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Uniaxial alignment of perovskite nanowires via brush painting technique for efficient flexible polarized photodetectors 被引量:1
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作者 Mi Kyong Kim Su Min Park +8 位作者 Haedam Jin Jeongbeom Cha Dohun Baek Tae Oh Yoon Gibaek Lee Se Gyo Han Sae Byeok Jo Seok Joo Yang Min Kim 《Journal of Materials Science & Technology》 2025年第4期24-33,共10页
A polarization-sensitive and flexible photodetector was fabricated through the precise alignment of perovskite nanowires(NWs)using a brush coating technique.The alignment of the NWs was meticulously examined,consideri... A polarization-sensitive and flexible photodetector was fabricated through the precise alignment of perovskite nanowires(NWs)using a brush coating technique.The alignment of the NWs was meticulously examined,considering various chemical properties of the solvent,such as boiling point,viscosity,and surface tension.Notably,when the NWs were brush-coated with toluene dispersion,the NWs were aligned in higher order than those processed from octane dispersion.The degree of alignment was correlated with the photodetector property.Especially,the well-aligned NW photodetector exhibited a two-fold disparity in current response contingent on the polarization direction.Furthermore,even after enduring 500 bending cycles,the device retained 80%of its photodetector performance.This approach underscores the potential of solution-processed flexible photodetectors for advanced optical applications under dynamic operating conditions. 展开更多
关键词 Perovskite photodetectors Perovskite nanowires Brush coating technique aligned nanowires
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SmartAxis,a software for accurate and rapid zone axis alignment of nanocrystalline materials 被引量:1
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作者 Jinfei Zhou Yujiao Wang +7 位作者 Binbin Lu Jia Lyu Nini Wei Jianfeng Huang Lingmei Liu Xiao Li Xinghua Li Daliang Zhang 《Nano Materials Science》 2025年第2期297-303,共7页
Nanocrystals have emerged as cutting-edge functional materials benefiting from the increased surface and enhanced coupling of electronic states.High-resolution imaging in transmission electron microscope can provide i... Nanocrystals have emerged as cutting-edge functional materials benefiting from the increased surface and enhanced coupling of electronic states.High-resolution imaging in transmission electron microscope can provide invaluable structural information of crystalline materials,albeit it remains greatly challenging to nanocrystals due to the arduousness of accurate zone axis adjustment.Herein,a homemade software package,called SmartAxis,is developed for rapid yet accurate zone axis alignment of nanocrystals.Incident electron beam tilt is employed as an eccentric goniometer to measure the angular deviation of a crystal to a zone axis,and then serves as a linkage to calculate theαandβtilts of goniometer based on an accurate quantitative relationship.In this way,high-resolution imaging of one identical small Au nanocrystal,as well as electron beam-sensitive MIL-101 metal-organic framework crystals,along multiple zone axes,was performed successfully by using this accurate,time-and electron dose-saving zone axis alignment software package. 展开更多
关键词 Zone axis alignment NANOCRYSTALS Beam tilt Electron beam-sensitive materials
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Joint Feature Encoding and Task Alignment Mechanism for Emotion-Cause Pair Extraction
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作者 Shi Li Didi Sun 《Computers, Materials & Continua》 SCIE EI 2025年第1期1069-1086,共18页
With the rapid expansion of social media,analyzing emotions and their causes in texts has gained significant importance.Emotion-cause pair extraction enables the identification of causal relationships between emotions... With the rapid expansion of social media,analyzing emotions and their causes in texts has gained significant importance.Emotion-cause pair extraction enables the identification of causal relationships between emotions and their triggers within a text,facilitating a deeper understanding of expressed sentiments and their underlying reasons.This comprehension is crucial for making informed strategic decisions in various business and societal contexts.However,recent research approaches employing multi-task learning frameworks for modeling often face challenges such as the inability to simultaneouslymodel extracted features and their interactions,or inconsistencies in label prediction between emotion-cause pair extraction and independent assistant tasks like emotion and cause extraction.To address these issues,this study proposes an emotion-cause pair extraction methodology that incorporates joint feature encoding and task alignment mechanisms.The model consists of two primary components:First,joint feature encoding simultaneously generates features for emotion-cause pairs and clauses,enhancing feature interactions between emotion clauses,cause