The Arno River Basin(Central Italy)is affected by a considerable anthropogenic pressure due to the presence of large cities and widespread industrial and agricultural practices.In this work,26 water samples from the A...The Arno River Basin(Central Italy)is affected by a considerable anthropogenic pressure due to the presence of large cities and widespread industrial and agricultural practices.In this work,26 water samples from the Arno River and its main tributaries were analyzed to assess the water pollution status.The geochemical composition of the Arno River changes from the source(dominated by a Ca-HCO_(3) facies)to the mouth(where a Na-Cl(SO4)chemistry prevails)with an increasing quality deterioration,as suggested by the Chemical Water Quality Index,due to anthropogenic contributions and seawater intrusion before flowing into the Ligurian Sea.The Ombrone and Usciana tributaries introduce anthropogenic pollutants into the Arno River,whilst Elsa tributary supplies significant contents of geogenic sulfate.The concentrations of dissolved nitrate and nitrite(up to 63 and 9 mg/L,respectively)and the respective isotopic values of𝛿15N and𝛿18O were also determined to understand origin and fate of the N-species in the Arno River Basin surface waters.The combined application of𝛿15N-NO_(3) and𝛿18O-NO_(3) and N-source apportionment modelling allowed the identification of soil organic nitrogen and sewage and domestic wastes as primary sources for dissolved NO_(3)-.The𝛿15N-NO_(2) and𝛿18O-NO_(2) values suggest that the nitrification process affects the ARB waters,thus controlling the abundances and proportion of the N-species.Our work indicates that additional efforts are needed to improve management strategies to reduce the release of nitrogenated species to the surface waters of the Arno River Basin,since little progress has been made from the early 2000s.展开更多
Sustainable water,energy and food(WEF)supplies are the bedrock upon which human society depends.Solar-driven interfacial evaporation,combined with electricity generation and cultivation,is a promising approach to miti...Sustainable water,energy and food(WEF)supplies are the bedrock upon which human society depends.Solar-driven interfacial evaporation,combined with electricity generation and cultivation,is a promising approach to mitigate the freshwater,energy and food crises.However,the performance of solar-driven systems decreases significantly during operation due to uncontrollable weather.This study proposes an integrated water/electricity cogeneration-cultivation system with superior thermal management.The energy storage evaporator,consisting of energy storage microcapsules/hydrogel composites,is optimally designed for sustainable desalination,achieving an evaporation rate of around 1.91 kg m^(-2)h^(-1).In the dark,heat released from the phase-change layer supported an evaporation rate of around 0.54kg m^(-2)h^(-1).Reverse electrodialysis harnessed the salinity-gradient energy enhanced during desalination,enabling the long-running WEC system to achieve a power output of~0.3 W m^(-2),which was almost three times higher than that of conventional seawater/surface water mixing.Additionally,an integrated crop irrigation platform utilized system drainage for real-time,on-demand wheat cultivation without secondary contaminants,facilitating seamless WEF integration.This work presents a novel approach to all-day solar water production,electricity generation and crop irrigation,offering a solution and blueprint for the sustainable development of WEF.展开更多
Petroleum leakage is a major groundwater contamination source,with chemical composition of water soluble fractions(WSFs)from diverse oil sources significantly impacting groundwater quality and source identification.Th...Petroleum leakage is a major groundwater contamination source,with chemical composition of water soluble fractions(WSFs)from diverse oil sources significantly impacting groundwater quality and source identification.The aim of this study was to assess impact of 15 diverse oils on groundwater quality and environmental forensics based on oil-water equilibrium experiments.Our results indicate that contamination of groundwater by gasoline and naphtha is primarily attributed to volatile hydrocarbons,while pollution from diesel,kerosene,and crude oil is predominantly from non-hydrocarbons.Rapid determination of the extent of non-hydrocarbon pollution in WSFs was achieved through a new quantitative index.Gasoline and naphtha exhibited the highest groundwater contamination potential while kerosene and light crude oils were also likely to cause groundwater contamina-tion.Although volatile hydrocarbons in the WSFs of diesel and jet fuel do not easily exceed current regulatory standards,unregulated non-hydrocarbons may pose a more severe contamination risk to groundwater.Notably,the presence of significant benzene and toluene,hydrogenation and alkylation products(e.g.,C4-C5 alkylben-zenes,alkylindenes,alkyltetralins,and dihydro-indenes),cycloalkanes in WSFs can effectively be utilized for preliminary source identification of light distillates,middle distillates,and crude oils,respectively.展开更多
The integration of Artificial Intelligence(AI)and Machine Learning(ML)into groundwater exploration and water resources management has emerged as a transformative approach to addressing global water challenges.This rev...The integration of Artificial Intelligence(AI)and Machine Learning(ML)into groundwater exploration and water resources management has emerged as a transformative approach to addressing global water challenges.This review explores key AI and ML concepts,methodologies,and their applications in hydrology,focusing on groundwater potential mapping,water quality prediction,and groundwater level forecasting.It discusses various data acquisition techniques,including remote sensing,geospatial analysis,and geophysical surveys,alongside preprocessing methods that are essential for enhancing model accuracy.The study highlights AI-driven solutions in water distribution,allocation optimization,and realtime resource management.Despite their advantages,the application of AI and ML in water sciences faces several challenges,including data scarcity,model reliability,and the integration of these tools with traditional water management systems.Ethical and regulatory concerns also demand careful consideration.The paper also outlines future research directions,emphasizing the need for improved data collection,interpretable models,real-time monitoring capabilities,and interdisciplinary collaboration.By leveraging AI and ML advancements,the water sector can enhance decision-making,optimize resource distribution,and support the development of sustainable water management strategies.展开更多
Access to clean drinking water is essential for human health,economic development,and environmental sustain-ability.To effectively preserve water quality and ensure a safe and stable water supply,it is essential to de...Access to clean drinking water is essential for human health,economic development,and environmental sustain-ability.To effectively preserve water quality and ensure a safe and stable water supply,it is essential to determine the priority control factors of potentially hazardous elements in water.This study focused on public drinking wa-ter fountains in Zaječar City(Serbia),examining water hydrochemistry,quality,potential sources of hazardous elements,and the health risks associated with consumption or dermal exposure.Among all potentially hazardous elements,iron showed a deviation from the limit in drinking water prescribed by the World Health Organization,reaching 631μg/L.However,all samples were categorized as excellent quality for drinking.Water composition was governed by water-rock interactions,distinguishing Na-HCO_(3)as the dominant water type.A total of 3.3%and 6.6%of samples exceeded the threshold of 1 for non-carcinogenic health risk for adults and children,re-spectively,with the mean HIa value of 0.35 and the mean HIc value of 0.57.However,the carcinogenic risk was within the allowable limits for children,whereas it surpassed the threshold of 1.0×10^(–4)for adults in 10%of the samples.The positive matrix factorization model identified four sources responsible for water quality,i.e.,natural source,industrial source,sewage source,and agricultural source,with contributions of 37.1%,35.0%,17.8%,and 10.1%,respectively.The Monte Carlo simulation of source-specific health risks revealed that the industrial source was the main contributor to both non-carcinogenic and carcinogenic risks,attributed to its high arsenic load.展开更多
