Based on Hamilton’s principle, the differential equations of free vibration of track-bridge systems with mortar gap are derived. Hence, a method for calculating the natural frequencies of track-bridge systems is prop...Based on Hamilton’s principle, the differential equations of free vibration of track-bridge systems with mortar gap are derived. Hence, a method for calculating the natural frequencies of track-bridge systems is proposed. The influence of the flexural stiffness of the track-bridge system, the vertical and longitudinal stiffness of the mortar layer,gap position and gap length on the natural frequencies of a track-bridge system is discussed. The results show that the natural frequencies of the track-bridge system are more sensitive to the change of the flexural stiffness of the bridge layer. The change of the longitudinal stiffness of the mortar layer and gap position has no obvious effect on the trackbridge system’s natural frequencies, while the interlayer vertical stiffness has a larger impact. The gap length has a more significant effect on the 4th-5th order natural frequencies of the track-bridge system. The range of the natural frequencies that are affected by the gap widens as the gap length increases.展开更多
The parameter diversity effect in coupled nonidentical elements has attracted persistent interest in nonlinear dynamics. Of fundamental importance is the so-called optimal configuration problem for how the spatial pos...The parameter diversity effect in coupled nonidentical elements has attracted persistent interest in nonlinear dynamics. Of fundamental importance is the so-called optimal configuration problem for how the spatial position of elements with different parameters precisely determines the dynamics of the whole system. In this work, we study the optimal configuration problem for the vibration spectra in the classical mass-spring model with a ring configuration, paying particular attention to how the configuration of different masses affects the second smallest vibration frequency （ω2） and the largest one （ωN）. For the extreme values of ω2 and ωN, namely, （ω2）min, （ω2）max, （ωN）min, and （ωN）max, we find some explicit organization rules for the optimal configurations and some approximation rules when the explicit organization rules are not available. The different distributions of ω2 and ωN are compared. These findings are interesting and valuable for uncovering the underlying mechanism of the parameter diversity effect in more general cases.展开更多
The dissociation limits of isotopic water molecules are derived for the ground state. The equilibrium geometries, the vibrational frequencies, the force constants and the dissociation energies for the ground states of...The dissociation limits of isotopic water molecules are derived for the ground state. The equilibrium geometries, the vibrational frequencies, the force constants and the dissociation energies for the ground states of all isotopic water molecules under the dipole electric fields from -0.05 a.u. to 0.05 a.u. are calculated using B3P86/6-311＋＋G（3df,3pf）. The results show that when the dipole electric fields change from -0.05 a.u. to 0.05 a.u., the bond length of H-O increases whereas the bond angle of H-O H decreases because of the charge transfer induced by the applied dipole electric field. The vibrational frequencies and the force constants of isotopic water molecules change under the influence of the strong external torque. The dissociation energies increase when the dipole electric fields change from -0.05 a.u. to 0.05 a.u. and the increased dissociation energies are in the order of H2O, HDO, HTO, D2O, DTO, and T2O under the same external electric fields.展开更多
The molecular structures,electron affinities,vibrational frequencies and IR intensities of the SF5OX/SF5OX-（X=F,Cl,Br）species have been determined by four different density functional theory（DFT）methods（B3LYP,BHL...The molecular structures,electron affinities,vibrational frequencies and IR intensities of the SF5OX/SF5OX-（X=F,Cl,Br）species have been determined by four different density functional theory（DFT）methods（B3LYP,BHLYP,BP86,BLYP）in conjunction with DZP＋＋ basis set.The BHLYP method predicts the best geometry parameters.The adiabatic electron affinities（EAad）predicted by the B3LYP/DZP＋＋ method are 4.36 eV（SF5OF）,4.13 eV（SF5OCl）,4.12 eV（SF5OBr）,respectively.Large electron affinity implies the corresponding anions are stable.The total intensities in the near IR ＂window＂ of the anions SF5OX-（X=F,Cl,Br）at B3LYP level are 1 602 km/mol（SF5OF-）,1 868 km/mol（SF5OCl-）and 1 916 km/mol（SF5OBr-）,respectively,larger than those of the corresponding neutrals.It suggests that SF5OX/SF5OX-（X=F,Cl,Br）may be used to ＂warm＂ Mars.展开更多
Purpose–This paper aims to analyze the transverse vibration characteristics of the high speed train window glass when passing through tunnel.Design/methodology/approach–The lateral vibration acceleration response of...Purpose–This paper aims to analyze the transverse vibration characteristics of the high speed train window glass when passing through tunnel.Design/methodology/approach–The lateral vibration acceleration response of glass chamber of high-speed train CR400BF-A on Beijing-Chengdu high-speed railway was tested at different speeds through the tunnel entrance,exit,tunnel interior,Tunnel Group and rendezvous time in the tunnel,the lateral distribution characteristics of vibration frequency and vibration power amplification coefficient of glass of high-speed train were analyzed.Findings–The results show that:The vibration of the high-speed train glass increases significantly during the tunnel,and the amplitude of vibration acceleration in the tunnel is significantly higher than outside the tunnel as the travel speed increases;the amplitude of lateral vibration acceleration of the glass of a high-speed train does not vary with changes in tunnel length and is not affected by the aerodynamic effects of the tunnel when traveling inside the tunnel,but its vibrations create noticeable fluctuations during variations when encountering oncoming traffic;The vibration characteristics of the high-speed train glass are forced harmonic vibrations,the excitation frequency does not vary with travel speed and travel position changes inside and outside the tunnel.The lateral vibration acceleration of the glass of a high-speed train is applied vertically and uniformly to the glass surface as an“inertial force”and creates a cyclic bending vibration stress that can easily lead to fatigue damage.Originality/value–The research results provide guidance for the prevention of glass failure in high-speed trains.展开更多