clauses,and emotion-cause pairs.Second,the task alignment technique is applied to reduce the labeling distance between emotion-cause pair extraction and the two assistant tasks,capturing deep semantic information interactions among tasks.The proposed method is evaluated on a Chinese benchmark corpus using 10-fold cross-validation,assessing key performance metrics such as precision,recall,and F1 score.Experimental results demonstrate that the model achieves an F1 score of 76.05%,surpassing the state-of-the-art by 1.03%.The proposed model exhibits significant improvements in emotion-cause pair extraction(ECPE)and cause extraction(CE)compared to existing methods,validating its effectiveness.This research introduces a novel approach based on joint feature encoding and task alignment mechanisms,contributing to advancements in emotion-cause pair extraction.However,the study’s limitation lies in the data sources,potentially restricting the generalizability of the findings. 展开更多
关键词 Emotion-cause pair extraction interactive information enhancement joint feature encoding label consistency task alignment mechanisms
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Band alignment of heterojunctions formed by PtSe_(2)with doped GaN
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作者 Zhuoyang Lv Guijuan Zhao +2 位作者 Wanting Wei Xiurui Lv Guipeng Liu 《Chinese Physics B》 2025年第4期535-542,共8页
In order to investigate the effect of different doping types on the band alignment of heterojunctions,we prepared PtSe_(2)/n-GaN,PtSe_(2)/p-GaN,and PtSe_(2)/u-GaN heterojunctions by wet transfer technique.The valence ... In order to investigate the effect of different doping types on the band alignment of heterojunctions,we prepared PtSe_(2)/n-GaN,PtSe_(2)/p-GaN,and PtSe_(2)/u-GaN heterojunctions by wet transfer technique.The valence band offsets(VBO)of the three heterojunctions were measured by x-ray photoelectron spectroscopy(XPS),while the PtSe_(2)/n-GaN is 3.70±0.15 eV,PtSe_(2)/p-GaN is 0.264±0.15 eV,and PtSe_(2)/u-GaN is 3.02±0.15 eV.The conduction band offset(CBO)of the three heterojunctions was calculated from the material bandgap and VBO,while the PtSe_(2)/n-GaN is 0.61±0.15 eV,PtSe_(2)/p-GaN is 2.83±0.15 eV,and PtSe_(2)/u-GaN is 0.07±0.15 eV.This signifies that both PtSe_(2)/u-GaN and PtSe_(2)/p-GaN exhibit type-Ⅰband alignment,but the PtSe_(2)/n-GaN heterojunction has type-Ⅲband alignment.This signifies that the band engineering of PtSe_(2)/GaN heterojunction can be achieved by manipulating the concentration and type of doping,which is significantly relevant for the advancement of related devices through the realization of band alignment and the modulation of the material properties of the PtSe_(2)/GaN heterojunction. 展开更多
关键词 van der Waals heterojunction x-ray photoelectron spectroscopy band alignment gallium nitride platinum diselenide
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On the apparent line-of-sight alignment of the peak X-ray intensity of the magnetosheath and the tangent to the magnetopause,as viewed by SMILE-SXI 被引量:2
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作者 Andrew Read 《Earth and Planetary Physics》 EI CSCD 2024年第1期155-172,共18页
The Soft X-ray Imager(SXI)on board the Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)spacecraft will be able to view the Earth’s magnetosheath in soft X-rays.Simulated images of the X-ray emission visible f... The Soft X-ray Imager(SXI)on board the Solar wind Magnetosphere Ionosphere Link Explorer(SMILE)spacecraft will be able to view the Earth’s magnetosheath in soft X-rays.Simulated images of the X-ray emission visible from the position of SMILE are created for a range of solar wind densities by using 3 years of the SMILE mission orbit,together with models of the expected X-ray emissivity from the Earth’s magnetosheath.Results from global magnetohydrodynamic simulations and a simple model for exospheric neutral densities are used to compare the locations of the lines of sight along which integrated soft X-ray intensities peak with the lines of sight lying tangent to surfaces(defined here to be the magnetopause)along which local soft X-ray intensities peak or exhibit their strongest gradients,or both,for strongly southward interplanetary magnetic field conditions when no depletion or low-latitude boundary layers are expected.Where,in the parameter space of the various times and seasons,orbital phases,solar wind conditions,and magnetopause models,the alignment of the X-ray emission peak with the magnetopause tangent is good,or is not,is presented.The main results are as follows.The spacecraft needs to be positioned well outside the magnetopause;low-altitude times near perigee are not good.In addition,there are seasonal aspects:dayside-apogee orbits are generally very good because the spacecraft travels out sunward at high altitude,but nightside-apogee orbits,behind the Earth,are bad because the spacecraft only rarely leaves the magnetopause.Dusk-apogee and dawnapogee orbits are intermediate.Dayside-apogee orbits worsen slightly over the first three mission years,whereas nightside-apogee orbits improve slightly.Additionally,many more times of good agreement with the peak-to-tangent hypothesis occur when the solar wind is in a high-density state,as opposed to a low-density state.In a high-density state,the magnetopause is compressed,and the spacecraft is more often a good distance outside the magnetopause. 展开更多
