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Role of vacancy-type defects in magnetism of GaMnN 被引量:1
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作者 邢海英 陈雨 +6 位作者 纪骋 蒋盛翔 苑梦尧 郭志英 李琨 崔明启 张国义 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第6期517-522,共6页
Role of vacancy-type(N vacancy(VN) and Ga vacancy(VGa)) defects in magnetism of GaMnN is investigated by first-principle calculation.Theoretical results show that both the VNand VGainfluence the ferromagnetic st... Role of vacancy-type(N vacancy(VN) and Ga vacancy(VGa)) defects in magnetism of GaMnN is investigated by first-principle calculation.Theoretical results show that both the VNand VGainfluence the ferromagnetic state of a system.The VNcan induce antiferromagnetic state and the VGaindirectly modify the stability of the ferromagnetic state by depopulating the Mn levels in GaMnN.The transfer of electrons between the vacancy defects and Mn ions results in converting Mn3+(d4) into Mn2+(d5).The introduced VNand the ferromagnetism become stronger and then gradually weaker with Mn concentration increasing,as well as the coexistence of Mn3+(d4) and Mn2+(d5) are found in GaMnN films grown by metal–organic chemical vapor deposition.The analysis suggests that a big proportion of Mn3+changing into Mn2+will reduce the exchange interaction and magnetic correlation of Mn atoms and lead to the reduction of ferromagnetism of material. 展开更多
关键词 GAMNN vacancy defect FERROMAGNETISM first-principles calculation MOCVD
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Solid-State Reaction and Vacancy-Type Defects in Bilayer Fe/Hf Studied by the Slow Positron Beam
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作者 K. Yamada T. Sasaki +5 位作者 T. Nagata I. Kanazawa R. Suzuki T. Ohdaira K. Nozawa F. Komori 《Journal of Applied Mathematics and Physics》 2015年第2期233-239,共7页
The positron annihilation lifetimes and the Doppler broadening by slow positron beam are measured in thin Fe films with thickness 500 nm, a thin Hf film with thickness 100 nm, and the bilayer Fe (50 nm)/Hf (50 nm) on ... The positron annihilation lifetimes and the Doppler broadening by slow positron beam are measured in thin Fe films with thickness 500 nm, a thin Hf film with thickness 100 nm, and the bilayer Fe (50 nm)/Hf (50 nm) on quartz glass substrate. We have analyzed the behavior in vacancy-type defects in each layer through some deposition temperatures and annealing. It is observed that the thin Fe film, the thin Hf film, and the bilayer Fe (50 nm)/Hf (50 nm) already contain many vacancy-type defects. We have investigated the change of densities of the vacancy-carbon complex and the small vacancy-cluster with carbons, through solid-state amorphization of Fe (50 nm)/Hf (50 nm) bilayer. 展开更多
关键词 Metallic Films POSITRON ANNIHILATION Measurement SOLID-STATE Reaction FE Film Diffusion vacancy-type defects
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Study on Vacancy-type Defects Induced by H/He Ion Mixed Beam Irradiation in SIMP Steel
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作者 Jin Peng Shen Tielong +1 位作者 Wang Zhiguang Li Jing 《IMP & HIRFL Annual Report》 2019年第1期96-97,共2页
The structural materials applied in future advanced nuclear energy systems will be exposed to high-energy and high-fux neutron irradiation,which puts forward high requirements for the neutron irradiation resistance of... The structural materials applied in future advanced nuclear energy systems will be exposed to high-energy and high-fux neutron irradiation,which puts forward high requirements for the neutron irradiation resistance of materials[1,2]. 展开更多
关键词 defectS energy STRUCTURAL
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Effect of Cu on the boron segregation at grain boundaries and vacancy-type defects in ultra-low carbon micro-alloy steels 被引量:3
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作者 YANG RuiJie WU Ping +4 位作者 LI XiangLong ZHANG ShiPing CHEN Sen WANG BaoYi JU Xin 《Science China(Technological Sciences)》 SCIE EI CAS 2014年第6期1135-1141,共7页
By thermal neutron irradiation particle tracking autoradiography(PTA)technique,the development of boron segregation at grain boundaries in ultra-low carbon micro-alloy steels was investigated during cooling from 1150&... By thermal neutron irradiation particle tracking autoradiography(PTA)technique,the development of boron segregation at grain boundaries in ultra-low carbon micro-alloy steels was investigated during cooling from 1150°C to 850°C,and the effect of Cu on boron segregation at grain boundaries was discussed.By positron annihilation lifetime(PAL)technique,the changes of vacancy-type defects with temperatures and the effect of Cu on vacancy-type defects in the cooling process were discussed.Results show that,the concentration of boron at grain boundaries increases rapidly at the beginning of the cooling;after that,it begins to decrease;and then,it increases gradually again.The addition of Cu not only increases the concentration of boron at grain boundaries but also speeds up the development process of boron segregation at grain boundaries.During the continuous cooling process,the addition of Cu significantly affects the change of vacancy-type defects with temperatures in ultra-low carbon micro-alloy steels. 展开更多
