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Synthesis, UV-curing Behavior and Surface Properties of New Fluorine-containing Aromatic Oxetane Monomers 被引量:2
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作者 Shu-Qing Fang Yu-Lian Pang Ying-Quan Zou 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2018年第4期521-527,共7页
In this paper, we combined high-end cationic UV-curable material with fluorinated chain obtaining a series of new fluorine-containing aromatic oxetane monomers via a mild nucleophilic substitution reaction. The struct... In this paper, we combined high-end cationic UV-curable material with fluorinated chain obtaining a series of new fluorine-containing aromatic oxetane monomers via a mild nucleophilic substitution reaction. The structures and properties of monomers were characterized using ~1 H-NMR, ^(19) F-NMR, dynamic viscosity tests and differential scanning calorimetry(DSC). It was determined that all of the fluorinated monomers obtained had much lower viscosity and higher thermostability after the introduction of hexafluorobenzene. Then, UV-curable coatings were prepared using four fluorine-containing aromatic oxetane monomers(FOX1-4); the UV-curing kinetics, with three kinds of initiators, and properties of the cured films were evaluated using real-time Fourier transform infrared(FTIR) spectroscopy, water and diiodomethane contact angle tests, surface energy calculations and scanning electron microscopy(SEM). The FTIR spectroscopy results showed that the coatings possessed excellent conversion rate(〉 99% with liquid initiator PAG-201 in 150 s), and as the fluorine content increased, the monomers exhibited decreased mobility with the increasing viscosity and worse solubility with fluorinated monomers, resulting in a lower conversion rate. Moreover, the coatings possessed favorable hydrophobic and oleophobic properties and low surface energies owing to the fluoride chains floating to the membrane-air interface, which was also confirmed by discrete concave structures in SEM images. These new kinds of monomers can replace traditional fluorinated cationic monomers applied to the fingerprint resistant, fouling resistant, scratch resistant and anti-aging coatings, adhesives or printing ink materials. 展开更多
关键词 Fluorine-containing monomers OXETANE uv-curing kinetics Surface properties
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Correction: Optimizing Exciton and Charge-Carrier Behavior in Thick-Film Organic Photovoltaics: A Comprehensive Review
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作者 Lu Wei Yaxin Yang +2 位作者 Lingling Zhan Shouchun Yin Hongzheng Chen 《Nano-Micro Letters》 2026年第1期608-608,共1页
Correction to:Nano-Micro Letters(2026)18:10.https://doi.org/10.1007/s40820-025-01852-8 Following publication of the original article[1],the authors reported that the last author’s name was inadvertently misspelled.Th... Correction to:Nano-Micro Letters(2026)18:10.https://doi.org/10.1007/s40820-025-01852-8 Following publication of the original article[1],the authors reported that the last author’s name was inadvertently misspelled.The published version showed“Hongzhen Chen”,whereas the correct spelling should be“Hongzheng Chen”.The correct author name has been provided in this Correction,and the original article[1]has been corrected. 展开更多
关键词 charge carrier behavior exciton behavior comprehensive review thick film organic photovoltaics nano micro letters
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Corrosion behavior of 650 MPa high strength low alloy steel in industrial polluted environments containing different concentrations of Cl^(-)
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作者 Lianjun Hao Xiaokun Cai +4 位作者 Tianqi Chen Chenyu Zhang Chao Liu Xuequn Cheng Xiaogang Li 《International Journal of Minerals,Metallurgy and Materials》 2026年第1期228-241,共14页
This study utilizes wet/dry cyclic corrosion testing combined with corrosion big data technology to investigate the mechanism by which chloride ions(Cl^(-))influence the corrosion behavior of 650 MPa high-strength low... This study utilizes wet/dry cyclic corrosion testing combined with corrosion big data technology to investigate the mechanism by which chloride ions(Cl^(-))influence the corrosion behavior of 650 MPa high-strength low-alloy(HSLA)steel in industrially polluted environments.The corrosion process of 650 MPa HSLA steel occurred in two distinct stages:an initial corrosion stage and a stable corrosion stage.During the initial phase,the weight loss rate increased rapidly owing to the instability of the rust layer.Notably,this study demonstrated that 650 MPa HSLA steel exhibited superior corrosion resistance in Cl-containing environments.The formation of a corrosion-product film eventually reduced the weight-loss rate.However,the intrusion of Cl^(-)at increasing concentrations gradually destabilized theα/γ^(*)phases of the rust layer,leading to a looser structure and lower polarization resistance(R_(p)).The application of corrosion big data technology in this study facilitated the validation and analysis of the experimental results,offering new insights into the corrosion mechanisms of HSLA steel in chloride-rich environments. 展开更多
