Photoreforming is an emerging photocatalytic process that converts organic waste into hydrogen H2 using solar energy,offering a dual solution for waste valorization and sustainable fuel production.This review comprehe...Photoreforming is an emerging photocatalytic process that converts organic waste into hydrogen H2 using solar energy,offering a dual solution for waste valorization and sustainable fuel production.This review comprehensively examines the fundamental mechanisms of photoreforming,emphasizing the critical role of photocatalyst design in optimizing hydrogen evolution.Key criteria for effective photocatalysts including suitable band edge positions,broad spectrum solar absorption,and photostability are systematically analyzed alongside advances in heterojunction engineering and defect modulation.The review further explores diverse waste-derived feedstocks,such as biomass:alcohols,saccharides,lignin and plastics:PET,PLA,polyolefins,highlighting substrate,specific challenges and pretreatment strategies.Despite progress,challenges like catalyst deactivation,limited visible-light utilization,and scalability persist.Future directions advocate for robust photocatalyst engineering,mechanistic insights into charge dynamics,and scalable reactor designs to realize photoreforming’s potential as a sustainable hydrogen production technology.展开更多
Waste graphitization cathode carbon blocks are a type of hazardous solid waste generated during the aluminum electrolysis process,and their proper disposal is a key step in the resource utilization of discarded graphi...Waste graphitization cathode carbon blocks are a type of hazardous solid waste generated during the aluminum electrolysis process,and their proper disposal is a key step in the resource utilization of discarded graphite.This study utilizes the porous“defect advantage”of a cathode carbon block matrix to prepare silicon-doped and asphalt-coated detoxified and purified waste graphitization cathode carbon blocks for use as high-performance silicon/carbon composite anode materials.The results show that the uniformly silicondoped silicon/carbon composite material features a unique amorphous carbon-encapsulated“locked silicon”structure,which effectively addresses issues such as cathode volume expansion,excessive growth of the solid electrolyte interphase(SEI)film,and poor electrical contact between active materials.Consequently,electrochemical performance is enhanced.After assembly in a half-cell,the PSCC/10%Si@C(purified waste graphitization cathode carbon/10%Si@C)material exhibits optimal electrochemical stability,with an initial charging specific capacity of 514.5 mAh/g at 0.1 C(1 C=170 mA/g)and a capacity retention rate of 95.1%after 100 cycles.At a charge rate of 2.0 C,a specific capacity of 216.9 mAh/g is achieved.This technology provides a new pathway for the economical and high-value utilization of waste cathode carbon blocks and the development of low-cost,high-performance anode materials.展开更多
The global energy landscape is undergoing a profound transformation,with wind energy,especially wind power,gaining increasing prominence due to its clean,renewable nature.However,as the installed capacity of wind powe...The global energy landscape is undergoing a profound transformation,with wind energy,especially wind power,gaining increasing prominence due to its clean,renewable nature.However,as the installed capacity of wind power continues to expand,the disposal of waste wind turbine blades(WWTB)has emerged as a significant challenge.These blades are predominantly composed of epoxy resin(EP)polymers,carbon fibers(CFs),and glass fibers(GFs).Improper disposal not only exacerbates environmental concerns but also leads to the loss of valuable resources,particularly carbon-based materials.Pyrolysis technology,a versatile and environmentally sustainable method for resource recovery,has garnered considerable attention in the context of WWTB disposal.This work presents a comprehensive review of the pyrolytic recycling of WWTB,focusing on the principles and classifications of pyrolysis technology,key factors influencing the pyrolysis process,as well as the pyrolysis methods,equipment,products,and their applications.Through an in-depth analysis of the current research on the pyrolytic recycling of WWTB,this review identifies critical unresolved issues in the field and provides a forward-looking perspective on emerging research trends.展开更多
This study investigates the performance enhancement of super-sulfated cement(SSC)derived from arsenic-containing bio-oxidation waste(BW)through the incorporation of carbonated recycled concrete fines(CRCF).The finding...This study investigates the performance enhancement of super-sulfated cement(SSC)derived from arsenic-containing bio-oxidation waste(BW)through the incorporation of carbonated recycled concrete fines(CRCF).The findings revealed that the addition of 5wt%CRCF yields optimal performance,with compressive strengths reaching approximately 1.83,12.59,and 42.81 MPa at 1,3,and 28 d,respectively.These values represented significant increases of 408.3%,10.0%,and 14.3%compared to the reference sample.The improvement was attributed to the synergistic effects of ultrafine CRCF particles acting as fillers and nucleation sites,as well as the high reactivity of silica gels,which promoted the formation of additional hydration gels.Microstructural analysis confirmed that CRCF addition refined pore structure,and enhanced the stiffness of C-S-H gels.Furthermore,CRCF served as a net CO_(2) sink,sequestering 0.268 kg CO_(2) per kilogram of CRCF and thereby reducing the carbon footprint of SSC.In addition,the feasibility of applying CRCF-modified SSC in cemented paste backfill(CPB)is highlighted,given the high cement-related carbon footprint of conventional CPB.When 5wt%CRCFmodified SSC was employed in CPB,its 3-d compressive strength attained over 70%of that of ordinary Portland cement(OPC),while the 28-d strength was comparable to that of OPC.The proposed binder thus provides a sustainable pathway for BW valorization,combining waste utilization,carbon sequestration,and improved engineering performance.展开更多
Europe is grappling with a colossal textile waste problem.Over 125 million tonnes of raw materials are devoured by the global industry each year,yet a mere fraction-less than 1%-of these fibres originate from recycled...Europe is grappling with a colossal textile waste problem.Over 125 million tonnes of raw materials are devoured by the global industry each year,yet a mere fraction-less than 1%-of these fibres originate from recycled textiles.The majority faces an unsustainable fate in landfills,incinerators,or is exported.A pivotal new report by Systemiq,"The Textile Recycling Breakthrough,"offers both a stark assessment and a strategic roadmap:Europe has the potential to amplify polyester textile recycling nearly tenfold by 2035,but this hinges on immediate,decisive action from policymakers and the industry.展开更多