Values of individuals and organizations involved in decision-making processes form the basis for prioritizing outcomes in water governance.The novelty of this study lies in applying values to a specific decision-makin...Values of individuals and organizations involved in decision-making processes form the basis for prioritizing outcomes in water governance.The novelty of this study lies in applying values to a specific decision-making context.It aims to assess the prioritized water governance outcomes and the underlying value systems shaping the actions of the primary water utility responsible for water governance in Delhi,the Delhi Jal Board(DJB).The paper will critically examine the policies and acts of the DJB that drive water governance in Delhi at present,utilizing a values-based framework in conjunction with secondary literature and expert interviews,to draw a picture of the values reflected.The study does not substantiate the notion of economic values dominating the water-related deci-sions;rather,recent policy guidelines indicate prioritization of equitable and fair distribution of water.Findings of this paper show that making the values explicit is largely disregarded in formulating water acts and policies,and values are never elucidated in the public domain,doing which can encourage water policies and practices that are socially,economically,and ecologically viable in the long run.It is expected that this paper will generate a discussion on water values being an integral part of water governance discourses.展开更多
Electrochemical water splitting represents a sustainable technology for hydrogen(H_(2))production.However,its large-scale implementation is hindered by the high overpotentials required for both the cathodic hydrogen e...Electrochemical water splitting represents a sustainable technology for hydrogen(H_(2))production.However,its large-scale implementation is hindered by the high overpotentials required for both the cathodic hydrogen evolution reaction(HER)and the anodic oxygen evolution reaction(OER).Transition metal-based catalysts have garnered significant research interest as promising alternatives to noble-metal catalysts,owing to their low cost,tunable composition,and noble-metal-like catalytic activity.Nevertheless,systematic reviews on their application as bifunctional catalysts for overall water splitting(OWS)are still limited.This review comprehensively outlines the principal categories of bifunctional transition metal electrocatalysts derived from electrospun nanofibers(NFs),including metals,oxides,phosphides,sulfides,and carbides.Key strategies for enhancing their catalytic performance are systematically summarized,such as heterointerface engineering,heteroatom doping,metal-nonmetal-metal bridging architectures,and single-atom site design.Finally,current challenges and future research directions are discussed,aiming to provide insightful perspectives for the rational design of high-performance electrocatalysts for OWS.展开更多
The discharge of micro-polluted water from sources such as agricultural runoff,urban stormwater,and treated effluents presents significant challenges to aquatic ecosystems.Constructed wetlands(CWs)have gained recog-ni...The discharge of micro-polluted water from sources such as agricultural runoff,urban stormwater,and treated effluents presents significant challenges to aquatic ecosystems.Constructed wetlands(CWs)have gained recog-nition as an eco-friendly solution for removing pollutants from various wastewater sources and are increasingly applied for micro-polluted water treatment.By reviewing 78 full-scale CW studies from Web of Science,it is summarized that the ranges of ammonium nitrogen(NH4+-N)concentrations in runoff,wastewater treatment plant effluent and polluted river were 0.1–6.6,0.3–12.3,and 0.2–41.1 mg/L,respectively.The ranges of ni-trate nitrogen concentrations were 0.2–14.2,0–5.7,and 0–2.6 mg/L,respectively.Removal efficiencies of CWs for micro-polluted water varied by CW types.The total nitrogen removal efficiencies for subsurface-flow CWs,free-water surface-flow CWs,and hybrid CWs ranged from 27.4%to 66.5%,16.8%to 89.8%,and 19.4%to 88.2%,respectively.The NH4+-N removal efficiencies ranged from 34.2%to 73.6%,38.4%to 89.4%and 13.5%to 94.2%,respectively.Additionally,other factors influencing contaminant removal efficiency such as hydraulic retention time,vegetation types,redox micro-environment and influent water quality were evaluated.Based on these findings,two strategies for improving the purification performance of CWs were proposed:the selection of incorporating electron donor substrates and the optimization of operation parameters.This paper serves as a synthesis of information to guide future research and full-scale CW applications in micro-polluted water treatment.展开更多
Nitrogen(N)and phosphorus(P)are essential nutrients and can significantly impact primary productivity of the ecosystem causing water environmental problems.However,their cycling mechanisms are not well understood in a...Nitrogen(N)and phosphorus(P)are essential nutrients and can significantly impact primary productivity of the ecosystem causing water environmental problems.However,their cycling mechanisms are not well understood in alpine mountains with climate change.Hence,94 samples of river water were collected from 2018 to 2020 in the headwaters of the Shule River Basin to assess the nutrients spatiotemporal distribution and combined ap-proach of water quality index to assess water quality and potential sources.The findings depict that high nutrient concentrations were found to coincide with snowmelt and glacial meltwater and rainfall recharge periods,while total flux peaked from June to September due to increased runoff.Notably,total nitrogen(TN)concentrations were significantly higher near the town,primarily attributed to the replenishment of nitrate(NO_(3)^(‒)-N)from live-stock manure.The high total P(TP)was near the glacier,which was attributed to the transportation of glacial sediments into the river,and pH was another critical factor.N was the primary nutrient limiting factor for the growth of phytoplankton in river water.Although the migration and transport of nutrients have altered with climate change,river water quality is good in alpine mountains based on an overall evaluation.These findings contribute to enriching nutrient datasets and highlight the importance of water resource management and water quality assessment in sensitive and fragile alpine mountains.展开更多
A trace analytical method based on solid-phase extraction gas chromatography-tandem mass spectrometry(SPE–GC–MS/MS)was developed for the rapid detection of 256 semi-volatile organic compounds(SVOCs),including 25 pol...A trace analytical method based on solid-phase extraction gas chromatography-tandem mass spectrometry(SPE–GC–MS/MS)was developed for the rapid detection of 256 semi-volatile organic compounds(SVOCs),including 25 polycyclic aromatic hydrocarbons(PAHs),70 polychlorinated biphenyls(PCBs),123 pesticides,20 phthalate esters(PAEs),4 organophosphate esters(OPEs),9 synthetic musks(SMs),and 5 UV filters(UVs)in water.No-tably,this method provided a decent linearity of calibration standards(R^(2)>0.999),excellent method limits of quantification(MLOQs)(0.12–11.41 ng/L),satisfactory matrix spiking recovery rates(60.4%–126%),and high precision(intra-day relative standard deviations(RSDs):1.0%–10.0%,inter-day RSDs:3.0%–15.0%,and inter-week RSDs:3.4%–15.7%),making it suitable for trace-level studies.Statistical analysis revealed that SVOCs with higher volatility exhibited enhanced recovery rates.Validation of the methodology involved analyzing SVOCs in real spring water and river water samples.Twenty-seven SVOCs were detected in spring water and 58 in river water,with an average concentration of 631.73 and 16,095 ng/L,respectively.Among the detected SVOCs,PAEs constituted the predominant proportion.This study underscored the presence of SVOCs contamination specifi-cally within the spring water,although SVOCs concentrations in river water were significantly greater than those found in spring water.In summary,this sensitive method based on SPE–GC–MS/MS was successfully developed and validated for the rapid analysis of a diverse array of 256 SVOCs at trace levels in water,including not only the traditional highly valued PAHs,PCBs,pesticides,and PAEs,but also the emerging OPEs,UVs,and SMs.展开更多
