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Recent progress in two-proton radioactivity 被引量:8
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作者 Long Zhou Si-Min Wang +1 位作者 De-Qing Fang Yu-Gang Ma 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2022年第8期118-146,共29页
During the last few decades,rare isotope beam facilities have provided unique data for studying the properties of nuclides located far from the beta-stability line.Such nuclei are often accompanied by exotic structure... During the last few decades,rare isotope beam facilities have provided unique data for studying the properties of nuclides located far from the beta-stability line.Such nuclei are often accompanied by exotic structures and radioactive modes,which represent the forefront of nuclear research.Among them,two-proton(2p)radioactivity is a rare decay mode found in a few highly proton-rich isotopes.The 2p decay lifetimes and properties of emitted protons hold invaluable information regarding the nuclear structures in the presence of a low-lying proton continuum;as such,they have attracted considerable research attention.In this review,we present some of the recent experimental and theoretical progress regarding the 2p decay,including technical innovations for measuring nucleon-nucleon correlations and developments in the models that connect their structural aspects with their decay properties.This impressive progress should play a significant role in elucidating the mechanism of these exotic decays,probing the corresponding components inside nuclei,and providing deep insights into the open quantum nature of dripline systems. 展开更多
关键词 Exotic decay two-proton radioactivity Nucleon-nucleon correlation Experimental and theoretical development
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Effect of source size and emission time on the p–p momentum correlation function in the two-proton emission process 被引量:4
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作者 Long Zhou De-Qing Fang 《Nuclear Science and Techniques》 SCIE CAS CSCD 2020年第5期64-69,共6页
The effect of source size and emission time on the proton-proton(p-p)momentum correlation function(Cpp(q))has been studied systematically.Assuming a spherical Gaussian source with space and time profile according to t... The effect of source size and emission time on the proton-proton(p-p)momentum correlation function(Cpp(q))has been studied systematically.Assuming a spherical Gaussian source with space and time profile according to the function S(r,t)~exp(-r2/2 r02-t/τ)in the correlation function calculation code(CRAB),the results indicate that one Cpp(q)distribution corresponds to a unique combination of source size r0 and emission timeτ.Considering the possible nuclear deformation from a spherical nucleus,an ellipsoidal Gaussian source characterized by the deformation parameter∈=ΔR/R has been simulated.There is almost no difference of Cpp(q)between the results of spherically and ellipsoidally shaped sources with small deformation.These results indicate that a unique source size r0 and emission time could be extracted from the p-p momentum correlation function,which is especially important for identifying the mechanism of twoproton emission from proton-rich nuclei.Furthermore,considering the possible existence of cluster structures within a nucleus,the double Gaussian source is assumed.The results show that the p-p momentum correlation function for a source with or without cluster structures has large systematical differences with the variance of r0 andτ.This may provide a possible method for experimentally observing the cluster structures in proton-rich nuclei. 展开更多
关键词 two-proton EMISSION p–p MOMENTUM correlation function SOURCE SIZE EMISSION time
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Two-proton sequential decay from excited states of ^(18)Ne
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作者 YU Ningal MAGLIONE Enrico FERREIRA Lidia 《Nuclear Science and Techniques》 SCIE CAS CSCD 2013年第5期89-91,共3页
Two-proton radioactivity from18Ne is discussed in terms of sequential decay.The branch ratios for oneproton emission from excited states are calculated,which including spectroscopic factors,obtained from a Shellmodel ... Two-proton radioactivity from18Ne is discussed in terms of sequential decay.The branch ratios for oneproton emission from excited states are calculated,which including spectroscopic factors,obtained from a Shellmodel calculation with realistic interactions.The branch ratios show that the two-proton emission from the 1-state of 18Ne at 7.94 MeV is most likely to go through the sequential decay.The same mechanism is discussed for other excited states at higher energy by different interactions. 展开更多
关键词 质子衰变 激发态 质子发射 分支比 放射性 壳模型 衰减 计算
