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A GC×GC-ToFMS Investigation of the Unresolved Complex Mixture and Associated Biomarkers in Biodegraded Petroleum 被引量:4
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作者 WANG Guangli Bernd Rolf Tatsuo SIMONEIT +3 位作者 SHI Shengbao WANG Tieguan ZHONG Ningning WANG Peirong 《Acta Geologica Sinica(English Edition)》 CAS CSCD 2018年第5期1959-1972,共14页
Heavy biodegraded crude oils have larger numbers of coeluting compounds than nonbiodegraded oils, and they are typically not resolved with conventional gas chromatography(GC). This unresolved complex mixture(UCM) ... Heavy biodegraded crude oils have larger numbers of coeluting compounds than nonbiodegraded oils, and they are typically not resolved with conventional gas chromatography(GC). This unresolved complex mixture(UCM) has been investigated using comprehensive two-dimensional gas chromatography–time-of-flight mass spectrometry(GC×GC-To FMS) within a set of biodegraded petroleums derived from distinct sedimentary basins, including northwestern Sichuan(Neoproterozoic, marine), Tarim(Early Paleozoic, marine), Bohai Bay(Eocene, saline/brackish) and Pearl River Mouth(Eocene, freshwater). In general, the hydrocarbons that constitute the UCM in petroleum saturate fractions can be classified into three catalogues based on the distributions of resolved compounds on two dimensional chromatograms. Group 1 is composed mainly of normal and branched alkanes, isoprenoid alkanes and monocyclic alkanes; Group 2 comprises primarily terpanes ranging from two to five rings, and Group 3 is dominated by monoaromatic hydrocarbons such as tetralins and monoaromatic steranes. In addition, the UCM is source dependent and varies between oil populations. i.e., the UCM of petroleum derived from Precambrian and Early Paleozoic marine, Eocene saline/brackish and freshwater source rocks is specifically rich in higher homologues of A-norsteranes, series of 1,1,3-trimethyl-2-alkylcyclohexanes(carotenoid-derived alkanes), and tetralin and indane compounds, respectively. 展开更多
关键词 unresolved complex mixture(UCM) biomarker source biodegradation comprehensive two-dimensional gas chromatography–time-of-flight mass spectrometry(GC×GC-ToFMS)
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Measurement of ^(232)Th(n,γ)cross section at the CSNS Back-n facility in the unresolved resonance region from 4 keV to 100 keV 被引量:3
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作者 Bing Jiang Jianlong Han +12 位作者 Jie Ren Wei Jiang Xiaohe Wang Zian Guo Jianglin Zhang Jifeng Hu Jingen Chen Xiangzhou Cai Hongwei Wang Longxiang Liu Xinxiang Li Xinrong Hu Yue Zhang 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第6期74-81,共8页
The neutron capture cross section of ^(232)Th was measured at the neutron time-of-flight facility Back-n of China Spallation Neutron Source(CSNS)for the first time.The measurement was performed with 4 hydrogen-free de... The neutron capture cross section of ^(232)Th was measured at the neutron time-of-flight facility Back-n of China Spallation Neutron Source(CSNS)for the first time.The measurement was performed with 4 hydrogen-free deuterated benzene C6D6 liquid scintillation detectors,in the ES#2 experiment station on the beam line,at a distance of about 76 m from the neutron-production assembly.The total energy detection principle in combination with the pulse height weighting technique(PHWT)was applied to analyze the measured data.Results of the ^(232)Th(n,γ)reaction cross section in the unresolved resonance region from 4 keV to 100 keV were obtained,which shows a good agreement with the existing experimental data from EXFOR,as well as with the evaluated data from the ENDF/B-VIII.0 and CENDL-3.1.In addition,the excitation function of ^(232)Th(n,γ)^(233)Th reaction in the unresolved resonance region was theoretically calculated by using the code TALYS-1.95.By fitting the experimental cross section and theoretical data,the average parameters in the unresolved resonance region were extracted. 展开更多
关键词 ^(232)Th(n g)cross section CSNS Back-n facility C_(6)D_(6)detectors unresolved resonance region
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Ground-state cooling based on a three-cavity optomechanical system in the unresolved-sideband regime 被引量:1