关键词 x-rays MAGNETOSPHERE MAGNETOSHEATH MAGNETOPAUSE Solar wind Magnetosphere Ionosphere Link Explorer(SMILE) Earth solar wind charge exchange
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Atomic Level Insight into the Variation and Tunability of Band Alignment between Si and Amorphous SiO_(2)/HfO_(2)
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作者 Wen-Feng Li Ting-Wei Liu +2 位作者 Zheng-Mei Yang Lin-Wang Wang Yue-Yang Liu 《Chinese Physics Letters》 2025年第1期147-152,共6页
The band alignment between silicon and high-k dielectrics,which is a key factor in device operation and reliability,still suffers from uncontrolled fluctuations and ambiguous understanding.In this study,by conducting ... The band alignment between silicon and high-k dielectrics,which is a key factor in device operation and reliability,still suffers from uncontrolled fluctuations and ambiguous understanding.In this study,by conducting atomic-level ab initio calculations on realistic Si/SiO_(2)/HfO_(2)stacks,we reveal the physical origin of band alignment fluctuations,i.e.,the oxygen density-dependent interface and surface dipoles,and demonstrate that band offsets can be tuned without introducing other materials.This is instructive for reducing the gate tunneling current,alleviating device-to-device variation,and tuning the threshold voltage.Additionally,this study indicates that significant attention should be focused on model construction in emerging atomistic studies on semiconductor devices. 展开更多
关键词 tuning alignment instru
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A Dual Stream Multimodal Alignment and Fusion Network for Classifying Short Videos
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作者 ZHOU Ming WANG Tong 《Journal of Donghua University(English Edition)》 2025年第1期88-95,共8页
Video classification is an important task in video understanding and plays a pivotal role in intelligent monitoring of information content.Most existing methods do not consider the multimodal nature of the video,and t... Video classification is an important task in video understanding and plays a pivotal role in intelligent monitoring of information content.Most existing methods do not consider the multimodal nature of the video,and the modality fusion approach tends to be too simple,often neglecting modality alignment before fusion.This research introduces a novel dual stream multimodal alignment and fusion network named DMAFNet for classifying short videos.The network uses two unimodal encoder modules to extract features within modalities and exploits a multimodal encoder module to learn interaction between modalities.To solve the modality alignment problem,contrastive learning is introduced between two unimodal encoder modules.Additionally,masked language modeling(MLM)and video text matching(VTM)auxiliary tasks are introduced to improve the interaction between video frames and text modalities through backpropagation of loss functions.Diverse experiments prove the efficiency of DMAFNet in multimodal video classification tasks.Compared with other two mainstream baselines,DMAFNet achieves the best results on the 2022 WeChat Big Data Challenge dataset. 展开更多
关键词 video classification multimodal fusion feature alignment
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Beyond Intentions:A Critical Survey of Misalignment in LLMs
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作者 Yubin Qu Song Huang +2 位作者 Long Li Peng Nie Yongming Yao 《Computers, Materials & Continua》 2025年第10期249-300,共52页
Large language models(LLMs)represent significant advancements in artificial intelligence.However,their increasing capabilities come with a serious challenge:misalignment,which refers to the deviation of model behavior... Large language models(LLMs)represent significant advancements in artificial intelligence.However,their increasing capabilities come with a serious challenge:misalignment,which refers to the deviation of model behavior from the designers’intentions and human values.This review aims to synthesize the current understanding of the LLM misalignment issue and provide researchers and practitioners with a comprehensive overview.We define the concept of misalignment and elaborate on its various manifestations,including generating harmful content,factual errors(hallucinations),propagating biases,failing to follow instructions,emerging deceptive behaviors,and emergent misalignment.We explore the multifaceted causes of misalignment,systematically analyzing factors from surface-level technical issues(e.g.,training data,objective function design,model scaling)to deeper fundamental challenges(e.g.,difficulties