Recycling of waste rubber(WR)is crucial for the sustainable development of the rubber industry.The enhancement of interfacial interactions is the main strategy for waste polymer recycling.However,there is a lack of me...Recycling of waste rubber(WR)is crucial for the sustainable development of the rubber industry.The enhancement of interfacial interactions is the main strategy for waste polymer recycling.However,there is a lack of methods for enhancing the interfacial interactions for WR recycling because WR contains abundant inert C―H bonds.Herein,we designed thioctic acid inverse vulcanization copolymers to endow recycled WR with dynamic disulfide interfacial interactions,significantly improving the mechanical properties of recycled WR.These disulfide interfacial interactions among the recycled WR tend to exchange,which dramatically increases the fractocohesive length and prevents stress concentration near the crack tips.When recycled WR is subjected to external stress,the loads are redistributed across a broad region of adjacent regions instead of being concentrated on a limited length scale,which resists crack propagation.This work effectively recycled WR,providing a strategy for solvent-free reaction-derived inverse vulcanization copolymers to improve the toughness of WR recycling.展开更多
Mass wasting is globally recognized as a key geomorphic agent in permanent gully expansion and greatly contributes to watershed sediment losses.Though its formation process has been assessed by some physical models,th...Mass wasting is globally recognized as a key geomorphic agent in permanent gully expansion and greatly contributes to watershed sediment losses.Though its formation process has been assessed by some physical models,the occurrence and rainfall threshold have been rarely documented.In this study,rainfall-induced mass wasting events in two permanent gullies located in the Mollisols region of Northeast China,with Mollisols(gully 1)and sandy soil(gully 2)underneath were observed,and their differences were explored based on their soil strengths,hydraulic properties,excess topographies,and theoretical rainfall amounts.The sandy soil had a higher strength,faster pore water pressure dissipation rate,and lower suction stress at a specific soil moisture content compared to the black soil.The erosion thickness of the gully bed and sidewalls in gully 1 was shallower compared to gully 2.This was confirmed by the relationship between the erosion thickness and excess topography.The differences in the mass wasting erosion of the gully bed and sidewalls were due to the higher shear strength and well-drained hydraulic properties of the sandy soil compared to the black-soil.An infinite model was chosen to examine the temporal order of the mass wasting in the two gullies.It was found that the mass wasting in gully 2 occurred earlier than that in gully 1.This was likely due to the occurrence of an intense storm with less rainfall at the location of gully 2,while a light storm with heavier rainfall occurred in the location of gully 1.As Mollisols and sandy soil are the typical soil horizons in the Mollisols region worldwide,the results of this work could provide insightful knowledge for understanding the physical process of permanent gully expansion,which may be helpful for developing prediction models for sediment losses in some watersheds with vast Mollisols and highly developed gully system.展开更多
To deal with a polluted by-product of coal production,central China’s Shanxi Province has explored a governance path that addresses both the symptoms and root causes.
This study explores the use of black soldier fly larvae protein as a bio-based adhesive to produce particleboards from sugarcane bagasse.A comprehensive evaluation was conducted,including rheological characterization ...This study explores the use of black soldier fly larvae protein as a bio-based adhesive to produce particleboards from sugarcane bagasse.A comprehensive evaluation was conducted,including rheological characterization of the adhesive and physical–mechanical testing of the panels according to European standards.The black soldier fly larvae-based adhesive exhibited gel-like viscoelastic behavior,rapid partial structural recovery after shear,and favorable application properties.Particleboards manufactured with this adhesive and sugarcane bagasse achieved promising mechanical performance,with modulus of rupture and modulus of elasticity values of 30.2 and 3500 MPa,respectively.Internal bond strength exceeded 0.4 MPa,complying with European standard 312-3 specifications.For comparative purposes,a panel made with Eucalyptus grandis particles was also produced under the same conditions to demonstrate the versatility of the adhesive system.Compared to other bio-based and synthetic adhesives,this bio-based system showed competitive performance and derives from the bioconversion of organic residues.Protein adhesives were synthesized fromHermetia illucens larvae grown commercially on agriculturalwaste frompotato chip production,emphasizing the renewable origin of both the biomass and the final adhesive.These results highlight the potential of insect proteins as sustainable and circular alternatives for the wood panel industry.展开更多
The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbi...The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbide nanowires using lignite and waste silicon powder as raw materials through carbothermal reduction.The staggered structure of nanowires promotes the creation of interfacial polarization,impedance matching,and multiple loss mechanisms,leading to enhanced electromagnetic absorption performance.The silicon carbide nanowires demonstrate outstanding electromagnetic absorption capabilities with the minimum reflection loss of-48.09 d B at10.08 GHz and an effective absorption bandwidth(the reflection loss less than-10 d B)ranging from 8.54 to 16.68 GHz with a thickness of 2.17 mm.This research presents an innovative approach for utilizing solid waste in an environmentally friendly manner to produce broadband silicon carbide composite absorbers.展开更多
Improving energy efficiency and lowering negative environmental impact through waste heat recovery(WHR)is a critical step toward sustainable cement manufacturing.This study analyzes advanced cogeneration systems for r...Improving energy efficiency and lowering negative environmental impact through waste heat recovery(WHR)is a critical step toward sustainable cement manufacturing.This study analyzes advanced cogeneration systems for recovering waste heat from the Fallujah White Cement Plant in Iraq.The novelty of this work lies in its direct application and comparative thermodynamic analysis of three distinct cogeneration cycles—the Organic Rankine Cycle,the Single-Flash Steam Cycle,and the Dual-Pressure Steam Cycle—within the Iraqi cement industry,a context that has not been widely studied.The main objective is to evaluate and compare these models to determine the most effective approach for enhancing energy and exergy efficiencies.Themethodology involved detailed thermodynamic and exergy analyses of each system,supported by mathematical modelling and simulation using data from plant operations.The results reveal that the Dual-Pressure Steam Cycle emerged as the most effective system,delivering 13.76 MW of net power with a thermal efficiency of 32.8%and an exergy efficiency of 51%.This significantly outperformed the baseline Organic Rankine Cycle(8.18MW,18.8%thermal efficiency,30.7%exergy efficiency).These findings confirm that multipressure steam cycles offer a robust and practical solution for the Fallujah plant.This application provides a clear,high-impact pathway to enhance national industrial energy efficiency,significantly reduce CO_(2) emissions,and promote clean energy sustainability in Iraq.Future work should consider economic feasibility and potential integration with renewable energy sources to further enhance sustainability.展开更多