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作者 Jing Wang 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第2期298-303,共6页
In the unresolved sideband regime,we propose a scheme for cooling mechanical resonator close to its ground state in a three-cavity optomechanical system,where the auxiliary cavities are indirectly connected with the m... In the unresolved sideband regime,we propose a scheme for cooling mechanical resonator close to its ground state in a three-cavity optomechanical system,where the auxiliary cavities are indirectly connected with the mechanical resonator through standard optomechanical subsystem.The standard optomechanical subsystem is driven by a strong pump laser field.With the help of the auxiliary cavities,the heating process is suppressed and the cooling process of the mechanical resonator is enhanced.More importantly,the average phonon number is much less than 1 in a larger range.This means that the mechanical resonator can be cooled down to its ground state.All these interesting features will significantly promote the physical realization of quantum effects in multi-cavity optomechanical systems. 展开更多
关键词 ground-state cooling three-cavity optomechanical system unresolved sideband regime
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An extended unresolved CFD-DEM coupling method for simulation of fluid and non-spherical particles 被引量:3
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作者 Liping He Zhengxian Liu Yongzhi Zhao 《Particuology》 SCIE EI CAS CSCD 2022年第9期1-12,共12页
This study develops an extended unresolved CFD-DEM coupling method for simulation of the fluid-solid flow with non-spherical particles.The limitation of fluid grid size is discussed,by simulating the settling of a cyl... This study develops an extended unresolved CFD-DEM coupling method for simulation of the fluid-solid flow with non-spherical particles.The limitation of fluid grid size is discussed,by simulating the settling of a cylinder in a Newtonian fluid based on the resolved and unresolved CFD-DEM coupling method.Then,the calculation of porosity and the fluid-particle relative velocity based on the particle shape enlarge-ment method for simulation of non-spherical particles is proposed.The availability of the particle shape enlargement method for the simulation of non-spherical particles with different sphericity is discussed in this work,by comparing it with the results from the equivalent diameter enlargement method.The lim-itation of the equivalent diameter enlargement method for non-spherical particles is revealed from the simulation results.Several typical cases are employed to elaborate and verify the extended unresolved CFD-DEM method based on particle shape enlargement method,by presenting a good consistency with the experimental results.It proves that the extended unresolved CFD-DEM method is suitable for differ-ent CFD grid size ratios,and consolidates that it is a universal calculation method for CFD-DEM coupling simulation. 展开更多
关键词 CFD-DEM unresolved method Fluid-solid flow Non-spherical particle ROD
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Study on the detection of the multiple unresloved targets 被引量:3
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作者 LiChaowei WangHongqiang LiXiang ZhuangZhaowen 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2005年第2期295-300,共6页
When the returns come from two or more unresolved targets (the signals are not resolved in the frequency or time domains) in a monopulse radar system, the direction-of-arrival (DOA)estimate indicated by the monopulse ... When the returns come from two or more unresolved targets (the signals are not resolved in the frequency or time domains) in a monopulse radar system, the direction-of-arrival (DOA)estimate indicated by the monopulse ratio is not the true information of the tracked target.Then the tracking systems is influenced. An approach has been proposed to detect whether the returns come from a single target or two unresolved targets. The above approach is extended from two to three unresolved targets. The simulation indicates that the detection probability under the three unresolved targets is not sure to exceed the detection probability under the two unresolved targets. 展开更多
关键词 monopulse radar unresolved targets DOA detection probability.
