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Characteristics and outcomes of trauma patients with unplanned intensive care unit admissions:Bounce backs and upgrades comparison 被引量:1
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作者 Alexander A Fokin Joanna Wycech Knight +4 位作者 Phoebe K Gallagher Justin Fengyuan Xie Kyler C Brinton Madison E Tharp Ivan Puente 《World Journal of Critical Care Medicine》 2025年第2期105-120,共16页
BACKGROUND The need for an emergency upgrade of a hospitalized trauma patient from the floor to the trauma intensive care unit(ICU)is an unanticipated event with possible life-threatening consequences.Unplanned ICU ad... BACKGROUND The need for an emergency upgrade of a hospitalized trauma patient from the floor to the trauma intensive care unit(ICU)is an unanticipated event with possible life-threatening consequences.Unplanned ICU admissions are associated with increased morbidity and mortality and are an indicator of trauma service quality.Two different types of unplanned ICU admissions include upgrades(patients admitted to the floor then moved to the ICU)and bounce backs(patients admitted to the ICU,discharged to the floor,and then readmitted to the ICU).Previous studies have shown that geriatric trauma patients are at higher risk for unfavorable outcomes.AIM To analyze the characteristics,management and outcomes of trauma patients who had an unplanned ICU admission during their hospitalization.METHODS This institutional review board approved,retrospective cohort study examined 203 adult trauma patients with unplanned ICU admission at an urban level 1 trauma center over a six-year period(2017-2023).This included 134 upgrades and 69 bounce backs.Analyzed variables included:(1)Age;(2)Sex;(3)Comorbidities;(4)Mechanism of injury(MOI);(5)Injury severity score(ISS);(6)Glasgow Coma Scale(GCS);(7)Type of injury;(8)Transfusions;(9)Consultations;(10)Timing and reason for unplanned admission;(11)Intubations;(12)Surgical interventions;(13)ICU and hospital lengths of stay;and(14)Mortality.RESULTS Unplanned ICU admissions comprised 4.2%of total ICU admissions.Main MOI was falls.Mean age was 70.7 years,ISS was 12.8 and GCS was 13.9.Main injuries were traumatic brain injury(37.4%)and thoracic injury(21.7%),and main reason for unplanned ICU admission was respiratory complication(39.4%).The 47.3%underwent a surgical procedure and 46.8%were intubated.Average timing for unplanned ICU admission was 2.9 days.Bounce backs occurred half as often as upgrades,however had higher rates of transfusions(63.8%vs 40.3%,P=0.002),consultations(4.8 vs 3.0,P<0.001),intubations(63.8%vs 38.1%%,P=0.001),longer ICU lengths of stay(13.2 days vs 6.4 days,P<0.001)and hospital lengths of stay(26.7 days vs 13.0 days,P<0.001).Mortality was 25.6%among unplanned ICU admissions,31.9%among geriatric unplanned ICU admissions and 11.9%among all trauma ICU patients.CONCLUSION Unplanned ICU admissions constituted 4.2%of total ICU admissions.Respiratory complications were the main cause of unplanned ICU admissions.Bounce backs occurred half as often as upgrades,but were associated with worse outcomes. 展开更多
关键词 Unplanned intensive care unit admissions Trauma intensive care unit Bounce backs upgrades Level 1 trauma center Geriatric trauma patients Quality of care indicator
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Gerber Technology Upgrades webPDM^(TM)
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《China Textile》 2010年第3期21-21,共1页
webPDM Version 6.1 demonstrates Gerber Technology’s commitmentto enhance,support and maintain its Product Data Management(PDM) application Tolland,Connecticut,USA-Gerber Technology announces the
关键词 PLM UI Gerber Technology upgrades webPDM LINE TM
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Efficient solutions for hot-rolling mill modernizations and upgrades
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作者 Stephan KRMER Stefan BERGER 《Baosteel Technical Research》 CAS 2010年第S1期110-,共1页
The recent steel boom was characterized by a steep increase in world wide hot-rolling capacity.Still new hot-rolling mills are scheduled to start production during the coming years.Existing plants,which may be in oper... The recent steel boom was characterized by a steep increase in world wide hot-rolling capacity.Still new hot-rolling mills are scheduled to start production during the coming years.Existing plants,which may be in operation since decades,have to compete with brand-new equipment and technology in terms of product quality and production efficiency.SMS Siemag have developed and successfully applied overall modernization concepts for hot-rolling mills as well as well-defined upgrade packages dedicated particularly to the improvement of product quality and the enlargement of product range.This paper describes the general methods of how SMS Siemag approaches hot-rolling mill modernization projects for maximum customer benefit and describes examples for overall modernization concepts as well as for powerful upgrade packages which have been put into operation during the recent years. 展开更多
