AIM: To explore recent trends, modes of diagnosis, ethnic distribution and the mortality to incidence ratio of primary liver cancer by subtypes in England and Wales.
Stone–Wales(SW) defects are possibly formed in graphene and other two-dimensional materials, and have multiple influence on their physical and chemical properties. In this study, the transition state of SW defects in...Stone–Wales(SW) defects are possibly formed in graphene and other two-dimensional materials, and have multiple influence on their physical and chemical properties. In this study, the transition state of SW defects in graphene is determined with the fully discrete Peierls theory. Furthermore, the atomic formation process is investigated by means of ab-initio simulations. The atomic structure change and energetics of the SW transformation are revealed. It is found that the transition state is at the SW bond rotation of 34.5°and the activation energy barrier is about 12 eV. This work provides a new method to investigate SW transformations in graphene-like materials and to explore unknown SW-type defects in other 2D materials.展开更多
The thermal conductivity of carbon nanotubes with certain defects （doping, Stone-Wales, and vacancy） is investigated by using the non-equilibrium molecular dynamics method. The defective carbon nanotubes （CNTs） ar...The thermal conductivity of carbon nanotubes with certain defects （doping, Stone-Wales, and vacancy） is investigated by using the non-equilibrium molecular dynamics method. The defective carbon nanotubes （CNTs） are compared with perfect tubes. The influences of type and concentration of the defect, length, diameter, and chirality of the tube, and the ambient temperature are taken into consideration. It is demonstrated that defects result in a dramatic reduction of thermal conductivity. Doping and Stone-Wales （SW） defects have greater effect on armchair tubes, while vacancy affects the zigzag ones more. Thermal conductivity of the nanotubes increases, reaches a peak, and then decreases with increasing temperature. The temperature at which the thermal conductivity peak occurs is dependent on the defect type. Different from SW or vacancy tubes, doped tubes are similar to the perfect ones with a sharp peak at the same temperature. Thermal conductivity goes up when the tube length grows or diameter declines. It seems that the length of thermal conductivity convergence for SW tubes is much shorter than perfect or vacancy ones. The SW or vacancy tubes are less sensitive to the diameter change, compared with perfect ones.展开更多
The Integrated Marine Observing System [IMOS] is an Australian national program for observing the oceans around Australia. As one of its important nodes, the New South Wales Integrated Marine Observing System （NSW-IM...The Integrated Marine Observing System [IMOS] is an Australian national program for observing the oceans around Australia. As one of its important nodes, the New South Wales Integrated Marine Observing System （NSW-IMOS] aims to provide more accurate descriptions of the East Australian Current [EAC]. The purpose of this paper is to evaluate the potential economic benefits from NSW-IMOS. Six related sectors which can potentially be among its main beneficiaries are considered： beach recreation, commercial fishing, recreational fishing, recreational boating, natural hazard predictions, and oil spill mitigation. The 1% constant percentage increase evaluation method is used to estimate the potential economic benefits to these six beneficiaries. By using this method, our study shows that the total potential economic benefit for these sectors is estimated to be $ 6.07 million per year. We consider that this is indicative but not conclusive in demonstrating some of the potential economic benefits that can be provided from information gathered by NSW-IMOS facilities. We conclude with further evaluative approaches that could be used to provide more accurate estimates of potential economic benefits.展开更多
Three major types of Ordovician intrusive-related gold-copper deposits are recognized in central-west New South Wales, Australia: porphyry, skarn and high sulphidation epithermal deposits. These deposits are mainly di...Three major types of Ordovician intrusive-related gold-copper deposits are recognized in central-west New South Wales, Australia: porphyry, skarn and high sulphidation epithermal deposits. These deposits are mainly distributed within two Ordovician volcano-intrusive belts of the Lachlan Fold Belt: the Orange-Wellington Belt and the Parkes-Narromine Belt. Available isotopic age data suggest that mineralization of the three types of deposits is essentially coeval with the Ordovician intrusive rocks (480-430 Ma).Porphyry gold-copper deposits can be further divided into two groups. The first group is associated with monzonite showing shoshonitic features, represented by Cadia and Goonumbla. The second group is associated with diorite and dacite, including the Copper Hill and Cargo gold-copper deposits. Gold skarn is associated with Late Ordovician (430-439 Ma) monzonitic intrusive complexes in the Junction Reefs area (Sheahan-Grants, Frenchmans, and Cor-nishmens), Endeavour 6, 7 and 44, Big and Little Cadia. The epithermal gold deposits with high sulphidation including Gidginbung (Temora) and Peak Hill mainly occur within Ordovician andesite and