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Direction estimation for two steady targets in monopulse radar 被引量:2
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作者 Zhenxing Lu Yunjie Li Meiguo Gao 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2015年第1期61-68,共8页
Traditional monopulse radar cannot resolve two targets present in one range and Doppler cell by means of the monopulse ratio. A novel algorithm is proposed to estimate the directions of two steady targets with two pul... Traditional monopulse radar cannot resolve two targets present in one range and Doppler cell by means of the monopulse ratio. A novel algorithm is proposed to estimate the directions of two steady targets with two pulses. The algorithm has a closedform expression and its variance is derived at high signal-to-noise ratios(SNRs). Furthermore, the pulse pair selection criterion and the estimation method with multiple pulses are given. Finally, some numerical results are shown to validate the proposed algorithm and the effect of slight target fluctuations is tested. 展开更多
关键词 direction estimation two unresolved targets monopulse radar
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Study of the 6.x nm short wavelength radiation spectra of laser-produced erbium plasmas for BEUV lithography 被引量:1
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作者 吴涛 王倩 +1 位作者 陈柳安 陆培祥 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第6期41-51,共11页
Beyond extreme ultraviolet(BEUV)radiation with a wavelength of 6.x nm for lithography is responsible for reducing the source wavelength to enable continued miniaturization of semiconductor devices.In this work,the Req... Beyond extreme ultraviolet(BEUV)radiation with a wavelength of 6.x nm for lithography is responsible for reducing the source wavelength to enable continued miniaturization of semiconductor devices.In this work,the Required BEUV light at 6.x nm wavelength was generated in dense and hot Nd:YAG laser-produced Er plasmas.The spectral contributions from the 4p–4d and 4d–4f transitions of singly,doubly and triply excited states of Er XXIV–Er XXXII in the BEUV band were calculated using Cowan and the Flexible Atomic Code.It was also found that the radiative transitions between multiply excited states dominate the narrow wavelength window around 6.x nm.Under the assumption of collisional radiative equilibrium of the laser-produced Er plasmas,the relative ion abundance in the experiment was inferred.Using the Boltzmann quantum state energy level distribution and Gram–Charlier fitting function of unresolved transition arrays(UTAs),the synthetic spectrum around 6.x nm was finally obtained and compared with the experimental spectrum.The spatio-temporal distributions of electron density and electron temperature were calculated based on radiation hydrodynamic simulation in order to identify the contributions of various ionic states to the UTAs arising from the Er plasmas near 6.x nm. 展开更多
关键词 laser-produced plasmas unresolved transition array collisional radiative equilibrium
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Potential Correlations between Unexplained Experimental Observables and Hot Projectile-Like Fragments in Primary Interactions above <i>E</i><sub>CM/<i>u</i></sub>≈ 150 MeV 被引量:2
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作者 Eberhard Ganssauge Wolfram Westmeier Reinhard Brandt 《World Journal of Nuclear Science and Technology》 2013年第4期155-161,共7页
An enhanced neutron production and an enhanced nuclear destruction due to secondary fragments have been observed in very thick targets irradiated with high energy ions. This enhancement is beyond theoretical calculati... An enhanced neutron production and an enhanced nuclear destruction due to secondary fragments have been observed in very thick targets irradiated with high energy ions. This enhancement is beyond theoretical calculations and it is an unresolved problem. It is observed only when primary ion interactions exceed an energy threshold (ECM/u ≈ 150 MeV). Investigations using nuclear emulsions for very high-energy nuclear reactions suggest that two distinctly different classes of relativistic projectile-like fragments are emitted in primary interactions: a “cool” channel with a temperature of (T(p)cool ≈ 10 MeV), and a “hot” channel with (T(p)hot ≈ 40 MeV. This second reaction class may induce the above mentioned enhanced reactions of secondary fragments, thus being responsible for unresolved problems. This assumption should be studied in further experiments. Nuclear interactions of secondary particles in thick targets are of interest, in particular in view of radiation protection needs for high energy and high intensity heavy ion accelerators. Many basic ideas of this paper go back to the late Professor E. Schopper (Frankfurt). 展开更多
