Waste heat generation,upgrading,and refrigeration are the fundamental ways to recover and utilize waste heat.Rationalizing the use of refrigerants also contributes to creating energy savings and minimizing carbon emis...Waste heat generation,upgrading,and refrigeration are the fundamental ways to recover and utilize waste heat.Rationalizing the use of refrigerants also contributes to creating energy savings and minimizing carbon emissions.This study evaluates the thermodynamics,economics,and environment of different refrigerants in three waste heat recovery schemes:generate electricity,heat pump,and refrigeration.Based on this,the entropy weight and technique for order preference by similarity to an ideal solution are combined to assess the overall performance of the refrigerants.A thorough analysis reveals that R1234ze(E)could replace R245fa and R123 in the organic Rankine cycle.The best refrigerant for vapor compression refrigeration and high-temperature heat pump systems is R1243zf.In addition,the multi-objective decision analysis shows that the performance difference among the nine selected refrigerants is the total cost,followed by the environmental impact.The approach successfully recognizes the variations between different refrigerants in the same waste heat recovery scheme and gives a thorough evaluation.It sets instructions for the future use of eco-friendly refrigerants and their application of waste heat recovery schemes.展开更多
To further enhance the recovery rate of low-temperature waste heat,the low-temperature flue gas in the sinter annular cooler was chosen as the heat source of an organic Rankine cycle(ORC)system,and the comprehensive e...To further enhance the recovery rate of low-temperature waste heat,the low-temperature flue gas in the sinter annular cooler was chosen as the heat source of an organic Rankine cycle(ORC)system,and the comprehensive evaluation of energy,exergy and economic performance of the ORC system was conducted deeply.The energy,exergy and economic performance models of the ORC system were established,and proper candidate organic working fluids(OWFs)were selected based on the thermo-physical properties of OWF and operating characteristics of ORC system.Then,the effects of ORC crucial parameters on the system energy,exergy and economic performances were evaluated in detail.Finally,the bi-objective optimization based on the genetic algorithm was conducted to analyze the optimal performance of the ORC system under the designed ORC crucial parameters,and the exergy efficiency and electricity production cost were set as the evaluation indexes of parametric optimization.The results indicate that the ORC system with the higher evaporation temperature and lower condensation temperature can obtain the larger system exergy efficiency and smaller electricity production cost.The smaller the superheat degree of OWF and pinch-point temperature difference in the evaporator are,the better the energy and exergy performances of the ORC system are.Under the optimization results,R245fa has the best comprehensive performance with the exergy efficiency of 46.34%and electricity production cost of 0.12123$/kWh among the selected candidate OWFs,which should be preferentially chosen as the OWF of the ORC system.展开更多
The efficient and environmentally friendly recycling technology of waste residue that including abundant heavy metal produced during the recovery of lithium batteries has become a research hotspot.Herein,a novelty pro...The efficient and environmentally friendly recycling technology of waste residue that including abundant heavy metal produced during the recovery of lithium batteries has become a research hotspot.Herein,a novelty process of acid leaching-selective electrodeposition-deep impurity removal-regeneration was proposed to recovery of the CuS slag,which has been efficient transferred to high purity cathode copper and commercially available ternary precursors.Copper cathode with a purity of 99.67%was prepared under electrochemical reaction conditions at-0.55 V for 2 h.A novel impurity remover-Mn powder,which was used to remove the residual impurities and as a feedstock for the ternary precursor.Finally,NCM523 was regenerated by co-precipitation.The process is superior to the traditional process in economy,energy consumption,CO_(2)emissions,product purity and process duration.This study provides a new approach for solid waste recovery and precious metal enrichment.展开更多
Two novel thermal cycles based on Brayton cycle and Rankine cycle are proposed, respectively, which integrate the recovery of low-level waste heat and Liquefied Nature Gas （LNG） cold energy utilization for power gen...Two novel thermal cycles based on Brayton cycle and Rankine cycle are proposed, respectively, which integrate the recovery of low-level waste heat and Liquefied Nature Gas （LNG） cold energy utilization for power generation. Cascade utilization of energy is realized in the two thermal cycles, where low-level waste heat,low-temperature exergy and pressure exergy of LNG are utilized efficiently through the system synthesis. The simulations are carried out using the commercial Aspen Plus 10.2, and the results are analyzed. Compared with the conventional Brayton cycle and Rankine cycle, the two novel cycles bring 60.94% and 60% in exergy efficiency, respectively and 53.08% and 52.31% in thermal efficiency, respectively.展开更多
Liquefied natural gas(LNG)is regarded as one of the cleanest fossil fuel and has experienced significant developments in recent years.The liquefaction process of natural gas is energy-intensive,while the regasificatio...Liquefied natural gas(LNG)is regarded as one of the cleanest fossil fuel and has experienced significant developments in recent years.The liquefaction process of natural gas is energy-intensive,while the regasification of LNG gives out a huge amount of waste energy since plenty of high grade cold energy(-160℃)from LNG is released to sea water directly in most cases,and also sometimes LNG is burned for regasification.On the other hand,liquid air energy storage(LAES)is an emerging energy storage technology for applications such as peak load shifting of power grids,which generates 30%-40%of compression heat(-200℃).Such heat could lead to energy waste if not recovered and used.The recovery of the compression heat is technically feasible but requires additional capital investment,which may not always be economically attractive.Therefore,we propose a power plant for recovering the waste cryogenic energy from LNG regasification and compression heat from the LAES.The challenge for such a power plant is the wide working temperature range between the low-temperature exergy source(-160℃)and heat source(-200℃).Nitrogen and argon are proposed as the working fluids to address the challenge.Thermodynamic analyses are carried out and the results show that the power plant could achieve a thermal efficiency of 27%and 19%and an exergy efficiency of 40%and 28%for nitrogen and argon,respectively.Here,with the nitrogen as working fluid undergoes a complete Brayton Cycle,while the argon based power plant goes through a combined Brayton and Rankine Cycle.Besides,the economic analysis shows that the payback period of this proposed system is only 2.2 years,utilizing the excess heat from a 5 MW/40 MWh LAES system.The findings suggest that the waste energy based power plant could be co-located with the LNG terminal and LAES plant,providing additional power output and reducing energy waste.展开更多
