Biopolymeric nanocomposites have attracted considerable attention because of their biocompatibility,biodegradability,and unique physicochemical properties.It is essential to manufacture three-dimensional(3D)biocompati...Biopolymeric nanocomposites have attracted considerable attention because of their biocompatibility,biodegradability,and unique physicochemical properties.It is essential to manufacture three-dimensional(3D)biocompatible micro/nanostructures using biopolymeric nanocomposites.Herein,we demonstrate the high-fidelity fabrication of biocompatible 3D features with sub-50 nm resolution using femtosecond laser direct writing(FsLDW)of a biopolymeric nanocomposite composed of egg white and sulfonated graphene(S-graphene).The biopolymer nanocomposite acts as a negative photoresist suitable for water-based lithography.The introduction of S-graphene not only dramatically lowered the laser power threshold but also significantly modulated the morphology of the 3D features constructed by FsLDW.Microstructures with porous,rough,or smooth morphologies were obtained by optimizing the S-graphene concentration and laser scanning speed.The fabricated egg-white/S-graphene microstructures exhibited biocompatibility and environmental degradability.Egg white/S-graphene was also employed to fabricate diffractive gratings with superior optical quality.This study provides a promising method to manufacture biocompatible 3D features with controllable morphology,which has potential applications in biological and photonic fields.展开更多
梳理国外知识隐藏相关文献,揭示知识隐藏的影响因素。基于Web of Science数据库,获取紧密相关的159篇文献,采用内容分析法,从能力、机会、动机、行为等4个方面归纳知识隐藏的研究内容。研究结果发现:知识隐藏行为受到能力因素、机会因...梳理国外知识隐藏相关文献,揭示知识隐藏的影响因素。基于Web of Science数据库,获取紧密相关的159篇文献,采用内容分析法,从能力、机会、动机、行为等4个方面归纳知识隐藏的研究内容。研究结果发现:知识隐藏行为受到能力因素、机会因素、动机因素等的影响,符合COM-B模型的规律;促进知识隐藏的关键环境因素主要包括环境压力、负面关系等;抑制知识隐藏的环境因素主要包括支持性环境、心理保障、积极动机等。研究结果证实COM-B模型可用于分析知识隐藏的行为轨迹,并提出实践启示及未来研究启示。展开更多
基金financially supported by the National Key Research and Development Program of China(Nos.2024YFB4607402 and 2016YFC1100502)the National Natural Science Foundation of China(Nos.51673208 and 61975213)。
文摘Biopolymeric nanocomposites have attracted considerable attention because of their biocompatibility,biodegradability,and unique physicochemical properties.It is essential to manufacture three-dimensional(3D)biocompatible micro/nanostructures using biopolymeric nanocomposites.Herein,we demonstrate the high-fidelity fabrication of biocompatible 3D features with sub-50 nm resolution using femtosecond laser direct writing(FsLDW)of a biopolymeric nanocomposite composed of egg white and sulfonated graphene(S-graphene).The biopolymer nanocomposite acts as a negative photoresist suitable for water-based lithography.The introduction of S-graphene not only dramatically lowered the laser power threshold but also significantly modulated the morphology of the 3D features constructed by FsLDW.Microstructures with porous,rough,or smooth morphologies were obtained by optimizing the S-graphene concentration and laser scanning speed.The fabricated egg-white/S-graphene microstructures exhibited biocompatibility and environmental degradability.Egg white/S-graphene was also employed to fabricate diffractive gratings with superior optical quality.This study provides a promising method to manufacture biocompatible 3D features with controllable morphology,which has potential applications in biological and photonic fields.
文摘梳理国外知识隐藏相关文献,揭示知识隐藏的影响因素。基于Web of Science数据库,获取紧密相关的159篇文献,采用内容分析法,从能力、机会、动机、行为等4个方面归纳知识隐藏的研究内容。研究结果发现:知识隐藏行为受到能力因素、机会因素、动机因素等的影响,符合COM-B模型的规律;促进知识隐藏的关键环境因素主要包括环境压力、负面关系等;抑制知识隐藏的环境因素主要包括支持性环境、心理保障、积极动机等。研究结果证实COM-B模型可用于分析知识隐藏的行为轨迹,并提出实践启示及未来研究启示。