关键词 hot strip mill modernization concepts powerful upgrade packages
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Standards facilitate effective upgrades and trade-ins
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作者 Jin Jili 《China Standardization》 2024年第6期40-43,共4页
Exerting the leading role of standards is very important for achieving the high-quality development. In recent years, China has unceasingly improved the mandatory national standards for energy efficiency and safety of... Exerting the leading role of standards is very important for achieving the high-quality development. In recent years, China has unceasingly improved the mandatory national standards for energy efficiency and safety of products, expedited the development and revision of standards in the areas of digital, intelligent, green and low-carbon development, and led the continuous technological upgrading of industrial and consumer goods. 展开更多
关键词 UPGRADING easing GOODS
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Upgrade Economics China renews subsidies for equipment upgrades and consumer goods trade-ins
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作者 Tao Xing 《Beijing Review》 2026年第4期34-35,共2页
The national consumer goods trade-in subsidy program has been a focal point for discussion among Chinese consumers in recent years.The program,which covers home appliances,digital products and vehicles,is part of Chin... The national consumer goods trade-in subsidy program has been a focal point for discussion among Chinese consumers in recent years.The program,which covers home appliances,digital products and vehicles,is part of China's stimulus package launched in 2024,which also includes incentives for large-scale equipment upgrades. 展开更多
关键词 economics equipment upgrades consumer goods trade ins subsidies stimulus package China
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Secure Method for Software Upgrades for Implantable Medical Devices 被引量:1
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作者 曹洋 胡春华 +3 位作者 马伯志 郝红伟 李路明 王伟明 《Tsinghua Science and Technology》 SCIE EI CAS 2010年第5期517-525,共9页
A non-invasive software upgrade method for permanent implantable medical devices was developed to alleviate patients' suffering due to malfunctions because of software faults,which may cause serious adverse health co... A non-invasive software upgrade method for permanent implantable medical devices was developed to alleviate patients' suffering due to malfunctions because of software faults,which may cause serious adverse health consequences or require enhancements with new software.The programs distributed to the internal implantable pulse generator(IPG) from the external programmer have been developed so that the upgrade service program in the IPG is simplified with most complex functions executed by the external programmer.A bidirectional protocol including frame definition and transmission mode was designed to insure secure upgrades.A neuro-stimulator was used to verify the upgrade solution with no additional elements,to maintain the hardware reliability.This study emphasizes how to insure a secure and stable upgrade process and reduce power consumption for special wireless and life safety-critical applications.Tests on rhesus monkeys to evaluate the feasibility of the approach for an IPG used for brain stimulation evaluation show that the software upgrade can be implemented stably with good tolerance to the wireless data transmissions. 展开更多
关键词 software upgrade secure upgrade NON-INVASIVE implantable medical device
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The City of Calgary’s Nose Creek Sanitary Sewer Trunk Phase B Contract 4
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作者 Mark Draper Zulfiqar Khowaja +1 位作者 Landon Evans Daniel Morse 《Journal of Civil Engineering and Architecture》 2025年第6期257-265,共9页
The City of Calgary’s Nose Creek Sanitary Sewer Trunk Phase B project has been constructed over several years to accommodate future population growth and open more developable lands in northern Calgary.The project wa... The City of Calgary’s Nose Creek Sanitary Sewer Trunk Phase B project has been constructed over several years to accommodate future population growth and open more developable lands in northern Calgary.The project was divided into three phases,Phase A,B,and C,with each phase delivered by a separate consultant.Phase A was the downstream section of this project and was undertaken by Stantec Consulting.Phase B was the upstream section designed by CH2MHILL(now Jacobs)and further divided into different contracts(1 through 5).Phase C was a separate sewer called the Saddleridge Trunk sewer and this was designed by Associated Engineering.This paper covers Phase B,Contract 4,which had several unique challenges and included many innovative design and procurement solutions.One procurement strategy included a two-phase qualification package,with the initial phase to select a tunnelling contractor with the experience to deliver technical installations under rail and creeks,and the second phase,a RFP(request for proposal),to select a general contractor,with broader experience in open-cut and stormwater drainage,which were other aspects included within the project.This approach ensured that The City had the most qualified team available to complete the project.Technical challenges discussed in this paper include an oblique CPKC(Canadian Pacific Kansas City)rail and Nose Creek crossing that required independent review,and CFD(computational fluid dynamics)and hydrogen sulfide modelling to confirm conditions within the trunk sewer. 展开更多