Waste heat recovery from hot steel slag was determined in a granular bed through the combination of numerical simulation and an industrial test method.First,the effective thermal conductivity of the granular bed was c...Waste heat recovery from hot steel slag was determined in a granular bed through the combination of numerical simulation and an industrial test method.First,the effective thermal conductivity of the granular bed was calculated.Then,the unsteady-state model was used to simulate the heat recovery under three different flow fields(O-type,S-type,and nonshielding type(Nontype)).Second,the simulation results were validated by in-situ industrial experiments.The two methods confirmed that the heat recovery efficiencies of the flow fields from high to low followed the order of Nontype,S-type,and O-type.Finally,heat recovery was carried out under the Nontype flow field in an industrial test.The heat recovery efficiency increased from~76%and~78%to~81%when the steel slag thickness decreased from 400 and 300 to 200 mm,corresponding to reductions in the steel slag mass from 3.96 and 2.97 to 1.98 t with a blower air volume of 14687 m^(3)/h.Therefore,the research results showed that numerical simulation can not only guide experiments on waste heat recovery but also optimize the flow field.Most importantly,the method proposed in this paper has achieved higher waste heat recovery from hot steel slag in industrial scale.展开更多
Dynamic performance is important to the controlling and monitoring of the organic Rankine cycle(ORC) system so to avoid the occurrence of unwanted conditions. A small scale waste heat recovery system with organic Rank...Dynamic performance is important to the controlling and monitoring of the organic Rankine cycle(ORC) system so to avoid the occurrence of unwanted conditions. A small scale waste heat recovery system with organic Rankine cycle was constructed and the dynamic behavior was presented. In the dynamic test, the pump was stopped and then started. In addition, there was a step change of the flue gas volume flow rate and the converter frequency of multistage pump, respectively. The results indicate that the working fluid flow rate has the shortest response time, followed by the expander inlet pressure and the expander inlet temperature.The operation frequency of pump is a key parameter for the ORC system. Due to a step change of pump frequency(39.49-35.24 Hz),the expander efficiency and thermal efficiency drop by 16% and 21% within 2 min, respectively. Besides, the saturated mixture can lead to an increase of the expander rotation speed.展开更多
The rapid development of the fluorinated pesticide industry has produced a large amount of fluorine-containing hazardous waste, especially inorganic fluoride-containing waste（IFCW）. A two-step process, including ext...The rapid development of the fluorinated pesticide industry has produced a large amount of fluorine-containing hazardous waste, especially inorganic fluoride-containing waste（IFCW）. A two-step process, including extraction and recovery, was developed to recover fluorine as synthetic cryolite from IFCW produced by the pesticide industry. The optimum conditions for extraction were found to be a temperature of 75℃, an initial p H（p Hi） of 12, a4-hr incubation time and a liquid-to-solid ratio of 40 m L/g; these conditions resulted in a fluorine extraction ratio of 99.0%. The effects of p H and the F/Al molar ratio on fluorine recovery and the compositional, mineralogical and morphological characteristics of the cryolite products were investigated. Field-emission scanning electron microscopy of recovered precipitates showed changes in morphology with the F/Al molar ratio. Coupling Fourier transform and infrared spectroscopy, X-ray diffraction indicated that the formation of Al F3-6was restricted as increasing p H. Both the amount of fluorine recovered and the quality of the cryolite were optimized at initial p H = 3 and a F/Al molar ratio 5.75. This study proposed a reliable and environmentally friendly method for the treatment of fluoridecontaining wastes, which could be suitable for industrial applications.展开更多
In order to improve the recovery and utilization rates of sinter waste heat effectively,the organic Rankine cycle(ORC)system with subcritical cycle was designed to recover the low-temperature sinter cooling flue gas w...In order to improve the recovery and utilization rates of sinter waste heat effectively,the organic Rankine cycle(ORC)system with subcritical cycle was designed to recover the low-temperature sinter cooling flue gas waste heat in an annular cooler for power generation.The thermodynamic,economic and multi-objective optimization models of ORC system were established,and R600a was selected as the ORC working medium.Subsequently,the variations in system thermodynamic performance and economic performance with the ORC thermal parameters were discussed in detail,and the optimal ORC thermal parameters were determined.The results show that the system net output power increases with increasing the evaporation temperature and decreasing the condensation temperature and increases first and then,decreases with the increase in superheat degree for a given flue gas outlet temperature in the evaporator,while the heat transfer area per unit net output power appears different variation trends in various ranges of flue gas outlet temperature.Taking the sinter cooling flue gas waste heat of 160℃as the ORC heat source,the optimal thermal parameters of ORC system were the flue gas outlet temperature of 90℃,the evaporation temperature of 95℃,the superheat degree of 10℃,and the condensation temperature of 28℃.展开更多
The common problem of cold strip continuous annealing furnaces is high exhaust gas temperature and great energy consumption. Taking the cold-strip continuous annealing furnaces of Baosteel No. 4 cold mill plant as an ...The common problem of cold strip continuous annealing furnaces is high exhaust gas temperature and great energy consumption. Taking the cold-strip continuous annealing furnaces of Baosteel No. 4 cold mill plant as an example, several waste heat recovery systems in the annealing furnaces are compared and their advantages and disadvantages are analyzed through different energy-saving technologies.展开更多