关键词 particle tracking autoradiography(PTA) technique boron segregation at grain boundaries positron annihilation lifetime(PAL) technique vacancy-type defects ultra-low carbon micro-alloy steels
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Status and Development of Rapid Detection Technology for Tunnel Structural Defects 被引量:3
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作者 LIU Xuezeng FANG Maoliu +3 位作者 WU Dexing LI Yinping LIU Xingen LI Gang 《隧道建设(中英文)》 北大核心 2025年第4期657-676,I0005-I0024,共40页
Based on inspection data,the authors analyze and summarize the main types and distribution characteristics of tunnel structural defects.These defects are classified into three types:surface defects,internal defects,an... Based on inspection data,the authors analyze and summarize the main types and distribution characteristics of tunnel structural defects.These defects are classified into three types:surface defects,internal defects,and defects behind the structure.To address the need for rapid detection of different defect types,the current state of rapid detection technologies and equipment,both domestically and internationally,is systematically reviewed.The research reveals that surface defect detection technologies and equipment have developed rapidly in recent years.Notably,the integration of machine vision and laser scanning technologies have significantly improved detection efficiency and accuracy,achieving crack detection precision of up to 0.1 mm.However,the non-contact rapid detection of internal and behind-the-structure defects remains constrained by hardware limitations,with traditional detection remaining dominant.Nevertheless,phased array radar,ultrasonic,and acoustic vibration detection technologies have become research hotspots in recent years,offering promising directions for detecting these challenging defect types.Additionally,the application of multisensor fusion technology in rapid detection equipment has further enhanced detection capabilities.Devices such as cameras,3D laser scanners,infrared thermal imagers,and radar demonstrate significant advantages in rapid detection.Future research in tunnel inspection should prioritize breakthroughs in rapid detection technologies for internal and behind-the-structure defects.Efforts should also focus on developing multifunctional integrated detection vehicles that can simultaneously inspect both surface and internal structures.Furthermore,progress in fully automated,intelligent systems with precise defect identification and real-time reporting will be essential to significantly improve the efficiency and accuracy of tunnel inspection. 展开更多
关键词 TUNNEL structural defect inspection techniques inspection equipment rapid inspection
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Quasi-visualizable detection of deep sub-wavelength defects in patterned wafers by breaking the optical form birefringence 被引量:1
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作者 Jiamin Liu Jinlong Zhu +8 位作者 Zhe Yu Xianrui Feng Zedi Li Lei Zhong Jinsong Zhang Honggang Gu Xiuguo Chen Hao Jiang Shiyuan Liu 《International Journal of Extreme Manufacturing》 2025年第1期623-639,共17页
In integrated circuit(IC)manufacturing,fast,nondestructive,and precise detection of defects in patterned wafers,realized by bright-field microscopy,is one of the critical factors for ensuring the final performance and... In integrated circuit(IC)manufacturing,fast,nondestructive,and precise detection of defects in patterned wafers,realized by bright-field microscopy,is one of the critical factors for ensuring the final performance and yields of chips.With the critical dimensions of IC nanostructures continuing to shrink,directly imaging or classifying deep-subwavelength defects by bright-field microscopy is challenging due to the well-known diffraction barrier,the weak scattering effect,and the faint correlation between the scattering cross-section and the defect morphology.Herein,we propose an optical far-field inspection method based on the form-birefringence scattering imaging of the defective nanostructure,which can identify and classify various defects without requiring optical super-resolution.The technique is built upon the principle of breaking the optical form birefringence of the original periodic nanostructures by the defect perturbation under the anisotropic illumination modes,such as the orthogonally polarized plane waves,then combined with the high-order difference of far-field images.We validated