Potential energy surfaces(PESs), vibrational frequencies, and infrared spectra are calculated for NF_(3)^(+) using ab initio calculations, based on UCCSD(T)/cc-p VTZ combined with vibrational configuration interaction...Potential energy surfaces(PESs), vibrational frequencies, and infrared spectra are calculated for NF_(3)^(+) using ab initio calculations, based on UCCSD(T)/cc-p VTZ combined with vibrational configuration interaction(VCI). Based on an iterative algorithm, the surfaces(SURF) program adds automatic points to the lattice representation of the potential function, the one-dimensional and two-dimensional PESs are calculated after reaching a convergence threshold, finally the smooth image of the potential energy surface is fitted. The PESs accurately account for the interaction between the different modes, with the mode q_(6) symmetrical stretching vibrations having the greatest effect on the potential energy change of the whole system throughout the potential energy surface shift. The anharmonic frequencies are obtained when the VCI matrix is diagonalized. Fundamental frequencies, overtones, and combination bands of NF_(3)^(+) are calculated, which generate the degenerate phenomenon between their frequencies. Finally, the calculated anharmonic frequency is used to plot the infrared spectra.Modal antisymmetric stretching ν_(5) and symmetric stretching ν_(6) exhibit a phenomenon of large-intensity borrowing. This study can provide data to support the characterization in the laboratory.展开更多
Cell membranes play a crucial role in many biological functions of cells. A small change in the composition of cell membranes can strongly influence the functions of membrane-associated proteins, such as ion and water...Cell membranes play a crucial role in many biological functions of cells. A small change in the composition of cell membranes can strongly influence the functions of membrane-associated proteins, such as ion and water channels, and thus mediate the chemical and physical balance in cells. Such composition change could originate from the introduction of short-chain alcohols, or other anesthetics into membranes. In this work, we have applied sum frequency generation vibrational spectroscopy （SFG-VS）, supplemented by attenuated total reflectance Fourier transform infrared spectroscopy （ATR-FTIR）, to investigate interaction between methanol and 1,2-dimyristoyl-d54-sn-glycero-3-phosphocholine （d54-DMPC） lipid bilayers. Lipid＇s hydrocarbon interior is deuterated while its head group is hydrogenated. At the same time, CH3 symmetric stretch from methanol and lipid head amine group has different frequency, thus we can distinguish the behaviors of methanol, lipid head amine group, and lipid hydrocarbon interior. Based on the spectral feature of the bending mode of the water molecules replaced by methanol, we determined that the methanol molecules are intercalated into the region between amine and phosphate groups at the lipid hydrophilic head. The dipole of CH3 groups of methanol and lipid head, and the water O-H M1 adopt the same orientation directions. The introduction of methanol into the lipid hydrophilic head group can strongly perturb the entire length of the alkyl chains, resulting that the signals of CD2 and CD3 groups from both leaflets can not cancel each other.展开更多
Blast-induced dominant vibration frequency （DVF） involves a complex, nonlinear and small sample system considering rock properties, blasting parameters and topography. In this study, a combination of grey relational...Blast-induced dominant vibration frequency （DVF） involves a complex, nonlinear and small sample system considering rock properties, blasting parameters and topography. In this study, a combination of grey relational analysis and dimensional analysis procedures for prediction of dominant vibration frequency are presented. Six factors are selected from extensive effect factor sequences based on grey relational analysis, and then a novel blast-induced dominant vibration frequency prediction is obtained by dimensional analysis. In addition, the prediction is simplified by sensitivity analysis with 195 experimental blast records. Validation is carried out for the proposed formula based on the site test database of the first- period blasting excavation in the Guangdong Lufeng Nuclear Power Plant （GLNPP）. The results show the proposed approach has a higher fitting degree and smaller mean error when compared with traditional predictions.展开更多
The properties of gray cast iron(GCI)are affected by density of matrix,size of flake graphite and primary austenite.In this paper,the Y-type specimen of GCI was prepared by lost foam casting(LFC)with and without vibra...The properties of gray cast iron(GCI)are affected by density of matrix,size of flake graphite and primary austenite.In this paper,the Y-type specimen of GCI was prepared by lost foam casting(LFC)with and without vibration,and the influence of vibration frequency on the density of matrix,size of primary phase,and properties of the GCI was studied.The results show that the length of the flake graphite and the size of the primary austenite in GCI firstly decrease and then increase with the increase of the vibration frequency.With a vibration frequency of 35 Hz,the length of the flake graphite is the shortest,the primary austenite is the finest and the density of the matrix is the highest.In addition,the tensile strength,elongation and hardness of the GCI firstly increase and then decrease with the increase of the vibration frequency,due to the refinement of the primary phase and the increase of the matrix density.In order to analyze the refinement mechanism of the primary phase of the GCI fabricated by the LFC with vibration,the solidification temperature fields of the GCI fabricated by the LFC with the vibration frequency of 0 and 35 Hz were measured.The results show that the vibration reduces the eutectic point of the GCI and increases the supercooling degree during the eutectic transformation.As a result,the length of the flake graphite and the size of the primary austenite in GCI fabricated by LFC with the vibration frequency of 35 Hz decrease.展开更多