formalizing values,discrepancies between training signals and real intentions).This review covers existing and emerging techniques for detecting and evaluating the degree of misalignment,such as benchmark tests,red-teaming,and formal safety assessments.Subsequently,we examine strategies to mitigate misalignment,focusing on mainstream alignment techniques such as RLHF,Constitutional AI(CAI),instruction fine-tuning,and novel approaches that address scalability and robustness.In particular,we analyze recent advances in misalignment attack research,including system prompt modifications,supervised fine-tuning,self-supervised representation attacks,and model editing,which challenge the robustness of model alignment.We categorize and analyze the surveyed literature,highlighting major findings,persistent limitations,and current contentious points.Finally,we identify key open questions and propose several promising future research directions,including constructing high-quality alignment datasets,exploring novel alignment methods,coordinating diverse values,and delving into the deep philosophical aspects of alignment.This work underscores the complexity and multidimensionality of LLM misalignment issues,calling for interdisciplinary approaches to reliably align LLMs with human values. 展开更多
关键词 Large language models alignment MISalignment AI safety human values
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In-depth understanding of the band alignment and interface states scenario in Bi_(2)O_(2)Se/SrTiO_(3) ultrathin heterojunction
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作者 Ke Zhang Yu-Sen Feng +6 位作者 Lei Hao Jing Mi Miao Du Ming-Hui Xu Yan Zhao Jian-Ping Meng Liang Qiao 《Rare Metals》 2025年第2期1204-1212,共9页
Bismuth oxyselenide(Bi_(2)O_(2)Se),a novel quasi-two-dimensional charge-carrying semiconductor,is recognized as one of the most promising emerging platforms for next-generation semiconductor devices.Recent advancement... Bismuth oxyselenide(Bi_(2)O_(2)Se),a novel quasi-two-dimensional charge-carrying semiconductor,is recognized as one of the most promising emerging platforms for next-generation semiconductor devices.Recent advancements in the development of diverse Bi_(2)O_(2)Se heterojunctions have unveiled extensive potential applications in both electronics and optoelectronics.However,achieving an in-depth understanding of band alignment and particularly interface dynamics remains a significant challenge.In this study,we conduct a comprehensive experimental investigation into band alignment utilizing high-resolution X-ray photoelectron spectroscopy(HRXPS),while also thoroughly discussing the properties of interface states.Our findings reveal that ultrathin films of Bi_(2)O_(2)Se grown on SrTiO_(3)(with TiO_(2)(001)termination)exhibit Type-I(straddling gap)band alignment characterized by a valence band offset(VBO)of approximately 1.77±0.04 eV and a conduction band offset(CBO)around 0.68±0.04 eV.Notably,when accounting for the influence of interface states,the bands at the interface display a herringbone configuration due to substantial built-in electric fields,which markedly deviate from conventional band alignments.Thus,our results provide valuable insights for advancing high-efficiency electronic and optoelectronic devices,particularly those where charge transfer is highly sensitive to interface states. 展开更多
关键词 Bismuth oxyselenide HETEROJUNCTIONS Band alignment Interface states Build-in electrical field
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Multi-Modal Pre-Synergistic Fusion Entity Alignment Based on Mutual Information Strategy Optimization
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作者 Huayu Li Xinxin Chen +3 位作者 Lizhuang Tan Konstantin I.Kostromitin Athanasios V.Vasilakos Peiying Zhang 《Computers, Materials & Continua》 2025年第11期4133-4153,共21页
To address the challenge of missing modal information in entity alignment and to mitigate information loss or bias arising frommodal heterogeneity during fusion,while also capturing shared information acrossmodalities... To address the challenge of missing modal information in entity alignment and to mitigate information loss or bias arising frommodal heterogeneity during fusion,while also capturing shared information acrossmodalities,this paper proposes a Multi-modal Pre-synergistic Entity Alignmentmodel based on Cross-modalMutual Information Strategy Optimization(MPSEA).The model first employs independent encoders to process multi-modal features,including text,images,and numerical values.Next,a multi-modal pre-synergistic fusion mechanism integrates graph structural and visual modal features into the textual modality as preparatory information.This pre-fusion strategy enables unified perception of heterogeneous modalities at the model’s initial stage,reducing discrepancies during the fusion process.Finally,using cross-modal deep perception reinforcement learning,the model achieves adaptive multilevel feature fusion between modalities,supporting learningmore effective alignment strategies.Extensive experiments on multiple public datasets show that the MPSEA method achieves gains of up to 7% in Hits@1 and 8.2% in MRR on the FBDB15K dataset,and up to 9.1% in Hits@1 and 7.7% in MRR on the FBYG15K dataset,compared to existing state-of-the-art methods.These results confirm the effectiveness of the proposed model. 展开更多
