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Extraction and characterization of alumina nanopowders from aluminum dross by acid dissolution process 被引量:30
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作者 Saifur Rahman Sarker Zahangir Alam +2 位作者 Rakibul Qadir M A Gafur Mohammad Moniruzzaman 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2015年第4期429-436,共8页
A significant amount of aluminum dross is available as a waste in foundry industries in Bangladesh. In this study, alumina was ex- tracted from aluminum dross collected from two foundry industries situated in Dhamrai ... A significant amount of aluminum dross is available as a waste in foundry industries in Bangladesh. In this study, alumina was ex- tracted from aluminum dross collected from two foundry industries situated in Dhamrai and Manikgang, near the capital city, Dhaka. Alu- minum dross samples were found to approximately contain 75wt% A1203 and 12wt% SIO2. An acid dissolution process was used to recover the alumina value from the dross. The effects of various parameters, e.g., temperature, acid concentration, and leaching time, on the extrac- tion of alumina were studied to optimize the dissolution process. First, AI(OH)3 was produced in the form of a gel. Calcination of the AI(OH)3 gel at 1000℃, 1200℃, and 1400℃ for 2 h produced O-AlcOa, (t~+O)-A1203, and u-alumina powder, respectively. Thermal charac- terization of the AI(OH)3 gel was performed by thermogravimetric/differential thermal analysis (TG/DTA) and differential scanning calo- rimetry (DSC). The phases and crystallite size of the alumina were determined by X-ray diffraction analysis. The dimensions of the alumina were found to be on the nano level. The chemical compositions of the aluminum dross and alumina were determined by X-ray fluorescence (XRF) spectroscopy. The microstructure and morphology of the alumina were studied with scanning electron microscopy. The purity of the alumina extracted in this study was found to be 99.0%. Thus, it is expected that the obtained alumina powders can be potentially utilized as biomaterials. 展开更多
关键词 aluminum dross ALUMINA NANOPARTICLES acid dissolution CALCINATION X-ray fluorescence analysis
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Mechanisms of Pb(Ⅱ) coprecipitation with natrojarosite and its behavior during acid dissolution 被引量:1
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作者 Meiqing Shi Xiaobo Min +6 位作者 Chen Tian Taixu Hao Sijie Zhu Yun Ge Qingwei Wang Xu Yan Zhang Lin 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2022年第12期128-137,共10页
Lead(Pb) coprecipitation with jarosite is common in natural and engineered environments,such as acid mine drainage(AMD) sites and hydrometallurgical industry. Despite the high relevance for environmental impact, few s... Lead(Pb) coprecipitation with jarosite is common in natural and engineered environments,such as acid mine drainage(AMD) sites and hydrometallurgical industry. Despite the high relevance for environmental impact, few studies have examined the exact interaction of Pb with jarosite and the dissolution behavior of each phase. In the present work, we demonstrate that Pb mainly interacts with jarosite in four modes, namely incorporation, occlusion,physically mixing, and chemically mixing. For comparison, the four modes of Pb-bearing natrojarosite were synthesized and characterized separately. Batch dissolution experiments were undertaken on these synthetic Pb-bearing natrojarosites under pH_(2) to simulate the AMD environments. The introduction of Pb decreases the final Fe releasing efficiency of jarosite-type compounds from 18.18% to 3.45%-5.01%, showing a remarkable inhibition of their dissolution. For Pb releasing behavior, PbSO_(4) dissolves in preference to Pb-substituted natrojarosite, i.e.,(Na, Pb)-jarosite, which primarily results in the sharp increase of Pb releasing concentration(> 40 mg/L). PbSO_(4) occlusion by jarosite-type compounds can significantly reduce the release of Pb. The results of this study could provide useful information regarding Fe and Pb cycling in acidic natural and engineered environments. 展开更多
关键词 Pb-bearing natrojarosite Interaction mechanism acid dissolution Releasing behavior
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Dissolution behavior of Caldag lateritic nickel ore subjected to a sequential organic acid leaching method 被引量:3
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作者 Sait Kursunoglu Muammer Kaya 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2015年第11期1131-1140,共10页
