Proton exchange membrane fuel cells(PEMFCs)have been widely acknowledged as a significant advancement in achieving sustainable energy conversion.However,the activation of newly established Pt-ionomer interfaces in the...Proton exchange membrane fuel cells(PEMFCs)have been widely acknowledged as a significant advancement in achieving sustainable energy conversion.However,the activation of newly established Pt-ionomer interfaces in the catalyst layer of PEMFCs can be a time-consuming and costly process to ensure proper coupling and performance.In order to gain valuable insights into this crucial activation process,we have conducted a comprehensive analysis and comparison of the commonly employed on-line(such as current or voltage control activation,short-circuiting activation,and air interruption activation)and off-line(including boiling or steaming,acidtreatment,and ultrasonic-treatment)activation methods.Our findings shed light on the underlying mechanisms that contribute to enhanced performance within the catalyst layer,such as the reduction of Pt oxides and hydroxides,improved proton transport,and the reduction of“dead”regions.Moreover,this review emphasizes the significant challenges and future opportunities that lie in further enhancing the performance within the catalyst layer through the activation process.展开更多
In 2025,I had the honor of delivering keynote speeches at the conferences of the International Society for Diet and Activity Methods in Toronto,Canada,and the International Society of Behavioural Nutrition and Physica...In 2025,I had the honor of delivering keynote speeches at the conferences of the International Society for Diet and Activity Methods in Toronto,Canada,and the International Society of Behavioural Nutrition and Physical Activity in Auckland,Aotearoa,New Zealand.These opportunities prompted deep reflection on scientific research in general,and on physical activity and health research specifically.展开更多
According to the chemical and mineral composition characteristics of the fly ash,alumina can be extracted from fly ash through the calcining method by using sodium carbonate and calcium carbonate additives.The effects...According to the chemical and mineral composition characteristics of the fly ash,alumina can be extracted from fly ash through the calcining method by using sodium carbonate and calcium carbonate additives.The effects on leaching rate of alumina have been investigated. The results showed that the fly ash can be activated effectively and the leaching rate of alumina can be improved to more than 92% through this method. The best process parameters were the ratio of raw materials,i. e. the material weight ratio of fly ash,calcium carbonate and sodium carbonate was 1. 0∶1. 2∶0. 9. The activating temperature was 850℃-900℃,activating time was 3 h. This process has a potential application prospect and improves the value of comprehensive utilization of fly ash.展开更多
For nonlinear stability problems of discretized conservative systems with multiple parameter variables and multiple state variables, the activation method is put forward, by which activated potential functions and act...For nonlinear stability problems of discretized conservative systems with multiple parameter variables and multiple state variables, the activation method is put forward, by which activated potential functions and activated equilibrium equations are derived. The activation method is the improvement and enhancement of Liapunov-Schmidt method in elastic stability theory. It is more generalized and more normalized than conventional perturbation methods. The activated potential functions may be transformed into normalized catastrophe potential functions. The activated equilibrium equations may be treated as bifurcation equations. The researches in this paper will motivate the combination of elastic stability theory with catastrophe theory and bifurcation theory展开更多
This paper aims to establish a comparison between both geomagnetic activity classification methods on foF2 diurnal variation over solar cycle phases. It concerns first a comparison of geomagnetic activity occurrences ...This paper aims to establish a comparison between both geomagnetic activity classification methods on foF2 diurnal variation over solar cycle phases. It concerns first a comparison of geomagnetic activity occurrences according to both classification methods;and second the geomagnetic effect on foF2 diurnal variation profiles as defined for the equatorial latitudes. The occurrences of the different disturbed geomagnetic activities (recurrent activity (RA), shock activity (SA) and fluctuant activity (FA)) according to both classifications (ancient classification (AC) and new classification (NC)) have been studied at Dakar ionosonde station (Lat: 14.8°N;Long: 342.6°E). Regarding both classifications, the RA occurs more during the decreasing phase. And it’s observed that the RA occurs the most during the increasing phase for the AC and during the minimum phase for the NC. The maximum gap of occurrence (<img src="Edit_e4627ea9-9a9a-4473-9017-202d04a16377.bmp" alt="" /><span><span style="font-family:Verdana;">) between both classifications is <span style="font-size:10.0pt;font-family:;" "=""><span style="font-family:Verdana, Helvetica, Arial;white-space:normal;background-color:#FFFFFF;">-</span></span></span><span style="font-family:;" "=""><span style="font-family:Verdana;">11.1%</span><span style="font-family:Verdana;"> (for the negative value which is observed during the increasing phase) and </span><span style="font-family:Verdana;">+16.74%</span><span style="font-family:Verdana;"> (for the positive one which is observed during the decreasing phase). The occurrence of the SA in relation with both classifications is the lowest during the minimum phase and the maximum occurrence is observed during the maximum and decreasing phases, for the AC, with a value close to </span><span style="font-family:Verdana;">37%</span><span style="font-family:Verdana;"> and for the NC at the maximum phase with a percentage of </span><span style="font-family:Verdana;">54.47%</span><span><span style="font-family:Verdana;">. The maximum gap of occurrence (</span><img src="Edit_20fa141b-ecee-4e06-8024-144ba0969395.bmp" alt="" /></span></span><span style="font-family:Verdana;">) between both classifications is <span style="font-size:10.0pt;font-family:;" "=""><span style="font-family:Verdana, Helvetica, Arial;white-space:normal;background-color:#FFFFFF;">-</span></span></span><span style="font-family:;" "=""><span style="font-family:Verdana;">17.85%</span><span style="font-family:Verdana;"> (for the negative value which is observed at maximum phase) and </span><span style="font-family:Verdana;">+13.53%</span><span style="font-family:Verdana;"> (for the positive one which is observed during the decreasing phase). For both classifications, the FA occurs the least during the minimum phase and the most during the maximum phase for the AC and at maximum and decreasing phases with percentage values of occurrence of roughly </span><span style="font-family:Verdana;">37%</span><span><span style="font-family:Verdana;"> for the NC. The maximum gap of occurrence (</span><img src="Edit_eecb8939-783e-4d43-b92c-80c528c1890b.bmp" alt="" /><span style="font-family:Verdana;"></span></span></span><span style="font-family:Verdana;">) between both classifications is <span style="font-size:10.0pt;font-family:;" "=""><span style="font-family:Verdana, Helvetica, Arial;white-space:normal;background-color:#FFFFFF;">-</span></span>10% (for the negative value which is observed during the decreasing phase) and </span><span style="font-family:;" "=""><span style="font-family:Verdana;">+20.11%</span><span style="font-family:Verdana;"> (for the positive one which is observed during the maximum phase). foF2 diurnal profiles throughout solar cycle phases concerning the AC and the NC have been compared. The FA diurnal profiles don’t present a difference. The RA and the SA present a difference during minimum and increasing phases and the least at maximum and decreasing phases.</span></span></span>展开更多