Pulsed dynamic electrolysis(PDE),driven by renewable energy,has emerged as an innovative electrocatalytic conversion method,demonstrating significant potential in addressing global energy challenges and promoting sust...Pulsed dynamic electrolysis(PDE),driven by renewable energy,has emerged as an innovative electrocatalytic conversion method,demonstrating significant potential in addressing global energy challenges and promoting sustainable development.Despite significant progress in various electrochemical systems,the regulatory mechanisms of PDE in energy and mass transfer and the lifespan extension of electrolysis systems,particularly in water electrolysis(WE)for hydrogen production,remain insufficiently explored.Therefore,there is an urgent need for a deeper understanding of the unique contributions of PDE in mass transfer enhancement,microenvironment regulation,and hydrogen production optimization,aiming to achieve low-energy consumption,high catalytic activity,and long-term stability in the generation of target products.Here,this review critically examines the microenvironmental effects of PDE on energy and mass transfer,the electrode degradation mechanisms in the lifespan extension of electrolysis systems,and the key factors in enhancing WE for hydrogen production,providing a comprehensive summary of current research progress.The review focuses on the complex regulatory mechanisms of frequency,duty cycle,amplitude,and other factors in hydrogen evolution reaction(HER)performance within PDE strategies,revealing the interrelationships among them.Finally,the potential future directions and challenges for transitioning from laboratory studies to industrial applications are proposed.展开更多
High‐entropy amorphous catalysts(HEACs)integrate multielement synergy with structural disorder,making them promising candidates for water splitting.Their distinctive features—including flexible coordination environm...High‐entropy amorphous catalysts(HEACs)integrate multielement synergy with structural disorder,making them promising candidates for water splitting.Their distinctive features—including flexible coordination environments,tunable electronic structures,abundant unsaturated active sites,and dynamic structural reassembly—collectively enhance electrochemical activity and durability under operating conditions.This review summarizes recent advances in HEACs for hydrogen evolution,oxygen evolution,and overall water splitting,highlighting their disorder-driven advantages over crystalline counterparts.Catalytic performance benchmarks are presented,and mechanistic insights are discussed,focusing on how multimetallic synergy,amorphization effect,and in‐situ reconstruction cooperatively regulate reaction pathways.These insights provide guidance for the rational design of next‐generation amorphous high‐entropy electrocatalysts with improved efficiency and durability.展开更多
Andrew Wangota,a 48-year-old Ugandan farmer,has been using agrivoltaics technology,a solar technology that uses agricultural land for both food production and solar power generation,on his farm in Bunashimolo Parish,B...Andrew Wangota,a 48-year-old Ugandan farmer,has been using agrivoltaics technology,a solar technology that uses agricultural land for both food production and solar power generation,on his farm in Bunashimolo Parish,Bukyiende Subcounty in Uganda where he has been cultivating plantain,coffee and Irish potatoes for the past 16 years.展开更多
Laser-induced aerosols,predominantly submicron in size,pose significant environmental and health risks during the decommissioning of nuclear reactors.This study experimentally investigated the removal of laser-generat...Laser-induced aerosols,predominantly submicron in size,pose significant environmental and health risks during the decommissioning of nuclear reactors.This study experimentally investigated the removal of laser-generated aerosol particles using a water spray system integrated with an innovative system for pre-injecting electrically charged mist in our facility.To simulate aerosol generation in reactor decommissioning,a high-power laser was used to irradiate various materials(including stainless steel,carbon steel,and concrete),generating aerosol particles that were agglomerated with injected water mist and subsequently scavenged by water spray.Experimental results demonstrate enhanced aerosol removal via aerosol-mist agglomeration,with charged mist significantly improving particle capture by increasing wettability and size.The average improvements for the stainless steel,carbon steel,and concrete were 40%,44%,and 21%,respectively.The results of experiments using charged mist with different polarities(both positive and negative)and different surface coatings reveal that the dominant polarity of aerosols varies with the irradiated materials,influenced by their crystal structure and electron emission properties.Notably,surface coatings such as ZrO_(2)and CeO_(2)were found to possibly alter aerosol charging characteristics,thereby affecting aerosol removal efficiency with charged mist configurations.The innovative aerosol-mist agglomeration approach shows promise in mitigating radiation exposure,ensuring environmental safety,and reducing contaminated water during reactor dismantling.This study contributes critical knowledge for the development of advanced aerosol management strategies for nuclear reactor decommissioning.The understanding obtained in this work is also expected to be useful for various environmental and chemical engineering applications such as gas decontamination,air purification,and pollution control.展开更多
Economical,stable,and corrosion-resistant catalytic electrodes are still urgently needed for the oxygen evolution reaction(OER)in water and seawater.Herein,a mild electroless plating strategy is used to achieve large-...Economical,stable,and corrosion-resistant catalytic electrodes are still urgently needed for the oxygen evolution reaction(OER)in water and seawater.Herein,a mild electroless plating strategy is used to achieve large-scale preparation of the“integrated”phosphorus-based precatalyst(FeP-NiP)on nickel foam(NF),which is in situ reconstructed into a highly active and corrosion-resistant(Fe)NiOOH phase for OER.The interaction between phosphate anions(PO_(x)^(y-))and iron ions(Fe^(3+))tunes the electronic structure of the catalytic phase to further enhance OER kinetics.The integrated FeP-NiP@NF electrode exhibits low overpotentials for OER in alkaline water/seawater,requiring only 275/289,320/336,and 349/358 mV to reach 0.1,0.5,and 1.0 A cm^(−2),respectively.The in situ reconstructed PO_(x)^(y-)anion electrostatically repels Cl−in seawater electrolytes,allowing stable operation for over 7 days at 1.0 A cm^(−2) in extreme electrolytes(1.0 M KOH+seawater and 6.0 M KOH+seawater),demonstrating industrial-level stability.This study overcomes the complex synthesis limitations of P-based materials through innovative material design,opening new avenues for electrochemical energy conversion.展开更多
The Southern Ocean is a critical component in the Earth system by dominating the global heat and anthropogenic carbon uptake and supplying heat to melt the largest ice sheet.Variability and changes in the water masses...The Southern Ocean is a critical component in the Earth system by dominating the global heat and anthropogenic carbon uptake and supplying heat to melt the largest ice sheet.Variability and changes in the water masses of the Southern Ocean are thus important to the global energy and water cycles,carbon cycling,and sea-level change.In this article,we review the recent progress on understanding the variability and changes in the four major water masses in the Southern Ocean,including Subantarctic Mode Water,Antarctic Intermediate Water,Circumpolar Deep Water and Antarctic Bottom Water.Subantarctic Mode Water and Antarctic Intermediate Water show statistically significant strong circumpolar shoaling,warming,and density reductions since 1970s,indicating that signals of global warming have entered the interior ocean.Meanwhile,strong regional variability of Subantarctic Mode Water and Antarctic Intermediate Water responding to surface buoyancy forcing and westerly winds is attracting more attention.Circumpolar Deep Water is an important modulator of heat content and nutrient concentrations on continental shelves around Antarctica and has made significant contributions to the basal melting of Antarctic ice shelves.Since the late 1950s,a long-term freshening trend in Antarctic Bottom Water in the Ross Sea and its downstream region has been observed and is mainly attributed to the accelerated basal melting of ice shelves in West Antarctica.The shrinking of Antarctic Bottom Water in the Weddell Sea during 1992–2020 has also been revealed and is attributed to reduced sea ice production over the southern Weddell continental shelf related to the Interdecadal Pacific Oscillation and the variability in the Amundsen Sea Low.Though significant advances have been achieved,there is an urgent need to enhance and improve both observations and model performances for better understandings and projections of the formation,transformation,and transport of the water masses in the Southern Ocean.展开更多