A broadband infrared surface sum frequency generation vibrational spectroscopy （SFG-VS） and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact h...A broadband infrared surface sum frequency generation vibrational spectroscopy （SFG-VS） and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact high vacuum cell, organic contaminants on TiO2 thin film surface prepared by RF magnetron sputtering were in situ removed under 266 nm irradiation in 10 kPa 02 atmosphere. We obtained the methanol spectrum in the CH3 stretching vibration region on TiO2 surface with changing the methanol pressure at room temperature. Features of both molecular and dissociative methanol, methoxy, adsorbed on this surface were resolved. The CH3 symmetric stretching vibration frequency and Fermi resonance of molecular methanol is red-shifted by about 6-8 cm-1 from low to high coverage. Moreover, the recombination of dissociative methanol and H on Surfaces in vacuum was also observed. Our results suggest two equilibria exist： between molecular methanol in the gas phase and that on surfaces, and between molecular methanol and dissociative methanol on surfaces.展开更多
Purpose:The purpose of this study was to compare the effects of an 8-week whole-body vibration training program in various frequency and amplitude settings under the same acceleration on the strength and power of the ...Purpose:The purpose of this study was to compare the effects of an 8-week whole-body vibration training program in various frequency and amplitude settings under the same acceleration on the strength and power of the knee extensors.Methods:Sixty-four young participants were randomly assigned to 1 of 4 groups with the same acceleration(4 g):high frequency and low amplitude(n = 16,32 Hz,1 mm) group,medium frequency and medium amplitude(n = 16,18 Hz,3 mm) group,low frequency and high amplitude(n = 16,3 Hz,114 mm) group,and control(n = 16,no vibration) group.All participants underwent 8 weeks of training with body mass dynamic squats,3 sessions a week.Results:The results showed that the high frequency and low amplitude group increased significantly in isometric contraction strength and 120°/s isokinetic concentric contraction strength;the medium frequency and medium amplitude group increased significantly in 60°/s and 120°/s isokinetic strength of both concentric and eccentric contraction;and the low frequency and high amplitude group increased significantly in 60°/s and 120°/s isokinetic eccentric contraction strength.Conclusion:All frequency and amplitude settings in the 8-week whole-body vibration training increased muscle strength,but different settings resulted in various neuromuscular adaptations despite the same intensity.展开更多
Quasi-ultrasonic vibration with a frequency of 15 kHz and a maximum output of 2 kW was imposed on the deep drawing process of AZ31 magnesium alloy sheet at room temperature,in order to reveal the effect of high freque...Quasi-ultrasonic vibration with a frequency of 15 kHz and a maximum output of 2 kW was imposed on the deep drawing process of AZ31 magnesium alloy sheet at room temperature,in order to reveal the effect of high frequency vibration on deformation behavior of AZ31 during the process.From the drawn results and the observation of the microstructure within the large deformation area,high frequency vibration has a great influence on the formability,the forming load and the failure mode of AZ31 sheet during the deep drawing process;the influence is a comprehensive result of so-called "volume effect" and "surface effect",and relies on the vibrating amplitude.Total forming load decreased significantly as soon as the vibration superimposed.According to the tensile test results of AZ31 bars under ultrasonic vibration,the formability of AZ31 sheet increases firstly with the increase of stimulating energy,then decreases and finally becomes brittle.Under the combined influence of "surface effect" and the "softening" in the "volume effect" near the relative low amplitude of 25%A in the experiment(A is the maximum amplitude),the formability of AZ31 reaches the largest value,and the samples possess the same distribution trend of cracks as those added with lubricating oil.With the increase of excitation energy,the "volume effect" gradually becomes apparent,and finally the "hardening" of the "volume effect" occupies a dominant position.展开更多
The effects of tension on vortex-induced vibration (VIV) responses for a tension-dominated long cylinder with an aspect ratio of 550 in uniform flows are experimentally investigated in this paper. The results show tha...The effects of tension on vortex-induced vibration (VIV) responses for a tension-dominated long cylinder with an aspect ratio of 550 in uniform flows are experimentally investigated in this paper. The results show that elevated tension suppresses fluctuations of maximum displacement with respect to flow velocity and makes chaotic VIV more likely to appear. With respect to periodic VIV, if elevated tension is applied, the dominant vibration frequency in the in-line (IL) direction will switch from a fundamental vibration frequency to twice the value of the fundamental vibration frequency, which results in a ratio of the dominant vibration frequency in the IL direction to that in the cross-flow direction of 2.0. The suppression of the elevated tension in the fluctuation of the maximum displacement causes the axial tension to become an active control parameter for the VIV maximum displacement of a tension-dominated long riser or tether of an engineering structure in deep oceans. However, the axial tension must be optimized before being used since the high dominant vibration frequency due to the elevated tension may unfavorably affect the fatigue life of the riser or tether.展开更多
Low frequency vibrations induced by underground railways have attracted increasing attention in recent years. To obtain the characteristics of low frequency vibrations and the low frequency performance of a floating s...Low frequency vibrations induced by underground railways have attracted increasing attention in recent years. To obtain the characteristics of low frequency vibrations and the low frequency performance of a floating slab track (FST), low frequency vibration tests on an FST in an underground laboratory at Beijing Jiaotong University were carried out. The FST and an unbalanced shaker SBZ30 for dynamic simulation were designed for use in low frequency vibration experiments. Vibration measurements were performed on the bogie of the unbalanced shaker, the rail, the slab, the tunnel invert, the tunnel wall, the tunnel apex, and on the ground surface at distances varying from 0 to 80 m from the track. Measurements were also made on several floors of an adjacent building. Detailed results of low frequency vibration tests were reported. The attenuation of low frequency vibrations with the distance from the track was presented, as well as the responses of different floors of the building. The experimental results could be regarded as a reference for developing methods to control low frequency vibrations and for adopting countermeasures.展开更多
