Single crystals of chlorine doped zinc cadmium thiocyanate (ZCTC:Cl) have bee n grown from the mixed solution of KCl and H 2O with the evaporation method at 40 degree.The content of the dopants in the crystal has been...Single crystals of chlorine doped zinc cadmium thiocyanate (ZCTC:Cl) have bee n grown from the mixed solution of KCl and H 2O with the evaporation method at 40 degree.The content of the dopants in the crystal has been determined and chan ges of crystal properties due to the dopants are described.Comparision of the pr operties between the doped ZCTC single crystal and the crystals grown from other solution is given.It is found that ZCTC single crystal doped with suitable amou nt of Cl has some better properties than the ZCTC crystals grown from other solu tion.Reasonable explanation has also been given.展开更多
zinc cadmium thiocyanate (ZCTC), ZnCd(SCN)_4, has been discoveredas a UV second-order nonlinear optical coordination crystal. Titsthermal and transmission Properties are reported. The thermaldecomposition is character...zinc cadmium thiocyanate (ZCTC), ZnCd(SCN)_4, has been discoveredas a UV second-order nonlinear optical coordination crystal. Titsthermal and transmission Properties are reported. The thermaldecomposition is characterized by using the X-ray Powder diffraction(XRPD) and infrared (IR) spectroscopy at room temperature. TheAbsorptions of intrinsic ions and ZCTC in a solution state arediscussed as well as Transmission properties of the ZCTC crystal. Aneffective method of reducing the surface Reflection loss of ZCTCcrystal is introduced.展开更多
文摘Single crystals of chlorine doped zinc cadmium thiocyanate (ZCTC:Cl) have bee n grown from the mixed solution of KCl and H 2O with the evaporation method at 40 degree.The content of the dopants in the crystal has been determined and chan ges of crystal properties due to the dopants are described.Comparision of the pr operties between the doped ZCTC single crystal and the crystals grown from other solution is given.It is found that ZCTC single crystal doped with suitable amou nt of Cl has some better properties than the ZCTC crystals grown from other solu tion.Reasonable explanation has also been given.
文摘zinc cadmium thiocyanate (ZCTC), ZnCd(SCN)_4, has been discoveredas a UV second-order nonlinear optical coordination crystal. Titsthermal and transmission Properties are reported. The thermaldecomposition is characterized by using the X-ray Powder diffraction(XRPD) and infrared (IR) spectroscopy at room temperature. TheAbsorptions of intrinsic ions and ZCTC in a solution state arediscussed as well as Transmission properties of the ZCTC crystal. Aneffective method of reducing the surface Reflection loss of ZCTCcrystal is introduced.
