The influence of in-situ precipitation on corrosion behaviors of wire arc directed energy deposited (WADED) Al-Mg-(Sc-Zr) was studied. WADED Al-Mg showed a homogeneous microstructure with coarse equiaxed grains. WADED...The influence of in-situ precipitation on corrosion behaviors of wire arc directed energy deposited (WADED) Al-Mg-(Sc-Zr) was studied. WADED Al-Mg showed a homogeneous microstructure with coarse equiaxed grains. WADED Al-Mg-Sc-Zr exhibited fine equiaxed grains along the molten pool boundary (MPB) and inter-layer zone (ITZ) while coarse equiaxed grains were inside the molten pool. The in-situ precipitation resulted in the primary Al_(3)(Sc, Zr) aggregated along MPB and ITZ while minor-sized secondary Al_(3)(Sc, Zr) existed inside the molten pool. WADED Al-Mg-Sc-Zr showed improved electrochemical behavior than Al-Mg. WADED Al-Mg presented random pittings that occurred near dispersed β-Al_(3)Mg_(2). WADED Al-Mg-Sc-Zr exhibited pittings along MPB and ITZ, where Al_(3)(Sc, Zr) aggregated and induced galvanic corrosion. Corrosion anisotropy was obvious in Al-Mg-Sc-Zr since more MPBs and ITZs make the XOZ plane susceptive to localized corrosion.展开更多
基金supported by the National Natu-ral Science Foundation of China(grant Nos.52105315,U20B2031,52075022,52075024,and 52175283)the Natural Science Founda-tion of Beijing Municipality(grant Nos.L248031 and3222013)+1 种基金the State Key Lab of Advanced Welding and Joining,Harbin Institute of Technology(No.AWJ-24M05)the Fundamental Research Funds for the Central Universities(Nos.JKF-20240264 andYWF-22-L-607).
文摘The influence of in-situ precipitation on corrosion behaviors of wire arc directed energy deposited (WADED) Al-Mg-(Sc-Zr) was studied. WADED Al-Mg showed a homogeneous microstructure with coarse equiaxed grains. WADED Al-Mg-Sc-Zr exhibited fine equiaxed grains along the molten pool boundary (MPB) and inter-layer zone (ITZ) while coarse equiaxed grains were inside the molten pool. The in-situ precipitation resulted in the primary Al_(3)(Sc, Zr) aggregated along MPB and ITZ while minor-sized secondary Al_(3)(Sc, Zr) existed inside the molten pool. WADED Al-Mg-Sc-Zr showed improved electrochemical behavior than Al-Mg. WADED Al-Mg presented random pittings that occurred near dispersed β-Al_(3)Mg_(2). WADED Al-Mg-Sc-Zr exhibited pittings along MPB and ITZ, where Al_(3)(Sc, Zr) aggregated and induced galvanic corrosion. Corrosion anisotropy was obvious in Al-Mg-Sc-Zr since more MPBs and ITZs make the XOZ plane susceptive to localized corrosion.