关键词 Sanitary sewer municipal infrastructure conveyance upgrades CONSULTING
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Call for Papers
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《Digital Communications and Networks》 2025年第4期1304-1304,共1页
SI:Agentic AI for 6G Networks.Introduction.6G networks are poised to provide full coverage across air,land,and sea,deliver terabit-per-second data rates,and achieve microsecond-level latency.They promise comprehensive... SI:Agentic AI for 6G Networks.Introduction.6G networks are poised to provide full coverage across air,land,and sea,deliver terabit-per-second data rates,and achieve microsecond-level latency.They promise comprehensive upgrades across industries through embedded intelligence,ushering in an era of intelligent interconnection of all things.However,managing real-time interactions among devices,infrastructure,and services in 6G networks is much more complex than in previous generations.Massive data streams from terrestrial nodes(e.g.,edge devices,sensors,distributed computing)and non-terrestrial nodes(LEO/MEO/GEO satellites)demand more intelligent and efficient processing. 展开更多
关键词 microsecond level latency embedded intelligenceushering G networks agentic AI intelligent interconnection terabit per second data rates comprehensive upgrades real time interactions
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JD Ceramics:Exhibiting all kinds of ceramic nozzle solutions
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《China Textile》 2025年第5期65-65,共1页
JD Ceramics has been specializing in the field of air interlacing jets,air texturizing jets,and water jets over 29 years.With several years of technical accumulation and continuous equipments upgrades,we have been con... JD Ceramics has been specializing in the field of air interlacing jets,air texturizing jets,and water jets over 29 years.With several years of technical accumulation and continuous equipments upgrades,we have been consistently delivering high-precision,highquality,cost-effective ceramic nozzle solutions to the market. 展开更多
关键词 technical accumulation ceramic nozzle air texturizing jets air interlacing jets equipment upgrades ceramic nozzles air interlacing jetsair texturizing jetsand water jets
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Development and validation of a predictive model for the pathological upgrading of gastric low-grade intraepithelial neoplasia 被引量:2
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作者 Kun-Ming Lyu Qian-Qian Chen +4 位作者 Yi-Fan Xu Yao-Qian Yuan Jia-Feng Wang Jun Wan En-Qiang Ling-Hu 《World Journal of Gastroenterology》 2025年第11期63-73,共11页
BACKGROUND The discrepancy between endoscopic biopsy pathology and the overall pathology of gastric low-grade intraepithelial neoplasia(LGIN)presents challenges in developing diagnostic and treatment protocols.AIM To ... BACKGROUND The discrepancy between endoscopic biopsy pathology and the overall pathology of gastric low-grade intraepithelial neoplasia(LGIN)presents challenges in developing diagnostic and treatment protocols.AIM To develop a risk prediction model for the pathological upgrading of gastric LGIN to aid clinical diagnosis and treatment.METHODS We retrospectively analyzed data from patients newly diagnosed with gastric LGIN who underwent complete endoscopic resection within 6 months at the First Medical Center of Chinese People’s Liberation Army General Hospital between January 2008 and December 2023.A risk prediction model for the pathological progression of gastric LGIN was constructed and evaluated for accuracy and clinical applicability.RESULTS A total of 171 patients were included in this study:93 patients with high-grade intraepithelial neoplasia or early gastric cancer and 78 with LGIN.The logistic stepwise regression model demonstrated a sensitivity and specificity of 0.868 and 0.800,respectively,while the least absolute shrinkage and selection operator(LASSO)regression model showed sensitivity and specificity values of 0.842 and 0.840,respectively.The area under the curve(AUC)for the logistic model was 0.896,slightly lower than the AUC of 0.904 for the LASSO model.Internal validation with 30%of the data yielded AUC scores of 0.908 for the logistic model and 0.905 for the LASSO model.The LASSO model provided greater utility in clinical decision-making.CONCLUSION A risk prediction model for the pathological upgrading of gastric LGIN based on white-light and magnifying endoscopic features can accurately and effectively guide clinical diagnosis and treatment. 展开更多
