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Effect of Si δ-Doping on the Linear and Nonlinear Optical Absorptions and Refractive Index Changes in InAlN/GaN Single Quantum Wells
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作者 Shaffa Almansour Hassen Dakhlaoui Emane Algrafy 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第2期102-105,共4页
In the framework of effective mass approximation, we theoretically investigate the electronic structure of the Si δ-doped InAIN/GaN single quantum well by solving numerically the coupled equations Schrodinger-Poisson... In the framework of effective mass approximation, we theoretically investigate the electronic structure of the Si δ-doped InAIN/GaN single quantum well by solving numerically the coupled equations Schrodinger-Poisson self-consistently. The linear, nonlinear optical absorption coefficients and relative refractive index changes are calculated as functions of the doping concentration and its thickness. The obtained results show that the position and the amplitude of the linear and total optical absorption coefficients and the refractive index changes can be modified by varying the doping concentration and its thickness. In addition, it is found that the maximum of the optical absorption can be red-shifted or blue-shifted by varying the doping concentration. The obtained results are important for the design of various electronic components such as high-power FETs and infrared photonic devices. 展开更多
关键词 of IS In GAN in Doping on the Linear and Nonlinear Optical absorptions and Refractive Index Changes in InAlN/GaN Single Quantum Wells on
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Studies on Linear and Nonlinear Intersubband Optical Absorptions in a Wurtzite AlGaN/GaN Coupling Quantum Well 被引量:3
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作者 ZHANG Li 《Communications in Theoretical Physics》 SCIE CAS CSCD 2008年第3期786-790,共5页
Based on the density matrix approach and iterative procedure, a detailed procedure for the calculation of the linear and nonlinear intersubband optical absorption coefficients is given in wurtzite GaN-based coupling q... Based on the density matrix approach and iterative procedure, a detailed procedure for the calculation of the linear and nonlinear intersubband optical absorption coefficients is given in wurtzite GaN-based coupling quantum wells (CQWs). The simple analytical formulas for electronic eigenstates and the linear and nonlinear optical absorption coefficients in the systems are also deduced. Numerical result on a typical A1GaN/GaN CQW shows that, the linear and nonlinear optical absorption coefficients sensitively depend on the structural parameters of the CQW system as well as the incident optics beam intensity. 展开更多
关键词 coupling quantum wells built-in electric field absorption coefficient nitride semiconductor
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First-principles Study on Infrared Absorptions of Transition Metal-doped ZnO with Oxygen Vacancy 被引量:2
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作者 Yinhua YAO Quanxi CAO 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2013年第4期467-472,共6页
Using first-principle theory, the infrared absorptions of transition metal (Mn, Fe, Co, Ni)-doped ZnO were investigated. The results indicate that the absorptions of Mn- and Co-incorporated ZnO without oxygen vacanc... Using first-principle theory, the infrared absorptions of transition metal (Mn, Fe, Co, Ni)-doped ZnO were investigated. The results indicate that the absorptions of Mn- and Co-incorporated ZnO without oxygen vacancy are reduced, while those of Fe- and Ni-doped ZnO are raised. This is consistent with the previous experimental results. The effects of oxygen vacancy on the absorptions of the doped systems were predicted. When a neutral oxygen vacancy is introduced, all doping elements decrease the absorptions. On the contrary, the absorptions of the doped systems are enhanced if the vacancies are charged. Degraded absorptions can be obtained by increasing the permeability. However, the appearance of anti-bonding states may cause enhanced absorptions. In the current study, Mn-doped ZnO is the most suitable for use as low infrared absorption materials. 展开更多
关键词 Infrared absorption Oxygen vacancy ZNO Transition metal
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Linear and Nonlinear Optical Absorptions of a Donor Impurity in Spherical Quantum Dots 被引量:1
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作者 XIE Wen-Fang 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第7期155-158,共4页