Prompt gamma neutron activation analysis (PGNAA) is a non-destructive online measurement nuclear analysis method. With its unique advantages, it has been widely used in online analysis of industrial materials such as ...Prompt gamma neutron activation analysis (PGNAA) is a non-destructive online measurement nuclear analysis method. With its unique advantages, it has been widely used in online analysis of industrial materials such as coal, cement, and minerals in recent years. </span><span style="font-family:Verdana;">However, there are many kinds of literature on PGNAA in the field of industrial materials detection, and there are still a few concluding articles. To this end,</span><span style="font-family:Verdana;"> based on the principle of PGNAA online analysis, the status quo and development of the real-time online detection of industrial material components in the field are reviewed and discussed by consulting a large number of domestic and foreign PGNAA related literature and data, to facilitate the reference of relevant scientific researchers.展开更多
Cyber-physical systems(CPSs)are regarded as the backbone of the fourth industrial revolution,in which communication,physical processes,and computer technology are integrated.In modern industrial systems,CPSs are widel...Cyber-physical systems(CPSs)are regarded as the backbone of the fourth industrial revolution,in which communication,physical processes,and computer technology are integrated.In modern industrial systems,CPSs are widely utilized across various domains,such as smart grids,smart healthcare systems,smart vehicles,and smart manufacturing,among others.Due to their unique spatial distribution,CPSs are highly vulnerable to cyber-attacks,which may result in severe performance degradation and even system instability.Consequently,the security concerns of CPSs have attracted significant attention in recent years.In this paper,a comprehensive survey on the security issues of CPSs under cyber-attacks is provided.Firstly,mathematical descriptions of various types of cyberattacks are introduced in detail.Secondly,two types of secure estimation and control processing schemes,including robust methods and active methods,are reviewed.Thirdly,research findings related to secure control and estimation problems for different types of CPSs are summarized.Finally,the survey is concluded by outlining the challenges and suggesting potential research directions for the future.展开更多
Natural gas hydrate(NGH)has a bright future as a clean energy source with huge reserves.Coring is one of the most direct methods for NGH exploration and research.Preserving the in-situ properties of the core as much a...Natural gas hydrate(NGH)has a bright future as a clean energy source with huge reserves.Coring is one of the most direct methods for NGH exploration and research.Preserving the in-situ properties of the core as much as possible during the coring process is crucial for the assessment of NGH resources.However,most existing NGH coring techniques cannot preserve the in-situ temperature of NGH,leading to distortion of the physical properties of the obtained core,which makes it difficult to effectively guide NGH exploration and development.To overcome this limitation,this study introduces an innovative active temperature-preserved coring method for NGH utilizing phase change materials(PCM).An active temperature-preserved corer(ATPC)is designed and developed,and an indoor experimental system is established to investigate the heat transfer during the coring process.Based on the experimental results under different environment temperatures,a heat transfer model for the entire ATPC coring process has been established.The indoor experimental results are consistent with the theoretical predictions of the heat transfer model,confirming its validity.This model has reconstructed the temperature changes of the NGH core during the coring process,demonstrating that compared to the traditional coring method with only passive temperature-preserved measures,ATPC can effectively reduce the core temperature by more than 5.25℃.With ATPC,at environment temperatures of 15,20,25,and 30℃,the duration of low-temperature state for the NGH core is 53.85,32.87,20.32,and 11.83 min,respectively.These findings provide new perspectives on temperature-preserving core sampling in NGH and provide technical support for exploration and development in NGH.展开更多
A series of photocatalysts of un-doped, single-doped and co-doped nanometer titanium diox- ide （TiO2） have been successfully prepared by template method using Fe（NO3）3.9H2O, La（NO3）3.6H2O, and tetrabutyl titanat...A series of photocatalysts of un-doped, single-doped and co-doped nanometer titanium diox- ide （TiO2） have been successfully prepared by template method using Fe（NO3）3.9H2O, La（NO3）3.6H2O, and tetrabutyl titanate as precursors and glucan as template. Scanning electron microscopy, X-ray diffraction, and N2 adsorption-desorption measurement were employed to characterize the morphology, crystal structure and surface structure of the samples. The photo-absorbance of the obtained catalysts was measured by UV-Vis absorption spectroscopy, and the photocatalytic activities of the prepared samples under UV and visible light were estimated by measuring the degradation rate of methyl orange in an aqueous solution. The characterizations indicated that the prepared photocatalysts consisted of anatase phase and possessed high surface area of ca. 163-176 m2/g. It was shown that the Fe and La co-doped nano-TiO2 could be activated by visible light and could thus be used as an effective catalyst in photo-oxidation reactions. The synergistic effect of Fe and La co-doping played an important role in improving the photocatalytic activity. In addition, the possibility of cyclic usage of co-doped nano-TiO2 was also confirmed, the photocatalytic activity of codoped nano-TiO2 remained above 89.6% of the fresh sample after being used four times.展开更多
