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Perspectives on water quality analysis emphasizing indexing,modeling,and application of artificial intelligence for comparison and trend forecasting
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作者 Rijurekha Dasgupta Subhasish Das +1 位作者 Gourab Banerjee Asis Mazumdar 《River》 2025年第2期265-286,共22页
reshwater essential for civilization faces risk from untreated effluents discharged by industries,agriculture,urban areas,and other sources.Increasing demand and abstraction of freshwater deteriorate the pollution sce... reshwater essential for civilization faces risk from untreated effluents discharged by industries,agriculture,urban areas,and other sources.Increasing demand and abstraction of freshwater deteriorate the pollution scenario more.Hence,water quality analysis(WQA)is an important task for researchers and policymakers to maintain sustainability and public health.This study aims to gather and discuss the methods used for WQA by the researchers,focusing on their advantages and limitations.Simultaneously,this study compares different WQA methods,discussing their trends and future directions.Publications from the past decade on WQA are reviewed,and insights are explored to aggregate them in particular categories.Three major approaches,namely—water quality indexing,water quality modeling(WQM)and artificial intelligence-based WQM,are recognized.Different methodologies adopted to execute these three approaches are presented in this study,which leads to formulate a comparative discussion.Using statistical operations and soft computing techniques have been done by researchers to combat the subjectivity error in indexing.To achieve better results,WQMs are being modified to incorporate the physical processes influencing water quality more robustly.The utilization of artificial intelligence was primarily restricted to conventional networks,but in the last 5 years,implications of deep learning have increased rapidly and exhibited good results with the hybridization of feature extracting and time series modeling.Overall,this study is a valuable resource for researchers dedicated to WQA. 展开更多
关键词 deep learning water quality analysis water quality index water quality modeling
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Application of Argo Data in the Analysis of Water Masses in the Northwest Pacific Ocean 被引量:3
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作者 孙朝辉 许建平 +2 位作者 刘增宏 童明荣 朱伯康 《Marine Science Bulletin》 CAS 2008年第2期1-13,共13页
The temperature and salinity distributions, and the water mass structures in Northwest Pacific Ocean are studied using the temperature and salinity data obtained by Argo profiling floats. The T-S relation in this regi... The temperature and salinity distributions, and the water mass structures in Northwest Pacific Ocean are studied using the temperature and salinity data obtained by Argo profiling floats. The T-S relation in this region indicates there exist 8 water masses, they are the North Pacific Tropical Surface Water (NPTSW), North P, acific Subsurface Water (NPSSW), North Pacific Intermediate Water (NPIW), North Pacific Subtropical Water (NPSTW), North Pacific Deep Water (NPDW) and Equatorial Surface Water (ESW), and the South Pacific Subsurface Water (SPSSW) and South Pacific Intermediate Water (SPIW). 展开更多
关键词 Argo profiling float T-S relation water mass analysis the Northwest Pacific Ocean
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Integration of solid phase extraction with HILIC-MS/MS for analysis of free amino acids in source water 被引量:4
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作者 Junlang Qiu Caley Craven +2 位作者 Nicholas Wawryk Kristin Carroll Xing-Fang Li 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2022年第7期190-196,共7页
Amino acids(AAs) are prevalent in source water, particularly during spring run-off. Monitoring of amino acids in source water is desirable for water treatment plants(WTP) to indicate changes in source water quality. T... Amino acids(AAs) are prevalent in source water, particularly during spring run-off. Monitoring of amino acids in source water is desirable for water treatment plants(WTP) to indicate changes in source water quality. The objective of this study was to establish analytical procedures for reliable monitoring of amino acids in source water. Therefore, we examined two different methods, large volume inject(LVI) and solid phase extraction(SPE), for sample preparation prior to HILIC-MS/MS. The LVI-HILIC-MS/MS method can provide fast and sensitive detection for clean samples, but suffers from matrix effects, resulting in irreproducible separation and shortening column lifetime. We have demonstrated that SPE was necessary prior to HILIC-MS/MS to achieve reproducible and reliable quantification of AAs in source water. A natural heterocyclic amine 1-methyl-1,2,3,4-tetrahydro-β-carboline-3-carboxylic acid(MTCCA) was also included in the method to indicate changes in other natural nitrogenous compounds in source water. The SPE-HILIC-MS/MS method was able to achieve limits of detection from 2.6-3400 ng/L for the amino acids and MTCCA with RSDs( n = 3) of 1.1%-4.8%. As well, retention times(RT) of the analytes were reproducible with variation less than 0.01 min( n = 3) through the entire project. We further applied the SPE-HILICMS/MS method to determine AAs in authentic source water samples collected from two drinking water treatment plants(WTPs) during the 2021 spring run-off season. The results support that the SPE-HILIC-MS/MS method does not require derivatization and can provide reliable, accurate, and robust analysis of AAs and MTCCA in source water, supporting future monitoring of source water quality. 展开更多
