This study investigated enhancing the wear resistance of Ti6Al4V alloys for medical applications by incorporating Ti C nanoreinforcements using advanced spark plasma sintering(SPS). The addition of up to 2.5wt% Ti C s...This study investigated enhancing the wear resistance of Ti6Al4V alloys for medical applications by incorporating Ti C nanoreinforcements using advanced spark plasma sintering(SPS). The addition of up to 2.5wt% Ti C significantly improved the mechanical properties, including a notable 18.2% increase in hardness(HV 332). Fretting wear tests against 316L stainless steel(SS316L) balls demonstrated a 20wt%–22wt% reduction in wear volume in the Ti6Al4V/Ti C composites compared with the monolithic alloy. Microstructural analysis revealed that Ti C reinforcement controlled the grain orientation and reduced the β-phase content, which contributed to enhanced mechanical properties. The monolithic alloy exhibited a Widmanstätten lamellar microstructure, while increasing the Ti C content modified the wear mechanisms from ploughing and adhesion(0–0.5wt%) to pitting and abrasion(1wt%–2.5wt%). At higher reinforcement levels, the formation of a robust oxide layer through tribo-oxide treatment effectively reduced the wear volume by minimizing the abrasive effects and plastic deformation. This study highlights the potential of SPS-mediated Ti C reinforcement as a transformative approach for improving the performance of Ti6Al4V alloys, paving the way for advanced medical applications.展开更多
Dry sliding wear tests on as-cast and cast＋T6 Mg-11Y-5Gd-2Zn magnesium alloys were performed using a ball-on-plate configuration. The wear rates were measured within a load range of 3-15 N, sliding speed range of 0.0...Dry sliding wear tests on as-cast and cast＋T6 Mg-11Y-5Gd-2Zn magnesium alloys were performed using a ball-on-plate configuration. The wear rates were measured within a load range of 3-15 N, sliding speed range of 0.03-0.24 m/s, test temperature range of 25-200 °C and at a constant sliding distance of 400 m. The wear tracks, worn surfaces and wear debris of the alloys were analyzed using scanning electron microscope （SEM）. The results show that the wear rate of the alloys increases almost linearly with increasing applied load and decreases with increasing sliding speed. The wear rate of the as-cast alloy is higher than that of the cast＋T6 alloy. The amount of Mg12Y1Zn1 phase, surface oxidation and retained wear debris affect the wear rate. The dominant wear mechanisms under the test condition are abrasion and plastic deformation.展开更多
The friction and wear behavior of magnesium matrix composites reinforced with particulate Mg2Si was characterized. The influence of Si, applied load and sliding rate on the wear behavior of Mg2Si/AM60 magnesium matrix...The friction and wear behavior of magnesium matrix composites reinforced with particulate Mg2Si was characterized. The influence of Si, applied load and sliding rate on the wear behavior of Mg2Si/AM60 magnesium matrix composites was studied. The results indicate that the particulate Mg2Si can be synthesized by adding Si into magnesium alloy. The wear properties of AM60 magnesium alloy are significantly improved with MgzSi particles. The wear mass losses of AM60 magnesium alloy and MgaSi/AM60 magnesium matrix composites decrease with increase in applied load and sliding rate. The wear feature of the AM60 magnesium alloy is adhesion wear. The wear mechanism of Mg2Si/AM60 magnesium matrix composites transforms from abrasive wear to adhesion wear with the increase of load.展开更多
The good combination of mechanical and wear properties for cemented carbides is crucial.In this work,the wear behavior of functionally graded cemented carbide(FGCC)and non-graded cemented carbide(CC),with CoNiFeCr mul...The good combination of mechanical and wear properties for cemented carbides is crucial.In this work,the wear behavior of functionally graded cemented carbide(FGCC)and non-graded cemented carbide(CC),with CoNiFeCr multi-principal-element alloy(MPEA)binder,has been investigated by performing sliding wear tests and composition characterization.The results showed that compared with CC,FGCC had higher hardness,stronger fracture toughness,better wear performance,and similar TRS.FGCCs exhibited lower wear rates(3.44×10^(−7)–6.95×10^(−6)mm^(3)/(N m))and coefficients of friction(COFs)(0.27–0.39)than CCs from RT to 600℃due to mitigation of multiple risks caused by binder removal,fragmentation and pull-out of WC grains,high-temperature oxidation and softening.In the low-temperature wear stage,the MPEA binder underwent dynamic recrystallization(DRX)and twinning deformation before removing from the surface.The binder removal caused dislocation pile-ups and stacking faults(SFs)to form under high stress,resulting in fragmentation and pull-out of WC grains.The low-temperature wear was dominated by abrasive wear and adhesive wear,with a low wear rate and a high and unstable COF.In the high-temperature wear stage,initial pitting oxidation of WC grains generated many subgrain boundaries,reducing heat transfer and exacerbating oxidation,resulting in an oxide layer enriched with WO3,Mx Oy,and MWO4.High-temperature wear was dominated by oxidation wear and high-temperature softening,with a high wear rate and a low and smooth COF.The results from the present study do not only provide theoretical guidance for an understanding of the antiwear mechanism of WC-CoNiFeCr,but also a new approach for the preparation of cemented carbides with high wear resistance.展开更多
本文探讨Art to Wear即“可以穿的艺术”,其中大部分作品为服装,少量作品是帽子和首饰。通过分析Art to Wear代表艺术家,解读Art to Wear艺术作品,从而探讨美国20世纪60年代到80年代女性艺术家群体如何以艺术为媒介对自身经历进行叙述...本文探讨Art to Wear即“可以穿的艺术”,其中大部分作品为服装,少量作品是帽子和首饰。通过分析Art to Wear代表艺术家,解读Art to Wear艺术作品,从而探讨美国20世纪60年代到80年代女性艺术家群体如何以艺术为媒介对自身经历进行叙述性表现。60年代末70年代初处于美国女性主义的第二次浪潮,众多美国名校的年轻白人女大学生,不断为女性的参政、就业、医疗、最低工资等争取更多的权利,而到了80年代遭到美国保守主义的强烈打击,追求自由平等的女性主义运动跌入低谷。第二次女性主义运动的跌宕正是Art to Wear艺术运动的发展时期,艺术学院在读青年女生们发起Art to Wear艺术运动,她们在保守主义与激进主义的影响下寻求精神、生活的平衡,极力反叛女性束身塑形来博得男性视觉愉悦、通过同性的嫉妒来肯定自身价值。她们对家庭、事业、社会地位开始深思,通过作品叙述对社会性别与身份认定的迷茫,表达保守与激进思想的内心纠结。展开更多
Large portions of the tunnel boring machine(TBM)construction cost are attributed to disc cutter consumption,and assessing the disc cutter's wear level can help determine the optimal time to replace the disc cutter...Large portions of the tunnel boring machine(TBM)construction cost are attributed to disc cutter consumption,and assessing the disc cutter's wear level can help determine the optimal time to replace the disc cutter.Therefore,the need to monitor disc cutter wear in real-time has emerged as a technical challenge for TBMs.In this study,real-time disc cutter wear monitoring is developed based on sound and vibration sensors.For this purpose,the microphone and accelerometer were used to record the sound and vibration signals of cutting three different types of rocks with varying abrasions on a laboratory scale.The relationship between disc cutter wear and the sound and vibration signal was determined by comparing the measurements of disc cutter wear with the signal plots for each sample.The features extracted from the signals showed that the sound and vibration signals are impacted by the progression of disc wear during the rock-cutting process.The signal features obtained from the rock-cutting operation were utilized to verify the machine learning techniques.The results showed that the multilayer perceptron(MLP),random subspace-based decision tree(RS-DT),DT,and random forest(RF)methods could predict the wear level of the disc cutter with an accuracy of 0.89,0.951,0.951,and 0.927,respectively.Based on the accuracy of the models and the confusion matrix,it was found that the RS-DT model has the best estimate for predicting the level of disc wear.This research has developed a method that can potentially determine when to replace a tool and assess disc wear in real-time.展开更多