关键词 Knowledge graph MULTI-MODAL entity alignment feature fusion pre-synergistic fusion
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Impact of “Seven Planets in Alignment” on Global Climate Change
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作者 Cuixiang Zhong 《Journal of Environmental Science and Engineering(A)》 2025年第4期187-191,共5页
Just a few days after the astronomical spectacle of the“seven planets in alignment”on February 28,2025,the weather in many places underwent a dramatic change.In Shanghai,which was still at the beginning of spring(Ma... Just a few days after the astronomical spectacle of the“seven planets in alignment”on February 28,2025,the weather in many places underwent a dramatic change.In Shanghai,which was still at the beginning of spring(March 1),the temperature suddenly soared to 29℃,the temperature of summer,while Shandong was hit by a sudden heavy snowstorm.There are various opinions and no consensus on this inexplicable weather change.For this reason,based on the principle of the role of planets in the luminescence and heat generation of stars,the author of this article reveals the significant impact of the“Seven planets in alignment”on global climate change,and also points out that the melting of polar glaciers and the approach of the moon to the Earth is another important cause of global climate change.Therefore,countermeasures to save the abnormal changes in global climate are proposed. 展开更多
关键词 Seven planets in alignment glaciers melting global climate change COUNTERMEASURES
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Chasing in virtual environment:Dynamic alignment for multi-user collaborative redirected walking
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作者 Tianyang DONG Shuqian LV +1 位作者 Hubin KONG Huanbo ZHANG 《虚拟现实与智能硬件(中英文)》 2025年第1期26-46,共21页
Background The redirected walking(RDW)method for multi-user collaboration requires maintaining the relative position between users in a virtual environment(VE)and physical environment(PE).A chasing game in a VE is a t... Background The redirected walking(RDW)method for multi-user collaboration requires maintaining the relative position between users in a virtual environment(VE)and physical environment(PE).A chasing game in a VE is a typical virtual reality game that entails multi-user collaboration.When a user approaches and interacts with a target user in the VE,the user is expected to approach and interact with the target user in the corresponding PE as well.Existing methods of multi-user RDW mainly focus on obstacle avoidance,which does not account for the relative positional relationship between the users in both VE and PE.Methods To enhance the user experience and facilitate potential interaction,this paper presents a novel dynamic alignment algorithm for multi-user collaborative redirected walking(DA-RDW)in a shared PE where the target user and other users are moving.This algorithm adopts improved artificial potential fields,where the repulsive force is a function of the relative position and velocity of the user with respect to dynamic obstacles.For the best alignment,this algorithm sets the alignment-guidance force in several cases and then converts it into a constrained optimization problem to obtain the optimal direction.Moreover,this algorithm introduces a potential interaction object selection strategy for a dynamically uncertain environment to speed up the subsequent alignment.To balance obstacle avoidance and alignment,this algorithm uses the dynamic weightings of the virtual and physical distances between users and the target to determine the resultant force vector.Results The efficacy of the proposed method was evaluated using a series of simulations and live-user experiments.The experimental results demonstrate that our novel dynamic alignment method for multi-user collaborative redirected walking can reduce the distance error in both VE and PE to improve alignment with fewer collisions. 展开更多
关键词 Virtual reality Multi-user redirected walking User collisions Dynamic alignment
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A simple method for automatic recreation of railway horizontal alignments
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作者 Alberte Castro Gerardo Casal +1 位作者 Duarte Santamarina Miguel E.Vázquez‑Méndez 《Railway Engineering Science》 2025年第1期62-78,共17页