关键词 water analysis Disinfection byproducts Amino acids HPLC MS HILIC
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Spectrofluorimetric Analysis of the Fungicide Carbendazim and Its Metabolite 2-Aminobenzimidazole in Natural Water
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作者 Diene Diegane Thiare Abdourakhmane Khonte +5 位作者 Amadou Diop Alphonse Mendy Atanasse Coly Francois Delattre Mame Diabou Gaye-Seye Alphonse Tine 《American Journal of Analytical Chemistry》 2015年第9期767-775,共9页
A spectrofluorimetric method for the direct analysis of carbendazim [methyl 2-benzimidazole carbamate (MBC)] fungicide and its metabolite 2-aminobenzimidazole (2-AB) in natural waters is described. Very low limit of d... A spectrofluorimetric method for the direct analysis of carbendazim [methyl 2-benzimidazole carbamate (MBC)] fungicide and its metabolite 2-aminobenzimidazole (2-AB) in natural waters is described. Very low limit of detection (LOD) and limit of quantification (LOQ) values of 0.002 - 0.06 ng/mL and 0.006 - 0.2 ng/mL, respectively, were determined by spectrofluorimetric method with small relative standard deviation (RSD) values < 1%. This spectrofluorimetric method was applied to the determination of MBC and 2-AB residues in natural waters, with satisfactory recovery values of (88.5% - 119.2%). 展开更多
关键词 CARBENDAZIM 2-Aminobenzimidazole water analysis FLUORESCENCE Analytical Method
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High-throughput miniaturized purge-and-trap device integrating semiconductor refrigeration storage for on-site extraction and long-term preservation of VOCs in water
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作者 Yuan Yang Yue Wang +4 位作者 Xi Wang Hanshuang Li Xiaoli Wu Yurong Deng Chengbin Zheng 《Chinese Chemical Letters》 2025年第10期558-562,共5页
To accomplish on-site separation, preconcentration and cold storage of highly volatile organic compounds(VOCs) from water samples as well as their rapid transportation to laboratory, a high-throughput miniaturized pur... To accomplish on-site separation, preconcentration and cold storage of highly volatile organic compounds(VOCs) from water samples as well as their rapid transportation to laboratory, a high-throughput miniaturized purge-and-trap(μP&T) device integrating semiconductor refrigeration storage was developed in this work. Water samples were poured into the purge vessels and purged with purified air generated by an air pump. The VOCs in water samples were then separated and preconcentrated with sorbent tubes. After their complete separation and preconcentration, the tubes were subsequently preserved in the semiconductor refrigeration unit of the μP&T device. Notably, the high integration, small size, light weight, and low power consumption of the device makes it easy to be hand-carried to the field and transport by drone from remote locations, significantly enhancing the flexibility of field sampling. The performances of the device were evaluated by comparing analytical figures of merit for the detection of four cyclic volatile methylsiloxanes(cVMSs) in water. Compared to conventional collection and preservation methods, our proposed device preserved the VOCs more consistently in the sorbent tubes, with less than 5% loss of all analytes, and maintained stability for at least 20 days at 4℃. As a proof-of-concept,10 municipal wastewater samples were pretreated using this device with recoveries ranging from 82.5% to 99.9% for the target VOCs. 展开更多
关键词 PURGE-AND-TRAP High throughput Semiconductor refrigeration storage On-site extraction Volatile organic compounds water analysis
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Hydrological behaviour and water balance analysis for Xitiaoxi catchment of Taihu Basin 被引量:3
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作者 Xue Lijuan Li Lijiao Zhang Qi 《Water Science and Engineering》 EI CAS 2008年第3期44-53,共10页
With the rapid social and economic development of the Taihu region, Taihu Lake now faces an increasingly severe eutrophication problem. Pollution from surrounding catchments contributes greatly to the eutrophication o... With the rapid social and economic development of the Taihu region, Taihu Lake now faces an increasingly severe eutrophication problem. Pollution from surrounding catchments contributes greatly to the eutrophication of water bodies in the region. Investigation of surface flow and associated mass transport for the Xitiaoxi catchment is of a significant degree of importance as the Xitiaoxi catchment is one of the major catchments within the Taihu region. A SWAT-based distributed hydrological model was established for the Xitiaoxi catchment. The model was calibrated and verified using hydrometeorological data from 