Magnetic resonance imaging(MRI)is one of the most widely used diagnostic techniques.Iron oxide nanoparticles,as a promising kind of contrast agents,have attracted intense research interest due to their low toxicity an...Magnetic resonance imaging(MRI)is one of the most widely used diagnostic techniques.Iron oxide nanoparticles,as a promising kind of contrast agents,have attracted intense research interest due to their low toxicity and superparamagnetism.However,it is still a great challenge to prepare ideal iron oxide based contrast agents with high uniformity,excellent water solubility and biocompatibility.In this paper,a novel water-soluble polymer ligand pentaerythritol tetrakis 3-mercaptopropionate-poly(N-vinyl-2-pyrrolidone)(PTMP-PVP)was used as a capping reagent to prepare iron oxide nanoparticles MIONs@PTMP-PVP through one-step co-precipitation of iron precursors in aqueous solution at 100℃.The obtained nanoparticles MIONs@PTMP-PVP had a small size and narrow size distribution,and they were found to be biocompatible as determined through CCK-8 assay and histology analysis.In vivo MRI study demonstrated that the obtained MIONs@PTMP-PVP can be potentially used as an effective T_(2)-weighted MRI contrast agent.展开更多
Mine surveying is an indispensable and crucial basic technical work in the process of mineral resource development.It plays an important role throughout the entire life cycle of a mine,from exploration,design,construc...Mine surveying is an indispensable and crucial basic technical work in the process of mineral resource development.It plays an important role throughout the entire life cycle of a mine,from exploration,design,construction,and production to closure,and is known as the“eyes of the mine”.With the rapid development of satellite technology,computer science,artificial intelligence,robotics,and spatiotemporal big data,mine surveying science and technology supported by spatial information technology is increasingly playing the role of the“brain of the mine”.This paper systematically summarizes the characteristics of mining surveying science and technology in contemporary and future mining development.First,based on the requirements of safe,efficient,and green development in modern mining,an analysis is conducted on the innovative practices of intelligent mining methods;secondly,it explains the transformation of regional economic and mining economic integration towards lengthening the industrial chain and scientific and technological innovation.Regarding intelligent mining,this paper discusses three technical dimensions:(1)By establishing a spatiotemporal data model of the mine,real-time perception and remote intelligent control of the production system are realized;(2)Based on the transparent mine three-dimensional geological modelling technology,the accuracy of geological condition prediction and the scientific nature of mining decisions are significantly improved;(3)By integrating multi-source remote sensing data and deep learning algorithms,a high-precision coal and rock identification system is constructed.The study further revealed the innovative application value of mine surveying in the post-mining era,including:diversified utilization of underground space in mining areas(tourism development,geothermal energy storage,pumped storage,etc.),multi-platform remote sensing coordinated ecological restoration monitoring,and optimized land space planning in mining areas.Practice has proved that mine surveying technology is an important technical engine for promoting green transformation and high-quality development in resource-based regions,and has irreplaceable strategic significance for achieving coordinated development of energy,economy,and environment.展开更多
Processes supported by process-aware information systems are subject to continuous and often subtle changes due to evolving operational,organizational,or regulatory factors.These changes,referred to as incremental con...Processes supported by process-aware information systems are subject to continuous and often subtle changes due to evolving operational,organizational,or regulatory factors.These changes,referred to as incremental concept drift,gradually alter the behavior or structure of processes,making their detection and localization a challenging task.Traditional process mining techniques frequently assume process stationarity and are limited in their ability to detect such drift,particularly from a control-flow perspective.The objective of this research is to develop an interpretable and robust framework capable of detecting and localizing incremental concept drift in event logs,with a specific emphasis on the structural evolution of control-flow semantics in processes.We propose DriftXMiner,a control-flow-aware hybrid framework that combines statistical,machine learning,and process model analysis techniques.The approach comprises three key components:(1)Cumulative Drift Scanner that tracks directional statistical deviations to detect early drift signals;(2)a Temporal Clustering and Drift-Aware Forest Ensemble(DAFE)to capture distributional and classification-level changes in process behavior;and(3)Petri net-based process model reconstruction,which enables the precise localization of structural drift using transition deviation metrics and replay fitness scores.Experimental validation on the BPI Challenge 2017 event log demonstrates that DriftXMiner effectively identifies and localizes gradual and incremental process drift over time.The framework achieves a detection accuracy of 92.5%,a localization precision of 90.3%,and an F1-score of 0.91,outperforming competitive baselines such as CUSUM+Histograms and ADWIN+Alpha Miner.Visual analyses further confirm that identified drift points align with transitions in control-flow models and behavioral cluster structures.DriftXMiner offers a novel and interpretable solution for incremental concept drift detection and localization in dynamic,process-aware systems.By integrating statistical signal accumulation,temporal behavior profiling,and structural process mining,the framework enables finegrained drift explanation and supports adaptive process intelligence in evolving environments.Its modular architecture supports extension to streaming data and real-time monitoring contexts.展开更多
Mineral resources in Asia continent and its mining industry play a significant role in the economic growth and industrialization of both Asia and the world.Asia continent boasts the most comprehensive kinds of mineral...Mineral resources in Asia continent and its mining industry play a significant role in the economic growth and industrialization of both Asia and the world.Asia continent boasts the most comprehensive kinds of minerals,with reserves of at least 38 of over 80 widely used minerals worldwide accounting for more than30%of the global total reserves.Asia continent experienced three main tectonic evolution and mineralization stages:The Precambrian,the Paleozoic,and the Mesozoic to Cenozoic.The abundant mineral resources in this continent can be divided into seven first-order metallogenic belts(metallogenic domains),18 second-order metallogenic belts(metallogenic provinces),61 third-order metallogenic belts(metallogenic zones),and nine main minerogenetic series.Asia continent exhibits the most significant metallogenic specialization among all continents.Specifically,granite belts of Asia continent manifest pronounced metallogenic specialization of tin,rare metals,and porphyry Cu-Au-Mo deposits.Its maficultramafic rock belts and ophiolite belts display notable metallogenic specialization of lateritic nickel deposits and magmatic type chromite deposits,while its Mesozoic to Cenozoic basalt belts show remarkable metallogenic specialization of lateritic bauxite deposits.Consequently,many giant metallogenic belts were formed,including the Southeast Asian tin belt,the Qinghai-Xizang Plateau rare metal metallogenic