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A simple model for two-proton radioactivity
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作者 Jie-Dong Jiang Xiao Liu +3 位作者 Dong-Meng Zhang Ming Li Xi-Jun Wu Xiao-Hua Li 《Chinese Physics C》 SCIE CAS CSCD 2024年第10期247-255,共9页
In this work,considering the preformation factor of the emitted two protons in parent nucleus S_(2p) and the effect of the parent nucleus deformation,based on the Wentzel-Kramers-Brillouin approximation and Bohr-Somme... In this work,considering the preformation factor of the emitted two protons in parent nucleus S_(2p) and the effect of the parent nucleus deformation,based on the Wentzel-Kramers-Brillouin approximation and Bohr-Sommerfeld quantization condition,we improve a simple phenomenological model proposed by Bayrak[J.Phys.G:47,025102(2020)]to systematically study 2p radioactivity half-lives.This model contains two adjustable parameters V_(0) and a_(β),which are related to the depth of nuclear potential and effect of deformation.The calculated results show that this model can effectively reproduce the experimental data with a corresponding root-mean-square(RMS)standard deviation of σ=0.683.For comparison,we include the Gamow-like model(GLM)proposed by Liu et al.[Chin.Phys.C 45,044110(2021)],generalized liquid drop model(GLDM)proposed by Cui et al.[Phys.Rev.C 101,014301(2020)],effective liquid drop model(ELDM)proposed by M.Gonalves et al.[Phys.Lett.B 774,14(2017)],two-potential approach with Skyrme-Hartree-Fock(TPASHF)proposed by Pan et al.[Chin.Phys.C 45,124104(2021)],phenomenological model with a screened electrostatic barrier(SEB)propoesed by Zou et al.[Chin.Phys.C 45,104101(2021)],unified fission model(UFM)proposed by Xing et al.[Chin.Phys.C 45,124105(2021)],Coulomb and proximity potential model for deformed nuclei(CPPMDN)proposed by Santhosh[Phys.Rev.C 104,064613(2021)],two-parameter empirical formula proposed by Liu et al.[Chin.Phys.C 45,024108(2021)],and four-parameter empirical formula proposed by Sreeja et al.[Eur.Phys.J.A 55,33(2019)].In addition,we use this model to 2p predict the radioactive half-lives of some possible potential nuclei whose 2p radioactivity are energetically allowed or observed but not yet quantified in NUBASE2020. 展开更多
关键词 two-proton radioactivity HALF-LIVES Wentzel-Kramers-Brillouin approximation
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Roles of tensor force and pairing correlation in two-proton radioactivity of halo nuclei 被引量:2
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作者 王艳召 邢凤竹 +2 位作者 崔建坡 高永浩 顾建中 《Chinese Physics C》 SCIE CAS CSCD 2023年第8期39-53,共15页
The tensor force and pairing correlation effects on the two-proton radioactivity of^(18)Mg and^(20)Si with a pronounced two-proton halo are explored in the framework of spherical Skyrme-Hartree-Fock-Bogoliubov theory.... The tensor force and pairing correlation effects on the two-proton radioactivity of^(18)Mg and^(20)Si with a pronounced two-proton halo are explored in the framework of spherical Skyrme-Hartree-Fock-Bogoliubov theory.It is shown that the halo sizes are enhanced with the increase in the strength of the tensor force and pairing correlation.Furthermore,the increasing halo sizes lead to the enhancement of diproton emission.Then,the tensor force is found to have a small influence on the two-proton decay energies,and the two-proton decay energies calculated with strong surface pairing are smaller than those with weak mixed pairing.Because the two-proton decay energies are relat-ively large,the predicted order of magnitude of half-lives within the effective liquid drop model is not sensitive to the decay energy variation caused by the tensor force and pairing correlation,which has a value of approximately 10^(-18)s. 展开更多
关键词 tensor force pairing correlation two-proton halo two-proton radioactivity Skyrme-Hartree-Fock-Bogoliubov theory
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Experimental research into the two-proton emissions from ^(17,18) Ne,^(28) P and ^(28,29)S 被引量:4
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作者 LIN ChengJian1, XU XinXing1, JIA HuiMing1, YANG Feng1, JIA Fei1, WU ZhenDong1, ZHANG ShiTao1, LIU ZuHua1, ZHANG HuanQiao1, XU HuShan2, SUN ZhiYu2, WANG JianSong2, HU ZhengGuo2, WANG Meng2, CHEN RuoFu2, ZHANG XueYing2, LI Chen2, LEI XiangGuo2, XU ZhiGuo2, XIAO GuoQing2 & ZHAN WenLong2 1China Institute of Atomic Energy, P. O. Box 275(10), Beijing 102413, China 2 Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000, China 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第S1期73-80,共8页