An investigation of the optical properties of a hydrogenic donor in spherical parabolic quantum dots hasbeen performed by using the matrix diagonalization method.The optical absorption coefficient between the ground(L... An investigation of the optical properties of a hydrogenic donor in spherical parabolic quantum dots hasbeen performed by using the matrix diagonalization method.The optical absorption coefficient between the ground(L=0) and the first excited state (L=1) have been examined based on the computed energies and wave functions.The results are presented as a function of the incident photon energy for the different values of the confinement strength.These results show the effects of the quantum size and the impurity on the optical absorption coefficient of a donorimpurity quantum dot. 展开更多
关键词 quantum dot optical absorption
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A correction method for the telluric absorptions and application to Lijiang Observatory 被引量:1
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作者 Kai-Xing Lu Zhi-Xiang Zhang +7 位作者 Ying-Ke Huang An-Bing Ren Liang Xu Hai-Cheng Feng Yu-Xin Xin Xu Ding Xiao-Guang Yu Jin-Ming Bai 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2021年第7期281-289,共9页
Observing a telluric standard star for correcting the telluric absorption lines of spectrum will take a significant amount of precious telescope time,especially in the long-term spectral monitoring project.Beyond that... Observing a telluric standard star for correcting the telluric absorption lines of spectrum will take a significant amount of precious telescope time,especially in the long-term spectral monitoring project.Beyond that,it is difficult to select a suitable telluric standard star near in both time and airmass to the scientific object.In this paper,we present a method of correcting the telluric absorption lines by combining the advantages of long slit spectroscopy.By rotating the slit,we observed the scientific object and a nearby comparison star in one exposure,so that the spectra of both objects should have the same telluric transmission spectrum.The telluric transmission spectrum was constructed by dividing the observed spectrum of the comparison star by its stellar template,and was used to correct the telluric absorption lines of the scientific object.Using the long slit spectrograph of the Lijiang 2.4-meter telescope,we designed a long-term spectroscopic observation strategy,and finished a four-year spectroscopic monitoring for a pair of objects(an active galactic nucleus and a non-varying comparison star).We applied this method to correct the telluric absorption lines of the long-term monitored spectra by the Lijiang 2.4-meter telescope,and investigated the variation of the telluric absorptions at Lijiang Observatory.We found that the telluric absorption transparency is mainly modulated by the seasonal variability of the relative humidity,airmass and seeing.Using the scatter of the [O Ⅲ] λ5007 fluxes emitted from the narrow-line region of active galactic nuclei as an indicator,we found that the correction accuracy of the telluric absorption lines is 1%. 展开更多
关键词 techniques:telluric absorption methods:data analysis techniques:spectroscopic quasars:individual(SDSS J1536+0441)
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GLOBAL BLOW-UP FOR A HEAT SYSTEM WITH LOCALIZED SOURCES AND ABSORPTIONS 被引量:1
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作者 Chen Youpeng 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2007年第2期213-225,共13页
In this paper there are established the global existence and finite time blow-up results of nonnegative solution for the following parabolic system ut = △u + v^P(x0, t) - au^τ, x ∈ Ω, t 〉 0, △u + v^P(x0, t... In this paper there are established the global existence and finite time blow-up results of nonnegative solution for the following parabolic system ut = △u + v^P(x0, t) - au^τ, x ∈ Ω, t 〉 0, △u + v^P(x0, t) - bu^τ, x ∈ Ω, t 〉 0 subject to homogeneous Dirichlet conditions and nonnegative initial data, where x0 ∈ Ω is a fixed point, p, q, r, s ≥ 1 and a, b 〉 0 are constants. In the situation when nonnegative solution (u, v) of the above problem blows up in finite time, it is showed that the blow-up is global and this differs from the local sources case. Moreover, for the special case r = s = 1, lim t→T*(T*-t)^p+1/pq-1u(x,t)=(p+1)^1/pq-1(q+1)^p/pq-1(pq-1)^-p+1/pq-1, lim t→T*(T*-t)^q+1/pq-1u(x,t)=(p+1)^1/pq-1(q+1)^p/pq-1(pq-1)^-p+1/pq-1 are obtained uniformly on compact subsets of/2, where T* is the blow-up time. 展开更多