Concentrating Solar Power(CSP)plants offer a promising way to generate low-emission energy.However,these plants face challenges such as reduced sunlight during winter and cloudy days,despite being located in high sola...Concentrating Solar Power(CSP)plants offer a promising way to generate low-emission energy.However,these plants face challenges such as reduced sunlight during winter and cloudy days,despite being located in high solar radiation areas.Furthermore,their dispatch capacities and yields can be affected by high electricity consumption,particularly at night.The present work aims to develop an off-design model that evaluates the hourly and annual performances of a parabolic trough power plant(PTPP)equipped with a waste heat recovery system.The study aims to compare the performances of this new layout with those of the conventional Andasol 1 plant,with the aim of assessing the improvements achieved in the new design.Based on the results,it can be concluded that the new layout has increased the annual generated power to almost 183 GWh(an increase of about 7.60% is achieved compared to the Andasol 1 layout that generates 169 GWh annually).Additionally,the proposed installation has achieved an efficiency of 20.55%,which represents a 7.87% increase compared to the previous design(19.05%).The Levelized Cost of Electricity(LCOE)of the new layout has been reduced by more than 5.8% compared to the Andasol 1 plant.Specifically,it has decreased from 13.11 to 12.35 c/kWh.This reduction in LCOE highlights the improved cost-effectiveness of the newlayout,making it amore economically viable option for generating electricity compared to the conventional Andasol 1 plant.展开更多
Data centers(DCs)are highly energy-intensive facilities,where about 30%–50%of the power consumed is attributable to the cooling of information technology equipment.This makes liquid cooling,especially in twophase mod...Data centers(DCs)are highly energy-intensive facilities,where about 30%–50%of the power consumed is attributable to the cooling of information technology equipment.This makes liquid cooling,especially in twophase mode,as an alternative to air cooling for the microprocessors in servers of interest.The need to meet the increased power density of server racks in high-performance DCs,along with the push towards lower global warming potential(GWP)refrigerants due to environmental concerns,has motivated research on the selection of two-phase heat transfer fluids for cooling servers while simultaneously recovering waste heat.With this regard,a heat pump-assisted absorption chiller(HPAAC)system for recovering waste heat in DCs with an on-chip twophase cooling loop driven by the compressor is proposed in the present paper and the low GWP hydrofluoroolefin refrigerants,including R1224yd(Z),R1233zd(E),R1234yf,R1234ze(E),R1234ze(Z),R1243zf and R1336mzz(Z),are evaluated and compared against R245fa as server coolant.For theHPAAC system,beginning with the development of energy and economic models,the performance is analyzed through both a parametric study and optimization using the coefficient of performance(COP),energy saving ratio(ESR),payback period(PBP)and net present value(NPV)as thermo-economic indicators.Using a standard vapor compression cooling system as a benchmark,the results indicate that with the evaporation temperature between 50℃and 70℃and the subcooling degree ranging from5℃to 15°C,R1233zd(E)with moderate compressor suction pressure and pressure ratio is the best refrigerant for the HPAAC systemwhile R1234yf performs the worst.More importantly,R1233zd(E)is also superior to R245fa based on thermo-economic performance,especially under work conditions with relatively lower evaporation temperature as well as subcooling degree.Under the given working conditions,the overall COP,ESR,NPV,and PBP of R1233zd(E)HPAAC with optimum subcooling degree range from4.99 to 11.27,25.53 to 64.59,1.13 to 4.10×10^(7) CNY and 5.77 to 2.22 years,respectively.Besides,the thermo-economic performance of R1233zd(E)HPAAC under optimum working conditions in terms of subcooling degree varying with the evaporation temperature is also investigated.展开更多
The waste referred to includes solid waste and sludge. Solid waste is mainly from urban garbage and industrial waste. Sludge is from water treatment factories, paper mills, chemical factories, pharmaceutical factories...The waste referred to includes solid waste and sludge. Solid waste is mainly from urban garbage and industrial waste. Sludge is from water treatment factories, paper mills, chemical factories, pharmaceutical factories, rivers and lakes. The waste and sludge are very harmful to water organisms, human health and drinking water, and directly affect the environment. Sludge and waste also occupy large areas of land. There are several methods to treat waste and sludge, such as burial, chemical treatment and incineration. Incineration is more effective than the展开更多
In this paper, a detailed thermodynamic analysis of the pure low-temperature waste heat recovery generation system is presented. The parameters affecting the system performance are compared to obtain the most signific...In this paper, a detailed thermodynamic analysis of the pure low-temperature waste heat recovery generation system is presented. The parameters affecting the system performance are compared to obtain the most significant ones; furthermore, parameter values are optimized for the largest power generating capability of the system. It is found that the most important parameters are inlet flue gas temperature, steam pressure and the pinch point temperature difference. There is an optimal superheated steam pressure value for giving the maximum generation power per unit flue gas. With the increase of inlet flue gas temperature, the generating power increases and the optimized steam pressure rises as well. However, with increase in pinch point temperature difference, the generating power decreases and the optimized steam pressure decreases as well. The theoretical calculation provides a theoretical basis for the parameters optimization in the design of the pure low-temperature waste heat recovery eeneration swtem展开更多
In recent years, China pays more attention to the protection of environment and resources in the process of social and economic development, puts forward the development concept of green, energy saving and environment...In recent years, China pays more attention to the protection of environment and resources in the process of social and economic development, puts forward the development concept of green, energy saving and environmental protection, and carries on a clear specification for the development of various industries. Under the current situation, flue gas waste heat recovery and utilization technology has attracted more and more attention, which can avoid the waste of energy and maximize the interests of enterprises. Therefore, relevant personnel should pay attention to study and analyze the application of flue gas waste heat recovery and utilization technology, in order to provide some help for the development of enterprises.展开更多
