.5 m depth of the C profile during 28 years from July 11, 1982 to July 10, 2009.展开更多
The power conversion efficiency(PCE)of polymer solar cells(PSCs)has recently increased quickly,propelling PSCs closer to large-scale commercialization.However,several critical issues,such as the cost of materials and ...The power conversion efficiency(PCE)of polymer solar cells(PSCs)has recently increased quickly,propelling PSCs closer to large-scale commercialization.However,several critical issues,such as the cost of materials and the sensitivity of the PCE to active-layer thickness,must be addressed before industrial application can be realized on a large scale.Here,we fabricated a high-performance ternary PSC based on a low-cost polymer donor PTQ10 and an A-DA’D-A-type small molecule acceptor(SMA)2,2'-((2Z,2'Z)-((12,13-bis(2-butyloctyl)-3,9-bis(4-(2-ethylhexyl)thiophen-2-yl)-12,13-dihydro-[1,2,5]thiadiazolo[3,4-e]thieno[2'',3'':4',5']thieno[2',3':4,5]pyrrolo[3,2-g]thieno[2',3':4,5]thieno[3,2-b]indole-2,10-diyl)bis(methaneylylidene))bis(5,6-difluoro-3-oxo-2,3-dihydro-1H-indene-2,1-diylidene))dimalononitrile(m-TEH)with a newA-DA’D-A-type SMA 2,2'-((2Z,2'Z)-((12,13-bis(2-butyloctyl)-3,9-bis(3-(2-ethylhexyl)phenyl)-12,13-dihydro-[1,2,5]thiadiazolo[3,4-e]thieno[2'',3'':4',5']thieno[2',3':4,5]pyrrolo[3,2-g]thieno[2',3':4,5]thieno[3,2-b]indole-2,10-diyl)bis(methaneylylidene))bis(5,6-difluoro-3-oxo-2,3-dihydro-1H-indene-2,1-diylidene))dimalononitrile(m-PEH)(with phenyl outer side chains)as the third component.Benefitting from the good compatibility and the unique alignment of the energy levels between PTQ10 and the two SMAs,the ternary system showed favorable phase separation and dominant face-on orientation,exhibiting suitable film morphology and enhanced charge transport.Therefore,the optimized ternary PSCs based on PTQ10∶m-TEH∶m-PEH(1.0∶0.9∶0.3,w/w/w)demonstrated an outstanding PCE of 19.34%,which is one of the highest PCEs reported for the single junction PSCs to date.More importantly,the ternary PSCs demonstrated superior tolerance to the active-layer thickness and showed a high PCE of 18.02% with a high fill factor(FF)of 76.56% for the devices with the active-layer thickness even reaching 300 nm.These results indicate that the ternary devices based on PTQ10∶m-TEH∶m-PEH are highly promising for future large-area fabrication and commercial application of PSCs.展开更多
Semitransparent organic photovoltaics(ST-OPVs),as a novel green energy acquisition technology,are one of the most promising applications in organic photovoltaics.Because of its intrinsic transmittance originated from ...Semitransparent organic photovoltaics(ST-OPVs),as a novel green energy acquisition technology,are one of the most promising applications in organic photovoltaics.Because of its intrinsic transmittance originated from ad-justable absorption,light weight and flexibility,ST-OPVs,compared with other inorganic photovoltaics,show unique potential in wearable devices,self-powered greenhouse roofs and building integrated photovoltaics.To further promote the practicality and industrialization of ST-OPVs,the light utili-zation efficiency is still the focus of research.Hence,the recent progress of ST-OPVs is reviewed from the theoretical models,transparent top electrodes,the optical modification and se-lection of active layer materials.We hope that this paper will provide valuable guidelines for the ST-OPV research.展开更多
基金funded by the National Basic Research Program of China (No. 2013CBA01808)the National Natural Science Foundation of China (No. 41273010)the China Postdoctoral Science Foundation (No. 2013M530436)
文摘Based on the historical documents and measured data from the active-layer temperature （ALT） at A, B and C locations （4 670, 4 720 and 4 770 m a.s.l.） on Baishui Glacier No. 1, southeastern Tibetan Plateau, this paper analyzed spatial-temporal characteristics of ALT and its relationship with air temperature, and revealed the response of the active layer ice temperature towards climate change in the monitoring period. The results showed that the influence of air temperature on the active-layer ice temperature had a hysteresis characteristic on the upper of ablation zone and the lag period in- creased gradually with the altitude elevating. The decrease amplitude of ALT in the accumulation pe- riod was far below its increase magnitude in the ablation period. At the same time, the mean glacier ice temperatures at 10 m depth （T10） in A, B and C profile were obviously higher than most of glaciers previously studied. Measured data also showed that the mean ALT increased by 0.24℃ in 0.5-8.5 m depth of the C profile during 28 years from July 11, 1982 to July 10, 2009.
