Large-grain REBa_(2)Cu_(3)O_(7-δ)(REBCO,RE=rare earth)bulk superconductors offer promising magnetic field trapping capabilities due to their high critical current density,making them ideal for many important applicat...Large-grain REBa_(2)Cu_(3)O_(7-δ)(REBCO,RE=rare earth)bulk superconductors offer promising magnetic field trapping capabilities due to their high critical current density,making them ideal for many important applications such as trapped field magnets.However,for such large-grain superconductor bulks,there are lots of voids and cracks forming during the process of melting preparation,and some of them can be up to hundreds of microns or even millimeters in size.Consequently,these larger size voids/cracks pose a great threat to the strength of the bulks due to the inherent brittleness of superconductor REBCO materials.In order to ensure the operational safety of related superconducting devices with bulk superconductors,it is firstly important to accurately detect these voids/cracks in them.In this paper,we proposed a method for quantitatively evaluating multiple voids/cracks in bulk superconductors through the magnetic field and displacement response signals at superconductor bulk surface.The proposed method utilizes a damage index constructed from the magnetic field signals and displacement responses to identify the number and preliminary location of multiple defects.By dividing the detection area into subdomains and combining the magnetic field signals with displacement responses within each subdomain,a particle swarm algorithm was employed to evaluate the location and size parameters of the defects.In contrast to other evaluation methods using only magnetic field or displacement response signals,the combined evaluation method using both signals can identify the number of cracks effectively.Numerical studies demonstrate that the morphology of voids and cracks reconstructed using the proposed algorithm ideally matches real defects and is applicable to cases where voids and cracks coexist.This study provides a theoretical basis for the quantitative detection of voids/cracks in bulk superconductors.展开更多
Four cellulose ethers（CEs） were compared for their effects on the pore structure of cement paste using mercury intrusion porosimetry. The experimental results show that the total pore volume and porosity of cement p...Four cellulose ethers（CEs） were compared for their effects on the pore structure of cement paste using mercury intrusion porosimetry. The experimental results show that the total pore volume and porosity of cement pastes containing the four cellulose ethers are significantly higher than that of the pure cement pastes and the total pore volume and porosity of cement pastes containing HEC（hydroxyethyl cellulose ether） or low viscosity cellulose ethers are low in four CEs. By changing the surface tension and viscosity of liquid phase and the strengthening of liquid film between air voids in cement pastes, CEs affect the formation, diameter evolution and upward movement of air voids and the pore structure of hardening cement paste. For the four CEs, the pore volume of cement pastes containing HEC or low viscosity cellulose ethers is higher with the diameter of 30-70 nm while lower with the diameter larger than 70 nm. CEs affect the pore structure of cement paste mainly through their effects on the evolvement of the small air voids into bigger ones when the pore diameter is below 70 nm and their effects on the entrainment and stabilization of air voids when the pore diameter is above 70 nm.展开更多
Nano-twinned copper(nt-Cu),with a preferred orientation,is highly promising as interconnect materials in high-density advanced packaging due to its considerable mechanical strength,excellent electrical conductivity,an...Nano-twinned copper(nt-Cu),with a preferred orientation,is highly promising as interconnect materials in high-density advanced packaging due to its considerable mechanical strength,excellent electrical conductivity,and resistance to thermal migration.However,its application is impeded by sulfur-containing byproducts from the electroplating process,exacerbating the formation of Kirkendall voids within solder joints during thermal aging.Herein,through the incorporation of Zinc(Zn)into the nt-Cu layer,we develop a nt-Cu/Zn composite structure.Our findings provide the first definitive confirmation of the mechanism by which sulfur atoms migrate to the Cu_(3)Sn/nt-Cu interface through interstitial diffusion,thereby reducing the activation energy for vacancy formation.We further demonstrate that Zn effectively an-choring sulfur atoms,forming ZnS within the nt-Cu layer during heat treatment,which increases the vacancy formation energy and inhibits the development of Kirkendall voids.Remarkably,no Kirkendall voids are observed in the modified interconnects even after prolonged aging at 150℃ for 1000 h.The nt-Cu/Zn composite metallization layers significantly decrease the growth rate of interfacial intermetallic compounds by 33.6% and enhance the shear strength of solder interconnections to 228.9%.This research underscores the potential of nt-Cu in advanced electronic packaging,offering new pathways for improving the power density and reliability of electronic devices.展开更多
Renewable energy storage technologies are critical for transitioning to sustainable energy systems,with salt caverns playing a significant role in large-scale solutions.In water-soluble mining of low-grade salt format...Renewable energy storage technologies are critical for transitioning to sustainable energy systems,with salt caverns playing a significant role in large-scale solutions.In water-soluble mining of low-grade salt formations,insoluble impurities and interlayers detach during salt dissolution and accumulate as sediment at the cavern base,thereby reducing the storage capacity and economic viability of salt cavern gas storage(SCGS).This study investigates sediment formation mechanisms,void distribution,and voidage in the Huai'an low-grade salt mine,introducing a novel self-developed physical simulation device for two butted-well horizontal(TWH)caverns that replicates compressed air injection and brine discharge.Experiments comparing“one injection and one discharge”and“two injections and one discharge”modes revealed that(1)compressed air effectively displaces brine from sediment voids,(2)a 0.5 MPa injection pressure corresponds to a 10.3 MPa operational lower limit in practice,aligning with field data,and(3)sediment voidage is approximately 46%,validated via air-brine interface theory.The“two injections and one discharge”mode outperformed in both discharge volume and rate.Additionally,a mathematical model for brine displacement via compressed air was established.These results provide foundational insights for optimizing compressed air energy storage(CAES)in low-grade salt mines,advancing their role in renewable energy integration.展开更多