Human motion induced vibration has very low frequency,ranging from 2 Hz to 5 Hz.Traditional vibration isolators are not effective in low-frequency regions due to the trade-off between the low natural frequency and the...Human motion induced vibration has very low frequency,ranging from 2 Hz to 5 Hz.Traditional vibration isolators are not effective in low-frequency regions due to the trade-off between the low natural frequency and the high load capacity.In this paper,inspired by the human spine,we propose a novel bionic human spine inspired quasi-zero stiffness(QZS)vibration isolator which consists of a cascaded multi-stage negative stiffness structure.The force and stiffness characteristics are investigated first,the dynamic model is established by Newton’s second law,and the isolation performance is analyzed by the harmonic balance method(HBM).Numerical results show that the bionic isolator can obtain better low-frequency isolation performance by increasing the number of negative structure stages,and reducing the damping values and external force values can obtain better low-frequency isolation performance.In comparison with the linear structure and existing traditional QZS isolator,the bionic spine isolator has better vibration isolation performance in low-frequency regions.It paves the way for the design of bionic ultra-low-frequency isolators and shows potential in many engineering applications.展开更多
Characterization of real-time and ultrafast motions of the complex molecules at surface and interface is critical to understand how interracial molecules function. It requires to develop surface-sensitive, fast-identi...Characterization of real-time and ultrafast motions of the complex molecules at surface and interface is critical to understand how interracial molecules function. It requires to develop surface-sensitive, fast-identification, and time-resolved techniques. In this study, we employ several key technical procedures and successfully develop a highly sensitive femtosecond time-resolved sum frequency generation vibrational spectroscopy （SFG-VS） system. This system is able to measure the spectra with two polarization combinations （ssp and ppp, or psp and ssp） simultaneously. It takes less than several seconds to collect one spectrum. To the best of our knowledge, it is the fastest speed of collecting SFG spectra reported by now. Using the time-resolved measurement, ultrafast vibrational dynamics of the N-H mode of α-helical peptide at water interface is determined. It is found that the membrane environment does not affect the N-H vibrational relaxation dynamics. It is expected that the time-resolved SFG system will play a vital role in the deep understanding of the dynamics and interaction of the complex molecules at surface and interface. Our method may also provide an important technical proposal for the people who plan to develop time-resolved SFG systems with simultaneous measurement of multiple polarization combinations.展开更多
In view of the influence and harm of low frequency vibration environment on the structure of spaceflight products,a low frequency dynamic study method for piezoelectric sensor based on the dynamic system of sinusoidal...In view of the influence and harm of low frequency vibration environment on the structure of spaceflight products,a low frequency dynamic study method for piezoelectric sensor based on the dynamic system of sinusoidal pressure is proposed.This method uses a sinusoidal pressure dynamic system with two-way dual channel import and export synchronization technology to study the low frequency characteristics of a piezoelectric sensor of PCB company,and its lower cut-off frequency is 0.26 Hz.It is also studied that when the frequency of the measured vibration or shock signal is 1-200 kHz,the error range of signal positive pressure action time is 4.87%-0.03%.The dynamic compensation for the low frequency of the vibration sensor is carried out,and the compensation effect is good.展开更多
Molecular structure, vibrational frequency and infrared intensity of UF6 are investigated by using the revised Perdew Burke-Enzerhof function with the triple-zeta polarized basis set. The calculation results are in go...Molecular structure, vibrational frequency and infrared intensity of UF6 are investigated by using the revised Perdew Burke-Enzerhof function with the triple-zeta polarized basis set. The calculation results are in good agreement with the experimental values and indicate the existence of a stable U2F6 molecule with a multiple bonded U2 unit. The calculation results also predict that the D3d symmetry of U2F6 is more stable than D3h. The optimized geometries, vibrational frequencies, and infrared intensities are also reported for U2F6 molecules in D3d symmetry. In addition, the isotopic shift of vibrational frequencies of the two molecules under isotopic substitution of uranium atom are also investigated with the same method. The U2F6 molecule is predicted to be better than UF6 for laser uranic isotope separation.展开更多
Ultrahigh resolution synthetic aperture radar(SAR)imaging for ship targets is significant in SAR imaging,but it suffers from high frequency vibration of the platform,which will induce defocus into SAR imaging results....Ultrahigh resolution synthetic aperture radar(SAR)imaging for ship targets is significant in SAR imaging,but it suffers from high frequency vibration of the platform,which will induce defocus into SAR imaging results.In this paper,a novel compensation method based on the sinusoidal frequency modulation Fourier-Bessel transform(SFMFBT)is proposed,it can estimate the vibration errors,and the phase shift ambiguity can be avoided via extracting the time frequency ridge consequently.By constructing the corresponding compensation function and combined with the inverse SAR(ISAR)technique,well-focused imaging results can be obtained.The simulation imaging results of ship targets demonstrate the validity of the proposed approach.展开更多
The laws that natural frequencies of rectangular plate with a cutout will change with size and position of cutout are obtained by analytic, numerical and experimental methods.