关键词 heat system localized source absorption global blow-up asymptotic behavior
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Terahertz field-induced modulations of intersubband absorptions in quantum wells
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作者 张拥华 王长 《Chinese Physics B》 SCIE EI CAS CSCD 2006年第3期649-653,共5页
Nonlinear optical properties of intersubband electrons in a 3-level quantum well under intense terahertz field are investigated by using a density matrix approach. The results show that the terahertz fields with diffe... Nonlinear optical properties of intersubband electrons in a 3-level quantum well under intense terahertz field are investigated by using a density matrix approach. The results show that the terahertz fields with different frequencies cause the distinct modulations of the intersubband absorptions. The terahertz-indueed sideband and Autler-Towns splitting in the absorption spectrum are obtained, respectively for the terahertz-photon energy below and close to the transition energy between the ground and first excited state. 展开更多
关键词 terahertz field intersubband transition sideband absorption AC-stark splitting
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The theory and experiment of solute migration caused by excited state absorptions
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作者 金肖 王玉晓 +5 位作者 税敏 李常伟 杨俊义 张学如 杨昆 宋瑛林 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第1期382-387,共6页
Nonsymmetrical transition from reverse-saturable absorption (RSA) to saturable absorption (SA) caused by excited state absorption induced mass transport of the CuPcTs dissolved in dimethyl sulfoxide is observed in... Nonsymmetrical transition from reverse-saturable absorption (RSA) to saturable absorption (SA) caused by excited state absorption induced mass transport of the CuPcTs dissolved in dimethyl sulfoxide is observed in an open aperture Z-scan experiment with a 21-ps laser pulse. The nonsymmetrical transition from RSA to SA is ascribed neither to saturation of excited state absorption nor to thermal induced mass transport, the so-called Sorer effect. In our consideration, strong nonlinear absorption causes the rapid accumulation of the non-uniform kinetic energy of the solute molecules. The non-uniform kinetic field in turn causes the migration of the solute molecules. Additionally, an energy-gradient-induced mass transport theory is presented to interpret the experimental results, and the theoretical calculations are also taken to fit our experimental results. 展开更多
关键词 solute migration excited state absorption energy-gradient
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Studies on the Effects of Polyaspartate Protease Fertilizer Enhancer in the Absorptions of Soil Nutrition and the Enzymatic Activities of Crops
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作者 JIANGGuoliang YANGDong +3 位作者 LIUYun ZHANGGuanghua LIZhongjun ZHANGXinhua 《Journal of Ocean University of Qingdao》 2003年第1期62-64,共3页
The effects of polyaspartate protease fertilizer enhancer, made from oyster shell proteins, on the absorption of soil nutrition and the enzymatic activities of crops were studied. It has been found that the enhancer c... The effects of polyaspartate protease fertilizer enhancer, made from oyster shell proteins, on the absorption of soil nutrition and the enzymatic activities of crops were studied. It has been found that the enhancer contributes 30%, 50% and 50% augmentation of nitrogen (N), phosphate (P) and potassium (K) absorption respectively and about 20% of nitrate reductase and peroxide enzyme activities of crops. These results show that polyaspartate protease fertilizer enhancer could improve significantly the absorption and utilization efficiencies of soil nutrition and the activities of nitrate reductase and peroxide enzyme of crops, thus elevating the utilization rates of chemical fertilizers to a certain extent. 展开更多
关键词 polyaspartate protease fertilizer enhancer absorption soil nutrition enzyme activity
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Electrospinning of FeNiCo/carbon nanofibers:a new paradigm for lightweight microwave absorbers
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作者 Yuan Wenpei Qu Lin +3 位作者 Wang Yajing Liu Pengyu Zhang Yanlan Wang Yongzhen 《新型炭材料(中英文)》 北大核心 2026年第1期234-252,共19页