the feasibility and effectiveness of the proposed method in detecting deep subwavelength defects through rigid vector imaging modeling and optical detection experiments of various defective nanostructures based on polarization microscopy.On this basis,an intelligent classification algorithm for typical patterned defects based on a dual-channel AlexNet neural network has been proposed,stabilizing the classification accuracy ofλ/16-sized defects with highly similar features at more than 90%.The strong classification capability of the two-channel network on typical patterned defects can be attributed to the high-order difference image and its transverse gradient being used as the network’s input,which highlights the polarization modulation difference between different patterned defects more significantly than conventional bright-field microscopy results.This work will provide a new but easy-to-operate method for detecting and classifying deep-subwavelength defects in patterned wafers or photomasks,which thus endows current online inspection equipment with more missions in advanced IC manufacturing. 展开更多
关键词 defect inspection form birefringence breaking high order difference anisotropic illumination modes deep-subwavelength sensitivity defect classification
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Phenanthrene perturbs hematopoietic development and causes hematopoietic defects in zebrafish 被引量:1
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作者 Lingyu Ren Yue Wang +2 位作者 Ying Ren Guangke Li Nan Sang 《Journal of Environmental Sciences》 2025年第5期573-581,共9页
Phenanthrene(Phe)is one of the common polycyclic aromatic hydrocarbons in the environment,and recent studies show that it can cause cardiac developmental toxicity and immunotoxicity.However,it is still unknown whether... Phenanthrene(Phe)is one of the common polycyclic aromatic hydrocarbons in the environment,and recent studies show that it can cause cardiac developmental toxicity and immunotoxicity.However,it is still unknown whether it can affect the hematopoietic development in aquatic organisms.To address this question,zebrafish(Danio rerio)were chronically exposed to Phe at different concentrations.We found that Phe caused structural damage to the renal tubules in the kidney,induced malformed erythrocytes in peripheral blood,and decreased the proportion of myeloid cells in adult zebrafish,suggesting possible negative impacts that Phe posed to hematopoietic development.Then,using in situ hybridization technology,we found that Phe decreased the expression of primitive hematopoietic marker genes,specifically gata1 and pu.1,accompanied by an obstruction of primitive erythrocyte circulation.Furthermore,Phe impaired definitive hematopoiesis,increased aberrations of the transient hematopoietic site(PBI),and reduced the generation of hematopoietic stem cells,ultimately influencing the number of erythrocytes and myeloid cells.The findings suggested that Phe could induce hematopoietic toxicity in zebrafish embryos and pose unknown ecological risks. 展开更多
关键词 PHENANTHRENE ZEBRAFISH Hematopoietic development Hematopoietic defect
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Asymmetric oxygen vacancy promotes CO-SCR performance on defect-engineered Rh/CeCuOx catalyst 被引量:1
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作者 Qian Wang Xinyu Han +3 位作者 Kaiting Chen Kaijie Liu Xiangguang Yang Yibo Zhang 《Journal of Environmental Sciences》 2025年第6期416-428,共13页
Selective catalytic reduction of NO_(x) with CO(CO-SCR)is a process that purifies both NO and CO pollutants through a catalytic reaction.Specifically,the cleavage of NO on the catalyst surface is crucial for promoting... Selective catalytic reduction of NO_(x) with CO(CO-SCR)is a process that purifies both NO and CO pollutants through a catalytic reaction.Specifically,the cleavage of NO on the catalyst surface is crucial for promoting the reaction.During the reaction,the presence of oxygen vacancies can extract oxygen from NO,thereby facilitating the cleavage of NO on the catalyst surface.Thus,the formation of oxygen vacancies is key to accelerating the CO-SCR reaction,with different types of oxygen vacancies being more conducive to their generation.In this study,Rh/CeCuO_(x) catalysts were synthesized using the co-crystallization and impregnation methods,and asymmetric oxygen vacancies were induced through hydrogen thermal treatment.This structuralmodification was aimed at regulating the behavior of NO on the catalyst surface.The Rh/Ce0.95Cu0.05O_(x)-H_(2) catalyst exhibited the best performance in CO-SCR,achieving above 90%NO conversion at 162℃.Various characterization techniques showed that the H_(2) treatment effectively reduced some of the CuO and Rh_(2)O_(3),creating asymmetric oxygen vacancies that accelerated the cleavage of NO on the catalyst surface,rather than forming difficult-to-decompose nitrates.This study offers a novel approach to constructing oxygen vacancies in new CO-SCR catalysts. 展开更多