基金Projects(U1934207,52078487,51778630) supported by the National Natural Science Foundation of ChinaProject(502501006) supported by the Fundamental Research Funds for the Central Universities,China+1 种基金Project(2019RS3009)supported by the Hunan Innovative Provincial Construction Project,ChinaProjects(HJGZ20211003,HJGZ20212009)supported by State Key Laboratory of Performance Monitoring and Protecting of Rail Transit Infrastructure,China。
文摘Based on Hamilton’s principle, the differential equations of free vibration of track-bridge systems with mortar gap are derived. Hence, a method for calculating the natural frequencies of track-bridge systems is proposed. The influence of the flexural stiffness of the track-bridge system, the vertical and longitudinal stiffness of the mortar layer,gap position and gap length on the natural frequencies of a track-bridge system is discussed. The results show that the natural frequencies of the track-bridge system are more sensitive to the change of the flexural stiffness of the bridge layer. The change of the longitudinal stiffness of the mortar layer and gap position has no obvious effect on the trackbridge system’s natural frequencies, while the interlayer vertical stiffness has a larger impact. The gap length has a more significant effect on the 4th-5th order natural frequencies of the track-bridge system. The range of the natural frequencies that are affected by the gap widens as the gap length increases.
基金Acknowledgements This work was supported by the National Natural Science Foundation of China under Grant Nos. 11075202 and 11475253.
文摘The parameter diversity effect in coupled nonidentical elements has attracted persistent interest in nonlinear dynamics. Of fundamental importance is the so-called optimal configuration problem for how the spatial position of elements with different parameters precisely determines the dynamics of the whole system. In this work, we study the optimal configuration problem for the vibration spectra in the classical mass-spring model with a ring configuration, paying particular attention to how the configuration of different masses affects the second smallest vibration frequency （ω2） and the largest one （ωN）. For the extreme values of ω2 and ωN, namely, （ω2）min, （ω2）max, （ωN）min, and （ωN）max, we find some explicit organization rules for the optimal configurations and some approximation rules when the explicit organization rules are not available. The different distributions of ω2 and ωN are compared. These findings are interesting and valuable for uncovering the underlying mechanism of the parameter diversity effect in more general cases.
基金Project supported by the National Natural Science Foundation of China (Grant No. 10676022)
文摘The dissociation limits of isotopic water molecules are derived for the ground state. The equilibrium geometries, the vibrational frequencies, the force constants and the dissociation energies for the ground states of all isotopic water molecules under the dipole electric fields from -0.05 a.u. to 0.05 a.u. are calculated using B3P86/6-311＋＋G（3df,3pf）. The results show that when the dipole electric fields change from -0.05 a.u. to 0.05 a.u., the bond length of H-O increases whereas the bond angle of H-O H decreases because of the charge transfer induced by the applied dipole electric field. The vibrational frequencies and the force constants of isotopic water molecules change under the influence of the strong external torque. The dissociation energies increase when the dipole electric fields change from -0.05 a.u. to 0.05 a.u. and the increased dissociation energies are in the order of H2O, HDO, HTO, D2O, DTO, and T2O under the same external electric fields.
基金Sponsored by the National Natural Science Foundation of China(20773014)the "111" Project of China(B07012)
文摘The molecular structures,electron affinities,vibrational frequencies and IR intensities of the SF5OX/SF5OX-（X=F,Cl,Br）species have been determined by four different density functional theory（DFT）methods（B3LYP,BHLYP,BP86,BLYP）in conjunction with DZP＋＋ basis set.The BHLYP method predicts the best geometry parameters.The adiabatic electron affinities（EAad）predicted by the B3LYP/DZP＋＋ method are 4.36 eV（SF5OF）,4.13 eV（SF5OCl）,4.12 eV（SF5OBr）,respectively.Large electron affinity implies the corresponding anions are stable.The total intensities in the near IR ＂window＂ of the anions SF5OX-（X=F,Cl,Br）at B3LYP level are 1 602 km/mol（SF5OF-）,1 868 km/mol（SF5OCl-）and 1 916 km/mol（SF5OBr-）,respectively,larger than those of the corresponding neutrals.It suggests that SF5OX/SF5OX-（X=F,Cl,Br）may be used to ＂warm＂ Mars.
基金supported by grants from the National Key Research and Development Program(Grant Nos.2023YFC3806205).