Water scarcity in Khuzestan Province,Iran,has attracted growing concerns despite the region's abundant water resources.The province predominantly relies on surface water,prompting an assessment of groundwater'...Water scarcity in Khuzestan Province,Iran,has attracted growing concerns despite the region's abundant water resources.The province predominantly relies on surface water,prompting an assessment of groundwater's potential to supplement water supplies during surface water shortages.This study assesses the province's groundwater availability and quality under increased exploitation conditions.Between 2008 and 2018,data on groundwater quantity and quality were collected from 204 exploration wells and 70 piezometric wells across 19 aquifers.The analysis revealed that 53%of aquifers in the eastern and northeastern regions experienced declining groundwater levels.Hydrochemical assessments indicated low concentrations of major ions in the northeastern,while high levels were observed from the central region towards the southeast.These variations were attributed to agricultural and industrial activities,seawater intrusion,and the influences of evaporation and geological factors.The dominant hydrochemical facies identified were of the Ca-Cl type.Water quality classification showed that 48%of groundwater samples fell within the C4S4-C4S1 category,primarily in the western,central,and southern regions,while 27%were classified as C3S2,C3S1,and 25%as C2S1,mainly in the northern and eastern regions.The Irrigation WWater Quality(IWQ)index indicated that many samples were suitable for irrigation.Additionally,the analysis potable groundwater was primarily found in the northern,northeastern,and eastern aquifers,with quality declining toward the south.The study highlights that certain aquifers in the northern and eastern regions offer greater potential for sustainable groundwater exploitation during water shortages.These findings provide valuable insights for on how to implement effective land and water management strategies to mitigate future water crises.展开更多
Clarifying the mechanisms through which coal mining affects groundwater storage(GWS)variations is crucial for water resource conservation and sustainable development.The Ordos Mining Region in China,a key energy base ...Clarifying the mechanisms through which coal mining affects groundwater storage(GWS)variations is crucial for water resource conservation and sustainable development.The Ordos Mining Region in China,a key energy base in China with significant strategic importance,has undergone intensive coal mining activities that have substantially disrupted regional groundwater circulation.This study integrated data from the Gravity Recovery and Climate Experiment Satellite(GRACE)and Famine Early Warning Systems Network(FEWS NET)Land Data Assimilation System(FLDAS)models,combined with weighted downscaling methodology and water balance principles,to reconstruct high-resolution(0.01°)terrestrial water storage(TWS)and GWS changes in the Ordos Mining Region,China from April 2002 to December 2021.The accuracy of GWS variations were validated through pumping test measurements.Subsequently,Geodetector analysis was implemented to quantify the contributions of natural and anthropogenic factors to groundwater storage dynamics.Key findings include:1)TWS in the study area showed a fluctuating but overall decreasing trend,with a total reduction of 8901.11 mm during study period.The most significant annual decrease occurred in 2021,reaching 1696.77 mm.2)GWS exhibited an accelerated decline,with an average annual change rate of 44.35 mm/yr,totaling a decrease of 887.05 mm.The lowest annual groundwater storage level was recorded in 2020,reaching 185.69 mm.3)Precipitation(PRE)contributed the most to GWS variation(q=0.52),followed by coal mining water consumption(MWS)(q=0.41).The interaction between PRE and MWS exhibited a nonlinear enhancement effect on GWS changes(0.54).The synergistic effect of natural hydrological factors has a great influence on the change of GWS,but coal mining water consumption will continue to reduce GWS.These findings provide critical references for the management and regulation of groundwater resource in mining regions.展开更多
Groundwater,surface water and tap water contamination by PTEs(Potentially Toxic Elements)was assessed in Kipushi town and Lupoto locality of Kipushi administrative territory in the Upper-Katanga province,Democratic Re...Groundwater,surface water and tap water contamination by PTEs(Potentially Toxic Elements)was assessed in Kipushi town and Lupoto locality of Kipushi administrative territory in the Upper-Katanga province,Democratic Republic of Congo.A total of fifty four water samples including thirty two samples from drilled water wells,ten samples from spade-sunk water wells,six samples from supplied tap water,four samples from a mine effluent and two samples from a river were collected from both localities in November and December 2017 and in January,February and March 2018.Then the samples were analyzed for their PTE contents by ICP-SF-MS(Inductively Coupled Plasma-Sector Field Mass Spectrometry).Twenty PTEs including aluminum,arsenic,barium,bismuth,cadmium,cesium,chromium,cobalt,copper,iron,lead,manganese,molybdenum,nickel,strontium,thallium,tungsten,uranium,vanadium and zinc were detected at various concentrations in each one of the samples.Many samples had concentrations and mean concentrations of PTE,such as arsenic,aluminum,cadmium,iron,lead,manganese and zinc,higher than the respective acceptable limits set for drinking water by the EU(European Union),the USEPA(United States Environmental Protection Agency),and the WHO(World Health Organization)standards.Most PTEs being deleterious to human health even at very low concentrations,people who use the groundwater,surface water and tap water to meet their water needs in both localities are at risk.展开更多
Water scarcity poses a significant challenge globally,with South Africa exemplifying the severe socio-economic and environmental impacts of limited water access.Despite advances in modern water management systems,the ...Water scarcity poses a significant challenge globally,with South Africa exemplifying the severe socio-economic and environmental impacts of limited water access.Despite advances in modern water management systems,the integration of indigenous knowledge(IK)into formal frameworks remains underutilized.This study systematically reviews the role of indigenous water conservation practices in South Africa,analyzing over 50 high-quality sources using the PRISMA methodology.The findings highlight the effectiveness of IK in addressing water scarcity through techniques such as rainwater harvesting,terracing,and wetland management,which are low-cost,environmentally sustainable,and deeply rooted in cultural practices.Indigenous methods also enhance climate resilience by enabling communities to adapt to droughts and floods through practices such as weather prediction and adaptive farming techniques.Furthermore,these practices foster social inclusivity and community empowerment,ensuring equitable water access and intergenerational knowledge transfer.The study underscores the potential of integrating IK with modern water technologies to create holistic solutions that are scalable,sustainable,and aligned with South Africa’s goal of achieving water security by 2030.Policy recommendations emphasize the need for institutional support,data collection,and financial incentives to sustain and mainstream indigenous approaches.By bridging the gap between traditional and contemporary systems,this research provides a roadmap for leveraging diverse knowledge systems to address water scarcity and build resilient communities.展开更多
文摘The Arno River Basin(Central Italy)is affected by a considerable anthropogenic pressure due to the presence of large cities and widespread industrial and agricultural practices.In this work,26 water samples from the Arno River and its main tributaries were analyzed to assess the water pollution status.The geochemical composition of the Arno River changes from the source(dominated by a Ca-HCO_(3) facies)to the mouth(where a Na-Cl(SO4)chemistry prevails)with an increasing quality deterioration,as suggested by the Chemical Water Quality Index,due to anthropogenic contributions and seawater intrusion before flowing into the Ligurian Sea.The Ombrone and Usciana tributaries introduce anthropogenic pollutants into the Arno River,whilst Elsa tributary supplies significant contents of geogenic sulfate.The concentrations of dissolved nitrate and nitrite(up to 63 and 9 mg/L,respectively)and the respective isotopic values of𝛿15N and𝛿18O were also determined to understand origin and fate of the N-species in the Arno River Basin surface waters.The combined application of𝛿15N-NO_(3) and𝛿18O-NO_(3) and N-source apportionment modelling allowed the identification of soil organic nitrogen and sewage and domestic wastes as primary sources for dissolved NO_(3)-.The𝛿15N-NO_(2) and𝛿18O-NO_(2) values suggest that the nitrification process affects the ARB waters,thus controlling the abundances and proportion of the N-species.Our work indicates that additional efforts are needed to improve management strategies to reduce the release of nitrogenated species to the surface waters of the Arno River Basin,since little progress has been made from the early 2000s.