Two-proton emissions from the excited states of 17,18Ne, 28P and 28,29S were investigated experimentally by the radioactive beams bombarding on the 197Au target via the Coulomb excitation. The complete-kinematics meas... Two-proton emissions from the excited states of 17,18Ne, 28P and 28,29S were investigated experimentally by the radioactive beams bombarding on the 197Au target via the Coulomb excitation. The complete-kinematics measurements were actualized by the stacks of silicon-strip detectors and CsI+PIN array detectors. The invariant mass of final systems as well as the relative momentum, opening angle, and relative energy of the two emitted protons was reconstructed under the framework of relativ istic kinematics. Visible proton-proton correlations were observed in these systems. The mechanisms of two-proton emission were analyzed in a simple schematic model, in which the extreme decay modes like He cluster emission, three-body 2 phase-space decay, and two-body sequential decay were taken into account. With the help of Monte-Carlo simulations, the two protons emitted from the 6.15 MeV excited state of Ne and the excited states in the energy region of 9.6–10.4 MeV of S, 18 29 respectively, exhibited prominent features of2 He cluster decay while for the other cases, no obvious diproton emissions were observed. 展开更多
关键词 two-proton emission RADIOACTIVE ion beam complete-kinematics measurement He cluster DECAY THREE-BODY 2 PHASE-SPACE DECAY two-body sequential DECAY
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Proton and Two-proton Emissions from Proton-rich Nuclei with 10 ≤ Z ≤ 20 被引量:3
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作者 林承键 徐新星 +17 位作者 王建松 孙立杰 贾会明 杨磊 马朋 马军兵 杨彦云 金仕纶 黄美容 白真 吴振东 杨峰 胡正国 王猛 雷相国 张焕乔 徐瑚珊 肖国青 《原子核物理评论》 CAS CSCD 北大核心 2016年第2期160-166,共7页
Proton(p) and two-proton(2p) emissions from the proton-rich nuclei with 10≤Z≤20 have been explored by the in-fight decay and implantation decay methods, respectively, in a series of experiments at the HIRFL-RIBLL fa... Proton(p) and two-proton(2p) emissions from the proton-rich nuclei with 10≤Z≤20 have been explored by the in-fight decay and implantation decay methods, respectively, in a series of experiments at the HIRFL-RIBLL facility. The in-flight 2p emissions from the excited states of ^(28,29)S/^(26,27)P and ^(17,18)Ne were studied by complete-kinematics measurements. Mechanisms of 2p decay and related p-p correlations have been explored. Obvious 2p correlated emissions have been observed in the cases of ^(28,29)S but not in ^(27,28)P, indicating the 2p halo plays an important role in the diproton emission. In the ^(17,18)Ne cases, a small 2p opening angles were deduced by the HBT analyses, implying the BCS-BEC crossover may occur in the dilute nuclear matter. Moreover,^(27)S/^(26)P/^(25)Si,^(22)Si/^(20)Mg,^(23)Si/^(22)Al/^(21)Mg,^(24)Si/^(23)Al, and ^(36,37)Ca were implanted in a thin double-sided-silicon-strip detector and their β-delayed p and 2p decays have been measured by a surrounding silicon detector array under the continuous-beam mode. Important information on the nuclear spectroscopy, such as energy, lifetime, branching-ratio, and so on, has been extracted, which helps us to understand the nuclear structures of proton-rich exotic nuclei close to the drip-line. 展开更多
关键词 proton emission two-proton emission proton-proton correlation complete-kinematics measurement implantation decay proton-rich exotic nucleus
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Two-proton radioactivity of ground and excited states within a unified fission model 被引量:1
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作者 Fengzhu Xing Jianpo Cui +1 位作者 Yanzhao Wang Jianzhong Gu 《Chinese Physics C》 SCIE CAS CSCD 2021年第12期129-139,共11页
A unified fission model is extended to study two-proton radioactivity of the ground states of nuclei,and a good agreement between the experimental and calculated half-lives is found.The two-proton radioactivity half-l... A unified fission model is extended to study two-proton radioactivity of the ground states of nuclei,and a good agreement between the experimental and calculated half-lives is found.The two-proton radioactivity half-lives of the ground states of some probable candidates are predicted within this model by inputting the released energies taken from the AME2020 table.It is shown that the predictive accuracy of the half-lives is comparable to those of other models.Then,two-proton radioactivity of the excited states of^(14)O,^(17,18)Ne,^(22)Mg,^(29)S,and^(94)Ag is discussed within the unified fission model and two analytical formulas.It is found that the experimental half-lives of the excited states are reproduced better within the unified fission model.Furthermore,the two formulas are not suitable for the study of two-proton radioactivity of excited states because their physical appearance deviates from the mechanism of quantum tunneling,and the parameters involved are obtained without including experimental data from the excited states. 展开更多