关键词 Endoscopic resection Gastric low-grade intraepithelial neoplasia Early gastric cancer Pathological upgrade Prediction model
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Detuning effect corrections using octupoles in diffraction-limited storage ring
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作者 Xuan Shouzhi Tian Shunqiang +2 位作者 Liu Xinzhong Gong Yihao Mao Linglong 《强激光与粒子束》 北大核心 2025年第7期72-82,共11页
The next generation of synchrotron radiation light sources features extremely low emittance,enabling the generation of synchrotron radiation with significantly higher brilliance,which facilitates the exploration of ma... The next generation of synchrotron radiation light sources features extremely low emittance,enabling the generation of synchrotron radiation with significantly higher brilliance,which facilitates the exploration of matter at smaller scales.However,the extremely low emittance results in stronger sextupole magnet strengths,leading to high natural chromaticity.This necessitates the use of sextupole magnets to correct the natural chromaticity.For the Shanghai Synchrotron Radiation Facility Upgrade(SSRF-U),a lattice was designed for the storage ring that can achieve an ultra-low natural emittance of 72.2 pm·rad at the beam energy of 3.5 GeV.However,the significant detuning effects,driven by high second-order resonant driving terms due to strong sextupoles,will degrade the performance of the facility.To resolve this issue,installation of octupoles in the SSRF-U storage ring has been planned.This paper presents the study results on configuration selection and optimization method for the octupoles.An optimal solution for the SSRF-U storage ring was obtained to effectively mitigate the amplitude-dependent tune shift and the second-order chromaticity,consequently leading to an increased dynamic aperture(DA),momentum acceptance(MA),and reduced sensitivity to magnetic field errors. 展开更多
关键词 Shanghai Synchrotron Radiation Facility Upgrade OCTUPOLE amplitude-dependent tune shift dynamic aperture momentum aperture
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It's time for high-quality development of China's textile industry In the first half of 2025,the economic operation of China's textile industry was basically stable
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《China Textile》 2025年第5期24-25,共2页
Since the beginning of this year,the international environment has been complex and volatile,the international economic and trade order has suffered severe setbacks,and instability and uncertainty have increased signi... Since the beginning of this year,the international environment has been complex and volatile,the international economic and trade order has suffered severe setbacks,and instability and uncertainty have increased significantly.Faced with this complex situation,China's textile industry has adhered to the general principle of seeking progress while maintaining stability,steadily advancing the optimization and adjustment of its industrial structure,and deepening the transformation and upgrading of foreign trade.Supported by the country's more proactive and effective macroeconomic policies,the economy remained generally stable in the first half of the year,with exports maintaining growth despite significant pressure,and its resilience being consolidated and unleashed.Looking ahead to the second half of 2025,the textile industry will continue to face numerous challenges while consolidating its stable and positive development foundation. 展开更多
关键词 economic operation industrial structure transformation upgrading seeking progress maintaining stabilitysteadily textile industry UPGRADING international environment optimization adjustment
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2025 Gaoyang Textile&Apparel Event:Boosting supply chain&industry upgrade in Beijing–Tianjin–Hebei region
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作者 Qiu Shuchen 《China Textile》 2025年第3期32-33,共2页
On May 21st,the launch ceremony of the 2025 Textile and Clothing"Optimization of Supply and Upgrade"event was held in Gaoyang,Hebei Province.The theme of the event is to promote the coordinated development a... On May 21st,the launch ceremony of the 2025 Textile and Clothing"Optimization of Supply and Upgrade"event was held in Gaoyang,Hebei Province.The theme of the event is to promote the coordinated development and supply-demand docking of the textile and clothing industry in the Beijing–Tianjin–Hebei Region.Representatives from the textile and clothing industries gathered in Gaoyang to discuss the coordinated development of regional industries.The Ministry of Industry and Information Technology,Industry Associations,and leaders of the three local governments jointly announced the official launch of the national industrial upgrading action. 展开更多
关键词 beijing tianjin hebei region industrial upgrading action industry upgrade supply chain TEXTILE coordinated development clothing supply demand docking