To elucidate the wear mechanisms of the scraper in shield tunneling through sandy pebble strata,this study aims to achieve high efficiency and low wear during the tunneling process.We evaluate the operational paramete...To elucidate the wear mechanisms of the scraper in shield tunneling through sandy pebble strata,this study aims to achieve high efficiency and low wear during the tunneling process.We evaluate the operational parameters and tool wear characteristics of a 9-m diameter spoke-type shield machine used on the Beijing Daxing Airport Line.The analysis focuses on the wear values of the scrapers and rippers,wear of the scraper in different wear forms,and scraper wear relative to the position of the rippers obtained from the field.The study yielded the following conclusions.The wear values of scrapers on different spokes vary significantly owing to ripper protection.The wear of the scrapers can be categorized into six types:tooth chipping,local damage of teeth,wear of side teeth,wave-type of wear,wear on intermediate teeth,and flat wear,with the majority exhibiting wear on the side and intermediate teeth.The 0°spoke maintained the initial shape of the scrapers,making it more suitable for tunneling in sandy pebble strata.Based on the differences in the relative positions of the ripper and scraper,a model is proposed to determine the ripper plowing influence area.It was found that this area depends on the geological conditions of the soil;thus,the influence angle of ripper plowing in the considered sandy pebble strata is determined to be between 35°and 50°.The results obtained in this study provide a theoretical reference for optimizing scraper layouts in shield construction,even when operating under varying geological conditions.展开更多
The impact-abrasive wear behavior of high-C martensitic steel was investigated,taking into account varying carbon(C)contents and different tempering temperatures.The evaluation was done through comprehensive microstru...The impact-abrasive wear behavior of high-C martensitic steel was investigated,taking into account varying carbon(C)contents and different tempering temperatures.The evaluation was done through comprehensive microstructural characterization,analysis of worn surface morphology,and measurement of key performance like impact toughness and surface hardening.The findings demonstrate that increasing C content and tempering temperature both has a positive effect on wear resistance,with C content exhibiting a more pronounced influence compared to the tempering temperature.The improved wear resistance of the steel with higher C content and tempering at a higher temperature can be attributed to its enhanced impact toughness.This increase in impact toughness is primarily a result of microstructural refinement and alterations in carbide morphology.Moreover,cyclic impact loading induces surface hardening due to dislocation strengthening within the martensite and the retained austenite,leading to an increase in surface hardness.The combination of surface hardening and excellent impact toughness synergistically contributes to the overall improved wear resistance observed in the experimental steel with higher C content after tempering at a higher temperature.Additionally,the dominant features observed on the worn surface are scratches and substrate delamination,indicative of a wear mechanism of the experimental steels characterized by micro-cutting/ploughing and fatigue wear.展开更多
The microstructural evolution,mechanical properties,and wear behavior of medium manganese steels(MMSs)with varying aluminum(Al)contents were investigated.It was observed that the microstructure of MMS transferred from...The microstructural evolution,mechanical properties,and wear behavior of medium manganese steels(MMSs)with varying aluminum(Al)contents were investigated.It was observed that the microstructure of MMS transferred from a predominantly martensitic phase(in the Al-free state)to a ferrite/martensite or ferrite/austenite duplex structure with increasing Al content.The hardness of MMS decreased with Al addition,while the impact absorbed energy and yield strength were optimized in 2%Al-containing variant.Frictional wear tests demonstrated that 2 wt.%Al-MMS exhibited superior wear resistance due to the twinning-induced plasticity effect.Conversely,under impact abrasion wear conditions,the Al-free MMS displayed the lowest mass loss,attributing to high surface hardness and remarkable work hardening capacity.These findings indicates that Al content-tailored MMSs can be selectively applied in different wear environments,with 2 wt.%Al-MMS being optimal for static load conditions and the Al-free MMS for dynamic impact abrasion scenarios.展开更多
CrN coatings are also employed to protect structural materials in nuclear power plants.It should be noted that the preparation process utilizing physical vapor deposition(PVD)techniques inevitably entails certain defe...CrN coatings are also employed to protect structural materials in nuclear power plants.It should be noted that the preparation process utilizing physical vapor deposition(PVD)techniques inevitably entails certain defects.Such a phenomenon will affect the protective properties of CrN coatings.In this study,low-energy laser shock peening(LE-LSP)with varying energies was employed for the post-treatment of CrN coatings.The effects of different laser energy LE-LSP treatments on the surface morphology,crystal structure and fretting wear properties of CrN coatings were investigated.The results revealed that the surface of the CrN coatings subjected to LE-LSP underwent significant plastic deformation and displayed a regular texture structure.The surface roughness and Vickers hardness of the CrN coatings exhibit a significant increase.Under a laser energy of 150 mJ,the surface hardness exhibits a maximum increase of 2.35 times.The residual stress of CrN coatings diminishes with the augmentation of laser energy due to the formation of surface cracks.Following LE-LSP treatment,the columnar crystal structure of the CrN coating was disrupted and fragmented into fine grains due to the impact force.As the laser energy augments,the fragmented CrN grains undergo further compaction.During fretting wear,all specimens were in the gross slip regime.The wear mechanism of the CrN coating,120 and 150 mJ specimens are primarily dominated by abrasive wear,and accompanied by oxidative wear.For specimens treated with 30,60 and 90 mJ,the predominant wear mechanisms are mainly peeling and abrasive wear,and accompanied by oxidative wear.Both the wear area and wear volume initially increase and then decrease as the laser energy increases.The 150 mJ specimen exhibited the smallest wear area and wear volume of all tested specimens.The wear volume was reduced by 76.32%when compared to that of the CrN coating.This study complements the existing research on PVD/LSP composite strengthening techniques.Introduces a novel post-treatment methodology for PVD coatings.Provides certain theoretical support for subsequent PVD/LSP composite strengthening.展开更多