This paper deals with the problem of recreating horizontal alignments of existing railway lines.The main objective is to propose a simple method for automatically obtaining optimized recreated alignments located as cl... This paper deals with the problem of recreating horizontal alignments of existing railway lines.The main objective is to propose a simple method for automatically obtaining optimized recreated alignments located as close as possible to an existing one.Based on a previously defined geometric model,two different constrained optimization problems are formulated.The first problem uses only the information provided by a set of points representing the track centerline while the second one also considers additional data about the existing alignment.The proposed methodology consists of a two-stage process in which both problems are solved consecutively using numerical techniques.The main results obtained applying this methodology are presented to show its performance and to prove its practical usefulness:an academic example used to compare with other methods,and a case study of a railway section located in Parga(Spain)in which the geometry of its horizontal alignment is successfully recovered. 展开更多
关键词 Railway horizontal alignment Geometrical model Constrained optimization problem Numerical resolution
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An amphiphilic peptide with unnatural amino acids as an alignment medium for RDC measurements
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作者 Yishen Wang Haizhi Yin +3 位作者 Yanling Yang Zheng-Hui Li Gao-Wei Li Xinxiang Lei 《Magnetic Resonance Letters》 2025年第2期30-37,共8页
The multiple oligopeptides have been regarded as promising alignment media due to their structural diverseness and tendency for self-assembly in solution.Herein,an assembled amphiphilic peptide alignment medium,i.e.,C... The multiple oligopeptides have been regarded as promising alignment media due to their structural diverseness and tendency for self-assembly in solution.Herein,an assembled amphiphilic peptide alignment medium,i.e.,C15eCONH-Phg-Phg-IIIKK-CONH2 with un-natural amino acids for the determination of anisotropic parameters of NMR is introduced.The amphiphilic peptide can be self-assembled at low concentrations in DMSO and is stable and highly homogeneous.The NMR spectrum collected with the addition of the medium had fewer background signals.The utility of the acquired RDC data is demon-strated to determine relative configuration of three natural products,Helminthosporic acid,Estrone,and a-Santonin. 展开更多
关键词 Amphiphilic peptide alignment medium Residual dipolar coupling Liquid crystals Structural determination
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UniTrans:Unified Parameter-Efficient Transfer Learning and Multimodal Alignment for Large Multimodal Foundation Model
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作者 Jiakang Sun Ke Chen +3 位作者 Xinyang He Xu Liu Ke Li Cheng Peng 《Computers, Materials & Continua》 2025年第4期219-238,共20页
With the advancements in parameter-efficient transfer learning techniques,it has become feasible to leverage large pre-trained language models for downstream tasks under low-cost and low-resource conditions.However,ap... With the advancements in parameter-efficient transfer learning techniques,it has become feasible to leverage large pre-trained language models for downstream tasks under low-cost and low-resource conditions.However,applying this technique to multimodal knowledge transfer introduces a significant challenge:ensuring alignment across modalities while minimizing the number of additional parameters required for downstream task adaptation.This paper introduces UniTrans,a framework aimed at facilitating efficient knowledge transfer across multiple modalities.UniTrans leverages Vector-based Cross-modal Random Matrix Adaptation to enable fine-tuning with minimal parameter overhead.To further enhance modality alignment,we introduce two key components:the Multimodal Consistency Alignment Module and the Query-Augmentation Side Network,specifically optimized for scenarios with extremely limited trainable parameters.Extensive evaluations on various cross-modal downstream tasks demonstrate that our approach surpasses state-of-the-art methods while using just 5%of their trainable parameters.Additionally,it achieves superior performance compared to fully fine-tuned models on certain benchmarks. 展开更多
关键词 Parameter-efficient transfer learning multimodal alignment image captioning image-text retrieval visual question answering
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Lamellar COF solid-state electrolytes for robust ambient-temperature lithium-ion transfer enhanced by PEI-driven channel alignment
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作者 Yafang Zhang Xinji Zhang +5 位作者 Jiajia Huang Zhirong Yang Shiyue Zhou Chenye Wang Wenjia Wu Jingtao Wang 《Green Energy & Environment》 2025年第5期982-993,共12页