关键词 HSLA steel CHLORINE corrosion behavior corrosion big data
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Self-management and help-seeking behavior for gastroesophageal reflux symptoms:A population-based survey
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作者 Lotte J Huibertse Jasmijn Sijben +1 位作者 Yonne Peters Peter D Siersema 《World Journal of Gastroenterology》 2026年第2期124-134,共11页
BACKGROUND Despite societal guidelines recommending targeted screening for Barrett’s esophagus(BE)and esophageal adenocarcinoma(EAC)in individuals with gastroesophageal reflux symptoms(GERS),screening adherence is su... BACKGROUND Despite societal guidelines recommending targeted screening for Barrett’s esophagus(BE)and esophageal adenocarcinoma(EAC)in individuals with gastroesophageal reflux symptoms(GERS),screening adherence is suboptimal.Current screening approaches fail to identify individuals not seeking medical consultation for GERS or whose GERS are managed with‘over-the-counter’(OTC)acid suppressant therapies.AIM To assess patients’self-management and help-seeking behavior for GERS.METHODS This cross-sectional study collected data from the Dutch general population aged 18-75 years between January and April 2023 using a web-based survey.The survey included questions regarding self-management(e.g.,use of acid suppressant therapy with or without prescription)and help-seeking behavior(e.g.,consulting a primary care provider)for GERS.Simple random sampling was performed to select individuals within the target age group.In total,18156 randomly selected individuals were invited to participate.The study protocol was registered in ClinicalTrials.gov(identifier:NCT05689918).RESULTS Of the 18156 invited individuals,3214 participants(17.7%)completed the survey,of which 1572 participants(48.9%)reported GERS.Of these,904 participants(57.5%)had never consulted a primary care provider for these symptoms,of which 331 participants(36.6%)reported taking OTC acid suppressant therapy in the past six months and 100 participants(11.1%)fulfilled the screening criteria for BE and EAC according to the European Society of Gastrointestinal Endoscopy Guideline.CONCLUSION The population fulfilling the screening criteria for BE and EAC is incompletely identified,suggesting potential underutilization of medical consultation.Raising public awareness of GERS as a risk factor for EAC is needed. 展开更多
关键词 Gastroesophageal reflux disease AWARENESS SELF-MANAGEMENT Help-seeking behavior Health promotion Patientreported outcomes
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Cognitive behavioral therapy enhances psychological and physiological outcomes in high-altitude respiratory patients
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作者 De-Feng Meng Dong-You Zhang +3 位作者 Fan Yang Peng-Li Meng Ting-Ting Wen Yu-Zhao Wang 《World Journal of Psychiatry》 2026年第1期212-220,共9页
BACKGROUND Due to the dry and cold climate,the obvious temperature difference between day and night,and the low oxygen content of the air in the plateau area,people are prone to upper respiratory tract diseases,and of... BACKGROUND Due to the dry and cold climate,the obvious temperature difference between day and night,and the low oxygen content of the air in the plateau area,people are prone to upper respiratory tract diseases,and often the condition is prolonged,and the patients are prone to anxiety and uneasiness,which may be related to the harshness of the plateau environment,somatic discomfort due to the lack of oxygen,anxiety about the disease,and other factors.AIM To investigate the effects of cognitive behavioral therapy(CBT)on anxiety,sleep disorders,and hypoxia tolerance in patients with high-altitude respiratory diseases.METHODS A total of 2337 patients with high-altitude-related respiratory diseases treated at our hospital between November 2023 and January 2024 were selected as the study subjects.The subjects’pre-high-altitude residential altitude was approximately 1700 meters.They were divided into two groups.Both groups were given symptomatic treatment,and the control group implemented conventional nursing intervention,while the research group simultaneously conducted CBT intervention;assessed the degree of health knowledge of the two groups,and applied the Hamilton Anxiety Scale and the Pittsburgh Sleep Quality Index to assess the anxiety and sleep quality of the patients before and after the intervention,respectively.It also observed the length and efficiency of sleep,and detected the level of serum hypoxia inducible factor-1α,erythropoietin(EPO)and clinical intervention before and after intervention.EPO levels,and investigated satisfaction with the clinical intervention.RESULTS The rate of excellent health knowledge in the intervention group was 93.64%,which was higher than that in the control group(74.23%;P<0.05).Before the intervention,there