The wear of work rolls significantly affects the production efficiency and product quality.However,existing methods for wear assessment fail to effectively quantify work roll surface wear conditions,thereby affecting ...The wear of work rolls significantly affects the production efficiency and product quality.However,existing methods for wear assessment fail to effectively quantify work roll surface wear conditions,thereby affecting the quality control of steel strips and maintenance strategies for rolls.To accurately assess the wear conditions of hot-rolling work rolls,this study initially established an apparatus for capturing high-precision roll surfaces images.Subsequently,a quantitative assessment of common surface wear morphologies was conducted,and a hot-rolling work roll surface wear dataset was constructed.The MobileNetV2 convolutional neural network(CNN),augmented by transfer learning,was employed to develop a MobileNetV2-wear detection and classification(WDC)surface wear grading model.A comparison with mainstream CNN models revealed that the MobileNetV2-WDC model achieved high-speed(21.92 ms)and accurate(96.86%)grading with minimal model parameters(2.27 M)and size(27 M),meeting the industrial efficiency and practicality requirements.A visual analysis of the model classification errors was conducted,outlining paths for further optimization.This study provides an efficient and accurate solution for detecting and grading surface wear on hot-rolling work rolls,enhancing product quality and extending the lifespan of rolls.展开更多
The friction and wear properties of Mg2B2O5 whisker reinforced 6061Al matrix composite fabricated via power ultrasonic-stir casting process were investigated using a ball-on-disk wear-testing machine against a GCr45 s...The friction and wear properties of Mg2B2O5 whisker reinforced 6061Al matrix composite fabricated via power ultrasonic-stir casting process were investigated using a ball-on-disk wear-testing machine against a GCr45 steel counterface under dry sliding conditions. The reinforcements include as-received Mg2B2O5 whiskers and Mg2B2O5 whiskers coated with CuO and ZnO. The volume fraction of the composites is 2%. The relationship between the wear rate and the coefficient of friction was discussed. The results indicate that the wear rate of the Mg2B2O5 whiskers coated with ZnO reinforced aluminum matrix composites is the lowest among the materials. As the applied load and sliding speed steadily increase the coefficients of friction and wear rates of the as-received matrix alloy and the fabricated composites decrease. As the applied load and sliding speed increase, the wear mechanisms of the composites shift from a mild to a severe regime.展开更多
To develop a wear-resistant steel with excellent mechanical properties and superior wear resistance,low alloy wear-resistant steels with different contents of rare earth were prepared through induction smelting,rollin...To develop a wear-resistant steel with excellent mechanical properties and superior wear resistance,low alloy wear-resistant steels with different contents of rare earth were prepared through induction smelting,rolling,quenching,and tempering.The effects of Ce on the inclusion characteristics,mechanical properties,and wear resistance of the test steels were investigated through scanning electron microscopy and energy dispersive X-ray spectroscopy,mechanical property testing,and impact abrasive wear testing.The results indicated that adding Ce to the low alloy wear-resistant steel significantly reduced the number and size of inclusions.When the Ce content reached 0.0037 wt.%,irregular Al_(2)O_(3) and MnS inclusions were significantly reduced and were replaced by nearly spherical Ce_(2)O_(2)S,CeS,and CeP inclusions.The comprehensive mechanical properties including the strength,post-fracture elongation,Brinell hardness,and impact toughness of the test steels were enhanced in various degrees.In particular,the low-temperature impact toughness of the test steels increased from 18 to 39 J as the Ce content rose from 0 to 0.0037 wt.%.The wear mass loss of the test steel gradually decreased with increasing the Ce content,indicating that the addition of Ce significantly enhances the wear resistance of low alloy wear-resistant steel.Under impact loading,a plastic deformation zone called sub-surface layer with a thickness of 10–30μm formed on the worn surface.Work hardening from the plastic deformation strengthened the microhardness of the sub-surface layer,thus improving the wear resistance of the test steel.With increasing the Ce content,the wear resistance of the test steel further improved due to thickening the sub-surface layer.展开更多
The wear patterns and wear mechanisms of solid cemented carbide are analyzed in high-speed milling of aluminum alloy. Results show that the dominant wear patterns are coating damage, crater wear, micro-chipping, break...The wear patterns and wear mechanisms of solid cemented carbide are analyzed in high-speed milling of aluminum alloy. Results show that the dominant wear patterns are coating damage, crater wear, micro-chipping, breakage, and so on. The main wear mechanisms are adhesion, diffusion and fatigue. Compared with conventional speed machining, the effect and impact of thermal-dynamical coupling field play an important role in the cutting tool wear in high-speed milling of aluminum alloy.展开更多
Wrought and laser powder bed fusion(LPBF)Ti−6Al−4V(Ti-6-4)specimens were comparatively evaluated,with the objective to determine LPBF Ti−6Al−4V’s suitability for biomedical applications.Testing included nanoindentati...Wrought and laser powder bed fusion(LPBF)Ti−6Al−4V(Ti-6-4)specimens were comparatively evaluated,with the objective to determine LPBF Ti−6Al−4V’s suitability for biomedical applications.Testing included nanoindentation,cyclic polarization in simulated body fluid(SBF,37°C),and dry and SBF“ball-on-plate”sliding.Wrought Ti-6-4 exhibited a lamellarα+βmicrostructure,whereas LPBF Ti-6-4 displayed a fine-grainedα′-martensite microstructure.LPBF Ti-6-4 demonstrated~3%higher indentation modulus and~32%higher hardness,while wrought Ti-6-4 showed~8%higher plasticity.Both alloys exhibited low corrosion rates(10−5 mA/cm^(2)order)and true passivity(10−4 mA/cm^(2)order).No localized corrosion was observed in either two alloys,except for occasional metastable pitting in the LPBF alloy.However,LPBF Ti-6-4 presented higher corrosion rate and passive current,ascribed to its martensitic structure.During dry sliding,LPBF Ti-6-4 exhibited~14%lower volume loss compared to wrought Ti-6-4.Sliding in SBF increased volume losses for both alloys,with wear resistances nearly equalized,as the advantage of LPBF Ti-6-4 decreased due to more intense wear-accelerated corrosion induced by the stressed martensite.Overall,the results demonstrate the suitability of LPBF Ti-6-4 for biomedical uses.展开更多
Dry sliding wear tests were performed on a Mg-10Y-4Gd-1.5Zn-0.4Zr alloy using a Ball-on-Flat type wear apparatus against an AISI 52100 type bearing steel ball counterface. The wear rates were measured within a load ra...Dry sliding wear tests were performed on a Mg-10Y-4Gd-1.5Zn-0.4Zr alloy using a Ball-on-Flat type wear apparatus against an AISI 52100 type bearing steel ball counterface. The wear rates were measured within a load range of 3-25 N, a sliding speed range of 0.03-0.3 m/s and a sliding temperature range of 25-200 ℃ at a constant sliding distance of 400 m. The morphologies of the worn surfaces and wear debris were studied by scanning electron microscopy （SEM） and energy dispersive X-ray spectroscopy （EDS）. Comparatively, the wear properties of a hypereutectic Al-Si aluminium alloy under the same condition were measured. The results indicate that the wear rates of Mg-10Y-4Gd-1.5Zn-0.4Zr alloy are lower than that of cast＋T6 AC9B aluminium alloy. The dominant mechanism of cast＋T6 Mg-10Y-4Gd-1.5Zn-0.4Zr alloy is abrasion wear mixed with other wear mechanisms, which tends to be an abrasion and plastic deformation wear at high normal load such as 10-25 N, abrasion and plastic deformation wears with small participation of delamination and oxidative wears at high sliding speed such as 0.12-0.3 m/s, and an oxidative and abrasion wear at high test temperature such as 100-200 ℃. The Mg12Y1Zn1 phase in Mg-10Y-4Gd-1.5Zn-0.4Zr alloy plays an important role in the wear rate.展开更多
