In agricultural systems, maintenance of soil organic matter has long been recognized as a strategy to reduce soil degradation. Manure amendments and green manures are management practices that can increase some nutrie...In agricultural systems, maintenance of soil organic matter has long been recognized as a strategy to reduce soil degradation. Manure amendments and green manures are management practices that can increase some nutrient contents and improve soil aggregation. We investigated the effects of 28 yr of winter planted green manure on soil aggregate-size distribution and aggregateassociated carbon（C） and nitrogen（N）. The study was a randomized completed block design with three replicates. The treatments included rice-rice-fallow, rice-rice-rape, rice-rice-Chinese milk vetch and rice-rice-ryegrass. The experiment was established in 1982 on a silty light clayey paddy soil derived from Quaternary red clay（classified as Fe-Accumuli-Stagnic Anthrosols） with continuous early and late rice. In 2009, soil samples were collected（0-15 cm depth） from the field treatment plots and separated into water-stable aggregates of different sizes（i.e., 〉5, 2-5, 1-2, 0.5-1, 0.25-0.5 and 〈0.25 mm） by wet sieving. The long-term winter planted green manure significantly increased total C and N, and the formation of the 2-5-mm water-stable aggregate fraction. Compared with rice-rice-rape, rice-rice-Chinese milk vetch and rice-rice-ryegrass, the rice-rice-fallow significantly reduced 2-5-mm water-stable aggregates, with a significant redistribution of aggregates into micro-aggregates. Long-term winter planted green manure obviously improved C/N ratio and macro-aggregate-associated C and N. The highest contribution to soil fertility was from macro-aggregates of 2-5 mm in most cases.展开更多
We investigated the size distribution of water-stable aggregates and the soil carbon, nitrogen and phosphorus concentration over aggregate size fractions based on a long-term （1990-2006） fertilization experiment in ...We investigated the size distribution of water-stable aggregates and the soil carbon, nitrogen and phosphorus concentration over aggregate size fractions based on a long-term （1990-2006） fertilization experiment in a reddish paddy soil. The results showed that the largest water-stable aggregate （WSA） （〉5 mm） and the smallest WSA （〈0.25 mm） took up the first largest proportion （38.3%） and the second largest proportion （23.3%）, respectively. Application of organic materials increased the proportion of the large WSA （〉2 mm） and decreased the proportion of the small WSA （〈1 ram）, resulting in an increase in the mean weight diameter of WSA, whereas application of chemical fertilizer had little effect. Application of organic materials, especially combined with chemical fertilizers, increased total carbon, nitrogen and phosphorus concentrations in all sizes of WSA, and total carbon, nitrogen and phosphorus were prone to concentrate in the large WSA. Further more, application of organic materials improved the supply effectiveness of available phosphorus, whereas had little influence on the labile carbon in WSA. Application of chemical fertilizers improved concentrations of total and available phosphorus in all sizes of WSA, whereas had little influence on total carbon and nitrogen contents. Economical fertilization model maintained the soil fertility when compared with full dose of chemical fertilizers, indicating that using organic materials could reduce chemical fertilizers by about one third.展开更多
Soil aggregate stability,as an important indicator of soil functions,may be affected by seasonal freezing and thawing(SFT)and land use in high cold and wet regions.Therefore,comprehensive understanding the effects of ...Soil aggregate stability,as an important indicator of soil functions,may be affected by seasonal freezing and thawing(SFT)and land use in high cold and wet regions.Therefore,comprehensive understanding the effects of SFT on aggregate stability in orchards during winter and spring is crucial to develop appropriate management strategies that can effectively alleviate the degradation of soil quality to ensure sustainable development of orchard ecosystems.To determine the mechanism of degradation in orchard soil quality,the effects of SFT on the stability of water-stable aggregates were examined in apple-pear orchards(Pyrus ussuriensis var.ovoidea)of four different ages(11,25,40,and 63 yr)on 0 to 5%slopes before freezing and after thawing from October 2015 to June 2016 in Longjing City,Yanbian Prefecture,Northeast China,involving a comparison of planted versus adjacent uncultivated lands(control).Soil samples were collected to investigate water-stable aggregate stability in three incremental soil layers(0–20,20–40 and 40–60 cm).In the same samples,iron oxide,organic matter,and clay contents of the soil were also determined.Results showed that the destructive influences of SFT on water-stable aggregates were more pronounced with the increased orchards ages,and SFT exerted severe effects on water-stable aggregates of older orchards(40 and 63 yr)than juvenile orchards.Undergoing SFT,the soil instability index and the percentage of aggregate destruction increased by mean 0.15 mm and 1.86%,the degree of aggregation decreased by mean 1.32%,and the erosion resistance weakened,which consequently led to aggregate stability decreased.In addition,soil free,amorphous,and crystalline iron oxide as well as soil organic matter and clay contents are all important factors affecting the stability of water-stable aggregates,and their changes in their contents were consistent with those in the stability of water-stable aggregates.The results of this study suggest that long-term planting fruit trees can exacerbate the damaging effects of SFT on aggregate stability and further soil erosion increases and nutrient losses in an orchard,which hider sustainable use of soil and the productivity orchards.展开更多
The distribution of light fraction carbon （LF-C） in the various size classes of aggregates and its relationship to water- stable aggregates as well as the influence of cultivation on the organic components in virgin...The distribution of light fraction carbon （LF-C） in the various size classes of aggregates and its relationship to water- stable aggregates as well as the influence of cultivation on the organic components in virgin and cultivated black soils were studied by wet sieving and density separation methods. The total organic carbon （TOC） and LF-C were significantly higher （P≤ 0.05） in the virgin soils than in the cultivated soils. The LF-C in aggregates of different size classes varied from 0.9 to 2.5 g kg^-1 in the cultivated soils and from 2.5 to 7.1 g kg^-1 in the virgin soils, whereas the ratio of LF-C to TOC varied from 1.9% to 7.3% and from 5.0% to 12.2%, respectively. After being incubated under constant temperature and controlled humidity for three months, the contribution of LF-C to TOC sharply decreased to an amount （1.7%4.5%） close to the level in soils that had been cultivated for 20 to 25 years （1.3%-8.8%）. As a result, the larger water-stable macro-aggregates （especially 〉 1 mm） decreased sharply, indicating that the LF-C pool in virgin soils declined quickly after cultivation, which reduced the water stability of soil aggregates.展开更多
Soil organic matter content in water-stable aggregates（WSA） in the arid ecosystems（abandoned agricultural lands especially） of China is poorly understood. In this study, we examined the WSA sizes and stability, an...Soil organic matter content in water-stable aggregates（WSA） in the arid ecosystems（abandoned agricultural lands especially） of China is poorly understood. In this study, we examined the WSA sizes and stability, and soil organic carbon（OC） and nitrogen（N） contents in agricultural lands with abandonment ages of 0, 3, 12, 20, 30 and 40 years, respectively, in the Minqin Oasis of Northwest China. The total soil OC and N contents at depths of 0–20, 20–40 and 40–60 cm in abandoned agricultural lands were compared to those in cultivated land（the control）. Agricultural land abandonment significantly（P0.25 mm） as the age of agricultural land abandonment increased. The effect of abandonment ages of agricultural lands on MWD was determined by the changes of OC and N accumulation in WSA sizes ＆gt;2 mm. The total OC and N contents presented a stratification phenomenon across soil depths in this arid ecosystem. That is, both of them decreased significantly at depths of 0–20 and 40–60 cm while increased at the depth of 20–40 cm. The WSA sizes ＆lt;0.053 mm had the highest soil OC and N contents（accounting for 51.41%–55.59% and 42.61%–48.94% of their total, respectively）. Soil OC and N contents in microaggregates（sizes 0.053–0.25 mm） were the dominant factors that influenced the variations of total OC and N contents in abandoned agricultural lands. The results of this study suggested that agricultural land abandonment may result in the recovery of WSA stability and the shifting of soil organic matter from the silt＋clay（＆lt;0.053 mm） and microaggregate fractions to the macroaggregate fractions. However, agricultural land abandonment did not increase total soil OC and N contents in the short-term.展开更多