Nickel-based alloys are the primary structural materials in steam generators of high-temperature gas reactors.To understand the irradiation effect of nickel-based alloys,it is necessary to examine dislocation movement...Nickel-based alloys are the primary structural materials in steam generators of high-temperature gas reactors.To understand the irradiation effect of nickel-based alloys,it is necessary to examine dislocation movement and its interaction with irradiation defects at the microscale.Hardening due to voids and Ni_(3)Al precipitates may significantly impact irradiation damage in nickel-based alloys.This paper employs the molecular dynamics method to analyze the interaction between edge dislocations and irradiation defects(void and Ni_(3)Al precipitates)in face-centered cubic nickel.The effects of temperature and defect size on the interaction are also explored.The results show that the interaction process of the edge dislocation and irradiation defects can be divided into four stages:dislocation free slip,dislocation attracted,dislocation pinned,and dislocation unpinned.Interaction modes include the formation of stair-rod dislocations and the climbing of extended dislocation bundles for voids,as well as the generation of stair-rod dislocation and dislocation shear for precipitates.Besides,the interactions of edge dislocations with voids and Ni_(3)Al precipitates are strongly influenced by temperature and defect size.展开更多
Cement stands as a dominant contributor to global energy consumption and carbon emissions in the construction industry.With the upgrading of infrastructure and the improvement of building standards,traditional cement ...Cement stands as a dominant contributor to global energy consumption and carbon emissions in the construction industry.With the upgrading of infrastructure and the improvement of building standards,traditional cement fails to reconcile ecological responsibility with advanced functional performance.By incorporating tailored fillers into cement matrices,the resulting composites achieve enhanced thermoelectric(TE)conversion capabilities.These materials can harness solar radiation from building envelopes and recover waste heat from indoor thermal gradients,facilitating bidirectional energy conversion.This review offers a comprehensive and timely overview of cementbased thermoelectric materials(CTEMs),integrating material design,device fabrication,and diverse applications into a holistic perspective.It summarizes recent advancements in TE performance enhancement,encompassing fillers optimization and matrices innovation.Additionally,the review consolidates fabrication strategies and performance evaluations of cement-based thermoelectric devices(CTEDs),providing detailed discussions on their roles in monitoring and protection,energy harvesting,and smart building.We also address sustainability,durability,and lifecycle considerations of CTEMs,which are essential for real-world deployment.Finally,we outline future research directions in materials design,device engineering,and scalable manufacturing to foster the practical application of CTEMs in sustainable and intelligent infrastructure.展开更多
Cemented paste backfill(CPB)is a technology that achieves safe mining by filling the goaf with waste rocks,tailings,and other materials.It is an inevitable choice to deal with the development of deep and highly diffic...Cemented paste backfill(CPB)is a technology that achieves safe mining by filling the goaf with waste rocks,tailings,and other materials.It is an inevitable choice to deal with the development of deep and highly difficult mines and meet the requirements of environmental protection and safety regulations.It promotes the development of a circular economy in mines through the development of lowgrade resources and the resource utilization of waste,and extends the service life of mines.The mass concentration of solid content(abbreviated as“concentration”)is a critical parameter for CPB.However,discrepancies often arise between the on-site measurements and the pre-designed values due to factors such as groundwater inflow and segregation within the goaf,which cannot be evaluated after the solidification of CPB.This paper innovatively provides an in-situ non-destructive approach to identify the real concentration of CPB after curing for certain days using hyperspectral imaging(HSI)technology.Initially,the spectral variation patterns under different concentration conditions were investigated through hyperspectral scanning experiments on CPB samples.The results demonstrate that as the CPB concentration increases from 61wt%to 73wt%,the overall spectral reflectance gradually increases,with two distinct absorption peaks observed at 1407 and 1917 nm.Notably,the reflectance at 1407 nm exhibited a strong linear relationship with the concentration.Subsequently,the K-nearest neighbors(KNN)and support vector machine(SVM)algorithms were employed to classify and identify different concentrations.The study revealed that,with the KNN algorithm,the highest accuracy was achieved when K(number of nearest neighbors)was 1,although this resulted in overfitting.When K=3,the model displayed the optimal balance between accuracy and stability,with an accuracy of 95.03%.In the SVM algorithm,the highest accuracy of 98.24%was attained with parameters C(regularization parameter)=200 and Gamma(kernel coefficient)=10.A comparative analysis of precision,accuracy,and recall further highlighted that the SVM provided superior stability and precision for identifying CPB concentration.Thus,HSI technology offers an effective solution for the in-situ,non-destructive monitoring of CPB concentration,presenting a promising approach for optimizing and controlling CPB characteristic parameters.展开更多
To investigate the pore structure of graphene oxide modified polymer cement mortar(GOPM)under salt-freeze-thaw(SFT)coupling effects and its impact on deterioration,this study modifies polymer cement mortar(EMCM)with g...To investigate the pore structure of graphene oxide modified polymer cement mortar(GOPM)under salt-freeze-thaw(SFT)coupling effects and its impact on deterioration,this study modifies polymer cement mortar(EMCM)with graphene oxide(GO).The micro-pore structure of GOPM is characterized using LF-NMR and SEM.Fractal theory is applied to calculate the fractal dimension of pore volume,and the deterioration patterns are analyzed based on the evolution characteristics of capillary pores.The experimental results indicate that,after 25 salt-freeze-thaw cycles(SFTc),SO2-4 ions penetrate the matrix,generating corrosion products that fill existing pores and enhance the compactness of the specimen.As the number of cycles increases,the ongoing formation and expansion of corrosion products within the matrix,combined with persistent freezing forces,and result in the degradation of the pore structure.Therefore,the mass loss rate(MLR)of the specimens shows a trend of first decreasing and then increasing,while the relative dynamic elastic modulus(RDEM)initially increases and then decreases.Compared to the PC group specimens,the G3PM group specimens show a 28.71% reduction in MLR and a 31.42% increase in RDEM after 150 SFTc.The fractal dimensions of the transition pores,capillary pores,and macropores in the G3PM specimens first increase and then decrease as the number of SFTc increases.Among them,the capillary pores show the highest correlation with MLR and RDEM,with correlation coefficients of 0.97438 and 0.98555,respectively.展开更多