In-situ formed high Mn steel coating reinforced by carbides was formed by laser surface alloying(LSA).Laser alloyed layers on 1Cr18Ni9Ti steel with Mn+W_(2)C(specimen A),Mn+NiWC(specimen B)and Mn+SiC(specimen C)powder...In-situ formed high Mn steel coating reinforced by carbides was formed by laser surface alloying(LSA).Laser alloyed layers on 1Cr18Ni9Ti steel with Mn+W_(2)C(specimen A),Mn+NiWC(specimen B)and Mn+SiC(specimen C)powders were fabricated to improve the wear and corrosion behavior of 1Cr18Ni9Ti steel blades in high speed mixers.Microstructure evolution,phases,element distribution,microhardness,wear and corrosion behavior of the laser alloyed layers were investigated.Results indicated that high Mn steel matrix composites with undissolved W_(2)C,WC and other in-situ formed carbides were formed by LSA with Mn+W_(2)C and Mn+NiWC while SiC totally dissolved into the high Mn matrix when adding Mn+SiC.Ni as the binding phase in Ni-WC powder decreased the crack sensitivity of the alloyed layer as compared with the addition of W_(2)C powder.An improvement in average microhardness was achieved in the matrix in specimen A,B and C,with the value of 615,602 and 277 HV_(0.5),while that of the substrate was 212 HV_(0.5).The increase of microhardness,wear and corrosion resistance is highly corelated to microstructure,formed phases,type and content of carbides,micro-hardness and toughness of the alloyed layers.展开更多
Co-based alloy coating was prepared on Zr alloy using laser melting and cladding technique to study the difference in the high-temperature oxidation behavior between pure metal Co coatings and Co-T800 alloy coatings,a...Co-based alloy coating was prepared on Zr alloy using laser melting and cladding technique to study the difference in the high-temperature oxidation behavior between pure metal Co coatings and Co-T800 alloy coatings,as well as the wear resistance of the coatings.Besides,the effect of changing the laser melting process on the coatings was also investigated.The oxidation mass gain at 800–1200℃and the high-temperature oxidation behavior during high-temperature treatment for 1 h of two coated Zr alloy samples were studied.Results show that the Co coating and the Co-T800 coating have better resistance against high-temperature oxidation.After oxidizing at 1000℃for 1 h,the thickness of the oxide layer of the uncoated sample was 241.0μm,whereas that of the sample with Co-based coating is only 11.8–35.5μm.The friction wear test shows that the depth of the abrasion mark of the coated sample is only 1/2 of that of the substrate,indicating that the hardness and wear resistance of the Zr substrate are greatly improved.The disadvantage of Co-based coatings is the inferior corrosion resistance in 3.5wt%NaCl solution.展开更多
WC particles reinforced CoCrFeNiMo high-entropy alloy(HEA)composite coatings were prepared on Cr12MoV steel successfully by laser cladding technology to improve the wear resistance of substrates.Effect of WC content o...WC particles reinforced CoCrFeNiMo high-entropy alloy(HEA)composite coatings were prepared on Cr12MoV steel successfully by laser cladding technology to improve the wear resistance of substrates.Effect of WC content on microstructure and wear property of the composite coatings was studied in detail.Large numbers of carbides with four main types:primary carbide crystals,eutectic structures,massive crystals growing along the periphery of the remaining WC particles and incompletely fused WC particles,were found to exist in the WC/CoCrFeNiMo composite coatings.With increasing WC content,the microhardness of coatings is gradually improved while the average friction coefficients follow the opposite trend due to solid solution strengthening and second phase strengthening effect.The maximum microhardness and minimum friction coefficient are HV_(0.2)689.7 and 0.72,respectively,for the composite coating with 30 wt.%WC,the wear resistance of the substrate is improved significantly,the wear mechanisms are spalling wear and abrasive wear due to their high microhardness.展开更多
Stainless steel parts with complex shape can be fabricated using additive manufacturing,which do not rely on molds and dies.However,coarse dendrites induced by repeated heating of additive manufacturing result in weak...Stainless steel parts with complex shape can be fabricated using additive manufacturing,which do not rely on molds and dies.However,coarse dendrites induced by repeated heating of additive manufacturing result in weak properties,which limits its application.In this study,an in-situ ultrasonic rolling(UR)device was developed to assist the laser directed energy deposition(LDED)process.The microstructural characteristics,as well as the microhardness and wear behavior,were studied for the 316L stainless steel manufactured by in-situ ultrasonic rolling assisted LDED.It is found that austenite,ferrite,and small Si oxides are the main constituents of both the LDED and LDED-UR alloy samples.Under the severe plastic deformation of ultrasonic rolling,the long-branched ferrites by LDED are transformed into the rod-like phases by LDED-UR.Meanwhile,the ferrite is more uniformly distributed in the LDED-UR alloy sample compared with that in LDED alloy sample.Columnar grains with the size of 97.85μm appear in the LDED alloy sample,which is larger than the fully equiaxed grains(22.35μm)of the LDED-UR alloy.The hardness of the LDED-UR alloy sample is about 266.13±13.62 HV_(0.2),which is larger than that of the LDED alloy sample(212.93±12.85 HV_(0.2)).Meanwhile,the wear resistance is also greatly enhanced by applying the assisted in-situ ultrasonic rolling.The achieved high wear resistance can be ascribed to the uniformly distributed hard matter(ferrites)and the impedance of dislocations by high fraction of grain boundaries.Abrasive wear and adhesive wear are identified as the primary wear mechanisms of the studied alloy.Gaining an in-depth understanding of the relationship between wear mechanisms and microstructures offers an effective approach in manufacturing high wear resistant alloys suitable for use in harsh working environments.展开更多
文摘This study investigated enhancing the wear resistance of Ti6Al4V alloys for medical applications by incorporating Ti C nanoreinforcements using advanced spark plasma sintering(SPS). The addition of up to 2.5wt% Ti C significantly improved the mechanical properties, including a notable 18.2% increase in hardness(HV 332). Fretting wear tests against 316L stainless steel(SS316L) balls demonstrated a 20wt%–22wt% reduction in wear volume in the Ti6Al4V/Ti C composites compared with the monolithic alloy. Microstructural analysis revealed that Ti C reinforcement controlled the grain orientation and reduced the β-phase content, which contributed to enhanced mechanical properties. The monolithic alloy exhibited a Widmanstätten lamellar microstructure, while increasing the Ti C content modified the wear mechanisms from ploughing and adhesion(0–0.5wt%) to pitting and abrasion(1wt%–2.5wt%). At higher reinforcement levels, the formation of a robust oxide layer through tribo-oxide treatment effectively reduced the wear volume by minimizing the abrasive effects and plastic deformation. This study highlights the potential of SPS-mediated Ti C reinforcement as a transformative approach for improving the performance of Ti6Al4V alloys, paving the way for advanced medical applications.