基金supported by the National Natural Science Foundation of China(No.52070057)China Postdoctoral Science Foundation(No.2023M730855)Heilongjiang Postdoctoral Fund(No.LBH-Z22183)for financial support。
文摘Sustainable water,energy and food(WEF)supplies are the bedrock upon which human society depends.Solar-driven interfacial evaporation,combined with electricity generation and cultivation,is a promising approach to mitigate the freshwater,energy and food crises.However,the performance of solar-driven systems decreases significantly during operation due to uncontrollable weather.This study proposes an integrated water/electricity cogeneration-cultivation system with superior thermal management.The energy storage evaporator,consisting of energy storage microcapsules/hydrogel composites,is optimally designed for sustainable desalination,achieving an evaporation rate of around 1.91 kg m^(-2)h^(-1).In the dark,heat released from the phase-change layer supported an evaporation rate of around 0.54kg m^(-2)h^(-1).Reverse electrodialysis harnessed the salinity-gradient energy enhanced during desalination,enabling the long-running WEC system to achieve a power output of~0.3 W m^(-2),which was almost three times higher than that of conventional seawater/surface water mixing.Additionally,an integrated crop irrigation platform utilized system drainage for real-time,on-demand wheat cultivation without secondary contaminants,facilitating seamless WEF integration.This work presents a novel approach to all-day solar water production,electricity generation and crop irrigation,offering a solution and blueprint for the sustainable development of WEF.
基金supported by the National Science Foundation of China(Nos.42177042,and 42477051)the National Key R&D Program of China(No.2023YFC3708700)the Science Foundation of China University of Petroleum-Beijing(No.2462022QNXZ006).
文摘Petroleum leakage is a major groundwater contamination source,with chemical composition of water soluble fractions(WSFs)from diverse oil sources significantly impacting groundwater quality and source identification.The aim of this study was to assess impact of 15 diverse oils on groundwater quality and environmental forensics based on oil-water equilibrium experiments.Our results indicate that contamination of groundwater by gasoline and naphtha is primarily attributed to volatile hydrocarbons,while pollution from diesel,kerosene,and crude oil is predominantly from non-hydrocarbons.Rapid determination of the extent of non-hydrocarbon pollution in WSFs was achieved through a new quantitative index.Gasoline and naphtha exhibited the highest groundwater contamination potential while kerosene and light crude oils were also likely to cause groundwater contamina-tion.Although volatile hydrocarbons in the WSFs of diesel and jet fuel do not easily exceed current regulatory standards,unregulated non-hydrocarbons may pose a more severe contamination risk to groundwater.Notably,the presence of significant benzene and toluene,hydrogenation and alkylation products(e.g.,C4-C5 alkylben-zenes,alkylindenes,alkyltetralins,and dihydro-indenes),cycloalkanes in WSFs can effectively be utilized for preliminary source identification of light distillates,middle distillates,and crude oils,respectively.
文摘The integration of Artificial Intelligence(AI)and Machine Learning(ML)into groundwater exploration and water resources management has emerged as a transformative approach to addressing global water challenges.This review explores key AI and ML concepts,methodologies,and their applications in hydrology,focusing on groundwater potential mapping,water quality prediction,and groundwater level forecasting.It discusses various data acquisition techniques,including remote sensing,geospatial analysis,and geophysical surveys,alongside preprocessing methods that are essential for enhancing model accuracy.The study highlights AI-driven solutions in water distribution,allocation optimization,and realtime resource management.Despite their advantages,the application of AI and ML in water sciences faces several challenges,including data scarcity,model reliability,and the integration of these tools with traditional water management systems.Ethical and regulatory concerns also demand careful consideration.The paper also outlines future research directions,emphasizing the need for improved data collection,interpretable models,real-time monitoring capabilities,and interdisciplinary collaboration.By leveraging AI and ML advancements,the water sector can enhance decision-making,optimize resource distribution,and support the development of sustainable water management strategies.
基金supported by the Ministry of Science,Technological Development and Innovation of the Republic of Serbia(No.451-03-136/2025-03/200135)。
文摘Access to clean drinking water is essential for human health,economic development,and environmental sustain-ability.To effectively preserve water quality and ensure a safe and stable water supply,it is essential to determine the priority control factors of potentially hazardous elements in water.This study focused on public drinking wa-ter fountains in Zaječar City(Serbia),examining water hydrochemistry,quality,potential sources of hazardous elements,and the health risks associated with consumption or dermal exposure.Among all potentially hazardous elements,iron showed a deviation from the limit in drinking water prescribed by the World Health Organization,reaching 631μg/L.However,all samples were categorized as excellent quality for drinking.Water composition was governed by water-rock interactions,distinguishing Na-HCO_(3)as the dominant water type.A total of 3.3%and 6.6%of samples exceeded the threshold of 1 for non-carcinogenic health risk for adults and children,re-spectively,with the mean HIa value of 0.35 and the mean HIc value of 0.57.However,the carcinogenic risk was within the allowable limits for children,whereas it surpassed the threshold of 1.0×10^(–4)for adults in 10%of the samples.The positive matrix factorization model identified four sources responsible for water quality,i.e.,natural source,industrial source,sewage source,and agricultural source,with contributions of 37.1%,35.0%,17.8%,and 10.1%,respectively.The Monte Carlo simulation of source-specific health risks revealed that the industrial source was the main contributor to both non-carcinogenic and carcinogenic risks,attributed to its high arsenic load.