The component synthesis active vibration suppression method （CSVS） can be applied to suppress the vibration of flexible systems. By this method, several same or similar time-varying components are arranged according...The component synthesis active vibration suppression method （CSVS） can be applied to suppress the vibration of flexible systems. By this method, several same or similar time-varying components are arranged according to certain rules along the time axis. The synthesized command can suppress the arbitrary unwanted vibration harmonic while achieving the desired rigid body motion. The number of the components increases rapidly when the number of harmonic vibration is growing. In this article, the CSVS based on zero-placement technique is used to construct the synthesized command to suppress the multi-harmonics simultaneously in the discrete domain. The nature of zero-placement method is to put enough zeros to cancel system poles at necessary points. The designed synthesized command has equal time intervals between each component and which is much easier to be implemented. Using this method, the number of components increases linearly with the increasing of the number of being suppressed harmonics. For the spacecraft with flexible appendages, CSVS based on zero-placement is used to design the time optimal large angle maneuver control strategy. Simulations have verified the validity and superiority of the proposed approach.展开更多
[Objective] This paper aims to study a new method of extracting pumpkin polysaccharide from pumpkin. Single factor experiments were conducted to examine the effects of extracting time,temperature,the solid-liquid rati...[Objective] This paper aims to study a new method of extracting pumpkin polysaccharide from pumpkin. Single factor experiments were conducted to examine the effects of extracting time,temperature,the solid-liquid ratio and pH value on the extraction yield of polysaccharide from pumpkin. [Method] The best enzyme ratio and extraction conditions for complex enzymes extraction were determined through orthogonal tests. Scavenging ·OH and O-2 activities of pumpkin polysaccharides were also investigated by salicylic acid and improved self-oxidation of o-pheno methods respectively. [Results] The results showed that the biggest extraction yield of polysaccharide from pumpkin can be got when adding 1% cellulose enzyme,1.5% pectinase,1.0% papain and Na2HPO4-citric acid buffer solution (pH was 4.6),and oscillating for 30 min under water at 40 ℃ with the solid-liquid ratio of 1:30. In addition,pumpkin polysaccharides had a strong activity of eliminating ·OH,but very weak activity to scavenge O-2. [Conclusion] This study provided basic data for research and application of Pumpkin polysaccharide.展开更多
In present paper,a study on reconstitution of porcine oocytes by using nuclear transfer with cumulus cells(CC) and fibroblast cells(FC) was carried out.Reconstituted oocytes which were the fusion with CC and showed a ...In present paper,a study on reconstitution of porcine oocytes by using nuclear transfer with cumulus cells(CC) and fibroblast cells(FC) was carried out.Reconstituted oocytes which were the fusion with CC and showed a cleavage rate of 56.7%,developed into morula (11.7%) and blastocysts (6.7%) phases which were higher than those derived from the fusion with FC( P <0.05).The results of this study also involved the effects of oocyte collection method,activation protocol and maturational age of recipient oocytes during the in vitro develpoment of nuclear transfer embryos which were reconstituted with cultured cumulus cells.The cumulus cells synchronized in G 0/G 1 phases through serum starvation culture,were transferred into enuclated oocytes which were collected by aspiration or dissection method and cultured for 33 or 44 h.Reconstituted embryos were activated with a combination of calcium ionophore A23187 or electric pulsation and 6 DMAP,and cultured for 6 days.As for the oocyte collection methods,activation treatment in the presence of cytochalasin B and activation protocols did not affect the developmental rate of embryos reconstituted with 44 h mature recipients.However,the development rate of reconstituted embryos with 33 h mature recipients were significantly higher( P <0.05) by activation with the combination of electric pulsation and 6 DMAP.These results suggest that the reconstituted porcine embryos derived from cultured cumulus cells can develop into the blastocyst stage and that the development of the former could be improved for the reconstitution with young oocyte cytoplast after the activation with the combination of electric pulsation and 6 DMAP.展开更多
With the quick development of the lithium industry,large amounts of solid waste of lithium slag are produced.Making high value-added products from lithium slag can not only alleviate environmental problems but also im...With the quick development of the lithium industry,large amounts of solid waste of lithium slag are produced.Making high value-added products from lithium slag can not only alleviate environmental problems but also improve resource utilization efficiency.However,the success of converting the lithium slag to valuable products is very limited.Herein,we reported a mild activation method for lithium slag and the synthesis of highly crystalline zeolite A with high sorption capacity(246.9 mg g^(−1)),fast sorption kinetics(reaching sorption equilibrium within 5 minutes),wide working pH(4–13)and excellent selectivity for the isotope of radioactive^(90)Sr from aqueous solution.The obtained zeolite A has a static water absorption capacity of 26.1 wt%,which is higher than the standard of the first-class grade of zeolite A in GB 6287-86,a Chinese national standard for commercial zeolite A.We also comprehensively investigated the evolution of the species during the activation of lithium slag,the crystallization field of zeolite A,the crystallization process of zeolite A under optimal conditions and the influence of various factors on the sorption of Sr^(2+)from aqueous solution.展开更多
A function projective synchronization of two identical hyperchaotic systems is defined and the theorem of sufficient condition is given. Based on the active control method and symbolic computation Maple, the scheme of...A function projective synchronization of two identical hyperchaotic systems is defined and the theorem of sufficient condition is given. Based on the active control method and symbolic computation Maple, the scheme of function projective synchronization is developed to synchronize the two identical new hyperchaotic systems constructed by Yan up to a scaling function matrix with different initial values. Numerical simulations are used to verify the effectiveness of the scheme.展开更多
PKS 2155-304 is a well studied BL Lac object in the southern sky. The historical optical data during different periods have been collected and compiled. Light curves spanning 35 yr have been constructed. The R-band li...PKS 2155-304 is a well studied BL Lac object in the southern sky. The historical optical data during different periods have been collected and compiled. Light curves spanning 35 yr have been constructed. The R-band light curve has been ana- lyzed by means of three methods： the epoch folding method, the Jurkevich method and the discrete correlation function method. It is derived that there is an evident periodic component of 317 d （i.e. 0.87 yr） superposed on a long-term trend with large- amplitude variation in the light curve. The variability of this source is accompanied by a slight color variation, and the brightness and color index are correlated with each other. On a long-term time scale, PKS 2155-304 exhibits a tendency of bluer-when- brighter, which means the spectrum becomes flatter when the source brightens.展开更多