The utilization of discarded coral debris in cementitious material is a prominent research area for island construction projects.The aim of this study is to explore the use of environment-friendly cement and waste cor...The utilization of discarded coral debris in cementitious material is a prominent research area for island construction projects.The aim of this study is to explore the use of environment-friendly cement and waste coral sand in the preparation of coral mortar,while investigating its performance when exposed to a chloride environment.Three types of low-carbon cements were employed,such as rapid hardening sulphoaluminate(RCSA)cement,high belite sulphoaluminate(HBCSA)cement,and slag sulphoaluminate cement(SSC).The coulomb electric flux,mechanical properties,free chloride content,and mass change of the cement mortar under exposed to 3.5 wt%NaCl solution were examined at various time intervals.X-ray diffraction analysis was conducted to identify the mineral phases present in the mortar samples.The results demonstrate that the flexural and compressive strength of the mortar consistently increase throughout the 360 days chloride exposure period.Incorporating coral sand into SSC-based mortars enhances their compressive strength from day 28 up until day 360.However,it adversely affects the strength of HBCSA-based mortars.The behavior of mortars exposed to a chloride-rich environment is closely associated with the amount of C-S-H gel present within them.SSC generates a significant quantity of C-S-H gel which possesses a large specific surface area capable of absorbing more chloride ions thereby reducing their concentration within the mortar matrix as well as increasing its mass and improving resistance against chloride ion penetration.展开更多
Additive manufacturing(AM)technology has emerged as a viable solution for manufacturing complexshaped WC−Co cemented carbide products,thereby expanding their applications in industries such as resource mining,equipmen...Additive manufacturing(AM)technology has emerged as a viable solution for manufacturing complexshaped WC−Co cemented carbide products,thereby expanding their applications in industries such as resource mining,equipment manufacturing,and electronic information.This review provides a comprehensive summary of the progress of AM technology in WC−Co cemented carbides.The fundamental principles and classification of AM techniques are introduced,followed by a categorization and evaluation of the AM techniques for WC−Co cemented carbides.These techniques are classified as either direct AM technology(DAM)or indirect AM technology(IDAM),depending on their inclusion of post-processes like de-binding and sintering.Through an analysis of microstructure features,the most suitable AM route for WC−Co cemented carbide products with controllable microstructure is identified as the indirect AM technology,such as binder jet printing(BJP),which integrates AM with conventional powder metallurgy.展开更多
One of the conventional ways to improve the mechanical behavior of soils is to mix them with cementing agents such as cement, lime and fly ash. Recently, introduction to alternative materials or sub-products that can ...One of the conventional ways to improve the mechanical behavior of soils is to mix them with cementing agents such as cement, lime and fly ash. Recently, introduction to alternative materials or sub-products that can be adopted to improve the soil strength is of paramount importance. Therefore, the present study aims to investigate the effects of porosity(h), dry unit weight(gd) of molding, cement content(C)and porosity/volumetric cement content ratio(h/Civ) or void/cement ratio on the unconfined compressive strength(quor UCS) of silty soileroof tile waste(RT) mixtures. Soil samples are molded into four different dry unit weights(i.e. 13 kN/m^3, 13.67 kN/m^3, 14.33 kN/m^3 and 15 kN/m^3) using 3%, 6% and 9%cement and 5%, 15% and 30% RT. The results show that with the addition of cement, the strength of the RT esoil mixtures increases in a linear manner. On the other hand, the addition of RT decreases quof the samples at a constant percentage of cement, and the decrease in porosity can increase qu. A dosage equation is derived from the experimental data using the porosity/volumetric cement content ratio(h/C_(iv)) where the control variables are the moisture content, crushed tile content, cement content and porosity.展开更多
Underground mining always create voids.These voids can cause subsidence of surface.So it is always a demand to fill the void in such a manner that the effect of underground mining can be minimized.Void filling using m...Underground mining always create voids.These voids can cause subsidence of surface.So it is always a demand to fill the void in such a manner that the effect of underground mining can be minimized.Void filling using mill tailings especially in metal mining is one of the best techniques.The tailings produced in milling process have traditionally been disposed in tailing ponds creating a waste disposal and environmental problems in terms of land degradation,air and water pollution,etc.This disposal practice is more acute in the metal milling industry where the fine grinding,required for value liberation,results in the production of very fine tailings in large percentage.This paper includes discussions on the effectiveness of different paste mixes with varying cement contents in paste backfilling operations.The results revealed that material composition and use of super plasticizer strongly influenced the strength of cemented backfill.展开更多
This paper aims at investigating the effect of voids on the tensile properties of [（±45）4/（0,90）/（±45）2] S and [（±45）/0 4/（±45）（0,90）] S composites.Specimens with void contents in the r...This paper aims at investigating the effect of voids on the tensile properties of [（±45）4/（0,90）/（±45）2] S and [（±45）/0 4/（±45）（0,90）] S composites.Specimens with void contents in the range of 0.4% to 9.0% were fabricated from carbon/epoxy fabric.The void content was determined by ultrasonic attenuation and optical image analysis,and microscopic inspection was also used to analyze the shape and size of the voids.The influence of voids on the tensile strength and modulus of both stacking sequence is compared in terms of the size and the shape of the voids.The effect of voids on the initiation and propagation of tensile failure of both stacking sequence composite was investigated.展开更多