To study the formation process of feldspathic sandstone and sand compound soil in the Mu Us Desert,1∶ 1,1∶ 2 and 1∶ 5 ratios of feldspathic sandstone and sand were mixed to obtain compound soil to plant crops,and a...To study the formation process of feldspathic sandstone and sand compound soil in the Mu Us Desert,1∶ 1,1∶ 2 and 1∶ 5 ratios of feldspathic sandstone and sand were mixed to obtain compound soil to plant crops,and analyze the rules of changes in water-stable aggregates of the compound soil among the 4 years crops growing process. The results showed,before crop planting,the order of mass percent of> 0. 25 mm and 0. 25-2. 00 mm water-stable aggregates in three kinds of compound soil was 1∶ 1 > 1∶ 2 > 1∶ 5,showing that the overall content was low; the mass percent of > 0. 25 mm water-stable aggregates remained at 18. 38%-28. 22%; the mass percent of 0. 25-0. 50 mm,0. 50-2. 00 mm,2. 00-5. 00 mm,and > 5. 00 mm water-stable aggregates was close with each other in each kind of compound soil. After4 years of planting,the mass percent of > 0. 25 mm water-stable aggregates in 1∶ 2 compound soil increased significantly and exceeded other2 kinds of compound soil,reached 32. 34%; the main components of > 0. 25 mm water stable aggregates in 1∶ 1,1∶ 2,and 1∶ 5 compound soil were 0. 25-0. 50 mm( 53. 54%),0. 25-0. 50 mm( 59. 43%),0. 05-2. 00 mm( 52. 16%),aggregates; 0. 25-2. 00 mm aggregates increased significantly in all three kinds of compound soil,with the highest increase in 1∶ 2 compound soil; the organic matters of 1∶ 2 compound soil were significantly correlated with 0. 25-0. 50 mm and 0. 25-2. 00 mm water-stable aggregates. The results showed that the ratio of 0. 25-2. 00 mm aggregates in the three kinds of compound soil was increased after 4 years of crop planting and 1∶ 2 compound soil was most favorable for the formation of aggregates.展开更多
Soil water-stable aggregates (WSAs) are the basic unit of soil constitution and can contribute to remaining the stable soil constitution. The objective of this study was to clarify the distribution and stability of WS...Soil water-stable aggregates (WSAs) are the basic unit of soil constitution and can contribute to remaining the stable soil constitution. The objective of this study was to clarify the distribution and stability of WSAs and the soil organic carbon (SOC), the total nitrogen (TN), and the total phosphorus (TP) concentrations in 0 - 20 cm and 20 - 40 cm soil layers under the different ages of Robinia pseudoacacia plantations. The 20, 25, 40, and 50 years-old Robinia pseudoacacia plantations were selected. Stepwise regression analysis showed that >5 mm and 1 - 2 mm WSAs, SOC concentration in 2 - 5 mm WSAs, and TN and TP concentrations in < 0.25 mm WSAs were dominant independent variables affecting aggregate stability and that SOC in 0.25 - 0.5 mm WSAs, TN in <0.25 mm and 1 - 2 mm WSAs and TP in 2 - 5 mm WSAs were dominant independent variables affecting SOC, TN, and TP concentrations in bulk soils.展开更多
Polycyclic aromatic hydrocarbons (PAHs) pollution in mangroves has drawn much attention, but knowledge of the sorption of PAHs in mangrove sediment is limited. This study investigated the particles and water-stable ag...Polycyclic aromatic hydrocarbons (PAHs) pollution in mangroves has drawn much attention, but knowledge of the sorption of PAHs in mangrove sediment is limited. This study investigated the particles and water-stable aggregates (WSA) of mangrove sediment in Jiulong River Estuary, China, and the characteristics of anthracene adsorption to them. The adsorption of anthracene was strongly influenced by the physicochemical and structural properties of sediment particles and WSA. The main sorbents of mangrove sediment were carbonized particles and clays. The porous structure of carbonized particles made it easy to sequestrate sequester the anthracene, and the aging allowed anthracene to move into deeper sites of the carbonized particles. Clays had high anthracene-fixing capacities, and they included organic matters and formed aggregates. The sorption contents coefficient <i>K<sub>f</sub></i> of anthracene with WSA of different sizes increased in the order 0.063 - 0.25 mm > 0.063 mm > 0.25 - 1.0 mm > 1.0 mm. The order was correlated with which due to the contents and characteristics of organic matters in the aggregates.展开更多
Soil carbohydrates constitute an important component of soil organic matter(SOM),and substantially contribute to the stabilization of soil aggregates.Here,we aimed to investigate the distribution of water-stable aggre...Soil carbohydrates constitute an important component of soil organic matter(SOM),and substantially contribute to the stabilization of soil aggregates.Here,we aimed to investigate the distribution of water-stable aggregates and carbohydrates within water-stable aggregates of soil in tea plantations located in Zhongfeng Township of Mingshan County,Sichuan,which is in southwest China.Samples were collected from tea plantations of different ages(18,25,33,and 55 years old)and an area of abandoned land was used as a control(CK).We also examined correlations between soil carbohydrates fractions and aggregate stability.The results showed that the mean weight diameter(MWD)of soil aggregates in the tea plan-tations was significantly higher than that the control.Furthermore,the soil aggregate stability was significantly enhanced in tea plantations,with the 25-year-old plantation showing the most pronounced effect.Soils in the plantations were also characterized by higher concentrated acid-extracted carbohy-drate content,and carbohydrate content in both surface and sub-surface layers were higher in the 25-year-old plantation.We also detected a significant positive correlation between the carbohydrate con-tent of soil and MWD after tea plantation(P<0.01).Notably,the association between dilute-acid extracted carbohydrate and the aggregate stability showed the highest correlation,indicating this car-bohydrate fraction could be used as an index to reflect changes in soil quality during tea plantation development.We should develop a potential fertilisation programme to maintain SOM-Carbohydrates within aggregates and the appropriate pH for preventing soil structure degradation after 25 years of tea planting.展开更多
In modern construction,Lightweight Aggregate Concrete(LWAC)has been recognized as a vital material of concern because of its unique properties,such as reduced density and improved thermal insulation.Despite the extens...In modern construction,Lightweight Aggregate Concrete(LWAC)has been recognized as a vital material of concern because of its unique properties,such as reduced density and improved thermal insulation.Despite the extensive knowledge regarding its macroscopic properties,there is a wide knowledge gap in understanding the influence of microscale parameters like aggregate porosity and volume ratio on the mechanical response of LWAC.This study aims to bridge this knowledge gap,spurred by the need to enhance the predictability and applicability of LWAC in various construction environments.With the help of advanced numerical methods,including the finite element method and a random circular aggregate model,this study critically evaluates the role played by these microscale factors.We found that an increase in the aggregate porosity from 23.5%to 48.5%leads to a drastic change of weakness from the bonding interface to the aggregate,reducing compressive strength by up to 24.2%and tensile strength by 27.8%.Similarly,the increase in the volume ratio of lightweight aggregate from 25%to 40%leads to a reduction in compressive strength by 13.0%and tensile strength by 9.23%.These results highlight the imperative role of microscale properties on the mechanical properties of LWAC.By supplying precise quantitative details on the effect of porosity and aggregate volume ratio,this research makes significant contributions to construction materials science by providing useful recommendations for the creation and optimization of LWAC with improved performance and sustainability in construction.展开更多