The dissolution behavior of Caldag lateritic nickel ore subjected to a sequential organic acid leaching method was investigated. The effects of the type of organic acid, acid concentration, leaching time, and leaching... The dissolution behavior of Caldag lateritic nickel ore subjected to a sequential organic acid leaching method was investigated. The effects of the type of organic acid, acid concentration, leaching time, and leaching temperature on the lateritic nickel ore were examined. Organic acids were used individually prior to sequential leaching. Citric acid was more effective than the other two acids for the selective leaching of nickel and cobalt. An increase in the citric acid concentration negligibly affected the dissolution of the metals, whereas temperature exhibited a strong beneficial effect. Oxalic acid was determined to be the most appropriate organic acid for the second leaching step. After 8 h(4 h + 4 h) of leaching with organic acids(0.5 M citric + 0.5 M oxalic) in sequence at 90°C, 89.63% Ni, 82.89% Co, and 69.63% Fe were leached from the lateritic nickel ore. A sequential citric + oxalic acid leaching method could represent a viable alternative for the dissolution of metals from lateritic nickel ore. 展开更多
关键词 laterite leaching citric acid oxalic acid dissolution
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A technological process for extracting vanadium from leaching solution of sodium roasting of vanadium slag by manganese salt pretreatment
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作者 Mengxia Liu Tao Jiang +4 位作者 Jing Wen Zibi Fu Tangxia Yu Changqing Li Xinyu An 《Chinese Journal of Chemical Engineering》 2025年第5期219-231,共13页
The ammonium salt precipitation method is frequently utilized for extracting vanadium from the leaching solution obtained through sodium roasting of vanadium slag.However,Na^(+)and NH_(4)^(+)ions in the vanadium preci... The ammonium salt precipitation method is frequently utilized for extracting vanadium from the leaching solution obtained through sodium roasting of vanadium slag.However,Na^(+)and NH_(4)^(+)ions in the vanadium precipitation solution can not be effectively separated,leading to a large amount of ammonia-nitrogen wastewater which is difficult to treat.In this study,the manganese salt pretreatment process is used to extract vanadium from a sodium roasting leaching solution,enabling the separation of vanadium and sodium.The vanadium extraction product of manganese salt is dissolved in acid to obtain vanadium-containing leaching solution,then vanadium is extracted by hydrolysis and vanadium precipitation,and V_(2)O_(5)is obtained after impurity removal and calcination.The results show that the rate of vanadium extraction by manganese salt is 98.23%.The vanadium extraction product by manganese salt is Mn_(2)V_(2)O_(7),and its sodium content is only 0.167%.Additionally,the acid solubility of vanadium extraction products by manganese salt is 99.52%,and the vanadium precipitation rate of manganese vanadate solution is 92.34%.After the removal of manganese and calcination process,the purity of V_(2)O_(5)product reached 97.73%,with a mere 0.64%loss of vanadium.The Mn_(2)^(+)and NH_(4)^(+)ions in the solution after vanadium precipitation are separated by precipitation method,which reduces the generation of ammonia-nitrogen wastewater.This is conducive to the green and sustainable development of the vanadium industry. 展开更多
关键词 Sodium roasting leaching solution of vanadium slag Manganese salt pretreatment acid dissolution Vanadium precipitation by hydrolysis V_(2)O_(5)
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Assessment of Potential Nutrient Release from Phosphate Rock and Dolostone for Application in Acid Soils 被引量:2
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作者 Rogério Borguete Alves RAFAEL María Luisa FERNáNDEZ-MARCOS +4 位作者 Stefania COCCO Maria Letizia RUELLO David C.WEINDORF Valeria CARDELLI Giuseppe CORTI 《Pedosphere》 SCIE CAS CSCD 2018年第1期44-58,共15页
Finding alternative local sources of plant nutrients is a practical, low-cost, and long-term strategy. In this study, laboratory column experiments were conducted in a completely randomized design to evaluate the feas... Finding alternative local sources of plant nutrients is a practical, low-cost, and long-term strategy. In this study, laboratory column experiments were conducted in a completely randomized design to evaluate the feasibility of using phosphate rock and dolostone as fertilizers or acid-neutralizing agents for application in tropical acid soils. The dissolution rates of different particle-size fractions(0.063–0.25, 0.25–0.5, and 0.5–2 mm) of both rocks were studied by citric acid solution at p H 4 and 2 and water, with extraction times of 1, 3, 5, 7, 12, 24, 72, 144, 240, and 360 h. The results showed that the dissolution of both rocks depended on the particle size,leaching