According to the basic idea of dual-complementarity, in a simple and unified way proposed by the author, various energy principles in theory of elastic materials with voids can be established systematically, In this p...According to the basic idea of dual-complementarity, in a simple and unified way proposed by the author, various energy principles in theory of elastic materials with voids can be established systematically, In this paper, an important integral relation is given, which can be considered essentially as the generalized pr- inciple of virtual work. Based on this relation, it is possible not only to obtain the principle of virtual work and the reciprocal theorem of work in theory of elastic materials with voids, but also to derive systematically the complementary functionals for the eight-field, six-field, four-field and two-field generalized variational principles, and the principle of minimum potential and complementary energies. Furthermore, with this appro ach, the intrinsic relationship among various principles can be explained clearly.展开更多
A mechanism of plastic how localization in ductile matter near microvoids is studied. The voids with the size-scale of micromillimeter exist in sheet specimens under tensile loading, and the plastic strain held around...A mechanism of plastic how localization in ductile matter near microvoids is studied. The voids with the size-scale of micromillimeter exist in sheet specimens under tensile loading, and the plastic strain held around voids is obtained by digital image processing of deformed grids. The size growth of the microvoids, the spacing change of the neighboring voids, and the development of shear bands in the ligament between the voids, are presented by experimental results accompanied with the plastic strain distribution, that gives good interpretation to the process of void growth and coalescence with the how localization in the ligaments.展开更多
The effects of rotation and gravity on an electro-magneto-thermoelastic medium with diffusion and voids in a generalized thermoplastic half-space are studied by using the Lord-Shulman (L-S) model and the dual-phase-la...The effects of rotation and gravity on an electro-magneto-thermoelastic medium with diffusion and voids in a generalized thermoplastic half-space are studied by using the Lord-Shulman (L-S) model and the dual-phase-lag (DPL) model. The analytical solutions for the displacements, stresses, temperature, diffusion concentration, and volume fraction field with different values of the magnetic field, the rotation, the gravity, and the initial stress are obtained and portrayed graphically. The results indicate that the effects of gravity, rotation, voids, diffusion, initial stress, and electromagnetic field are very pronounced on the physical properties of the material.展开更多
From the Boltzmann's constitutive law of viscoelastic materials and the linear theory of elastic materials with voids, a constitutive model of generalized force fields for viscoelastic solids with voids was given....From the Boltzmann's constitutive law of viscoelastic materials and the linear theory of elastic materials with voids, a constitutive model of generalized force fields for viscoelastic solids with voids was given. By using the variational integral method, the convolution-type functional was given and the corresponding generalized variational principles and potential energy principle of viscoelastic solids with voids were presented. It can be shown that the variational principles correspond to the differential equations and the initial and boundary conditions of viscoelastic body with voids. As an application, a generalized variational principle of viscoelastic Timoshenko beams with damage was obtained which corresponds to the differential equations of generalized motion and the initial and boundary conditions of beams. The variational principles provide a way for solving problems of viscoelastic solids with voids.展开更多
The distribution characteristics of air voids in ultrathin asphalt friction course(UAFC) samples with different gradations and compaction methods were statistically analyzed using X-ray computed tomography(CT) and ima...The distribution characteristics of air voids in ultrathin asphalt friction course(UAFC) samples with different gradations and compaction methods were statistically analyzed using X-ray computed tomography(CT) and image analysis techniques. Based on the results, compared with the AC-5 sample, the OGFC-5mixture has a higher air void ratio, a larger air void size and a greater number of air voids, with the distribution of internal air voids being more uniform and their shapes being more rounded. The two-parameter Weibull function was applied to fit the gradation of air voids. The fitting results is good, and the function parameters are sensitive to changes in both mineral gradation and compaction method. Moreover, two homogeneity indices were proposed to evaluate the compaction uniformity of UAFC samples. Compared with the Marshall method,the SGC method is more conducive to improve the compaction uniformity of UAFC samples. The compaction method significantly influences the air void distribution characteristics and compaction uniformity of AC-5sample, but has a less significant impact on OGFC-5 sample. The experimental results in the study provides a solid foundation for further explorations on the internal structure and mixture design of UAFC.展开更多
Often in abandoned mine sites are present both underground voids produced by mining and the tailings of treatment plant.An interesting solution for the rehabilitation of the sites would be to place the tailings of the...Often in abandoned mine sites are present both underground voids produced by mining and the tailings of treatment plant.An interesting solution for the rehabilitation of the sites would be to place the tailings of the process in the underground mining voids,thus obtaining the reclamation of surface areas and the stabilization of abandoned voids to prevent the dangerous phenomena of subsidence.However,these operations require inert waste,which must not be source of pollution,and the choice of a water/solid optimum to ensure good conditions of pumpability.展开更多
According to the basic idea of dual-complementarity,in a simple and unified way proposed by the author,some basic principles in dynamic theory of elastic materials with voids can be established sys- tematically.In thi...According to the basic idea of dual-complementarity,in a simple and unified way proposed by the author,some basic principles in dynamic theory of elastic materials with voids can be established sys- tematically.In this paper, an important integral relation in terms of convolutions is given,which can be con- sidered as the generalized principle of virtual work in mechanics.Based on this relation,it is possible not on- ly to obtain the principle of virtual work and the reciprocal theorem in dynamic theory of elastic materials with voids,but also to derive systematically the complementary functionals for the eight-field,six-field, four-field and two-field simplified Gurtin-type variational principles.Furthermore,with this approach,the in- trinsic relationship among various principles can be explained clearly.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.12232005 and 12072101).