belt,the Tethyan porphyry Cu-Au-Mo metallogenic belt,the circum-Pacific porphyry Cu-Au-Mo metallogenic belt,the Southeast Asian lateritic bauxite metallogenic belt,the Deccan Plateau lateritic bauxite metallogenic belt in India,the Southeast Asian lateritic nickel metallogenic belt,and the Tethyan magmatic type chromite metallogenic belt—all of which are significant metallogenic belts in Asia continent.Future mineral exploration in Asia should focus primarily on the Precambrian mineralization of ancient cratons,the Paleozoic mineralization of the Central Asian-Mongolian orogenic belt,and the Mesozoic to Cenozoic mineralization of the Tethyan and circum-Pacific mobile belts.Asia's mining industry not only underpins its own economic growth but also propels global economic development and industrialization,contributing significantly to the world economy.Asia boasts the highest production value of minerals,the largest annual production of minerals,and the greatest trade value of mineral products among all the continents,having emerged as the trade center of global mineral products and the center of the mining industry economy.China is identified as one of the few countries that possess the most comprehensive kinds of minerals,and its mining industry has supported and driven the economic development and industrialization of Asia and even the world.Standing as the largest mineral producer worldwide,China ranked first in the production of 28 mineral commodities in the world in 2022.Besides,China exhibits the highest annual production value of minerals and the largest trade value of mineral products among all countries.Therefore,China's demand for global mineral products influences the global supply and demand patterns of minerals and the world economic situation.展开更多
A Si-substituted rhodamine based water-soluble fluorescent probe bearing a tetrathia-azacrown was designed for fluorescence imaging of Cu^(+) with substantial affinity and selectivity.In physiological condition,the de...A Si-substituted rhodamine based water-soluble fluorescent probe bearing a tetrathia-azacrown was designed for fluorescence imaging of Cu^(+) with substantial affinity and selectivity.In physiological condition,the developed probe with outstanding water-solubility exhibits ultrahigh sensitivity to Cu^(+),ensuring the reliable fluorescence imaging in vivo.展开更多
Identification of the most appropriate chemically extractable pool for evaluating Cd and Pb availability remains elusive,hindering accurate assessment on environmental risks and effectiveness of remediation strategies...Identification of the most appropriate chemically extractable pool for evaluating Cd and Pb availability remains elusive,hindering accurate assessment on environmental risks and effectiveness of remediation strategies.This study evaluated the feasibility of European Community Bureau of Reference(BCR)sequential extraction,Ca(NO_(3))_(2)extraction,and water extraction on assessing Cd and Pb availability in agricultural soil amended with slaked lime,magnesium hydroxide,corn stover biochar,and calcium dihydrogen phosphate.Moreover,the enriched isotope tracing technique(^(112)Cd and^(206)Pb)was employed to evaluate the aging process of newly introduced Cd and Pbwithin 56 days’incubation.Results demonstrated that extractable pools by BCR and Ca(NO_(3))_(2)extraction were little impacted by amendments and showed little correlation with soil pH.This is notable because soil pH is closely linked to metal availability,indicating these extraction methods may not adequately reflect metal availability.Conversely,water-soluble concentrations of Cd and Pb were markedly influenced by amendments and exhibited strong correlations with pH(Pearson’s r:-0.908 to-0.825,P<0.001),suggesting water extraction as a more sensitive approach.Furthermore,newly introduced metals underwent a more evident aging process as demonstrated by acid-soluble and water-soluble pools.Additionally,water-soluble concentrations of essential metals were impacted by soil amendments,raising caution on their potential effects on plant growth.These findings suggest water extraction as a promising and attractive method to evaluate Cd and Pb availability,which will help provide assessment guidance for environmental risks caused by heavy metals and develop efficient remediation strategies.展开更多
Water-soluble organic nitrogen(WSON)affects the formation,hygroscopicity,acidity of organic aerosols,and nitrogen biogeochemical cycles.However,qualitative and quantitative characterizations of WSON remain limited due...Water-soluble organic nitrogen(WSON)affects the formation,hygroscopicity,acidity of organic aerosols,and nitrogen biogeochemical cycles.However,qualitative and quantitative characterizations of WSON remain limited due to its chemical complexity.In the study,1-year field samples of particulate matter 2.5(PM_(2.5))were collected fromJune 2022 to May 2023 to analyze the WSON concentration in PM_(2.5),and correlation analysis,positive matrix factor(PMF),and potential source contribution function(PSCF)modelswere employed to elucidate WSON source apportionment and transport pathways.The results revealed that the mean WSON concentrations reached 1.98±2.64μg/m^(3) with a mean WSON to water-soluble total nitrogen(WSTN)ratio of 21%.Further,WSON concentration exhibited a seasonal variation trend,with higher values in winter and lower in summer.Five sources were identified as contributors to WSON in PM_(2.5) within the reservoir area through a comprehensive analysis including correlation analysis,PSCF and concentration weighted trajectory(CWT),and PMF analyses.These sources were agricultural,dust,combustion,traffic,and industrial sources,of which agricultural source emerged as the primary contributor(76.69%).The atmosphere in the reservoir area were primarily influenced by the transport of northeastern air masses,local agricultural activities,industrial cities along the trajectory,and coastal regions,exerting significant influences on the concentration of WSON in the reservoir area.The findings of this study addressed the research gap concerning organic nitrogen in PM_(2.5) within the reservoir area,thereby offering a theoretical foundation and data support in controlling nitrogen pollution in the Danjiangkou Reservoir area.展开更多
Enhancing the mining speed of a working face has become the primary approach to achieve high production and efficiency in coal mines,thereby further improving the production capacity.However,the problem of rock bursts...Enhancing the mining speed of a working face has become the primary approach to achieve high production and efficiency in coal mines,thereby further improving the production capacity.However,the problem of rock bursts resulting from this approach has become increasingly serious.Therefore,to implement coal mine safety and efficient extraction,the impact of deformation pressure caused by different mining speeds should be considered,and a reasonable mining speed of the working face should be determined.The influence of mining speed on overlying rock breaking in the stope is analyzed by establishing a key layer block rotation and subsidence model.Results show that with the increasing mining speed,the compression amount of gangue in the goaf decreases,and the rotation and subsidence amount of rock block B above goaf decreases,forcing the rotation and subsidence amount of rock block A above roadway to increase.Consequently,the contact mode between rock block A and rock block B changes from line contact to point contact,and the horizontal thrust and shear force between blocks increase.The increase in rotation and subsidence of rock block A intensifies the compression degree of coal and rock mass below the key layer,thereby increasing the stress concentration degree of coal and rock mass as well as the total energy accumulation.In addition,due to the insufficient compression of gangue in the goaf,the bending and subsidence space of the far-field key layer are limited,the length of the suspended roof increases,and the influence range of mining stress and the energy accumulation range expand.Numerical test results and underground microseismic monitoring results verify the correlation between mining speed and stope energy,and high-energy events generally appear 1-2 d after the change in mining speed.On this basis,the statistical principle confirms that the maximum mining speed of the working face at 6 m/d is reasonable.展开更多