A series of Ce, H3PW12O40 co-doped TiO2 hollow fibers photocatalysts have been prepared by sol-gel method using ammonium ceric nitrate, H3PW12O40 and tetrabutyltitanate as precursors and cotton fibers as template, fol...A series of Ce, H3PW12O40 co-doped TiO2 hollow fibers photocatalysts have been prepared by sol-gel method using ammonium ceric nitrate, H3PW12O40 and tetrabutyltitanate as precursors and cotton fibers as template, followed by calcination at 500 ℃ in N2 atmosphere for 2 h. Scanning electron microscopy, X-ray diffraction, nitrogen adsorption-desorption mea- surements, and UV-Vis spectroscopy are employed to characterize the morphology, crystal structure, surface structure, and optical absorption properties of the samples. The photo- catalytic performance of the samples has been studied by photodegradation phenol in water under UV and visible light irradiation. The results show that the TiO2 fiber materials have hollow structures, and the co-doped TiO2 hollow fibers exhibit higher photocatalytic activities for the degradation of phenol than un-doped, single-doped TiO2 hollow fibers under UV and visible light. In addition, the recyclability of co-doped TiO2 fibers is also confirmed that the TiO2 fiber retains ca. 90% of its activity after being used four times. It is shown that the co-doped TiO2 fibers can be activated by visible light and may be potentially applied to the treatment of water contaminated by organic pollutants. The synergistic effect of Ce and H3PW12O40 co-doping plays an important role in improving the photocatalytic activity.展开更多
Vertebrobasilar dolichoectasia(VBD),a rare posterior circulation vascular variant disease,is an important risk factor for many acute cerebrovascular diseases.An insufficient understanding of VBD often leads to misdiag...Vertebrobasilar dolichoectasia(VBD),a rare posterior circulation vascular variant disease,is an important risk factor for many acute cerebrovascular diseases.An insufficient understanding of VBD often leads to misdiagnose.Two cases of VBD that were initially diagnosed as posterior circulation watershed infarction are reported here.Absence of common causes of stroke including hypoperfusion,blood system diseases,carotid and aortic dissection,and eosinophil elevation,the symptoms of the 2 patients met the diagnostic criteria of VBD.Both patients displayed symptoms that were in line with the Traditional Chinese Medicine(TCM)syndrome pattern of"Qi deficiency and blood stasis".Accordingly,they were comprehensively treated with Supplementing Qi and activating blood circulation method.The clinical manifestations of the 2 patients were remarkably improved and no recurrence of watershed infarction was found in a 1-year follow-up.A detailed medical history and laboratory examination are capable of improving diagnostic accuracy of VBD.TCM treatment based on syndrome identification might be a promising candidate for VBD management.展开更多
Convolutional neural networks （CNNs） have been applied in state-of-the-art visual tracking tasks to represent the target. However, most existing algorithms treat visual tracking as an object-specific task. Therefore...Convolutional neural networks （CNNs） have been applied in state-of-the-art visual tracking tasks to represent the target. However, most existing algorithms treat visual tracking as an object-specific task. Therefore, the model needs to be retrained for different test video sequences. We propose a branch-activated multi-domain convolutional neural network （BAMDCNN）. In contrast to most existing trackers based on CNNs which require frequent online training, BAMDCNN only needs offine training and online fine-tuning. Specifically, BAMDCNN exploits category-specific features that are more robust against variations. To allow for learning category-specific information, we introduce a group algorithm and a branch activation method. Experimental results on challenging benchmark show that the proposed algorithm outperforms other state-of-the-art methods. What＇s more, compared with CNN based trackers, BAMDCNN increases tracking speed.展开更多
We investigate the wavelet transform of yearly mean relative sunspot number series from 1700 to 2002. The curve of the global wavelet power spectrum peaks at 11-yr, 53-yr and 101-yr periods. The evolution of the ampli...We investigate the wavelet transform of yearly mean relative sunspot number series from 1700 to 2002. The curve of the global wavelet power spectrum peaks at 11-yr, 53-yr and 101-yr periods. The evolution of the amplitudes of the three periods is studied. The results show that around 1750 and 1800, the amplitude of the 53-yr period was much higher than that of the the 11-yr period, that the ca. 53-yr period was apparent only for the interval from 1725 to 1850, and was very low after 1850, that around 1750, 1800 and 1900, the amplitude of the 101-yr period was higher than that of the 11-yr period and that, from 1940 to 2000, the 11-yr period greatly dominates over the other two periods.展开更多
To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut sh...To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut shell AC activated by nitric acid as the support and iron oxide as the active component.The crystal structure,surface morphology,pore structure,functional groups and valence states of the active components of Fe/AC catalysts were characterised by X-ray diffraction,scanning electron microscopy,nitrogen adsorption and desorption,Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy,respectively.The effect of Fe loading and calcination temperature on the low-temperature denitration of NH_(3)-SCR over Fe/AC catalysts was studied using NH_(3)as the reducing gas at low temperature(150℃).The results show that the iron oxide on the Fe/AC catalyst is spherical and uniformly dispersed on the surface of AC,thereby improving the crystallisation performance and increasing the number of active sites and specific surface area on AC in contact with the reaction gas.Hence,a rapid NH_(3)-SCR reaction was realised.When the roasting temperature remains constant,the iron oxide crystals formed by increasing the amount of loading can enter the AC pore structure and accumulate to form more micropores.When the roasting temperature is raised from 400 to 500℃,the iron oxide is mainly transformed fromα-Fe_(2)O_(3)toγ-Fe_(2)O_(3),which improves the iron oxide dispersion and increases its denitration active site,allowing gas adsorption.When the Fe loading amount is 10%,and the roasting temperature is 500℃,the NO removal rate of the Fe/AC catalyst can reach 95%.According to the study,the low-temperature NH_(3)-SCR mechanism of Fe/AC catalyst is proposed,in which the redox reaction between Fe~(2+)and Fe~(3+)will facilitate the formation of reactive oxygen vacancies,which increases the amount of oxygen adsorption on the surface,especially the increase in surface acid sites,and promotes and adsorbs more reaction gases(NH_(3),O_(2),NO).The transformation from the standard SCR reaction to the fast SCR reaction is accelerated.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.51802059,21905070,22075062)Shenzhen Science and Technology Program(JCYJ20210324120400002,and SGDX20210823103803017)+5 种基金Key Research and Development Program of Shandong Province(2022CXGC010305)Heilongjiang Postdoctoral Fund(LBH-Z18066)Heilongjiang Touyan Team(Grant No.HITTY-20190033)the Fundamental Research Funds for the Central Universities(Grant No.FRFCU5710051922)High-Level Professional Team in Shenzhen(Grant No.KQTD20210811090045006)Guangdong Basic and Applied Basic Research Foundation(2022B1515120001).
