We have performed first-principles density functional theory calculations to investigate the retention and migration of hydrogen in Be_（22） W, a stable low-W intermetallic compound. The solution energy of interstiti...We have performed first-principles density functional theory calculations to investigate the retention and migration of hydrogen in Be_（22） W, a stable low-W intermetallic compound. The solution energy of interstitial H in Be_（22） W is found to be 0.49 eV lower, while the diffusion barrier, on the other hand, is higher by 0.13 eV compared to those in pure hcp-Be. The higher solubility and lower diffusivity for H atoms make Be_（22） W a potential beneficial secondary phase in hcp-Be to impede the accumulation of H atoms, and hence better resist H blistering. We also find that in Be_（22） W, the attraction between an interstitial H and a beryllium vacancy ranges from 0.34 eV to 1.08 eV, which indicates a weaker trapping for hydrogen than in pure Be. Our calculated results suggest that small size Be_（22） W particles in hcp-Be might serve as the hydrogen trapping centers, hinder hydrogen bubble growth, and improve the resistance to irradiation void swelling, just as dispersed oxide particles in steel do.展开更多
W型潜坝作为一种新型的堰坝结构,不仅具有消能、护岸、分流和改善通航条件等功能,而且具有显著的生态功能。选取鲫鱼幼鱼为目标鱼类,研究不同粒径组成的W型潜坝的河流流速分布及对目标鱼类聚集的影响,探明W型潜坝的生境改良效果,为裁弯...W型潜坝作为一种新型的堰坝结构,不仅具有消能、护岸、分流和改善通航条件等功能,而且具有显著的生态功能。选取鲫鱼幼鱼为目标鱼类,研究不同粒径组成的W型潜坝的河流流速分布及对目标鱼类聚集的影响,探明W型潜坝的生境改良效果,为裁弯河段生态涵养区建设提供依据。研究结果表明不同粒径的W型潜坝作用下,[10,20]mm较大粒径组成的W型潜坝透水性更好,流速梯度小于小粒径组,流态多样性高。在流量0.09 m 3/s条件下,[10,20]mm粒径组成的W型潜坝鱼类聚集区域停留最多达到85次;[10,20]mm较大粒径组成的W型潜坝生境多样性高,可以为试验鱼提供更好的栖息和庇护场所。因此,在人工运河修建中裁弯河段生态涵养区建议选透水效果较好的大粒径潜坝方案。流态多样性指数与鱼类平均聚集度存在线性关系,可作为评价栖息地质量的依据,研究成果为河流生境异质性研究和生态优化设计提供理论支撑。展开更多
基金Project supported by the National Magnetic Confinement Fusion Program of China(Grant Nos.2014GB104003 and 2015GB105001)the National Natural Science Foundation of China(Grant No.51504033)
文摘We have performed first-principles density functional theory calculations to investigate the retention and migration of hydrogen in Be_（22） W, a stable low-W intermetallic compound. The solution energy of interstitial H in Be_（22） W is found to be 0.49 eV lower, while the diffusion barrier, on the other hand, is higher by 0.13 eV compared to those in pure hcp-Be. The higher solubility and lower diffusivity for H atoms make Be_（22） W a potential beneficial secondary phase in hcp-Be to impede the accumulation of H atoms, and hence better resist H blistering. We also find that in Be_（22） W, the attraction between an interstitial H and a beryllium vacancy ranges from 0.34 eV to 1.08 eV, which indicates a weaker trapping for hydrogen than in pure Be. Our calculated results suggest that small size Be_（22） W particles in hcp-Be might serve as the hydrogen trapping centers, hinder hydrogen bubble growth, and improve the resistance to irradiation void swelling, just as dispersed oxide particles in steel do.
文摘W型潜坝作为一种新型的堰坝结构,不仅具有消能、护岸、分流和改善通航条件等功能,而且具有显著的生态功能。选取鲫鱼幼鱼为目标鱼类,研究不同粒径组成的W型潜坝的河流流速分布及对目标鱼类聚集的影响,探明W型潜坝的生境改良效果,为裁弯河段生态涵养区建设提供依据。研究结果表明不同粒径的W型潜坝作用下,[10,20]mm较大粒径组成的W型潜坝透水性更好,流速梯度小于小粒径组,流态多样性高。在流量0.09 m 3/s条件下,[10,20]mm粒径组成的W型潜坝鱼类聚集区域停留最多达到85次;[10,20]mm较大粒径组成的W型潜坝生境多样性高,可以为试验鱼提供更好的栖息和庇护场所。因此,在人工运河修建中裁弯河段生态涵养区建议选透水效果较好的大粒径潜坝方案。流态多样性指数与鱼类平均聚集度存在线性关系,可作为评价栖息地质量的依据,研究成果为河流生境异质性研究和生态优化设计提供理论支撑。