Concrete production often relies on natural aggregates,which can lead to resource depletion and environmental harm.In addition,improper disposal of thermoplastic waste exacerbates ecological problems.Although signific...Concrete production often relies on natural aggregates,which can lead to resource depletion and environmental harm.In addition,improper disposal of thermoplastic waste exacerbates ecological problems.Although significant attention has recently been given to recycling various waste materials into concrete,studies specifically addressing thermoplastic recycled aggregates are still trending.This underscores the need to comprehensively review existing literature,identify research trends,and recognize gaps in understanding the mechanical performance of thermoplastic-based recycled aggregate concrete.Accordingly,this review summarizes recent investigations focused on the mechanical properties of thermoplastic-based recycled aggregate concrete,emphasizing aspects such as compressive strength,tensile behavior,modulus of elasticity,and durability characteristics.The primary aim is to consolidate scattered research findings,identify key parameters influencing mechanical behavior,and propose future research directions.Understanding the influence of recycled thermoplastic aggregates on concrete performance significantly supports sustainable construction practices by reducing dependency on virgin aggregates and mitigating environmental impacts associated with waste disposal.In addition,assessing mechanical performance contributes to confidence in the practical application,encouraging the broader adoption of thermoplastic-based recycled aggregate concrete in construction projects.Through this critical synthesis,the review guides researchers and industry practitioners toward informed decisions on the feasibility and reliability of integrating thermoplastic waste into concrete,thereby promoting sustainable infrastructure development.展开更多
Freeze-thaw cycles(FTCs)have an important effect on soil aggregate stability by altering soil structures,thereby influencing soil wind and water erosion on the eastern Qinghai-Tibet Plateau.However,the effects of FTCs...Freeze-thaw cycles(FTCs)have an important effect on soil aggregate stability by altering soil structures,thereby influencing soil wind and water erosion on the eastern Qinghai-Tibet Plateau.However,the effects of FTCs on the stability of these soils remain unclear.Here,we conducted freeze-thaw simulations in laboratory to investigate the effects of FTCs(0 to 15 cycles)on the wet-and dry-sieving aggregate stability of undisturbed sandy loam from Maqu county,which was treated with different initial soil moisture contents(1%to 25%in increments of 4%)and initial aggregate diameters(<2,2-5,5-10,and 10-15 mm).Results show that soil aggregates with initial diameters larger than 2 mm exhibit higher soil organic carbon contents(1.45%-1.57%)and silt contents(34.63%-35.52%)than those smaller than 2 mm(0.93%and 31.38%,respectively).The stability of both wet-and dry-sieving aggregates increases with larger initial diameters.Increasing initial soil moisture content from 1%to 25%reduces aggregate stability,with reductions of 2.4%-88.0%for wet-sieving aggregates and 2.1%-25.5%for dry-sieving aggregates(>2 mm).With increasing FTCs,wet-sieving aggregate(>2 mm)stability exhibits a fluctuating upward trend,with increases of 79.2%-87.4%after 15 FTCs,while dry-sieving aggregate(>2 mm)stability decreases significantly(5.7%-21.7%)upon the first FTC and remains unchanged thereafter.The stability of both the wet-and dry-sieving aggregates smaller than 2 mm remains unchanged with increasing FTCs(p>0.05).SOC content decreases by 22.3%on average with increasing FTCs from 1 to 15 and shows no significant correlations with wet-and dry-sieving aggregate stability.Higher silt content(r=0.39,p<0.05)and lower sand content(r=-0.38,p<0.05)enhances the wet-sieving aggregate stability of sandy loam.Frequent FTCs tend to improve wet-sieving aggregate stability but reduce dry-sieving aggregate stability in the sandy loam.The findings provide certain guidance for preventing freeze-thaw-induced wind erosion.展开更多
We investigated the effects of fly ash(FA)content on the mechanical properties of recycled aggregate concrete(RAC)and its regeneration potential under freeze and thaw(F-T)cycles.The physical properties of second-gener...We investigated the effects of fly ash(FA)content on the mechanical properties of recycled aggregate concrete(RAC)and its regeneration potential under freeze and thaw(F-T)cycles.The physical properties of second-generation recycled concrete aggregates(RCA)were used to analyze the regeneration potential of RAC after F-T cycles.Scanning electron microscopy was used to study the interfacial transition zone microstructure of RAC after F-T cycles.Results showed that adding 20%FA to RAC significantly enhanced its mechanical properties and frost resistance.Before the F-T cycles,the compressive strength of RAC with 20%FA reached 48.3 MPa,exceeding research strength target of 40 MPa.A majority of second-generation RCA with FA had been verified to attain class Ⅲ,which enabled their practical application in non-structural projects such as backfill trenches and road pavement.However,the second-generation RCA with 20%FA can achieve class Ⅱ,making it ideal for 40 MPa structural concrete.展开更多
Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In ...Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In this study,the effect of land use type on carbon storage and fractionation was quantified based on organic carbon and its ^(13)C abundance at the microscale of soil aggregates and density fractions in Tibetan alpine ecosystems.The sequence of soil aggregate destruction in the land use types of plantation(13.1%)<shrubland(32.7%)<grassland(47.9%)<farmland(61.8%)shows that plantations strengthen the soil structure.Plantation land had a greater contribution of light fraction organic carbon(28.3%)but a lower contribution of mineral-associated organic carbon(40.6%)to the carbon stock compared to farmland(13.5 and 70.3%).Interestingly,plantation land enhanced the aggregational differentiation of organic carbon and ^(13)C in each density fraction,whereas no such phenomenon existed in the soil organic carbon.Carbon isotope analyses revealed that carbon transfer in the plantation land occurred from the light fraction in macroaggregates(–24.9‰)to the mineral-associated fraction in microaggregates(–19.9‰).When compared to the other three land use types,the low transferability of carbon in aggregates and density fractions in plantation land provides a stable carbon pool for the Tibetan Plateau.This study shows that plantations can mitigate global climate change by slowing carbon transfer and increasing carbon storage at the microscale of aggregates and density fractions in alpine regions.展开更多
Enhancing soil organic carbon(SOC)stocks is a key aspect of modern agriculture,but whether this can be achieved by incorporating legume green manure crops in cereal production to substitute synthetic N fertilizers is ...Enhancing soil organic carbon(SOC)stocks is a key aspect of modern agriculture,but whether this can be achieved by incorporating legume green manure crops in cereal production to substitute synthetic N fertilizers is unknown.This study used a six-year(2017-2022)field study to explore the impacts of intercropping green manure with maize and reducing nitrogen fertilization on SOC stocks,while specifically focusing on the relationship between aggregate composition and carbon sequestration.Maize intercropped with common vetch(M/V),maize intercropped with rapeseed(M/R),and sole maize(M),were each tested at conventional(N2,360 kg ha^(-1))and reduced(N1,270 kg ha^(-1),25% reduced)N application rates.Soil was sampled in 2020,2021,and 2022.Compared with sole maize,intercropping with green manure(M/V and M/R)significantly increased SOC stocks which compensated for any negative effect due to the 25% reduction in N application.Based on 3-year averages,intercropping with M/V and M/R increased the SOC content compared to sole maize(M)by 12.1 and 9.1%,respectively,with intercropping further mitigating the negative impact of reduced nitrogen application.There was no significant difference between M/V and M/R.The SOC content at N1 was reduced by 9.3-10.5%compared to that at N2 in sole maize,but the differences in SOC stocks between N1 and N2 were not significant in the intercropping patterns(M/V and M/R).The intercropped M/V and M/R showed 20.9 and 16.3% higher SOC contents compared to sole maize at N1,with no differences at N2.Intercropping green manure led to a 5.3% greater SOC in the 0-20 cm depth soil in 2022 compared to that in 2020,due to the cumulative effect of two years of green manure intercropping.Intercropping green manure(M/V and M/R)increased the proportion of macroaggregates(>0.25 mm)and aggregate stability while reducing the proportion of microaggregates compared to sole maize under the N1 application.Structural equation modeling indicated that cropping patterns and nitrogen application levels mainly affect SOC indirectly by regulating the composition of macroaggregates and aggregate organic carbon(AOC).Correlation analysis further revealed that the composition of macroaggregates is significantly and positively correlated with the SOC content(R^(2)=0.64).In addition,intercropping green manure can maintain high crop yields by increasing SOC under reduced chemical nitrogen application.The results of this study show that intercropping green manure with grain crops can be a viable measure for increasing SOC sinks and maize productivity by optimizing the aggregate composition with reduced N application in the Hexi Oasis Irrigation Area.展开更多