Water-soluble organic aerosol(WSOA)plays a significant role in air quality and human health.Here we characterized the chemical properties and molecular compositions of WSOA at a rural site in North China Plain during ...Water-soluble organic aerosol(WSOA)plays a significant role in air quality and human health.Here we characterized the chemical properties and molecular compositions of WSOA at a rural site in North China Plain during winter using a high-resolution aerosol mass spectrometer and electrospray ionization high-resolution orbitrap mass spectrometer(ESI-HRMS).Our results show that the mass concentration of WSOA was significantly higher than that observed in Beijing in winter 2020,contributing about 56%of OA on average.CHO compounds(56%-74%)and CHN compounds(66%-80%)dominated in negative mode and positive mode,respectively,while CHON accounted for 15%-41%across both modes.The chemical characteristics of WSOA varied with polluted levels and between day and night.As pollution intensified,the abundance of CHO-compounds with condensed aromatics increased by 9%and the number of highly oxygenated molecules(HOMs)molecular formula detected in server haze was more than double that of clean days.CHO-compounds with ten carbon atoms(C_(10))were more abundant at night while those with nine carbon atoms(C_(9))were higher during the day.High levels of CHN+compounds were linked to nighttime biomass burning,whereas CHON compounds were more abundant during the day.Increased pollution also led to the formation of more complex CHON-compounds,indicating that organonitrates continue to play a significant role in rural pollution.展开更多
Five water-soluble poly(aminoheterocyclic amine)s containing s-triazole ring were synthesized as respective HC1 salts(5a-5e).Biological activities in L1210(murine leukemia)and Chinese hamster ovary(CHO)cell lines were...Five water-soluble poly(aminoheterocyclic amine)s containing s-triazole ring were synthesized as respective HC1 salts(5a-5e).Biological activities in L1210(murine leukemia)and Chinese hamster ovary(CHO)cell lines were investigated via IC50 cytotoxicity determinations.The tide compounds represented moderate cytotoxicity(low IC50 values between 15 and 68μmol/L)in L1210 but high cytotoxicity(lower IC50 values:0.25,0.018,0.014μmol/L for Sa-5e,respectively)in CHO cell lines,while the corresponding HC1 salts of the intermediates(3a-3e)without polyamine tether and starting materials amino-s-triazoles(1a-1e)showed poor or no activities against the above cell lines.展开更多
Water-soluble organic acid anions(WSOAA)in subsurface water have been intensively studied during past several decades.They are used as natural gas precursor,tracer for the movement of underground fluid,indicator for p...Water-soluble organic acid anions(WSOAA)in subsurface water have been intensively studied during past several decades.They are used as natural gas precursor,tracer for the movement of underground fluid,indicator for porosity improvement,and detecter of deep subsurface life on the Earth.However,little is known about the distributions and origins of organic acids at deep-ultradeep depth underground.Herein,we collected twenty-nine source rock samples covering a wide maturity range from the Ordos,Qinshui,Junggar,Minhe,and Southern North China basins,as well as six subsurface water samples with depth between 6544 and 8396 m from industrial gas producing wells in the Tarim Basin,China.We carried out pyrolysis experiments at various temperatures(250–450℃)to investigate the role of water on the generation of organic acids.Results show that there are considerable amounts of WSOAA detected in both high-over mature source rocks and deep-ultradeep subsurface water.WSOAA mainly consists of monocarboxylates,predominately formate and acetate.High-TOC oil-generating source rock has low production rate of organic acids due to lack of hydrogen.Different source rocks have distinct ratios of formate to acetate concentration,expressed as c(formate)/c(acetate),which is due to significant differences in both initial molecular structure and metabolite.This indicates that c(formate)/c(acetate)can be used to distinguish types of organic matters(OMs).Concentrations of WSOAA show a“sharp decrease-slight increase-slow decrease”evolution trend with progressive maturity.Moreover,there are higher production rates of organic acids under hydrous pyrolysis experiments at≥400℃.All geochemical signatures indicate that at both deep-ultradeep depth and high-over mature stages,the formation of organic acids is attributed to the thermochemical oxidation of organic components by mainly hydroxyl radicals,challenging the traditional model of organic acid evolution.This work suggests that petroleum exploration can be extended to great depths in sedimentary basins,when formation temperatures are not exceeding 230℃.展开更多
Monodispersed and water-soluble TbF3 nanoparticles were synthesized at a relatively low temperature in aqueous solution using citric acid as an additive,and characterized by X-ray diffraction（XRD）,field emission sca...Monodispersed and water-soluble TbF3 nanoparticles were synthesized at a relatively low temperature in aqueous solution using citric acid as an additive,and characterized by X-ray diffraction（XRD）,field emission scanning electron microscopy（FE-SEM）,Fourier transform infrared spectra（FTIR）,photoluminescence（PL） spectra and lifetime.The as-prepared TbF3 nanoparticles had orthorhombic structure and were composed of monodispersed spherical particles with an average particle size of 50 nm.The excitation spectrum of TbF3 nanoparticles obtained by monitoring the emission of Tb3＋ at 543 nm was composed of the characteristics f-f transition lines within the Tb3＋ 4f8 configuration.Under the UV light irradiation,the emission spectrum exhibited four obvious lines centered at 489,543,589,and 618 nm,which was corresponding to the 5D4→7FJ（J=6,5,4,3） transitions of the Tb3＋ ions in TbF3 nanoparticles.展开更多
In the context of increasing demand for coal mine resources in China’s current socio-economic development,traditional mining methods have been difficult to effectively meet the requirements of safety production and e...In the context of increasing demand for coal mine resources in China’s current socio-economic development,traditional mining methods have been difficult to effectively meet the requirements of safety production and environmental protection.As a result,coal mine filling mining technology has emerged,which can effectively achieve the goal of controlling surface subsidence in practical applications,while also significantly improving the recovery rate of coal resources.Based on this,this study will first elaborate on the characteristics of filling mining technology,and then analyze the key points of the application of supporting technology for mechanical and electrical equipment in the corresponding working face based on actual cases,in order to provide support for improving the efficiency of coal mining.展开更多
Reported here is the synthesis of a new macrocycle bearing anionic carboxylate groups with water-soluble aggregation-induced emission(AIE).The water-soluble macrocycle without typical AIE luminogens is constructed bas...Reported here is the synthesis of a new macrocycle bearing anionic carboxylate groups with water-soluble aggregation-induced emission(AIE).The water-soluble macrocycle without typical AIE luminogens is constructed based on the building block of benzothiadiazole.It exhibits a remarkable AIE effect.This watersoluble macrocycle can selectively bind different types of biogenic amines in aqueous media with the tightest binding towards spermine.The fluorescence enhancement induced by supramolecular encapsulation is used to detect spermine.展开更多