solution, and extraction time. The dissolution rate of rock-forming minerals increased as the specific surface area increased,corresponding to a decrease in particle size. In all cases, the release kinetics was characterized by two phases: 1) a first stage of rapid release that lasted 24 h and would ensure short-term nutrient release, and 2) a second stage of slow release after 24 h, representing the long-term nutrient release efficiency. Both rocks were suitable as slow-release fertilizers in strongly acid soils and would ensure the replenishment of P, Ca, and Mg. A combination of fine and medium particle-size fractions should be used to ensure high nutrient-release efficiency. Much work could remain to determine the overall impact of considerable amounts of fresh rocks in soils. 展开更多
关键词 citric acid dissolution rate leaching solution particle-size fraction release kinetics slow-release fertilizer
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Reservoir characteristics and controlling factor of tight sandstone in Shuixigou Group in Taibei depression,Turpan-Hami basin 被引量:3
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作者 Tong Lin Xuan Chen +3 位作者 Fan Yang Hongguang Gou Mingyu Liu Runze Yang 《Energy Geoscience》 EI 2024年第2期70-80,共11页
The positive structure belts surrounding the Taibei Sag,Turpan-Hami Basin,have been the main targets for oil and gas exploration for years and are now left with remaining resources scattering in reservoirs adjacent to... The positive structure belts surrounding the Taibei Sag,Turpan-Hami Basin,have been the main targets for oil and gas exploration for years and are now left with remaining resources scattering in reservoirs adjacent to source rocks in the sag,where the Shuixigou Group with substantial oil and gas potential constitutes the primary focus for near-source exploration.Consequently,characterization of development and key controlling factors of reservoir space becomes a must for future exploration in the area.This study investigates the development traits,genesis,and controlling factors of the Xishanyao and Sangonghe formations in the Shengbei and Qiudong Sub-sags of the Taibei Sag with techniques such as cast thin-section observation,porosity and permeability tests,high-pressure mercury injection,and saturation fluid NMR analysis of reservoir rocks.The findings reveal that the Shuixigou Group in the Taibei Sag consists of lithic sandstone.Reservoirs in the group are mostly poor in terms of physical properties,with undeveloped primary pores dominated by intergranular dissolved pores as a result of a strong compaction.Comparative analysis of key controlling factors of the Sangonghe Formation reveals significant distinctions in sandstone particle size,sand body thickness,genesis and distribution,provenance location,and source rock type between the Qiudong area and Shengbei area.Vertically,the coal seams of the Xishanyao Formation exhibit heightened development with shallower burial depth and lower maturity compared to those of the Sangonghe Formation.Consequently,this environment fosters the formation of organic acids,which have a stronger dissolution effect on minerals to develop secondary dissolution pores,and ultimately resulting in better reservoir physical properties.Overall,the reservoirs within the Qiudong area of the Taibei Sag demonstrate superior characteristics compared to those in the Shengbei area.Furthermore,the reservoir physical properties of the Xishanyao Formation are better than those of the Sangonghe Formation.The research findings will provide valuable guidance for the exploration and development of lithological oil and gas reservoirs within the Taibei Sag. 展开更多
关键词 Intergranular dissolved pore Organic acid dissolution Secondary dissolution pore Tight sandstone Shuixigou group Turpan-Hami basin
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A new alternative approach for investigating acidization dissolution front propagation in fluid-saturated carbonate rocks 被引量:6
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作者 ZHAO ChongBin HOBBS Bruce ORD Alison 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2017年第8期1197-1210,共14页