was no significant difference in Hamilton Anxiety Scale and Pittsburgh Sleep Quality Index scores between the two groups(P>0.05),and after the intervention,the scores of the study group were significantly lower than those of the control group(P<0.05).There was no significant difference in sleep duration and sleep efficiency between the groups before the intervention(P>0.05),and after the intervention,the scores of the study group were significantly larger than those of the control group(P<0.05).There was no significant difference in serum hypoxia inducible factor-1αand EPO between the two groups before intervention(P>0.05),and both research groups were significantly lower than the control group after intervention(P<0.05).According to the questionnaire survey,the intervention satisfaction of the study group was 95.53%,which was higher than that of the control group(80.14%;P<0.05).CONCLUSION The CBT intervention in the treatment of patients with high-altitude-related respiratory diseases helps improve patients'health knowledge,relieve anxiety,improve sleep quality and hypoxia tolerance,and improve nursing satisfaction. 展开更多
关键词 Cognitive behavioral therapy High altitude respiratory disease ANXIETY Sleep quality Hypoxia tolerance
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Influence of cognitive behavioral therapy-based psychological interventions on psychological well-being and quality of life among laryngeal carcinoma patients
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作者 Hong-Zhu Tao You-Min Deng +1 位作者 Shu-Feng Xia Yan Feng 《World Journal of Psychiatry》 2026年第1期136-144,共9页
BACKGROUND Approximately 30%of patients with head and neck cancer experience adverse effects caused by anxiety and depression.Considering the high prevalence,implementing customized interventions to ease adverse emoti... BACKGROUND Approximately 30%of patients with head and neck cancer experience adverse effects caused by anxiety and depression.Considering the high prevalence,implementing customized interventions to ease adverse emotional states is imperative.AIM To evaluate the efficacy of cognitive behavioral therapy(CBT)-based psychological interventions in improving the psychological well-being and quality of life(QoL)of patients with laryngeal carcinoma.METHODS This study enrolled 120 patients admitted from February 2022 to February 2024.The control group,comprising 50 participants,received standard supportive psychological care,while the research group,consisting 70 participants,underwent CBT-based interventions.Several clinical outcomes were systematically assessed that included postoperative recovery metrics(duration of tracheostomy and nasogastric tube dependence and length of hospitalization),psychological status(Self-Rating Anxiety Scale and Self-Rating Depression Scale),nutritional markers(serum albumin and hemoglobin levels),sleep quality(Self-Rating Scale of Sleep and Athens Insomnia Scale),and QoL(Functional Assessment of Cancer Therapy-Head and Neck).RESULTS The results demonstrated that the research group experienced superior outcomes,with significantly reduced durations of tracheostomy and nasogastric tube dependence,as well as shorter hospital stays,compared with the control group.Additionally,the research group exhibited markedly lower post-intervention Self-Rating Anxiety Scale,Self-Rating Depression Scale,Self-Rating Scale of Sleep,and Athens Insomnia Scale scores,along with minimal but higher change in serum albumin and hemoglobin levels compared with the control group.All five domains of Functional Assessment of Cancer Therapy-Head and Neck showed notable improvements in the research group,exceeding those observed in the control group.CONCLUSION CBT-based psychological support positively affects the mental well-being and QoL of patients with laryngeal carcinoma,highlighting its potential for broader clinical application. 展开更多
关键词 Laryngeal carcinoma Cognitive behavioral therapy Psychological intervention Mental state Quality of life
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Exploring artificial intelligence literacy’s role in healthy behaviors and mental health
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作者 Jaewon Lee Jennifer Allen Gyuhyun Choi 《World Journal of Psychiatry》 2026年第1期55-60,共6页