文摘Proton exchange membrane fuel cells(PEMFCs)have been widely acknowledged as a significant advancement in achieving sustainable energy conversion.However,the activation of newly established Pt-ionomer interfaces in the catalyst layer of PEMFCs can be a time-consuming and costly process to ensure proper coupling and performance.In order to gain valuable insights into this crucial activation process,we have conducted a comprehensive analysis and comparison of the commonly employed on-line(such as current or voltage control activation,short-circuiting activation,and air interruption activation)and off-line(including boiling or steaming,acidtreatment,and ultrasonic-treatment)activation methods.Our findings shed light on the underlying mechanisms that contribute to enhanced performance within the catalyst layer,such as the reduction of Pt oxides and hydroxides,improved proton transport,and the reduction of“dead”regions.Moreover,this review emphasizes the significant challenges and future opportunities that lie in further enhancing the performance within the catalyst layer through the activation process.
文摘In 2025,I had the honor of delivering keynote speeches at the conferences of the International Society for Diet and Activity Methods in Toronto,Canada,and the International Society of Behavioural Nutrition and Physical Activity in Auckland,Aotearoa,New Zealand.These opportunities prompted deep reflection on scientific research in general,and on physical activity and health research specifically.
文摘According to the chemical and mineral composition characteristics of the fly ash,alumina can be extracted from fly ash through the calcining method by using sodium carbonate and calcium carbonate additives.The effects on leaching rate of alumina have been investigated. The results showed that the fly ash can be activated effectively and the leaching rate of alumina can be improved to more than 92% through this method. The best process parameters were the ratio of raw materials,i. e. the material weight ratio of fly ash,calcium carbonate and sodium carbonate was 1. 0∶1. 2∶0. 9. The activating temperature was 850℃-900℃,activating time was 3 h. This process has a potential application prospect and improves the value of comprehensive utilization of fly ash.
基金Project supported by the National Natural Science Foundation and of the Ministry of Construction of China
文摘For nonlinear stability problems of discretized conservative systems with multiple parameter variables and multiple state variables, the activation method is put forward, by which activated potential functions and activated equilibrium equations are derived. The activation method is the improvement and enhancement of Liapunov-Schmidt method in elastic stability theory. It is more generalized and more normalized than conventional perturbation methods. The activated potential functions may be transformed into normalized catastrophe potential functions. The activated equilibrium equations may be treated as bifurcation equations. The researches in this paper will motivate the combination of elastic stability theory with catastrophe theory and bifurcation theory
文摘This paper aims to establish a comparison between both geomagnetic activity classification methods on foF2 diurnal variation over solar cycle phases. It concerns first a comparison of geomagnetic activity occurrences according to both classification methods;and second the geomagnetic effect on foF2 diurnal variation profiles as defined for the equatorial latitudes. The occurrences of the different disturbed geomagnetic activities (recurrent activity (RA), shock activity (SA) and fluctuant activity (FA)) according to both classifications (ancient classification (AC) and new classification (NC)) have been studied at Dakar ionosonde station (Lat: 14.8°N;Long: 342.6°E). Regarding both classifications, the RA occurs more during the decreasing phase. And it’s observed that the RA occurs the most during the increasing phase for the AC and during the minimum phase for the NC. The maximum gap of occurrence (<img src="Edit_e4627ea9-9a9a-4473-9017-202d04a16377.bmp" alt="" /><span><span style="font-family:Verdana;">) between both classifications is <span style="font-size:10.0pt;font-family:;" "=""><span style="font-family:Verdana, Helvetica, Arial;white-space:normal;background-color:#FFFFFF;">-</span></span></span><span style="font-family:;" "=""><span style="font-family:Verdana;">11.1%</span><span style="font-family:Verdana;"> (for the negative value which is observed during the increasing phase) and </span><span style="font-family:Verdana;">+16.74%</span><span style="font-family:Verdana;"> (for the positive one which is observed during the decreasing phase). The occurrence of the SA in relation with both classifications is the lowest during the minimum phase and the maximum occurrence is observed during the maximum and decreasing phases, for the AC, with a value close to </span><span style="font-family:Verdana;">37%</span><span style="font-family:Verdana;"> and for the NC at the maximum phase with a percentage of </span><span style="font-family:Verdana;">54.47%</span><span><span style="font-family:Verdana;">. The maximum gap of occurrence (</span><img src="Edit_20fa141b-ecee-4e06-8024-144ba0969395.bmp" alt="" /></span></span><span style="font-family:Verdana;">) between both classifications is <span style="font-size:10.0pt;font-family:;" "=""><span style="font-family:Verdana, Helvetica, Arial;white-space:normal;background-color:#FFFFFF;">-</span></span></span><span style="font-family:;" "=""><span style="font-family:Verdana;">17.85%</span><span style="font-family:Verdana;"> (for the negative value which is observed at maximum phase) and </span><span style="font-family:Verdana;">+13.53%</span><span style="font-family:Verdana;"> (for the positive one which is observed during the decreasing phase). For both classifications, the FA occurs the least during the minimum phase and the most during the maximum phase for the AC and at maximum and decreasing phases with percentage values of occurrence of roughly </span><span style="font-family:Verdana;">37%</span><span><span style="font-family:Verdana;"> for the NC. The maximum gap of occurrence (</span><img src="Edit_eecb8939-783e-4d43-b92c-80c528c1890b.bmp" alt="" /><span style="font-family:Verdana;"></span></span></span><span style="font-family:Verdana;">) between both classifications is <span style="font-size:10.0pt;font-family:;" "=""><span style="font-family:Verdana, Helvetica, Arial;white-space:normal;background-color:#FFFFFF;">-</span></span>10% (for the negative value which is observed during the decreasing phase) and </span><span style="font-family:;" "=""><span style="font-family:Verdana;">+20.11%</span><span style="font-family:Verdana;"> (for the positive one which is observed during the maximum phase). foF2 diurnal profiles throughout solar cycle phases concerning the AC and the NC have been compared. The FA diurnal profiles don’t present a difference. The RA and the SA present a difference during minimum and increasing phases and the least at maximum and decreasing phases.</span></span></span>