关键词 Oxygen vacancy Rare earth CO-SCR defect engineering RHODIUM
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Biomaterials for surgical repair of osteoporotic bone defects 被引量:1
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作者 Xu Luo Jinwen Xiao +6 位作者 Qiming Yang Xiaolong Lu Qianjun Huang Xiaojun Ai Bo Li Li Sun Long Chen 《Chinese Chemical Letters》 2025年第1期92-98,共7页
As the global population ages,osteoporotic bone fractures leading to bone defects are increasingly becoming a significant challenge in the field of public health.Treating this disease faces many challenges,especially ... As the global population ages,osteoporotic bone fractures leading to bone defects are increasingly becoming a significant challenge in the field of public health.Treating this disease faces many challenges,especially in the context of an imbalance between osteoblast and osteoclast activities.Therefore,the development of new biomaterials has become the key.This article reviews various design strategies and their advantages and disadvantages for biomaterials aimed at osteoporotic bone defects.Overall,current research progress indicates that innovative design,functionalization,and targeting of materials can significantly enhance bone regeneration under osteoporotic conditions.By comprehensively considering biocompatibility,mechanical properties,and bioactivity,these biomaterials can be further optimized,offering a range of choices and strategies for the repair of osteoporotic bone defects. 展开更多
关键词 Osteoporotic bone defect BIOMATERIALS NANOMATERIALS Bone tissue engineering Bone regeneration
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Steel Surface Defect Recognition in Smart Manufacturing Using Deep Ensemble Transfer Learning-Based Techniques
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作者 Tajmal Hussain Jongwon Seok 《Computer Modeling in Engineering & Sciences》 SCIE EI 2025年第1期231-250,共20页
Smart manufacturing and Industry 4.0 are transforming traditional manufacturing processes by utilizing innovative technologies such as the artificial intelligence(AI)and internet of things(IoT)to enhance efficiency,re... Smart manufacturing and Industry 4.0 are transforming traditional manufacturing processes by utilizing innovative technologies such as the artificial intelligence(AI)and internet of things(IoT)to enhance efficiency,reduce costs,and ensure product quality.In light of the recent advancement of Industry 4.0,identifying defects has become important for ensuring the quality of products during the manufacturing process.In this research,we present an ensemble methodology for accurately classifying hot rolled steel surface defects by combining the strengths of four pre-trained convolutional neural network(CNN)architectures:VGG16,VGG19,Xception,and Mobile-Net V2,compensating for their individual weaknesses.We evaluated our methodology on the Xsteel surface defect dataset(XSDD),which comprises seven different classes.The ensemble methodology integrated the predictions of individual models through two methods:model averaging and weighted averaging.Our evaluation showed that the model averaging ensemble achieved an accuracy of 98.89%,a recall of 98.92%,a precision of 99.05%,and an F1-score of 98.97%,while the weighted averaging ensemble reached an accuracy of 99.72%,a recall of 99.74%,a precision of 99.67%,and an F1-score of 99.70%.The proposed weighted averaging ensemble model outperformed the model averaging method and the individual models in detecting defects in terms of accuracy,recall,precision,and F1-score.Comparative analysis with recent studies also showed the superior performance of our methodology. 展开更多
关键词 Smart manufacturing CNN steel defects ensemble models
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Optimizing electronic structure through point defect engineering for enhanced electrocatalytic energy conversion
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作者 Wei Ma Jiahao Yao +6 位作者 Fang Xie Xinqi Wang Hao Wan Xiangjian Shen Lili Zhang Menggai Jiao Zhen Zhou 《Green Energy & Environment》 SCIE EI CAS 2025年第1期109-131,共23页