Using the boiler smoke waste heat, the actual energy saving reconstruction in case of boiler flue gas waste heat recovery and energy saving effect is analyzed, the design of waste heat recovery plan, improve the boile...Using the boiler smoke waste heat, the actual energy saving reconstruction in case of boiler flue gas waste heat recovery and energy saving effect is analyzed, the design of waste heat recovery plan, improve the boiler heating water temperature, in order to improve the boiler thermal efficiency, at the same time reduce the emissions of pollutants such as flue gas nitrogen oxides, achieve energy conservation and emissions reduction.展开更多
In order to address the synergistic optimization of energy efficiency improvement in the waste incineration power plant(WIPP)and renewable energy accommodation,an electricity-hydrogen-waste multi-energy system integra...In order to address the synergistic optimization of energy efficiency improvement in the waste incineration power plant(WIPP)and renewable energy accommodation,an electricity-hydrogen-waste multi-energy system integrated with phase change material(PCM)thermal storage is proposed.First,a thermal energy management framework is constructed,combining PCM thermal storage with the alkaline electrolyzer(AE)waste heat recovery and the heat pump(HP),while establishing a PCM-driven waste drying system to enhance the efficiency of waste incineration power generation.Next,a flue gas treatment method based on purification-separation-storage coordination is adopted,achieving spatiotemporal decoupling between waste incineration and flue gas treatment.Subsequently,a two-stage optimal dispatching strategy for the multi-energy system is developed:the first stage establishes a dayahead economic dispatch model with the objective of minimizing net system costs,while the second stage introduces model predictive control(MPC)to realize intraday rolling optimization.Finally,The optimal dispatching strategies under different scenarios are obtained using the Gurobi solver,followed by a comparative analysis of the optimized operational outcomes.Simulation results demonstrate that the proposed system optimizes the output and operational states of each unit,simultaneously reducing carbon trading costs while increasing electricity sales revenue.The proposed scheduling strategy demonstrates effective grid peak-shaving functionality,thereby simultaneously improving the system’s economic performance and operational flexibility while providing an innovative technical pathway for municipal solid waste(MSW)resource utilization and low-carbon transformation of energy systems.展开更多
The aim of the research was to develop new products and processes from a manufacturing waste from an Italian metallurgic company.The company produced thin silver metallic films and the production scraps were silver fl...The aim of the research was to develop new products and processes from a manufacturing waste from an Italian metallurgic company.The company produced thin silver metallic films and the production scraps were silver flakes.The possibility to use the silver flakes in water disinfection processes was studied.The antimicrobial activity of the flakes was investigated in batch using Escherichia coli as Gram-negative microorganism model.The flakes did not show any antimicrobial activity,so they were activated with two different processes： thermal activation in reducing atmosphere and chemical activation,obtaining,respectively,reduced flakes （RF） and chemical flakes （CF）.The flakes,activated with either treatment,showed antimicrobial activity against E.coli.The kill rate was dependent on the type of activated flakes.The chemical flakes were more efficient than reduced flakes.The kill rate determined for 1 g of CF,1.0 ± 0.2 min ？1 ,was greater than the kill rate determined for 1 g of RF,0.069 ± 0.004 min ？1 .This was confirmed also by the minimum inhibitory concentration values.It was demonstrated that the antimicrobial capability was dependent on flakes amount and on the type of aqueous medium.Furthermore,the flakes maintained their properties also when used a second time.Finally,the antimicrobial activities of flakes were tested in an effluent of a wastewater treatment plant where a variety of heterotrophic bacteria were present.展开更多
Possibility of combustible gas production from municipal solid waste （MSW） using hot blast furnace （BF） slag has been studied.The objective of this work is to generate combustible gas from MSW using heated BF slag...Possibility of combustible gas production from municipal solid waste （MSW） using hot blast furnace （BF） slag has been studied.The objective of this work is to generate combustible gas from MSW using heated BF slag.In this experiment,the thermal stability of the MSW was analyzed by thermogravimetric analysis,and effects of temperature,gasifying agent （air,N2,steam） and BF slag on the gas products were investigated at 600？900 ？C.The thermogravimetric analysis indicates that the weight loss of MSW includes four stages：evaporation of the moisture,combustion of volatile materials,burning of carbon residue and burnout of ash.The contents of the combustible gas increase with increasing temperature,and the lower calorific value （LCV） increases rapidly at 600？900 ？C.It is found that volume fraction of CO,H2 and CH4 at different atmospheres increases in the order N2〈air〈steam.It is believed that BF slag acts as the catalyst and the heat carrier,which promotes the gasification reactivity of MSW.展开更多
Low temperature exhaust gases carrying large amount of waste heat are released by steel-making process and many other industries, Organic Rankine Cycles （ORCs） are proven to be the most promising technology to re- c...Low temperature exhaust gases carrying large amount of waste heat are released by steel-making process and many other industries, Organic Rankine Cycles （ORCs） are proven to be the most promising technology to re- cover the low-temperature waste heat, thereby to get more financial benefits for these industries. The exergy analysis of ORC units driven by low-temperature exhaust gas waste heat and charged with dry and isentropic fluid was per- formed, and an intuitive approach with simple impressions was developed to calculate the performances of the ORC unit. Parameter optimization was conducted with turbine inlet temperature simplified as the variable and exergy effi- ciency or power output as the objective function by means of Penalty Function and Golden Section Searching algo- rithm based on the formulation of the optimization problem. The power generated by the optimized ORC unit can be nearly as twice as that generated by a non-optimized ORC unit. In addition, cycle parametric analysis was performed to examine the effects of thermodynamic parameters on the cycle performances such as thermal efficiency and exergy efficiency. It is proven that performance of ORC unit is mainly affected by the thermodynamic property of working fluid, the waste heat temperature, the pinch point temperature of the evaporator, the specific heat capacity of the heat carrier and the turbine inlet temperature under a given environment temperature.展开更多
基金supported by the National Natural Science Foundation of China(22178190)the National Youth Natural Science Foundation of China(22408195).