文摘Large-grain REBa_(2)Cu_(3)O_(7-δ)(REBCO,RE=rare earth)bulk superconductors offer promising magnetic field trapping capabilities due to their high critical current density,making them ideal for many important applications such as trapped field magnets.However,for such large-grain superconductor bulks,there are lots of voids and cracks forming during the process of melting preparation,and some of them can be up to hundreds of microns or even millimeters in size.Consequently,these larger size voids/cracks pose a great threat to the strength of the bulks due to the inherent brittleness of superconductor REBCO materials.In order to ensure the operational safety of related superconducting devices with bulk superconductors,it is firstly important to accurately detect these voids/cracks in them.In this paper,we proposed a method for quantitatively evaluating multiple voids/cracks in bulk superconductors through the magnetic field and displacement response signals at superconductor bulk surface.The proposed method utilizes a damage index constructed from the magnetic field signals and displacement responses to identify the number and preliminary location of multiple defects.By dividing the detection area into subdomains and combining the magnetic field signals with displacement responses within each subdomain,a particle swarm algorithm was employed to evaluate the location and size parameters of the defects.In contrast to other evaluation methods using only magnetic field or displacement response signals,the combined evaluation method using both signals can identify the number of cracks effectively.Numerical studies demonstrate that the morphology of voids and cracks reconstructed using the proposed algorithm ideally matches real defects and is applicable to cases where voids and cracks coexist.This study provides a theoretical basis for the quantitative detection of voids/cracks in bulk superconductors.
基金the National Natural Science Foundation of China(Nos.51461135001 and 51741804)the Natural Science Foundation of Hunan Province,China(No.2017JJ2066)the Scientific Research Project of Education Department,Hunan Province,China(No.17A054)
文摘Four cellulose ethers（CEs） were compared for their effects on the pore structure of cement paste using mercury intrusion porosimetry. The experimental results show that the total pore volume and porosity of cement pastes containing the four cellulose ethers are significantly higher than that of the pure cement pastes and the total pore volume and porosity of cement pastes containing HEC（hydroxyethyl cellulose ether） or low viscosity cellulose ethers are low in four CEs. By changing the surface tension and viscosity of liquid phase and the strengthening of liquid film between air voids in cement pastes, CEs affect the formation, diameter evolution and upward movement of air voids and the pore structure of hardening cement paste. For the four CEs, the pore volume of cement pastes containing HEC or low viscosity cellulose ethers is higher with the diameter of 30-70 nm while lower with the diameter larger than 70 nm. CEs affect the pore structure of cement paste mainly through their effects on the evolvement of the small air voids into bigger ones when the pore diameter is below 70 nm and their effects on the entrainment and stabilization of air voids when the pore diameter is above 70 nm.
基金financially supported by National Natural Science Foundation of China(No.U2241223)Pre-Research Foundation of China(No.909010203-202).
文摘Nano-twinned copper(nt-Cu),with a preferred orientation,is highly promising as interconnect materials in high-density advanced packaging due to its considerable mechanical strength,excellent electrical conductivity,and resistance to thermal migration.However,its application is impeded by sulfur-containing byproducts from the electroplating process,exacerbating the formation of Kirkendall voids within solder joints during thermal aging.Herein,through the incorporation of Zinc(Zn)into the nt-Cu layer,we develop a nt-Cu/Zn composite structure.Our findings provide the first definitive confirmation of the mechanism by which sulfur atoms migrate to the Cu_(3)Sn/nt-Cu interface through interstitial diffusion,thereby reducing the activation energy for vacancy formation.We further demonstrate that Zn effectively an-choring sulfur atoms,forming ZnS within the nt-Cu layer during heat treatment,which increases the vacancy formation energy and inhibits the development of Kirkendall voids.Remarkably,no Kirkendall voids are observed in the modified interconnects even after prolonged aging at 150℃ for 1000 h.The nt-Cu/Zn composite metallization layers significantly decrease the growth rate of interfacial intermetallic compounds by 33.6% and enhance the shear strength of solder interconnections to 228.9%.This research underscores the potential of nt-Cu in advanced electronic packaging,offering new pathways for improving the power density and reliability of electronic devices.
