Developing alloys with exceptional strength-ductility combinations across a broad temperature range is crucial for advanced structural applications.The emerging face-centered cubic medium-entropy alloys(MEAs)demonstra...Developing alloys with exceptional strength-ductility combinations across a broad temperature range is crucial for advanced structural applications.The emerging face-centered cubic medium-entropy alloys(MEAs)demonstrate outstanding mechanical properties at both ambient and cryogenic temperatures.They are anticipated to extend their applicability to elevated temperatures,owing to their inherent advantages in leveraging multiple strengthening and deformation mechanisms.Here,a dual heterostructure,comprising of heterogeneous grain structure with heterogeneous distribution of the micro-scale Nb-rich Laves phases,is introduced in a CrCoNi-based MEA through thermo-mechanical processing.Additionally,a high-density nano-coherentγ’phase is introduced within the grains through isothermal aging treatments.The superior thermal stability of the heterogeneously distributed precipitates enables the dual heterostructure to persist at temperatures up to 1073 K,allowing the MEA to maintain excellent mechanical properties across a wide temperature range.The yield strength of the dual-heterogeneous-structured MEA reaches up to 1.2 GPa,1.1 GPa,0.8 GPa,and 0.6 GPa,coupled with total elongation values of 28.6%,28.4%,12.6%,and 6.1%at 93 K,298 K,873 K,and 1073 K,respectively.The high yield strength primar-ily stems from precipitation strengthening and hetero-deformation-induced strengthening.The high flow stress and low stacking fault energy of the dual-heterogeneous-structured MEA promote the formation of high-density stacking faults and nanotwins during deformation from 93 K to 1073 K,and their density increase with decreasing deformation temperature.This greatly contributes to the enhanced strainhardening capability and ductility across a wide temperature range.This study offers a practical solution for designing dual-heterogeneous-structured MEAs with both high yield strength and large ductility across a wide temperature range.展开更多
Poly(_(L)-lactide)(PLLA),a leading biodegradable polyester,has demonstrated potential as a sustainable alternative,owing to its excellent biodegradability and rigidity.However,their slow crystallization kinetics and p...Poly(_(L)-lactide)(PLLA),a leading biodegradable polyester,has demonstrated potential as a sustainable alternative,owing to its excellent biodegradability and rigidity.However,their slow crystallization kinetics and poor heat resistance limit their application scope.Recent advances have highlighted that the combination of extensional flow and thermal fields can achieve toughness–stiffness balance,high transparency,and good heat resistance.However,the effect of extensional flow on the post-non-isothermal crystallization of PLLA during heating and the resulting crystalline texture remains unclear.In this study,PLLA with a heterogeneous amorphous structure and oriented polymorph was prepared by extensional flow.The effect of heterogeneous amorphous structures on non-isothermal crystallization kinetics during the heating process was studied by thermal analysis,polarized optical microscopy,infrared spectroscopy,and ex situ/in situ X-ray characterization.These results clearly illustrate that extensional flow enhances the formation of oriented crystalline structures,accelerates non-isothermal crystallization,and modulates the polymorphic composition of PLLA.Moreover,an unexpected dual cold-crystallization behavior is identified in ordered PLLA samples upon extensional flow,which is from the extensional flow-induced heterogeneous amorphous phase into α' phase(low-temperature peak)and the pristine amorphous phase intoαphase(high-temperature peak).The extensional flow primarily promotes the formation of the more perfectαandα'phases,but has a negative effect on the final content ofαphase formed after cold crystallization andα'-to-αphase transformation.The findings of this work advance the understanding of PLLA non-isothermal crystallization after extensional flow and offer valuable guidance for high-performance PLLA upon heat treatment in practical processing.展开更多
Based on the characteristics of urban-rural dual economic structure in China,we build a dynamic endogenous urban-rural dual economic model closely linked to China's reality,and carry out mathematical economics ana...Based on the characteristics of urban-rural dual economic structure in China,we build a dynamic endogenous urban-rural dual economic model closely linked to China's reality,and carry out mathematical economics analysis of optimized conditions for urban and rural sectors. The main results show that:(i) The labor growth rate of urban-rural sectors must be greater than the time discount rate,or else there would be a vicious cycle of diminishing returns in the sectors;(ii) The accumulation rate of physical capital and human capital of urban-rural sectors,and the rate of technological progress,need to be greater than the corresponding depreciation rate plus the time discount rate,otherwise there would be a vicious cycle of diminishing returns in the sectors;(iii) The low accumulation rate in the rural sector,and the occurrence of labor outflow,human capital loss and lack of investment,will expand income gap between urban and rural areas,which is a reason for solidification of urban-rural dual economic structure.展开更多
China＇ s urban and rural economic and social structures are persisted, perfectly shaped, very typical. Since the new century, the Chinese government began to adjust serious distorted urban-rural relations. New rural ...China＇ s urban and rural economic and social structures are persisted, perfectly shaped, very typical. Since the new century, the Chinese government began to adjust serious distorted urban-rural relations. New rural construction, total abolition of agricultural tax, the construction of modern agriculture and other major strategic decisions have been introduced; free compulsory education in rural areas, the new rural cooperative medical care, rural public infrastructure, cultural services and other specific measures have been rolled out building. But these still can not slow down our growing urban-rural gap, China＇ s economic and social development is still running under the urban and rural pattern, and the trend has increased.展开更多