1988 to 2001. The results indicate that the modeled daily and annual stream flow match the observed data both in the calibration period and the verification period, with a linear regression coefficient R2 and a coefficient e for modeled daily stream flow greater than 0.8 at Hengtangcun and Fanjiacun gauge stations. The results show that the runoff process in the Xitiaoxi catchment is affected both by rainfall and human activities (e.g., reservoirs and polder areas). Moreover, the human activities weaken flood peaks more noticeably during rainstorms. The Water balance analysis reveals the percentages of precipitation made up by surface flow, evapotranspiration, groundwater recharge' and the change of soil storage, all of which are considered useful to the further understanding of the hydrological processes in the Xitiaoxi catchment. This study provides a good base for further studies in mass transport modeling and comparison of modeling results from similar hydrological models. 展开更多
关键词 water balance analysis distributed hydrological model SWAT model Xitiaoxi catchment Taihu Lake
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Analysis and control on anomaly water inrush in roof of fully-mechanized mining field 被引量:3
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作者 Peng Linjun Yang Xiaojie Sun Xiaoming 《Mining Science and Technology》 EI CAS 2011年第1期89-92,共4页
Caving of mine roofs from water inrush due to anomalous pressure is one of the major disasters and accidents that can occur in mines during production.Roof water inrush can trigger a wide range of roof collapse,causin... Caving of mine roofs from water inrush due to anomalous pressure is one of the major disasters and accidents that can occur in mines during production.Roof water inrush can trigger a wide range of roof collapse,causing major accidents from breaking roof supports while caving.These failures flood wells and do a great deal of damage to mines and endanger mine safety.Our objective is to analyze the anomalies of water inrush crushing the support at the #6301 working face in the Jisan Coal Mine of the Yanzhou Mining Group.Through information of water inrush to the roof,damage caused by tectonic movements,information on the damage caused by roof collapse and the theory about the distribution of pressure in mine abutments,we advice adjusting the length of the working face and the position of open-off cut relatively to the rich water area.In the case of anomalous roof pressure we should develop a state equation to estimate preventive measures with"transferring rock beam"theory.Simultaneously, we improve the capacity of drainage equipment and ensured adequate water retention at the storehouse. These are all major technologies to ensure the control and prevention against accidents caused by anomalous water inrush in roofs,thus ensuring safety in the production process of a coal mine. 展开更多
关键词 Roof water inrush pressure Anomaly analysis Control
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Research of Water Quality Analysis,Treatment and Reuse Technology for Rainwater on the North University Campus 被引量:1
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作者 Chen Shufang Shi Jingwei +1 位作者 Shao Yanjun Tu Chao 《Meteorological and Environmental Research》 CAS 2018年第1期62-65,共4页
The pollution situation of different underlying surface and the change rule of each water quality index were researched,on the basis of rainwater quality monitoring by different approaches in a university campus. The ... The pollution situation of different underlying surface and the change rule of each water quality index were researched,on the basis of rainwater quality monitoring by different approaches in a university campus. The results showed that due to some factors,such as the underlying surface material pollution,road materials,road surface pollution condition and surrounding atmospheric environment quality,the pollution of different underlying surface rainwater would be different. Main pollutants of rainwater runoff in the city campus area were such as COD,SS,NH;-N,TP,etc. Ultimately,along with the increase of accumulated rainfall,the pollutants tended to gradually decrease. The road rain pollution was more serious than roof runoff pollution and the early rain pollution was serious,but the late rain water quality was much better. According to the rainwater conditions,subsequent rainwater recycling technology and processing technology were determined as a way to alleviate the problem of water shortage and water pollution. 展开更多
关键词 NORTH Rainwater on campus water quality analysis Variation rule Reuse technology
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Provenance analysis of surface sediments in the Holocene mud area of the southern coastal waters off Shandong Peninsula,China 被引量:6
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作者 ZHANG Xiaobo BI Shipu +5 位作者 ZHANG Yong YANG Yuan LIU Shanshan KONG Xianghuai LI Xiaoyue CHU Hongxian 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2016年第5期124-133,共10页