关键词 Very High Energy PROJECTILE HOT PROJECTILE FRAGMENTS Cool Target FRAGMENTS unresolved Problems
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Suppression of Stokes heating processes and improved optomechanical cooling with frequency modulation
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作者 Yang Bao Qinghong Liao +1 位作者 Qingmin Zhao Jing Wu 《Communications in Theoretical Physics》 SCIE CAS CSCD 2022年第4期42-51,共10页
Ground-state cooling of mesoscopic mechanical objects is still a major challenge in the unresolved-sideband regime.We present a frequency modulation(FM)scheme to achieve cooling of the mechanical resonator to its grou... Ground-state cooling of mesoscopic mechanical objects is still a major challenge in the unresolved-sideband regime.We present a frequency modulation(FM)scheme to achieve cooling of the mechanical resonator to its ground-state in a double-cavity optomechanical system containing a mechanical resonator.The mean phonon number is determined by numerically solving a set of differential equations derived from the quantum master equations.Due to efficient suppression of Stokes heating processes in the presence of FM,the ground-state cooling,indicated by numerical calculations,is significantly achievable,regardless of whether in the resolved-sideband regime or the unresolved-sideband regime.Furthermore,by choosing parameters reasonably,the improvement of the quantum cooling limit is found to be capable of being positively correlated with the modulation frequency.This method provides new insight into quantum manipulation and creates more possibilities for applications of quantum devices. 展开更多
关键词 ground-state cooling Stokes heating processes frequency modulation unresolved sideband
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A study on soft x-ray spectra from pulsed 1 μm Nd:YAG laser-induced ytterbium plasmas
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作者 Tao WU Jun HE +1 位作者 Li YANG Peixiang LU 《Plasma Science and Technology》 SCIE EI CAS CSCD 2020年第10期119-125,共7页
The Nd:YAG laser with a wavelength of 1.064 μm was used to generate plasmas on a high-purity solid ytterbium(70 Yb) target in a vacuum chamber. The soft x-ray time-and space-integration spectra from the Yb plasmas we... The Nd:YAG laser with a wavelength of 1.064 μm was used to generate plasmas on a high-purity solid ytterbium(70 Yb) target in a vacuum chamber. The soft x-ray time-and space-integration spectra from the Yb plasmas were measured in the wavelength range of 1.0–8.5 nm under different power densities. The atomic spectral data of the unresolved transition arrays from highly charged Yb ions were calculated based on Cowan's suite of codes, including configuration interaction. The calculated Gaussian envelope of the emission determined by the weighted spontaneous transition rates was compared with the experimental spectra, and a good agreement between them was obtained. The spatial-temporal evolutions of the plasmas under the experimental conditions are simulated based on the collisional-radiative model, enabling the understanding of the mechanism of the plasma conditions for optimal water window waveband emission output. 展开更多
关键词 laser produced plasma water window sources unresolved transition arrays YTTERBIUM
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On the Sum of Reciprocals of Mersenne Primes
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作者 Yoshihiro Tanaka 《American Journal of Computational Mathematics》 2017年第2期145-148,共4页
The sum of reciprocals of Mersenne primes converges to 0.51645417894078856533···, which is an example of a probably infinite subset of primes whose sum of reciprocals is finite and can be computed accur... The sum of reciprocals of Mersenne primes converges to 0.51645417894078856533···, which is an example of a probably infinite subset of primes whose sum of reciprocals is finite and can be computed accurately. This value is larger than , where ?is the set of perfect powers of prime numbers. 展开更多
关键词 Mersenne PRIMES the SUM of Reciprocals unresolved PROBLEM
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Best Practice Grievance Handling: Exploring Its Importance to the Internal/External Customer Satisfaction Equation at a Caribbean University
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作者 Zuwena Paul 《Journalism and Mass Communication》 2014年第2期101-124,共24页