Utilization of ceramic wastes to fabricate concrete can not only effectively dispose the wastes,but also reduce the energy and source consumptions.Therefore,we fabricated a green ultra high performance concrete using ...Utilization of ceramic wastes to fabricate concrete can not only effectively dispose the wastes,but also reduce the energy and source consumptions.Therefore,we fabricated a green ultra high performance concrete using ceramic waste powder(CWP)to replace 55%of cement,and ceramic waste aggregate(CWA)to replace 100%natural quartz sand.However,high content of ceramic wastes will harm the concrete performance including workability and mechanical properties.Therefore,a low-cost and low carbon nano-calcium carbonate(NC)was introduced to compensate for the defects caused by large amounts of CWP and CWA to workability and mechanical behavior.The experimental results show that the workability of ultra high performance concrete with large amounts of CWP and CWA(UHPCLCC)increases by 28.57%with NC content of 5%.Moreover,the flexural strengths,fracture energy,compressive strengths,and compressive toughness of UHPCLCC increase up to 29.6%,56.5%,20.4%,and 37.6%,respectively,which is caused by the nano-core effect of NC.展开更多
Pyrolysis technology has emerged as a promising method for converting waste polyurethane(WPU)from waste refrigerators into high-value chemicals.In this study,the copper(Cu)-assisted pyrolysis strategy was employed to ...Pyrolysis technology has emerged as a promising method for converting waste polyurethane(WPU)from waste refrigerators into high-value chemicals.In this study,the copper(Cu)-assisted pyrolysis strategy was employed to enhance the thermal degradation efficiency and product quality of WPU.Kinetic analysis revealed that the activation energy(E_(a)) of the Cu-assisted pyrolysis was 136.64 kJ·mol^(−1) and Cu-assisted pyrolysis was controlled by the combined processes of diffusion,nucleation and phase boundary reactions.Comprehensive product analysis,including gas chromatography–mass spectrometry and thermogravimetric Fourier transform infrared spectroscopy–mass spectrometry suggested that Cu promoted the cleavage of urethane bonds and accelerated the decarboxylation of isocyanates,increasing the yields of aniline and ethanol at lower temperatures.Meanwhile,Cu effectively suppressed the formation of halogenated and heterocyclic compounds by promoting the cleavage of C–X(X=Cl,F)bonds through electron transfer interactions.Thus,the E_(a) is decreased and the halogenated compounds is reduced.This work provides the theoretical basis for converting waste to high-valued products through co-pyrolysis techniques.展开更多
The development of metallic mineral resources generates a significant amount of solid waste,such as tailings and waste rock.Cemented tailings and waste-rock backfill(CTWB)is an effective method for managing and dispos...The development of metallic mineral resources generates a significant amount of solid waste,such as tailings and waste rock.Cemented tailings and waste-rock backfill(CTWB)is an effective method for managing and disposing of this mining waste.This study employs a macro-meso-micro testing method to investigate the effects of the waste rock grading index(WGI)and loading rate(LR)on the uniaxial compressive strength(UCS),pore structure,and micromorphology of CTWB materials.Pore structures were analyzed using scanning electron microscopy(SEM)and mercury intrusion porosimetry(MIP).The particles(pores)and cracks analysis system(PCAS)software was used to quantitatively characterize the multi-scale micropores in the SEM images.The key findings indicate that the macroscopic results(UCS)of CTWB materials correspond to the microscopic results(pore structure and micromorphology).Changes in porosity largely depend on the conditions of waste rock grading index and loading rate.The inclusion of waste rock initially increases and then decreases the UCS,while porosity first decreases and then increases,with a critical waste rock grading index of 0.6.As the loading rate increases,UCS initially rises and then falls,while porosity gradually increases.Based on MIP and SEM results,at waste rock grading index 0.6,the most probable pore diameters,total pore area(TPA),pore number(PN),maximum pore area(MPA),and area probability distribution index(APDI)are minimized,while average pore form factor(APF)and fractal dimension of pore porosity distribution(FDPD)are maximized,indicating the most compact pore structure.At a loading rate of 12.0 mm/min,the most probable pore diameters,TPA,PN,MPA,APF,and APDI reach their maximum values,while FDPD reaches its minimum value.Finally,the mechanism of CTWB materials during compression is analyzed,based on the quantitative results of UCS and porosity.The research findings play a crucial role in ensuring the successful application of CTWB materials in deep metal mines.展开更多
Industrial waste salts are commonly used to make value-added snow-melting agents to ensure traffic safety in northern China during winter and spring after snowfall.However,heavy metals in industrial waste salts may po...Industrial waste salts are commonly used to make value-added snow-melting agents to ensure traffic safety in northern China during winter and spring after snowfall.However,heavy metals in industrial waste salts may pose certain environmental risks.Snow-melting agents and snow samples were collected and analyzed from highways,arterial roads,footbridges,and other locations in Beijing after the snowstorm in December 2023.It was found that the main component of snow-melting agents was sodium chloride with high concentrations of Cu,Mn,and Zn,which are not regulated in the current policies,despite the recent promotion of environmentally friendly snow-melting agents.The Pb,Zn and Cr contents of some snow samples exceeded the limitation value of surface water quality standards,potentially affecting the soil and water environment near roadsides,although the snow-melting agents comply with relevant standards,which indicates the policy gap in the management of recycled industrial salts.We reviewed and analyzed the relevant standards for snow-melting agents and industrial waste salts proposed nationally and internationally over the past 30 years.Through comparative analysis,we proposed relevant policy recommendations to the existing quality standards of snow-melting agents and the management regulations of industrial waste salts,and the formulation of corresponding usage strategies,aimed at reducing the potential environmental release of heavy metals from the use of snow-melting agents,thereby promoting more sustainable green urban development and environmentally sound waste management.展开更多