The natural phenomenon associated with the chemical dissolution of dissolvable minerals of rocks can be employed to develop innovative technology in mining and oil extracting engineering. This paper presents a new alt... The natural phenomenon associated with the chemical dissolution of dissolvable minerals of rocks can be employed to develop innovative technology in mining and oil extracting engineering. This paper presents a new alternative approach for theoretically dealing with chemical dissolution front (CDF) propagation in fluid-saturated carbonate rocks. Note that the CDF is represented by the porosity front in this study. In this new approach, the porosity, pore-fluid velocity and acid concentration are directly used as independent variables. To illustrate how to use the present new approach, an aeidization dissolution system (ADS) consisting of carbonate rocks, which belongs to one of the many general chemical dissolution systems (CDSs), is taken as an application example. When the acid dissolution capacity (ADC) number (that is defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid) approaches zero, the present new approach can be used to obtain analytical solutions for the stable ADS. However, if the ADC number is a nonzero finite number, then numerical solutions can be only obtained for the ADS, especially when the ADS is in an unstable state. The related theoretical results have demonstrated that: (1) When the ADS is in a stable state and in the case of the ADC number approaching zero, the present new approach is mathematically equivalent to the previous approach, in which the porosity, pore-fluid pressure and acid concentration are used as independent variables. However, when the ADS is in an unstable state, the use of the present new approach leads to a free parameter that needs to be determined by some other ways. (2) The existence of a non-step-type dissolution front within a transient region should at least satisfy that none of the ADC number, injected acid velocity and reciprocal of the dissolution reaction rate is equal to zero in the stable ADS. 展开更多
关键词 acidization dissolution front propagation critical length alternative approach critical time carbonate rocks
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Physical simulation experiments on pore evolution in high-temperature and overpressure reservoirs 被引量:1
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作者 You Li Qu Xiyu +4 位作者 Zhong Jia Li Cai Wu Shijiu Gao Yuan Cui Jinggang 《Natural Gas Industry B》 2020年第1期30-39,共10页
At present,simulation on reservoir evolution under normal pressure is common while that under abnormal pressure is rare.In this paper,the Miocene“high-temperature and overpressure”reservoir in the LedongeLingshui Sa... At present,simulation on reservoir evolution under normal pressure is common while that under abnormal pressure is rare.In this paper,the Miocene“high-temperature and overpressure”reservoir in the LedongeLingshui Sag of the Qiongdongnan Basin was taken as the research object to quantitatively define the effects of high pressure and overpressure on the evolution of reservoir pores.After the temperature and pressure field in this area was divided in the setting of sedimentation and diagenesis,the evolution characteristics of pores in different temperature and pressure field were analyzed by means of natural analogy and physical simulation experiment.Then,the effects of overpressure and fluids on the evolution of reservoir pores were discussed.Finally,the main factors controlling the development of high-quality reservoirs were determined.And the following research results were obtained.First,the temperature and pressure field of the Miocene reservoir in the LedongeLingshui Sag can be divided into three zones,i.e.,high temperature and normal pressure zone,high temperature and overpressure zone,and high temperature and super overpressure zone.Second,overpressure and super overpressure can provide some preservation on primary pores.In the same diagenetic stage,the plane porosity of overpressure and super overpressure reservoirs is 1.23e6.74%higher than that of normal pressure reservoirs.Once the reservoir pressure in overpressure and super overpressure areas is higher than hydrostatic pressure by 8 MPa and 4 MPa,respectively,about 1%primary pores are preserved.Third,the dissolution of organic acid makes greater contribution to the secondary pores in reservoirs and its plane porosity is 0.96-7.38%higher than that of normal compaction reservoirs.Fourth,the leaching effect of meteorological water on reservoir physical properties is slight,and its plane porosity is only 0.19%higher than that of normal compaction reservoirs.In conclusion,the dissolution of organic acid is the most constructive effect for the reservoirs in high temperature and normal pressure.In addition,preservation of primary pores by overpressure is the most constructive effect for the reservoirs in high temperature and(super)overpressure,and the higher the overpressure is,the more preservation effect it provides on pores. 展开更多
关键词 Overpressure pore preservation dissolution of organic acid Secondary pore Pore evolution Control factor Qiongdongnan basin LedongeLingshui sag MIOCENE
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