In 2012, 92 Administrative, Technical and Service Staff (ATS S) grievances (unresolved departmental conflicts) were referred to the Industrial Relations arm of the HR division of the UWI St Augustine Campus. Of th... In 2012, 92 Administrative, Technical and Service Staff (ATS S) grievances (unresolved departmental conflicts) were referred to the Industrial Relations arm of the HR division of the UWI St Augustine Campus. Of these trade disputes, 52 cases were "resolved" and 10 unresolved cases were referred to the Ministry of Labor. In 2009, 692 disputes from various organizations nationally were lodged at the Industrial Court of Trinidad and Tobago--781 in 2010, 778 in 2011 and at September 25th, 2012, 566 were filed (Swamber, 2012). Vincent Cabera, president of the Banking, Insurance and General Workers Union, expressing his grave concern about these statistics cited inter alia, noted that "work stoppages that currently persist in society owed to the malfunctioning of the industrial relations system of the twin island". Legitimate members of the Recognized Majority Union (RMU), who have within the past year at the Campus experienced unresolved conflicts at the departmental level that progressed to trade disputes will be eligible to participate and electronically administered a semi-structured questionnaire developed to determine the frequency and causes of unresolved conflict, their perceptions of its handling, as well as Form A of the Rahim Organizational Conflict Inventory II (ROCI-II) (Rahim, 1983) to classify the conflict management style of their Heads of departments. 展开更多
关键词 GRIEVANCE DISPUTE CONFLICT unresolved TRADE
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Two Ways of High-Energy Heavy Ion Interactions: Spallation and Burst
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作者 Reinhard Brandt Valery Ditlov +5 位作者 Maria Haiduc Elena Firu Alina Tania Neagu Eberhard Ganssauge Reza Hashemi-Nezhad Wolfram Westmeier 《World Journal of Nuclear Science and Technology》 2015年第2期73-87,共15页
A new approach to solving the observation of enhanced neutron production in high-energy heavy ion induced reactions in thick targets is presented. Two different reaction mechanisms in these interactions are considered... A new approach to solving the observation of enhanced neutron production in high-energy heavy ion induced reactions in thick targets is presented. Two different reaction mechanisms in these interactions are considered: 1) Limited fragmentation of the projectile, called SPALLATION;2) Complete nuclear fragmentation of the projectile fragment into individual relativistic hadrons only, referred to as “BURST”. The abundance of this second path increases with the charge and energy of the projectile and may be responsible for enhanced neutron production observed with radiochemical methods in 44 GeV 12C and 72 GeV 40Ar irradiations. Interactions of 72 GeV 22Ne in nuclear emulsions show that SPALLATION and BURST have strongly different interaction signatures, and also that the rate of BURSTS increases from (26 ± 3)% of all interactions in the 1st generation to (78 ± 6)% in the 2nd generation. Further experimental signatures of BURSTS will be described;however, no model based on physics concepts can be presented. This effect may have practical consequences for neutron safety considerations in the construction of advanced heavy ion accelerators. 展开更多
关键词 THICK TARGET High Energy PROJECTILE unresolved Problems BURST
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Comment on the Recent Start of a New “IUPAC-Project”
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作者 Reinhard Brandt Valery Ditlov +5 位作者 Elena Firu Eberhard Ganssauge Maria Haiduc Reza Hashemi-Nezhad Alina Tania Neagu Wolfram Westmeier 《World Journal of Nuclear Science and Technology》 2018年第3期121-127,共7页
The opening of a new IUPAC-project is highly appreciated. In the year 2009, the IUPAC had published an article “Discovery of the element with atomic number 112 (IUPAC Technical Report)” [1]* which contains a section... The opening of a new IUPAC-project is highly appreciated. In the year 2009, the IUPAC had published an article “Discovery of the element with atomic number 112 (IUPAC Technical Report)” [1]* which contains a section on the work of the Marinov collaboration. It appears that this section is not always in agreement with conventional standards for scientific publications. This present comment focuses on these formal questions. 展开更多
关键词 IUPAC Project 2017-014-2-200 eka-Hg unresolved Problems