Firstly,this paper reviews and analyzes historic background of urban-rural integration of Chongqing,and the evolution and trend of urban and rural dual economic structure.On the basis of previous researches,it selects...Firstly,this paper reviews and analyzes historic background of urban-rural integration of Chongqing,and the evolution and trend of urban and rural dual economic structure.On the basis of previous researches,it selects factors and variables influencing urban and rural dual economic structure,and establishes an econometric model.By state space Kalman filtering method,it analyzes dynamic influence of factors upon urban-rural dual economic intensity.According to empirical conclusion,it puts forward corresponding policy recommendations for promoting integrated urban and rural economic development of Chongqing.展开更多
Controlled photocatalytic conversion of CO_(2) into premium fuel such as methane(CH4)offers a sustainable pathway towards a carbon energy cycle.However,the photocatalytic efficiency and selectivity are still unsatisfa...Controlled photocatalytic conversion of CO_(2) into premium fuel such as methane(CH4)offers a sustainable pathway towards a carbon energy cycle.However,the photocatalytic efficiency and selectivity are still unsatisfactory due to the limited availability of active sites on the current photocatalysts.To resolve this issue,the design of oxygen vacancies(OVs)in metal-oxide semiconductors is an effective option.Herein,in situ deposition of TiO_(2) onto SiO_(2) nanospheres to construct a SiO_(2)@TiO_(2) core-shell structure was performed to modulate the oxygen vacancy concentrations.Meanwhile,charge redistribution led to the formation of abundant OV-regulated Ti-Ti(Ti-OV-Ti)dual sites.It is revealed that Ti-OV-Ti dual sites served as the key active site for capturing the photogenerated electrons during light-driven CO_(2) reduction reaction(CO_(2)RR).Such electron-rich active sites enabled efficient CO_(2) adsorption and activation,thus lowering the energy barrier associated with the rate-determining step.More importantly,the formation of a highly stable*CHO intermediate at Ti-OV-Ti dual sites energetically favored the reaction pathway towards the production of CH4 rather than CO,thereby facilitating the selective product of CH_(4).As a result,SiO_(2)@TiO_(2)-50 with an optimized oxygen vacancy concentration of 9.0% showed a remarkable selectivity(90.32%)for CH_(4) production with a rate of 13.21μmol g^(-1) h^(-1),which is 17.38-fold higher than that of pristine TiO_(2).This study provides a new avenue for engineering superior photocatalysts through a rational methodology towards selective reduction of CO_(2).展开更多
The irreversible phase transition and interface side reactions during the cycling process severely limit the large scale application of nickel-rich layered oxides Li[Ni_(x)Co_(y)Mn_(1−x−y)]O_(2)(NCM,x>0.8).Herein,w...The irreversible phase transition and interface side reactions during the cycling process severely limit the large scale application of nickel-rich layered oxides Li[Ni_(x)Co_(y)Mn_(1−x−y)]O_(2)(NCM,x>0.8).Herein,we have designed LiNi_(0.8)Co_(0.1)Mn 0.1 O_(2)cathodes modified by Nb/Al co-doping and LiNbO_(3)/LiAlO_(2)composite coating.Detailed characterization reveals that Nb/Al co-doping can stabilize the crystal structure of the cathodes and expand the layer spacing of the layered lattice,thereby increasing the diffusion rate and reversibility of Li^(+).And the composite coatings can improve the electrochemical kinetic and inhibit the erosion of acidic substances by hindering direct contact between the cathodes and electrolyte.As a result,the Ni-rich cathodes with dual modification can still exhibit a higher capacity of 184.02 mA·h/g after 100 cycles with a capacity retention of up to 98.1%,and can still release a capacity of 161.6 mA·h/g at a high rate of 7 C,meanwhile,it shows excellent thermal stability compared to bare NCM.This work provides a new perspective for enhancing electrochemical properties of cathodes through integrated strategies.展开更多
Firstly,this paper conducts theoretical analysis and current situation analysis,and then proposes research hypotheses.Secondly,using spatial Dubin model and partial differential method,it empirically studies the impac...Firstly,this paper conducts theoretical analysis and current situation analysis,and then proposes research hypotheses.Secondly,using spatial Dubin model and partial differential method,it empirically studies the impact of industrial structure advancement and rationalization on the urban-rural income gap.The results show that:(1)Both industrial structure and urban-rural income gap have significant spatial dependence;(2)The increase in the industrial structure rationalization will narrow the urban-rural income gap in local region,while its spillover effect on neighboring areas is not obvious.(3)The impact of the industrial structure advancement on the urban-rural income gap is not linear.It is first expanded and then narrowed.The industrial structure advancement in the Yangtze River Delta will generally narrow the urban-rural income gap at this stage.Finally,this paper put forward relevant suggestions.展开更多
With the continuous development of political, economic,social, empty nesters and more problems, it is not a simple personal issues, has become urgent to break the social proposition.This paper intr~,duces the concepts...With the continuous development of political, economic,social, empty nesters and more problems, it is not a simple personal issues, has become urgent to break the social proposition.This paper intr~,duces the concepts at the same time,Further analysis of the current situation empty-nesters of the problem and sort out the history of urban-rural dual structure,Finally, find information put forward some countermeasures and suggestions.展开更多
The research progress of soil loss under the dual structure of southwest karst is systematically studied. The results show that the research of the soil erosion in karst mountainous area started late, and the basic re...The research progress of soil loss under the dual structure of southwest karst is systematically studied. The results show that the research of the soil erosion in karst mountainous area started late, and the basic research is lagging. Most of the existing research results focus on the present situation, causes and control measures of surface erosion. The view of underground soil loss in the context of karst diploid structure has been recognized by most scholars. However, limited to the research methods and the lack of observational data, the way of underground soil loss, the amount of loss and its harm are still unclear. Therefore, seeking the necessary technical means to carry out the necessary field observation from the way and process of loss is the focus of the study of soil loss under karst structure in the future.展开更多