Healthy behavior has long been linked to mental health outcomes.However,the role of artificial intelligence(AI)literacy in shaping healthy behaviors and its potential impact on mental health remains underexplored.This... Healthy behavior has long been linked to mental health outcomes.However,the role of artificial intelligence(AI)literacy in shaping healthy behaviors and its potential impact on mental health remains underexplored.This paper presents a scoping review offering a novel perspective on the intersection of healthy behaviors,mental health,and AI literacy.By examining how individuals’understanding of AI influences their choices regarding nutrition and their susceptibility to mental health issues,the current study explores emerging trends in health behavior decision-making.This emphasizes the need for integrating AI literacy into mental health and health behaviors education,as well as the development of AI-driven tools to support healthier behavior choices.It highlights that individuals with low AI literacy may misinterpret or overly depend on AI guidance,resulting in maladaptive health choices,while those with high AI literacy may be more likely to engage reflectively and sustain positive behaviors.The paper outlines the importance of inclusive education,user-centered design,and community-based support systems to enhance AI literacy for digitally marginalized groups.AI literacy may be positioned as a key determinant of health equity,better allowing for interdisciplinary strategies that empower individuals to make informed,autonomous decisions that promote both physical and mental health. 展开更多
关键词 Artificial intelligence literacy Mental health Healthy behavior Digital health education Technology acceptance
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Dynamic fracture behavior and coupled impact effect of as-cast W-Zr-Ti energetic structural material
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作者 Yuxuan Qi Liang Mao +3 位作者 Chunlan Jiang Guitao Liu Kongxun Zhao Mengchen Zhang 《Defence Technology(防务技术)》 2026年第1期422-435,共14页
This paper prepared a novel as-cast W-Zr-Ti metallic ESM using high-frequency vacuum induction melting technique.The above ESM performs a typical elastic-brittle material feature and strain rate strengthening behavior... This paper prepared a novel as-cast W-Zr-Ti metallic ESM using high-frequency vacuum induction melting technique.The above ESM performs a typical elastic-brittle material feature and strain rate strengthening behavior.The specimens exhibit violent chemical reaction during the fracture process under the impact loading,and the size distribution of their residual debris follows Rosin-Rammler model.The dynamic fracture toughness is obtained by the fitting of debris length scale,approximately 1.87 MPa·m~(1/2).Microstructure observation on residual debris indicates that the failure process is determined by primary crack propagation under quasi-static compression,while it is affected by multiple cracks propagation in both particle and matrix in the case of dynamic impact.Impact test demonstrates that the novel energetic fragment performs brilliant penetration and combustion effect behind the front target,leading to the effective ignition of fuel tank.For the brittleness of as-cast W-ZrTi ESM,further study conducted bond-based peridynamic(BB-PD)C++computational code to simulate its fracture behavior during penetration.The BB-PD method successfully captured the fracture process and debris cloud formation of the energetic fragment.This paper explores a novel as-cast metallic ESM,and provides an available numerical avenue to the simulation of brittle energetic fragment. 展开更多
关键词 Energetic structural material Dynamic fracture behavior Coupled impact effect Mechanical property Peridynamics As-cast W-Zr-Ti alloy
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Microstructure evolution and corrosion behavior of refill friction stir spot welding joint for dissimilar Al alloys
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作者 Fang-yuan JIANG Da ZHANG +3 位作者 Yan-kun MA Jiang-tao XIONG Wei GUO Jing-long LI 《Transactions of Nonferrous Metals Society of China》 2026年第1期80-95,共16页
The dissimilar 2B06 and 7B04 Al alloy joints were prepared by refill friction stir spot welding(RFSSW),and the microstructural evolution and corrosion behavior of the joints were investigated.Based on microstructural ... The dissimilar 2B06 and 7B04 Al alloy joints were prepared by refill friction stir spot welding(RFSSW),and the microstructural evolution and corrosion behavior of the joints were investigated.Based on microstructural analysis,the welded joints exhibit distinct microstructural zones,including the stir zone(SZ),thermomechanically affected zone(TMAZ),and heat-affected zone(HAZ).The grain size of each zone is in the order of HAZ>TMAZ>SZ.Notably,the TMAZ and HAZ contain significantly larger secondary-phase particles compared to the SZ,with particle size in the HAZ increasing at higher rotational speeds.Electrochemical tests indicate that corrosion susceptibility follows the sequence of HAZ>TMAZ>SZ>BM,with greater sensitivity observed at increased rotational speeds.Post-corrosion mechanical performance degradation primarily arises from crevice corrosion at joint overlaps,but not from the changes in the microstructure. 展开更多
关键词 refill friction stir spot welding high strength Al alloy dissimilar joint microstructure evolution corrosion behavior
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Privacy-Preserving Gender-Based Customer Behavior Analytics in Retail Spaces Using Computer Vision
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作者 Ginanjar Suwasono Adi Samsul Huda +4 位作者 Griffani Megiyanto Rahmatullah Dodit Suprianto Dinda Qurrota Aini Al-Sefy Ivon Sandya Sari Putri Lalu Tri Wijaya Nata Kusuma 《Computers, Materials & Continua》 2026年第1期1839-1861,共23页