Coal mine underground reservoir(CMUR) technology mitigates water scarcity in China's coal-rich western regions but lacks tailored solutions for steeply inclined coal seams.This study develops a novel framework of ...Coal mine underground reservoir(CMUR) technology mitigates water scarcity in China's coal-rich western regions but lacks tailored solutions for steeply inclined coal seams.This study develops a novel framework of steeply inclined coal mine underground reservoirs(SICMUR),which is a paradigm shift from conventional CMUR that the coal seam itself serves as the reservoir floor,challenging conventional designs due to depth-dependent permeability and mechanical constraints.Triaxial mechanical-seepage tests on Xinjiang Wudong coal samples(100,200,300 m depths) revealed a 3.5 MPa triaxial strength increase per 100 m depth and a 58-fold post-peak permeability surge at 300 versus 100 m.Similar model simulations revealed mining-induced stress redistribution and significant deformation effects,particularly subsidence and water-conducting fractures during lower coal seam mining.Results indicate a minimum 40 m safety distance between reservoirs and lower coal seams.Critical construction parameters were investigated for Wudong mine SICMUR as collapse zone heights(9.9–12.31 m) and waterconducting fracture zone heights(31.96–37.40 m).This work systematically bridges SICMUR concepts to field implementation,offering a framework for water preservation in steeply inclined mining while addressing safety concerns,providing a new approach for water reservation in steeply inclined coal mining.展开更多
39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.Ar...39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.ArcGIS inverse distance weight difference method was used to analyze the characteristics of pollution distribution,and single-factor pollution index,Nemerow comprehensive pollution index,ground accumulation index,and potential ecological risk index were selected to evaluate the characteristics of heavy metal pollution.Based on correlation analysis,the absolute principal component-multiple linear regression(APCS-MLR)and positive definite matrix factorization(PMF)models were used to analyze the sources of soil heavy metals.The results showed that the average concentrations of all eight heavy metals exceeded both national and Guangxi soil background values.Hg,Cd,and Zn exhibited high variation(greater than 0.5),indicating significant external disturbances,and their spatial distribution was closely related to mining activity locations.The single-factor pollution index evaluation indicated varying degrees of pollution risk for Cd,Zn,and As,with Cd and Zn being the most severe pollutants,as 69.23%and 30.77%of the samples fell into the moderate pollution or higher category.The geoaccumulation index analysis ranked the mean pollution levels of the eight elements as follows:Zn>Cd>Ni>Pb>Cu>Cr>Hg>As,with Cd and Zn showing the most severe contamination,and 51.28%of the samples exhibiting moderate or higher pollution levels.The Nemerow comprehensive pollution index evaluation showed that 74.35%of soil samples were classified as moderate to heavy pollution.The potential ecological risk index assessment indicated significant ecological risks posed by Cd and Zn,with 82.05%and 5.12%of the samples classified as causing strong to extreme ecological risks,respectively.The source apportionment analysis revealed minor differences between the two models.The APCS-MLR model identified three pollution sources and their contribution rates:anthropogenic mining sources(31.13%),parent material sources(40.38%),and unidentified sources(28.49%).The PMF model identified three pollution sources with contribution rates of anthropogenic mining sources(26.10%),parent material sources(46.96%),and a combined traffic and agricultural source(26.61%).Pb,Hg,Cd,and Zn mainly originated from mining activities;Cr,As,and Ni were primarily derived from the parent material,while Cu was predominantly attributed to traffic and agricultural sources.These findings provide a scientific basis for the prevention and control of heavy metal pollution in mining areas.展开更多
A series of boron- and phosphorus-doped silicon wafers are used to prepare a series of doped silicon nanocrystals （nc-Si） by high-energy ball milling with carboxylic acid-terminated surface. The sizes of the nc-Si s...A series of boron- and phosphorus-doped silicon wafers are used to prepare a series of doped silicon nanocrystals （nc-Si） by high-energy ball milling with carboxylic acid-terminated surface. The sizes of the nc-Si samples are demonstrated to be 〈 S nm. The doping levels of the nc-Si are found to be nonlinearly dependent on the original doping level of the wafers by x-ray photoelectron spectroscopy measurement. It is found that the nonlinear doping process will lead to the nonlinear chemical passivation and photoluminescence （I3L） intensity evolution. The doping, chemical passivation and PL mechanisms of the doped nc-Si samples prepared by mechanochemical synthesis are analyzed in detail.展开更多
Xinli district of Sanshandao Gold Mine is the first subsea metal mine in China.To achieve 6 kt/d production capacity under the premise of safe mining,high-intensity mining might destroy the in-situ stress filed and th...Xinli district of Sanshandao Gold Mine is the first subsea metal mine in China.To achieve 6 kt/d production capacity under the premise of safe mining,high-intensity mining might destroy the in-situ stress filed and the stability of rockmass.According to sampling and testing of ore-rock and backfill and in-situ stress field measurement,safety factor method calculation model based on stress-strain strength reduction at arbitrary points and Mohr-Coulomb yield criterion was established and limit displacement subsidence values under the safety factor of different limit stoping steps were calculated.The results from three years in-situ mining and strata movement monitoring using multi-point displacements meter showed that the lower settlement frame stope hierarchical level filling mining method,mining sequence are reasonable and rockmass stability evaluation using safety factor method,in-situ real-time monitoring can provide the technical foundation for the safety of seabed mining.展开更多
基金financially supported by the International Cooperation Program from the Ministry of Science and Technology of Hubei Province(No.2023EHA069)Shenzhen Science and Technology Program(No.JCYJ20230807143702005)National Foreign Experts Program(No.G2022027015L)。
文摘Magnetic resonance imaging(MRI)is one of the most widely used diagnostic techniques.Iron oxide nanoparticles,as a promising kind of contrast agents,have attracted intense research interest due to their low toxicity and superparamagnetism.However,it is still a great challenge to prepare ideal iron oxide based contrast agents with high uniformity,excellent water solubility and biocompatibility.In this paper,a novel water-soluble polymer ligand pentaerythritol tetrakis 3-mercaptopropionate-poly(N-vinyl-2-pyrrolidone)(PTMP-PVP)was used as a capping reagent to prepare iron oxide nanoparticles MIONs@PTMP-PVP through one-step co-precipitation of iron precursors in aqueous solution at 100℃.The obtained nanoparticles MIONs@PTMP-PVP had a small size and narrow size distribution,and they were found to be biocompatible as determined through CCK-8 assay and histology analysis.In vivo MRI study demonstrated that the obtained MIONs@PTMP-PVP can be potentially used as an effective T_(2)-weighted MRI contrast agent.