基金Water Security and Sustainable Development Hub funded by the UK Research and Innovation's Global Challenges Research Fund(GCRF),Grant/Award Number:ES/S008179/1。
文摘Values of individuals and organizations involved in decision-making processes form the basis for prioritizing outcomes in water governance.The novelty of this study lies in applying values to a specific decision-making context.It aims to assess the prioritized water governance outcomes and the underlying value systems shaping the actions of the primary water utility responsible for water governance in Delhi,the Delhi Jal Board(DJB).The paper will critically examine the policies and acts of the DJB that drive water governance in Delhi at present,utilizing a values-based framework in conjunction with secondary literature and expert interviews,to draw a picture of the values reflected.The study does not substantiate the notion of economic values dominating the water-related deci-sions;rather,recent policy guidelines indicate prioritization of equitable and fair distribution of water.Findings of this paper show that making the values explicit is largely disregarded in formulating water acts and policies,and values are never elucidated in the public domain,doing which can encourage water policies and practices that are socially,economically,and ecologically viable in the long run.It is expected that this paper will generate a discussion on water values being an integral part of water governance discourses.
基金Supported by the National Natural Science Foundation of China(No.52273056)the Science and Technology Development Program of Jilin Province,China(No.YDZJ202501ZYTS305)。
文摘Electrochemical water splitting represents a sustainable technology for hydrogen(H_(2))production.However,its large-scale implementation is hindered by the high overpotentials required for both the cathodic hydrogen evolution reaction(HER)and the anodic oxygen evolution reaction(OER).Transition metal-based catalysts have garnered significant research interest as promising alternatives to noble-metal catalysts,owing to their low cost,tunable composition,and noble-metal-like catalytic activity.Nevertheless,systematic reviews on their application as bifunctional catalysts for overall water splitting(OWS)are still limited.This review comprehensively outlines the principal categories of bifunctional transition metal electrocatalysts derived from electrospun nanofibers(NFs),including metals,oxides,phosphides,sulfides,and carbides.Key strategies for enhancing their catalytic performance are systematically summarized,such as heterointerface engineering,heteroatom doping,metal-nonmetal-metal bridging architectures,and single-atom site design.Finally,current challenges and future research directions are discussed,aiming to provide insightful perspectives for the rational design of high-performance electrocatalysts for OWS.
基金supported by the Natural Science Foundation of China(No.52470105)the Young Taishan Scholars Program of Shandong Province(No.358202103017).
文摘The discharge of micro-polluted water from sources such as agricultural runoff,urban stormwater,and treated effluents presents significant challenges to aquatic ecosystems.Constructed wetlands(CWs)have gained recog-nition as an eco-friendly solution for removing pollutants from various wastewater sources and are increasingly applied for micro-polluted water treatment.By reviewing 78 full-scale CW studies from Web of Science,it is summarized that the ranges of ammonium nitrogen(NH4+-N)concentrations in runoff,wastewater treatment plant effluent and polluted river were 0.1–6.6,0.3–12.3,and 0.2–41.1 mg/L,respectively.The ranges of ni-trate nitrogen concentrations were 0.2–14.2,0–5.7,and 0–2.6 mg/L,respectively.Removal efficiencies of CWs for micro-polluted water varied by CW types.The total nitrogen removal efficiencies for subsurface-flow CWs,free-water surface-flow CWs,and hybrid CWs ranged from 27.4%to 66.5%,16.8%to 89.8%,and 19.4%to 88.2%,respectively.The NH4+-N removal efficiencies ranged from 34.2%to 73.6%,38.4%to 89.4%and 13.5%to 94.2%,respectively.Additionally,other factors influencing contaminant removal efficiency such as hydraulic retention time,vegetation types,redox micro-environment and influent water quality were evaluated.Based on these findings,two strategies for improving the purification performance of CWs were proposed:the selection of incorporating electron donor substrates and the optimization of operation parameters.This paper serves as a synthesis of information to guide future research and full-scale CW applications in micro-polluted water treatment.
基金supported by the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)(No.2019QZKK0208)the National Natural Science Foundation of China(Nos.42171148 and 42330512)the Key R&D Project from the Science and Technology Department of Tibet(No.XZ202501ZY0030).
文摘Nitrogen(N)and phosphorus(P)are essential nutrients and can significantly impact primary productivity of the ecosystem causing water environmental problems.However,their cycling mechanisms are not well understood in alpine mountains with climate change.Hence,94 samples of river water were collected from 2018 to 2020 in the headwaters of the Shule River Basin to assess the nutrients spatiotemporal distribution and combined ap-proach of water quality index to assess water quality and potential sources.The findings depict that high nutrient concentrations were found to coincide with snowmelt and glacial meltwater and rainfall recharge periods,while total flux peaked from June to September due to increased runoff.Notably,total nitrogen(TN)concentrations were significantly higher near the town,primarily attributed to the replenishment of nitrate(NO_(3)^(‒)-N)from live-stock manure.The high total P(TP)was near the glacier,which was attributed to the transportation of glacial sediments into the river,and pH was another critical factor.N was the primary nutrient limiting factor for the growth of phytoplankton in river water.Although the migration and transport of nutrients have altered with climate change,river water quality is good in alpine mountains based on an overall evaluation.These findings contribute to enriching nutrient datasets and highlight the importance of water resource management and water quality assessment in sensitive and fragile alpine mountains.
基金supported by the National Natural Science Foundation of China(No.51939009)Shenzhen Science and Technology Program(Nos.JCYJ20241202125905008 and GXWD20201231165807007-20200810165349001).
文摘A trace analytical method based on solid-phase extraction gas chromatography-tandem mass spectrometry(SPE–GC–MS/MS)was developed for the rapid detection of 256 semi-volatile organic compounds(SVOCs),including 25 polycyclic aromatic hydrocarbons(PAHs),70 polychlorinated biphenyls(PCBs),123 pesticides,20 phthalate esters(PAEs),4 organophosphate esters(OPEs),9 synthetic musks(SMs),and 5 UV filters(UVs)in water.No-tably,this method provided a decent linearity of calibration standards(R^(2)>0.999),excellent method limits of quantification(MLOQs)(0.12–11.41 ng/L),satisfactory matrix spiking recovery rates(60.4%–126%),and high precision(intra-day relative standard deviations(RSDs):1.0%–10.0%,inter-day RSDs:3.0%–15.0%,and inter-week RSDs:3.4%–15.7%),making it suitable for trace-level studies.Statistical analysis revealed that SVOCs with higher volatility exhibited enhanced recovery rates.Validation of the methodology involved analyzing SVOCs in real spring water and river water samples.Twenty-seven SVOCs were detected in spring water and 58 in river water,with an average concentration of 631.73 and 16,095 ng/L,respectively.Among the detected SVOCs,PAEs constituted the predominant proportion.This study underscored the presence of SVOCs contamination specifi-cally within the spring water,although SVOCs concentrations in river water were significantly greater than those found in spring water.In summary,this sensitive method based on SPE–GC–MS/MS was successfully developed and validated for the rapid analysis of a diverse array of 256 SVOCs at trace levels in water,including not only the traditional highly valued PAHs,PCBs,pesticides,and PAEs,but also the emerging OPEs,UVs,and SMs.