In the competitive retail industry of the digital era,data-driven insights into gender-specific customer behavior are essential.They support the optimization of store performance,layout design,product placement,and ta... In the competitive retail industry of the digital era,data-driven insights into gender-specific customer behavior are essential.They support the optimization of store performance,layout design,product placement,and targeted marketing.However,existing computer vision solutions often rely on facial recognition to gather such insights,raising significant privacy and ethical concerns.To address these issues,this paper presents a privacypreserving customer analytics system through two key strategies.First,we deploy a deep learning framework using YOLOv9s,trained on the RCA-TVGender dataset.Cameras are positioned perpendicular to observation areas to reduce facial visibility while maintaining accurate gender classification.Second,we apply AES-128 encryption to customer position data,ensuring secure access and regulatory compliance.Our system achieved overall performance,with 81.5%mAP@50,77.7%precision,and 75.7%recall.Moreover,a 90-min observational study confirmed the system’s ability to generate privacy-protected heatmaps revealing distinct behavioral patterns between male and female customers.For instance,women spent more time in certain areas and showed interest in different products.These results confirm the system’s effectiveness in enabling personalized layout and marketing strategies without compromising privacy. 展开更多
关键词 Business intelligence customer behavior privacy-preserving analytics computer vision deep learning smart retail gender recognition heatmap privacy RCA-TVGender dataset
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Pressure-Modulated Activation Energy as a Unified Descriptor of Mechanical Behavior in Metallic Glass
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作者 Huanrong Liu Jian Li +1 位作者 Shan Zhang Pengfei Guan 《Chinese Physics Letters》 2026年第1期71-82,共12页
The functional properties of glasses are governed by their formation history and the complex relaxation processes they undergo.However,under extreme conditions,glass behaviors are still elusive.In this study,we employ... The functional properties of glasses are governed by their formation history and the complex relaxation processes they undergo.However,under extreme conditions,glass behaviors are still elusive.In this study,we employ simulations with varied protocols to evaluate the effectiveness of different descriptors in predicting mechanical properties across both low-and high-pressure regimes.Our findings demonstrate that conventional structural and configurational descriptors fail to correlate with the mechanical response following pressure release,whereas the activation energy descriptor exhibits robust linearity with shear modulus after correcting for pressure effects.Notably,the soft mode parameter emerges as an ideal and computationally efficient alternative for capturing this mechanical behavior.These findings provide critical insights into the influence of pressure on glassy properties,integrating the distinct features of compressed glasses into a unified theoretical framework. 展开更多
关键词 pressure modulated activation energy predicting mechanical properties metallic glass relaxation processes functional properties mechanical behavior simulations varied protocols structural configurational descriptors
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Self-assembly and UV-curing Property of Polymerized Lyotropic Liquid Crystal Monomer of Sodium 3,4,5-tris(ll-acryloxyundecyloxy)benzoate 被引量:1
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作者 白玉勤 郭金宝 +1 位作者 王影 魏杰 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第1期95-101,I0004,共8页
A polymerized lyotropic liquid crystal monomer of sodium 3,4,5-tris(11-acryloxyundecyloxy)- benzoate was synthesized by a convenient route starting from 3,4,5-trihydroxybenzoic acid via esterification followed by et... A polymerized lyotropic liquid crystal monomer of sodium 3,4,5-tris(11-acryloxyundecyloxy)- benzoate was synthesized by a convenient route starting from 3,4,5-trihydroxybenzoic acid via esterification followed by etherification, acylation and finally neutralization. The chemi- cal structure was confirmed by Fourier transform infrared (FT-IR) and 1H nuclear magnetic resonance spectral analysis. The self-organization behavior of the monomer with deionized water in methanol at room temperature was also demonstrated. The assemblies were char- acterized by polarized optical microscope and X-ray diffraction. The results show that a solution containing 80:20 of the monomer to water was found to be able to self-organize into Lamellar (La) phase and 92:8 with inverted hexagonal (H]I) phase, which was in ac- cordance with the theoretical calculation of critical packing parameter. It suggests that the concentration of the monomer was the key factor to influence assembly structure. Addi- tionally, the acrylate conversion with different photoinitiators and nanostructure retention after polymerization were investigated. The research shows that the acrylate conversion of the monomer with Darocur2959 could reach up to 78% when irradiated by 30 mW/cm2 UV light of 365 nm for 30 min characterized by Real-time FT-IR as well as the sol-gel method. Meanwhile, the La and HII phase nanostructures were both retained after polymerization. 展开更多