文摘Purpose–This paper aims to analyze the transverse vibration characteristics of the high speed train window glass when passing through tunnel.Design/methodology/approach–The lateral vibration acceleration response of glass chamber of high-speed train CR400BF-A on Beijing-Chengdu high-speed railway was tested at different speeds through the tunnel entrance,exit,tunnel interior,Tunnel Group and rendezvous time in the tunnel,the lateral distribution characteristics of vibration frequency and vibration power amplification coefficient of glass of high-speed train were analyzed.Findings–The results show that:The vibration of the high-speed train glass increases significantly during the tunnel,and the amplitude of vibration acceleration in the tunnel is significantly higher than outside the tunnel as the travel speed increases;the amplitude of lateral vibration acceleration of the glass of a high-speed train does not vary with changes in tunnel length and is not affected by the aerodynamic effects of the tunnel when traveling inside the tunnel,but its vibrations create noticeable fluctuations during variations when encountering oncoming traffic;The vibration characteristics of the high-speed train glass are forced harmonic vibrations,the excitation frequency does not vary with travel speed and travel position changes inside and outside the tunnel.The lateral vibration acceleration of the glass of a high-speed train is applied vertically and uniformly to the glass surface as an“inertial force”and creates a cyclic bending vibration stress that can easily lead to fatigue damage.Originality/value–The research results provide guidance for the prevention of glass failure in high-speed trains.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.52002318 and 22103061)。
文摘Potential energy surfaces(PESs), vibrational frequencies, and infrared spectra are calculated for NF_(3)^(+) using ab initio calculations, based on UCCSD(T)/cc-p VTZ combined with vibrational configuration interaction(VCI). Based on an iterative algorithm, the surfaces(SURF) program adds automatic points to the lattice representation of the potential function, the one-dimensional and two-dimensional PESs are calculated after reaching a convergence threshold, finally the smooth image of the potential energy surface is fitted. The PESs accurately account for the interaction between the different modes, with the mode q_(6) symmetrical stretching vibrations having the greatest effect on the potential energy change of the whole system throughout the potential energy surface shift. The anharmonic frequencies are obtained when the VCI matrix is diagonalized. Fundamental frequencies, overtones, and combination bands of NF_(3)^(+) are calculated, which generate the degenerate phenomenon between their frequencies. Finally, the calculated anharmonic frequency is used to plot the infrared spectra.Modal antisymmetric stretching ν_(5) and symmetric stretching ν_(6) exhibit a phenomenon of large-intensity borrowing. This study can provide data to support the characterization in the laboratory.
文摘Cell membranes play a crucial role in many biological functions of cells. A small change in the composition of cell membranes can strongly influence the functions of membrane-associated proteins, such as ion and water channels, and thus mediate the chemical and physical balance in cells. Such composition change could originate from the introduction of short-chain alcohols, or other anesthetics into membranes. In this work, we have applied sum frequency generation vibrational spectroscopy （SFG-VS）, supplemented by attenuated total reflectance Fourier transform infrared spectroscopy （ATR-FTIR）, to investigate interaction between methanol and 1,2-dimyristoyl-d54-sn-glycero-3-phosphocholine （d54-DMPC） lipid bilayers. Lipid＇s hydrocarbon interior is deuterated while its head group is hydrogenated. At the same time, CH3 symmetric stretch from methanol and lipid head amine group has different frequency, thus we can distinguish the behaviors of methanol, lipid head amine group, and lipid hydrocarbon interior. Based on the spectral feature of the bending mode of the water molecules replaced by methanol, we determined that the methanol molecules are intercalated into the region between amine and phosphate groups at the lipid hydrophilic head. The dipole of CH3 groups of methanol and lipid head, and the water O-H M1 adopt the same orientation directions. The introduction of methanol into the lipid hydrophilic head group can strongly perturb the entire length of the alkyl chains, resulting that the signals of CD2 and CD3 groups from both leaflets can not cancel each other.
基金National Natural Science Funds for Distinguished Young Scholar under Grant No.51009086Hubei Key Laboratory of Roadway Bridge and Structure Engineering under Grant No.DQJJ201313Major State Basic Research Development Program of China(973 Program)under Grant No.2010CB732001
文摘Blast-induced dominant vibration frequency （DVF） involves a complex, nonlinear and small sample system considering rock properties, blasting parameters and topography. In this study, a combination of grey relational analysis and dimensional analysis procedures for prediction of dominant vibration frequency are presented. Six factors are selected from extensive effect factor sequences based on grey relational analysis, and then a novel blast-induced dominant vibration frequency prediction is obtained by dimensional analysis. In addition, the prediction is simplified by sensitivity analysis with 195 experimental blast records. Validation is carried out for the proposed formula based on the site test database of the first- period blasting excavation in the Guangdong Lufeng Nuclear Power Plant （GLNPP）. The results show the proposed approach has a higher fitting degree and smaller mean error when compared with traditional predictions.
基金financially supported by the National High Technology Research and Development Program of China(No.2007AA03Z113)
文摘The properties of gray cast iron(GCI)are affected by density of matrix,size of flake graphite and primary austenite.In this paper,the Y-type specimen of GCI was prepared by lost foam casting(LFC)with and without vibration,and the influence of vibration frequency on the density of matrix,size of primary phase,and properties of the GCI was studied.The results show that the length of the flake graphite and the size of the primary austenite in GCI firstly decrease and then increase with the increase of the vibration frequency.With a vibration frequency of 35 Hz,the length of the flake graphite is the shortest,the primary austenite is the finest and the density of the matrix is the highest.In addition,the tensile strength,elongation and hardness of the GCI firstly increase and then decrease with the increase of the vibration frequency,due to the refinement of the primary phase and the increase of the matrix density.In order to analyze the refinement mechanism of the primary phase of the GCI fabricated by the LFC with vibration,the solidification temperature fields of the GCI fabricated by the LFC with the vibration frequency of 0 and 35 Hz were measured.The results show that the vibration reduces the eutectic point of the GCI and increases the supercooling degree during the eutectic transformation.As a result,the length of the flake graphite and the size of the primary austenite in GCI fabricated by LFC with the vibration frequency of 35 Hz decrease.