To ease the scarcity of lithium(Li)resource and cut down on environmental pollution,an efficient,selective,inexpensive and sustainable Li recycling process from waste batteries is needed,which is yet to be achieved.He...To ease the scarcity of lithium(Li)resource and cut down on environmental pollution,an efficient,selective,inexpensive and sustainable Li recycling process from waste batteries is needed,which is yet to be achieved.Here,we report a low-potential photoelectrochemical(PEC)system that selectively and efficiently extracts Li metals from multi-cation electrolytes under 1 sun illumination.Based on the difference of redox potential,we can get rid of the disturbance of other cations(i.e.,Fe,Co and Ni ions)by a bias-free PEC device to realize the extraction of high-purity Li metals on a coplanar Si-based photocathode-TiO_(2) photoanode tandem device at 2 V of applied bias(far less than the redox potentials of Li^(+)/Li).In such system,the extraction rate of Li metals(purity>99.5%)exceeds 1.35 g h^(-1)m^(-2)with 90%of Faradaic efficiency.Long-term experiments,different electrode/electrolyte tests,and various price assessments further demonstrate the stability,compatibility and economy of PEC extraction system,enabling a solar-driven pathway for the recycling of critical metal resources.展开更多
The utilisation of waste in green sustainable technology can provide a clean environment and support energy demand.This work aims to design and analyse the performance of a developed indirect flat-plate Solar Air Heat...The utilisation of waste in green sustainable technology can provide a clean environment and support energy demand.This work aims to design and analyse the performance of a developed indirect flat-plate Solar Air Heater(SAH)integrated with an internal thermal storage unit using Waste Automotive Oil(WAO).The SAH was designed based on the circulation of confined air around the internal thermal storage unit due to the updraft effects of hot air.Two SAHs were tested to compare the performance of WAO and water,with the results being compared to previous work that utilised phase change material.Results showed that WAO responds faster in the early stage,while water has slightly higher daytime efficiency,with a maximum temperature of 60℃,while WAO reached a maximum temperature of 76℃.During the discharge cycle,WAO achieved an efficiency of 65.7%,while the water’s efficiency 73.2% within the same period.The highest outlet air temperatures recorded were 43℃ for WAO and 33.8℃ for water.These findings support that water is suitable for applications requiring rapid thermal charging,while WAO offers extended thermal stability.The study highlights the feasibility of using low-cost materials,such as WAO and water,to enhance the performance of solar energy systems,thereby making them more viable for industrial applications like drying and heating.展开更多
The growing demand for renewable energy has increased the use of wood pellets as a clean and efficient biomass fuel.This study aims to evaluate the physical properties of wood pellets produced from Acacia hybrid(AC)ve...The growing demand for renewable energy has increased the use of wood pellets as a clean and efficient biomass fuel.This study aims to evaluate the physical properties of wood pellets produced from Acacia hybrid(AC)veneer waste and Pine wood(PW)waste mixed with varying ratios.The objectives are to investigate the effect of different blend ratios ofAcacia hybrid veneer waste and pine wood waste on the physical properties,specificallymoisture content,density,and pellet durability index(PDI)of wood pellets,and to identify the optimal ratio that yields the most desirable pellet quality.The wood pellets were produced by blending Acacia hybrid veneer waste and Pine wood waste(AC:PW)in weight ratios of 100:0,75:25,50:50,25:75,and 0:100.The materials were dried to 10%–12%moisture before pelletizing using a pellet mill under consistent pressure and temperature.Moisture content(MC),density(ρ)and pellet durability index(PDI)were measured following the International Organization for Standardization(ISO).The study found that blending Acacia hybrid veneer waste with Pine wood waste significantly improved pellet density and durability compared to the control.The moisture was lowest in pellets with 50:50 and 25:75 blends,indicating better drying and stability.The blend 50:50 achieves the highest density,and for pellet durability index,the best blend is 25:75,suggesting improved resistance to breakage.Overall,the 50:50 and 25:75 ratios produced pellet with the most desirable combination of low moisture,high density,high durability and the blend meets key ISO 17225 and ENplus quality standards for industrial wood pellet.展开更多
Thermomagnetic generation(TMG),a heat-to-electricity conversion technology based on the thermomagnetic effect,offers high reliability and broad adaptability to diverse heat sources.By exploiting the temperature-depend...Thermomagnetic generation(TMG),a heat-to-electricity conversion technology based on the thermomagnetic effect,offers high reliability and broad adaptability to diverse heat sources.By exploiting the temperature-dependent magnetization of thermomagnetic materials,TMG converts thermal energy into electrical energy through cyclic changes in magnetic flux based on Faraday's law.The performance of TMG systems is largely governed by the intrinsic properties of the working materials and the design of device architecture.Ideal TMG materials exhibit sharp and reversible magnetization transitions near the operating temperature,low thermal hysteresis,and high thermal conductivity.Device configurations can be broadly categorized into active and passive systems:active TMG devices rely on controlled thermal cycling and optimized magnetic circuits for enhanced output,whereas passive devices utilize self-actuated mechanical motion to generate electricity.In this topical review,we provide a comprehensive overview of recent advances in TMG materials and device configurations.Furthermore,we discuss future development trends and offer perspectives on experimental strategies to advance this field.展开更多
基金supported by Universiti Teknologi PETRONAS and the Institute of Technology PETRONAS Sdn.Bhd.(ITPSB)through the Graduate Assistantship Scheme。
文摘Photoreforming is an emerging photocatalytic process that converts organic waste into hydrogen H2 using solar energy,offering a dual solution for waste valorization and sustainable fuel production.This review comprehensively examines the fundamental mechanisms of photoreforming,emphasizing the critical role of photocatalyst design in optimizing hydrogen evolution.Key criteria for effective photocatalysts including suitable band edge positions,broad spectrum solar absorption,and photostability are systematically analyzed alongside advances in heterojunction engineering and defect modulation.The review further explores diverse waste-derived feedstocks,such as biomass:alcohols,saccharides,lignin and plastics:PET,PLA,polyolefins,highlighting substrate,specific challenges and pretreatment strategies.Despite progress,challenges like catalyst deactivation,limited visible-light utilization,and scalability persist.Future directions advocate for robust photocatalyst engineering,mechanistic insights into charge dynamics,and scalable reactor designs to realize photoreforming’s potential as a sustainable hydrogen production technology.