关键词 Polymerized lyotropic liquid crystal SELF-ASSEMBLY La phase HII phase uv-curing
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UV-curing of hyperbranched polyurethane acrylate-polyurethane diacrylate/SiO_2 dispersion and TGA/FTIR study of cured films 被引量:11
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作者 GAO Qiong-zhi LI Hong-qiang ZENG Xing-rong 《Journal of Central South University》 SCIE EI CAS 2012年第1期63-70,共8页
UV-curable hyperbranched polyurethane acrylate-polyurethane diacrylate/SiO2 dispersion (HBPUA-PUDA/SiO2) was prepared with isophorone diisocyanate (IPDI), hyperbranched polyester Boltorn H20 (H20), hydroxy-ethyl... UV-curable hyperbranched polyurethane acrylate-polyurethane diacrylate/SiO2 dispersion (HBPUA-PUDA/SiO2) was prepared with isophorone diisocyanate (IPDI), hyperbranched polyester Boltorn H20 (H20), hydroxy-ethyl acrylate (HEA), polyethyleneglycol (PEG-200)and nano-SiO2. The UV curing kinetics of the films was investigated by FTIR. The results show that the curing speed of the films increases with the adding of nano-SiO2 and decreases with the adding of PUDA due to the slower chain movement. The thermal stability of the HBPUA-PUDA/SiO2 films was studied by using thermogravimetric analysis coupled with Fourier transform infrared spectroscopy (TGA/FTIR). The results show that all films exhibit two degradation stages located at about 320 and 440℃ corresponding to the degradation for hard segments of urethane-acrylate and the degradation for soft segment and polyester core. In addition, the results from the analysis of TGA/FTIR also indicate that the decomposition temperature of HBPUA-PUDA/SiO2 film is 15℃ higher than that obtained for pure polymer. The degradation mechanism was proposed according to TGA/FTIR results. 展开更多
关键词 uv-curing hyperbranched polyurethane acrylate urethane diacrylate TGA/FTIR thermal degradation
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Photocuring Behaviors of UV-Curable Perfluoropolyether-Based Fluoropolymers with and without Tertiary Amine 被引量:1
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作者 Jung-Dae Cho Dong-Pyo Kim Jin-Who Hong 《Open Journal of Organic Polymer Materials》 2014年第1期6-9,共4页
UV-curable perfluoropolyether (PFPE)-based fluoropolymer (PFPE-DMA) was synthesized and the photocuring behaviors of PFPE-DMA/HDDA systems with and without tertiary triethyl amine (TEA) were investigated using photo-D... UV-curable perfluoropolyether (PFPE)-based fluoropolymer (PFPE-DMA) was synthesized and the photocuring behaviors of PFPE-DMA/HDDA systems with and without tertiary triethyl amine (TEA) were investigated using photo-DSC under air and nitrogen atmospheres. Photo-DSC analysis revealed that N2 purging and the presence of TEA mitigated oxygen inhibition in the photopolymerization of the UV-curable free-radical PFPE-DMA/ HDDA system. In addition, TEA synergistically acted as a coinitiator or photosynergist under nitrogen atmosphere, which increased the cure rate and percentage conversion for the photopolymerization of PFPE-DMA/ HDDA. TEA acted as both oxygen scavenger and photosynergist. The results presented here demonstrate that investigating the photocuring behaviors of PFPE-DMA/HDDA systems is very helpful to determine the optimal curing conditions for the PFPE-DMA fluoropolymer. 展开更多
关键词 FLUOROPOLYMER PHOTOCURING behaviorS Oxygen Inhibition Photosynergist
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Fabrication of UV-Curing Linalool-Polysiloxane Hybrid Films with High Refractive Index and Transparency
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作者 Wenqing Xiao Lewen Tan +2 位作者 Xunjun Chen Qiaoguang Li Yunqing Ruan 《Journal of Renewable Materials》 EI CAS 2024年第3期569-583,共15页
In this article,a series of high refractive indices(1.50-1.53)thiol phenyl polysiloxane(TPS)were synthesized via hydrolytic sol-gel reaction.The Fourier transform infrared spectra(FT-IR)and nuclear magnetic resonance ... In this article,a series of high refractive indices(1.50-1.53)thiol phenyl polysiloxane(TPS)were synthesized via hydrolytic sol-gel reaction.The Fourier transform infrared spectra(FT-IR)and nuclear magnetic resonance spectra(NMR)results showed that TPS conformed to the predicted structures.Natural terpene linalool was exploited as photocrosslinker to fabricate UV-curing linalool-polysiloxane hybrid films(LPH)with TPS via photoinitiated thiol-ene reaction.LPH rapidly cured under UV irradiation at the intensity of 80 mW/cm^(2) in 30 s,exhibiting good UV-curing properties.The optical transmittance of LPH in the wavelength of 300-800 nm was over 90%,exhibiting good optical transparency.The water contact angle and water vapor permeability results showed that the introduction of phenyl groups enhance the hydrophobicity and water vapor barrier properties of LPH.The results indicated the potential of LPHs in the applications of optical functional coatings. 展开更多