A numerical model is developed by use of the boundary integral equation method to investigate the responses of a two-dimensional floating structure. The structure under consideration consisting of two pontoons, is con...A numerical model is developed by use of the boundary integral equation method to investigate the responses of a two-dimensional floating structure. The structure under consideration consisting of two pontoons, is connected by a rigid framework, and linked to the sea floor by a mooring system. The theoretical conception is based on potential theory with hnear external forces, and applied to an arbitrarily shaped body and water depth. The discussion includes the influence of draft and space between pontoons on the responses of the floating structure. Finally, the validity of the method is adequately verified by experimental results.展开更多
Shock wave/boundary layer interaction(SWBLI)is still one of the unresolved bottlenecks that restrict the development of more advanced flight vehicles.Supersonic forward-facing step(FFS),an extreme case of compression ...Shock wave/boundary layer interaction(SWBLI)is still one of the unresolved bottlenecks that restrict the development of more advanced flight vehicles.Supersonic forward-facing step(FFS),an extreme case of compression ramp,often occurs severe SWBLIs with a large separation bubble.In this paper,experimental investigations on vortical structures and density fluctuations characteristics of supersonic FFS controlled by self-sustaining dual synthetic jets(SDSJ)are carried out in a Mach number 2.95 wind tunnel.High spatial–temporal resolution flowfield images of FFS without/with active flow control are captured by adopting nano-particle-based planar laser scattering technique.The control effects of the distance between the actuator and the step are mainly compared.The paper finds that the SDSJ can effectively change the feature of flowfield,eliminate the separation shock and the reattachment shock,compel the original shock induced by the step leading edge to distort and reduce its intensity finally.Density fluctuations analysis demonstrates that the whole flows seem to move upstream with the increase of distance(dS-J).Discrete Fourier transformation spectrums results reveal that the fluctuations are mainly located in the low-frequency region at first.High-frequency components and frequency bandwidth increase slightly after the SDSJ are applied.展开更多
Multiphase flow in low permeability porous media is involved in numerous energy and environmental applications.However,a complete description of this process is challenging due to the limited modeling scale and the ef...Multiphase flow in low permeability porous media is involved in numerous energy and environmental applications.However,a complete description of this process is challenging due to the limited modeling scale and the effects of complex pore structures and wettability.To address this issue,based on the digital rock of low permeability sandstone,a direct numerical simulation is performed considering the interphase drag and boundary slip to clarify the microscopic water-oil displacement process.In addition,a dual-porosity pore network model(PNM)is constructed to obtain the water-oil relative permeability of the sample.The displacement efficiency as a recovery process is assessed under different wetting and pore structure properties.Results show that microscopic displacement mechanisms explain the corresponding macroscopic relative permeability.The injected water breaks through the outlet earlier with a large mass flow,while thick oil films exist in rough hydrophobic surfaces and poorly connected pores.The variation of water-oil relative permeability is significant,and residual oil saturation is high in the oil-wet system.The flooding is extensive,and the residual oil is trapped in complex pore networks for hydrophilic pore surfaces;thus,water relative permeability is lower in the water-wet system.While the displacement efficiency is the worst in mixed-wetting systems for poor water connectivity.Microporosity negatively correlates with invading oil volume fraction due to strong capillary resistance,and a large microporosity corresponds to low residual oil saturation.This work provides insights into the water-oil flow from different modeling perspectives and helps to optimize the development plan for enhanced recovery.展开更多
The phase composition, phase transition and phase structure transformation of the wire-cut section of functionally graded WC-Co cemented carbide with dual phase structure were investigated by XRD phase analysis. It is...The phase composition, phase transition and phase structure transformation of the wire-cut section of functionally graded WC-Co cemented carbide with dual phase structure were investigated by XRD phase analysis. It is shown that the composition of η phase in the core zone is Co_3W_3C (M_6 C type). The structure of cobalt based solid solution binder phase is fcc type. At the cooling stage of the sintering process, the phase transition of η phase, i.e. M_6C→M_12C and the martensitic phase transition of the cobalt based solid solution binder phase, i.e. fcc→hcp are suppressed, which facilitates the strengthening of the alloy. Because the instantaneous temperature of the discharge channel is as high as 10 000 ℃ during the wire cutting process, the processed surface is oxidized. Nevertheless, the oxide layer thickness is in micro grade. In the oxide film, η phase is decomposed into W_2C and CoO, and cobalt based solid solution binder is selectively oxidized, while WC remains stable due to the existence of carbon containing liquid organic cutting medium.展开更多
Hierarchically three-dimensional(3D)materials present a pivotal challenge and opportunity in achieving effective microwave absorption with synergistic effects.In this work,α-Fe_(2)O_(3)@ZrO_(2)with core-shell structu...Hierarchically three-dimensional(3D)materials present a pivotal challenge and opportunity in achieving effective microwave absorption with synergistic effects.In this work,α-Fe_(2)O_(3)@ZrO_(2)with core-shell structure were fabricated in-situ on aramid nanofibers by a solvothermal method.Following calcination,3D ZrO_(2)/Fe_(3)O_(4)/C nanocomposites with Janus structure have been successfully synthesized.By controlling the lattice match and mismatch in both processes,a core-shell structure ofα-Fe_(2)O_(3)@ZrO_(2)and Janus structure of ZrO_(2)/Fe_(3)O_(4)have been well-define performed.The composite material ZrO_(2)/Fe_(3)O_(4)/C-700 has a minimum reflection loss(RLmin)of−67.4 dB at a thickness of 2.0 mm.The effective absorption bandwidth(EAB)at a thickness of 2.4 mm is 6.0 GHz(11.0-17.0 GHz).This study provides a novel strategy for fabricating high-efficiency electromagnetic wave absorption materials with dual synergistic effects in nanosized scale.展开更多
