The title compound,C 12 N 2 O 4 H 14 （M r=250.3）,crystallizes in triclinic P1 space group with a=7.7709（9）,b=8.7534（11）,c=9.6958（12）,α=77.103（2）,β=80.496（2）,γ=86.726（2）o,V=633.9（1） 3,Z=2,F（000）=26...The title compound,C 12 N 2 O 4 H 14 （M r=250.3）,crystallizes in triclinic P1 space group with a=7.7709（9）,b=8.7534（11）,c=9.6958（12）,α=77.103（2）,β=80.496（2）,γ=86.726（2）o,V=633.9（1） 3,Z=2,F（000）=264,D c=1.311 Mg/m 3,μ（MoKα）=0.1 mm-1,the final R=0.056,and wR=0.15 for 2239 observed reflections （I 2σ（Ⅰ））.The molecules in the crystal are linked through O-H···O type of hydrogen bonding interaction forming an infinite chainlike structure.The phenylhydrazone ring and oxobutanoate groups are almost planar.The keto hydrazo group adopts a Z-configuration in the molecule and the torsion angle is-177.6（2）°.展开更多
The molecular structures of compounds (Z)-1-phenyl-1-phenylseleno-2-(p-tolyl- sulfonyl) ethene 1 (C21H18O2SSe, Mr = 413.37) and 1,3-diphenyl-3-phenylseleno-2-(p-tolylsulfonyl) -2-propen-1-ol 2 (C28H24O3SSe, Mr = 519.4...The molecular structures of compounds (Z)-1-phenyl-1-phenylseleno-2-(p-tolyl- sulfonyl) ethene 1 (C21H18O2SSe, Mr = 413.37) and 1,3-diphenyl-3-phenylseleno-2-(p-tolylsulfonyl) -2-propen-1-ol 2 (C28H24O3SSe, Mr = 519.49) were determined by single-crystal X-ray diffraction analyses. Crystal 1 crystallizes in monoclinic, space group P21/n with a = 12.574(4), b = 12.087(3), c = 13.132(4) , b = 107.973(4), V = 1898.5(9) ?, Z = 4, Dc = 1.446 g/cm3, m = 2.098 mm-1, l = 0.71073 ? F(000) = 840, R = 0.0484 and wR = 0.1085. Crystal 2 crystallizes in monoclinic, space group P21/n with a = 7.0710(4), b = 14.6604(9), c = 24.3432(5) ? b = 94.76(1), V = 2514.8(3) 3, Z = 4, Dc = 1.372 g/cm3, m = 1.603 mm-1, l = 0.71073 ? F (000) = 1064, R = 0.0366 and wR = 0.0573. The X-ray diffraction analysis shows that both of the title compounds are in Z- configuration.展开更多
文摘The title compound,C 12 N 2 O 4 H 14 （M r=250.3）,crystallizes in triclinic P1 space group with a=7.7709（9）,b=8.7534（11）,c=9.6958（12）,α=77.103（2）,β=80.496（2）,γ=86.726（2）o,V=633.9（1） 3,Z=2,F（000）=264,D c=1.311 Mg/m 3,μ（MoKα）=0.1 mm-1,the final R=0.056,and wR=0.15 for 2239 observed reflections （I 2σ（Ⅰ））.The molecules in the crystal are linked through O-H···O type of hydrogen bonding interaction forming an infinite chainlike structure.The phenylhydrazone ring and oxobutanoate groups are almost planar.The keto hydrazo group adopts a Z-configuration in the molecule and the torsion angle is-177.6（2）°.
基金the National Natural Science Foundation of China (No. 20272050) and the Foundation of Education Committee of Anhui province (2003jgl08)
文摘The molecular structures of compounds (Z)-1-phenyl-1-phenylseleno-2-(p-tolyl- sulfonyl) ethene 1 (C21H18O2SSe, Mr = 413.37) and 1,3-diphenyl-3-phenylseleno-2-(p-tolylsulfonyl) -2-propen-1-ol 2 (C28H24O3SSe, Mr = 519.49) were determined by single-crystal X-ray diffraction analyses. Crystal 1 crystallizes in monoclinic, space group P21/n with a = 12.574(4), b = 12.087(3), c = 13.132(4) , b = 107.973(4), V = 1898.5(9) ?, Z = 4, Dc = 1.446 g/cm3, m = 2.098 mm-1, l = 0.71073 ? F(000) = 840, R = 0.0484 and wR = 0.1085. Crystal 2 crystallizes in monoclinic, space group P21/n with a = 7.0710(4), b = 14.6604(9), c = 24.3432(5) ? b = 94.76(1), V = 2514.8(3) 3, Z = 4, Dc = 1.372 g/cm3, m = 1.603 mm-1, l = 0.71073 ? F (000) = 1064, R = 0.0366 and wR = 0.0573. The X-ray diffraction analysis shows that both of the title compounds are in Z- configuration.