基金supported by the National Natural Science Foundation of China(No.52274346).
文摘Waste graphitization cathode carbon blocks are a type of hazardous solid waste generated during the aluminum electrolysis process,and their proper disposal is a key step in the resource utilization of discarded graphite.This study utilizes the porous“defect advantage”of a cathode carbon block matrix to prepare silicon-doped and asphalt-coated detoxified and purified waste graphitization cathode carbon blocks for use as high-performance silicon/carbon composite anode materials.The results show that the uniformly silicondoped silicon/carbon composite material features a unique amorphous carbon-encapsulated“locked silicon”structure,which effectively addresses issues such as cathode volume expansion,excessive growth of the solid electrolyte interphase(SEI)film,and poor electrical contact between active materials.Consequently,electrochemical performance is enhanced.After assembly in a half-cell,the PSCC/10%Si@C(purified waste graphitization cathode carbon/10%Si@C)material exhibits optimal electrochemical stability,with an initial charging specific capacity of 514.5 mAh/g at 0.1 C(1 C=170 mA/g)and a capacity retention rate of 95.1%after 100 cycles.At a charge rate of 2.0 C,a specific capacity of 216.9 mAh/g is achieved.This technology provides a new pathway for the economical and high-value utilization of waste cathode carbon blocks and the development of low-cost,high-performance anode materials.
基金Supported by the National Natural Science Foundation of China(22468035,22468036,22368038,22308048)the Natural Science Foundation of Inner Mongolia(2024QN02018,2025MS02030)+2 种基金First-class Discipline Research Special Project of Inner Mongolia(YLXKZX-NGD-045)Inner Mongolia Autonomous Region Postgraduate Research Innovation Project(KC2024047B)Research Foundation for Introducing High-level Talents in Inner Mongolia Autonomous Region。
文摘The global energy landscape is undergoing a profound transformation,with wind energy,especially wind power,gaining increasing prominence due to its clean,renewable nature.However,as the installed capacity of wind power continues to expand,the disposal of waste wind turbine blades(WWTB)has emerged as a significant challenge.These blades are predominantly composed of epoxy resin(EP)polymers,carbon fibers(CFs),and glass fibers(GFs).Improper disposal not only exacerbates environmental concerns but also leads to the loss of valuable resources,particularly carbon-based materials.Pyrolysis technology,a versatile and environmentally sustainable method for resource recovery,has garnered considerable attention in the context of WWTB disposal.This work presents a comprehensive review of the pyrolytic recycling of WWTB,focusing on the principles and classifications of pyrolysis technology,key factors influencing the pyrolysis process,as well as the pyrolysis methods,equipment,products,and their applications.Through an in-depth analysis of the current research on the pyrolytic recycling of WWTB,this review identifies critical unresolved issues in the field and provides a forward-looking perspective on emerging research trends.
基金supports from the National Natural Science Foundation of China(No.52304148)the Youth Project of Shanxi Basic Research Program(No.202203021212262).
文摘This study investigates the performance enhancement of super-sulfated cement(SSC)derived from arsenic-containing bio-oxidation waste(BW)through the incorporation of carbonated recycled concrete fines(CRCF).The findings revealed that the addition of 5wt%CRCF yields optimal performance,with compressive strengths reaching approximately 1.83,12.59,and 42.81 MPa at 1,3,and 28 d,respectively.These values represented significant increases of 408.3%,10.0%,and 14.3%compared to the reference sample.The improvement was attributed to the synergistic effects of ultrafine CRCF particles acting as fillers and nucleation sites,as well as the high reactivity of silica gels,which promoted the formation of additional hydration gels.Microstructural analysis confirmed that CRCF addition refined pore structure,and enhanced the stiffness of C-S-H gels.Furthermore,CRCF served as a net CO_(2) sink,sequestering 0.268 kg CO_(2) per kilogram of CRCF and thereby reducing the carbon footprint of SSC.In addition,the feasibility of applying CRCF-modified SSC in cemented paste backfill(CPB)is highlighted,given the high cement-related carbon footprint of conventional CPB.When 5wt%CRCFmodified SSC was employed in CPB,its 3-d compressive strength attained over 70%of that of ordinary Portland cement(OPC),while the 28-d strength was comparable to that of OPC.The proposed binder thus provides a sustainable pathway for BW valorization,combining waste utilization,carbon sequestration,and improved engineering performance.
文摘Europe is grappling with a colossal textile waste problem.Over 125 million tonnes of raw materials are devoured by the global industry each year,yet a mere fraction-less than 1%-of these fibres originate from recycled textiles.The majority faces an unsustainable fate in landfills,incinerators,or is exported.A pivotal new report by Systemiq,"The Textile Recycling Breakthrough,"offers both a stark assessment and a strategic roadmap:Europe has the potential to amplify polyester textile recycling nearly tenfold by 2035,but this hinges on immediate,decisive action from policymakers and the industry.
基金financially supported by the National Natural Science Foundation of China(No.52363007)。
文摘Recycling of waste rubber(WR)is crucial for the sustainable development of the rubber industry.The enhancement of interfacial interactions is the main strategy for waste polymer recycling.However,there is a lack of methods for enhancing the interfacial interactions for WR recycling because WR contains abundant inert C―H bonds.Herein,we designed thioctic acid inverse vulcanization copolymers to endow recycled WR with dynamic disulfide interfacial interactions,significantly improving the mechanical properties of recycled WR.These disulfide interfacial interactions among the recycled WR tend to exchange,which dramatically increases the fractocohesive length and prevents stress concentration near the crack tips.When recycled WR is subjected to external stress,the loads are redistributed across a broad region of adjacent regions instead of being concentrated on a limited length scale,which resists crack propagation.This work effectively recycled WR,providing a strategy for solvent-free reaction-derived inverse vulcanization copolymers to improve the toughness of WR recycling.