The sedimentary record of mud areas is an important carrier of information on the Holocene evolution of marine environments. Based on fine interpretations of the shallow stratigraphic section data, a small mud deposit... The sedimentary record of mud areas is an important carrier of information on the Holocene evolution of marine environments. Based on fine interpretations of the shallow stratigraphic section data, a small mud deposit area has been found in the southern coastal waters off Shandong Peninsula. This mud area is mainly distributed in coastal waters north of Laoshantou to the vicinity of Rushan Estuary. Overall, it is parallel to the coastline and spreads in a banded pattern, gradually thinning from offshore to the sea. The isopach map of depth distribution is parallel with the shoreline, and the depocenter lies in coastal waters of the Aoshan Bay where the maximum thickness is up to 22.5 m. Accelerator mass spectrometry(AMS) ^(14)C dating shows that the mud area was formed in the Holocene. The test data of surface sediments from the mud area, including particle size, mineral characteristics, and rare earth element contents, are used in comparisons with the composition of materials from the major surrounding medium and small rivers flowing into the sea and the Huanghe(Yellow) River. In this paper, the sedimentary characteristics and provenance of the mud deposit area are discussed. The results show that the formation of this mud area resulted from the joint action of the Huanghe River and surrounding rivers flowing into the sea. 展开更多
关键词 southern coastal waters off Shandong Peninsula mud area provenance analysis
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Chemical Analysis of Water and the Resource of Br,K Prospects of Oilfield Brines from Ordovician and Carboniferous in Tarim,China 被引量:1
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作者 SU Kui ZHENG Mianping +2 位作者 CHEN Lixin LI Baohua CHEN Yongquan 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2014年第S1期250-250,共1页
China is lack of bromine and potassium seriously.Oilfield brines is the headline goal of bromine and potassium resources exploration.Applicants grab 24oilfield brines samples from various wells of Ordovician
关键词 Chemical analysis of water and the Resource of Br K Prospects of Oilfield Brines from Ordovician and Carboniferous in Tarim China BR
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Analysis of Water and Soil Quality Characteristics in Turpan City
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作者 RABIYAM Mamat ABDISALAM Jialaldin GULHAN Amar 《Meteorological and Environmental Research》 CAS 2013年第11期44-46,共3页
[ Objective] The study aimed to analyze water and soil quality characteristics in Turpan City. [ Method] According to Drinking Water Hy- gienic Standards (GB5749-2006) and Standards for Irrigation Water Quality (GB... [ Objective] The study aimed to analyze water and soil quality characteristics in Turpan City. [ Method] According to Drinking Water Hy- gienic Standards (GB5749-2006) and Standards for Irrigation Water Quality (GB5084-2005), five kinds of water samples collected from a karez, motor-pumped well, canal, village well and Aydingkol Lake in Turpan City as well as two types of soil samples irrigated by the karez and motor- pumped well water were analyzed in quality. [ Remit] Chloride and sulfate content in the village well and Aydingkol Lake water were higher than their limits in Dnnking Water Hygienic Standards, as well as sulfate content in the motor-pumped well and canal water. However, chloride and sul- fate content in the karez water did not exceed their limits. The soil irrigated by the karez water was salinized slightly, and organic matter content was higher; the soil irrigated by the motor-pumped well water was salinized seriously, and organic matter content was lower. [ Conclusion] The karez water is more applicable to farmland irrigation. 展开更多
关键词 water quality analysis Soil quality analysis Turpan City China
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Groundwater Quality Analysis and Vulnerability Assessment in Longdong Area
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作者 Mao Huaixin Ren Xiaorong +1 位作者 Zhou Lihui Li Yan 《Meteorological and Environmental Research》 CAS 2014年第10期49-51,55,共4页
Groundwater is important drinking water source in Longdong area. In recent years,as gradual expanding of industrial and agricultural production scales,seen from change trend of water quality,major impact factors of gr... Groundwater is important drinking water source in Longdong area. In recent years,as gradual expanding of industrial and agricultural production scales,seen from change trend of water quality,major impact factors of groundwater in the zone were ammonia nitrogen,COD,sulfate and total dissolved solid. By using specific thought of parameter system method,vulnerability assessment factor system of groundwater and meter point system calculation model in the zone were established. Via calculation and analysis,vulnerability distribution of groundwater in the zone was obtained. According to vulnerability index( higher,moderate and lower),zone dividing was conducted,and the areas were respectively 623. 25,4 005. 00 and 6 621. 75 km2,which respectively accounted for 5.54%,35. 60% and 58. 86%. The evaluation provided research basis for prevention,control and protection of groundwater environment in Longdong area. 展开更多