volcaniclastic rocks, and are associated with advanced argillic alteration. Available isotopic age data indicate that both alteration and mineralization of the porphyry, skarn and epithermal gold-copper deposits are broadly coeval with the Late Ordovician shoshonitic magmatism, which is thought to result from the melting of sub-continental lithosphere caused by Palaeozoic subduction events.The Ordovician intrusive-related gold-copper deposits are restricted to two longitudinal parallel volcano-intrusive belts, rarely extending outside them. Diagonal intra-belt trends of mineralization are common, particularly at the intersections of longitudinal and transverse (oblique) fault/fracture zones based on the authors' review of available geological data. The locations of these gold-copper deposits are obviously influenced by transverse (oblique) fault/fracture zones that are oriented northwest, eastwest and northeast. The conjunctions of these fault/fractures zones are thought to be zones of structural weakness, and appear to be the favourable locus for the Ordovician intrusive-related gold-copper deposits. Differences in structural patterns, intrusive, wall rock types, and depths of ore formation may contribute to the differences among the deposits.展开更多
We show an effective method of healing the Stone–Wales(SW)defects through low energy electron irradiation using ab initio molecular dynamics simulation.The SW defects can be healed by irradiation through bond rotatio...We show an effective method of healing the Stone–Wales(SW)defects through low energy electron irradiation using ab initio molecular dynamics simulation.The SW defects can be healed by irradiation through bond rotation.Although the healing energy shows an anisotropic behavior,it is lower than the displacement threshold energy.The healing of the SW defect through electron irradiation can be effectively used in other sp2-bonded materials.展开更多
Defect-based engineering of carbon nanostructures is becoming an important and powerful method to modify the electron transport properties in graphene nanoribbon FETs. In this paper, the impact of the position and sym...Defect-based engineering of carbon nanostructures is becoming an important and powerful method to modify the electron transport properties in graphene nanoribbon FETs. In this paper, the impact of the position and symmetry of the ISTW defect on the performance of low dimensional 9AGNR double-gate graphene nanoribbon FET (DG-GNRFET) is investigated. Analyzing the transmission spectra, density of states and current-voltage characteristics shows that the defect effect on the electron transport is considerably varied depending on the positions and the orientations (the symmetric and asymmetric configuration) of the ISTW defect in the channel length. Based on the results, the asymmetric ISTW defect leads to a more controllability of the gate voltages over drain current, and drain current increases more than 5 times. The results have also con rmed the ISTW defect engineering potential on controlling the channel electrical current of DG-AGNR FET.展开更多
The Lachlan Orogen of New South Wales,Victoria and eastern Tasmania is the best understood element of the eastern Australian Tasmanides.The Tasmanides encompass continental growth in a Neoproterozoic passive margin se...The Lachlan Orogen of New South Wales,Victoria and eastern Tasmania is the best understood element of the eastern Australian Tasmanides.The Tasmanides encompass continental growth in a Neoproterozoic passive margin setting and a Paleozoic–Mesozoic active margin in east Gondwana,bounded to the east by the Pacific Ocean.In the Ordovician,the supra-subduction zone element in the Lachlan Orogen is the Macquarie Arc.This comprises one minor and three major belts of mafic to intermediate volcanic and volcaniclastic rocks,limestones and intrusions that,with two hiatuses in magmatism,span the Ordovician and extend into the Early Silurian.The three major belts in central New South Wales are separated by Silurian–Devonian rift basins and are therefore,inferred to have been rifted apart during crustal extension.Chemical and isotopic data suggest the Macquarie Arc is intraoceanic,developed on primitive oceanic crust.Despite this,key features such as its longevity,stacked magmatic phases,little deformation and flanking coeval craton-derived turbidites and black shales with no provenance mixing indicate differences from modern intraoceanic arcs.Paleogeographic setting and magmatic evolution of the Macquarie Arc provided perfect conditions for mainly porphyry-related,rich Au-Cu deposits,in the Ordovician,and especially in the Early Silurian after amalgamation of the arc with its flanking terranes.展开更多
采用密度泛函理论中的UB3LYP方法,研究了石墨烯中的Stone-wales缺陷对铂原子催化解离氧气分子的影响.通过计算发现,氧气分子在以Stone-wales缺陷石墨烯片为载体的铂上(Pt-SW)形成3种吸附结构,通过4条路径,最终生成两种产物.氧气分子最...采用密度泛函理论中的UB3LYP方法,研究了石墨烯中的Stone-wales缺陷对铂原子催化解离氧气分子的影响.通过计算发现,氧气分子在以Stone-wales缺陷石墨烯片为载体的铂上(Pt-SW)形成3种吸附结构,通过4条路径,最终生成两种产物.氧气分子最易通过[2+1]环加成作用,吸附在以Stone-wales缺陷石墨烯片为载体的Pt的表面上,吸附能(Eads)为-0.64eV.由于石墨烯片上的Stone-wales缺陷的存在,氧气分子在Pt-SW上解离的4条路径中最有利的解离路径中的决速步能垒都明显高于氧气在以完美石墨烯为载体的Pt(Pt/Graphene)上解离的能垒(1.51eV vs 1.35eV),相应吸收的热量也高于在Pt/Graphene上吸收的热量(0.79eVvs0.15eV).展开更多
文摘AIM: To explore recent trends, modes of diagnosis, ethnic distribution and the mortality to incidence ratio of primary liver cancer by subtypes in England and Wales.