The genetic based Dual Instinct Theory is determined by evolutionary history. Aggression is required for survival and sex for propagation of species. Aggressive and sexual drive derivatives with their corresponding de...The genetic based Dual Instinct Theory is determined by evolutionary history. Aggression is required for survival and sex for propagation of species. Aggressive and sexual drive derivatives with their corresponding defence mechanisms are combined with biologically based stages of infant/child development and the functional entity of Structural Theory. This model of human nature is the applied to the diagnostic categories of DSM-5-TR. Objectives: To follow the innate Dual Instinct Theory from life to death and through Artificial Intelligence;connect it with biological stages of development of the Structural Theory and illustrate its manifestations in DSM-5-TR classifications. Method: Review of selected published literature. Applying the principle of focus and cognition of informed clinical observation of innate drive derivatives in conjunction with The Structural Theory. Both theories are functional entities with no structures involved. Sigmund Freud’s biologically based stages of development;oral, anal, genital pubic, adult, and geriatric along with a variety of unconscious, automatic, and persistent defense mechanisms are selectively folded into diagnosis listed in the manual.展开更多
A dual structure of composite right/left handed (CRLH) transmission line (TL) is analyzed in which an inductance LR is in parallel with a capacitance CL and a shunt capacitance CR is in series with an inductance LL. B...A dual structure of composite right/left handed (CRLH) transmission line (TL) is analyzed in which an inductance LR is in parallel with a capacitance CL and a shunt capacitance CR is in series with an inductance LL. Both the distributed and lumped cases are considered. The dispersion diagram and transmission properties of the dual CRLH TL are given and compared with those of a standard CRLH TL. Contrary to the frequency response of a standard CRLH TL, a dual CRLH TL has a left-handed (negative phase shift) band at higher frequencies and a right-handed (positive phase shift) band at lower frequencies. A novel dual-band balun is presented as an application.展开更多
The detailed kinematic structure of a heavy rain event that occurred in the middle reaches of the Yangtze River was investigated using dual-Doppler radar observation. A variational analysis method was developed to obt...The detailed kinematic structure of a heavy rain event that occurred in the middle reaches of the Yangtze River was investigated using dual-Doppler radar observation. A variational analysis method was developed to obtain the three-dimensional wind fields. Before the analysis, a data preprocessing procedure was carried out, in which the temporal variation with the scanning time interval and the effect of the earth curvature on the data position were taken into account. The analysis shows that a shear line in the lower and middle levels played an important role in the rainfall event. The precipitation fell mainly on the south end of the shear line where southerly flow prevailed and convergence and updraft were obvious. With the movement and decay of the shear line, the precipitation moved and decayed correspondingly.展开更多
Dual-asymmetric poly（vinylidene fluoride） （PVDF） separators have been fabricated by thermally induced phase separation with dimethyl sulfone （DMSO2） and glycerol as mixed diluents. The separators have a porous b...Dual-asymmetric poly（vinylidene fluoride） （PVDF） separators have been fabricated by thermally induced phase separation with dimethyl sulfone （DMSO2） and glycerol as mixed diluents. The separators have a porous bulk with large interconnected pores （-1.0 μm） and two surfaces with small pores （-30 nm）. This dual-asymmetric porous structure endows the separators with higher electrolyte uptake amount and rapider uptake rate, as well as better electrolyte retention ability than the commercialized Celgard 2400. The separators even maintain their dimensional stability up to 160 ℃, at which temperature the surface pores close up, leading to a dramatic decrease of air permeability. The electrolyte filled separators also show high ion conductivity （1.72 mS.cm-1） at room temperature. Lithium iron phosphate （LiFePO4）/lithium （Li） cells using these separators display superior discharge capacity and better rate performance as compared with those from the commercialized ones. The results provide new insight into the design and development of separators for high-performance lithium ion batteries with enhanced safety.展开更多
The as-cast structures of semi-continuous casting aluminum alloy under dual-frequency electromagnetic field were experimental investigated.The results showed that the electromagnetic fields with different frequency ha...The as-cast structures of semi-continuous casting aluminum alloy under dual-frequency electromagnetic field were experimental investigated.The results showed that the electromagnetic fields with different frequency have different function for improving the cast structure of aluminum alloy casting.Imposing medium frequency electromagnetic field can change the surface morphology of melt pool in the casting process,increase the height of melt meniscus,improve the ingot's surface quality,and reduce the thickness of surface segregation.The low frequency electromagnetic field is most obvious to as-cast structure improvement effect because of its high permeability in conductance material.Imposing low-frequency electromagnetic field can change flow pattern and temperature field in the melt,strengthen the heat transfer and mass transfer in the melt,decrease the depth of the sttmp and reduce the temperature gradient.Thus,the as-cast structures are greatly refined,which can lead to the fine equiaxed as-cast structures throughout the cross-section of the ingot.展开更多
基金supported by the Tianjin Science and Technology Plan Project(No.22JCQNJC01280)the Central Funds Guiding the Local Science and Technology Development of Hebei Province(Nos.226Z1001G and 226Z1012G)+1 种基金the National Natural Science Foundation of China(No.52002109,52071124)the Young Elite Scientists Sponsorship Program by CAST(No.2022QNRC001).