基金Project (51074106) supported by the National Natural Science Foundation of ChinaProject (2009AA033501) supported by the Hi-Tech Research and Development Program of China+1 种基金Project (09JC1408200) supported by the Science and Technology Commission of Shanghai Municipality, ChinaProject (20100480586) supported by Postdoctoral Science Foundation of China
文摘Dry sliding wear tests on as-cast and cast＋T6 Mg-11Y-5Gd-2Zn magnesium alloys were performed using a ball-on-plate configuration. The wear rates were measured within a load range of 3-15 N, sliding speed range of 0.03-0.24 m/s, test temperature range of 25-200 °C and at a constant sliding distance of 400 m. The wear tracks, worn surfaces and wear debris of the alloys were analyzed using scanning electron microscope （SEM）. The results show that the wear rate of the alloys increases almost linearly with increasing applied load and decreases with increasing sliding speed. The wear rate of the as-cast alloy is higher than that of the cast＋T6 alloy. The amount of Mg12Y1Zn1 phase, surface oxidation and retained wear debris affect the wear rate. The dominant wear mechanisms under the test condition are abrasion and plastic deformation.
基金Project supported by the Key Laboratory of Ministry of Education for Conveyance and Equipment (East China Jiaotong University), ChinaProject (GJJ11094) supported by Science Funds of Jiangxi Provincial Education Project on Department, China
文摘The friction and wear behavior of magnesium matrix composites reinforced with particulate Mg2Si was characterized. The influence of Si, applied load and sliding rate on the wear behavior of Mg2Si/AM60 magnesium matrix composites was studied. The results indicate that the particulate Mg2Si can be synthesized by adding Si into magnesium alloy. The wear properties of AM60 magnesium alloy are significantly improved with MgzSi particles. The wear mass losses of AM60 magnesium alloy and MgaSi/AM60 magnesium matrix composites decrease with increase in applied load and sliding rate. The wear feature of the AM60 magnesium alloy is adhesion wear. The wear mechanism of Mg2Si/AM60 magnesium matrix composites transforms from abrasive wear to adhesion wear with the increase of load.
基金financially supported by the National Key Research and Development Program of China(No.2021YFB3701800)Special funding support for the Yuelu Mountain National University Science and Technology City“Ranking the Top of the List”Research Project:(Tunnel Boring Machine High-performance Long-life Cutting Tools)the State Key Laboratory of Powder Metallurgy,Central South University,Changsha,China.
文摘The good combination of mechanical and wear properties for cemented carbides is crucial.In this work,the wear behavior of functionally graded cemented carbide(FGCC)and non-graded cemented carbide(CC),with CoNiFeCr multi-principal-element alloy(MPEA)binder,has been investigated by performing sliding wear tests and composition characterization.The results showed that compared with CC,FGCC had higher hardness,stronger fracture toughness,better wear performance,and similar TRS.FGCCs exhibited lower wear rates(3.44×10^(−7)–6.95×10^(−6)mm^(3)/(N m))and coefficients of friction(COFs)(0.27–0.39)than CCs from RT to 600℃due to mitigation of multiple risks caused by binder removal,fragmentation and pull-out of WC grains,high-temperature oxidation and softening.In the low-temperature wear stage,the MPEA binder underwent dynamic recrystallization(DRX)and twinning deformation before removing from the surface.The binder removal caused dislocation pile-ups and stacking faults(SFs)to form under high stress,resulting in fragmentation and pull-out of WC grains.The low-temperature wear was dominated by abrasive wear and adhesive wear,with a low wear rate and a high and unstable COF.In the high-temperature wear stage,initial pitting oxidation of WC grains generated many subgrain boundaries,reducing heat transfer and exacerbating oxidation,resulting in an oxide layer enriched with WO3,Mx Oy,and MWO4.High-temperature wear was dominated by oxidation wear and high-temperature softening,with a high wear rate and a low and smooth COF.The results from the present study do not only provide theoretical guidance for an understanding of the antiwear mechanism of WC-CoNiFeCr,but also a new approach for the preparation of cemented carbides with high wear resistance.
文摘本文探讨Art to Wear即“可以穿的艺术”,其中大部分作品为服装,少量作品是帽子和首饰。通过分析Art to Wear代表艺术家,解读Art to Wear艺术作品,从而探讨美国20世纪60年代到80年代女性艺术家群体如何以艺术为媒介对自身经历进行叙述性表现。60年代末70年代初处于美国女性主义的第二次浪潮,众多美国名校的年轻白人女大学生,不断为女性的参政、就业、医疗、最低工资等争取更多的权利,而到了80年代遭到美国保守主义的强烈打击,追求自由平等的女性主义运动跌入低谷。第二次女性主义运动的跌宕正是Art to Wear艺术运动的发展时期,艺术学院在读青年女生们发起Art to Wear艺术运动,她们在保守主义与激进主义的影响下寻求精神、生活的平衡,极力反叛女性束身塑形来博得男性视觉愉悦、通过同性的嫉妒来肯定自身价值。她们对家庭、事业、社会地位开始深思,通过作品叙述对社会性别与身份认定的迷茫,表达保守与激进思想的内心纠结。
文摘Large portions of the tunnel boring machine(TBM)construction cost are attributed to disc cutter consumption,and assessing the disc cutter's wear level can help determine the optimal time to replace the disc cutter.Therefore,the need to monitor disc cutter wear in real-time has emerged as a technical challenge for TBMs.In this study,real-time disc cutter wear monitoring is developed based on sound and vibration sensors.For this purpose,the microphone and accelerometer were used to record the sound and vibration signals of cutting three different types of rocks with varying abrasions on a laboratory scale.The relationship between disc cutter wear and the sound and vibration signal was determined by comparing the measurements of disc cutter wear with the signal plots for each sample.The features extracted from the signals showed that the sound and vibration signals are impacted by the progression of disc wear during the rock-cutting process.The signal features obtained from the rock-cutting operation were utilized to verify the machine learning techniques.The results showed that the multilayer perceptron(MLP),random subspace-based decision tree(RS-DT),DT,and random forest(RF)methods could predict the wear level of the disc cutter with an accuracy of 0.89,0.951,0.951,and 0.927,respectively.Based on the accuracy of the models and the confusion matrix,it was found that the RS-DT model has the best estimate for predicting the level of disc wear.This research has developed a method that can potentially determine when to replace a tool and assess disc wear in real-time.