关键词 uv-curing polysiloxane hybrid films high refractive index TRANSPARENCY
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Synthesis of A Novel UV-curable Oligmer 1,4-cyclohexanedimethanol Glycidyl Ether Acrylate and Study on Its UV-curing Properties
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作者 黄笔武 DENG Chong +2 位作者 XU Qinchang CHEN Weiqing ZOU Huaihua 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2014年第6期1283-1289,共7页
A novel UV-curable oligmer 1,4-cyclohexanedimethanol glycidyl ether acrylate(CHDMGEA) was synthesized by utilizing 1,4-cyclohexanedimethanol glycidyl ether(CHDMGE) and acrylic acid(AA) as starting materials, tri... A novel UV-curable oligmer 1,4-cyclohexanedimethanol glycidyl ether acrylate(CHDMGEA) was synthesized by utilizing 1,4-cyclohexanedimethanol glycidyl ether(CHDMGE) and acrylic acid(AA) as starting materials, triphenyl phosphine as catalyst and p-hydroxyanisole as inhibitor. The optimum synthetic conditions were that the concentration of triphenyl phosphine was 0.90% of reactants by weight, the concentration of p-hydroxyanisole was 0.20% of reactants by weight, the reaction temperature was 90-100 ℃, and the molar ratio of CHDMGE to AA was 0.5:1.1. The experimental results show that CHDMGEA is a kind of good UV-curable oligmer. The impact resistance of the UV-cured films with CHDMGEA as oligmer to prepare UV-curing coating was superior to that of the UV-cured films with bisphenol A diglycidyl ether diacrylate(BPGEA) as oligmer to prepare UV-curing coating. 展开更多
关键词 1 4-cyclohexanedimethanol glycidyl ether acrylate synthesis acrylic acid uv-curable oligmer film
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Fracture Behavior of Nickel-Based Single Crystal Superalloy During High-Cycle Fatigue at 850℃ 被引量:1
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作者 Zhang Jingang Liu Xinling +4 位作者 Chen Xing Li Zhen Liu Jiabin Teng Peng Liu Changkui 《稀有金属材料与工程》 北大核心 2025年第11期2777-2785,共9页
The high-cycle fatigue fracture characteristics and damage mechanism of nickel-based single crystal superalloys at 850℃ was investigated.The results indicate that high-cycle fatigue cracks in single crystal superallo... The high-cycle fatigue fracture characteristics and damage mechanism of nickel-based single crystal superalloys at 850℃ was investigated.The results indicate that high-cycle fatigue cracks in single crystal superalloys generally originate from defect locations on the subsurface or interior of the specimen at 850℃.Under the condition of stress ratio R=0.05,as the fatigue load decreases,the high-cycle fatigue life gradually increases.The high-cycle fatigue fracture is mainly characterized by octahedral slip mechanism.At high stress and low lifespan,the fracture exhibits single or multiple slip surface features.Some fractures originate along a vertical small plane and then propagate along the{111}slip surface.At low stress and high lifespan,the fracture surface tend to alternate and expand along multiple slip planes after originating from subsurface or internal sources,exhibiting characteristics of multiple slip planes.Through electron backscatter diffraction and transmission electron microscope analysis,there is obvious oxidation behavior on the surface of the high-cycle fatigue fracture,and the fracture section is composed of oxidation layer,distortion layer,and matrix layer from the outside to the inside.Among them,the main components of the oxidation layer are oxides of Ni and Co.The distortion layer is mainly distributed in the form of elongated or short rod-shaped oxides of Al,Ta,and W.The matrix layer is a single crystal layer.Crack initiation and propagation mechanism were obtained by systematical analysis of a large number of highcycle fatigue fractures.In addition,the stress ratio of 0.05 is closer to the vibration mode of turbine blades during actual service,providing effective guidance for the study of failure and fracture mechanisms of turbine blades. 展开更多
关键词 single crystal superalloys high-cycle fatigue oxidation behavior SLIP oxidation layer
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Research progress on the effects of sedentary behavior and physical activity on diabetes mellitus 被引量:1
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作者 CHEN Qi LI Chuan-Fen JING Wen 《生理学报》 北大核心 2025年第1期62-74,共13页