文摘Developing alloys with exceptional strength-ductility combinations across a broad temperature range is crucial for advanced structural applications.The emerging face-centered cubic medium-entropy alloys(MEAs)demonstrate outstanding mechanical properties at both ambient and cryogenic temperatures.They are anticipated to extend their applicability to elevated temperatures,owing to their inherent advantages in leveraging multiple strengthening and deformation mechanisms.Here,a dual heterostructure,comprising of heterogeneous grain structure with heterogeneous distribution of the micro-scale Nb-rich Laves phases,is introduced in a CrCoNi-based MEA through thermo-mechanical processing.Additionally,a high-density nano-coherentγ’phase is introduced within the grains through isothermal aging treatments.The superior thermal stability of the heterogeneously distributed precipitates enables the dual heterostructure to persist at temperatures up to 1073 K,allowing the MEA to maintain excellent mechanical properties across a wide temperature range.The yield strength of the dual-heterogeneous-structured MEA reaches up to 1.2 GPa,1.1 GPa,0.8 GPa,and 0.6 GPa,coupled with total elongation values of 28.6%,28.4%,12.6%,and 6.1%at 93 K,298 K,873 K,and 1073 K,respectively.The high yield strength primar-ily stems from precipitation strengthening and hetero-deformation-induced strengthening.The high flow stress and low stacking fault energy of the dual-heterogeneous-structured MEA promote the formation of high-density stacking faults and nanotwins during deformation from 93 K to 1073 K,and their density increase with decreasing deformation temperature.This greatly contributes to the enhanced strainhardening capability and ductility across a wide temperature range.This study offers a practical solution for designing dual-heterogeneous-structured MEAs with both high yield strength and large ductility across a wide temperature range.
基金supported by the National Natural Science Foundation of China(Nos.U23A20583,52033005,U21A2090,and 52173040)Department of Science and Technology of Sichuan Province(No.2024NSFTD0003)。
文摘Poly(_(L)-lactide)(PLLA),a leading biodegradable polyester,has demonstrated potential as a sustainable alternative,owing to its excellent biodegradability and rigidity.However,their slow crystallization kinetics and poor heat resistance limit their application scope.Recent advances have highlighted that the combination of extensional flow and thermal fields can achieve toughness–stiffness balance,high transparency,and good heat resistance.However,the effect of extensional flow on the post-non-isothermal crystallization of PLLA during heating and the resulting crystalline texture remains unclear.In this study,PLLA with a heterogeneous amorphous structure and oriented polymorph was prepared by extensional flow.The effect of heterogeneous amorphous structures on non-isothermal crystallization kinetics during the heating process was studied by thermal analysis,polarized optical microscopy,infrared spectroscopy,and ex situ/in situ X-ray characterization.These results clearly illustrate that extensional flow enhances the formation of oriented crystalline structures,accelerates non-isothermal crystallization,and modulates the polymorphic composition of PLLA.Moreover,an unexpected dual cold-crystallization behavior is identified in ordered PLLA samples upon extensional flow,which is from the extensional flow-induced heterogeneous amorphous phase into α' phase(low-temperature peak)and the pristine amorphous phase intoαphase(high-temperature peak).The extensional flow primarily promotes the formation of the more perfectαandα'phases,but has a negative effect on the final content ofαphase formed after cold crystallization andα'-to-αphase transformation.The findings of this work advance the understanding of PLLA non-isothermal crystallization after extensional flow and offer valuable guidance for high-performance PLLA upon heat treatment in practical processing.
基金Supported by Chongqing Social Science Planning Project(2010YBJJ13)the Fundamental Research Funds for the Central Universities(XDJK2010C103)+1 种基金Humanities and Social Sciences Youth Project,the Ministry of Education(10YJC630205)Chongqing Key Humanities and Social Sciences Project(SWU 0810026)
文摘Based on the characteristics of urban-rural dual economic structure in China,we build a dynamic endogenous urban-rural dual economic model closely linked to China's reality,and carry out mathematical economics analysis of optimized conditions for urban and rural sectors. The main results show that:(i) The labor growth rate of urban-rural sectors must be greater than the time discount rate,or else there would be a vicious cycle of diminishing returns in the sectors;(ii) The accumulation rate of physical capital and human capital of urban-rural sectors,and the rate of technological progress,need to be greater than the corresponding depreciation rate plus the time discount rate,otherwise there would be a vicious cycle of diminishing returns in the sectors;(iii) The low accumulation rate in the rural sector,and the occurrence of labor outflow,human capital loss and lack of investment,will expand income gap between urban and rural areas,which is a reason for solidification of urban-rural dual economic structure.