文摘Waste heat generation,upgrading,and refrigeration are the fundamental ways to recover and utilize waste heat.Rationalizing the use of refrigerants also contributes to creating energy savings and minimizing carbon emissions.This study evaluates the thermodynamics,economics,and environment of different refrigerants in three waste heat recovery schemes:generate electricity,heat pump,and refrigeration.Based on this,the entropy weight and technique for order preference by similarity to an ideal solution are combined to assess the overall performance of the refrigerants.A thorough analysis reveals that R1234ze(E)could replace R245fa and R123 in the organic Rankine cycle.The best refrigerant for vapor compression refrigeration and high-temperature heat pump systems is R1243zf.In addition,the multi-objective decision analysis shows that the performance difference among the nine selected refrigerants is the total cost,followed by the environmental impact.The approach successfully recognizes the variations between different refrigerants in the same waste heat recovery scheme and gives a thorough evaluation.It sets instructions for the future use of eco-friendly refrigerants and their application of waste heat recovery schemes.
基金the financial support for this work provided by the National Natural Science Foundation of China(51974087)Anhui Provincial Natural Science Foundation(1908085QE203)+1 种基金University Natural Science Research Foundation of Anhui Province(2022AH050262)Science Research Foundation of Anhui Jianzhu University(2020QDZ02).
文摘To further enhance the recovery rate of low-temperature waste heat,the low-temperature flue gas in the sinter annular cooler was chosen as the heat source of an organic Rankine cycle(ORC)system,and the comprehensive evaluation of energy,exergy and economic performance of the ORC system was conducted deeply.The energy,exergy and economic performance models of the ORC system were established,and proper candidate organic working fluids(OWFs)were selected based on the thermo-physical properties of OWF and operating characteristics of ORC system.Then,the effects of ORC crucial parameters on the system energy,exergy and economic performances were evaluated in detail.Finally,the bi-objective optimization based on the genetic algorithm was conducted to analyze the optimal performance of the ORC system under the designed ORC crucial parameters,and the exergy efficiency and electricity production cost were set as the evaluation indexes of parametric optimization.The results indicate that the ORC system with the higher evaporation temperature and lower condensation temperature can obtain the larger system exergy efficiency and smaller electricity production cost.The smaller the superheat degree of OWF and pinch-point temperature difference in the evaporator are,the better the energy and exergy performances of the ORC system are.Under the optimization results,R245fa has the best comprehensive performance with the exergy efficiency of 46.34%and electricity production cost of 0.12123$/kWh among the selected candidate OWFs,which should be preferentially chosen as the OWF of the ORC system.
基金financially supported by the Key Project of Research and Development Plan of Jiangxi Province(Nos.20223BBG74006 and 20201BBE51007)the National Science Foundation of China(No.52060018)the National Science Fund for Distinguished Young Scholars(No.52125002)。
文摘The efficient and environmentally friendly recycling technology of waste residue that including abundant heavy metal produced during the recovery of lithium batteries has become a research hotspot.Herein,a novelty process of acid leaching-selective electrodeposition-deep impurity removal-regeneration was proposed to recovery of the CuS slag,which has been efficient transferred to high purity cathode copper and commercially available ternary precursors.Copper cathode with a purity of 99.67%was prepared under electrochemical reaction conditions at-0.55 V for 2 h.A novel impurity remover-Mn powder,which was used to remove the residual impurities and as a feedstock for the ternary precursor.Finally,NCM523 was regenerated by co-precipitation.The process is superior to the traditional process in economy,energy consumption,CO_(2)emissions,product purity and process duration.This study provides a new approach for solid waste recovery and precious metal enrichment.
基金the Science and Technology Foundation of Shaanxi Province (No.2002K08-G9).
文摘Two novel thermal cycles based on Brayton cycle and Rankine cycle are proposed, respectively, which integrate the recovery of low-level waste heat and Liquefied Nature Gas （LNG） cold energy utilization for power generation. Cascade utilization of energy is realized in the two thermal cycles, where low-level waste heat,low-temperature exergy and pressure exergy of LNG are utilized efficiently through the system synthesis. The simulations are carried out using the commercial Aspen Plus 10.2, and the results are analyzed. Compared with the conventional Brayton cycle and Rankine cycle, the two novel cycles bring 60.94% and 60% in exergy efficiency, respectively and 53.08% and 52.31% in thermal efficiency, respectively.