Crushing waste coral concrete into recycled aggregates to create recycled coral aggregate concrete(RCAC)contributes to sustainable construction development on offshore islands and reefs.To investigate the impact of re...Crushing waste coral concrete into recycled aggregates to create recycled coral aggregate concrete(RCAC)contributes to sustainable construction development on offshore islands and reefs.To investigate the impact of recycled coral aggregate on concrete properties,this study performed a comprehensive analysis of the physical properties of recycled coral aggregate and the basic mechanical properties and microstructure of RCAC.The test results indicate that,compared to coral debris,the crushing index of recycled coral aggregate was reduced by 9.4%,while porosity decreased by 33.5%.Furthermore,RCAC retained the early strength characteristics of coral concrete,with compressive strength and flexural strength exhibiting a notable increase as the water-cement ratio decreased.Under identical conditions,the compressive strength and flexural strength of RCAC were 12.7% and 2.5% higher than coral concrete's,respectively,with porosity correspondingly reduced from 3.13% to 5.11%.This enhancement could be attributed to the new mortar filling the recycled coral aggregate.Scanning electron microscopy(SEM)analysis revealed three distinct interface transition zones within RCAC,with the‘new mortar-old mortar’interface identified as the weakest.The above findings provided a reference for the sustainable use of coral concrete in constructing offshore islands.展开更多
The practical application of lithium metal batteries(LMBs)requires electrolytes that simultaneously ensure high safety and interfacial stability.Although locally concentrated ionic liquid electrolytes(LCILEs)exhibit e...The practical application of lithium metal batteries(LMBs)requires electrolytes that simultaneously ensure high safety and interfacial stability.Although locally concentrated ionic liquid electrolytes(LCILEs)exhibit exceptional electrochemical stability and compatibility with electrode electrolyte interfaces(EEIs),two major challenges persist:(i)safety risks caused by excessive low-flash-point diluents,and(ii)insufficient understanding of how diluents modulate solvation structures.Herein,we introduce a low-diluent-content LCILE system composed of lithium bis(fluorosulfonyl)imide(LiFSI)salt,N-methyl-N-propyl-pyrrolidinium bis(fluorosulfonyl)imide(Pyr_(13)FSI)ionic liquid,and trifluoromethanesulfonate(TFS)diluent.The TFS diluent strengthens ion-ion interactions by lowering the dielectric constant of the electrolyte,resulting in the formation of a unique nanometric anion aggregates(N-AGGs)reinforced solvation structure.These large anionic clusters exhibit accelerated redox decomposition kinetics,facilitating the rapid formation of a thin,dense,and low-impedance EEI.Consequently,the Li/LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)coin cell achieves 87.8%capacity retention over 300 cycles at 4.3 V,while a practical 1.4 Ah Li/NCM622 pouch cell retains 84.5%capacity after 80 cycles at 4.5 V.Furthermore,the electrolyte demonstrates exceptional safety,and 2 Ah Li metal pouch cells successfully pass rigorous nail penetration tests without any ignition or explosion.This work not only provides a design strategy for intrinsically safe and high-performance electrolytes but also highlights the critical role of anion cluster decomposition kinetics in shaping EEI formation.展开更多
Aims Reforestation can enhance soil carbon(C)stability and promote soil C accumulation.Experimental results are,however,highly variable,and the efficacy of reforestation in enhancing soil C stability is still in debat...Aims Reforestation can enhance soil carbon(C)stability and promote soil C accumulation.Experimental results are,however,highly variable,and the efficacy of reforestation in enhancing soil C stability is still in debate.Consequently,it remains unclear how the different soil C pools respond to reforestation in forest ecosystems.Methods The response of different soil C fractions to reforestation was examined in five subtropical forests,including the plantations of Eucalyptus urophylla(EU),Acacia crassicarpa(AC),Castanopsis hystrix(CH)and 10 species mixed(MX),and a naturally recovered shrubland(NS).Soil labile C fractions(readily oxidized organic C by KMnO4:ROC;dissolved organic C:DOC),distribution of aggregate-size classes and aggregate-associated C from different soil layers(0–10,10–20,20–40 and 40–60 cm)were evaluated.Important Findings We found that reforestation and forest type did not affect ROC concentration,yet the highest DOC concentration was detected in NS at four soil layers.Aggregate C concentration was the highest in all aggregate-size classes of CH at 0–10 cm depth.In addition,forest type did not alter the proportion of soil water-stable aggregates at four soil layers.However,soil depths significantly affected the distribution of soil aggregates with>0.25 mm aggregates dominating in the topsoils(0–20 cm),but 0.053–2 mm aggregates being dominant in the deep soils(20–60 cm).These results indicate that reforestation and forest type affected soil DOC(0–60 cm)and aggregate C(0–10 cm).Furthermore,soil DOC and aggregate C were more susceptive to reforestation than ROC.The findings suggest that plantations reduce soil DOC concentration,highlighting that C leaching loss may decrease compared with natural recovery.Moreover,C.hystrix plantation may enhance soil C stability by physical protection in topsoil.This study provides valuable information on tree species selection for reforestation concerning soil C sequestration in southern subtropical China.展开更多
The accumulation of soil organic carbon(SOC)and total nitrogen(TN)is easily accomplished by returning crop straw,which strongly affects the formation and pore structure of aggregates,especially in black soil.We return...The accumulation of soil organic carbon(SOC)and total nitrogen(TN)is easily accomplished by returning crop straw,which strongly affects the formation and pore structure of aggregates,especially in black soil.We returned maize straw at different rates(6,000,9,000,12,000 and 15,000 kg ha^(-1))for nine years to investigate its influence on the SOC and TN contents in the SOC fractions of aggregates by combining size and density fractionation.Their subsequent influences on pore morphology and size distribution characteristics were examined using X-ray microcomputed tomography scanning(μCT).The results showed that returning straw significantly increased the contents of C and N in the SOC fractions of aggregates,especially at the return rates of 12,000 and 15,000 kg ha^(-1),which in turn promoted aggregate formation and stability,and ultimately amended pore structure.The pore size>100μm,porosity(>2μm),and morphological characteristics(anisotropy,circularity,connectivity and fractal dimension)significantly increased,but the total number of pores significantly decreased(P<0.05).Our results indicated that the amendment of the pore morphology and size distribution of soil aggregates was primarily controlled by the higher contents of C and N in the density fractions of aggregates,rather than in the aggregate sizes.Furthermore,this pore network reconfiguration favored the storage of C and N simultaneously.The findings of this study offer valuable new insights into the relationships between C and N storage and the pore characteristics in soil aggregates under straw return.展开更多
基金funded by the Special Fund for AgroScientific Research in the Public Interest of China (20110300508, 201203030)supported in partial by the Key Technologies R&D Program of China during the 12th Five-Year Plan period (2012BAD05B05-3, 2013BAD07B11)the International Plant Nutrition Institute, Canada (IPNI China Program: Hunan-17)
文摘In agricultural systems, maintenance of soil organic matter has long been recognized as a strategy to reduce soil degradation. Manure amendments and green manures are management practices that can increase some nutrient contents and improve soil aggregation. We investigated the effects of 28 yr of winter planted green manure on soil aggregate-size distribution and aggregateassociated carbon（C） and nitrogen（N）. The study was a randomized completed block design with three replicates. The treatments included rice-rice-fallow, rice-rice-rape, rice-rice-Chinese milk vetch and rice-rice-ryegrass. The experiment was established in 1982 on a silty light clayey paddy soil derived from Quaternary red clay（classified as Fe-Accumuli-Stagnic Anthrosols） with continuous early and late rice. In 2009, soil samples were collected（0-15 cm depth） from the field treatment plots and separated into water-stable aggregates of different sizes（i.e., 〉5, 2-5, 1-2, 0.5-1, 0.25-0.5 and 〈0.25 mm） by wet sieving. The long-term winter planted green manure significantly increased total C and N, and the formation of the 2-5-mm water-stable aggregate fraction. Compared with rice-rice-rape, rice-rice-Chinese milk vetch and rice-rice-ryegrass, the rice-rice-fallow significantly reduced 2-5-mm water-stable aggregates, with a significant redistribution of aggregates into micro-aggregates. Long-term winter planted green manure obviously improved C/N ratio and macro-aggregate-associated C and N. The highest contribution to soil fertility was from macro-aggregates of 2-5 mm in most cases.