基金Supported by Beijing Municipal Natural Science Foundation of China(Grant No.8252017)National Natural Science Foundation of China(Grant Nos.51608521,52178375)Beijing Urban Construction Group Co.,Ltd.
文摘To elucidate the wear mechanisms of the scraper in shield tunneling through sandy pebble strata,this study aims to achieve high efficiency and low wear during the tunneling process.We evaluate the operational parameters and tool wear characteristics of a 9-m diameter spoke-type shield machine used on the Beijing Daxing Airport Line.The analysis focuses on the wear values of the scrapers and rippers,wear of the scraper in different wear forms,and scraper wear relative to the position of the rippers obtained from the field.The study yielded the following conclusions.The wear values of scrapers on different spokes vary significantly owing to ripper protection.The wear of the scrapers can be categorized into six types:tooth chipping,local damage of teeth,wear of side teeth,wave-type of wear,wear on intermediate teeth,and flat wear,with the majority exhibiting wear on the side and intermediate teeth.The 0°spoke maintained the initial shape of the scrapers,making it more suitable for tunneling in sandy pebble strata.Based on the differences in the relative positions of the ripper and scraper,a model is proposed to determine the ripper plowing influence area.It was found that this area depends on the geological conditions of the soil;thus,the influence angle of ripper plowing in the considered sandy pebble strata is determined to be between 35°and 50°.The results obtained in this study provide a theoretical reference for optimizing scraper layouts in shield construction,even when operating under varying geological conditions.
基金supported by Science and Technology Project of Guangzhou(2023A04J0297)Guangdong Basic and Applied Basic Research Foundation(2024A1515011622)+3 种基金National Natural Science Foundation of China(52301040)GDAS’Project of Science and Technology Development(2023GDASQNRC-0205 and 2022GDASZH-2022010107)Evaluation Project of Guangdong Provincial Key Laboratory(2023B1212060043)Young Elite Scientists Sponsorship Program by CAST(2022QNRC001).
文摘The impact-abrasive wear behavior of high-C martensitic steel was investigated,taking into account varying carbon(C)contents and different tempering temperatures.The evaluation was done through comprehensive microstructural characterization,analysis of worn surface morphology,and measurement of key performance like impact toughness and surface hardening.The findings demonstrate that increasing C content and tempering temperature both has a positive effect on wear resistance,with C content exhibiting a more pronounced influence compared to the tempering temperature.The improved wear resistance of the steel with higher C content and tempering at a higher temperature can be attributed to its enhanced impact toughness.This increase in impact toughness is primarily a result of microstructural refinement and alterations in carbide morphology.Moreover,cyclic impact loading induces surface hardening due to dislocation strengthening within the martensite and the retained austenite,leading to an increase in surface hardness.The combination of surface hardening and excellent impact toughness synergistically contributes to the overall improved wear resistance observed in the experimental steel with higher C content after tempering at a higher temperature.Additionally,the dominant features observed on the worn surface are scratches and substrate delamination,indicative of a wear mechanism of the experimental steels characterized by micro-cutting/ploughing and fatigue wear.
基金supported by the Guangxi Major Science and Technology Project(AB24010120)Young Talent Support Project of Guangzhou Association for Science and Technology(QT-2024-047)+3 种基金Key-Area Research and Development Program of Jiangxi Province(20243BBG71023)GDAS'Project of Science and Technology Development(2023GDASQNRC-0205 and 2024GDASZH-2024010102)Evaluation Project of Guangdong Provincial Key Laboratory(2023B1212060043)Young Elite Scientists Sponsorship Program by CAST(2022QNRC001).
文摘The microstructural evolution,mechanical properties,and wear behavior of medium manganese steels(MMSs)with varying aluminum(Al)contents were investigated.It was observed that the microstructure of MMS transferred from a predominantly martensitic phase(in the Al-free state)to a ferrite/martensite or ferrite/austenite duplex structure with increasing Al content.The hardness of MMS decreased with Al addition,while the impact absorbed energy and yield strength were optimized in 2%Al-containing variant.Frictional wear tests demonstrated that 2 wt.%Al-MMS exhibited superior wear resistance due to the twinning-induced plasticity effect.Conversely,under impact abrasion wear conditions,the Al-free MMS displayed the lowest mass loss,attributing to high surface hardness and remarkable work hardening capacity.These findings indicates that Al content-tailored MMSs can be selectively applied in different wear environments,with 2 wt.%Al-MMS being optimal for static load conditions and the Al-free MMS for dynamic impact abrasion scenarios.
基金Supported by National Key R&D Projects(Grant No.2022YFB3401900)Sichuan Provincial Science and Technology Projects(Grant No.2022JDJQ0019)Fundamental Research Funds for the Central University(Grant No.2682024GF004).
文摘CrN coatings are also employed to protect structural materials in nuclear power plants.It should be noted that the preparation process utilizing physical vapor deposition(PVD)techniques inevitably entails certain defects.Such a phenomenon will affect the protective properties of CrN coatings.In this study,low-energy laser shock peening(LE-LSP)with varying energies was employed for the post-treatment of CrN coatings.The effects of different laser energy LE-LSP treatments on the surface morphology,crystal structure and fretting wear properties of CrN coatings were investigated.The results revealed that the surface of the CrN coatings subjected to LE-LSP underwent significant plastic deformation and displayed a regular texture structure.The surface roughness and Vickers hardness of the CrN coatings exhibit a significant increase.Under a laser energy of 150 mJ,the surface hardness exhibits a maximum increase of 2.35 times.The residual stress of CrN coatings diminishes with the augmentation of laser energy due to the formation of surface cracks.Following LE-LSP treatment,the columnar crystal structure of the CrN coating was disrupted and fragmented into fine grains due to the impact force.As the laser energy augments,the fragmented CrN grains undergo further compaction.During fretting wear,all specimens were in the gross slip regime.The wear mechanism of the CrN coating,120 and 150 mJ specimens are primarily dominated by abrasive wear,and accompanied by oxidative wear.For specimens treated with 30,60 and 90 mJ,the predominant wear mechanisms are mainly peeling and abrasive wear,and accompanied by oxidative wear.Both the wear area and wear volume initially increase and then decrease as the laser energy increases.The 150 mJ specimen exhibited the smallest wear area and wear volume of all tested specimens.The wear volume was reduced by 76.32%when compared to that of the CrN coating.This study complements the existing research on PVD/LSP composite strengthening techniques.Introduces a novel post-treatment methodology for PVD coatings.Provides certain theoretical support for subsequent PVD/LSP composite strengthening.