基金partial support of UK EPSRC under grants EP/V012053/1,EP/S032622/1,EP/P004709/1,EP/P003605/1 and EP/N032888/1the British Council under 2020-RLWK12-10478 and 2019-RLWK11-10724。
文摘Liquefied natural gas(LNG)is regarded as one of the cleanest fossil fuel and has experienced significant developments in recent years.The liquefaction process of natural gas is energy-intensive,while the regasification of LNG gives out a huge amount of waste energy since plenty of high grade cold energy(-160℃)from LNG is released to sea water directly in most cases,and also sometimes LNG is burned for regasification.On the other hand,liquid air energy storage(LAES)is an emerging energy storage technology for applications such as peak load shifting of power grids,which generates 30%-40%of compression heat(-200℃).Such heat could lead to energy waste if not recovered and used.The recovery of the compression heat is technically feasible but requires additional capital investment,which may not always be economically attractive.Therefore,we propose a power plant for recovering the waste cryogenic energy from LNG regasification and compression heat from the LAES.The challenge for such a power plant is the wide working temperature range between the low-temperature exergy source(-160℃)and heat source(-200℃).Nitrogen and argon are proposed as the working fluids to address the challenge.Thermodynamic analyses are carried out and the results show that the power plant could achieve a thermal efficiency of 27%and 19%and an exergy efficiency of 40%and 28%for nitrogen and argon,respectively.Here,with the nitrogen as working fluid undergoes a complete Brayton Cycle,while the argon based power plant goes through a combined Brayton and Rankine Cycle.Besides,the economic analysis shows that the payback period of this proposed system is only 2.2 years,utilizing the excess heat from a 5 MW/40 MWh LAES system.The findings suggest that the waste energy based power plant could be co-located with the LNG terminal and LAES plant,providing additional power output and reducing energy waste.
基金financially supported by the National Natural Science Foundation of China(No.51972019)the National Key Research and Development Program of China(No.2019YFC1905702)。
文摘Waste heat recovery from hot steel slag was determined in a granular bed through the combination of numerical simulation and an industrial test method.First,the effective thermal conductivity of the granular bed was calculated.Then,the unsteady-state model was used to simulate the heat recovery under three different flow fields(O-type,S-type,and nonshielding type(Nontype)).Second,the simulation results were validated by in-situ industrial experiments.The two methods confirmed that the heat recovery efficiencies of the flow fields from high to low followed the order of Nontype,S-type,and O-type.Finally,heat recovery was carried out under the Nontype flow field in an industrial test.The heat recovery efficiency increased from~76%and~78%to~81%when the steel slag thickness decreased from 400 and 300 to 200 mm,corresponding to reductions in the steel slag mass from 3.96 and 2.97 to 1.98 t with a blower air volume of 14687 m^(3)/h.Therefore,the research results showed that numerical simulation can not only guide experiments on waste heat recovery but also optimize the flow field.Most importantly,the method proposed in this paper has achieved higher waste heat recovery from hot steel slag in industrial scale.
基金Project(2009Gk2009)supported by the Science and Technology Department Funds of Hunan Province,ChinaProject(12C0379)supported by the Scientific Research Fund of Hunan Province,ChinaProject(13QDZ04)supported by the Scientific Research Foundation for Doctors of Xiang Tan University,China
文摘Dynamic performance is important to the controlling and monitoring of the organic Rankine cycle(ORC) system so to avoid the occurrence of unwanted conditions. A small scale waste heat recovery system with organic Rankine cycle was constructed and the dynamic behavior was presented. In the dynamic test, the pump was stopped and then started. In addition, there was a step change of the flue gas volume flow rate and the converter frequency of multistage pump, respectively. The results indicate that the working fluid flow rate has the shortest response time, followed by the expander inlet pressure and the expander inlet temperature.The operation frequency of pump is a key parameter for the ORC system. Due to a step change of pump frequency(39.49-35.24 Hz),the expander efficiency and thermal efficiency drop by 16% and 21% within 2 min, respectively. Besides, the saturated mixture can lead to an increase of the expander rotation speed.
基金supported by the Hi-Tech Research and Development Program (863) of China (No. 2007AA061300)the Innovation Program of Undergraduate Students in Shanghai Province (No. 0400107092)Collaborative Innovation Center for Regional Environmental Quality
文摘The rapid development of the fluorinated pesticide industry has produced a large amount of fluorine-containing hazardous waste, especially inorganic fluoride-containing waste（IFCW）. A two-step process, including extraction and recovery, was developed to recover fluorine as synthetic cryolite from IFCW produced by the pesticide industry. The optimum conditions for extraction were found to be a temperature of 75℃, an initial p H（p Hi） of 12, a4-hr incubation time and a liquid-to-solid ratio of 40 m L/g; these conditions resulted in a fluorine extraction ratio of 99.0%. The effects of p H and the F/Al molar ratio on fluorine recovery and the compositional, mineralogical and morphological characteristics of the cryolite products were investigated. Field-emission scanning electron microscopy of recovered precipitates showed changes in morphology with the F/Al molar ratio. Coupling Fourier transform and infrared spectroscopy, X-ray diffraction indicated that the formation of Al F3-6was restricted as increasing p H. Both the amount of fluorine recovered and the quality of the cryolite were optimized at initial p H = 3 and a F/Al molar ratio 5.75. This study proposed a reliable and environmentally friendly method for the treatment of fluoridecontaining wastes, which could be suitable for industrial applications.
基金support for this work provided by the National Natural Science Foundation of China(51974087 and 51904074)Anhui Provincial Natural Science Foundation(1908085QE203)+1 种基金Natural Science Research Foundation of Anhui Province University(2022AH050262)Science Research Foundation of Anhui Jianzhu University(2020QDZ02).