With the rapid development of modern electronic technology,the demand for high-performance microwave absorption materials has increased dramatically.In order to meet this demand,the electrospinning of FeNiCo/carbon na... With the rapid development of modern electronic technology,the demand for high-performance microwave absorption materials has increased dramatically.In order to meet this demand,the electrospinning of FeNiCo/carbon nanofiber(FeNiCo/CNF)composites with excellent microwave absorption properties was developed,and their potential as high frequency microwave absorption materials was evaluated.Experiment showed that FeNiCo/CNFs achieve a minimum reflection loss(RL_(min))of−55.5 dB with a matching thickness of only 1.6 mm.Microstructure analysis and electromagnetic parameter testing showed that the excellent microwave absorbing properties were mainly due to the combined effect of the network structure of carbon nanofibers and the FeNiCo alloy.This interaction promotes multiple reflections and the efficient absorption of microwaves.Computer simulation also showed that the FeNiCo/CNF composites produce an excellent radar cross-section reduction in typical radar operating frequency bands,which validates their potential application in stealth technology.This is a new concept in the development of high-performance microwave absorption materials. 展开更多
关键词 ELECTROSPINNING ALLOY Composite nanofibers Radar cross section Microwave absorption
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A method for enhancing the performance of infrared filters based on ratemodulated deposition of germanium films
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作者 LIU Bao-Jian LI Da-Qi +7 位作者 DUAN Wei-Bo YU De-Ming CAI Qing-Yuan YU Tian-Yan JIANG Lin YANG Yu-Ting ZHUANG Qiu-Hui ZHENG Yu-Xiang 《红外与毫米波学报》 北大核心 2026年第1期157-165,共9页
This study systematically investigated the influence of deposition rate on the structure,broadband opti⁃cal properties(1.0-13.0μm),and stress characteristics of Germanium(Ge)films.Additionally,a method for enhancing ... This study systematically investigated the influence of deposition rate on the structure,broadband opti⁃cal properties(1.0-13.0μm),and stress characteristics of Germanium(Ge)films.Additionally,a method for enhancing the performance of infrared filters based on rate-modulated deposition of Ge films was proposed.The optical absorption of Ge films in the short-wave infrared(SWIR)and long-wave infrared(LWIR)bands can be effectively reduced by modulating the deposition rate.As the deposition rate increases,the Ge films maintain an amorphous structure.The optical constants of the films in the 1.0-2.5μm and 2.5-13.0μm bands were precisely determined using the Cody-Lorentz model and the classical Lorentz oscillator model,respectively.Notably,high⁃er deposition rates result in a gradual increase in the refractive index.The extinction coefficient increases with the deposition rate in the SWIR region,attributed to the widening of the Urbach tail,while it decreases in the LWIR region due to the reduced absorption caused by the Ge-O stretching mode.Additionally,the films exhibit a tensile stress that decreases with increasing deposition rate.Finally,the effectiveness of the proposed fabrication method for an infrared filter with Ge films deposited at an optimized rate was demonstrated through practical examples.This work provides theoretical and technical support for the application of Ge films in high-performance infrared filters. 展开更多
关键词 optical coatings germanium film optical absorption infrared filter
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Preparation and tailoring electromagnetic shielding and microwave absorbing performance of Fe_(3)O_(4)modified activated carbon foam based on mesophase coal pitch pyrolysis foaming
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作者 GE Yuanyuan WANG Yuzhe +4 位作者 XU Guozhong ZHU Yaming YUAN Xia SHI Guimei ZHONG Xiangyun 《燃料化学学报(中英文)》 北大核心 2026年第1期120-134,共15页