基金financial support from the National Key Research and Development Program of China(No.2024YFB4007100)the Basic ForwardLooking Project of the Sinopec Science and Technology Department,“Research on the Long-Term Sealing Mechanism of Multi-layer Salt Cavern Hydrogen Storage”(No.P24197-4)。
文摘Renewable energy storage technologies are critical for transitioning to sustainable energy systems,with salt caverns playing a significant role in large-scale solutions.In water-soluble mining of low-grade salt formations,insoluble impurities and interlayers detach during salt dissolution and accumulate as sediment at the cavern base,thereby reducing the storage capacity and economic viability of salt cavern gas storage(SCGS).This study investigates sediment formation mechanisms,void distribution,and voidage in the Huai'an low-grade salt mine,introducing a novel self-developed physical simulation device for two butted-well horizontal(TWH)caverns that replicates compressed air injection and brine discharge.Experiments comparing“one injection and one discharge”and“two injections and one discharge”modes revealed that(1)compressed air effectively displaces brine from sediment voids,(2)a 0.5 MPa injection pressure corresponds to a 10.3 MPa operational lower limit in practice,aligning with field data,and(3)sediment voidage is approximately 46%,validated via air-brine interface theory.The“two injections and one discharge”mode outperformed in both discharge volume and rate.Additionally,a mathematical model for brine displacement via compressed air was established.These results provide foundational insights for optimizing compressed air energy storage(CAES)in low-grade salt mines,advancing their role in renewable energy integration.
基金supported by the Ministry of Industry and Information Technology of China(grant number TC220A04W-7,203)CNNC Youth Elite Scientific Research Project,the National Key R&D Plan of China(grant number 2020YFB1901600)the National Science Technology Major Project of China(grant numbers 2017ZX06902012 and 2017ZX06901024).
文摘Nickel-based alloys are the primary structural materials in steam generators of high-temperature gas reactors.To understand the irradiation effect of nickel-based alloys,it is necessary to examine dislocation movement and its interaction with irradiation defects at the microscale.Hardening due to voids and Ni_(3)Al precipitates may significantly impact irradiation damage in nickel-based alloys.This paper employs the molecular dynamics method to analyze the interaction between edge dislocations and irradiation defects(void and Ni_(3)Al precipitates)in face-centered cubic nickel.The effects of temperature and defect size on the interaction are also explored.The results show that the interaction process of the edge dislocation and irradiation defects can be divided into four stages:dislocation free slip,dislocation attracted,dislocation pinned,and dislocation unpinned.Interaction modes include the formation of stair-rod dislocations and the climbing of extended dislocation bundles for voids,as well as the generation of stair-rod dislocation and dislocation shear for precipitates.Besides,the interactions of edge dislocations with voids and Ni_(3)Al precipitates are strongly influenced by temperature and defect size.
基金supported by the National Natural Science Foundation of China(No.52242305).
文摘Cement stands as a dominant contributor to global energy consumption and carbon emissions in the construction industry.With the upgrading of infrastructure and the improvement of building standards,traditional cement fails to reconcile ecological responsibility with advanced functional performance.By incorporating tailored fillers into cement matrices,the resulting composites achieve enhanced thermoelectric(TE)conversion capabilities.These materials can harness solar radiation from building envelopes and recover waste heat from indoor thermal gradients,facilitating bidirectional energy conversion.This review offers a comprehensive and timely overview of cementbased thermoelectric materials(CTEMs),integrating material design,device fabrication,and diverse applications into a holistic perspective.It summarizes recent advancements in TE performance enhancement,encompassing fillers optimization and matrices innovation.Additionally,the review consolidates fabrication strategies and performance evaluations of cement-based thermoelectric devices(CTEDs),providing detailed discussions on their roles in monitoring and protection,energy harvesting,and smart building.We also address sustainability,durability,and lifecycle considerations of CTEMs,which are essential for real-world deployment.Finally,we outline future research directions in materials design,device engineering,and scalable manufacturing to foster the practical application of CTEMs in sustainable and intelligent infrastructure.
基金funded by the National Natural Science Foundation of China(Nos.52474165 and 52522404)。
文摘Cemented paste backfill(CPB)is a technology that achieves safe mining by filling the goaf with waste rocks,tailings,and other materials.It is an inevitable choice to deal with the development of deep and highly difficult mines and meet the requirements of environmental protection and safety regulations.It promotes the development of a circular economy in mines through the development of lowgrade resources and the resource utilization of waste,and extends the service life of mines.The mass concentration of solid content(abbreviated as“concentration”)is a critical parameter for CPB.However,discrepancies often arise between the on-site measurements and the pre-designed values due to factors such as groundwater inflow and segregation within the goaf,which cannot be evaluated after the solidification of CPB.This paper innovatively provides an in-situ non-destructive approach to identify the real concentration of CPB after curing for certain days using hyperspectral imaging(HSI)technology.Initially,the spectral variation patterns under different concentration conditions were investigated through hyperspectral scanning experiments on CPB samples.The results demonstrate that as the CPB concentration increases from 61wt%to 73wt%,the overall spectral reflectance gradually increases,with two distinct absorption peaks observed at 1407 and 1917 nm.Notably,the reflectance at 1407 nm exhibited a strong linear relationship with the concentration.Subsequently,the K-nearest neighbors(KNN)and support vector machine(SVM)algorithms were employed to classify and identify different concentrations.The study revealed that,with the KNN algorithm,the highest accuracy was achieved when K(number of nearest neighbors)was 1,although this resulted in overfitting.When K=3,the model displayed the optimal balance between accuracy and stability,with an accuracy of 95.03%.In the SVM algorithm,the highest accuracy of 98.24%was attained with parameters C(regularization parameter)=200 and Gamma(kernel coefficient)=10.A comparative analysis of precision,accuracy,and recall further highlighted that the SVM provided superior stability and precision for identifying CPB concentration.Thus,HSI technology offers an effective solution for the in-situ,non-destructive monitoring of CPB concentration,presenting a promising approach for optimizing and controlling CPB characteristic parameters.