文摘In order to improve the recovery and utilization rates of sinter waste heat effectively,the organic Rankine cycle(ORC)system with subcritical cycle was designed to recover the low-temperature sinter cooling flue gas waste heat in an annular cooler for power generation.The thermodynamic,economic and multi-objective optimization models of ORC system were established,and R600a was selected as the ORC working medium.Subsequently,the variations in system thermodynamic performance and economic performance with the ORC thermal parameters were discussed in detail,and the optimal ORC thermal parameters were determined.The results show that the system net output power increases with increasing the evaporation temperature and decreasing the condensation temperature and increases first and then,decreases with the increase in superheat degree for a given flue gas outlet temperature in the evaporator,while the heat transfer area per unit net output power appears different variation trends in various ranges of flue gas outlet temperature.Taking the sinter cooling flue gas waste heat of 160℃as the ORC heat source,the optimal thermal parameters of ORC system were the flue gas outlet temperature of 90℃,the evaporation temperature of 95℃,the superheat degree of 10℃,and the condensation temperature of 28℃.
文摘The common problem of cold strip continuous annealing furnaces is high exhaust gas temperature and great energy consumption. Taking the cold-strip continuous annealing furnaces of Baosteel No. 4 cold mill plant as an example, several waste heat recovery systems in the annealing furnaces are compared and their advantages and disadvantages are analyzed through different energy-saving technologies.
文摘Concentrating Solar Power(CSP)plants offer a promising way to generate low-emission energy.However,these plants face challenges such as reduced sunlight during winter and cloudy days,despite being located in high solar radiation areas.Furthermore,their dispatch capacities and yields can be affected by high electricity consumption,particularly at night.The present work aims to develop an off-design model that evaluates the hourly and annual performances of a parabolic trough power plant(PTPP)equipped with a waste heat recovery system.The study aims to compare the performances of this new layout with those of the conventional Andasol 1 plant,with the aim of assessing the improvements achieved in the new design.Based on the results,it can be concluded that the new layout has increased the annual generated power to almost 183 GWh(an increase of about 7.60% is achieved compared to the Andasol 1 layout that generates 169 GWh annually).Additionally,the proposed installation has achieved an efficiency of 20.55%,which represents a 7.87% increase compared to the previous design(19.05%).The Levelized Cost of Electricity(LCOE)of the new layout has been reduced by more than 5.8% compared to the Andasol 1 plant.Specifically,it has decreased from 13.11 to 12.35 c/kWh.This reduction in LCOE highlights the improved cost-effectiveness of the newlayout,making it amore economically viable option for generating electricity compared to the conventional Andasol 1 plant.
基金supported by the Key Science and Technology Project of China Southern Grid Co.,Ltd.(No.090000KK52220020).
文摘Data centers(DCs)are highly energy-intensive facilities,where about 30%–50%of the power consumed is attributable to the cooling of information technology equipment.This makes liquid cooling,especially in twophase mode,as an alternative to air cooling for the microprocessors in servers of interest.The need to meet the increased power density of server racks in high-performance DCs,along with the push towards lower global warming potential(GWP)refrigerants due to environmental concerns,has motivated research on the selection of two-phase heat transfer fluids for cooling servers while simultaneously recovering waste heat.With this regard,a heat pump-assisted absorption chiller(HPAAC)system for recovering waste heat in DCs with an on-chip twophase cooling loop driven by the compressor is proposed in the present paper and the low GWP hydrofluoroolefin refrigerants,including R1224yd(Z),R1233zd(E),R1234yf,R1234ze(E),R1234ze(Z),R1243zf and R1336mzz(Z),are evaluated and compared against R245fa as server coolant.For theHPAAC system,beginning with the development of energy and economic models,the performance is analyzed through both a parametric study and optimization using the coefficient of performance(COP),energy saving ratio(ESR),payback period(PBP)and net present value(NPV)as thermo-economic indicators.Using a standard vapor compression cooling system as a benchmark,the results indicate that with the evaporation temperature between 50℃and 70℃and the subcooling degree ranging from5℃to 15°C,R1233zd(E)with moderate compressor suction pressure and pressure ratio is the best refrigerant for the HPAAC systemwhile R1234yf performs the worst.More importantly,R1233zd(E)is also superior to R245fa based on thermo-economic performance,especially under work conditions with relatively lower evaporation temperature as well as subcooling degree.Under the given working conditions,the overall COP,ESR,NPV,and PBP of R1233zd(E)HPAAC with optimum subcooling degree range from4.99 to 11.27,25.53 to 64.59,1.13 to 4.10×10^(7) CNY and 5.77 to 2.22 years,respectively.Besides,the thermo-economic performance of R1233zd(E)HPAAC under optimum working conditions in terms of subcooling degree varying with the evaporation temperature is also investigated.
文摘The waste referred to includes solid waste and sludge. Solid waste is mainly from urban garbage and industrial waste. Sludge is from water treatment factories, paper mills, chemical factories, pharmaceutical factories, rivers and lakes. The waste and sludge are very harmful to water organisms, human health and drinking water, and directly affect the environment. Sludge and waste also occupy large areas of land. There are several methods to treat waste and sludge, such as burial, chemical treatment and incineration. Incineration is more effective than the
文摘In this paper, a detailed thermodynamic analysis of the pure low-temperature waste heat recovery generation system is presented. The parameters affecting the system performance are compared to obtain the most significant ones; furthermore, parameter values are optimized for the largest power generating capability of the system. It is found that the most important parameters are inlet flue gas temperature, steam pressure and the pinch point temperature difference. There is an optimal superheated steam pressure value for giving the maximum generation power per unit flue gas. With the increase of inlet flue gas temperature, the generating power increases and the optimized steam pressure rises as well. However, with increase in pinch point temperature difference, the generating power decreases and the optimized steam pressure decreases as well. The theoretical calculation provides a theoretical basis for the parameters optimization in the design of the pure low-temperature waste heat recovery eeneration swtem
文摘In recent years, China pays more attention to the protection of environment and resources in the process of social and economic development, puts forward the development concept of green, energy saving and environmental protection, and carries on a clear specification for the development of various industries. Under the current situation, flue gas waste heat recovery and utilization technology has attracted more and more attention, which can avoid the waste of energy and maximize the interests of enterprises. Therefore, relevant personnel should pay attention to study and analyze the application of flue gas waste heat recovery and utilization technology, in order to provide some help for the development of enterprises.