Point defect engineering endows catalysts with novel physical and chemical properties,elevating their electrocatalytic efficiency.The introduction of defects emerges as a promising strategy,effectively modifying the e... Point defect engineering endows catalysts with novel physical and chemical properties,elevating their electrocatalytic efficiency.The introduction of defects emerges as a promising strategy,effectively modifying the electronic structure of active sites.This optimization influences the adsorption energy of intermediates,thereby mitigating reaction energy barriers,altering paths,enhancing selectivity,and ultimately improving the catalytic efficiency of electrocatalysts.To elucidate the impact of defects on the electrocatalytic process,we comprehensively outline the roles of various point defects,their synthetic methodologies,and characterization techniques.Importantly,we consolidate insights into the relationship between point defects and catalytic activity for hydrogen/oxygen evolution and CO_(2)/O_(2)/N_(2) reduction reactions by integrating mechanisms from diverse reactions.This underscores the pivotal role of point defects in enhancing catalytic performance.At last,the principal challenges and prospects associated with point defects in current electrocatalysts are proposed,emphasizing their role in advancing the efficiency of electrochemical energy storage and conversion materials. 展开更多
关键词 Point defect engineering DOPING VACANCY ELECTROCATALYSIS Electronic structure
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Weld defects detection method based on improved YOLOv5s 被引量:1
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作者 Runchao Liu Jiyang Qi +1 位作者 Dongliang Shui Tang Ebolo Micheline Hortense 《China Welding》 2025年第2期119-131,共13页
To solve the problem of low detection accuracy for complex weld defects,the paper proposes a weld defects detection method based on improved YOLOv5s.To enhance the ability to focus on key information in feature maps,t... To solve the problem of low detection accuracy for complex weld defects,the paper proposes a weld defects detection method based on improved YOLOv5s.To enhance the ability to focus on key information in feature maps,the scSE attention mechanism is intro-duced into the backbone network of YOLOv5s.A Fusion-Block module and additional layers are added to the neck network of YOLOv5s to improve the effect of feature fusion,which is to meet the needs of complex object detection.To reduce the computation-al complexity of the model,the C3Ghost module is used to replace the CSP2_1 module in the neck network of YOLOv5s.The scSE-ASFF module is constructed and inserted between the neck network and the prediction end,which is to realize the fusion of features between the different layers.To address the issue of imbalanced sample quality in the dataset and improve the regression speed and accuracy of the loss function,the CIoU loss function in the YOLOv5s model is replaced with the Focal-EIoU loss function.Finally,ex-periments are conducted based on the collected weld defect dataset to verify the feasibility of the improved YOLOv5s for weld defects detection.The experimental results show that the precision and mAP of the improved YOLOv5s in detecting complex weld defects are as high as 83.4%and 76.1%,respectively,which are 2.5%and 7.6%higher than the traditional YOLOv5s model.The proposed weld defects detection method based on the improved YOLOv5s in this paper can effectively solve the problem of low weld defects detection accuracy. 展开更多
关键词 Weld defects detection Improved YOLOv5s scSE-ASFF Feature fusion
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Defect Engineering with Rational Dopants Modulation for High‑Temperature Energy Harvesting in Lead‑Free Piezoceramics
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作者 Kaibiao Xi Jianzhe Guo +2 位作者 Mupeng Zheng Mankang Zhu Yudong Hou 《Nano-Micro Letters》 SCIE EI CAS 2025年第3期87-101,共15页
High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,inclu... High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,including high figure of merit(FOM),insulation resistivity(ρ)and depolarization temperature(Td)are indispensable but hard to achieve in lead-free piezoceramics,especially operating at 250°C has not been reported before.Herein,well-balanced performances are achieved in BiFeO3–BaTiO3 ceramics via innovative defect engineering with respect to delicate manganese doping.Due to the synergistic effect of enhancing electrostrictive coefficient by polarization configuration optimization,regulating iron ion oxidation state by high valence manganese ion and stabilizing domain orientation by defect dipole,comprehensive excellent electrical performances(Td=340°C,ρ250°C>10^(7)Ωcm and FOM_(250°C)=4905×10^(–15)m^(2)N^(−1))are realized at the solid solubility limit of manganese ions.The HT-PEHs assembled using the rationally designed piezoceramic can allow for fast charging of commercial electrolytic capacitor at 250°C with high energy conversion efficiency(η=11.43%).These characteristics demonstrate that defect engineering tailored BF-BT can satisfy high-end HT-PEHs requirements,paving a new way in developing selfpowered wireless sensors working in HT environments. 展开更多
关键词 Lead-free piezoceramic defect engineering Dopants modulation High-temperature Piezoelectric energy harvester
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Defect Engineering:Can it Mitigate Strong Coulomb Effect of Mg^(2+)in Cathode Materials for Rechargeable Magnesium Batteries?