基金supported by the National Natural Science Foundation of China(Nos.52394193 and U22A20569)the National Key R&D Program Projects(Nos.2023YFC3804200 and 2023YFC3804205).
文摘Mine surveying is an indispensable and crucial basic technical work in the process of mineral resource development.It plays an important role throughout the entire life cycle of a mine,from exploration,design,construction,and production to closure,and is known as the“eyes of the mine”.With the rapid development of satellite technology,computer science,artificial intelligence,robotics,and spatiotemporal big data,mine surveying science and technology supported by spatial information technology is increasingly playing the role of the“brain of the mine”.This paper systematically summarizes the characteristics of mining surveying science and technology in contemporary and future mining development.First,based on the requirements of safe,efficient,and green development in modern mining,an analysis is conducted on the innovative practices of intelligent mining methods;secondly,it explains the transformation of regional economic and mining economic integration towards lengthening the industrial chain and scientific and technological innovation.Regarding intelligent mining,this paper discusses three technical dimensions:(1)By establishing a spatiotemporal data model of the mine,real-time perception and remote intelligent control of the production system are realized;(2)Based on the transparent mine three-dimensional geological modelling technology,the accuracy of geological condition prediction and the scientific nature of mining decisions are significantly improved;(3)By integrating multi-source remote sensing data and deep learning algorithms,a high-precision coal and rock identification system is constructed.The study further revealed the innovative application value of mine surveying in the post-mining era,including:diversified utilization of underground space in mining areas(tourism development,geothermal energy storage,pumped storage,etc.),multi-platform remote sensing coordinated ecological restoration monitoring,and optimized land space planning in mining areas.Practice has proved that mine surveying technology is an important technical engine for promoting green transformation and high-quality development in resource-based regions,and has irreplaceable strategic significance for achieving coordinated development of energy,economy,and environment.
文摘Processes supported by process-aware information systems are subject to continuous and often subtle changes due to evolving operational,organizational,or regulatory factors.These changes,referred to as incremental concept drift,gradually alter the behavior or structure of processes,making their detection and localization a challenging task.Traditional process mining techniques frequently assume process stationarity and are limited in their ability to detect such drift,particularly from a control-flow perspective.The objective of this research is to develop an interpretable and robust framework capable of detecting and localizing incremental concept drift in event logs,with a specific emphasis on the structural evolution of control-flow semantics in processes.We propose DriftXMiner,a control-flow-aware hybrid framework that combines statistical,machine learning,and process model analysis techniques.The approach comprises three key components:(1)Cumulative Drift Scanner that tracks directional statistical deviations to detect early drift signals;(2)a Temporal Clustering and Drift-Aware Forest Ensemble(DAFE)to capture distributional and classification-level changes in process behavior;and(3)Petri net-based process model reconstruction,which enables the precise localization of structural drift using transition deviation metrics and replay fitness scores.Experimental validation on the BPI Challenge 2017 event log demonstrates that DriftXMiner effectively identifies and localizes gradual and incremental process drift over time.The framework achieves a detection accuracy of 92.5%,a localization precision of 90.3%,and an F1-score of 0.91,outperforming competitive baselines such as CUSUM+Histograms and ADWIN+Alpha Miner.Visual analyses further confirm that identified drift points align with transitions in control-flow models and behavioral cluster structures.DriftXMiner offers a novel and interpretable solution for incremental concept drift detection and localization in dynamic,process-aware systems.By integrating statistical signal accumulation,temporal behavior profiling,and structural process mining,the framework enables finegrained drift explanation and supports adaptive process intelligence in evolving environments.Its modular architecture supports extension to streaming data and real-time monitoring contexts.