基金primarily supported by the National Key Research and Development Program of China(Grant No.2024YFD1501201-3)partially supported by the National Key Research and Development Program of China(Grant No.2021YFD1500700)。
文摘Mass wasting is globally recognized as a key geomorphic agent in permanent gully expansion and greatly contributes to watershed sediment losses.Though its formation process has been assessed by some physical models,the occurrence and rainfall threshold have been rarely documented.In this study,rainfall-induced mass wasting events in two permanent gullies located in the Mollisols region of Northeast China,with Mollisols(gully 1)and sandy soil(gully 2)underneath were observed,and their differences were explored based on their soil strengths,hydraulic properties,excess topographies,and theoretical rainfall amounts.The sandy soil had a higher strength,faster pore water pressure dissipation rate,and lower suction stress at a specific soil moisture content compared to the black soil.The erosion thickness of the gully bed and sidewalls in gully 1 was shallower compared to gully 2.This was confirmed by the relationship between the erosion thickness and excess topography.The differences in the mass wasting erosion of the gully bed and sidewalls were due to the higher shear strength and well-drained hydraulic properties of the sandy soil compared to the black-soil.An infinite model was chosen to examine the temporal order of the mass wasting in the two gullies.It was found that the mass wasting in gully 2 occurred earlier than that in gully 1.This was likely due to the occurrence of an intense storm with less rainfall at the location of gully 2,while a light storm with heavier rainfall occurred in the location of gully 1.As Mollisols and sandy soil are the typical soil horizons in the Mollisols region worldwide,the results of this work could provide insightful knowledge for understanding the physical process of permanent gully expansion,which may be helpful for developing prediction models for sediment losses in some watersheds with vast Mollisols and highly developed gully system.
文摘To deal with a polluted by-product of coal production,central China’s Shanxi Province has explored a governance path that addresses both the symptoms and root causes.
基金supported by the Consejo Nacional de Investigaciones Cientificas y Tecnicas(CONICET)via grant Proyectos de Investigacion Plurianuales(PIP 2021:2894)Agencia I+D+i via grant Proyectos de Investigacion Cientifica y Tecnologica(PICT-2021-I-A-00294).
文摘This study explores the use of black soldier fly larvae protein as a bio-based adhesive to produce particleboards from sugarcane bagasse.A comprehensive evaluation was conducted,including rheological characterization of the adhesive and physical–mechanical testing of the panels according to European standards.The black soldier fly larvae-based adhesive exhibited gel-like viscoelastic behavior,rapid partial structural recovery after shear,and favorable application properties.Particleboards manufactured with this adhesive and sugarcane bagasse achieved promising mechanical performance,with modulus of rupture and modulus of elasticity values of 30.2 and 3500 MPa,respectively.Internal bond strength exceeded 0.4 MPa,complying with European standard 312-3 specifications.For comparative purposes,a panel made with Eucalyptus grandis particles was also produced under the same conditions to demonstrate the versatility of the adhesive system.Compared to other bio-based and synthetic adhesives,this bio-based system showed competitive performance and derives from the bioconversion of organic residues.Protein adhesives were synthesized fromHermetia illucens larvae grown commercially on agriculturalwaste frompotato chip production,emphasizing the renewable origin of both the biomass and the final adhesive.These results highlight the potential of insect proteins as sustainable and circular alternatives for the wood panel industry.
基金supported by the National Natural Science Foundation of China(No.52436008)the Inner Mongolia Science and Technology Projects,China(Nos.JMRHZX20210003 and 2023YFCY0009)+3 种基金the Huaneng Group Co Ltd.,China(No.HNKJ23-H50)the National Natural Science Foundation of China(No.22408044)the China Postdoctoral Science Foundation(No.2024M761877)the National Key R&D Program of China(No.SQ2024YFD2200039)。
文摘The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbide nanowires using lignite and waste silicon powder as raw materials through carbothermal reduction.The staggered structure of nanowires promotes the creation of interfacial polarization,impedance matching,and multiple loss mechanisms,leading to enhanced electromagnetic absorption performance.The silicon carbide nanowires demonstrate outstanding electromagnetic absorption capabilities with the minimum reflection loss of-48.09 d B at10.08 GHz and an effective absorption bandwidth(the reflection loss less than-10 d B)ranging from 8.54 to 16.68 GHz with a thickness of 2.17 mm.This research presents an innovative approach for utilizing solid waste in an environmentally friendly manner to produce broadband silicon carbide composite absorbers.
文摘Improving energy efficiency and lowering negative environmental impact through waste heat recovery(WHR)is a critical step toward sustainable cement manufacturing.This study analyzes advanced cogeneration systems for recovering waste heat from the Fallujah White Cement Plant in Iraq.The novelty of this work lies in its direct application and comparative thermodynamic analysis of three distinct cogeneration cycles—the Organic Rankine Cycle,the Single-Flash Steam Cycle,and the Dual-Pressure Steam Cycle—within the Iraqi cement industry,a context that has not been widely studied.The main objective is to evaluate and compare these models to determine the most effective approach for enhancing energy and exergy efficiencies.Themethodology involved detailed thermodynamic and exergy analyses of each system,supported by mathematical modelling and simulation using data from plant operations.The results reveal that the Dual-Pressure Steam Cycle emerged as the most effective system,delivering 13.76 MW of net power with a thermal efficiency of 32.8%and an exergy efficiency of 51%.This significantly outperformed the baseline Organic Rankine Cycle(8.18MW,18.8%thermal efficiency,30.7%exergy efficiency).These findings confirm that multipressure steam cycles offer a robust and practical solution for the Fallujah plant.This application provides a clear,high-impact pathway to enhance national industrial energy efficiency,significantly reduce CO_(2) emissions,and promote clean energy sustainability in Iraq.Future work should consider economic feasibility and potential integration with renewable energy sources to further enhance sustainability.
