The influence of V contents(0.6 wt%,0.8 wt%and 1.0 wt%)on the microstructure and creep behavior of a Nickel-based superalloy was investigated.The results revealed that the V content exerted a significant impact on the...The influence of V contents(0.6 wt%,0.8 wt%and 1.0 wt%)on the microstructure and creep behavior of a Nickel-based superalloy was investigated.The results revealed that the V content exerted a significant impact on the morphology of carbide.Notably,in the alloy containing 0.8 wt%V,coarse blocky M_(6)C carbides formed adjacent to MC carbides,while in the 1.0 wt%V alloy,fine granular M_(6)C carbides exhibited a nearly continuous distribution along grain boundaries(GBs).The influence of V content on creep properties exhibited significant variations depending on temperature.At 650℃/1010 MPa,the 1.0 wt%V alloy,containing a high density of granular M_(6)C carbides,demonstrated enhanced intergranular bonding strength,which contributed to prolonged creep life.In contrast,at higher temperatures(750℃/620 MPa and 800℃/500 MPa),GB mobility was activated,making GB slip the dominant creep mechanism.The near-continuous distribution of M_(6)C carbides in the 1.0 wt%V alloy restricted GB deformation compatibility,promoting stress localization and an increased density of micropores along GBs.As a result,the 0.8 wt%V alloy,with its discrete M_(6)C carbide distribution,exhibited superior creep resistance at elevated temperatures.展开更多
The virtual laminated element method (VLEM) can resolve structural shap e optimization problems with a new method. According to the characteristics of V LEM , only some characterized layer thickness values need be def...The virtual laminated element method (VLEM) can resolve structural shap e optimization problems with a new method. According to the characteristics of V LEM , only some characterized layer thickness values need be defined as design v ariables instead of boundary node coordinates or some other parameters determini ng the system boundary. One of the important features of this method is that it is not necessary to regenerate the FE(finite element) grid during the optimizati on process so as to avoid optimization failures resulting from some distortion grid elements. Th e thickness distribution in thin plate optimization problems in other studies be fore is of stepped shape. However, in this paper, a continuous thickness distrib ution can be obtained after optimization using VLEM, and is more reasonable. Fur thermore, an approximate reanalysis method named ″behavior model technique″ ca n be used to reduce the amount of structural reanalysis. Some typical examples are offered to prove the effectiveness and practicality of the proposed method.展开更多
In this paper, an optimal V-cycle multigrid method for some conforming and nonconforming plate elements are constructed. A new method dealing with nonnested multigrid methods is presented.
Adjusting the intrinsic activity and conductivity of electrocatalysts may be a crucial way for excellent performance for water splitting.Herein,the rational design of vanadium element doped cobalt phosphide(V-doped Co...Adjusting the intrinsic activity and conductivity of electrocatalysts may be a crucial way for excellent performance for water splitting.Herein,the rational design of vanadium element doped cobalt phosphide(V-doped CoP)nanoparticles has been investigated through a facile gaseous phosphorization using cobalt vanadium oxide or hydroxide(Co-V hydr(oxy)oxide)as precursor.The physical characterization shows that the homogeneous dispersion of V element on V-doped CoP nanoparticles have obtained,which may imply the enhanced electrocatalytic activity for hydrogen evolution reaction(HER)and oxygen evolution reaction(OER).The electrochemical measurements of the prepared V-doped CoP in alkaline electrolyte demonstrate the superior electrocatalytic activity for both HER(overpotential of 235 mV@10 mA cm^-2)and OER(overpotential of 340 mV@10 mA cm^-2).Further,V-doped CoP nanoparticles used as anode and cathode simultaneously in a cell require only 370 mV to achieve a current density of 10 mA cm^-2.The outstanding electrocatalytic activity may be ascribed to the improved conductivity and intrinsic activity owing to phosphating and the doping of V element.In addition,the long-term stability of V-doped Co P has been obtained.Therefore,metal doping into transition metal-based phosphides may be a promising strategy for the remarkable bifunctional electrocatalyst for water splitting.展开更多
基金support from the National Science and Technology Major Project(No.J2019-VI-0006-0120)the National Key R&D Program of China(No.2019YFA0705300)+2 种基金the Youth Innovation Promotion Association,CAS(No.2023202)the Natural Science Foundation Project of Liaoning Province(No.2023-MS-024)the Innovation Program of Institute of Metal Research,Chinese Academy of Sciences(No.2023-PY08).