基金funded by the Knowledge Innovativation Program of the Chinese Academy of Sciences (KZCX2-YW-423)the National Basic Research Program of China (2005CB121106)
文摘We investigated the size distribution of water-stable aggregates and the soil carbon, nitrogen and phosphorus concentration over aggregate size fractions based on a long-term （1990-2006） fertilization experiment in a reddish paddy soil. The results showed that the largest water-stable aggregate （WSA） （〉5 mm） and the smallest WSA （〈0.25 mm） took up the first largest proportion （38.3%） and the second largest proportion （23.3%）, respectively. Application of organic materials increased the proportion of the large WSA （〉2 mm） and decreased the proportion of the small WSA （〈1 ram）, resulting in an increase in the mean weight diameter of WSA, whereas application of chemical fertilizer had little effect. Application of organic materials, especially combined with chemical fertilizers, increased total carbon, nitrogen and phosphorus concentrations in all sizes of WSA, and total carbon, nitrogen and phosphorus were prone to concentrate in the large WSA. Further more, application of organic materials improved the supply effectiveness of available phosphorus, whereas had little influence on the labile carbon in WSA. Application of chemical fertilizers improved concentrations of total and available phosphorus in all sizes of WSA, whereas had little influence on total carbon and nitrogen contents. Economical fertilization model maintained the soil fertility when compared with full dose of chemical fertilizers, indicating that using organic materials could reduce chemical fertilizers by about one third.
基金Under the auspices of National Natural Science Foundation of China(No.31460117,41877024)。
文摘Soil aggregate stability,as an important indicator of soil functions,may be affected by seasonal freezing and thawing(SFT)and land use in high cold and wet regions.Therefore,comprehensive understanding the effects of SFT on aggregate stability in orchards during winter and spring is crucial to develop appropriate management strategies that can effectively alleviate the degradation of soil quality to ensure sustainable development of orchard ecosystems.To determine the mechanism of degradation in orchard soil quality,the effects of SFT on the stability of water-stable aggregates were examined in apple-pear orchards(Pyrus ussuriensis var.ovoidea)of four different ages(11,25,40,and 63 yr)on 0 to 5%slopes before freezing and after thawing from October 2015 to June 2016 in Longjing City,Yanbian Prefecture,Northeast China,involving a comparison of planted versus adjacent uncultivated lands(control).Soil samples were collected to investigate water-stable aggregate stability in three incremental soil layers(0–20,20–40 and 40–60 cm).In the same samples,iron oxide,organic matter,and clay contents of the soil were also determined.Results showed that the destructive influences of SFT on water-stable aggregates were more pronounced with the increased orchards ages,and SFT exerted severe effects on water-stable aggregates of older orchards(40 and 63 yr)than juvenile orchards.Undergoing SFT,the soil instability index and the percentage of aggregate destruction increased by mean 0.15 mm and 1.86%,the degree of aggregation decreased by mean 1.32%,and the erosion resistance weakened,which consequently led to aggregate stability decreased.In addition,soil free,amorphous,and crystalline iron oxide as well as soil organic matter and clay contents are all important factors affecting the stability of water-stable aggregates,and their changes in their contents were consistent with those in the stability of water-stable aggregates.The results of this study suggest that long-term planting fruit trees can exacerbate the damaging effects of SFT on aggregate stability and further soil erosion increases and nutrient losses in an orchard,which hider sustainable use of soil and the productivity orchards.
基金Project supported by the State Key Basic Research Development Program (No. G1999011804) the Knowledge Innovation Program of the Chinese Academy of Sciences (No. KZCXZ-SW-416).
文摘The distribution of light fraction carbon （LF-C） in the various size classes of aggregates and its relationship to water- stable aggregates as well as the influence of cultivation on the organic components in virgin and cultivated black soils were studied by wet sieving and density separation methods. The total organic carbon （TOC） and LF-C were significantly higher （P≤ 0.05） in the virgin soils than in the cultivated soils. The LF-C in aggregates of different size classes varied from 0.9 to 2.5 g kg^-1 in the cultivated soils and from 2.5 to 7.1 g kg^-1 in the virgin soils, whereas the ratio of LF-C to TOC varied from 1.9% to 7.3% and from 5.0% to 12.2%, respectively. After being incubated under constant temperature and controlled humidity for three months, the contribution of LF-C to TOC sharply decreased to an amount （1.7%4.5%） close to the level in soils that had been cultivated for 20 to 25 years （1.3%-8.8%）. As a result, the larger water-stable macro-aggregates （especially 〉 1 mm） decreased sharply, indicating that the LF-C pool in virgin soils declined quickly after cultivation, which reduced the water stability of soil aggregates.
基金funded by the Science & Technology Pillar Program of Gansu Province (1104FKCH162, 1204FKCH164, 1304FKCH102)the National Natural Science Foundation of China (31560170)
文摘Soil organic matter content in water-stable aggregates（WSA） in the arid ecosystems（abandoned agricultural lands especially） of China is poorly understood. In this study, we examined the WSA sizes and stability, and soil organic carbon（OC） and nitrogen（N） contents in agricultural lands with abandonment ages of 0, 3, 12, 20, 30 and 40 years, respectively, in the Minqin Oasis of Northwest China. The total soil OC and N contents at depths of 0–20, 20–40 and 40–60 cm in abandoned agricultural lands were compared to those in cultivated land（the control）. Agricultural land abandonment significantly（P0.25 mm） as the age of agricultural land abandonment increased. The effect of abandonment ages of agricultural lands on MWD was determined by the changes of OC and N accumulation in WSA sizes ＆gt;2 mm. The total OC and N contents presented a stratification phenomenon across soil depths in this arid ecosystem. That is, both of them decreased significantly at depths of 0–20 and 40–60 cm while increased at the depth of 20–40 cm. The WSA sizes ＆lt;0.053 mm had the highest soil OC and N contents（accounting for 51.41%–55.59% and 42.61%–48.94% of their total, respectively）. Soil OC and N contents in microaggregates（sizes 0.053–0.25 mm） were the dominant factors that influenced the variations of total OC and N contents in abandoned agricultural lands. The results of this study suggested that agricultural land abandonment may result in the recovery of WSA stability and the shifting of soil organic matter from the silt＋clay（＆lt;0.053 mm） and microaggregate fractions to the macroaggregate fractions. However, agricultural land abandonment did not increase total soil OC and N contents in the short-term.