文摘Prompt gamma neutron activation analysis (PGNAA) is a non-destructive online measurement nuclear analysis method. With its unique advantages, it has been widely used in online analysis of industrial materials such as coal, cement, and minerals in recent years. </span><span style="font-family:Verdana;">However, there are many kinds of literature on PGNAA in the field of industrial materials detection, and there are still a few concluding articles. To this end,</span><span style="font-family:Verdana;"> based on the principle of PGNAA online analysis, the status quo and development of the real-time online detection of industrial material components in the field are reviewed and discussed by consulting a large number of domestic and foreign PGNAA related literature and data, to facilitate the reference of relevant scientific researchers.
文摘Cyber-physical systems(CPSs)are regarded as the backbone of the fourth industrial revolution,in which communication,physical processes,and computer technology are integrated.In modern industrial systems,CPSs are widely utilized across various domains,such as smart grids,smart healthcare systems,smart vehicles,and smart manufacturing,among others.Due to their unique spatial distribution,CPSs are highly vulnerable to cyber-attacks,which may result in severe performance degradation and even system instability.Consequently,the security concerns of CPSs have attracted significant attention in recent years.In this paper,a comprehensive survey on the security issues of CPSs under cyber-attacks is provided.Firstly,mathematical descriptions of various types of cyberattacks are introduced in detail.Secondly,two types of secure estimation and control processing schemes,including robust methods and active methods,are reviewed.Thirdly,research findings related to secure control and estimation problems for different types of CPSs are summarized.Finally,the survey is concluded by outlining the challenges and suggesting potential research directions for the future.
基金financially supported by Shenzhen Science and Technology Program(Nos.JSGG20220831105002005 and KJZD20231025152759002)the National Natural Science Foundation of China(Nos.52274133 and 523B2101).
文摘Natural gas hydrate(NGH)has a bright future as a clean energy source with huge reserves.Coring is one of the most direct methods for NGH exploration and research.Preserving the in-situ properties of the core as much as possible during the coring process is crucial for the assessment of NGH resources.However,most existing NGH coring techniques cannot preserve the in-situ temperature of NGH,leading to distortion of the physical properties of the obtained core,which makes it difficult to effectively guide NGH exploration and development.To overcome this limitation,this study introduces an innovative active temperature-preserved coring method for NGH utilizing phase change materials(PCM).An active temperature-preserved corer(ATPC)is designed and developed,and an indoor experimental system is established to investigate the heat transfer during the coring process.Based on the experimental results under different environment temperatures,a heat transfer model for the entire ATPC coring process has been established.The indoor experimental results are consistent with the theoretical predictions of the heat transfer model,confirming its validity.This model has reconstructed the temperature changes of the NGH core during the coring process,demonstrating that compared to the traditional coring method with only passive temperature-preserved measures,ATPC can effectively reduce the core temperature by more than 5.25℃.With ATPC,at environment temperatures of 15,20,25,and 30℃,the duration of low-temperature state for the NGH core is 53.85,32.87,20.32,and 11.83 min,respectively.These findings provide new perspectives on temperature-preserving core sampling in NGH and provide technical support for exploration and development in NGH.
文摘A series of photocatalysts of un-doped, single-doped and co-doped nanometer titanium diox- ide （TiO2） have been successfully prepared by template method using Fe（NO3）3.9H2O, La（NO3）3.6H2O, and tetrabutyl titanate as precursors and glucan as template. Scanning electron microscopy, X-ray diffraction, and N2 adsorption-desorption measurement were employed to characterize the morphology, crystal structure and surface structure of the samples. The photo-absorbance of the obtained catalysts was measured by UV-Vis absorption spectroscopy, and the photocatalytic activities of the prepared samples under UV and visible light were estimated by measuring the degradation rate of methyl orange in an aqueous solution. The characterizations indicated that the prepared photocatalysts consisted of anatase phase and possessed high surface area of ca. 163-176 m2/g. It was shown that the Fe and La co-doped nano-TiO2 could be activated by visible light and could thus be used as an effective catalyst in photo-oxidation reactions. The synergistic effect of Fe and La co-doping played an important role in improving the photocatalytic activity. In addition, the possibility of cyclic usage of co-doped nano-TiO2 was also confirmed, the photocatalytic activity of codoped nano-TiO2 remained above 89.6% of the fresh sample after being used four times.