基金Funded by the National Science Foundation of China(No.52368031)the China Postdoctoral Science Foundation(No.2022M713497)+1 种基金the Jiangxi Provincial Natural Science Foundation(No.20252BAC250115)the Jiangxi Provincial Department of Transportation Science and Technology Project(No.2022H0017)。
文摘Utilization of ceramic wastes to fabricate concrete can not only effectively dispose the wastes,but also reduce the energy and source consumptions.Therefore,we fabricated a green ultra high performance concrete using ceramic waste powder(CWP)to replace 55%of cement,and ceramic waste aggregate(CWA)to replace 100%natural quartz sand.However,high content of ceramic wastes will harm the concrete performance including workability and mechanical properties.Therefore,a low-cost and low carbon nano-calcium carbonate(NC)was introduced to compensate for the defects caused by large amounts of CWP and CWA to workability and mechanical behavior.The experimental results show that the workability of ultra high performance concrete with large amounts of CWP and CWA(UHPCLCC)increases by 28.57%with NC content of 5%.Moreover,the flexural strengths,fracture energy,compressive strengths,and compressive toughness of UHPCLCC increase up to 29.6%,56.5%,20.4%,and 37.6%,respectively,which is caused by the nano-core effect of NC.
基金supported by the Natural Science Foundation of Shandong Province(ZR2022QE042)China Postdoctoral Science Foundation(2023M741856)the National Natural Science Foundation of China(52172093).
文摘Pyrolysis technology has emerged as a promising method for converting waste polyurethane(WPU)from waste refrigerators into high-value chemicals.In this study,the copper(Cu)-assisted pyrolysis strategy was employed to enhance the thermal degradation efficiency and product quality of WPU.Kinetic analysis revealed that the activation energy(E_(a)) of the Cu-assisted pyrolysis was 136.64 kJ·mol^(−1) and Cu-assisted pyrolysis was controlled by the combined processes of diffusion,nucleation and phase boundary reactions.Comprehensive product analysis,including gas chromatography–mass spectrometry and thermogravimetric Fourier transform infrared spectroscopy–mass spectrometry suggested that Cu promoted the cleavage of urethane bonds and accelerated the decarboxylation of isocyanates,increasing the yields of aniline and ethanol at lower temperatures.Meanwhile,Cu effectively suppressed the formation of halogenated and heterocyclic compounds by promoting the cleavage of C–X(X=Cl,F)bonds through electron transfer interactions.Thus,the E_(a) is decreased and the halogenated compounds is reduced.This work provides the theoretical basis for converting waste to high-valued products through co-pyrolysis techniques.
基金Project(2022YFC2904103)supported by the National Key Research and Development Program of ChinaProjects(52374112,52274108)supported by the National Natural Science Foundation of China+1 种基金Projects(BX20220036,BX20230041)supported by the Postdoctoral Innovation Talents Support Program,ChinaProject(2232080)supported by the Beijing Natural Science Foundation,China。
文摘The development of metallic mineral resources generates a significant amount of solid waste,such as tailings and waste rock.Cemented tailings and waste-rock backfill(CTWB)is an effective method for managing and disposing of this mining waste.This study employs a macro-meso-micro testing method to investigate the effects of the waste rock grading index(WGI)and loading rate(LR)on the uniaxial compressive strength(UCS),pore structure,and micromorphology of CTWB materials.Pore structures were analyzed using scanning electron microscopy(SEM)and mercury intrusion porosimetry(MIP).The particles(pores)and cracks analysis system(PCAS)software was used to quantitatively characterize the multi-scale micropores in the SEM images.The key findings indicate that the macroscopic results(UCS)of CTWB materials correspond to the microscopic results(pore structure and micromorphology).Changes in porosity largely depend on the conditions of waste rock grading index and loading rate.The inclusion of waste rock initially increases and then decreases the UCS,while porosity first decreases and then increases,with a critical waste rock grading index of 0.6.As the loading rate increases,UCS initially rises and then falls,while porosity gradually increases.Based on MIP and SEM results,at waste rock grading index 0.6,the most probable pore diameters,total pore area(TPA),pore number(PN),maximum pore area(MPA),and area probability distribution index(APDI)are minimized,while average pore form factor(APF)and fractal dimension of pore porosity distribution(FDPD)are maximized,indicating the most compact pore structure.At a loading rate of 12.0 mm/min,the most probable pore diameters,TPA,PN,MPA,APF,and APDI reach their maximum values,while FDPD reaches its minimum value.Finally,the mechanism of CTWB materials during compression is analyzed,based on the quantitative results of UCS and porosity.The research findings play a crucial role in ensuring the successful application of CTWB materials in deep metal mines.
基金supported by a grant from NIH(R01AI132695)to RM。
文摘Chronic wasting disease—a prion disease affecting cervids:Many neurological conditions,including Alzheimer's and Parkinson's diseases,amyotrophic lateral sclerosis,frontotemporal dementias,among others,are caused by the accumulation of misfolded proteins in the brain.These diseases affect not only humans,but also animals.
基金supported by the National Natural Science Foundation of China(No.22176200)the Industrial Innovation Entrepreneurial Team Project of Ordos 2021.
文摘Industrial waste salts are commonly used to make value-added snow-melting agents to ensure traffic safety in northern China during winter and spring after snowfall.However,heavy metals in industrial waste salts may pose certain environmental risks.Snow-melting agents and snow samples were collected and analyzed from highways,arterial roads,footbridges,and other locations in Beijing after the snowstorm in December 2023.It was found that the main component of snow-melting agents was sodium chloride with high concentrations of Cu,Mn,and Zn,which are not regulated in the current policies,despite the recent promotion of environmentally friendly snow-melting agents.The Pb,Zn and Cr contents of some snow samples exceeded the limitation value of surface water quality standards,potentially affecting the soil and water environment near roadsides,although the snow-melting agents comply with relevant standards,which indicates the policy gap in the management of recycled industrial salts.We reviewed and analyzed the relevant standards for snow-melting agents and industrial waste salts proposed nationally and internationally over the past 30 years.Through comparative analysis,we proposed relevant policy recommendations to the existing quality standards of snow-melting agents and the management regulations of industrial waste salts,and the formulation of corresponding usage strategies,aimed at reducing the potential environmental release of heavy metals from the use of snow-melting agents,thereby promoting more sustainable green urban development and environmentally sound waste management.