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作者 Zhengqing Fan Ruimin Li +3 位作者 Xin Zhang Wanyu Zhao Zhenghui Pan Xiaowei Yang 《Nano-Micro Letters》 SCIE EI CAS 2025年第1期135-159,共25页
Rechargeable magnesium batteries(RMBs)have been considered a promising“post lithium-ion battery”system to meet the rapidly increasing demand of the emerging electric vehicle and grid energy storage market.However,th... Rechargeable magnesium batteries(RMBs)have been considered a promising“post lithium-ion battery”system to meet the rapidly increasing demand of the emerging electric vehicle and grid energy storage market.However,the sluggish diffusion kinetics of bivalent Mg^(2+)in the host material,related to the strong Coulomb effect between Mg^(2+)and host anion lattices,hinders their further development toward practical applications.Defect engineering,regarded as an effective strategy to break through the slow migration puzzle,has been validated in various cathode materials for RMBs.In this review,we first thoroughly understand the intrinsic mechanism of Mg^(2+)diffusion in cathode materials,from which the key factors affecting ion diffusion are further presented.Then,the positive effects of purposely introduced defects,including vacancy and doping,and the corresponding strategies for introducing various defects are discussed.The applications of defect engineering in cathode materials for RMBs with advanced electrochemical properties are also summarized.Finally,the existing challenges and future perspectives of defect engineering in cathode materials for the overall high-performance RMBs are described. 展开更多
关键词 Rechargeable magnesium battery Sluggish diffusion kinetic defect engineering Cathode materials Ion migration
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A Lightweight Multiscale Feature Fusion Network for Solar Cell Defect Detection
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作者 Xiaoyun Chen Lanyao Zhang +3 位作者 Xiaoling Chen Yigang Cen Linna Zhang Fugui Zhang 《Computers, Materials & Continua》 SCIE EI 2025年第1期521-542,共22页
Solar cell defect detection is crucial for quality inspection in photovoltaic power generation modules.In the production process,defect samples occur infrequently and exhibit random shapes and sizes,which makes it cha... Solar cell defect detection is crucial for quality inspection in photovoltaic power generation modules.In the production process,defect samples occur infrequently and exhibit random shapes and sizes,which makes it challenging to collect defective samples.Additionally,the complex surface background of polysilicon cell wafers complicates the accurate identification and localization of defective regions.This paper proposes a novel Lightweight Multiscale Feature Fusion network(LMFF)to address these challenges.The network comprises a feature extraction network,a multi-scale feature fusion module(MFF),and a segmentation network.Specifically,a feature extraction network is proposed to obtain multi-scale feature outputs,and a multi-scale feature fusion module(MFF)is used to fuse multi-scale feature information effectively.In order to capture finer-grained multi-scale information from the fusion features,we propose a multi-scale attention module(MSA)in the segmentation network to enhance the network’s ability for small target detection.Moreover,depthwise separable convolutions are introduced to construct depthwise separable residual blocks(DSR)to reduce the model’s parameter number.Finally,to validate the proposed method’s defect segmentation and localization performance,we constructed three solar cell defect detection datasets:SolarCells,SolarCells-S,and PVEL-S.SolarCells and SolarCells-S are monocrystalline silicon datasets,and PVEL-S is a polycrystalline silicon dataset.Experimental results show that the IOU of our method on these three datasets can reach 68.5%,51.0%,and 92.7%,respectively,and the F1-Score can reach 81.3%,67.5%,and 96.2%,respectively,which surpasses other commonly usedmethods and verifies the effectiveness of our LMFF network. 展开更多
关键词 defect segmentation multi-scale feature fusion multi-scale attention depthwise separable residual block
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Influence of Casting Defects on Weldability of a Nickel-Based Superalloy
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作者 Chu Qingquan Hou Xingyu +4 位作者 Cheng Yin Qin Jian Wang Shiyang Sun Yuan Sun Xiaofeng 《稀有金属材料与工程》 北大核心 2025年第8期1917-1925,共9页