文摘The component synthesis active vibration suppression method （CSVS） can be applied to suppress the vibration of flexible systems. By this method, several same or similar time-varying components are arranged according to certain rules along the time axis. The synthesized command can suppress the arbitrary unwanted vibration harmonic while achieving the desired rigid body motion. The number of the components increases rapidly when the number of harmonic vibration is growing. In this article, the CSVS based on zero-placement technique is used to construct the synthesized command to suppress the multi-harmonics simultaneously in the discrete domain. The nature of zero-placement method is to put enough zeros to cancel system poles at necessary points. The designed synthesized command has equal time intervals between each component and which is much easier to be implemented. Using this method, the number of components increases linearly with the increasing of the number of being suppressed harmonics. For the spacecraft with flexible appendages, CSVS based on zero-placement is used to design the time optimal large angle maneuver control strategy. Simulations have verified the validity and superiority of the proposed approach.
基金Supported by the Key Scientific and Technological Project of Henan Province (102102110157)the Scientific Research Found Project of Henan University of Urban Construction (2010JZD008)~~
文摘[Objective] This paper aims to study a new method of extracting pumpkin polysaccharide from pumpkin. Single factor experiments were conducted to examine the effects of extracting time,temperature,the solid-liquid ratio and pH value on the extraction yield of polysaccharide from pumpkin. [Method] The best enzyme ratio and extraction conditions for complex enzymes extraction were determined through orthogonal tests. Scavenging ·OH and O-2 activities of pumpkin polysaccharides were also investigated by salicylic acid and improved self-oxidation of o-pheno methods respectively. [Results] The results showed that the biggest extraction yield of polysaccharide from pumpkin can be got when adding 1% cellulose enzyme,1.5% pectinase,1.0% papain and Na2HPO4-citric acid buffer solution (pH was 4.6),and oscillating for 30 min under water at 40 ℃ with the solid-liquid ratio of 1:30. In addition,pumpkin polysaccharides had a strong activity of eliminating ·OH,but very weak activity to scavenge O-2. [Conclusion] This study provided basic data for research and application of Pumpkin polysaccharide.
文摘In present paper,a study on reconstitution of porcine oocytes by using nuclear transfer with cumulus cells(CC) and fibroblast cells(FC) was carried out.Reconstituted oocytes which were the fusion with CC and showed a cleavage rate of 56.7%,developed into morula (11.7%) and blastocysts (6.7%) phases which were higher than those derived from the fusion with FC( P <0.05).The results of this study also involved the effects of oocyte collection method,activation protocol and maturational age of recipient oocytes during the in vitro develpoment of nuclear transfer embryos which were reconstituted with cultured cumulus cells.The cumulus cells synchronized in G 0/G 1 phases through serum starvation culture,were transferred into enuclated oocytes which were collected by aspiration or dissection method and cultured for 33 or 44 h.Reconstituted embryos were activated with a combination of calcium ionophore A23187 or electric pulsation and 6 DMAP,and cultured for 6 days.As for the oocyte collection methods,activation treatment in the presence of cytochalasin B and activation protocols did not affect the developmental rate of embryos reconstituted with 44 h mature recipients.However,the development rate of reconstituted embryos with 33 h mature recipients were significantly higher( P <0.05) by activation with the combination of electric pulsation and 6 DMAP.These results suggest that the reconstituted porcine embryos derived from cultured cumulus cells can develop into the blastocyst stage and that the development of the former could be improved for the reconstitution with young oocyte cytoplast after the activation with the combination of electric pulsation and 6 DMAP.
基金the National Natural Science Foundation of China(U1967215,21835002,21621001,21875221)the“111”Project(B17020).
文摘With the quick development of the lithium industry,large amounts of solid waste of lithium slag are produced.Making high value-added products from lithium slag can not only alleviate environmental problems but also improve resource utilization efficiency.However,the success of converting the lithium slag to valuable products is very limited.Herein,we reported a mild activation method for lithium slag and the synthesis of highly crystalline zeolite A with high sorption capacity(246.9 mg g^(−1)),fast sorption kinetics(reaching sorption equilibrium within 5 minutes),wide working pH(4–13)and excellent selectivity for the isotope of radioactive^(90)Sr from aqueous solution.The obtained zeolite A has a static water absorption capacity of 26.1 wt%,which is higher than the standard of the first-class grade of zeolite A in GB 6287-86,a Chinese national standard for commercial zeolite A.We also comprehensively investigated the evolution of the species during the activation of lithium slag,the crystallization field of zeolite A,the crystallization process of zeolite A under optimal conditions and the influence of various factors on the sorption of Sr^(2+)from aqueous solution.
基金＊The project supported by the Natural Science Foundations of Zhejiang Province under Grant No. Y604056 and the Doctoral Foundation of Ningbo City under Grant No. 2005A61030
文摘A function projective synchronization of two identical hyperchaotic systems is defined and the theorem of sufficient condition is given. Based on the active control method and symbolic computation Maple, the scheme of function projective synchronization is developed to synchronize the two identical new hyperchaotic systems constructed by Yan up to a scaling function matrix with different initial values. Numerical simulations are used to verify the effectiveness of the scheme.
基金supported by the National Natural Science Foundation of China (Grant No.11273008)
文摘PKS 2155-304 is a well studied BL Lac object in the southern sky. The historical optical data during different periods have been collected and compiled. Light curves spanning 35 yr have been constructed. The R-band light curve has been ana- lyzed by means of three methods： the epoch folding method, the Jurkevich method and the discrete correlation function method. It is derived that there is an evident periodic component of 317 d （i.e. 0.87 yr） superposed on a long-term trend with large- amplitude variation in the light curve. The variability of this source is accompanied by a slight color variation, and the brightness and color index are correlated with each other. On a long-term time scale, PKS 2155-304 exhibits a tendency of bluer-when- brighter, which means the spectrum becomes flatter when the source brightens.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.41373127） and Liaon- ing Provincial Natural Science Foundation of China （No.2013020121）.