文摘China＇ s urban and rural economic and social structures are persisted, perfectly shaped, very typical. Since the new century, the Chinese government began to adjust serious distorted urban-rural relations. New rural construction, total abolition of agricultural tax, the construction of modern agriculture and other major strategic decisions have been introduced; free compulsory education in rural areas, the new rural cooperative medical care, rural public infrastructure, cultural services and other specific measures have been rolled out building. But these still can not slow down our growing urban-rural gap, China＇ s economic and social development is still running under the urban and rural pattern, and the trend has increased.
基金Supported by Social Science Planning Project of Chongqing(2010YBJJ13)the Fundamental Research Funds for the Central Universities(XDJK2010C103)Ph.D Foundation Project of Southwest University(SWU1209303)
文摘Firstly,this paper reviews and analyzes historic background of urban-rural integration of Chongqing,and the evolution and trend of urban and rural dual economic structure.On the basis of previous researches,it selects factors and variables influencing urban and rural dual economic structure,and establishes an econometric model.By state space Kalman filtering method,it analyzes dynamic influence of factors upon urban-rural dual economic intensity.According to empirical conclusion,it puts forward corresponding policy recommendations for promoting integrated urban and rural economic development of Chongqing.
基金supported by the National Natural Science Foundation of China(No.21773089,22202037)the Science and Technology Development Plan Project of Jilin Province,China(No.20240101192JC)the Fundamental Research Funds for the Central Universities(No.2412023QD019).
文摘Controlled photocatalytic conversion of CO_(2) into premium fuel such as methane(CH4)offers a sustainable pathway towards a carbon energy cycle.However,the photocatalytic efficiency and selectivity are still unsatisfactory due to the limited availability of active sites on the current photocatalysts.To resolve this issue,the design of oxygen vacancies(OVs)in metal-oxide semiconductors is an effective option.Herein,in situ deposition of TiO_(2) onto SiO_(2) nanospheres to construct a SiO_(2)@TiO_(2) core-shell structure was performed to modulate the oxygen vacancy concentrations.Meanwhile,charge redistribution led to the formation of abundant OV-regulated Ti-Ti(Ti-OV-Ti)dual sites.It is revealed that Ti-OV-Ti dual sites served as the key active site for capturing the photogenerated electrons during light-driven CO_(2) reduction reaction(CO_(2)RR).Such electron-rich active sites enabled efficient CO_(2) adsorption and activation,thus lowering the energy barrier associated with the rate-determining step.More importantly,the formation of a highly stable*CHO intermediate at Ti-OV-Ti dual sites energetically favored the reaction pathway towards the production of CH4 rather than CO,thereby facilitating the selective product of CH_(4).As a result,SiO_(2)@TiO_(2)-50 with an optimized oxygen vacancy concentration of 9.0% showed a remarkable selectivity(90.32%)for CH_(4) production with a rate of 13.21μmol g^(-1) h^(-1),which is 17.38-fold higher than that of pristine TiO_(2).This study provides a new avenue for engineering superior photocatalysts through a rational methodology towards selective reduction of CO_(2).
基金Project(2023JJ40759)supported by the Natural Science Foundation of Hunan Province,China。
文摘The irreversible phase transition and interface side reactions during the cycling process severely limit the large scale application of nickel-rich layered oxides Li[Ni_(x)Co_(y)Mn_(1−x−y)]O_(2)(NCM,x>0.8).Herein,we have designed LiNi_(0.8)Co_(0.1)Mn 0.1 O_(2)cathodes modified by Nb/Al co-doping and LiNbO_(3)/LiAlO_(2)composite coating.Detailed characterization reveals that Nb/Al co-doping can stabilize the crystal structure of the cathodes and expand the layer spacing of the layered lattice,thereby increasing the diffusion rate and reversibility of Li^(+).And the composite coatings can improve the electrochemical kinetic and inhibit the erosion of acidic substances by hindering direct contact between the cathodes and electrolyte.As a result,the Ni-rich cathodes with dual modification can still exhibit a higher capacity of 184.02 mA·h/g after 100 cycles with a capacity retention of up to 98.1%,and can still release a capacity of 161.6 mA·h/g at a high rate of 7 C,meanwhile,it shows excellent thermal stability compared to bare NCM.This work provides a new perspective for enhancing electrochemical properties of cathodes through integrated strategies.
文摘Firstly,this paper conducts theoretical analysis and current situation analysis,and then proposes research hypotheses.Secondly,using spatial Dubin model and partial differential method,it empirically studies the impact of industrial structure advancement and rationalization on the urban-rural income gap.The results show that:(1)Both industrial structure and urban-rural income gap have significant spatial dependence;(2)The increase in the industrial structure rationalization will narrow the urban-rural income gap in local region,while its spillover effect on neighboring areas is not obvious.(3)The impact of the industrial structure advancement on the urban-rural income gap is not linear.It is first expanded and then narrowed.The industrial structure advancement in the Yangtze River Delta will generally narrow the urban-rural income gap at this stage.Finally,this paper put forward relevant suggestions.