基金Supported by National Key Research and Development Program of China(Grant No.2018YFA0707300)Hebei Natural Science Foundation(Grant No.E2023203260)+1 种基金Scientific and Technological Research Projects of Hebei Higher Education Institutions(Grant No.CXY2024009)Central Government Guide Local Science and Technology Development Fund Project(Grant No.216Z1602G)。
文摘The wear of work rolls significantly affects the production efficiency and product quality.However,existing methods for wear assessment fail to effectively quantify work roll surface wear conditions,thereby affecting the quality control of steel strips and maintenance strategies for rolls.To accurately assess the wear conditions of hot-rolling work rolls,this study initially established an apparatus for capturing high-precision roll surfaces images.Subsequently,a quantitative assessment of common surface wear morphologies was conducted,and a hot-rolling work roll surface wear dataset was constructed.The MobileNetV2 convolutional neural network(CNN),augmented by transfer learning,was employed to develop a MobileNetV2-wear detection and classification(WDC)surface wear grading model.A comparison with mainstream CNN models revealed that the MobileNetV2-WDC model achieved high-speed(21.92 ms)and accurate(96.86%)grading with minimal model parameters(2.27 M)and size(27 M),meeting the industrial efficiency and practicality requirements.A visual analysis of the model classification errors was conducted,outlining paths for further optimization.This study provides an efficient and accurate solution for detecting and grading surface wear on hot-rolling work rolls,enhancing product quality and extending the lifespan of rolls.
基金Project(2011CB612200)supported by the National Basic Research Program of China
文摘The friction and wear properties of Mg2B2O5 whisker reinforced 6061Al matrix composite fabricated via power ultrasonic-stir casting process were investigated using a ball-on-disk wear-testing machine against a GCr45 steel counterface under dry sliding conditions. The reinforcements include as-received Mg2B2O5 whiskers and Mg2B2O5 whiskers coated with CuO and ZnO. The volume fraction of the composites is 2%. The relationship between the wear rate and the coefficient of friction was discussed. The results indicate that the wear rate of the Mg2B2O5 whiskers coated with ZnO reinforced aluminum matrix composites is the lowest among the materials. As the applied load and sliding speed steadily increase the coefficients of friction and wear rates of the as-received matrix alloy and the fabricated composites decrease. As the applied load and sliding speed increase, the wear mechanisms of the composites shift from a mild to a severe regime.
文摘To develop a wear-resistant steel with excellent mechanical properties and superior wear resistance,low alloy wear-resistant steels with different contents of rare earth were prepared through induction smelting,rolling,quenching,and tempering.The effects of Ce on the inclusion characteristics,mechanical properties,and wear resistance of the test steels were investigated through scanning electron microscopy and energy dispersive X-ray spectroscopy,mechanical property testing,and impact abrasive wear testing.The results indicated that adding Ce to the low alloy wear-resistant steel significantly reduced the number and size of inclusions.When the Ce content reached 0.0037 wt.%,irregular Al_(2)O_(3) and MnS inclusions were significantly reduced and were replaced by nearly spherical Ce_(2)O_(2)S,CeS,and CeP inclusions.The comprehensive mechanical properties including the strength,post-fracture elongation,Brinell hardness,and impact toughness of the test steels were enhanced in various degrees.In particular,the low-temperature impact toughness of the test steels increased from 18 to 39 J as the Ce content rose from 0 to 0.0037 wt.%.The wear mass loss of the test steel gradually decreased with increasing the Ce content,indicating that the addition of Ce significantly enhances the wear resistance of low alloy wear-resistant steel.Under impact loading,a plastic deformation zone called sub-surface layer with a thickness of 10–30μm formed on the worn surface.Work hardening from the plastic deformation strengthened the microhardness of the sub-surface layer,thus improving the wear resistance of the test steel.With increasing the Ce content,the wear resistance of the test steel further improved due to thickening the sub-surface layer.
文摘The wear patterns and wear mechanisms of solid cemented carbide are analyzed in high-speed milling of aluminum alloy. Results show that the dominant wear patterns are coating damage, crater wear, micro-chipping, breakage, and so on. The main wear mechanisms are adhesion, diffusion and fatigue. Compared with conventional speed machining, the effect and impact of thermal-dynamical coupling field play an important role in the cutting tool wear in high-speed milling of aluminum alloy.
基金supported by the Ministry of Education and Science of Ukraine(No.0123U101834)support in the framework of the“EU Next generation EU through the Recovery and Resilience Plan for Slovakia”(Nos.09I03-03-V01-00061 and 09I03-03-V01-00099)。
文摘Wrought and laser powder bed fusion(LPBF)Ti−6Al−4V(Ti-6-4)specimens were comparatively evaluated,with the objective to determine LPBF Ti−6Al−4V’s suitability for biomedical applications.Testing included nanoindentation,cyclic polarization in simulated body fluid(SBF,37°C),and dry and SBF“ball-on-plate”sliding.Wrought Ti-6-4 exhibited a lamellarα+βmicrostructure,whereas LPBF Ti-6-4 displayed a fine-grainedα′-martensite microstructure.LPBF Ti-6-4 demonstrated~3%higher indentation modulus and~32%higher hardness,while wrought Ti-6-4 showed~8%higher plasticity.Both alloys exhibited low corrosion rates(10−5 mA/cm^(2)order)and true passivity(10−4 mA/cm^(2)order).No localized corrosion was observed in either two alloys,except for occasional metastable pitting in the LPBF alloy.However,LPBF Ti-6-4 presented higher corrosion rate and passive current,ascribed to its martensitic structure.During dry sliding,LPBF Ti-6-4 exhibited~14%lower volume loss compared to wrought Ti-6-4.Sliding in SBF increased volume losses for both alloys,with wear resistances nearly equalized,as the advantage of LPBF Ti-6-4 decreased due to more intense wear-accelerated corrosion induced by the stressed martensite.Overall,the results demonstrate the suitability of LPBF Ti-6-4 for biomedical uses.
基金Project(51404082)supported by the National Natural Science Foundation of ChinaProject(E201442)supported by the Natural Science Foundation of Heilongjiang Province,China+2 种基金Project(12531116)supported by the Foundation of Educational Committee of Heilongjiang Province,ChinaProject(2013RFQXJ137)supported by the Harbin Special Funds for Creative Talents in Science and Technology,ChinaProject(201510)supported by Science Funds for the Young Innovative Talents of HUST,China
文摘Dry sliding wear tests were performed on a Mg-10Y-4Gd-1.5Zn-0.4Zr alloy using a Ball-on-Flat type wear apparatus against an AISI 52100 type bearing steel ball counterface. The wear rates were measured within a load range of 3-25 N, a sliding speed range of 0.03-0.3 m/s and a sliding temperature range of 25-200 ℃ at a constant sliding distance of 400 m. The morphologies of the worn surfaces and wear debris were studied by scanning electron microscopy （SEM） and energy dispersive X-ray spectroscopy （EDS）. Comparatively, the wear properties of a hypereutectic Al-Si aluminium alloy under the same condition were measured. The results indicate that the wear rates of Mg-10Y-4Gd-1.5Zn-0.4Zr alloy are lower than that of cast＋T6 AC9B aluminium alloy. The dominant mechanism of cast＋T6 Mg-10Y-4Gd-1.5Zn-0.4Zr alloy is abrasion wear mixed with other wear mechanisms, which tends to be an abrasion and plastic deformation wear at high normal load such as 10-25 N, abrasion and plastic deformation wears with small participation of delamination and oxidative wears at high sliding speed such as 0.12-0.3 m/s, and an oxidative and abrasion wear at high test temperature such as 100-200 ℃. The Mg12Y1Zn1 phase in Mg-10Y-4Gd-1.5Zn-0.4Zr alloy plays an important role in the wear rate.