Diabetes mellitus(DM)has become one of the most serious and common chronic diseases around the world,leading to various complications and a reduction in life expectancy.Increased sedentary behavior(SB)and decreased ph... Diabetes mellitus(DM)has become one of the most serious and common chronic diseases around the world,leading to various complications and a reduction in life expectancy.Increased sedentary behavior(SB)and decreased physical activity(PA)are important contributors to the rising prevalence of DM.This article reviews the research progress on the pathogenesis of DM,the effects of SB and PA on the risk of DM,aiming to explore the influence of different PA intensities,amounts,frequencies,durations and types on the incidence of DM.Research has shown that blood glucose levels tend to increase with the prolongation of SB.Within a certain range,PA intensity and PA amount are negatively correlated with the risk of DM;Performing PA for more than 3 days per week maintains normal glucose tolerance and lower blood pressure;Engaging in 150–300 min of moderate intensity exercise or 75–150 min of high-intensity exercise per week reduces the risk of DM;PA during leisure time reduces the risk of DM,while PA during work increases the risk of DM;Both aerobic training and resistance training reduce the risk of DM,and the combination of the two training methods produces better benefits;Various types of exercises,such as cycling,soccer,aerobics,yoga,tai chi,all reduce the risk of DM.In summary,prolonged SB increases the risk of DM,while appropriate PA reduces the risk of DM.As the intensity,amount,and frequency of PA increase,the effect of reducing DM risk becomes more significant.Different exercise methods have different effects on reducing DM risk. 展开更多
关键词 sedentary behavior physical activity diabetes mellitus sports rehabilitation health promotion
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Psychometric properties of the Chinese-version Behavioral Inhibition System/Behavioral Activation System Scales among stroke survivors with depressive symptoms 被引量:1
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作者 Dan Shi Yuen Yu Chong +1 位作者 Lijuan Zhou Ho Yu Cheng 《International Journal of Nursing Sciences》 2025年第1期74-80,共7页
Objective:This study aimed to examine the reliability and validity of the Chinese version of the Behavioral Inhibition System/Behavioral Activation System(BIS/BAS)scales among stroke survivors.Methods:The cross-sectio... Objective:This study aimed to examine the reliability and validity of the Chinese version of the Behavioral Inhibition System/Behavioral Activation System(BIS/BAS)scales among stroke survivors.Methods:The cross-sectional study was conducted at four comprehensive hospitals in Taizhou,Jiangsu,China.A sample of 232 first-ever stroke survivors were recruited from June to August 2023.Validity was examined using face validity and construct validity,which used confirmatory factor analysis(CFA)and known-group analysis.Reliability was evaluated by internal consistency and test-retest reliability.Results:The BIS/BAS scales demonstrated satisfactory face validity.The findings of CFAs supported the original four-factor structure of BAS-reward,BAS-drive,BAS-fun seeking,and BIS with acceptable model fit indices.Discriminative validity,assessed via known-group analysis,indicated that stroke survivors with probable depression had significantly lower mean BAS-reward,BAS-drive,and BAS-fun seeking scores(P<0.001)and a higher mean BIS score(P=0.028)compared to those without probable depression.The internal consistency,measured by Cronbach’s a coefficients for the subscales,ranged from 0.669 to 0.964.Test-retest reliability,assessed using intra-class correlation coefficients,ranged from 0.61 to 0.93.Conclusions:The Chinese version of the BIS/BAS scales could be a reliable and valid instrument for measuring behavioral activation among stroke survivors. 展开更多
关键词 behavior DEPRESSION Reliability STROKE Validity
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Electrochemical behavior and discharge performance of as-rolled precipitate-free Mg-Sn alloy as anode for Mg-air batteries 被引量:2
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作者 Xu LI Wei-li CHENG +7 位作者 Jian LI Fei-er SHANGGUAN Hui YU Li-fei WANG Hang LI Hong-xia WANG Jin-hui WANG Hua HOU 《Transactions of Nonferrous Metals Society of China》 2025年第3期832-848,共17页
A novel precipitate-free Mg-0.1Sn anode with a homogeneous equal-axis grain structure was developed and rolled successfully at 573 K.Electrochemical test results indicate that the Mg-0.1Sn alloy exhibits enhanced anod... A novel precipitate-free Mg-0.1Sn anode with a homogeneous equal-axis grain structure was developed and rolled successfully at 573 K.Electrochemical test results indicate that the Mg-0.1Sn alloy exhibits enhanced anode dissolution kinetics.A Mg-air battery prepared using this anode exhibits a cell voltage of 1.626 V at 0.5 mA/cm^(2),reasonable anodic efficiency of 58.17%,and good specific energy of 1730.96 mW·h/g at 10 mA/cm^(2).This performance is attributed to the effective reactive anode surface,the suppressed chunk effect,and weak self-corrosion owing to the homogeneous basal texture. 展开更多
关键词 Mg-air battery Mg-Sn anode grain structure electrochemical behavior discharge performance
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