A family of exceptionally thermally stable[Ni_(8)]cages is reported,each being templated by a rareη^(3):η^(3):μ_(6)-O_(2)^(2-)species produced by dioxygen activation,where the reducing agent for the O_(2)reduction ...A family of exceptionally thermally stable[Ni_(8)]cages is reported,each being templated by a rareη^(3):η^(3):μ_(6)-O_(2)^(2-)species produced by dioxygen activation,where the reducing agent for the O_(2)reduction appears to be the ligand used in the reaction mixtures,which was found within the nickel cages in its oxidized form.展开更多
文摘A family of exceptionally thermally stable[Ni_(8)]cages is reported,each being templated by a rareη^(3):η^(3):μ_(6)-O_(2)^(2-)species produced by dioxygen activation,where the reducing agent for the O_(2)reduction appears to be the ligand used in the reaction mixtures,which was found within the nickel cages in its oxidized form.