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Performance Evaluation of a Silicon-Based 6U CubeSat Detector for Soft γ-Ray Astronomy
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作者 Rishank Diwan Kees de Kuijper +4 位作者 Partha Sarathi Pal Andreas Ritter Pablo M.Saz Parkinson Andy C.T.Kong Quentin A.Parker 《Space(Science & Technology)》 2024年第1期40-50,共11页
The observation of the low-energyγ-ray(0.1 to 30 MeV)sky has been significantly limited since the COMPTEL instrument aboard the Compton Gamma Ray Observatory(CGRO)satellite was decommissioned in 2000.The exploration... The observation of the low-energyγ-ray(0.1 to 30 MeV)sky has been significantly limited since the COMPTEL instrument aboard the Compton Gamma Ray Observatory(CGRO)satellite was decommissioned in 2000.The exploration ofγ-ray photons within this energy band,often referred to as the MeV gap,is crucial to address numerous unresolved mysteries in high-energy and multi-messenger astrophysics.Although several large MeVγ-ray missions have been proposed(e.g.,e-ASTROGAM,AMEGO,and COSI),most of these are in the planning phase,with launches not expected until the next decade,at the earliest.Recently,there has been a surge in proposed CubeSat missions as cost-effective and rapidly implementable pathfinder alternatives.An MeV CubeSat dedicated toγ-ray astronomy could serve as a valuable demonstrator for large-scale future MeV payloads.This paper proposes aγ-ray payload design with a silicon-based tracker and a cesium iodide-based calorimeter.We report the results of a simulation study to assess the performance of this payload concept and compare the results with those of previousγ-ray instruments.As part of the performance assessment and comparison,we show that with our proposed payload design,a sensitivity better than IBIS can be achieved for energies between 0.1 and 10 MeV,and for energies up to around 1 MeV,the achieved sensitivity is comparable to COMPTEL,therefore opening up a window toward cost-effective observational astronomy with comparable performance to past missions. 展开更多
关键词 U cubesat compton gamma ray observatory cgro satellite address numerous unresolved mysteries silicon based detector soft ray astronomy E ASTROGAM comptel instrument low energy ray
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Hepatic venous pressure gradient in hepatic resection for hepatocellular carcinoma
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作者 Sarah Shalaby Patrizia Burra Marco Senzolo 《Hepatoma Research》 2023年第1期669-682,共14页
Liver transplantation is considered the gold standard for curative treatment of hepatocellular carcinoma(HCC)in patients with cirrhosis,but limited organ availability and high costs necessitate alternative options.Hep... Liver transplantation is considered the gold standard for curative treatment of hepatocellular carcinoma(HCC)in patients with cirrhosis,but limited organ availability and high costs necessitate alternative options.Hepatic resection(HR)is preferred for select patients,providing tumor removal and prognostic information.However,HR has been associated with life-threatening complications,especially in the presence of clinically significant portal hypertension(CSPH).Current guidelines recommend HR only for patients with well-preserved liver function,normal bilirubin levels,good performance status,and no CSPH.However,advancements in surgical techniques and portal hypertension management are challenging these guidelines,potentially allowing the consideration of hepatic resection for HCC in cirrhotic patients with CSPH.Indeed,minimally invasive approaches improve safety and outcomes for selected CSPH patients and accurate assessment of CSPH allows risk stratification according to liver function,tumor location,and extent of resection.Thus,despite the negative impact of CSPH on HR outcomes,careful patient selection and minimally invasive techniques expand the potential for HR in CSPH patients.This comprehensive review examines the evidence on HR in HCC treatment for cirrhotic patients with CSPH,highlighting challenges in surgical decision-making,the importance of direct measurement of hepatic venous pressure gradient,and exploring the benefits and risks associated with HR.Moreover,it underscores the need for refined prediction models and algorithms to optimize patient selection and enhance surgical outcomes. 展开更多
关键词 Hepatocellular carcinoma hepatic resection hepatic venous pressure gradient clinically significant portal hypertension unresolved postoperative hepatic decompensation
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