Ionic covalent organic framework(COF)lamellar membranes are the alternative materials as promising Li^(+)conductors for all-solid-state lithium batteries.However,COF lamellar membrane suffers from poor structural stab... Ionic covalent organic framework(COF)lamellar membranes are the alternative materials as promising Li^(+)conductors for all-solid-state lithium batteries.However,COF lamellar membrane suffers from poor structural stability and inevitable cross-layer transfer resistance due to the weak interaction at interface of adjacent nanosheets.Herein,a lamellar polymer-threaded ionic COF(PEI@TpPa-SO_(3)Li)composite electrolyte with single Li^(+)conduction was prepared by assembling lithium sulfonated COF(TpPa-SO_(3)Li)nanosheets and then threading them with polyethyleneimine(PEI)chains.It reveals that the threaded PEI chains induce the oriented permutation of pore channel of PEI@TpPa-SO_(3)Li electrolyte through electrostatic interaction between-NH_(2)/-NH-and-SO_(3)Li groups.This enables the construction of continuous and aligned-SO_(3)^(-)...Li^(+)...-NH_(2)/-NH-pairs along pore channels,which act as efficient Li^(+)conducting sites and afford high Li^(+)hopping conduction(1.4×10^(-4)S cm^(-1)at 30℃)with a high Young's modulus of 408.7 MP and wide electrochemical stability window of 0~4.7 V.The assembled LiFePO_(4)‖Li and LiNi_(0.8)Mn_(0.1)Co_(0.1)O_(2)‖Li half-cells achieve high discharge capacities of 155.0 mAh g^(-1)and 167.2 mAh g^(-1)at 30℃under0.2 C,respectively,with high capacity retention of 98%after 300 cycles.This study provides an alternative route to highly ion-conductive lamellar porous electrolytes for high-performance energy devices. 展开更多
关键词 Lamellar composite electrolyte COF nanosheets Polymer-driven channel alignment Ionic conductivity All-solid-state lithium battery
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Alignment-dependent ionization of molecules in near-circularly polarized intense laser fields
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作者 Jie Liu Yong-Kang Zhang Xiao-Lei Hao 《Chinese Physics B》 2025年第5期347-354,共8页
The alignment-dependent photoelectron spectrum is a valuable tool for mapping out the electronic structure of molecular orbitals.However,this approach may not be applicable to all molecules,such as CO_(2),as the ioniz... The alignment-dependent photoelectron spectrum is a valuable tool for mapping out the electronic structure of molecular orbitals.However,this approach may not be applicable to all molecules,such as CO_(2),as the ionization process in a linearly polarized laser field involves contributions from orbitals other than the highest occupied molecular orbital(HOMO).Here,we conducted a theoretical investigation into the ionization process of N_(2) and CO_(2) in near-circularly polarized laser field using the Coulomb-corrected strong-field approximation(CCSFA)method for molecules.In particular,we introduced a generalized dressed state into the CCSFA method in order to account for the impact of the laser field on the molecular initial state.The simulated alignment-dependent photoelectron momentum distribution(PMD)of the two molecules exhibited markedly disparate behaviors,which were in excellent agreement with the previous experimental observations reported in[Phys.Rev.A 102,013117(2020)].Our findings indicate that under a near-circularly polarized laser field,the alignment-dependent PMD of molecules is primarily sourced from the HOMO,in contrast to the situation under a linearly polarized laser field.Moreover,a satisfactory correlation between the alignment-dependent angular distribution and the orbital symmetry was observed,which suggests an effective approach for molecular orbital imaging. 展开更多
关键词 alignment Coulomb-corrected strong-field approximation(CCSFA) photoelectron momentum distribution(PMD) image
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Self-FAGCFN:Graph-Convolution Fusion Network Based on Feature Fusion and Self-Supervised Feature Alignment for Pneumonia and Tuberculosis Diagnosis
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作者 Junding Sun Wenhao Tang +5 位作者 Lei Zhao Chaosheng Tang Xiaosheng Wu Zhaozhao Xu Bin Pu Yudong Zhang 《Journal of Bionic Engineering》 2025年第4期2012-2029,共18页
Feature fusion is an important technique in medical image classification that can improve diagnostic accuracy by integrating complementary information from multiple sources.Recently,Deep Learning(DL)has been widely us... Feature fusion is an important technique in medical image classification that can improve diagnostic accuracy by integrating complementary information from multiple sources.Recently,Deep Learning(DL)has been widely used in pulmonary disease diagnosis,such as pneumonia and tuberculosis.However,traditional feature fusion methods often suffer from feature disparity,information loss,redundancy,and increased complexity,hindering the further extension of DL algorithms.To solve this problem,we propose a Graph-Convolution Fusion Network with Self-Supervised Feature Alignment(Self-FAGCFN)to address the limitations of traditional feature fusion methods in deep learning-based medical image classification for respiratory diseases such as pneumonia and tuberculosis.The network integrates Convolutional Neural Networks(CNNs)for robust feature extraction from two-dimensional grid structures and Graph Convolutional Networks(GCNs)within a Graph Neural Network branch to capture features based