文摘With the continuous development of political, economic,social, empty nesters and more problems, it is not a simple personal issues, has become urgent to break the social proposition.This paper intr~,duces the concepts at the same time,Further analysis of the current situation empty-nesters of the problem and sort out the history of urban-rural dual structure,Finally, find information put forward some countermeasures and suggestions.
基金Supported by the National Science&Technology Pillar Program during the Twelfth FiveYear Plan Period of China(2012BAD05B06)the Fund Program for Science and Technology of Guizhou in 2012(Qiankehe Code J LKS[2012]No.27~~
文摘The research progress of soil loss under the dual structure of southwest karst is systematically studied. The results show that the research of the soil erosion in karst mountainous area started late, and the basic research is lagging. Most of the existing research results focus on the present situation, causes and control measures of surface erosion. The view of underground soil loss in the context of karst diploid structure has been recognized by most scholars. However, limited to the research methods and the lack of observational data, the way of underground soil loss, the amount of loss and its harm are still unclear. Therefore, seeking the necessary technical means to carry out the necessary field observation from the way and process of loss is the focus of the study of soil loss under karst structure in the future.
文摘A numerical model is developed by use of the boundary integral equation method to investigate the responses of a two-dimensional floating structure. The structure under consideration consisting of two pontoons, is connected by a rigid framework, and linked to the sea floor by a mooring system. The theoretical conception is based on potential theory with hnear external forces, and applied to an arbitrarily shaped body and water depth. The discussion includes the influence of draft and space between pontoons on the responses of the floating structure. Finally, the validity of the method is adequately verified by experimental results.
基金The present research was supported by the National Natural Science Foundation of China(Grants 11972369,51809271,11872374 and 11602299).
文摘Shock wave/boundary layer interaction(SWBLI)is still one of the unresolved bottlenecks that restrict the development of more advanced flight vehicles.Supersonic forward-facing step(FFS),an extreme case of compression ramp,often occurs severe SWBLIs with a large separation bubble.In this paper,experimental investigations on vortical structures and density fluctuations characteristics of supersonic FFS controlled by self-sustaining dual synthetic jets(SDSJ)are carried out in a Mach number 2.95 wind tunnel.High spatial–temporal resolution flowfield images of FFS without/with active flow control are captured by adopting nano-particle-based planar laser scattering technique.The control effects of the distance between the actuator and the step are mainly compared.The paper finds that the SDSJ can effectively change the feature of flowfield,eliminate the separation shock and the reattachment shock,compel the original shock induced by the step leading edge to distort and reduce its intensity finally.Density fluctuations analysis demonstrates that the whole flows seem to move upstream with the increase of distance(dS-J).Discrete Fourier transformation spectrums results reveal that the fluctuations are mainly located in the low-frequency region at first.High-frequency components and frequency bandwidth increase slightly after the SDSJ are applied.
基金supported by National Natural Science Foundation of China(Grant No.42172159)Science Foundation of China University of Petroleum,Beijing(Grant No.2462023XKBH002).
文摘Multiphase flow in low permeability porous media is involved in numerous energy and environmental applications.However,a complete description of this process is challenging due to the limited modeling scale and the effects of complex pore structures and wettability.To address this issue,based on the digital rock of low permeability sandstone,a direct numerical simulation is performed considering the interphase drag and boundary slip to clarify the microscopic water-oil displacement process.In addition,a dual-porosity pore network model(PNM)is constructed to obtain the water-oil relative permeability of the sample.The displacement efficiency as a recovery process is assessed under different wetting and pore structure properties.Results show that microscopic displacement mechanisms explain the corresponding macroscopic relative permeability.The injected water breaks through the outlet earlier with a large mass flow,while thick oil films exist in rough hydrophobic surfaces and poorly connected pores.The variation of water-oil relative permeability is significant,and residual oil saturation is high in the oil-wet system.The flooding is extensive,and the residual oil is trapped in complex pore networks for hydrophilic pore surfaces;thus,water relative permeability is lower in the water-wet system.While the displacement efficiency is the worst in mixed-wetting systems for poor water connectivity.Microporosity negatively correlates with invading oil volume fraction due to strong capillary resistance,and a large microporosity corresponds to low residual oil saturation.This work provides insights into the water-oil flow from different modeling perspectives and helps to optimize the development plan for enhanced recovery.
基金Projects(50323008, 50574104) supported by the National Natural Science Foundation of ChinaProject (04JJ3084) supported by the Natural Science Foundation of Hunan Province, China
文摘The phase composition, phase transition and phase structure transformation of the wire-cut section of functionally graded WC-Co cemented carbide with dual phase structure were investigated by XRD phase analysis. It is shown that the composition of η phase in the core zone is Co_3W_3C (M_6 C type). The structure of cobalt based solid solution binder phase is fcc type. At the cooling stage of the sintering process, the phase transition of η phase, i.e. M_6C→M_12C and the martensitic phase transition of the cobalt based solid solution binder phase, i.e. fcc→hcp are suppressed, which facilitates the strengthening of the alloy. Because the instantaneous temperature of the discharge channel is as high as 10 000 ℃ during the wire cutting process, the processed surface is oxidized. Nevertheless, the oxide layer thickness is in micro grade. In the oxide film, η phase is decomposed into W_2C and CoO, and cobalt based solid solution binder is selectively oxidized, while WC remains stable due to the existence of carbon containing liquid organic cutting medium.