基金Supported by Special Project of Public Welfare Industry of Ministry of Land and Resources(201411008)
文摘To study the formation process of feldspathic sandstone and sand compound soil in the Mu Us Desert,1∶ 1,1∶ 2 and 1∶ 5 ratios of feldspathic sandstone and sand were mixed to obtain compound soil to plant crops,and analyze the rules of changes in water-stable aggregates of the compound soil among the 4 years crops growing process. The results showed,before crop planting,the order of mass percent of> 0. 25 mm and 0. 25-2. 00 mm water-stable aggregates in three kinds of compound soil was 1∶ 1 > 1∶ 2 > 1∶ 5,showing that the overall content was low; the mass percent of > 0. 25 mm water-stable aggregates remained at 18. 38%-28. 22%; the mass percent of 0. 25-0. 50 mm,0. 50-2. 00 mm,2. 00-5. 00 mm,and > 5. 00 mm water-stable aggregates was close with each other in each kind of compound soil. After4 years of planting,the mass percent of > 0. 25 mm water-stable aggregates in 1∶ 2 compound soil increased significantly and exceeded other2 kinds of compound soil,reached 32. 34%; the main components of > 0. 25 mm water stable aggregates in 1∶ 1,1∶ 2,and 1∶ 5 compound soil were 0. 25-0. 50 mm( 53. 54%),0. 25-0. 50 mm( 59. 43%),0. 05-2. 00 mm( 52. 16%),aggregates; 0. 25-2. 00 mm aggregates increased significantly in all three kinds of compound soil,with the highest increase in 1∶ 2 compound soil; the organic matters of 1∶ 2 compound soil were significantly correlated with 0. 25-0. 50 mm and 0. 25-2. 00 mm water-stable aggregates. The results showed that the ratio of 0. 25-2. 00 mm aggregates in the three kinds of compound soil was increased after 4 years of crop planting and 1∶ 2 compound soil was most favorable for the formation of aggregates.
文摘Soil water-stable aggregates (WSAs) are the basic unit of soil constitution and can contribute to remaining the stable soil constitution. The objective of this study was to clarify the distribution and stability of WSAs and the soil organic carbon (SOC), the total nitrogen (TN), and the total phosphorus (TP) concentrations in 0 - 20 cm and 20 - 40 cm soil layers under the different ages of Robinia pseudoacacia plantations. The 20, 25, 40, and 50 years-old Robinia pseudoacacia plantations were selected. Stepwise regression analysis showed that >5 mm and 1 - 2 mm WSAs, SOC concentration in 2 - 5 mm WSAs, and TN and TP concentrations in < 0.25 mm WSAs were dominant independent variables affecting aggregate stability and that SOC in 0.25 - 0.5 mm WSAs, TN in <0.25 mm and 1 - 2 mm WSAs and TP in 2 - 5 mm WSAs were dominant independent variables affecting SOC, TN, and TP concentrations in bulk soils.
文摘Polycyclic aromatic hydrocarbons (PAHs) pollution in mangroves has drawn much attention, but knowledge of the sorption of PAHs in mangrove sediment is limited. This study investigated the particles and water-stable aggregates (WSA) of mangrove sediment in Jiulong River Estuary, China, and the characteristics of anthracene adsorption to them. The adsorption of anthracene was strongly influenced by the physicochemical and structural properties of sediment particles and WSA. The main sorbents of mangrove sediment were carbonized particles and clays. The porous structure of carbonized particles made it easy to sequestrate sequester the anthracene, and the aging allowed anthracene to move into deeper sites of the carbonized particles. Clays had high anthracene-fixing capacities, and they included organic matters and formed aggregates. The sorption contents coefficient <i>K<sub>f</sub></i> of anthracene with WSA of different sizes increased in the order 0.063 - 0.25 mm > 0.063 mm > 0.25 - 1.0 mm > 1.0 mm. The order was correlated with which due to the contents and characteristics of organic matters in the aggregates.
基金support from the Key R&D Project of Sichuan Province(Grant No.2019YFS0463)for this research.
文摘Soil carbohydrates constitute an important component of soil organic matter(SOM),and substantially contribute to the stabilization of soil aggregates.Here,we aimed to investigate the distribution of water-stable aggregates and carbohydrates within water-stable aggregates of soil in tea plantations located in Zhongfeng Township of Mingshan County,Sichuan,which is in southwest China.Samples were collected from tea plantations of different ages(18,25,33,and 55 years old)and an area of abandoned land was used as a control(CK).We also examined correlations between soil carbohydrates fractions and aggregate stability.The results showed that the mean weight diameter(MWD)of soil aggregates in the tea plan-tations was significantly higher than that the control.Furthermore,the soil aggregate stability was significantly enhanced in tea plantations,with the 25-year-old plantation showing the most pronounced effect.Soils in the plantations were also characterized by higher concentrated acid-extracted carbohy-drate content,and carbohydrate content in both surface and sub-surface layers were higher in the 25-year-old plantation.We also detected a significant positive correlation between the carbohydrate con-tent of soil and MWD after tea plantation(P<0.01).Notably,the association between dilute-acid extracted carbohydrate and the aggregate stability showed the highest correlation,indicating this car-bohydrate fraction could be used as an index to reflect changes in soil quality during tea plantation development.We should develop a potential fertilisation programme to maintain SOM-Carbohydrates within aggregates and the appropriate pH for preventing soil structure degradation after 25 years of tea planting.
基金supported by National Science Foundation of China(10972015,11172015)the Beijing Natural Science Foundation(8162008).
文摘In modern construction,Lightweight Aggregate Concrete(LWAC)has been recognized as a vital material of concern because of its unique properties,such as reduced density and improved thermal insulation.Despite the extensive knowledge regarding its macroscopic properties,there is a wide knowledge gap in understanding the influence of microscale parameters like aggregate porosity and volume ratio on the mechanical response of LWAC.This study aims to bridge this knowledge gap,spurred by the need to enhance the predictability and applicability of LWAC in various construction environments.With the help of advanced numerical methods,including the finite element method and a random circular aggregate model,this study critically evaluates the role played by these microscale factors.We found that an increase in the aggregate porosity from 23.5%to 48.5%leads to a drastic change of weakness from the bonding interface to the aggregate,reducing compressive strength by up to 24.2%and tensile strength by 27.8%.Similarly,the increase in the volume ratio of lightweight aggregate from 25%to 40%leads to a reduction in compressive strength by 13.0%and tensile strength by 9.23%.These results highlight the imperative role of microscale properties on the mechanical properties of LWAC.By supplying precise quantitative details on the effect of porosity and aggregate volume ratio,this research makes significant contributions to construction materials science by providing useful recommendations for the creation and optimization of LWAC with improved performance and sustainability in construction.