基金the National Natural Science Foundation of China(22479047,22409058)the Outstanding Youth Scientist Foundation of Hunan Province(2022JJ10023)the Provincial Natural Science Foundation of Guangdong(2023A1515011745)for financial support of this research。
文摘To ease the scarcity of lithium(Li)resource and cut down on environmental pollution,an efficient,selective,inexpensive and sustainable Li recycling process from waste batteries is needed,which is yet to be achieved.Here,we report a low-potential photoelectrochemical(PEC)system that selectively and efficiently extracts Li metals from multi-cation electrolytes under 1 sun illumination.Based on the difference of redox potential,we can get rid of the disturbance of other cations(i.e.,Fe,Co and Ni ions)by a bias-free PEC device to realize the extraction of high-purity Li metals on a coplanar Si-based photocathode-TiO_(2) photoanode tandem device at 2 V of applied bias(far less than the redox potentials of Li^(+)/Li).In such system,the extraction rate of Li metals(purity>99.5%)exceeds 1.35 g h^(-1)m^(-2)with 90%of Faradaic efficiency.Long-term experiments,different electrode/electrolyte tests,and various price assessments further demonstrate the stability,compatibility and economy of PEC extraction system,enabling a solar-driven pathway for the recycling of critical metal resources.
文摘The utilisation of waste in green sustainable technology can provide a clean environment and support energy demand.This work aims to design and analyse the performance of a developed indirect flat-plate Solar Air Heater(SAH)integrated with an internal thermal storage unit using Waste Automotive Oil(WAO).The SAH was designed based on the circulation of confined air around the internal thermal storage unit due to the updraft effects of hot air.Two SAHs were tested to compare the performance of WAO and water,with the results being compared to previous work that utilised phase change material.Results showed that WAO responds faster in the early stage,while water has slightly higher daytime efficiency,with a maximum temperature of 60℃,while WAO reached a maximum temperature of 76℃.During the discharge cycle,WAO achieved an efficiency of 65.7%,while the water’s efficiency 73.2% within the same period.The highest outlet air temperatures recorded were 43℃ for WAO and 33.8℃ for water.These findings support that water is suitable for applications requiring rapid thermal charging,while WAO offers extended thermal stability.The study highlights the feasibility of using low-cost materials,such as WAO and water,to enhance the performance of solar energy systems,thereby making them more viable for industrial applications like drying and heating.
基金the financial support provided by UMS Great(GUG0670-1/2024),which played a crucial role in the completion of this studyAdditionally,we would like to express our sincere appreciation for the financial assistance and scholarships generously offered by the University of Malaysia Sabah(UMS)throughout the Ministry of Higher Education Malaysia(KPT)throughout the research period.These contributions were invaluable in facilitating our research endeavors.
文摘The growing demand for renewable energy has increased the use of wood pellets as a clean and efficient biomass fuel.This study aims to evaluate the physical properties of wood pellets produced from Acacia hybrid(AC)veneer waste and Pine wood(PW)waste mixed with varying ratios.The objectives are to investigate the effect of different blend ratios ofAcacia hybrid veneer waste and pine wood waste on the physical properties,specificallymoisture content,density,and pellet durability index(PDI)of wood pellets,and to identify the optimal ratio that yields the most desirable pellet quality.The wood pellets were produced by blending Acacia hybrid veneer waste and Pine wood waste(AC:PW)in weight ratios of 100:0,75:25,50:50,25:75,and 0:100.The materials were dried to 10%–12%moisture before pelletizing using a pellet mill under consistent pressure and temperature.Moisture content(MC),density(ρ)and pellet durability index(PDI)were measured following the International Organization for Standardization(ISO).The study found that blending Acacia hybrid veneer waste with Pine wood waste significantly improved pellet density and durability compared to the control.The moisture was lowest in pellets with 50:50 and 25:75 blends,indicating better drying and stability.The blend 50:50 achieves the highest density,and for pellet durability index,the best blend is 25:75,suggesting improved resistance to breakage.Overall,the 50:50 and 25:75 ratios produced pellet with the most desirable combination of low moisture,high density,high durability and the blend meets key ISO 17225 and ENplus quality standards for industrial wood pellet.
基金supported by the National Natural Science Foundation of China(Grant Nos.52171169 and 52101210)the National Key Research and Development Program of China(Grant No.2021YFB3501204)+3 种基金the State Key Laboratory for Advanced Metals and Materials(Grant No.2023-ZD01)USTB Concept Verification Funding Project(Grant No.GNYZ-2024-6)Fundamental Research Funds for the Central Universities(Grant No.FRF-TP-24-004A)USTB Research Center for International People-to-people Exchange in Science,Technology and Civilization(Grant Nos.2024KFZD001 and 2024KFYB004)。
文摘Thermomagnetic generation(TMG),a heat-to-electricity conversion technology based on the thermomagnetic effect,offers high reliability and broad adaptability to diverse heat sources.By exploiting the temperature-dependent magnetization of thermomagnetic materials,TMG converts thermal energy into electrical energy through cyclic changes in magnetic flux based on Faraday's law.The performance of TMG systems is largely governed by the intrinsic properties of the working materials and the design of device architecture.Ideal TMG materials exhibit sharp and reversible magnetization transitions near the operating temperature,low thermal hysteresis,and high thermal conductivity.Device configurations can be broadly categorized into active and passive systems:active TMG devices rely on controlled thermal cycling and optimized magnetic circuits for enhanced output,whereas passive devices utilize self-actuated mechanical motion to generate electricity.In this topical review,we provide a comprehensive overview of recent advances in TMG materials and device configurations.Furthermore,we discuss future development trends and offer perspectives on experimental strategies to advance this field.