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Mechanism and Implementation Panths of Low-Altitude Economy in Promoting Transformation and Upgrading of Tourism Industry in Zhejiang Province
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作者 Zhenzi GUO 《Asian Agricultural Research》 2025年第8期13-15,26,共4页
Taking Zhejiang Province as an example,this paper explores the mechanisms and implementation pathways through which the low-altitude economy drives the transformation and upgrading of the tourism industry.It finds tha... Taking Zhejiang Province as an example,this paper explores the mechanisms and implementation pathways through which the low-altitude economy drives the transformation and upgrading of the tourism industry.It finds that the low-altitude economy can effectively promote the development of high-end and diversified tourism in Zhejiang by innovating tourism formats,optimizing resource allocation,and enhancing tourist experiences.Besides,it analyzes the current development status of the low-altitude economy in Zhejiang and its potential for integration with tourism,revealing specific enabling pathways for tourism transformation,including low-altitude sightseeing,aviation tourism,and low-altitude sports.Finally,it proposes policy recommendations such as strengthening policy support,enhancing infrastructure development,and cultivating market entities.The findings aim to provide theoretical references and practical guidance for the high-quality development of tourism in Zhejiang Province. 展开更多
关键词 LOW-ALTITUDE ECONOMY Transformation and upgrading of the tourism industry Action MECHANISM IMPLEMENTATION path ZHEJIANG Province
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Upcycling of monomers derived from waste polyester plastics via electrocatalysis
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作者 Haoye Wang Richard Lee Smith Jr Xinhua Qi 《Journal of Energy Chemistry》 2025年第2期535-561,I0011,共28页
Electrocatalysis offers efficient and targeted conversion of monomers derived from waste polyester plastics to chemical products under ambient temperature and pressure conditions.This review provides analysis of resea... Electrocatalysis offers efficient and targeted conversion of monomers derived from waste polyester plastics to chemical products under ambient temperature and pressure conditions.This review provides analysis of research on electrochemical upgrading of monomers derived from waste polyester plastics published from2021 to present.Factors for assessing upgrading of waste polyester plastics include alkaline hydrolysis pretreatment,indices of electrochemical reaction process(activity,stability,and techno-economic a nalysis),separation,and product recovery.Types of depolymerization monomers and their value-added products are summarized along with electrocatalytic mechanisms and reaction pathways.Notably,cathode coupled reactions offer significant value for anodic waste plastic oxidation during electrolysis processes.Development of bifunctional electrocatalysts can reduce the cost of coupled systems and complexity of the electrolyzer.Upgrading and recycling of waste plastic monomers using electrocatalytic technology should undergo downstream processing to form high-value products containing C-N and C-S derived functional groups obtained from depolymerized monomers,Electrochemical conversion and upgrading of monomers derived from waste polyester plastics can contribute to industrialization and global economies and help to realize environmental sustainability. 展开更多
关键词 Waste plastics MONOMER ELECTROCATALYSIS Value-added products Upgrade recycling Coupling reaction
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Metallic cobalt mediated molybdenum nitride for efficient glycerol upgrading with water electrolysis
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作者 Yiming Guo Zhouhong Yu +1 位作者 Bin He Pengzuo Chen 《Chinese Chemical Letters》 2025年第9期589-594,共6页
Integrating electrochemical upgrading of glycerol and water electrolysis is regarded as a promising and energy-saving approach for the co-production of chemicals and hydrogen.However,developing efficient electrocataly... Integrating electrochemical upgrading of glycerol and water electrolysis is regarded as a promising and energy-saving approach for the co-production of chemicals and hydrogen.However,developing efficient electrocatalyst towards this technology remains challenging.Herein,a metallic cobalt mediated molybdenum nitride heterostructural material has been exploited on nickel foam(Co@Mo_(2)N/NF)for the glycerol oxidation reaction(GOR)and hydrogen evolution reaction(HER).Remarkably,the obtained Co@Mo_(2)N/NF realizes eminent performance with low overpotential of 49 mV at 50 mA/cm^(2)for HER and high Faradaic efficiency of formate of 95.03%at 1.35 V vs.RHE for GOR,respectively.The systematic in-situ experiments reveal that the Co@Mo_(2)N heterostructure promotes the cleavage of C-C bond in glycerol by active CoOOH species and boosts the conversion of glycerol to aldehyde intermediates to formate product.Moreover,the density functional theory(DFT)calculations confirm the strong interaction at Co@Mo_(2)N interface,which contributes to the optimized water dissociation and the transformation of H^(*)to H^(2).Benefiting from those advantages,the built HER||GOR electrolyzer delivers a low voltage of 1.61 V at 50 mA/cm^(2),high Faradaic efficiency,and robust stability over 120 h for sustained and stable electrolysis. 展开更多