基金Funded by the National Natural Science Foundation of China(Nos.5226804252468035)。
文摘To investigate the pore structure of graphene oxide modified polymer cement mortar(GOPM)under salt-freeze-thaw(SFT)coupling effects and its impact on deterioration,this study modifies polymer cement mortar(EMCM)with graphene oxide(GO).The micro-pore structure of GOPM is characterized using LF-NMR and SEM.Fractal theory is applied to calculate the fractal dimension of pore volume,and the deterioration patterns are analyzed based on the evolution characteristics of capillary pores.The experimental results indicate that,after 25 salt-freeze-thaw cycles(SFTc),SO2-4 ions penetrate the matrix,generating corrosion products that fill existing pores and enhance the compactness of the specimen.As the number of cycles increases,the ongoing formation and expansion of corrosion products within the matrix,combined with persistent freezing forces,and result in the degradation of the pore structure.Therefore,the mass loss rate(MLR)of the specimens shows a trend of first decreasing and then increasing,while the relative dynamic elastic modulus(RDEM)initially increases and then decreases.Compared to the PC group specimens,the G3PM group specimens show a 28.71% reduction in MLR and a 31.42% increase in RDEM after 150 SFTc.The fractal dimensions of the transition pores,capillary pores,and macropores in the G3PM specimens first increase and then decrease as the number of SFTc increases.Among them,the capillary pores show the highest correlation with MLR and RDEM,with correlation coefficients of 0.97438 and 0.98555,respectively.
基金Funded by the National Natural Science Foundation of China(No.51708290)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
文摘The utilization of discarded coral debris in cementitious material is a prominent research area for island construction projects.The aim of this study is to explore the use of environment-friendly cement and waste coral sand in the preparation of coral mortar,while investigating its performance when exposed to a chloride environment.Three types of low-carbon cements were employed,such as rapid hardening sulphoaluminate(RCSA)cement,high belite sulphoaluminate(HBCSA)cement,and slag sulphoaluminate cement(SSC).The coulomb electric flux,mechanical properties,free chloride content,and mass change of the cement mortar under exposed to 3.5 wt%NaCl solution were examined at various time intervals.X-ray diffraction analysis was conducted to identify the mineral phases present in the mortar samples.The results demonstrate that the flexural and compressive strength of the mortar consistently increase throughout the 360 days chloride exposure period.Incorporating coral sand into SSC-based mortars enhances their compressive strength from day 28 up until day 360.However,it adversely affects the strength of HBCSA-based mortars.The behavior of mortars exposed to a chloride-rich environment is closely associated with the amount of C-S-H gel present within them.SSC generates a significant quantity of C-S-H gel which possesses a large specific surface area capable of absorbing more chloride ions thereby reducing their concentration within the mortar matrix as well as increasing its mass and improving resistance against chloride ion penetration.
基金supported by Major Science and Technology Projects in Fujian Province,China(No.2023HZ021005)State Key Laboratory of Powder Metallurgy,Central South University,ChinaFujian Key Laboratory of Rare-earth Functional Materials,China。
文摘Additive manufacturing(AM)technology has emerged as a viable solution for manufacturing complexshaped WC−Co cemented carbide products,thereby expanding their applications in industries such as resource mining,equipment manufacturing,and electronic information.This review provides a comprehensive summary of the progress of AM technology in WC−Co cemented carbides.The fundamental principles and classification of AM techniques are introduced,followed by a categorization and evaluation of the AM techniques for WC−Co cemented carbides.These techniques are classified as either direct AM technology(DAM)or indirect AM technology(IDAM),depending on their inclusion of post-processes like de-binding and sintering.Through an analysis of microstructure features,the most suitable AM route for WC−Co cemented carbide products with controllable microstructure is identified as the indirect AM technology,such as binder jet printing(BJP),which integrates AM with conventional powder metallurgy.
文摘One of the conventional ways to improve the mechanical behavior of soils is to mix them with cementing agents such as cement, lime and fly ash. Recently, introduction to alternative materials or sub-products that can be adopted to improve the soil strength is of paramount importance. Therefore, the present study aims to investigate the effects of porosity(h), dry unit weight(gd) of molding, cement content(C)and porosity/volumetric cement content ratio(h/Civ) or void/cement ratio on the unconfined compressive strength(quor UCS) of silty soileroof tile waste(RT) mixtures. Soil samples are molded into four different dry unit weights(i.e. 13 kN/m^3, 13.67 kN/m^3, 14.33 kN/m^3 and 15 kN/m^3) using 3%, 6% and 9%cement and 5%, 15% and 30% RT. The results show that with the addition of cement, the strength of the RT esoil mixtures increases in a linear manner. On the other hand, the addition of RT decreases quof the samples at a constant percentage of cement, and the decrease in porosity can increase qu. A dosage equation is derived from the experimental data using the porosity/volumetric cement content ratio(h/C_(iv)) where the control variables are the moisture content, crushed tile content, cement content and porosity.
文摘Underground mining always create voids.These voids can cause subsidence of surface.So it is always a demand to fill the void in such a manner that the effect of underground mining can be minimized.Void filling using mill tailings especially in metal mining is one of the best techniques.The tailings produced in milling process have traditionally been disposed in tailing ponds creating a waste disposal and environmental problems in terms of land degradation,air and water pollution,etc.This disposal practice is more acute in the metal milling industry where the fine grinding,required for value liberation,results in the production of very fine tailings in large percentage.This paper includes discussions on the effectiveness of different paste mixes with varying cement contents in paste backfilling operations.The results revealed that material composition and use of super plasticizer strongly influenced the strength of cemented backfill.