The impact of casting defects on the weldability of K4951 superalloy was investigated using tungsten inert gas(TIG)welding.The as-cast K4951 superalloy samples with prefabricated U-shaped grooves of varying depths and... The impact of casting defects on the weldability of K4951 superalloy was investigated using tungsten inert gas(TIG)welding.The as-cast K4951 superalloy samples with prefabricated U-shaped grooves of varying depths and widths were TIG welded,and the microstructures,cracks morphology,and precipitated phases were analyzed using optical microscope,scanning electron microscope,transmission electron microscope,and energy dispersive X-ray spectrometer.The results reveal that the dimensions of casting defects significantly affect the weldability of K4951.Deep defects(greater than 2 mm)lead to rapid crack propagation,while wider defects can moderate the propagation process of cracks.Elemental segregation and the formation of precipitated phases,such as MC carbides,are observed in the fusion zone,contributing to welding cracks.An optimal groove aspect ratio(depth-to-width)between 0.2 and 0.5 minimizes crack formation tendency and enhances tensile strength,resulting in a mixed brittle-ductile fracture mode of joint after high-temperature tensile testing. 展开更多
关键词 casting defect K4951 TIG WELDABILITY
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Functional design and understanding of effective additives for achieving high-quality perovskite films and passivating surface defects 被引量:1
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作者 Fengwu Liu Jiacheng Xu +7 位作者 Yongchao Ma Yoomi Ahn Xiangrui Du Eunhye Yang Haicheng Xia Bo Ram Lee Pesi Mwitumwa Hangoma Sung Heum Park 《Journal of Energy Chemistry》 2025年第3期597-608,共12页
Achieving high-quality perovskite films without surface defects is regarded as a crucial target for the development of durable high-performance perovskite solar cells.Additive engineering is commonly employed to simul... Achieving high-quality perovskite films without surface defects is regarded as a crucial target for the development of durable high-performance perovskite solar cells.Additive engineering is commonly employed to simultaneously control the growth of perovskite crystals and passivate defects.Here,4-(trifluoromethyl)benzoic anhydride(4-TBA)composed of benzene rings functionalized with carbonyl and trifluoromethyl groups was used as an example additive to study the characteristics of additives used for producing high-quality perovskites and controlling their surface properties.The interaction between4-TBA and perovskite precursor materials was investigated using density functional theory(DFT)simulations.The electron-rich carbonyl group efficiently passivated the under-coordinated lead-ion defects.Additionally,hydrogen bonding between trifluoromethyl and organic cations prevents the generation of cation vacancies.Because of its intrinsic hydrophobicity,the trifluoromethyl group simultaneously improves the moisture and heat stability of the film.4-TBA serves as a universal modifier for various perovskite compositions.The power conversion efficiency(PCE)of inverted perovskite solar cells(PSCs)based on methylammonium(MA)with 4-TBA was improved from 16.15%to 19.28%.Similarly,the PCE of inverted PSCs based on a cesium formamidinium MA(CsFAMA)perovskite film increased from20.72%to 23.58%,upon addition of 4-TBA.Furthermore,the moisture and thermal stability of 4-TBAtreated films and devices was significantly enhanced,along with prolonged device performance.Our work provides guidance on selecting the structure and functional groups that are essential for surface defect passivation and the production of high-quality perovskites. 展开更多
关键词 Perovskite solar cells Regulated crystal growth defect passivation 4-(trifluoromethyl)benzoic anhydride Perovskite stability
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Masquelet technique using an allogeneic cortical bone graft for a large bone defect:A case report
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作者 Hai-Yang Zong Yu Liu +2 位作者 Xing Yin Wei Zhou Nan Li 《World Journal of Clinical Cases》 SCIE 2025年第5期36-43,共8页
BACKGROUND The induced-membrane technique was initially described by Masquelet as an effective treatment for large bone defects,especially those caused by infection.Here,we report a case of chronic osteomyelitis of th... BACKGROUND The induced-membrane technique was initially described by Masquelet as an effective treatment for large bone defects,especially those caused by infection.Here,we report a case of chronic osteomyelitis of the radius associated with a 9 cm bone defect,which was filled with a large allogeneic cortical bone graft from a bone bank.Complete bony union was achieved after 14 months of follow-up.Previous studies have used autogenous bone as the primary bone source for the Masquelet technique;in our case,the exclusive use of allografts is as successful as the use of autologous bone grafts.With the advent of bone banks,it is possible to obtain an unlimited amount of allograft,and the Masquelet technique may be further improved based on this new way of bone grafting.CASE SUMMARY In this study,we reported a case of repair of a long bone defect in a 40-year-old male patient,which was characterized by the utilization of allograft cortical bone combined with the Masquelet technique for the treatment of the patient's long bone defect in the forearm.The patient's results of functional recovery of the forearm were surprising,which further deepens the scope of application of Masquelet technique and helps to strengthen the efficacy of Masquelet technique in the treatment of long bones indeed.CONCLUSION Allograft cortical bone combined with the Masquelet technique provides a new method of treatment to large bone defect. 展开更多
