The doping effects on the frustration and the magnetic properties in hexagonal compounds ot YMn0.9A0.1O3 （A=A1, Fe and Cu） are investigated. Experimental results indicate that both the non-magnetic and magnetic ion ...The doping effects on the frustration and the magnetic properties in hexagonal compounds ot YMn0.9A0.1O3 （A=A1, Fe and Cu） are investigated. Experimental results indicate that both the non-magnetic and magnetic ion dopants lead to the increase of magnetic moments and the decrease of the absolute value of Curie-Weiss temperature （｜θcw｜）- Compared with pure YMnOa, the geometrical frustration of YMn0.9 A0. 1O3 is greatly suppressed and the magnetic coupling in that exhibits dopant-dependent. In addition, for the doped YMno.gAo.103, the antiferromagnetic transition temperature （TN） is also suppressed slightly, which shows an abnormal dilution effect and it may be ascribed to the reduction of frustration due to the chemical substitution.展开更多
YMn2O5nanorods were synthesized through a modified polyacrylamide gel route.The synthesis strategy in this work is based on a sol-gel process using a polyacrylamide gel method in which oxalic acid,citric acid or tarta...YMn2O5nanorods were synthesized through a modified polyacrylamide gel route.The synthesis strategy in this work is based on a sol-gel process using a polyacrylamide gel method in which oxalic acid,citric acid or tartaric acid is employed as the chelating agent.In the gel routes,oxalic acid was used as a carboxyl chelating agent,while citric acid or tartaric acid was a carboxyl and hydroxyl chelating agent.The as-prepared samples were characterized by means of techniques such as X-ray powder diffraction(XRD)measurement,thermogravimetric analysis(TG),differential scanning calorimetry analysis(DSC),Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS),thermal expansion measurement and field-emission scanning electron microscopy(SEM)investigations.It was found that oxalic acid is the best chelating agent with Y(NO3)3·6H2O and Mn(CH3COO)2·4H2O as precursors to prepare a single orthorhombic YMn2O5nanorods at 1000°C.Scanning electron microscope observation shows that the morphology of YMn2O5powders is significantly dependent on the chelating agent.The peaks(single orthorhombic YMn2O5nanorods)at 642,600,573,546,521,493,486,468,448 and 400cm?1were observed from FTIR spectra.The phase,surface morphology and chelation mechanisms of YMn2O5samples have been discussed on the basis of the experimental results.展开更多
The electronic structure of multiferroic YMn2O5 material has been studied by use of the generalized gradient approximation （GGA）. The results demonstrate that the oxygen 2p and manganese 3d orbitals are strongly hyb...The electronic structure of multiferroic YMn2O5 material has been studied by use of the generalized gradient approximation （GGA）. The results demonstrate that the oxygen 2p and manganese 3d orbitals are strongly hybridized. Considering the on-site Coulomb interaction U, we performed the GGA＋U calculations for 0 〈 U ≤8 eV, and it is found that the increase of U could enlarge the band gap and, on the other hand, weaken the Mn-O hybridization. The experimental measurements of the electron energy-loss spectrometry （EELS） exhibit a rich variety of structural features in both O-K edge and Mn-L edges. A theoretical and experimental analysis on the O-K edge suggests that the on-site Coulomb interaction （U） in YMn2O5 could be less than 4 eV. Certain electronic structural features of LaMn2O5 have been discussed in comparison with those of YMn2O5.展开更多
The vortex domains, structural properties and ferroelectric polarization in Y1-xInxMn O3 with 0 B x B 0.6have been extensively investigated in well-characterized samples. X-ray diffraction measurements demonstrated th...The vortex domains, structural properties and ferroelectric polarization in Y1-xInxMn O3 with 0 B x B 0.6have been extensively investigated in well-characterized samples. X-ray diffraction measurements demonstrated that the lattice parameters change continuously following the substitution of In for Y. Measurements of magnetic susceptibilities revealed that In substitution could visibly affect the magnetic transition and low-temperature magnetic properties. Transmission electron microscopy study showed that In substitution could result in notable decrease of the size of ferroelectric vortex domains. Cs-corrected scanning transmission electron microscopy observations and our careful analysis on atomic-poling configurations demonstrate that the ferroelectric polarizations of Y1-xInxMn O3 are suppressed with the increase of In content.展开更多
基金Supported by the National Natural Science Foundation of China under Grant No 11104091
文摘The doping effects on the frustration and the magnetic properties in hexagonal compounds ot YMn0.9A0.1O3 （A=A1, Fe and Cu） are investigated. Experimental results indicate that both the non-magnetic and magnetic ion dopants lead to the increase of magnetic moments and the decrease of the absolute value of Curie-Weiss temperature （｜θcw｜）- Compared with pure YMnOa, the geometrical frustration of YMn0.9 A0. 1O3 is greatly suppressed and the magnetic coupling in that exhibits dopant-dependent. In addition, for the doped YMno.gAo.103, the antiferromagnetic transition temperature （TN） is also suppressed slightly, which shows an abnormal dilution effect and it may be ascribed to the reduction of frustration due to the chemical substitution.