基金This work was supported by the National Ba- sic Research Program of China （No.2013CB834600） and the National Natural Science Foundation of China （No.II27002/B030403, No.II290162/A040106, and No.21322310/B030402）.
文摘A broadband infrared surface sum frequency generation vibrational spectroscopy （SFG-VS） and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact high vacuum cell, organic contaminants on TiO2 thin film surface prepared by RF magnetron sputtering were in situ removed under 266 nm irradiation in 10 kPa 02 atmosphere. We obtained the methanol spectrum in the CH3 stretching vibration region on TiO2 surface with changing the methanol pressure at room temperature. Features of both molecular and dissociative methanol, methoxy, adsorbed on this surface were resolved. The CH3 symmetric stretching vibration frequency and Fermi resonance of molecular methanol is red-shifted by about 6-8 cm-1 from low to high coverage. Moreover, the recombination of dissociative methanol and H on Surfaces in vacuum was also observed. Our results suggest two equilibria exist： between molecular methanol in the gas phase and that on surfaces, and between molecular methanol and dissociative methanol on surfaces.
基金"Ministry" of Science and Technology,Taiwan,China(NSC 97-2622-B003-001-CC2)Tonic Fitness Technology Inc.(Magtonic,Taiwan,China) provided the funding and the customized vibration platform
文摘Purpose:The purpose of this study was to compare the effects of an 8-week whole-body vibration training program in various frequency and amplitude settings under the same acceleration on the strength and power of the knee extensors.Methods:Sixty-four young participants were randomly assigned to 1 of 4 groups with the same acceleration(4 g):high frequency and low amplitude(n = 16,32 Hz,1 mm) group,medium frequency and medium amplitude(n = 16,18 Hz,3 mm) group,low frequency and high amplitude(n = 16,3 Hz,114 mm) group,and control(n = 16,no vibration) group.All participants underwent 8 weeks of training with body mass dynamic squats,3 sessions a week.Results:The results showed that the high frequency and low amplitude group increased significantly in isometric contraction strength and 120°/s isokinetic concentric contraction strength;the medium frequency and medium amplitude group increased significantly in 60°/s and 120°/s isokinetic strength of both concentric and eccentric contraction;and the low frequency and high amplitude group increased significantly in 60°/s and 120°/s isokinetic eccentric contraction strength.Conclusion:All frequency and amplitude settings in the 8-week whole-body vibration training increased muscle strength,but different settings resulted in various neuromuscular adaptations despite the same intensity.
基金the Fundamental Research Funds for the Central Universities (No.CDJZR10110029)
文摘Quasi-ultrasonic vibration with a frequency of 15 kHz and a maximum output of 2 kW was imposed on the deep drawing process of AZ31 magnesium alloy sheet at room temperature,in order to reveal the effect of high frequency vibration on deformation behavior of AZ31 during the process.From the drawn results and the observation of the microstructure within the large deformation area,high frequency vibration has a great influence on the formability,the forming load and the failure mode of AZ31 sheet during the deep drawing process;the influence is a comprehensive result of so-called "volume effect" and "surface effect",and relies on the vibrating amplitude.Total forming load decreased significantly as soon as the vibration superimposed.According to the tensile test results of AZ31 bars under ultrasonic vibration,the formability of AZ31 sheet increases firstly with the increase of stimulating energy,then decreases and finally becomes brittle.Under the combined influence of "surface effect" and the "softening" in the "volume effect" near the relative low amplitude of 25%A in the experiment(A is the maximum amplitude),the formability of AZ31 reaches the largest value,and the samples possess the same distribution trend of cracks as those added with lubricating oil.With the increase of excitation energy,the "volume effect" gradually becomes apparent,and finally the "hardening" of the "volume effect" occupies a dominant position.
基金supported by the Construction Technology Program of the Ministry of Transport (Grant 2013 318 740050)
文摘The effects of tension on vortex-induced vibration (VIV) responses for a tension-dominated long cylinder with an aspect ratio of 550 in uniform flows are experimentally investigated in this paper. The results show that elevated tension suppresses fluctuations of maximum displacement with respect to flow velocity and makes chaotic VIV more likely to appear. With respect to periodic VIV, if elevated tension is applied, the dominant vibration frequency in the in-line (IL) direction will switch from a fundamental vibration frequency to twice the value of the fundamental vibration frequency, which results in a ratio of the dominant vibration frequency in the IL direction to that in the cross-flow direction of 2.0. The suppression of the elevated tension in the fluctuation of the maximum displacement causes the axial tension to become an active control parameter for the VIV maximum displacement of a tension-dominated long riser or tether of an engineering structure in deep oceans. However, the axial tension must be optimized before being used since the high dominant vibration frequency due to the elevated tension may unfavorably affect the fatigue life of the riser or tether.