The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D i... The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D interconnected pore structure was prepared through the high pressure pyrolysis of mesophase coal tar pitch.It is found that the 3D interconnected cellular pores of MPCF facilitate multiple reflections of electromagnetic waves,which results in the minimum reflection loss(RLmin)value of MPCF reaches-37.84 dB with the effective absorption bandwidth(EAB)of 5.44 GHz at a thickness of 2.70 mm,and the total average electromagnetic shielding effectiveness(SE_(T))under 3.00 mm thickness achieves 26.52 dB in X-band.Subsequently,MPCF is activated by KOH to obtain activated carbon foam(A-MPCF).The average SE_(T)of A-MPCF achieves 103.00 dB for abundant nanopores on the pore cell walls,which leads to a transition from the multiple reflections of electromagnetic waves on the walls to diffuse reflection.Unfortunately,the reflection coefficient(R)of A-MPCF increases from 0.78 to 0.90.To reduce the R value,Fe_(3)O_(4)/A-MPCF was fabricated via the in situ growth of nano Fe_(3)O_(4)on A-MPCF.Consequently,the R value of Fe_(3)O_(4)/A-MPCF was reduced from 0.90 to 0.74,whereas the MWA performance was only slightly decreased.This work proposes a simple strategy for simultaneously adjusting MWA and EMI shielding performances of materials. 展开更多
关键词 carbon foam microwave absorption electromagnetic interference shielding mesophase pitch
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Chitosan as oral absorption enhancer and inhibitor:A comprehensive review
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作者 Sajid Hussain Omer M.A.Dagah +8 位作者 Essam A.M.S Obaid Peng Jin Ovas Ahmed Dar Muhammd Irfan Yiming Qi Qinghua Wu Ming Jin Tengli Zhang Lei Luo 《Chinese Chemical Letters》 2026年第1期137-147,共11页
Chitosan(CS),a natural polymer derived from chitin found in the exoskeletons of crustaceans,has garnered significant interest in the pharmaceutical field due to its unique properties,including biocompatibility and bio... Chitosan(CS),a natural polymer derived from chitin found in the exoskeletons of crustaceans,has garnered significant interest in the pharmaceutical field due to its unique properties,including biocompatibility and biodegradability.In recent years,various studies have reported that CS can affect drug bioavailability,and interestingly,it works as an oral absorption enhancer and inhibitor.This review offers an in-depth analysis of the mechanisms underlying such a phenomenon and supports its application as a pharmaceutical excipient.CS enhances oral drug absorption through various mechanisms,such as interaction with the intestinal mucosa,tight junction modulation,inhibition of efflux transporters,enzyme inhibition,solubility and stability enhancement,and complexation.On the other side,CS exhibits the ability to inhibit the absorption of certain drugs by adsorbing to lipids and sterols,modulating bile acids and gut microbiota,altering drug-cell interaction at the polar interface,and mucus-mediated entrapment and interference.Future potential pharmaceutical research in this field includes elucidating the underneath absorption relevant mechanisms,rational use in formulations as excipient,exploring functional CS derivatives,and developing CS-based drug delivery systems.This comprehensive review highlights CS's versatile and significant role in enhancing and inhibiting oral drug absorption,providing insights into the complexities of drug delivery and the potential of CS to improve therapeutic outcomes. 展开更多
关键词 Oral absorption EXCIPIENTS CHITOSAN ENHANCER INHIBITOR
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Optimization of the Extraction Process and Study of theI n Vitro Transdermal Absorption Characteristics of Annona Squamosa Water Extract
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作者 Shao Qinghui Xie Zhiping +2 位作者 Lu Jinxia ZHONG Yu HE Qiuxing 《China Detergent & Cosmetics》 2026年第1期52-60,共9页
Using the pulp of Annona squamosa L.as the raw material,polysaccharides were extracted using ultrasonicassisted hot water extraction,with polysaccharide yield as the response variable.The effects of four factors on ex... Using the pulp of Annona squamosa L.as the raw material,polysaccharides were extracted using ultrasonicassisted hot water extraction,with polysaccharide yield as the response variable.The effects of four factors on extraction efficiency were investigated,and the extraction process was optimized using an orthogonal experimental design.The monosaccharide composition of the polysaccharides was analyzed using ion chromatography(IC).The antioxidant activity was evaluated through DPPH radical scavenging,hydroxyl radical(·OH)scavenging,and ferric reducing antioxidant power(FRAP)assays.Additionally,Franz diffusion cells were used to conduct in vitro transdermal absorption experiments,measuring cumulative permeation and calculating permeation kinetics parameters.The results showed that under optimized extraction conditions,the polysaccharide yield was 50.57%±0.02%.Ion chromatography analysis revealed that the main monosaccharide components were