关键词 OSTEOMYELITIS Bone defect Allogeneic cortical bone Masquelet technique Membrane induction technique Case report
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Defect Dipole Thermal-stability to the Electro-mechanical Properties of Fe Doped PZT Ceramics
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作者 SUN Yuxuan WANG Zheng +5 位作者 SHI Xue SHI Ying DU Wentong MAN Zhenyong ZHENG Liaoying LI Guorong 《无机材料学报》 北大核心 2025年第5期545-551,I0009-I0010,共9页
The accepted doping ion in Ti^(4+)-site of PbZr_(y)Ti_(1–y)O_(3)(PZT)-based piezoelectric ceramics is a well-known method to increase mechanical quality factor(Q_(m)),since the acceptor coupled by oxygen vacancy beco... The accepted doping ion in Ti^(4+)-site of PbZr_(y)Ti_(1–y)O_(3)(PZT)-based piezoelectric ceramics is a well-known method to increase mechanical quality factor(Q_(m)),since the acceptor coupled by oxygen vacancy becomes defect dipole,which prevents the domain rotation.In this field,a serious problem is that generally,Qm decreases as the temperature(T)increases,since the oxygen vacancies are decoupled from the defect dipoles.In this work,Q_(m) of Pb_(0.95)Sr_(0.05)(Zr_(0.53)Ti_(0.47))O_(3)(PSZT)ceramics doped by 0.40%Fe_(2)O_(3)(in mole)abnormally increases as T increases,of which the Qm and piezoelectric coefficient(d_(33))at room temperature and Curie temperature(TC)are 507,292 pC/N,and 345℃,respectively.The maximum Qm of 824 was achieved in the range of 120–160℃,which is 62.52%higher than that at room temperature,while the dynamic piezoelectric constant(d_(31))was just slightly decreased by 3.85%.X-ray diffraction(XRD)and piezoresponse force microscopy results show that the interplanar spacing and the fine domains form as temperature increases,and the thermally stimulated depolarization current shows that the defect dipoles are stable even the temperature up to 240℃.It can be deduced that the aggregation of oxygen vacancies near the fine domains and defect dipole can be stable up to 240℃,which pins domain rotation,resulting in the enhanced Q_(m) with the increasing temperature.These results give a potential path to design high Q_(m) at high temperature. 展开更多
关键词 defect dipole temperature characteristic oxygen vacancy electro-mechanical property mechanical quality factor hardening doping
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Evaluation of On-Vehicle Bone-Conduct Acoustic Emission Detection for Rail Defects
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作者 Lei Jia Jee Woong Park +2 位作者 Ming Zhu Yingtao Jiang Hualiang Teng 《Journal of Transportation Technologies》 2025年第1期95-121,共27页
Rail defects can pose significant safety risks in railway operations, raising the need for effective detection methods. Acoustic Emission (AE) technology has shown promise for identifying and monitoring these defects,... Rail defects can pose significant safety risks in railway operations, raising the need for effective detection methods. Acoustic Emission (AE) technology has shown promise for identifying and monitoring these defects, and this study evaluates an advanced on-vehicle AE detection approach using bone-conduct sensors—a solution to improve upon previous AE methods of using on-rail sensor installations, which required extensive, costly on-rail sensor networks with limited effectiveness. In response to these challenges, the study specifically explored bone-conduct sensors mounted directly on the vehicle rather than rails by evaluating AE signals generated by the interaction between rails and the train’s wheels while in motion. In this research, a prototype detection system was developed and tested through initial trials at the Nevada Railroad Museum using a track with pre-damaged welding defects. Further testing was conducted at the Transportation Technology Center Inc. (rebranded as MxV Rail) in Colorado, where the system’s performance was evaluated across various defect types and train speeds. The results indicated that bone-conduct sensors were insufficient for detecting AE signals when mounted on moving vehicles. These findings highlight the limitations of contact-based methods in real-world applications and indicate the need for exploring improved, non-contact approaches. 展开更多
关键词 Railroad Infrastructure Rail defect Detection Rail Health Monitoring Wavelet Analysis Acoustic Emission Detection
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