基金Project supported by the National Natural Science Foundation of China (Grant No. 11847089)the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Grant No. 20KJB430002)GuiZhou Provincial Department of Science and Technology, China (Grant No. QKHJC[2019]1167)。
文摘Stone–Wales(SW) defects are possibly formed in graphene and other two-dimensional materials, and have multiple influence on their physical and chemical properties. In this study, the transition state of SW defects in graphene is determined with the fully discrete Peierls theory. Furthermore, the atomic formation process is investigated by means of ab-initio simulations. The atomic structure change and energetics of the SW transformation are revealed. It is found that the transition state is at the SW bond rotation of 34.5°and the activation energy barrier is about 12 eV. This work provides a new method to investigate SW transformations in graphene-like materials and to explore unknown SW-type defects in other 2D materials.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 50876010 and 51176011)the Program for New Century Excellent Talents in University of Ministry of Education of China (Grant No. NCET-08-0721)
文摘The thermal conductivity of carbon nanotubes with certain defects （doping, Stone-Wales, and vacancy） is investigated by using the non-equilibrium molecular dynamics method. The defective carbon nanotubes （CNTs） are compared with perfect tubes. The influences of type and concentration of the defect, length, diameter, and chirality of the tube, and the ambient temperature are taken into consideration. It is demonstrated that defects result in a dramatic reduction of thermal conductivity. Doping and Stone-Wales （SW） defects have greater effect on armchair tubes, while vacancy affects the zigzag ones more. Thermal conductivity of the nanotubes increases, reaches a peak, and then decreases with increasing temperature. The temperature at which the thermal conductivity peak occurs is dependent on the defect type. Different from SW or vacancy tubes, doped tubes are similar to the perfect ones with a sharp peak at the same temperature. Thermal conductivity goes up when the tube length grows or diameter declines. It seems that the length of thermal conductivity convergence for SW tubes is much shorter than perfect or vacancy ones. The SW or vacancy tubes are less sensitive to the diameter change, compared with perfect ones.
文摘The Integrated Marine Observing System [IMOS] is an Australian national program for observing the oceans around Australia. As one of its important nodes, the New South Wales Integrated Marine Observing System （NSW-IMOS] aims to provide more accurate descriptions of the East Australian Current [EAC]. The purpose of this paper is to evaluate the potential economic benefits from NSW-IMOS. Six related sectors which can potentially be among its main beneficiaries are considered： beach recreation, commercial fishing, recreational fishing, recreational boating, natural hazard predictions, and oil spill mitigation. The 1% constant percentage increase evaluation method is used to estimate the potential economic benefits to these six beneficiaries. By using this method, our study shows that the total potential economic benefit for these sectors is estimated to be $ 6.07 million per year. We consider that this is indicative but not conclusive in demonstrating some of the potential economic benefits that can be provided from information gathered by NSW-IMOS facilities. We conclude with further evaluative approaches that could be used to provide more accurate estimates of potential economic benefits.