关键词 GROUNDwater Vulnerability assessment water quality analysis Longdong area China
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Preliminary analysis of distribution and variation of perennialmonthly mean water masses in the Bohai Sea,the Huanghai Sea and the East China Sea 被引量:6
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作者 Liu Shuxun, Shen Xinqiang, Wang Youqin and Han Shixin 1. East China Sea Fisheries Research Institute, No. 300, Jungong Road, Shanghai 200090, China 《Acta Oceanologica Sinica》 SCIE CAS CSCD 1992年第4期483-498,共16页
On the basis of perennial monthly mean temperature and salinity data, the classification of monthly water masses at the surface and the bottom in the Bohai Sea, the Huanghai Sea and the East China Sea, has been made b... On the basis of perennial monthly mean temperature and salinity data, the classification of monthly water masses at the surface and the bottom in the Bohai Sea, the Huanghai Sea and the East China Sea, has been made by using the method of fuzzy cluster from the modified characteristic of water masses in the shallow water area. In this paper, the basic features, growth and decline patterns of water masses in relation to fishing grounds in the whole shelves of the Bohai Sea, the Huanghai Sea and the East China Sea are discussed with emphasis. 展开更多
关键词 Preliminary analysis of distribution and variation of perennialmonthly mean water masses in the Bohai Sea the Huanghai Sea and the East China Sea
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APPLICATION OF REMOTE SENSING IN THE ANALYSIS OF WATER ENVIRONMENT IN ZHUJIANG RIVER ESTUARY
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作者 Rao Kaiyan (The Scientific Research Institute, Zhujiang River Water Resource Commission) Gu Qiushen, Li Xia, Liao Qifang (Guangzhou Institute of Geography) 《遥感信息》 CSCD 1990年第A02期19-20,共2页
1. PREFACE Lingdingyang is a trumpet estuary. It accepts the runoff of the Dongjiang River, the Beijiang River, the Zhengjiang River and the Liusihe River. It also accepts a part of the runoff of the Xijiang River. It... 1. PREFACE Lingdingyang is a trumpet estuary. It accepts the runoff of the Dongjiang River, the Beijiang River, the Zhengjiang River and the Liusihe River. It also accepts a part of the runoff of the Xijiang River. Its mean year runoff is 1.742×10" M^3. In resent ten years, industry and agriculture are developing rapidly in Guangzhou City, Dongguan City, Zhongshan City, Shunde County, Panyu County. Lingdingyang’s pollution is increesing. Water quality of lingdingyang is steadily deteriorated. In order to investigate the situation of water environment of Lingdingyang, we study its static environmental capacity of nitrogen and phosphorus. LANDSAT imageries are used in the study. The concentrations of nitrogen and phosphorous is detected by convention method. 展开更多
关键词 APPLICATION OF REMOTE SENSING IN THE analysis OF water ENVIRONMENT IN ZHUJIANG RIVER ESTUARY 习占
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Water Environmental Impact Assessment and Analysis of Foshan Brewery Project
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作者 Jianqiao QIN Jierong CHEN +7 位作者 Donghang JIANG Tianxian TANG Xiangxuan WU Huiling WANG Yingli JIE Zemin ZHENG Haojia XU Xiaoxiao LIAO 《Meteorological and Environmental Research》 CAS 2023年第2期66-71,77,共7页
In recent years, the beer industry is a biological food industry that consumes a lot of water, and it has developed rapidly in China. The sewage discharged from the mass production of beer poses a huge threat to the e... In recent years, the beer industry is a biological food industry that consumes a lot of water, and it has developed rapidly in China. The sewage discharged from the mass production of beer poses a huge threat to the environment. In order to evaluate and better solve the possible environmental impacts of beer treatment engineering projects, a brewery project in Foshan City is taken as an example to investigate the water pollution generation links of the engineering process including surface water and groundwater. According to the relevant technical methods and standards, water pollution factors are screened, and concentration and discharge are monitored. Through comprehensive analysis, predictive evaluation is obtained. It is confirmed that the project meets the requirements of national laws and regulations and environmental protection standards. 展开更多
关键词 Brewery project engineering water environment evaluation and analysis Improved A 2/O process
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Predictive analysis of stress regime and possible squeezing deformation for super-long water conveyance tunnels in Pakistan
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作者 Wang Chenghu Bao Linhai 《International Journal of Mining Science and Technology》 SCIE EI 2014年第6期825-831,共7页