关键词 Metallic Co Molybdenum nitride HETEROSTRUCTURE Glycerol upgrading Water electrolysis
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Molecular Transformation and Sustainable Optimization of Bitumen in Alberta Oil Sands,Canada with RDV■Chemical Technology
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作者 William J.Jiménez Hernán O.González Víctor J.Silva 《Journal of Energy and Power Engineering》 2025年第4期150-158,共9页
RDV■(dynamic vasoactive reactor)chemical technology represents a disruptive innovation operating under both surface and downhole conditions,producing irreversible and in situ adaptable effects.It has demonstrated tra... RDV■(dynamic vasoactive reactor)chemical technology represents a disruptive innovation operating under both surface and downhole conditions,producing irreversible and in situ adaptable effects.It has demonstrated transformative capacity across crude oils of various API gravities,with notable impact on extra-heavy crudes and bitumens,through a mechanism based on targeted proton donation that induces selective protonation of polar structures,generating transient carbocations that catalyze molecular fragmentation.This work presents a comprehensive analysis of the effects of RDV-DMG001■treatment(currently named RDV-01L■)on bitumen samples from the Primrose field,Alberta,Canada,using capillary chromatography,SARA analysis,and rheological evaluation,complemented with comparative data on prior applications of RDV-01L■in extra-heavy crudes from Venezuela(Boscán and El Salto).Results for Primrose bitumen show an 85%reduction in viscosity(from 500,000 to 75,000 cP),an increase in API gravity from 8.5 to 15.0(+76.4%),and molecular redistribution toward medium-chain hydrocarbons(C_(13)-C_(16)),with increases in molar and mass fractions up to 39.1%and 62.3%,respectively.SARA analysis confirmed fragmentation of asphaltenes(2.0%mass reduction)and a 5.8%increase in resins,improving colloidal stability and lowering precipitation risk.These changes align with RDV■’s mechanism of action based on carbocation generation.Notably,in field conditions-which are more dynamic and energetically favorable-RDV■treatment efficacy tends to exceed laboratory results,due to synergy among temperature,pressure,and fluid flow gradients which accelerate and enhance protonation and molecular fragmentation.Validated in contexts of advanced chemical transformation(Venezuela,Canada),the technology enables substantial improvements in fluidity,transport,processing,and recovery,with significant potential for annual cost savings in extraction and processing.This study positions RDV■as a disruptive,irreversible,and in situ adaptable chemical solution superior to conventional technologies such as surfactants,nanocatalysts,or aquathermolysis.RDV■is a quantum-impact chemical technology operating via molecular protonation reactions and controlled carbocation formation.The term“quantum”is used here as a conceptual analogy to describe the magnitude and specificity of the molecular reconfiguration induced by RDV■,without asserting direct experimental evidence of quantum reactivity. 展开更多
关键词 RDV■ PROTONATION CARBOCATIONS BITUMEN oil sands SARA CHROMATOGRAPHY viscosity extra-heavy crude in situ upgrading
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Platinum modification of metallic cobalt defect sites for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural
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作者 Haoyu Zhan Baixue Cheng +6 位作者 Yankun Lu Danning Xing Xingshuai Lv Huining Huang Thomas Frauenheim Tao Wang Peng Zhou 《Journal of Energy Chemistry》 2025年第2期463-473,I0010,共12页
Co_(3)O_(4)possesses both direct and indirect oxidation effects and is considered as a promising catalyst for the oxidation of 5-hydroxymethylfurfural(HMF).However,the enrichment and activation effects of Co_(3)O_(4)o... Co_(3)O_(4)possesses both direct and indirect oxidation effects and is considered as a promising catalyst for the oxidation of 5-hydroxymethylfurfural(HMF).However,the enrichment and activation effects of Co_(3)O_(4)on OH-and HMF are weak,which limits its further application.Metal defect engineering can regulate the electronic structure,optimize the adsorption of intermediates,and improve the catalytic activity by breaking the symmetry of the material,which is rarely involved in the upgrading of biomass.In this work,we prepare Co_(3)O_(4)with metal defects and load the precious metal platinum at the defect sites(PtVco).The results of in-situ characterizatio ns,electrochemical measurements,and theoretical calculations indicate that the reduction of Co-Co coordination number and the formation of Pt-Co bond induce the