文摘Using the boiler smoke waste heat, the actual energy saving reconstruction in case of boiler flue gas waste heat recovery and energy saving effect is analyzed, the design of waste heat recovery plan, improve the boiler heating water temperature, in order to improve the boiler thermal efficiency, at the same time reduce the emissions of pollutants such as flue gas nitrogen oxides, achieve energy conservation and emissions reduction.
文摘In order to address the synergistic optimization of energy efficiency improvement in the waste incineration power plant(WIPP)and renewable energy accommodation,an electricity-hydrogen-waste multi-energy system integrated with phase change material(PCM)thermal storage is proposed.First,a thermal energy management framework is constructed,combining PCM thermal storage with the alkaline electrolyzer(AE)waste heat recovery and the heat pump(HP),while establishing a PCM-driven waste drying system to enhance the efficiency of waste incineration power generation.Next,a flue gas treatment method based on purification-separation-storage coordination is adopted,achieving spatiotemporal decoupling between waste incineration and flue gas treatment.Subsequently,a two-stage optimal dispatching strategy for the multi-energy system is developed:the first stage establishes a dayahead economic dispatch model with the objective of minimizing net system costs,while the second stage introduces model predictive control(MPC)to realize intraday rolling optimization.Finally,The optimal dispatching strategies under different scenarios are obtained using the Gurobi solver,followed by a comparative analysis of the optimized operational outcomes.Simulation results demonstrate that the proposed system optimizes the output and operational states of each unit,simultaneously reducing carbon trading costs while increasing electricity sales revenue.The proposed scheduling strategy demonstrates effective grid peak-shaving functionality,thereby simultaneously improving the system’s economic performance and operational flexibility while providing an innovative technical pathway for municipal solid waste(MSW)resource utilization and low-carbon transformation of energy systems.
基金Lombardia Region for financial support (Progetto Ingenio)
文摘The aim of the research was to develop new products and processes from a manufacturing waste from an Italian metallurgic company.The company produced thin silver metallic films and the production scraps were silver flakes.The possibility to use the silver flakes in water disinfection processes was studied.The antimicrobial activity of the flakes was investigated in batch using Escherichia coli as Gram-negative microorganism model.The flakes did not show any antimicrobial activity,so they were activated with two different processes： thermal activation in reducing atmosphere and chemical activation,obtaining,respectively,reduced flakes （RF） and chemical flakes （CF）.The flakes,activated with either treatment,showed antimicrobial activity against E.coli.The kill rate was dependent on the type of activated flakes.The chemical flakes were more efficient than reduced flakes.The kill rate determined for 1 g of CF,1.0 ± 0.2 min ？1 ,was greater than the kill rate determined for 1 g of RF,0.069 ± 0.004 min ？1 .This was confirmed also by the minimum inhibitory concentration values.It was demonstrated that the antimicrobial capability was dependent on flakes amount and on the type of aqueous medium.Furthermore,the flakes maintained their properties also when used a second time.Finally,the antimicrobial activities of flakes were tested in an effluent of a wastewater treatment plant where a variety of heterotrophic bacteria were present.
基金supported by the Applied Basic Research Key Project of Yunnan Province (No.2007E0014Z)
文摘Possibility of combustible gas production from municipal solid waste （MSW） using hot blast furnace （BF） slag has been studied.The objective of this work is to generate combustible gas from MSW using heated BF slag.In this experiment,the thermal stability of the MSW was analyzed by thermogravimetric analysis,and effects of temperature,gasifying agent （air,N2,steam） and BF slag on the gas products were investigated at 600？900 ？C.The thermogravimetric analysis indicates that the weight loss of MSW includes four stages：evaporation of the moisture,combustion of volatile materials,burning of carbon residue and burnout of ash.The contents of the combustible gas increase with increasing temperature,and the lower calorific value （LCV） increases rapidly at 600？900 ？C.It is found that volume fraction of CO,H2 and CH4 at different atmospheres increases in the order N2〈air〈steam.It is believed that BF slag acts as the catalyst and the heat carrier,which promotes the gasification reactivity of MSW.
基金Sponsored by National Natural Science Foundation of China (5106602,U0937604)Natural Science Foundation of Yunnan Provincial (2008KA002,2008CD001)
文摘Low temperature exhaust gases carrying large amount of waste heat are released by steel-making process and many other industries, Organic Rankine Cycles （ORCs） are proven to be the most promising technology to re- cover the low-temperature waste heat, thereby to get more financial benefits for these industries. The exergy analysis of ORC units driven by low-temperature exhaust gas waste heat and charged with dry and isentropic fluid was per- formed, and an intuitive approach with simple impressions was developed to calculate the performances of the ORC unit. Parameter optimization was conducted with turbine inlet temperature simplified as the variable and exergy effi- ciency or power output as the objective function by means of Penalty Function and Golden Section Searching algo- rithm based on the formulation of the optimization problem. The power generated by the optimized ORC unit can be nearly as twice as that generated by a non-optimized ORC unit. In addition, cycle parametric analysis was performed to examine the effects of thermodynamic parameters on the cycle performances such as thermal efficiency and exergy efficiency. It is proven that performance of ORC unit is mainly affected by the thermodynamic property of working fluid, the waste heat temperature, the pinch point temperature of the evaporator, the specific heat capacity of the heat carrier and the turbine inlet temperature under a given environment temperature.