基金financially supported by the Key Research and Development Program of Heilongjiang Province(No.2024ZXJ03C06)National Natural Science Foundation of China(No.52476192,No.52106237)+1 种基金Natural Science Foundation of Heilongjiang Province(No.YQ2022E027)Technology Project of China Datang Technology Innovation Co.,Ltd(No.DTKC-2024-20610).
文摘Pulsed dynamic electrolysis(PDE),driven by renewable energy,has emerged as an innovative electrocatalytic conversion method,demonstrating significant potential in addressing global energy challenges and promoting sustainable development.Despite significant progress in various electrochemical systems,the regulatory mechanisms of PDE in energy and mass transfer and the lifespan extension of electrolysis systems,particularly in water electrolysis(WE)for hydrogen production,remain insufficiently explored.Therefore,there is an urgent need for a deeper understanding of the unique contributions of PDE in mass transfer enhancement,microenvironment regulation,and hydrogen production optimization,aiming to achieve low-energy consumption,high catalytic activity,and long-term stability in the generation of target products.Here,this review critically examines the microenvironmental effects of PDE on energy and mass transfer,the electrode degradation mechanisms in the lifespan extension of electrolysis systems,and the key factors in enhancing WE for hydrogen production,providing a comprehensive summary of current research progress.The review focuses on the complex regulatory mechanisms of frequency,duty cycle,amplitude,and other factors in hydrogen evolution reaction(HER)performance within PDE strategies,revealing the interrelationships among them.Finally,the potential future directions and challenges for transitioning from laboratory studies to industrial applications are proposed.
基金supported by the Australian Research Council(ARC)Projects(DP220101139,DP220101142,and LP240100542).
文摘High‐entropy amorphous catalysts(HEACs)integrate multielement synergy with structural disorder,making them promising candidates for water splitting.Their distinctive features—including flexible coordination environments,tunable electronic structures,abundant unsaturated active sites,and dynamic structural reassembly—collectively enhance electrochemical activity and durability under operating conditions.This review summarizes recent advances in HEACs for hydrogen evolution,oxygen evolution,and overall water splitting,highlighting their disorder-driven advantages over crystalline counterparts.Catalytic performance benchmarks are presented,and mechanistic insights are discussed,focusing on how multimetallic synergy,amorphization effect,and in‐situ reconstruction cooperatively regulate reaction pathways.These insights provide guidance for the rational design of next‐generation amorphous high‐entropy electrocatalysts with improved efficiency and durability.
文摘Andrew Wangota,a 48-year-old Ugandan farmer,has been using agrivoltaics technology,a solar technology that uses agricultural land for both food production and solar power generation,on his farm in Bunashimolo Parish,Bukyiende Subcounty in Uganda where he has been cultivating plantain,coffee and Irish potatoes for the past 16 years.
基金financial support from the Nuclear Energy Science&Technology and Human Resource Development Project of the Japan Atomic Energy Agency/Collaborative Laboratories for Advanced Decommissioning Science(No.R04I034)The author Ruicong Xu appreciates the scholarship(financial support)from the China Scholarship Council(CSC,No.202106380073).
文摘Laser-induced aerosols,predominantly submicron in size,pose significant environmental and health risks during the decommissioning of nuclear reactors.This study experimentally investigated the removal of laser-generated aerosol particles using a water spray system integrated with an innovative system for pre-injecting electrically charged mist in our facility.To simulate aerosol generation in reactor decommissioning,a high-power laser was used to irradiate various materials(including stainless steel,carbon steel,and concrete),generating aerosol particles that were agglomerated with injected water mist and subsequently scavenged by water spray.Experimental results demonstrate enhanced aerosol removal via aerosol-mist agglomeration,with charged mist significantly improving particle capture by increasing wettability and size.The average improvements for the stainless steel,carbon steel,and concrete were 40%,44%,and 21%,respectively.The results of experiments using charged mist with different polarities(both positive and negative)and different surface coatings reveal that the dominant polarity of aerosols varies with the irradiated materials,influenced by their crystal structure and electron emission properties.Notably,surface coatings such as ZrO_(2)and CeO_(2)were found to possibly alter aerosol charging characteristics,thereby affecting aerosol removal efficiency with charged mist configurations.The innovative aerosol-mist agglomeration approach shows promise in mitigating radiation exposure,ensuring environmental safety,and reducing contaminated water during reactor dismantling.This study contributes critical knowledge for the development of advanced aerosol management strategies for nuclear reactor decommissioning.The understanding obtained in this work is also expected to be useful for various environmental and chemical engineering applications such as gas decontamination,air purification,and pollution control.
基金funding support from Natural Science Foundation of Shanghai(Grant No.23ZR1443900)the National Natural Science Foundation of China(Grant Nos.22178309,22476131 and 22176127)。
文摘Economical,stable,and corrosion-resistant catalytic electrodes are still urgently needed for the oxygen evolution reaction(OER)in water and seawater.Herein,a mild electroless plating strategy is used to achieve large-scale preparation of the“integrated”phosphorus-based precatalyst(FeP-NiP)on nickel foam(NF),which is in situ reconstructed into a highly active and corrosion-resistant(Fe)NiOOH phase for OER.The interaction between phosphate anions(PO_(x)^(y-))and iron ions(Fe^(3+))tunes the electronic structure of the catalytic phase to further enhance OER kinetics.The integrated FeP-NiP@NF electrode exhibits low overpotentials for OER in alkaline water/seawater,requiring only 275/289,320/336,and 349/358 mV to reach 0.1,0.5,and 1.0 A cm^(−2),respectively.The in situ reconstructed PO_(x)^(y-)anion electrostatically repels Cl−in seawater electrolytes,allowing stable operation for over 7 days at 1.0 A cm^(−2) in extreme electrolytes(1.0 M KOH+seawater and 6.0 M KOH+seawater),demonstrating industrial-level stability.This study overcomes the complex synthesis limitations of P-based materials through innovative material design,opening new avenues for electrochemical energy conversion.
基金The Independent Research Foundation of Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)under contract Nos SML2023SP201 and SML2021SP306the Natural Science Foundation of Guangdong Province of China under contract No.2024A1515012717+5 种基金the Initial Research Foundation of Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)under contract Nos 313021004,313022009,and 313022001the National Natural Science Foundation of China under contract No.41706225the National Key R&D Program of China under contract No.2018YFA0605701the Impact and Response of Antarctic Seas to Climate Change under contract No.IRASCC 1-02-01Bthe Shenlan Program funded by Shanghai Jiao Tong University under contract No.SL2020MS021the fund from Shanghai Frontiers Science Center of Polar Research.