decrease of electron filling in the antibonding orbitals of Co element.The resulting upward shift of the d-band center of Co combined with the characteristic adsorption of Pt species synergically enhances the enrichment and activation of organic molecules and OH species,thus exhibiting excellent HMF oxidation activity(including a lower onset potential(1.14 V)and 19 times higher current density than pure Co_(3)O_(4)at 1.35 V).In summary,this work explores the adsorption enhancement mechanism of metal defect sites modified by precious metal in detail,provides a new option for improving the HMF oxidation activity of cobalt-based materials,broadens the application field of metal defect based materials,and gives an innovative guidance for the functional utilization of metal defect sites in biomass conversion. 展开更多
关键词 ELECTROCATALYSIS Biomass upgrading Metallic defect Coordination environment Adsorption enhancement
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Rational design of oxygen vacancy-rich self-supporting NiCo(OH)_(2)electrode for efficient biomass upgrading
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作者 Diexin Xie Jiabin Chen +4 位作者 Jingxin Hou Fangfang Yang Runping Feng Changsheng Cao Zailai Xie 《Journal of Energy Chemistry》 2025年第9期558-566,I0015,共10页
Transition metal-based electrocatalysts are a promising alternative to noble metal catalysts for electrochemical upgrading of biomass-derived 5-hydroxymethylfurfural(HMF)into high-value 2,5-furandicarboxylic acid(FDCA... Transition metal-based electrocatalysts are a promising alternative to noble metal catalysts for electrochemical upgrading of biomass-derived 5-hydroxymethylfurfural(HMF)into high-value 2,5-furandicarboxylic acid(FDCA).However,the rational design of efficient electrocatalysts with precisely tailored structure-activity correlations remains a critical challenge.Herein,we report a hierarchically structured self-supporting electrode(Vo-NiCo(OH)_(2)-NF)synthesized through in situ electrochemical reconstruction of NiCo-Prussian blue analogue(NiCo-PBA)precursor,in which oxygen vacancy(Vo)-rich Co-doped Ni(OH)_(2)nanosheet arrays are vertically aligned on nickel foam(NF),creating an interconnected conductive network.When evaluated for the HMF oxidation reaction(HMFOR),Vo-NiCo(OH)_(2)-NF exhibits exceptional electrochemical performance,achieving near-complete HMF conversion(99%),ultrahigh FDCA Faradaic efficiency(97.5%),and remarkable product yield(96.2%)at 1.45 V,outperforming conventional Co-doped Ni(OH)_(2)(NiCo(OH)_(2)-NF)and pristine Ni(OH)_(2)(Ni(OH)_(2)-NF)electrodes.By combining in situ spectroscopic characterization and theoretical calculations,we elucidate that the synergistic effects of Co-doping and oxygen vacancy engineering effectively modulate the electronic structure of Ni active centers,favor the formation of high-valent Ni^(3+)species,and optimize HMF adsorption,thereby improving the HMFOR performance.This work provides valuable mechanistic insights for catalyst design and may inspire the development of advanced transition metal-based electrodes for efficient biomass conversion systems. 展开更多
关键词 Biomass upgrading Hierarchical structure Oxygen vacancy Transition metal-based electrodes ELECTROLYSIS
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Sensation-thinking-simulacrum-construction:Upgrading path of sustainable design driven by modern artificial intelligence
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作者 GAO Yun-ting 《Ecological Economy》 2025年第4期380-400,共21页
Artificial intelligence(AI)is moving toward a new stage in its generalized development.To explain the upgrading path of sustainable design driven by AI can provide a certain basis and support for its application in de... Artificial intelligence(AI)is moving toward a new stage in its generalized development.To explain the upgrading path of sustainable design driven by AI can provide a certain basis and support for its application in design.Based on research into modern intelligence technology and design practices,this article(1)focuses on AI+,by means of relational comparisons and hierarchical structure analysis;(2)studies the value-added effect and new characteristics exhibited by the content,method,process,form,effect,and other aspects of design under the concept of sustainability;and(3)explores the upgrading mode and technological application of sustainable design,whose development is obviously influenced by the new generation of intelligence technology,through the upgrading paths of sensation,thinking,simulacrum,and construction.The continuous integration of sustainable design and AI is a trend that will endow the design process and designed objects with intelligent functions and multiple characteristics from the dimensions of cognition,thought,expression,and action.New tools and subjects will profoundly affect the value creation of design in the dimensions of environment,economy,and society. 展开更多
关键词 sustainable design artificial intelligence technology application UPGRADING
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