文摘This paper aims at investigating the effect of voids on the tensile properties of [（±45）4/（0,90）/（±45）2] S and [（±45）/0 4/（±45）（0,90）] S composites.Specimens with void contents in the range of 0.4% to 9.0% were fabricated from carbon/epoxy fabric.The void content was determined by ultrasonic attenuation and optical image analysis,and microscopic inspection was also used to analyze the shape and size of the voids.The influence of voids on the tensile strength and modulus of both stacking sequence is compared in terms of the size and the shape of the voids.The effect of voids on the initiation and propagation of tensile failure of both stacking sequence composite was investigated.
基金The project supported by the National Natural Science Foundation of China
文摘According to the basic idea of dual-complementarity, in a simple and unified way proposed by the author, various energy principles in theory of elastic materials with voids can be established systematically, In this paper, an important integral relation is given, which can be considered essentially as the generalized pr- inciple of virtual work. Based on this relation, it is possible not only to obtain the principle of virtual work and the reciprocal theorem of work in theory of elastic materials with voids, but also to derive systematically the complementary functionals for the eight-field, six-field, four-field and two-field generalized variational principles, and the principle of minimum potential and complementary energies. Furthermore, with this appro ach, the intrinsic relationship among various principles can be explained clearly.
基金The project supported by the National Natural Science Foundation of China
文摘A mechanism of plastic how localization in ductile matter near microvoids is studied. The voids with the size-scale of micromillimeter exist in sheet specimens under tensile loading, and the plastic strain held around voids is obtained by digital image processing of deformed grids. The size growth of the microvoids, the spacing change of the neighboring voids, and the development of shear bands in the ligament between the voids, are presented by experimental results accompanied with the plastic strain distribution, that gives good interpretation to the process of void growth and coalescence with the how localization in the ligaments.
文摘The effects of rotation and gravity on an electro-magneto-thermoelastic medium with diffusion and voids in a generalized thermoplastic half-space are studied by using the Lord-Shulman (L-S) model and the dual-phase-lag (DPL) model. The analytical solutions for the displacements, stresses, temperature, diffusion concentration, and volume fraction field with different values of the magnetic field, the rotation, the gravity, and the initial stress are obtained and portrayed graphically. The results indicate that the effects of gravity, rotation, voids, diffusion, initial stress, and electromagnetic field are very pronounced on the physical properties of the material.
文摘From the Boltzmann's constitutive law of viscoelastic materials and the linear theory of elastic materials with voids, a constitutive model of generalized force fields for viscoelastic solids with voids was given. By using the variational integral method, the convolution-type functional was given and the corresponding generalized variational principles and potential energy principle of viscoelastic solids with voids were presented. It can be shown that the variational principles correspond to the differential equations and the initial and boundary conditions of viscoelastic body with voids. As an application, a generalized variational principle of viscoelastic Timoshenko beams with damage was obtained which corresponds to the differential equations of generalized motion and the initial and boundary conditions of beams. The variational principles provide a way for solving problems of viscoelastic solids with voids.
基金Funded by Technology Innovation Demonstration Project of the Transportation Department of Yunnan Province (Science and Technology Education Section of Transport Department of Yunnan Province [2019](No.14)。
文摘The distribution characteristics of air voids in ultrathin asphalt friction course(UAFC) samples with different gradations and compaction methods were statistically analyzed using X-ray computed tomography(CT) and image analysis techniques. Based on the results, compared with the AC-5 sample, the OGFC-5mixture has a higher air void ratio, a larger air void size and a greater number of air voids, with the distribution of internal air voids being more uniform and their shapes being more rounded. The two-parameter Weibull function was applied to fit the gradation of air voids. The fitting results is good, and the function parameters are sensitive to changes in both mineral gradation and compaction method. Moreover, two homogeneity indices were proposed to evaluate the compaction uniformity of UAFC samples. Compared with the Marshall method,the SGC method is more conducive to improve the compaction uniformity of UAFC samples. The compaction method significantly influences the air void distribution characteristics and compaction uniformity of AC-5sample, but has a less significant impact on OGFC-5 sample. The experimental results in the study provides a solid foundation for further explorations on the internal structure and mixture design of UAFC.
文摘Often in abandoned mine sites are present both underground voids produced by mining and the tailings of treatment plant.An interesting solution for the rehabilitation of the sites would be to place the tailings of the process in the underground mining voids,thus obtaining the reclamation of surface areas and the stabilization of abandoned voids to prevent the dangerous phenomena of subsidence.However,these operations require inert waste,which must not be source of pollution,and the choice of a water/solid optimum to ensure good conditions of pumpability.
基金The project supported by the Foundation of Zhongshan University Advanced Research Center
文摘According to the basic idea of dual-complementarity,in a simple and unified way proposed by the author,some basic principles in dynamic theory of elastic materials with voids can be established sys- tematically.In this paper, an important integral relation in terms of convolutions is given,which can be con- sidered as the generalized principle of virtual work in mechanics.Based on this relation,it is possible not on- ly to obtain the principle of virtual work and the reciprocal theorem in dynamic theory of elastic materials with voids,but also to derive systematically the complementary functionals for the eight-field,six-field, four-field and two-field simplified Gurtin-type variational principles.Furthermore,with this approach,the in- trinsic relationship among various principles can be explained clearly.