基金funded by the National Key Research and Development Program of China(grant no.2019YFA0705900)by Ministry Of Science and Technology(MOST)the National Natural Science Foundation of China(grant nos.51820105003,61904181,52173188,52103243,and 52203248)the Basic and Applied Basic Research Major Program of Guangdong Province(grant no.2019B030302007).
文摘The power conversion efficiency(PCE)of polymer solar cells(PSCs)has recently increased quickly,propelling PSCs closer to large-scale commercialization.However,several critical issues,such as the cost of materials and the sensitivity of the PCE to active-layer thickness,must be addressed before industrial application can be realized on a large scale.Here,we fabricated a high-performance ternary PSC based on a low-cost polymer donor PTQ10 and an A-DA’D-A-type small molecule acceptor(SMA)2,2'-((2Z,2'Z)-((12,13-bis(2-butyloctyl)-3,9-bis(4-(2-ethylhexyl)thiophen-2-yl)-12,13-dihydro-[1,2,5]thiadiazolo[3,4-e]thieno[2'',3'':4',5']thieno[2',3':4,5]pyrrolo[3,2-g]thieno[2',3':4,5]thieno[3,2-b]indole-2,10-diyl)bis(methaneylylidene))bis(5,6-difluoro-3-oxo-2,3-dihydro-1H-indene-2,1-diylidene))dimalononitrile(m-TEH)with a newA-DA’D-A-type SMA 2,2'-((2Z,2'Z)-((12,13-bis(2-butyloctyl)-3,9-bis(3-(2-ethylhexyl)phenyl)-12,13-dihydro-[1,2,5]thiadiazolo[3,4-e]thieno[2'',3'':4',5']thieno[2',3':4,5]pyrrolo[3,2-g]thieno[2',3':4,5]thieno[3,2-b]indole-2,10-diyl)bis(methaneylylidene))bis(5,6-difluoro-3-oxo-2,3-dihydro-1H-indene-2,1-diylidene))dimalononitrile(m-PEH)(with phenyl outer side chains)as the third component.Benefitting from the good compatibility and the unique alignment of the energy levels between PTQ10 and the two SMAs,the ternary system showed favorable phase separation and dominant face-on orientation,exhibiting suitable film morphology and enhanced charge transport.Therefore,the optimized ternary PSCs based on PTQ10∶m-TEH∶m-PEH(1.0∶0.9∶0.3,w/w/w)demonstrated an outstanding PCE of 19.34%,which is one of the highest PCEs reported for the single junction PSCs to date.More importantly,the ternary PSCs demonstrated superior tolerance to the active-layer thickness and showed a high PCE of 18.02% with a high fill factor(FF)of 76.56% for the devices with the active-layer thickness even reaching 300 nm.These results indicate that the ternary devices based on PTQ10∶m-TEH∶m-PEH are highly promising for future large-area fabrication and commercial application of PSCs.
基金supported by the Beijing Natural Science Foundation (Z230019)the National Key R&D Program of China (2019YFA0705900)+2 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB0520202)the International Partnership Program of the Chinese Academy of Sciences (027GJHZ2022036GC)the National Natural Science Foundation of China (52225305 and 22175187)。
文摘Semitransparent organic photovoltaics(ST-OPVs),as a novel green energy acquisition technology,are one of the most promising applications in organic photovoltaics.Because of its intrinsic transmittance originated from ad-justable absorption,light weight and flexibility,ST-OPVs,compared with other inorganic photovoltaics,show unique potential in wearable devices,self-powered greenhouse roofs and building integrated photovoltaics.To further promote the practicality and industrialization of ST-OPVs,the light utili-zation efficiency is still the focus of research.Hence,the recent progress of ST-OPVs is reviewed from the theoretical models,transparent top electrodes,the optical modification and se-lection of active layer materials.We hope that this paper will provide valuable guidelines for the ST-OPV research.