文摘Concrete production often relies on natural aggregates,which can lead to resource depletion and environmental harm.In addition,improper disposal of thermoplastic waste exacerbates ecological problems.Although significant attention has recently been given to recycling various waste materials into concrete,studies specifically addressing thermoplastic recycled aggregates are still trending.This underscores the need to comprehensively review existing literature,identify research trends,and recognize gaps in understanding the mechanical performance of thermoplastic-based recycled aggregate concrete.Accordingly,this review summarizes recent investigations focused on the mechanical properties of thermoplastic-based recycled aggregate concrete,emphasizing aspects such as compressive strength,tensile behavior,modulus of elasticity,and durability characteristics.The primary aim is to consolidate scattered research findings,identify key parameters influencing mechanical behavior,and propose future research directions.Understanding the influence of recycled thermoplastic aggregates on concrete performance significantly supports sustainable construction practices by reducing dependency on virgin aggregates and mitigating environmental impacts associated with waste disposal.In addition,assessing mechanical performance contributes to confidence in the practical application,encouraging the broader adoption of thermoplastic-based recycled aggregate concrete in construction projects.Through this critical synthesis,the review guides researchers and industry practitioners toward informed decisions on the feasibility and reliability of integrating thermoplastic waste into concrete,thereby promoting sustainable infrastructure development.
基金supported by National Natural Science Foundation of China(Grant No.42201080)Young Scientific and Technological Talents Program of Shaanxi Province(Grant No.2025ZC-KJXX-57)Special Scientific Research Program of the Shaanxi Provincial Department of Education(Grant No.21JK0967)。
文摘Freeze-thaw cycles(FTCs)have an important effect on soil aggregate stability by altering soil structures,thereby influencing soil wind and water erosion on the eastern Qinghai-Tibet Plateau.However,the effects of FTCs on the stability of these soils remain unclear.Here,we conducted freeze-thaw simulations in laboratory to investigate the effects of FTCs(0 to 15 cycles)on the wet-and dry-sieving aggregate stability of undisturbed sandy loam from Maqu county,which was treated with different initial soil moisture contents(1%to 25%in increments of 4%)and initial aggregate diameters(<2,2-5,5-10,and 10-15 mm).Results show that soil aggregates with initial diameters larger than 2 mm exhibit higher soil organic carbon contents(1.45%-1.57%)and silt contents(34.63%-35.52%)than those smaller than 2 mm(0.93%and 31.38%,respectively).The stability of both wet-and dry-sieving aggregates increases with larger initial diameters.Increasing initial soil moisture content from 1%to 25%reduces aggregate stability,with reductions of 2.4%-88.0%for wet-sieving aggregates and 2.1%-25.5%for dry-sieving aggregates(>2 mm).With increasing FTCs,wet-sieving aggregate(>2 mm)stability exhibits a fluctuating upward trend,with increases of 79.2%-87.4%after 15 FTCs,while dry-sieving aggregate(>2 mm)stability decreases significantly(5.7%-21.7%)upon the first FTC and remains unchanged thereafter.The stability of both the wet-and dry-sieving aggregates smaller than 2 mm remains unchanged with increasing FTCs(p>0.05).SOC content decreases by 22.3%on average with increasing FTCs from 1 to 15 and shows no significant correlations with wet-and dry-sieving aggregate stability.Higher silt content(r=0.39,p<0.05)and lower sand content(r=-0.38,p<0.05)enhances the wet-sieving aggregate stability of sandy loam.Frequent FTCs tend to improve wet-sieving aggregate stability but reduce dry-sieving aggregate stability in the sandy loam.The findings provide certain guidance for preventing freeze-thaw-induced wind erosion.
基金Funded by the Natural Science Foundation of Jiangsu Province(No.BK20220626)the National Natural Science Foundation of China(No.52078068)+2 种基金Science and Technology Innovation Foundation of NIT(No.KCTD006)Jiangsu Marine Structure Service Performance Improvement Engineering Research CenterKey Laboratory of Jiangsu"Marine Floating Wind Power Technology and Equipment"。
文摘We investigated the effects of fly ash(FA)content on the mechanical properties of recycled aggregate concrete(RAC)and its regeneration potential under freeze and thaw(F-T)cycles.The physical properties of second-generation recycled concrete aggregates(RCA)were used to analyze the regeneration potential of RAC after F-T cycles.Scanning electron microscopy was used to study the interfacial transition zone microstructure of RAC after F-T cycles.Results showed that adding 20%FA to RAC significantly enhanced its mechanical properties and frost resistance.Before the F-T cycles,the compressive strength of RAC with 20%FA reached 48.3 MPa,exceeding research strength target of 40 MPa.A majority of second-generation RCA with FA had been verified to attain class Ⅲ,which enabled their practical application in non-structural projects such as backfill trenches and road pavement.However,the second-generation RCA with 20%FA can achieve class Ⅱ,making it ideal for 40 MPa structural concrete.
基金financially supported by the National Natural Science Foundation of China (42477044,32171648 and U23A2017)the Hubei Provincial Science and Technology Program,China (2025AFD451 and 2022CFB030)。
文摘Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In this study,the effect of land use type on carbon storage and fractionation was quantified based on organic carbon and its ^(13)C abundance at the microscale of soil aggregates and density fractions in Tibetan alpine ecosystems.The sequence of soil aggregate destruction in the land use types of plantation(13.1%)<shrubland(32.7%)<grassland(47.9%)<farmland(61.8%)shows that plantations strengthen the soil structure.Plantation land had a greater contribution of light fraction organic carbon(28.3%)but a lower contribution of mineral-associated organic carbon(40.6%)to the carbon stock compared to farmland(13.5 and 70.3%).Interestingly,plantation land enhanced the aggregational differentiation of organic carbon and ^(13)C in each density fraction,whereas no such phenomenon existed in the soil organic carbon.Carbon isotope analyses revealed that carbon transfer in the plantation land occurred from the light fraction in macroaggregates(–24.9‰)to the mineral-associated fraction in microaggregates(–19.9‰).When compared to the other three land use types,the low transferability of carbon in aggregates and density fractions in plantation land provides a stable carbon pool for the Tibetan Plateau.This study shows that plantations can mitigate global climate change by slowing carbon transfer and increasing carbon storage at the microscale of aggregates and density fractions in alpine regions.
基金supported by the National Key Research and Development Program of China(2021YFD1700204)the National Natural Science Foundation of China(U21A20218 and 32372238)+1 种基金the Modern Agro-Industry Technology Research System of China(CARS-22-G-12)the“Innovation Star”Program of Graduate Students in 2025 of Gansu Province,China(2025CXZX-749)。
文摘Enhancing soil organic carbon(SOC)stocks is a key aspect of modern agriculture,but whether this can be achieved by incorporating legume green manure crops in cereal production to substitute synthetic N fertilizers is unknown.This study used a six-year(2017-2022)field study to explore the impacts of intercropping green manure with maize and reducing nitrogen fertilization on SOC stocks,while specifically focusing on the relationship between aggregate composition and carbon sequestration.Maize intercropped with common vetch(M/V),maize intercropped with rapeseed(M/R),and sole maize(M),were each tested at conventional(N2,360 kg ha^(-1))and reduced(N1,270 kg ha^(-1),25% reduced)N application rates.Soil was sampled in 2020,2021,and 2022.Compared with sole maize,intercropping with green manure(M/V and M/R)significantly increased SOC stocks which compensated for any negative effect due to the 25% reduction in N application.Based on 3-year averages,intercropping with M/V and M/R increased the SOC content compared to sole maize(M)by 12.1 and 9.1%,respectively,with intercropping further mitigating the negative impact of reduced nitrogen application.There was no significant difference between M/V and M/R.The SOC content at N1 was reduced by 9.3-10.5%compared to that at N2 in sole maize,but the differences in SOC stocks between N1 and N2 were not significant in the intercropping patterns(M/V and M/R).The intercropped M/V and M/R showed 20.9 and 16.3% higher SOC contents compared to sole maize at N1,with no differences at N2.Intercropping green manure led to a 5.3% greater SOC in the 0-20 cm depth soil in 2022 compared to that in 2020,due to the cumulative effect of two years of green manure intercropping.Intercropping green manure(M/V and M/R)increased the proportion of macroaggregates(>0.25 mm)and aggregate stability while reducing the proportion of microaggregates compared to sole maize under the N1 application.Structural equation modeling indicated that cropping patterns and nitrogen application levels mainly affect SOC indirectly by regulating the composition of macroaggregates and aggregate organic carbon(AOC).Correlation analysis further revealed that the composition of macroaggregates is significantly and positively correlated with the SOC content(R^(2)=0.64).In addition,intercropping green manure can maintain high crop yields by increasing SOC under reduced chemical nitrogen application.The results of this study show that intercropping green manure with grain crops can be a viable measure for increasing SOC sinks and maize productivity by optimizing the aggregate composition with reduced N application in the Hexi Oasis Irrigation Area.