基金funded by geological survey project of China Geological Survey(DD20211404)。
文摘Mineral resources in Asia continent and its mining industry play a significant role in the economic growth and industrialization of both Asia and the world.Asia continent boasts the most comprehensive kinds of minerals,with reserves of at least 38 of over 80 widely used minerals worldwide accounting for more than30%of the global total reserves.Asia continent experienced three main tectonic evolution and mineralization stages:The Precambrian,the Paleozoic,and the Mesozoic to Cenozoic.The abundant mineral resources in this continent can be divided into seven first-order metallogenic belts(metallogenic domains),18 second-order metallogenic belts(metallogenic provinces),61 third-order metallogenic belts(metallogenic zones),and nine main minerogenetic series.Asia continent exhibits the most significant metallogenic specialization among all continents.Specifically,granite belts of Asia continent manifest pronounced metallogenic specialization of tin,rare metals,and porphyry Cu-Au-Mo deposits.Its maficultramafic rock belts and ophiolite belts display notable metallogenic specialization of lateritic nickel deposits and magmatic type chromite deposits,while its Mesozoic to Cenozoic basalt belts show remarkable metallogenic specialization of lateritic bauxite deposits.Consequently,many giant metallogenic belts were formed,including the Southeast Asian tin belt,the Qinghai-Xizang Plateau rare metal metallogenic belt,the Tethyan porphyry Cu-Au-Mo metallogenic belt,the circum-Pacific porphyry Cu-Au-Mo metallogenic belt,the Southeast Asian lateritic bauxite metallogenic belt,the Deccan Plateau lateritic bauxite metallogenic belt in India,the Southeast Asian lateritic nickel metallogenic belt,and the Tethyan magmatic type chromite metallogenic belt—all of which are significant metallogenic belts in Asia continent.Future mineral exploration in Asia should focus primarily on the Precambrian mineralization of ancient cratons,the Paleozoic mineralization of the Central Asian-Mongolian orogenic belt,and the Mesozoic to Cenozoic mineralization of the Tethyan and circum-Pacific mobile belts.Asia's mining industry not only underpins its own economic growth but also propels global economic development and industrialization,contributing significantly to the world economy.Asia boasts the highest production value of minerals,the largest annual production of minerals,and the greatest trade value of mineral products among all the continents,having emerged as the trade center of global mineral products and the center of the mining industry economy.China is identified as one of the few countries that possess the most comprehensive kinds of minerals,and its mining industry has supported and driven the economic development and industrialization of Asia and even the world.Standing as the largest mineral producer worldwide,China ranked first in the production of 28 mineral commodities in the world in 2022.Besides,China exhibits the highest annual production value of minerals and the largest trade value of mineral products among all countries.Therefore,China's demand for global mineral products influences the global supply and demand patterns of minerals and the world economic situation.
基金supported by the National Natural Science Foundation of China(Nos.21602250,81830106)Natural Science Foundation of Shanghai(Nos.19ZR1480000,20ZR1470200).
文摘A Si-substituted rhodamine based water-soluble fluorescent probe bearing a tetrathia-azacrown was designed for fluorescence imaging of Cu^(+) with substantial affinity and selectivity.In physiological condition,the developed probe with outstanding water-solubility exhibits ultrahigh sensitivity to Cu^(+),ensuring the reliable fluorescence imaging in vivo.
基金supported by the National Natural Science Foundation of Shandong(No.ZR2020ZD20)the National Natural Science Foundation of China(No.22193051)+1 种基金the National Young Top-Notch Talents(No.W03070030)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.Y202011).
文摘Identification of the most appropriate chemically extractable pool for evaluating Cd and Pb availability remains elusive,hindering accurate assessment on environmental risks and effectiveness of remediation strategies.This study evaluated the feasibility of European Community Bureau of Reference(BCR)sequential extraction,Ca(NO_(3))_(2)extraction,and water extraction on assessing Cd and Pb availability in agricultural soil amended with slaked lime,magnesium hydroxide,corn stover biochar,and calcium dihydrogen phosphate.Moreover,the enriched isotope tracing technique(^(112)Cd and^(206)Pb)was employed to evaluate the aging process of newly introduced Cd and Pbwithin 56 days’incubation.Results demonstrated that extractable pools by BCR and Ca(NO_(3))_(2)extraction were little impacted by amendments and showed little correlation with soil pH.This is notable because soil pH is closely linked to metal availability,indicating these extraction methods may not adequately reflect metal availability.Conversely,water-soluble concentrations of Cd and Pb were markedly influenced by amendments and exhibited strong correlations with pH(Pearson’s r:-0.908 to-0.825,P<0.001),suggesting water extraction as a more sensitive approach.Furthermore,newly introduced metals underwent a more evident aging process as demonstrated by acid-soluble and water-soluble pools.Additionally,water-soluble concentrations of essential metals were impacted by soil amendments,raising caution on their potential effects on plant growth.These findings suggest water extraction as a promising and attractive method to evaluate Cd and Pb availability,which will help provide assessment guidance for environmental risks caused by heavy metals and develop efficient remediation strategies.
基金supported by the National Natural Science Foundation of China(Nos.U23A2016,U1704241,and 42007175).
文摘Water-soluble organic nitrogen(WSON)affects the formation,hygroscopicity,acidity of organic aerosols,and nitrogen biogeochemical cycles.However,qualitative and quantitative characterizations of WSON remain limited due to its chemical complexity.In the study,1-year field samples of particulate matter 2.5(PM_(2.5))were collected fromJune 2022 to May 2023 to analyze the WSON concentration in PM_(2.5),and correlation analysis,positive matrix factor(PMF),and potential source contribution function(PSCF)modelswere employed to elucidate WSON source apportionment and transport pathways.The results revealed that the mean WSON concentrations reached 1.98±2.64μg/m^(3) with a mean WSON to water-soluble total nitrogen(WSTN)ratio of 21%.Further,WSON concentration exhibited a seasonal variation trend,with higher values in winter and lower in summer.Five sources were identified as contributors to WSON in PM_(2.5) within the reservoir area through a comprehensive analysis including correlation analysis,PSCF and concentration weighted trajectory(CWT),and PMF analyses.These sources were agricultural,dust,combustion,traffic,and industrial sources,of which agricultural source emerged as the primary contributor(76.69%).The atmosphere in the reservoir area were primarily influenced by the transport of northeastern air masses,local agricultural activities,industrial cities along the trajectory,and coastal regions,exerting significant influences on the concentration of WSON in the reservoir area.The findings of this study addressed the research gap concerning organic nitrogen in PM_(2.5) within the reservoir area,thereby offering a theoretical foundation and data support in controlling nitrogen pollution in the Danjiangkou Reservoir area.
基金supported by Technology Innovation Fund of China Coal Research Institute(2022CX-I-04)Science and Technology Innovation Venture Capital Project of China Coal Technology Engineering Group(2020-2-TD-CXY005)。
文摘Enhancing the mining speed of a working face has become the primary approach to achieve high production and efficiency in coal mines,thereby further improving the production capacity.However,the problem of rock bursts resulting from this approach has become increasingly serious.Therefore,to implement coal mine safety and efficient extraction,the impact of deformation pressure caused by different mining speeds should be considered,and a reasonable mining speed of the working face should be determined.The influence of mining speed on overlying rock breaking in the stope is analyzed by establishing a key layer block rotation and subsidence model.Results show that with the increasing mining speed,the compression amount of gangue in the goaf decreases,and the rotation and subsidence amount of rock block B above goaf decreases,forcing the rotation and subsidence amount of rock block A above roadway to increase.Consequently,the contact mode between rock block A and rock block B changes from line contact to point contact,and the horizontal thrust and shear force between blocks increase.The increase in rotation and subsidence of rock block A intensifies the compression degree of coal and rock mass below the key layer,thereby increasing the stress concentration degree of coal and rock mass as well as the total energy accumulation.In addition,due to the insufficient compression of gangue in the goaf,the bending and subsidence space of the far-field key layer are limited,the length of the suspended roof increases,and the influence range of mining stress and the energy accumulation range expand.Numerical test results and underground microseismic monitoring results verify the correlation between mining speed and stope energy,and high-energy events generally appear 1-2 d after the change in mining speed.On this basis,the statistical principle confirms that the maximum mining speed of the working face at 6 m/d is reasonable.