文摘The Southern Ocean is a critical component in the Earth system by dominating the global heat and anthropogenic carbon uptake and supplying heat to melt the largest ice sheet.Variability and changes in the water masses of the Southern Ocean are thus important to the global energy and water cycles,carbon cycling,and sea-level change.In this article,we review the recent progress on understanding the variability and changes in the four major water masses in the Southern Ocean,including Subantarctic Mode Water,Antarctic Intermediate Water,Circumpolar Deep Water and Antarctic Bottom Water.Subantarctic Mode Water and Antarctic Intermediate Water show statistically significant strong circumpolar shoaling,warming,and density reductions since 1970s,indicating that signals of global warming have entered the interior ocean.Meanwhile,strong regional variability of Subantarctic Mode Water and Antarctic Intermediate Water responding to surface buoyancy forcing and westerly winds is attracting more attention.Circumpolar Deep Water is an important modulator of heat content and nutrient concentrations on continental shelves around Antarctica and has made significant contributions to the basal melting of Antarctic ice shelves.Since the late 1950s,a long-term freshening trend in Antarctic Bottom Water in the Ross Sea and its downstream region has been observed and is mainly attributed to the accelerated basal melting of ice shelves in West Antarctica.The shrinking of Antarctic Bottom Water in the Weddell Sea during 1992–2020 has also been revealed and is attributed to reduced sea ice production over the southern Weddell continental shelf related to the Interdecadal Pacific Oscillation and the variability in the Amundsen Sea Low.Though significant advances have been achieved,there is an urgent need to enhance and improve both observations and model performances for better understandings and projections of the formation,transformation,and transport of the water masses in the Southern Ocean.
文摘Water scarcity in Khuzestan Province,Iran,has attracted growing concerns despite the region's abundant water resources.The province predominantly relies on surface water,prompting an assessment of groundwater's potential to supplement water supplies during surface water shortages.This study assesses the province's groundwater availability and quality under increased exploitation conditions.Between 2008 and 2018,data on groundwater quantity and quality were collected from 204 exploration wells and 70 piezometric wells across 19 aquifers.The analysis revealed that 53%of aquifers in the eastern and northeastern regions experienced declining groundwater levels.Hydrochemical assessments indicated low concentrations of major ions in the northeastern,while high levels were observed from the central region towards the southeast.These variations were attributed to agricultural and industrial activities,seawater intrusion,and the influences of evaporation and geological factors.The dominant hydrochemical facies identified were of the Ca-Cl type.Water quality classification showed that 48%of groundwater samples fell within the C4S4-C4S1 category,primarily in the western,central,and southern regions,while 27%were classified as C3S2,C3S1,and 25%as C2S1,mainly in the northern and eastern regions.The Irrigation WWater Quality(IWQ)index indicated that many samples were suitable for irrigation.Additionally,the analysis potable groundwater was primarily found in the northern,northeastern,and eastern aquifers,with quality declining toward the south.The study highlights that certain aquifers in the northern and eastern regions offer greater potential for sustainable groundwater exploitation during water shortages.These findings provide valuable insights for on how to implement effective land and water management strategies to mitigate future water crises.
基金Under the National Key R&D Program Key Project(No.2021YFC3201201)National Natural Science Foundation of China(No.52360032)+2 种基金Basic Scientific Research Business Fee Project of Colleges And Universities Directly Under the Inner Mongolia Autonomous Region(No.JBYYWF2022001)Development Plan of Innovation Team of Colleges And Universities in Inner Mongolia Autonomous Region(No.NMGIRT2313)the Innovation Team of‘Grassland Talents’。
文摘Clarifying the mechanisms through which coal mining affects groundwater storage(GWS)variations is crucial for water resource conservation and sustainable development.The Ordos Mining Region in China,a key energy base in China with significant strategic importance,has undergone intensive coal mining activities that have substantially disrupted regional groundwater circulation.This study integrated data from the Gravity Recovery and Climate Experiment Satellite(GRACE)and Famine Early Warning Systems Network(FEWS NET)Land Data Assimilation System(FLDAS)models,combined with weighted downscaling methodology and water balance principles,to reconstruct high-resolution(0.01°)terrestrial water storage(TWS)and GWS changes in the Ordos Mining Region,China from April 2002 to December 2021.The accuracy of GWS variations were validated through pumping test measurements.Subsequently,Geodetector analysis was implemented to quantify the contributions of natural and anthropogenic factors to groundwater storage dynamics.Key findings include:1)TWS in the study area showed a fluctuating but overall decreasing trend,with a total reduction of 8901.11 mm during study period.The most significant annual decrease occurred in 2021,reaching 1696.77 mm.2)GWS exhibited an accelerated decline,with an average annual change rate of 44.35 mm/yr,totaling a decrease of 887.05 mm.The lowest annual groundwater storage level was recorded in 2020,reaching 185.69 mm.3)Precipitation(PRE)contributed the most to GWS variation(q=0.52),followed by coal mining water consumption(MWS)(q=0.41).The interaction between PRE and MWS exhibited a nonlinear enhancement effect on GWS changes(0.54).The synergistic effect of natural hydrological factors has a great influence on the change of GWS,but coal mining water consumption will continue to reduce GWS.These findings provide critical references for the management and regulation of groundwater resource in mining regions.
文摘Groundwater,surface water and tap water contamination by PTEs(Potentially Toxic Elements)was assessed in Kipushi town and Lupoto locality of Kipushi administrative territory in the Upper-Katanga province,Democratic Republic of Congo.A total of fifty four water samples including thirty two samples from drilled water wells,ten samples from spade-sunk water wells,six samples from supplied tap water,four samples from a mine effluent and two samples from a river were collected from both localities in November and December 2017 and in January,February and March 2018.Then the samples were analyzed for their PTE contents by ICP-SF-MS(Inductively Coupled Plasma-Sector Field Mass Spectrometry).Twenty PTEs including aluminum,arsenic,barium,bismuth,cadmium,cesium,chromium,cobalt,copper,iron,lead,manganese,molybdenum,nickel,strontium,thallium,tungsten,uranium,vanadium and zinc were detected at various concentrations in each one of the samples.Many samples had concentrations and mean concentrations of PTE,such as arsenic,aluminum,cadmium,iron,lead,manganese and zinc,higher than the respective acceptable limits set for drinking water by the EU(European Union),the USEPA(United States Environmental Protection Agency),and the WHO(World Health Organization)standards.Most PTEs being deleterious to human health even at very low concentrations,people who use the groundwater,surface water and tap water to meet their water needs in both localities are at risk.
文摘Water scarcity poses a significant challenge globally,with South Africa exemplifying the severe socio-economic and environmental impacts of limited water access.Despite advances in modern water management systems,the integration of indigenous knowledge(IK)into formal frameworks remains underutilized.This study systematically reviews the role of indigenous water conservation practices in South Africa,analyzing over 50 high-quality sources using the PRISMA methodology.The findings highlight the effectiveness of IK in addressing water scarcity through techniques such as rainwater harvesting,terracing,and wetland management,which are low-cost,environmentally sustainable,and deeply rooted in cultural practices.Indigenous methods also enhance climate resilience by enabling communities to adapt to droughts and floods through practices such as weather prediction and adaptive farming techniques.Furthermore,these practices foster social inclusivity and community empowerment,ensuring equitable water access and intergenerational knowledge transfer.The study underscores the potential of integrating IK with modern water technologies to create holistic solutions that are scalable,sustainable,and aligned with South Africa’s goal of achieving water security by 2030.Policy recommendations emphasize the need for institutional support,data collection,and financial incentives to sustain and mainstream indigenous approaches.By bridging the gap between traditional and contemporary systems,this research provides a roadmap for leveraging diverse knowledge systems to address water scarcity and build resilient communities.