arabinose(0.6%),glucose(40.5%),and fructose(58.9%).Antioxidant evaluation indicated that with the addition of 80μL of the extract,the DPPH radical scavenging rate reached 94.13%±0.81%;with 600μL,the hydroxyl radical scavenging rate was 93.33%±0.92%,and the FRAP value was(38.07±1.30)mmol/L.Transdermal absorption experiments demonstrated that the skin retention rates of the polysaccharide aqueous extract at 75%and 100%concentrations were 4.65%±1.52%and 12.37%±2.14%,respectively,with 12 h cumulative permeation rates of 57.43%±1.08%and 74.24%±0.74%.Kinetic analysis of transdermal absorption showed that the process followed zero-order kinetics,indicating a constant release rate under steady-state conditions,consistent with Fick’s diffusion law.This study systematically combined optimization of polysaccharide aqueous extraction,monosaccharide composition analysis,antioxidant activity evaluation,and transdermal permeation performance analysis.It revealed the bioactive properties and potential applications of Annona squamosa L.polysaccharides,particularly in the fields of antioxidant activity and transdermal permeation.The findings provide essential data to support the development of functional products based on Annona squamosa L.polysaccharides. 展开更多
关键词 ANNONA ANTIOXIDANT transdermal absorption in vitro
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Enhanced electromagnetic wave absorption in biochar/yttrium iron garnet hybrid composites for electromagnetic interference shielding applications
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作者 Ozgur Yasin Keskin 《International Journal of Minerals,Metallurgy and Materials》 2026年第1期335-346,共12页
Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the... Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz. 展开更多
关键词 BIOCHAR electromagnetic shielding electromagnetic wave absorption COMPOSITE
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Solid 226 nm laser pumped by a Nd:YAG laser for two-photon absorption detection of oxygen
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作者 Yi Zhang Shaoyi Wang +2 位作者 Minghao Yu Zhongqi Feng Dacheng Zhang 《Advanced Photonics Nexus》 2026年第1期82-87,共6页
We present a solid 226 nm deep ultraviolet laser system pumped by a Nd:YAG laser.A diamond Raman laser with a 1485 nm wavelength was generated up to 2.53 mJ pumped by a 9.7 mJ 1064 nm laser,which is the highest pulse ... We present a solid 226 nm deep ultraviolet laser system pumped by a Nd:YAG laser.A diamond Raman laser with a 1485 nm wavelength was generated up to 2.53 mJ pumped by a 9.7 mJ 1064 nm laser,which is the highest pulse energy of a second Stokes diamond Raman laser pumped by a 1064 nm laser as we know.Then,the Raman laser is mixed with the frequency-quadrupled 1064 nm laser to produce the 226 nm laser.The maximum output pulse energy at 226 nm reaches 0.49 mJ.The overall conversion efficiency from1064 to 226 nm is up to 1.14%,which is significantly higher than conventional optical parametric oscillator technology for the generation of 226 nm laser.The 226 nm laser system has been used in a laser-induced fluorescence(LIF)experiment of oxygen two-photon to demonstrate its potential for LIF measurements. 展开更多
关键词 Raman laser deep ultraviolet laser-induced fluorescence SUM-FREQUENCY two-photon absorption
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Push-Pull Bridged Stilbenes as Small Solvatochromic Aggregation-Induced Emission Luminogen:Design and Excited-state Deactivation Dynamics
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作者 Takuya Tanaka Hirosato Koyanagi +6 位作者 Takumi Ehara Tomohiro Ryu Kiyoshi Miyata Satoshi Suzuki Kazunobu Igawa Ken Onda Gen-ichi Konishi 《Aggregate》 2026年第2期336-349,共14页
Aggregation-induced emission luminogens(AIEgens)are typically largeπ-conjugated molecules,but their low affinity and noninvasiveness toward analytes limit practical applications.To address this,smaller,more planar AI... Aggregation-induced emission luminogens(AIEgens)are typically largeπ-conjugated molecules,but their low affinity and noninvasiveness toward analytes limit practical applications.To address this,smaller,more planar AIEgens are needed.Stilbene,though structurally suitable,lacks visible luminescence.Here,we report a minimally modified stilbene-based AIEgen-4-dipropylamino-4'-cyano-bridged stilbene(DpCBS[7])-that exhibits fluorescence solvatochromism and efficient AIE across a broad polarity range in the visible region.DpCBS[7]exhibits low quantum yields(Φ_(fl)=0.010.04)in solvents from nonpolar n-hexane