文摘In-situ formed high Mn steel coating reinforced by carbides was formed by laser surface alloying(LSA).Laser alloyed layers on 1Cr18Ni9Ti steel with Mn+W_(2)C(specimen A),Mn+NiWC(specimen B)and Mn+SiC(specimen C)powders were fabricated to improve the wear and corrosion behavior of 1Cr18Ni9Ti steel blades in high speed mixers.Microstructure evolution,phases,element distribution,microhardness,wear and corrosion behavior of the laser alloyed layers were investigated.Results indicated that high Mn steel matrix composites with undissolved W_(2)C,WC and other in-situ formed carbides were formed by LSA with Mn+W_(2)C and Mn+NiWC while SiC totally dissolved into the high Mn matrix when adding Mn+SiC.Ni as the binding phase in Ni-WC powder decreased the crack sensitivity of the alloyed layer as compared with the addition of W_(2)C powder.An improvement in average microhardness was achieved in the matrix in specimen A,B and C,with the value of 615,602 and 277 HV_(0.5),while that of the substrate was 212 HV_(0.5).The increase of microhardness,wear and corrosion resistance is highly corelated to microstructure,formed phases,type and content of carbides,micro-hardness and toughness of the alloyed layers.
基金National Natural Science Foundation of China(52071126)Natural Science Foundation of Tianjin City,China(22JCQNJC01240)+2 种基金Central Guidance on Local Science and Technology Development Fund of Hebei Province(226Z1009G)Special Funds for Science and Technology Innovation in Hebei(2022X19)Anhui Provincial Natural Science Foundation(2308085ME135)。
文摘Co-based alloy coating was prepared on Zr alloy using laser melting and cladding technique to study the difference in the high-temperature oxidation behavior between pure metal Co coatings and Co-T800 alloy coatings,as well as the wear resistance of the coatings.Besides,the effect of changing the laser melting process on the coatings was also investigated.The oxidation mass gain at 800–1200℃and the high-temperature oxidation behavior during high-temperature treatment for 1 h of two coated Zr alloy samples were studied.Results show that the Co coating and the Co-T800 coating have better resistance against high-temperature oxidation.After oxidizing at 1000℃for 1 h,the thickness of the oxide layer of the uncoated sample was 241.0μm,whereas that of the sample with Co-based coating is only 11.8–35.5μm.The friction wear test shows that the depth of the abrasion mark of the coated sample is only 1/2 of that of the substrate,indicating that the hardness and wear resistance of the Zr substrate are greatly improved.The disadvantage of Co-based coatings is the inferior corrosion resistance in 3.5wt%NaCl solution.
基金Project(2021YFC2801904)supported by the National Key R&D Program of ChinaProject(KY10100230067)supported by the Basic Product Innovation Research Project,China+3 种基金Projects(52271130,52305344)supported by the National Natural Science Foundation of ChinaProjects(ZR2020ME017,ZR2020QE186)supported by the Natural Science Foundation of Shandong Province,ChinaProjects(AMGM2024F11,AMGM2021F10,AMGM2023F06)supported by the Science Fund of Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai,ChinaProject(KY90200210015)supported by Leading Scientific Research Project of China National Nuclear Corporation(CNNC),China。
文摘WC particles reinforced CoCrFeNiMo high-entropy alloy(HEA)composite coatings were prepared on Cr12MoV steel successfully by laser cladding technology to improve the wear resistance of substrates.Effect of WC content on microstructure and wear property of the composite coatings was studied in detail.Large numbers of carbides with four main types:primary carbide crystals,eutectic structures,massive crystals growing along the periphery of the remaining WC particles and incompletely fused WC particles,were found to exist in the WC/CoCrFeNiMo composite coatings.With increasing WC content,the microhardness of coatings is gradually improved while the average friction coefficients follow the opposite trend due to solid solution strengthening and second phase strengthening effect.The maximum microhardness and minimum friction coefficient are HV_(0.2)689.7 and 0.72,respectively,for the composite coating with 30 wt.%WC,the wear resistance of the substrate is improved significantly,the wear mechanisms are spalling wear and abrasive wear due to their high microhardness.
基金supports from the National Natural Science Foundation of China(No.52305440)the Natural Science Foundation of Changsha City(Nos.kq2208272,kq2208274)+1 种基金the Tribology Science Fund of the State Key Laboratory of Tribology in Advanced Equipment(No.SKLTKF22B09)the National Key Research and Development Program of China(No.2022YFB3706902)were acknowledged.
文摘Stainless steel parts with complex shape can be fabricated using additive manufacturing,which do not rely on molds and dies.However,coarse dendrites induced by repeated heating of additive manufacturing result in weak properties,which limits its application.In this study,an in-situ ultrasonic rolling(UR)device was developed to assist the laser directed energy deposition(LDED)process.The microstructural characteristics,as well as the microhardness and wear behavior,were studied for the 316L stainless steel manufactured by in-situ ultrasonic rolling assisted LDED.It is found that austenite,ferrite,and small Si oxides are the main constituents of both the LDED and LDED-UR alloy samples.Under the severe plastic deformation of ultrasonic rolling,the long-branched ferrites by LDED are transformed into the rod-like phases by LDED-UR.Meanwhile,the ferrite is more uniformly distributed in the LDED-UR alloy sample compared with that in LDED alloy sample.Columnar grains with the size of 97.85μm appear in the LDED alloy sample,which is larger than the fully equiaxed grains(22.35μm)of the LDED-UR alloy.The hardness of the LDED-UR alloy sample is about 266.13±13.62 HV_(0.2),which is larger than that of the LDED alloy sample(212.93±12.85 HV_(0.2)).Meanwhile,the wear resistance is also greatly enhanced by applying the assisted in-situ ultrasonic rolling.The achieved high wear resistance can be ascribed to the uniformly distributed hard matter(ferrites)and the impedance of dislocations by high fraction of grain boundaries.Abrasive wear and adhesive wear are identified as the primary wear mechanisms of the studied alloy.Gaining an in-depth understanding of the relationship between wear mechanisms and microstructures offers an effective approach in manufacturing high wear resistant alloys suitable for use in harsh working environments.