文摘Three major types of Ordovician intrusive-related gold-copper deposits are recognized in central-west New South Wales, Australia: porphyry, skarn and high sulphidation epithermal deposits. These deposits are mainly distributed within two Ordovician volcano-intrusive belts of the Lachlan Fold Belt: the Orange-Wellington Belt and the Parkes-Narromine Belt. Available isotopic age data suggest that mineralization of the three types of deposits is essentially coeval with the Ordovician intrusive rocks (480-430 Ma).Porphyry gold-copper deposits can be further divided into two groups. The first group is associated with monzonite showing shoshonitic features, represented by Cadia and Goonumbla. The second group is associated with diorite and dacite, including the Copper Hill and Cargo gold-copper deposits. Gold skarn is associated with Late Ordovician (430-439 Ma) monzonitic intrusive complexes in the Junction Reefs area (Sheahan-Grants, Frenchmans, and Cor-nishmens), Endeavour 6, 7 and 44, Big and Little Cadia. The epithermal gold deposits with high sulphidation including Gidginbung (Temora) and Peak Hill mainly occur within Ordovician andesite and volcaniclastic rocks, and are associated with advanced argillic alteration. Available isotopic age data indicate that both alteration and mineralization of the porphyry, skarn and epithermal gold-copper deposits are broadly coeval with the Late Ordovician shoshonitic magmatism, which is thought to result from the melting of sub-continental lithosphere caused by Palaeozoic subduction events.The Ordovician intrusive-related gold-copper deposits are restricted to two longitudinal parallel volcano-intrusive belts, rarely extending outside them. Diagonal intra-belt trends of mineralization are common, particularly at the intersections of longitudinal and transverse (oblique) fault/fracture zones based on the authors' review of available geological data. The locations of these gold-copper deposits are obviously influenced by transverse (oblique) fault/fracture zones that are oriented northwest, eastwest and northeast. The conjunctions of these fault/fractures zones are thought to be zones of structural weakness, and appear to be the favourable locus for the Ordovician intrusive-related gold-copper deposits. Differences in structural patterns, intrusive, wall rock types, and depths of ore formation may contribute to the differences among the deposits.
基金Supported by the China Postdoctoral Science Foundation under Grant No 20090461331the Natural Science Foundation of Zhanjiang Normal College under Grant No ZL1005.
文摘We show an effective method of healing the Stone–Wales(SW)defects through low energy electron irradiation using ab initio molecular dynamics simulation.The SW defects can be healed by irradiation through bond rotation.Although the healing energy shows an anisotropic behavior,it is lower than the displacement threshold energy.The healing of the SW defect through electron irradiation can be effectively used in other sp2-bonded materials.
文摘Defect-based engineering of carbon nanostructures is becoming an important and powerful method to modify the electron transport properties in graphene nanoribbon FETs. In this paper, the impact of the position and symmetry of the ISTW defect on the performance of low dimensional 9AGNR double-gate graphene nanoribbon FET (DG-GNRFET) is investigated. Analyzing the transmission spectra, density of states and current-voltage characteristics shows that the defect effect on the electron transport is considerably varied depending on the positions and the orientations (the symmetric and asymmetric configuration) of the ISTW defect in the channel length. Based on the results, the asymmetric ISTW defect leads to a more controllability of the gate voltages over drain current, and drain current increases more than 5 times. The results have also con rmed the ISTW defect engineering potential on controlling the channel electrical current of DG-AGNR FET.
文摘The Lachlan Orogen of New South Wales,Victoria and eastern Tasmania is the best understood element of the eastern Australian Tasmanides.The Tasmanides encompass continental growth in a Neoproterozoic passive margin setting and a Paleozoic–Mesozoic active margin in east Gondwana,bounded to the east by the Pacific Ocean.In the Ordovician,the supra-subduction zone element in the Lachlan Orogen is the Macquarie Arc.This comprises one minor and three major belts of mafic to intermediate volcanic and volcaniclastic rocks,limestones and intrusions that,with two hiatuses in magmatism,span the Ordovician and extend into the Early Silurian.The three major belts in central New South Wales are separated by Silurian–Devonian rift basins and are therefore,inferred to have been rifted apart during crustal extension.Chemical and isotopic data suggest the Macquarie Arc is intraoceanic,developed on primitive oceanic crust.Despite this,key features such as its longevity,stacked magmatic phases,little deformation and flanking coeval craton-derived turbidites and black shales with no provenance mixing indicate differences from modern intraoceanic arcs.Paleogeographic setting and magmatic evolution of the Macquarie Arc provided perfect conditions for mainly porphyry-related,rich Au-Cu deposits,in the Ordovician,and especially in the Early Silurian after amalgamation of the arc with its flanking terranes.
文摘采用密度泛函理论中的UB3LYP方法,研究了石墨烯中的Stone-wales缺陷对铂原子催化解离氧气分子的影响.通过计算发现,氧气分子在以Stone-wales缺陷石墨烯片为载体的铂上(Pt-SW)形成3种吸附结构,通过4条路径,最终生成两种产物.氧气分子最易通过[2+1]环加成作用,吸附在以Stone-wales缺陷石墨烯片为载体的Pt的表面上,吸附能(Eads)为-0.64eV.由于石墨烯片上的Stone-wales缺陷的存在,氧气分子在Pt-SW上解离的4条路径中最有利的解离路径中的决速步能垒都明显高于氧气在以完美石墨烯为载体的Pt(Pt/Graphene)上解离的能垒(1.51eV vs 1.35eV),相应吸收的热量也高于在Pt/Graphene上吸收的热量(0.79eVvs0.15eV).