to polar dimethyl sulfoxide,with large Stokes shifts,viscosity-sensitive luminescence,and highly efficient solid-state luminescence(Φ_(fl)=0.70).To elucidate its dual solvatochromic and AiE behavior,femtosecond transient absorption spectroscopy was conducted.In solution,DpCBS[7]displays transient absorption with lifetimes of 21 ps(toluene)and 56 ps(acetonitrile)at 293 K,indicating ultrafast nonradiative decay leading to low Φ_(fl).Arrhenius analysis over the temperature range of 263-313 K revealed activation energies(ΔE_(a))of 9.90kJ/mol in toluene and 12.8 kJ/mol in acetonitrile for the S_(1)→S_(0) decay of DpCBS[7].The ΔE_(a) values show no clear systematic dependence on solvent polarity.In contrast,pre-exponential factor A remains consistently high regardless of solvent polarity,indicating that the striking photophysical response is governed primarily by the pre-exponential factor rather than by modulation of the activation energy.These findings highlight the fundamental importance of tailoring the distribution function through structural modification as a robust strategy to control AiE characteristics. 展开更多
关键词 aggregation-induced emission conical intersection bridged stilbene transient absorption spectroscopy SOLVATOCHROMISM
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Dietary micromineral proteinates improve mineral utilization by regulating transport and homeostatic proteins in pigs
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作者 Chao-Yue Ge Chen-Hao Zou +8 位作者 Yu-Jie Lv Wei-Chen Huang Shen-Ao Zhan Xin-Yu Shen Xiao-Xu Wang Hong-Meng Yuan Gang Lin Dong-You Yu Bing Liu 《Life Research》 2026年第1期61-72,共12页
Background:Excessive use of inorganic trace minerals(ITMs)in swine production leads to high fecal mineral excretion and environmental risks,while most studies on organic trace minerals(OTMs)focus on single elements,wi... Background:Excessive use of inorganic trace minerals(ITMs)in swine production leads to high fecal mineral excretion and environmental risks,while most studies on organic trace minerals(OTMs)focus on single elements,with limited data on the synergistic effects and molecular mechanisms of combined OTMs(Fe,Cu,Mn,Zn)in growing-finishing pigs.Methods:This study aimed to investigate the effects of graded levels of micromineral proteinates(combined OTMs)on growth performance,mineral metabolism,and mRNA expression of mineral regulatory proteins.A total of 360 crossbred Duroc×Landrace×Large White pigs(initial body weight 47.1±4.8 kg)were randomly assigned to 6 dietary treatments:basal diet without microminerals(CON),basal diet with ITMs at commercially recommended levels(IT),and basal diets with 15%(OT 15%),25%(OT 25%),35%(OT 35%)commercially recommended levels(CRL)of combined micromineral proteinates.After a 70-day feeding trial,samples were analyzed using ICP-OES,ELISA,and RT-qPCR.Results:Results showed that reduced levels(15-35%CRL)of micromineral proteinates did not significantly affect average daily gain,average daily feed intake,or feed conversion ratio(gain-to-feed ratio)compared to IT(P>0.05),but significantly increased plasma Cu(1.73-1.83μg/mL)and Zn(1.72-1.97μg/mL)concentrations(P<0.05)and elevated activities of Cu/Zn-superoxide dismutase(32.9-35.9 U/L)and manganese superoxide dismutase(20.5-24.1 U/L)compared to CON(P<0.05),with no significant differences from IT(P>0.05).Fecal excretion of Fe,Cu,Mn,and Zn was significantly reduced by 35-50%in OT 15%-OT 35%groups compared to IT(P<0.05).OT 25%group exhibited the highest apparent absorptivity of Fe(38.5%),Cu(27.8%),and Zn(42.4%)(P<0.05),which was associated with significantly regulated mRNA expression of mineral regulatory proteins:upregulated DMT1,FPN1,ZIP4,and MT1A in the duodenum,and modulated HAMP,ATP7B,ZIP14,and ZnT1 in the liver(P<0.05).Conclusion:In conclusion,dietary supplementation with 25%CRL or less of combined micromineral proteinates can fully meet the nutritional needs of growing-finishing pigs,improve mineral absorptivity,and reduce fecal mineral excretion by regulating intestinal and hepatic mineral transport and homeostatic proteins,providing a sustainable alternative to high-dose ITMs. 展开更多
关键词 trace mineral proteinates apparent absorptivity mineral transporters homeostatic proteins PIGS
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Advances in Fe-based electromagnetic wave absorbers:Multiscale engineering from atomic defects to macroscopic architectures for performance optimization