基金Funded by Natural Science Foundation of Guangxi(No.2025GXNSFBA069565)Guangxi Science and Technology Program(No.AD25069101)Guangxi Bagui Scholars Fund。
文摘Crushing waste coral concrete into recycled aggregates to create recycled coral aggregate concrete(RCAC)contributes to sustainable construction development on offshore islands and reefs.To investigate the impact of recycled coral aggregate on concrete properties,this study performed a comprehensive analysis of the physical properties of recycled coral aggregate and the basic mechanical properties and microstructure of RCAC.The test results indicate that,compared to coral debris,the crushing index of recycled coral aggregate was reduced by 9.4%,while porosity decreased by 33.5%.Furthermore,RCAC retained the early strength characteristics of coral concrete,with compressive strength and flexural strength exhibiting a notable increase as the water-cement ratio decreased.Under identical conditions,the compressive strength and flexural strength of RCAC were 12.7% and 2.5% higher than coral concrete's,respectively,with porosity correspondingly reduced from 3.13% to 5.11%.This enhancement could be attributed to the new mortar filling the recycled coral aggregate.Scanning electron microscopy(SEM)analysis revealed three distinct interface transition zones within RCAC,with the‘new mortar-old mortar’interface identified as the weakest.The above findings provided a reference for the sustainable use of coral concrete in constructing offshore islands.
基金supported by the National Key R&D Program of China(Grant No.2022YFE0207300)the National Natural Science Foundation of China(Grant Nos.22179142 and 22075314)+1 种基金Jiangsu Provincial Science and Technology Program(Grant No.BG 2024020).XPSWAXS and TOF-SIMS characterizations were supported by Nano-X(Vacuum Interconnected Nanotech Workstation,Suzhou Institute of Nano-Tech and Nano-Bionics,Chinese Academy of Sciences(SINANO),Suzhou 215123,China)。
文摘The practical application of lithium metal batteries(LMBs)requires electrolytes that simultaneously ensure high safety and interfacial stability.Although locally concentrated ionic liquid electrolytes(LCILEs)exhibit exceptional electrochemical stability and compatibility with electrode electrolyte interfaces(EEIs),two major challenges persist:(i)safety risks caused by excessive low-flash-point diluents,and(ii)insufficient understanding of how diluents modulate solvation structures.Herein,we introduce a low-diluent-content LCILE system composed of lithium bis(fluorosulfonyl)imide(LiFSI)salt,N-methyl-N-propyl-pyrrolidinium bis(fluorosulfonyl)imide(Pyr_(13)FSI)ionic liquid,and trifluoromethanesulfonate(TFS)diluent.The TFS diluent strengthens ion-ion interactions by lowering the dielectric constant of the electrolyte,resulting in the formation of a unique nanometric anion aggregates(N-AGGs)reinforced solvation structure.These large anionic clusters exhibit accelerated redox decomposition kinetics,facilitating the rapid formation of a thin,dense,and low-impedance EEI.Consequently,the Li/LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)coin cell achieves 87.8%capacity retention over 300 cycles at 4.3 V,while a practical 1.4 Ah Li/NCM622 pouch cell retains 84.5%capacity after 80 cycles at 4.5 V.Furthermore,the electrolyte demonstrates exceptional safety,and 2 Ah Li metal pouch cells successfully pass rigorous nail penetration tests without any ignition or explosion.This work not only provides a design strategy for intrinsically safe and high-performance electrolytes but also highlights the critical role of anion cluster decomposition kinetics in shaping EEI formation.
基金the National Natural Science Foundation of China(31901194)the Joint Funds of National Natural Science Foundation of China and Henan Province of China(U1904204).
文摘Aims Reforestation can enhance soil carbon(C)stability and promote soil C accumulation.Experimental results are,however,highly variable,and the efficacy of reforestation in enhancing soil C stability is still in debate.Consequently,it remains unclear how the different soil C pools respond to reforestation in forest ecosystems.Methods The response of different soil C fractions to reforestation was examined in five subtropical forests,including the plantations of Eucalyptus urophylla(EU),Acacia crassicarpa(AC),Castanopsis hystrix(CH)and 10 species mixed(MX),and a naturally recovered shrubland(NS).Soil labile C fractions(readily oxidized organic C by KMnO4:ROC;dissolved organic C:DOC),distribution of aggregate-size classes and aggregate-associated C from different soil layers(0–10,10–20,20–40 and 40–60 cm)were evaluated.Important Findings We found that reforestation and forest type did not affect ROC concentration,yet the highest DOC concentration was detected in NS at four soil layers.Aggregate C concentration was the highest in all aggregate-size classes of CH at 0–10 cm depth.In addition,forest type did not alter the proportion of soil water-stable aggregates at four soil layers.However,soil depths significantly affected the distribution of soil aggregates with>0.25 mm aggregates dominating in the topsoils(0–20 cm),but 0.053–2 mm aggregates being dominant in the deep soils(20–60 cm).These results indicate that reforestation and forest type affected soil DOC(0–60 cm)and aggregate C(0–10 cm).Furthermore,soil DOC and aggregate C were more susceptive to reforestation than ROC.The findings suggest that plantations reduce soil DOC concentration,highlighting that C leaching loss may decrease compared with natural recovery.Moreover,C.hystrix plantation may enhance soil C stability by physical protection in topsoil.This study provides valuable information on tree species selection for reforestation concerning soil C sequestration in southern subtropical China.
基金the Chinese Academy of Sciences for their financial support and research facilitiesfunded by the National Key Research and Development Program of China(2022YFD1500100)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA28070100)the China Agriculture Research System of MOF and MARA(CARS04)。
文摘The accumulation of soil organic carbon(SOC)and total nitrogen(TN)is easily accomplished by returning crop straw,which strongly affects the formation and pore structure of aggregates,especially in black soil.We returned maize straw at different rates(6,000,9,000,12,000 and 15,000 kg ha^(-1))for nine years to investigate its influence on the SOC and TN contents in the SOC fractions of aggregates by combining size and density fractionation.Their subsequent influences on pore morphology and size distribution characteristics were examined using X-ray microcomputed tomography scanning(μCT).The results showed that returning straw significantly increased the contents of C and N in the SOC fractions of aggregates,especially at the return rates of 12,000 and 15,000 kg ha^(-1),which in turn promoted aggregate formation and stability,and ultimately amended pore structure.The pore size>100μm,porosity(>2μm),and morphological characteristics(anisotropy,circularity,connectivity and fractal dimension)significantly increased,but the total number of pores significantly decreased(P<0.05).Our results indicated that the amendment of the pore morphology and size distribution of soil aggregates was primarily controlled by the higher contents of C and N in the density fractions of aggregates,rather than in the aggregate sizes.Furthermore,this pore network reconfiguration favored the storage of C and N simultaneously.The findings of this study offer valuable new insights into the relationships between C and N storage and the pore characteristics in soil aggregates under straw return.