文摘A series of Ce, H3PW12O40 co-doped TiO2 hollow fibers photocatalysts have been prepared by sol-gel method using ammonium ceric nitrate, H3PW12O40 and tetrabutyltitanate as precursors and cotton fibers as template, followed by calcination at 500 ℃ in N2 atmosphere for 2 h. Scanning electron microscopy, X-ray diffraction, nitrogen adsorption-desorption mea- surements, and UV-Vis spectroscopy are employed to characterize the morphology, crystal structure, surface structure, and optical absorption properties of the samples. The photo- catalytic performance of the samples has been studied by photodegradation phenol in water under UV and visible light irradiation. The results show that the TiO2 fiber materials have hollow structures, and the co-doped TiO2 hollow fibers exhibit higher photocatalytic activities for the degradation of phenol than un-doped, single-doped TiO2 hollow fibers under UV and visible light. In addition, the recyclability of co-doped TiO2 fibers is also confirmed that the TiO2 fiber retains ca. 90% of its activity after being used four times. It is shown that the co-doped TiO2 fibers can be activated by visible light and may be potentially applied to the treatment of water contaminated by organic pollutants. The synergistic effect of Ce and H3PW12O40 co-doping plays an important role in improving the photocatalytic activity.
基金the 2019 Major Difficult Diseases Clinical Collaboration Capacity Building Project of Traditional Chinese and Western Medicine-cerebral Infarction(No.YW082)。
文摘Vertebrobasilar dolichoectasia(VBD),a rare posterior circulation vascular variant disease,is an important risk factor for many acute cerebrovascular diseases.An insufficient understanding of VBD often leads to misdiagnose.Two cases of VBD that were initially diagnosed as posterior circulation watershed infarction are reported here.Absence of common causes of stroke including hypoperfusion,blood system diseases,carotid and aortic dissection,and eosinophil elevation,the symptoms of the 2 patients met the diagnostic criteria of VBD.Both patients displayed symptoms that were in line with the Traditional Chinese Medicine(TCM)syndrome pattern of"Qi deficiency and blood stasis".Accordingly,they were comprehensively treated with Supplementing Qi and activating blood circulation method.The clinical manifestations of the 2 patients were remarkably improved and no recurrence of watershed infarction was found in a 1-year follow-up.A detailed medical history and laboratory examination are capable of improving diagnostic accuracy of VBD.TCM treatment based on syndrome identification might be a promising candidate for VBD management.
基金the Innovation Action Plan Foundation of Shanghai(No.16511101200)
文摘Convolutional neural networks （CNNs） have been applied in state-of-the-art visual tracking tasks to represent the target. However, most existing algorithms treat visual tracking as an object-specific task. Therefore, the model needs to be retrained for different test video sequences. We propose a branch-activated multi-domain convolutional neural network （BAMDCNN）. In contrast to most existing trackers based on CNNs which require frequent online training, BAMDCNN only needs offine training and online fine-tuning. Specifically, BAMDCNN exploits category-specific features that are more robust against variations. To allow for learning category-specific information, we introduce a group algorithm and a branch activation method. Experimental results on challenging benchmark show that the proposed algorithm outperforms other state-of-the-art methods. What＇s more, compared with CNN based trackers, BAMDCNN increases tracking speed.
基金Supported by the National Natural Science Foundation of China
文摘We investigate the wavelet transform of yearly mean relative sunspot number series from 1700 to 2002. The curve of the global wavelet power spectrum peaks at 11-yr, 53-yr and 101-yr periods. The evolution of the amplitudes of the three periods is studied. The results show that around 1750 and 1800, the amplitude of the 53-yr period was much higher than that of the the 11-yr period, that the ca. 53-yr period was apparent only for the interval from 1725 to 1850, and was very low after 1850, that around 1750, 1800 and 1900, the amplitude of the 101-yr period was higher than that of the 11-yr period and that, from 1940 to 2000, the 11-yr period greatly dominates over the other two periods.
基金Funded by the General Project of Science and Technology Plan of Yunnan Science and Technology Department(Nos.202001AT070029,2019FB077)Open Fund of Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education(No.FMRUlab-20-4)。
文摘To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut shell AC activated by nitric acid as the support and iron oxide as the active component.The crystal structure,surface morphology,pore structure,functional groups and valence states of the active components of Fe/AC catalysts were characterised by X-ray diffraction,scanning electron microscopy,nitrogen adsorption and desorption,Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy,respectively.The effect of Fe loading and calcination temperature on the low-temperature denitration of NH_(3)-SCR over Fe/AC catalysts was studied using NH_(3)as the reducing gas at low temperature(150℃).The results show that the iron oxide on the Fe/AC catalyst is spherical and uniformly dispersed on the surface of AC,thereby improving the crystallisation performance and increasing the number of active sites and specific surface area on AC in contact with the reaction gas.Hence,a rapid NH_(3)-SCR reaction was realised.When the roasting temperature remains constant,the iron oxide crystals formed by increasing the amount of loading can enter the AC pore structure and accumulate to form more micropores.When the roasting temperature is raised from 400 to 500℃,the iron oxide is mainly transformed fromα-Fe_(2)O_(3)toγ-Fe_(2)O_(3),which improves the iron oxide dispersion and increases its denitration active site,allowing gas adsorption.When the Fe loading amount is 10%,and the roasting temperature is 500℃,the NO removal rate of the Fe/AC catalyst can reach 95%.According to the study,the low-temperature NH_(3)-SCR mechanism of Fe/AC catalyst is proposed,in which the redox reaction between Fe~(2+)and Fe~(3+)will facilitate the formation of reactive oxygen vacancies,which increases the amount of oxygen adsorption on the surface,especially the increase in surface acid sites,and promotes and adsorbs more reaction gases(NH_(3),O_(2),NO).The transformation from the standard SCR reaction to the fast SCR reaction is accelerated.