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作者 Xixi Luo Hui Xie +3 位作者 Yi Ma Di Lan Guanglei Wu Zirui Jia 《International Journal of Minerals,Metallurgy and Materials》 2026年第3期768-797,共30页
The rapid development of electronic devices and communication technologies has resulted in increasingly severe electromagnetic-wave(EW)pollution.Efficient EW absorption(EWA)materials are essential to mitigate their im... The rapid development of electronic devices and communication technologies has resulted in increasingly severe electromagnetic-wave(EW)pollution.Efficient EW absorption(EWA)materials are essential to mitigate their impact and ensure human safety in modern society.Fe-based EWA materials have garnered significant attention owing to their cost-effectiveness,high saturation magnetization,and superior magnetic loss capabilities.This review begins with an introduction to Fe-based EWA materials,followed by a brief description of their EWA mechanisms.Various pristine Fe-based absorbers,such as carbonyl iron powder,ferrite-based materials,Fe-based alloys,Fe-based high-entropy alloys(HEAs),and Fe-based layered ternary transition-metal borides,have been systematically reviewed.Key strategies to enhance the performance of Fe-based composite absorbers,including doping,in-situ oxidation,porous structuring,and composite construction,are critically discussed.Finally,the review presents a summary and future perspectives in this field,highlighting the synergy between Fe-based and high-entropy materials in advancing next-generation EWA for applications in stealth technology,wear-able electronics,and harsh environments. 展开更多
关键词 Fe-based absorber electromagnetic wave absorption DOPING in-situ oxidation porous structure composite construction
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Energy absorption mechanism and cost-benefit assessment of UHMWPE and para-aramid hybrid fabrics for protective structures
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作者 Bo Feng Hongming Li +3 位作者 Jianhua Shao Zhijun Wang Chuang Feng Jitao Zhong 《Defence Technology(防务技术)》 2026年第3期363-376,共14页
UHMWPE(Ultra-High Molecular Weight Polyethylene)plain-weave fabric,characterized by its lightweight and high-strength properties,is widely used in protective equipment such as bulletproof vests and stab-resistant vest... UHMWPE(Ultra-High Molecular Weight Polyethylene)plain-weave fabric,characterized by its lightweight and high-strength properties,is widely used in protective equipment such as bulletproof vests and stab-resistant vests,serving as a key material for enhancing protective performance.This study systematically investigates the influence mechanism of interfacial properties on the energy absorption characteristics of UHMWPE-based protective structures through multi-scale experiments and numerical simulations,and establishes a cross-scale design methodology.Innovatively,an orthotropic constitutive model incorporating dynamic friction coefficients is constructed,combined with a modified Johnson-Cook failure criterion,to achieve high-precision simulation of the entire ballistic impact process(error<3.5%).Additionally,a friction field prediction model considering strain rate effects is developed,and the friction evolution laws of UHMWPE and Para-aramid(Kevlar)fabrics under strain rates of 10^(−3) and 10^(−4) s^(−1) are obtained through MTS pull-out tests.The results show that:(1)there exists a critical yarn-yarn friction coefficient(μ=0.2);exceeding this value leads to a 19%reduction in energy absorption capacity,while viscous interfaces increase the energy dissipation peak by 16%;(2)UHMWPE shows kinetically-dominated absorption(58%)with high rate but high load,increasing damage risk.Para-aramid has friction-dominated absorption(53%)with a lower rate but stable load.Hybrid fabrics use potential-dominated absorption(49%)at a moderate rate,balancing stability and protection.(3)3–5 layers of UHMWPE fabric yield optimal cost-effectiveness,with the unit cost reduction rate of the HS+5U scheme reaching 2.74 m/(s·$),which is 91%higher than that of the hybrid scheme.(4)For HS+5U(5-ply UHMWPE),V50 is 520 m/s,meeting primary protection requirement.For hybrid solutions with U/K≥3(e.g.,HS+6U+2K),V50 reaches 580 m/s(≥540 m/s),satisfying advanced protection requirement.This research provides critical references for the design of flexible protective structures and their engineering applications. 展开更多
关键词 UHMWPE Interfacial friction Multi-scale representation Energy absorption mechanism Cost-benefit assessment
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