基金the financial support of the National Natural Science Foundation of China(Nos.20806013, 20923006)the National Key Technology R&D Program(No. 2011BAE07B08)
文摘Received 26 September 2012 Received in revised form 18 December 20 Accepted 1 January 2013 Available online 4 February 2013
基金supported by the National Natural Science Foundation of China(No.42307139)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB0760200)。
文摘Water-soluble organic aerosol(WSOA)plays a significant role in air quality and human health.Here we characterized the chemical properties and molecular compositions of WSOA at a rural site in North China Plain during winter using a high-resolution aerosol mass spectrometer and electrospray ionization high-resolution orbitrap mass spectrometer(ESI-HRMS).Our results show that the mass concentration of WSOA was significantly higher than that observed in Beijing in winter 2020,contributing about 56%of OA on average.CHO compounds(56%-74%)and CHN compounds(66%-80%)dominated in negative mode and positive mode,respectively,while CHON accounted for 15%-41%across both modes.The chemical characteristics of WSOA varied with polluted levels and between day and night.As pollution intensified,the abundance of CHO-compounds with condensed aromatics increased by 9%and the number of highly oxygenated molecules(HOMs)molecular formula detected in server haze was more than double that of clean days.CHO-compounds with ten carbon atoms(C_(10))were more abundant at night while those with nine carbon atoms(C_(9))were higher during the day.High levels of CHN+compounds were linked to nighttime biomass burning,whereas CHON compounds were more abundant during the day.Increased pollution also led to the formation of more complex CHON-compounds,indicating that organonitrates continue to play a significant role in rural pollution.
文摘Five water-soluble poly(aminoheterocyclic amine)s containing s-triazole ring were synthesized as respective HC1 salts(5a-5e).Biological activities in L1210(murine leukemia)and Chinese hamster ovary(CHO)cell lines were investigated via IC50 cytotoxicity determinations.The tide compounds represented moderate cytotoxicity(low IC50 values between 15 and 68μmol/L)in L1210 but high cytotoxicity(lower IC50 values:0.25,0.018,0.014μmol/L for Sa-5e,respectively)in CHO cell lines,while the corresponding HC1 salts of the intermediates(3a-3e)without polyamine tether and starting materials amino-s-triazoles(1a-1e)showed poor or no activities against the above cell lines.
基金supported by the National Nature Science Foundation of China(Nos.42203027,U2244209,41872147)the China Postdoctoral Science Foundation(No.2023M730039).
文摘Water-soluble organic acid anions(WSOAA)in subsurface water have been intensively studied during past several decades.They are used as natural gas precursor,tracer for the movement of underground fluid,indicator for porosity improvement,and detecter of deep subsurface life on the Earth.However,little is known about the distributions and origins of organic acids at deep-ultradeep depth underground.Herein,we collected twenty-nine source rock samples covering a wide maturity range from the Ordos,Qinshui,Junggar,Minhe,and Southern North China basins,as well as six subsurface water samples with depth between 6544 and 8396 m from industrial gas producing wells in the Tarim Basin,China.We carried out pyrolysis experiments at various temperatures(250–450℃)to investigate the role of water on the generation of organic acids.Results show that there are considerable amounts of WSOAA detected in both high-over mature source rocks and deep-ultradeep subsurface water.WSOAA mainly consists of monocarboxylates,predominately formate and acetate.High-TOC oil-generating source rock has low production rate of organic acids due to lack of hydrogen.Different source rocks have distinct ratios of formate to acetate concentration,expressed as c(formate)/c(acetate),which is due to significant differences in both initial molecular structure and metabolite.This indicates that c(formate)/c(acetate)can be used to distinguish types of organic matters(OMs).Concentrations of WSOAA show a“sharp decrease-slight increase-slow decrease”evolution trend with progressive maturity.Moreover,there are higher production rates of organic acids under hydrous pyrolysis experiments at≥400℃.All geochemical signatures indicate that at both deep-ultradeep depth and high-over mature stages,the formation of organic acids is attributed to the thermochemical oxidation of organic components by mainly hydroxyl radicals,challenging the traditional model of organic acid evolution.This work suggests that petroleum exploration can be extended to great depths in sedimentary basins,when formation temperatures are not exceeding 230℃.
基金Project supported by the National Natural Science Foundation of China (21171179)Henan Educational Committee (2011B140025)+3 种基金University Key Teacher of Henan Province (2009GGJS-119)HASTIT (2011HASTIT030)the State Key Laboratory Program of Rare Earth Resource UtilizationStartup Fund for Doctoral Program of Zhoukou Normal University
文摘Monodispersed and water-soluble TbF3 nanoparticles were synthesized at a relatively low temperature in aqueous solution using citric acid as an additive,and characterized by X-ray diffraction（XRD）,field emission scanning electron microscopy（FE-SEM）,Fourier transform infrared spectra（FTIR）,photoluminescence（PL） spectra and lifetime.The as-prepared TbF3 nanoparticles had orthorhombic structure and were composed of monodispersed spherical particles with an average particle size of 50 nm.The excitation spectrum of TbF3 nanoparticles obtained by monitoring the emission of Tb3＋ at 543 nm was composed of the characteristics f-f transition lines within the Tb3＋ 4f8 configuration.Under the UV light irradiation,the emission spectrum exhibited four obvious lines centered at 489,543,589,and 618 nm,which was corresponding to the 5D4→7FJ（J=6,5,4,3） transitions of the Tb3＋ ions in TbF3 nanoparticles.