基金supported by the Joint Fund of the National Natural Science Foundation of China and the China Academy of Engineering Physics(11076008)the National Natural Science Foundation of China(61178018,51202024)+1 种基金the Ph.D.Funding Support Program of Education Ministry of China(20110185110007)the Fundamental Research Funds for the Central Universities(2672012ZYGX2012J048)
文摘YMn2O5nanorods were synthesized through a modified polyacrylamide gel route.The synthesis strategy in this work is based on a sol-gel process using a polyacrylamide gel method in which oxalic acid,citric acid or tartaric acid is employed as the chelating agent.In the gel routes,oxalic acid was used as a carboxyl chelating agent,while citric acid or tartaric acid was a carboxyl and hydroxyl chelating agent.The as-prepared samples were characterized by means of techniques such as X-ray powder diffraction(XRD)measurement,thermogravimetric analysis(TG),differential scanning calorimetry analysis(DSC),Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS),thermal expansion measurement and field-emission scanning electron microscopy(SEM)investigations.It was found that oxalic acid is the best chelating agent with Y(NO3)3·6H2O and Mn(CH3COO)2·4H2O as precursors to prepare a single orthorhombic YMn2O5nanorods at 1000°C.Scanning electron microscope observation shows that the morphology of YMn2O5powders is significantly dependent on the chelating agent.The peaks(single orthorhombic YMn2O5nanorods)at 642,600,573,546,521,493,486,468,448 and 400cm?1were observed from FTIR spectra.The phase,surface morphology and chelation mechanisms of YMn2O5samples have been discussed on the basis of the experimental results.
文摘The electronic structure of multiferroic YMn2O5 material has been studied by use of the generalized gradient approximation （GGA）. The results demonstrate that the oxygen 2p and manganese 3d orbitals are strongly hybridized. Considering the on-site Coulomb interaction U, we performed the GGA＋U calculations for 0 〈 U ≤8 eV, and it is found that the increase of U could enlarge the band gap and, on the other hand, weaken the Mn-O hybridization. The experimental measurements of the electron energy-loss spectrometry （EELS） exhibit a rich variety of structural features in both O-K edge and Mn-L edges. A theoretical and experimental analysis on the O-K edge suggests that the on-site Coulomb interaction （U） in YMn2O5 could be less than 4 eV. Certain electronic structural features of LaMn2O5 have been discussed in comparison with those of YMn2O5.
基金supported by the National Basic Research Program of China(2011CB921703,2011CBA00101,2010CB923002,2012CB821404)the National Natural Science Foundation of China(51272277,91221102,11190022,11274368)the Strategic Priority Research Program of the Chinese Academyof Sciences(XDB07020000)
文摘The vortex domains, structural properties and ferroelectric polarization in Y1-xInxMn O3 with 0 B x B 0.6have been extensively investigated in well-characterized samples. X-ray diffraction measurements demonstrated that the lattice parameters change continuously following the substitution of In for Y. Measurements of magnetic susceptibilities revealed that In substitution could visibly affect the magnetic transition and low-temperature magnetic properties. Transmission electron microscopy study showed that In substitution could result in notable decrease of the size of ferroelectric vortex domains. Cs-corrected scanning transmission electron microscopy observations and our careful analysis on atomic-poling configurations demonstrate that the ferroelectric polarizations of Y1-xInxMn O3 are suppressed with the increase of In content.