基金supported by the National Natural Science Foundation of China(No.51873004)。
文摘Hierarchically three-dimensional(3D)materials present a pivotal challenge and opportunity in achieving effective microwave absorption with synergistic effects.In this work,α-Fe_(2)O_(3)@ZrO_(2)with core-shell structure were fabricated in-situ on aramid nanofibers by a solvothermal method.Following calcination,3D ZrO_(2)/Fe_(3)O_(4)/C nanocomposites with Janus structure have been successfully synthesized.By controlling the lattice match and mismatch in both processes,a core-shell structure ofα-Fe_(2)O_(3)@ZrO_(2)and Janus structure of ZrO_(2)/Fe_(3)O_(4)have been well-define performed.The composite material ZrO_(2)/Fe_(3)O_(4)/C-700 has a minimum reflection loss(RLmin)of−67.4 dB at a thickness of 2.0 mm.The effective absorption bandwidth(EAB)at a thickness of 2.4 mm is 6.0 GHz(11.0-17.0 GHz).This study provides a novel strategy for fabricating high-efficiency electromagnetic wave absorption materials with dual synergistic effects in nanosized scale.
文摘The genetic based Dual Instinct Theory is determined by evolutionary history. Aggression is required for survival and sex for propagation of species. Aggressive and sexual drive derivatives with their corresponding defence mechanisms are combined with biologically based stages of infant/child development and the functional entity of Structural Theory. This model of human nature is the applied to the diagnostic categories of DSM-5-TR. Objectives: To follow the innate Dual Instinct Theory from life to death and through Artificial Intelligence;connect it with biological stages of development of the Structural Theory and illustrate its manifestations in DSM-5-TR classifications. Method: Review of selected published literature. Applying the principle of focus and cognition of informed clinical observation of innate drive derivatives in conjunction with The Structural Theory. Both theories are functional entities with no structures involved. Sigmund Freud’s biologically based stages of development;oral, anal, genital pubic, adult, and geriatric along with a variety of unconscious, automatic, and persistent defense mechanisms are selectively folded into diagnosis listed in the manual.
基金Project supported by the National Basic Research Program (973) of China (No. 2004CB719802), and the Science and Technology De-partment of Zhejiang Province (No. 2005C31004), China
文摘A dual structure of composite right/left handed (CRLH) transmission line (TL) is analyzed in which an inductance LR is in parallel with a capacitance CL and a shunt capacitance CR is in series with an inductance LL. Both the distributed and lumped cases are considered. The dispersion diagram and transmission properties of the dual CRLH TL are given and compared with those of a standard CRLH TL. Contrary to the frequency response of a standard CRLH TL, a dual CRLH TL has a left-handed (negative phase shift) band at higher frequencies and a right-handed (positive phase shift) band at lower frequencies. A novel dual-band balun is presented as an application.
基金This work was supported by the National Natural Science Foundation of China(Grant No.40175010)
文摘The detailed kinematic structure of a heavy rain event that occurred in the middle reaches of the Yangtze River was investigated using dual-Doppler radar observation. A variational analysis method was developed to obtain the three-dimensional wind fields. Before the analysis, a data preprocessing procedure was carried out, in which the temporal variation with the scanning time interval and the effect of the earth curvature on the data position were taken into account. The analysis shows that a shear line in the lower and middle levels played an important role in the rainfall event. The precipitation fell mainly on the south end of the shear line where southerly flow prevailed and convergence and updraft were obvious. With the movement and decay of the shear line, the precipitation moved and decayed correspondingly.
基金financially supported by the National Natural Science Foundation of China(Nos.21174124 and 21534009)
文摘Dual-asymmetric poly（vinylidene fluoride） （PVDF） separators have been fabricated by thermally induced phase separation with dimethyl sulfone （DMSO2） and glycerol as mixed diluents. The separators have a porous bulk with large interconnected pores （-1.0 μm） and two surfaces with small pores （-30 nm）. This dual-asymmetric porous structure endows the separators with higher electrolyte uptake amount and rapider uptake rate, as well as better electrolyte retention ability than the commercialized Celgard 2400. The separators even maintain their dimensional stability up to 160 ℃, at which temperature the surface pores close up, leading to a dramatic decrease of air permeability. The electrolyte filled separators also show high ion conductivity （1.72 mS.cm-1） at room temperature. Lithium iron phosphate （LiFePO4）/lithium （Li） cells using these separators display superior discharge capacity and better rate performance as compared with those from the commercialized ones. The results provide new insight into the design and development of separators for high-performance lithium ion batteries with enhanced safety.
基金Item Sponsored by National Natural Science Foundation of China[No.51004036]
文摘The as-cast structures of semi-continuous casting aluminum alloy under dual-frequency electromagnetic field were experimental investigated.The results showed that the electromagnetic fields with different frequency have different function for improving the cast structure of aluminum alloy casting.Imposing medium frequency electromagnetic field can change the surface morphology of melt pool in the casting process,increase the height of melt meniscus,improve the ingot's surface quality,and reduce the thickness of surface segregation.The low frequency electromagnetic field is most obvious to as-cast structure improvement effect because of its high permeability in conductance material.Imposing low-frequency electromagnetic field can change flow pattern and temperature field in the melt,strengthen the heat transfer and mass transfer in the melt,decrease the depth of the sttmp and reduce the temperature gradient.Thus,the as-cast structures are greatly refined,which can lead to the fine equiaxed as-cast structures throughout the cross-section of the ingot.