基金Project supported by the National Natural Science Foundation of China (No. 51008017)the Fundamental Research Funds for the Central Universities of China (Nos. 2009JBM074 and 2009JBM075)
文摘Low frequency vibrations induced by underground railways have attracted increasing attention in recent years. To obtain the characteristics of low frequency vibrations and the low frequency performance of a floating slab track (FST), low frequency vibration tests on an FST in an underground laboratory at Beijing Jiaotong University were carried out. The FST and an unbalanced shaker SBZ30 for dynamic simulation were designed for use in low frequency vibration experiments. Vibration measurements were performed on the bogie of the unbalanced shaker, the rail, the slab, the tunnel invert, the tunnel wall, the tunnel apex, and on the ground surface at distances varying from 0 to 80 m from the track. Measurements were also made on several floors of an adjacent building. Detailed results of low frequency vibration tests were reported. The attenuation of low frequency vibrations with the distance from the track was presented, as well as the responses of different floors of the building. The experimental results could be regarded as a reference for developing methods to control low frequency vibrations and for adopting countermeasures.
基金supported by the National Natural Science Foundation of China(No.12072221)the Natural Science Foundation of Liaoning Province of China(No.2019-KF-01-09)。
文摘Human motion induced vibration has very low frequency,ranging from 2 Hz to 5 Hz.Traditional vibration isolators are not effective in low-frequency regions due to the trade-off between the low natural frequency and the high load capacity.In this paper,inspired by the human spine,we propose a novel bionic human spine inspired quasi-zero stiffness(QZS)vibration isolator which consists of a cascaded multi-stage negative stiffness structure.The force and stiffness characteristics are investigated first,the dynamic model is established by Newton’s second law,and the isolation performance is analyzed by the harmonic balance method(HBM).Numerical results show that the bionic isolator can obtain better low-frequency isolation performance by increasing the number of negative structure stages,and reducing the damping values and external force values can obtain better low-frequency isolation performance.In comparison with the linear structure and existing traditional QZS isolator,the bionic spine isolator has better vibration isolation performance in low-frequency regions.It paves the way for the design of bionic ultra-low-frequency isolators and shows potential in many engineering applications.
文摘Characterization of real-time and ultrafast motions of the complex molecules at surface and interface is critical to understand how interracial molecules function. It requires to develop surface-sensitive, fast-identification, and time-resolved techniques. In this study, we employ several key technical procedures and successfully develop a highly sensitive femtosecond time-resolved sum frequency generation vibrational spectroscopy （SFG-VS） system. This system is able to measure the spectra with two polarization combinations （ssp and ppp, or psp and ssp） simultaneously. It takes less than several seconds to collect one spectrum. To the best of our knowledge, it is the fastest speed of collecting SFG spectra reported by now. Using the time-resolved measurement, ultrafast vibrational dynamics of the N-H mode of α-helical peptide at water interface is determined. It is found that the membrane environment does not affect the N-H vibrational relaxation dynamics. It is expected that the time-resolved SFG system will play a vital role in the deep understanding of the dynamics and interaction of the complex molecules at surface and interface. Our method may also provide an important technical proposal for the people who plan to develop time-resolved SFG systems with simultaneous measurement of multiple polarization combinations.
文摘In view of the influence and harm of low frequency vibration environment on the structure of spaceflight products,a low frequency dynamic study method for piezoelectric sensor based on the dynamic system of sinusoidal pressure is proposed.This method uses a sinusoidal pressure dynamic system with two-way dual channel import and export synchronization technology to study the low frequency characteristics of a piezoelectric sensor of PCB company,and its lower cut-off frequency is 0.26 Hz.It is also studied that when the frequency of the measured vibration or shock signal is 1-200 kHz,the error range of signal positive pressure action time is 4.87%-0.03%.The dynamic compensation for the low frequency of the vibration sensor is carried out,and the compensation effect is good.
基金Project supported by the Natural Science Foundation of Shaanxi Province, China (Grant No. 2009JM1007)
文摘Molecular structure, vibrational frequency and infrared intensity of UF6 are investigated by using the revised Perdew Burke-Enzerhof function with the triple-zeta polarized basis set. The calculation results are in good agreement with the experimental values and indicate the existence of a stable U2F6 molecule with a multiple bonded U2 unit. The calculation results also predict that the D3d symmetry of U2F6 is more stable than D3h. The optimized geometries, vibrational frequencies, and infrared intensities are also reported for U2F6 molecules in D3d symmetry. In addition, the isotopic shift of vibrational frequencies of the two molecules under isotopic substitution of uranium atom are also investigated with the same method. The U2F6 molecule is predicted to be better than UF6 for laser uranic isotope separation.
基金supported by the National Natural Science Foundation of China(61871146)the Fundamental Research Funds for the Central Universities(FRFCU5710093720)。
文摘Ultrahigh resolution synthetic aperture radar(SAR)imaging for ship targets is significant in SAR imaging,but it suffers from high frequency vibration of the platform,which will induce defocus into SAR imaging results.In this paper,a novel compensation method based on the sinusoidal frequency modulation Fourier-Bessel transform(SFMFBT)is proposed,it can estimate the vibration errors,and the phase shift ambiguity can be avoided via extracting the time frequency ridge consequently.By constructing the corresponding compensation function and combined with the inverse SAR(ISAR)technique,well-focused imaging results can be obtained.The simulation imaging results of ship targets demonstrate the validity of the proposed approach.
文摘The laws that natural frequencies of rectangular plate with a cutout will change with size and position of cutout are obtained by analytic, numerical and experimental methods.