文摘In the context of increasing demand for coal mine resources in China’s current socio-economic development,traditional mining methods have been difficult to effectively meet the requirements of safety production and environmental protection.As a result,coal mine filling mining technology has emerged,which can effectively achieve the goal of controlling surface subsidence in practical applications,while also significantly improving the recovery rate of coal resources.Based on this,this study will first elaborate on the characteristics of filling mining technology,and then analyze the key points of the application of supporting technology for mechanical and electrical equipment in the corresponding working face based on actual cases,in order to provide support for improving the efficiency of coal mining.
基金the Natural Science Foundation of Zhejiang Province(Nos.LR24B020003 and LQ24B020003)the National Natural Science Foundation of China(No.21921003)for financial support。
文摘Reported here is the synthesis of a new macrocycle bearing anionic carboxylate groups with water-soluble aggregation-induced emission(AIE).The water-soluble macrocycle without typical AIE luminogens is constructed based on the building block of benzothiadiazole.It exhibits a remarkable AIE effect.This watersoluble macrocycle can selectively bind different types of biogenic amines in aqueous media with the tightest binding towards spermine.The fluorescence enhancement induced by supramolecular encapsulation is used to detect spermine.
基金supported by Beijing Natural Science Foundation (No.8254049)the National Natural Science Foundation of China (No.52374139)the Deep Earth Probe and Mineral Resources Exploration-National Science and Technology Major Project (No.2024ZD1004505)。
文摘Coal mine underground reservoir(CMUR) technology mitigates water scarcity in China's coal-rich western regions but lacks tailored solutions for steeply inclined coal seams.This study develops a novel framework of steeply inclined coal mine underground reservoirs(SICMUR),which is a paradigm shift from conventional CMUR that the coal seam itself serves as the reservoir floor,challenging conventional designs due to depth-dependent permeability and mechanical constraints.Triaxial mechanical-seepage tests on Xinjiang Wudong coal samples(100,200,300 m depths) revealed a 3.5 MPa triaxial strength increase per 100 m depth and a 58-fold post-peak permeability surge at 300 versus 100 m.Similar model simulations revealed mining-induced stress redistribution and significant deformation effects,particularly subsidence and water-conducting fractures during lower coal seam mining.Results indicate a minimum 40 m safety distance between reservoirs and lower coal seams.Critical construction parameters were investigated for Wudong mine SICMUR as collapse zone heights(9.9–12.31 m) and waterconducting fracture zone heights(31.96–37.40 m).This work systematically bridges SICMUR concepts to field implementation,offering a framework for water preservation in steeply inclined mining while addressing safety concerns,providing a new approach for water reservation in steeply inclined coal mining.
文摘39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.ArcGIS inverse distance weight difference method was used to analyze the characteristics of pollution distribution,and single-factor pollution index,Nemerow comprehensive pollution index,ground accumulation index,and potential ecological risk index were selected to evaluate the characteristics of heavy metal pollution.Based on correlation analysis,the absolute principal component-multiple linear regression(APCS-MLR)and positive definite matrix factorization(PMF)models were used to analyze the sources of soil heavy metals.The results showed that the average concentrations of all eight heavy metals exceeded both national and Guangxi soil background values.Hg,Cd,and Zn exhibited high variation(greater than 0.5),indicating significant external disturbances,and their spatial distribution was closely related to mining activity locations.The single-factor pollution index evaluation indicated varying degrees of pollution risk for Cd,Zn,and As,with Cd and Zn being the most severe pollutants,as 69.23%and 30.77%of the samples fell into the moderate pollution or higher category.The geoaccumulation index analysis ranked the mean pollution levels of the eight elements as follows:Zn>Cd>Ni>Pb>Cu>Cr>Hg>As,with Cd and Zn showing the most severe contamination,and 51.28%of the samples exhibiting moderate or higher pollution levels.The Nemerow comprehensive pollution index evaluation showed that 74.35%of soil samples were classified as moderate to heavy pollution.The potential ecological risk index assessment indicated significant ecological risks posed by Cd and Zn,with 82.05%and 5.12%of the samples classified as causing strong to extreme ecological risks,respectively.The source apportionment analysis revealed minor differences between the two models.The APCS-MLR model identified three pollution sources and their contribution rates:anthropogenic mining sources(31.13%),parent material sources(40.38%),and unidentified sources(28.49%).The PMF model identified three pollution sources with contribution rates of anthropogenic mining sources(26.10%),parent material sources(46.96%),and a combined traffic and agricultural source(26.61%).Pb,Hg,Cd,and Zn mainly originated from mining activities;Cr,As,and Ni were primarily derived from the parent material,while Cu was predominantly attributed to traffic and agricultural sources.These findings provide a scientific basis for the prevention and control of heavy metal pollution in mining areas.
基金Supported by the National Natural Science Foundation of China under Grant No 61575216
文摘A series of boron- and phosphorus-doped silicon wafers are used to prepare a series of doped silicon nanocrystals （nc-Si） by high-energy ball milling with carboxylic acid-terminated surface. The sizes of the nc-Si samples are demonstrated to be 〈 S nm. The doping levels of the nc-Si are found to be nonlinearly dependent on the original doping level of the wafers by x-ray photoelectron spectroscopy measurement. It is found that the nonlinear doping process will lead to the nonlinear chemical passivation and photoluminescence （I3L） intensity evolution. The doping, chemical passivation and PL mechanisms of the doped nc-Si samples prepared by mechanochemical synthesis are analyzed in detail.
基金Project(10872218) supported by the National Natural Science Foundation of ChinaProject(2010CB732004) supported by the National Key Basic Research Program of China+1 种基金Project(20090461022) supported by the National Postdoctoral Foundation of ChinaProject (11MX21) supported by the Students' Innovation Project Aubsidize Award of Arcelor Mittal
文摘Xinli district of Sanshandao Gold Mine is the first subsea metal mine in China.To achieve 6 kt/d production capacity under the premise of safe mining,high-intensity mining might destroy the in-situ stress filed and the stability of rockmass.According to sampling and testing of ore-rock and backfill and in-situ stress field measurement,safety factor method calculation model based on stress-strain strength reduction at arbitrary points and Mohr-Coulomb yield criterion was established and limit displacement subsidence values under the safety factor of different limit stoping steps were calculated.The results from three years in-situ mining and strata movement monitoring using multi-point displacements meter showed that the lower settlement frame stope hierarchical level filling mining method,mining sequence are reasonable and rockmass stability evaluation using safety factor method,in-situ real-time monitoring can provide the technical foundation for the safety of seabed mining.