The prediction of the stress field of deep-buried tunnels is a fundamental problem for scientists and engineers. In this study, the authors put forward a systematic solution for this problem. Databases from the World ... The prediction of the stress field of deep-buried tunnels is a fundamental problem for scientists and engineers. In this study, the authors put forward a systematic solution for this problem. Databases from the World Stress Map and the Crustal Stress of China, and previous research findings can offer prediction of stress orientations in an engineering area. At the same time, the Andersonian theory can be used to analyze the possible stress orientation of a region. With limited in-situ stress measurements, the Hock-Brown Criterion can be used to estimate the strength of rock mass in an area of interest by utilizing the geotechnical investigation data, and the modified Sheorey's model can subsequently be employed to predict the areas' stress profile, without stress data, by taking the existing in-situ stress measurements as input parameters. In this paper, a case study was used to demonstrate the application of this systematic solution. The planned Kohala hydropower plant is located on the western edge of Qinghai-Tibet Plateau. Three hydro-fracturing stress measurement campaigns indicated that the stress state of the area is SH - Sh 〉 Sv or SH 〉Sv 〉 Sh. The measured orientation of Sn is NEE (N70.3°-89°E), and the regional orientation of SH from WSM is NE, which implies that the stress orientation of shallow crust may be affected by landforms. The modified Sheorey model was utilized to predict the stress profile along the water sewage tunnel for the plant. Prediction results show that the maximum and minimum horizontal principal stres- ses of the points with the greatest burial depth were up to 56.70 and 40.14 MPa, respectively, and the stresses of areas with a burial depth of greater than 500 m were higher. Based on the predicted stress data, large deformations of the rock mass surrounding water conveyance tunnels were analyzed. Results showed that the large deformations will occur when the burial depth exceeds 300 m. When the burial depth is beyond 800 m, serious squeezing deformations will occur in the surrounding rock masses, thus requiring more attention in the design and construction. Based on the application efficiency in this case study, this prediction method proposed in this paper functions accurately. 展开更多
关键词 Super-long water conveyance tunnel In-situ stress state Squeezing deformation Prediction analysis Kohala hydropower plant
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Quantitative analysis on water head variation resulted from pumping and its function
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《Global Geology》 1998年第1期115-115,共1页
关键词 HEAD Quantitative analysis on water head variation resulted from pumping and its function
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System analysis of structure of water resources and eco-environment in Yellow river delta,China
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《Global Geology》 1998年第1期60-60,共1页
关键词 System analysis of structure of water resources and eco-environment in Yellow river delta China
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Analysis of the influence of exploiting water closing to the river on the regional environment in northern suburb water resource of Zhengzhou
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《Global Geology》 1998年第1期104-104,共1页
关键词 analysis of the influence of exploiting water closing to the river on the regional environment in northern suburb water resource of Zhengzhou
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Determination of Ultratrace Amounts of Copper(Ⅱ) in Water Samples by Electrothermal Atomic Absorption Spectrometry After Cloud Point Extraction 被引量:10
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作者 CHEN Jian-guo CHEN neng-wu +2 位作者 CHEN Shao-hong LIN Li ZHONG Ying-ying 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2007年第2期143-147,共5页
A novel approach was developed for the determination of ultratrace amounts of copper in water samples by using electrothermal atomic absorption spectrometry (ETAAS) after cloud point extraction ( CPE ). 1-( 2-Pyr... A novel approach was developed for the determination of ultratrace amounts of copper in water samples by using electrothermal atomic absorption spectrometry (ETAAS) after cloud point extraction ( CPE ). 1-( 2-Pyridylazo ) -2- naphthol was used as the chelating reagent and Triton X-114 as the mieellar-forming surfactant. CPE was conducted in a pH 8. 0 medium at 40 ℃ for 10 rain. After the separation of the phases by contrifugafion, the surfactant-rieh phase was diluted with 1 mL of a methanol solution of 0. 1 mol/L HNO3. Then 20μL of the diluted surfactant-rieh phase was injected into the graphite furnace for atomization in the absence of any matrix modifier. Various experimental conditions that affect the extraction and atomization processes were optimized. A detection limit of 5 ng/L was obtained after preconeentration. The linear dynamic range of the copper mass concentration was found to be 0-2.0 ng/mL, and the relative standard deviation was found to be less than 3. 1% for a sample containing 1.0 ng/mL Cu ( Ⅱ ). This developed method was successfully applied to the determination of uhratraee amounts of Cu in drinking water, tap water, and seawater samples. 展开更多
关键词 Cloud point extraction Preconeentration Electrothermal atomic absorption spectrometry Copper( Ⅱ) water analysis
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