文摘The influence of V contents(0.6 wt%,0.8 wt%and 1.0 wt%)on the microstructure and creep behavior of a Nickel-based superalloy was investigated.The results revealed that the V content exerted a significant impact on the morphology of carbide.Notably,in the alloy containing 0.8 wt%V,coarse blocky M_(6)C carbides formed adjacent to MC carbides,while in the 1.0 wt%V alloy,fine granular M_(6)C carbides exhibited a nearly continuous distribution along grain boundaries(GBs).The influence of V content on creep properties exhibited significant variations depending on temperature.At 650℃/1010 MPa,the 1.0 wt%V alloy,containing a high density of granular M_(6)C carbides,demonstrated enhanced intergranular bonding strength,which contributed to prolonged creep life.In contrast,at higher temperatures(750℃/620 MPa and 800℃/500 MPa),GB mobility was activated,making GB slip the dominant creep mechanism.The near-continuous distribution of M_(6)C carbides in the 1.0 wt%V alloy restricted GB deformation compatibility,promoting stress localization and an increased density of micropores along GBs.As a result,the 0.8 wt%V alloy,with its discrete M_(6)C carbide distribution,exhibited superior creep resistance at elevated temperatures.
文摘The virtual laminated element method (VLEM) can resolve structural shap e optimization problems with a new method. According to the characteristics of V LEM , only some characterized layer thickness values need be defined as design v ariables instead of boundary node coordinates or some other parameters determini ng the system boundary. One of the important features of this method is that it is not necessary to regenerate the FE(finite element) grid during the optimizati on process so as to avoid optimization failures resulting from some distortion grid elements. Th e thickness distribution in thin plate optimization problems in other studies be fore is of stepped shape. However, in this paper, a continuous thickness distrib ution can be obtained after optimization using VLEM, and is more reasonable. Fur thermore, an approximate reanalysis method named ″behavior model technique″ ca n be used to reduce the amount of structural reanalysis. Some typical examples are offered to prove the effectiveness and practicality of the proposed method.
基金The rescarch was supported by the Doctoral Point Foundation of chinese Universities and NSF
文摘In this paper, an optimal V-cycle multigrid method for some conforming and nonconforming plate elements are constructed. A new method dealing with nonnested multigrid methods is presented.
基金financially supported by the National Natural Science Foundation of China(21776314)Major Program of Shandong Province Natural Science Foundation(ZR2018ZC0639)+2 种基金Shandong Provincial Natural Science Foundation(ZR2017MB059)the Fundamental Research Funds for the Central Universities(18CX05016A)Postgraduate Innovation Project of China University of Petroleum(YCX2018034)
文摘Adjusting the intrinsic activity and conductivity of electrocatalysts may be a crucial way for excellent performance for water splitting.Herein,the rational design of vanadium element doped cobalt phosphide(V-doped CoP)nanoparticles has been investigated through a facile gaseous phosphorization using cobalt vanadium oxide or hydroxide(Co-V hydr(oxy)oxide)as precursor.The physical characterization shows that the homogeneous dispersion of V element on V-doped CoP nanoparticles have obtained,which may imply the enhanced electrocatalytic activity for hydrogen evolution reaction(HER)and oxygen evolution reaction(OER).The electrochemical measurements of the prepared V-doped CoP in alkaline electrolyte demonstrate the superior electrocatalytic activity for both HER(overpotential of 235 mV@10 mA cm^-2)and OER(overpotential of 340 mV@10 mA cm^-2).Further,V-doped CoP nanoparticles used as anode and cathode simultaneously in a cell require only 370 mV to achieve a current density of 10 mA cm^-2.The outstanding electrocatalytic activity may be ascribed to the improved conductivity and intrinsic activity owing to phosphating and the doping of V element.In addition,the long-term stability of V-doped Co P has been obtained.Therefore,metal doping into transition metal-based phosphides may be a promising strategy for the remarkable bifunctional electrocatalyst for water splitting.