on graph structure,focusing on significant node representations.Additionally,an Attention-Embedding Ensemble Block is included to capture critical features from GCN outputs.To ensure effective feature alignment between pre-and post-fusion stages,we introduce a feature alignment loss that minimizes disparities.Moreover,to address the limitations of proposed methods,such as inappropriate centroid discrepancies during feature alignment and class imbalance in the dataset,we develop a Feature-Centroid Fusion(FCF)strategy and a Multi-Level Feature-Centroid Update(MLFCU)algorithm,respectively.Extensive experiments on public datasets LungVision and Chest-Xray demonstrate that the Self-FAGCFN model significantly outperforms existing methods in diagnosing pneumonia and tuberculosis,highlighting its potential for practical medical applications. 展开更多
关键词 Feature fusion Self-supervised feature alignment Convolutional neural networks Graph convolutional networks Class imbalance Feature-centroid fusion
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Evolution of Microstructure and Mechanical Properties of AZ31 Sheets with Different Initial Microstructures During the Corrugated Wide Limit Alignment Process
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作者 Hongyang Zhang Huihui Nie +3 位作者 Zhijian Li Hongsheng Chen Wei Liang Liuwei Zheng 《Acta Metallurgica Sinica(English Letters)》 2025年第6期1012-1028,共17页
Presetting tensile twins(TTs)can enhance the mechanical properties of magnesium(Mg)alloys.Two as-received(AR)sheets,as-received state-A(AR-A)with fiber texture and nonuniform grains and as-received state-B with basal ... Presetting tensile twins(TTs)can enhance the mechanical properties of magnesium(Mg)alloys.Two as-received(AR)sheets,as-received state-A(AR-A)with fiber texture and nonuniform grains and as-received state-B with basal texture and uniform equiaxial grains are selected to induce TTs via a novel method called corrugated wide limit alignment(CWLA),and the corresponding CWLA-processed sheets are denoted as CWLA-processed state-A(C-A)and CWLA-processed state-B(C-B).The results demonstrate that a larger initial average grain size correlates with a higher fraction of TTs induced in Mg sheets,thereby refining the grains and forming a new rolling direction(RD)tilted texture during CWLA.The ultimate tensile strength increases by 32%from AR-A to C-A,primarily due to refinement strengthening and twinning-induced strain hardening.The recrystallization mechanism of C-A is dominated by twinning-induced dynamic recrystallization(DRX),where DRX grains prefer to inherit the orientation of TTs,resulting in an enhanced RD-tilted texture and the formation of multi-modal texture.The recrystallization mechanism of C-B is mainly discontinuous DRX and continuous DRX,and the DRX grains prefer to inherit the orientation of matrix grains,ultimately forming a basal texture.In summary,the tensile mechanical behavior of pre-twinned Mg sheets significantly depends on the grain size and texture of the AR sheets,so they present similar changing trends during tensile deformation. 展开更多
关键词 Mg sheet Texture Grain size Corrugated wide limit alignment(CWLA) Tensile twin(TT) Dynamic recrystallization(DRX)
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Band alignment of SnO/β-Ga_(2)O_(3) heterojunction and its electrical properties for power device application
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作者 Xia Wu Chenyang Huang +6 位作者 Xiuxing Xu Jun Wang Xinwang Yao Yanfang Liu Xiujuan Wang Chunyan Wu Linbao Luo 《Journal of Semiconductors》 2025年第8期76-82,共7页
In this study,we present the fabrication of vertical SnO/β-Ga_(2)O_(3) heterojunction diode(HJD)via radio frequency(RF)reactive magnetron sputtering.The valence and conduction band offsets betweenβ-Ga_(2)O_(3) and S... In this study,we present the fabrication of vertical SnO/β-Ga_(2)O_(3) heterojunction diode(HJD)via radio frequency(RF)reactive magnetron sputtering.The valence and conduction band offsets betweenβ-Ga_(2)O_(3) and SnO are determined to be 2.65and 0.75 eV,respectively,through X-ray photoelectron spectroscopy,showing a type-Ⅱband alignment.Compared to its Schottky barrier diode(SBD)counterpart,the HJD presents a comparable specific ON-resistances(R_(on,sp))of 2.8 mΩ·cm^(2) and lower reverse leakage current(I_R),leading to an enhanced reverse blocking characteristics with breakdown voltage(BV)of 1675 V and power figure of merit(PFOM)of 1.0 GW/cm~2.This demonstrates the high quality of the SnO/β-Ga_(2)O_(3) heterojunction interface.Silvaco TCAD simulation further reveals that electric field crowding at the edge of anode for the SBD was greatly depressed by the introduction of SnO film,revealing the potential application of SnO/β-Ga_(2)O_(3) heterojunction in the futureβ-Ga_(2)O_(3)-based power devices.data mining,AI training,and similar technologies,are reserved. 展开更多
关键词 band alignment heterojunction diode(HJD) power semiconductor devices β-gallium oxide(β-Ga_(2)O_(3))
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