关键词 two-proton radioactivity released energy HALF-LIFE unified fission model analytical formula
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Time-dependent Calculations for Two-proton Decay Width with Schematic Density-dependent Contact Pairing Interaction
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作者 Oishi Tomohiro 《原子核物理评论》 CAS CSCD 北大核心 2016年第2期203-206,共4页
We calculate the two-proton decay width of the6 Be nucleus employing the schematic densitydependent contact potential for the proton-proton pairing interaction. The decay width is calculated with a time-dependent meth... We calculate the two-proton decay width of the6 Be nucleus employing the schematic densitydependent contact potential for the proton-proton pairing interaction. The decay width is calculated with a time-dependent method, in which the two-proton emission is described as a time-evolution of a threebody meta-stable state. Model-dependence of the two-proton decay width has been shown by comparing the results obtained with the two different pairing models, schematic density-dependent contact and Minnesota interactions, which have zero and finite ranges, respectively. 展开更多
关键词 two-proton radioactivity nuclear pairing interaction time-dependent method
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Systematic study of two-proton radioactivity half-lives using the two-potential and Skyrme-Hartree-Fock approaches
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作者 Xiao Pan You-Tian Zou +4 位作者 Hong-Ming Liu Biao He Xiao-Hua Li Xi-Jun Wu Zhen Zhang 《Chinese Physics C》 SCIE CAS CSCD 2021年第12期122-128,共7页
In this work,we systematically study the two-proton(2_(p))radioactivity half-lives using the two-potential approach,and the nuclear potential is obtained using the Skyrme-Hartree-Fock approach and the Skyrme effective... In this work,we systematically study the two-proton(2_(p))radioactivity half-lives using the two-potential approach,and the nuclear potential is obtained using the Skyrme-Hartree-Fock approach and the Skyrme effective interaction of SLy8.For true 2_(p) radioactivity(Q2_(p)>0 and Q_(p)<0,where Q_(p) and Q2_(p) are the released energies of the one-proton and two-proton radioactivity,respectively),the standard deviation between the experimental half-lives and our theoretical calculations is 0.701.In addition,we extend this model to predict the half-lives of 15 possible 2_(p) radioactivity candidates with Q2_(p)>0 obtained from the evaluated atomic mass table AME2016.The calcu-lated results indicate a clear linear relationship between the logarithmic 2_(p) radioactivity half-lives(logio10T_(1/2))and coulomb parameters[(Z_(d)^(0.8)+l^(0.25))Q_(2_(p))^(-1/2)]considering the effect of orbital angular momentum proposed by Liu et al.[Chin.Phys.C 45,024108(2021)].For comparison,the generalized liquid drop model(GLDM),effective liquid drop model(ELDM),and Gamow-like model are also used.Our predicted results are consistent with those obtained using other relevant models. 展开更多
关键词 two-proton radioactivity Skyrme-Hartree-Fock two-potential approach
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Systematic study of two-proton radioactivity within a Gamow-like model
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作者 Hong-Ming Liu Xiao Pan +4 位作者 You-Tian Zou Jiu-Long Chen Jun-Hao Cheng Biao He Xiao-Hua Li 《Chinese Physics C》 SCIE CAS CSCD 2021年第4期359-365,共7页
In this study,based on the Gamow-like model,we systematically analyze two-proton(2p) radioactivity half-lives of nuclei near or beyond the proton drip line.It is found that the calculated results can reproduce experim... In this study,based on the Gamow-like model,we systematically analyze two-proton(2p) radioactivity half-lives of nuclei near or beyond the proton drip line.It is found that the calculated results can reproduce experimental data well.Furthermore,using this model,we predict the half-lives of possible 2p radioactivity candidates whose 2p radioactivity is energetically allowed or observed but not yet quantified in the latest table of evaluated nuclear properties,i.e.,NUBASE2016.The predicted results are in good agreement with those from other theoretical models and empirical formulas,namely the effective liquid drop model(ELDM),generalized liquid drop model(GLDM),Sreej a formula,and Liu formula. 展开更多
关键词 two-proton radioactivity Gamow-like model HALF-LIFE
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New Geiger-Nuttall law for two-proton radioactivity
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作者 Hong-Ming Liu You-Tian Zou +3 位作者 Xiao Pan Jiu-Long Chen Biao He Xiao-Hua Li 《Chinese Physics C》 SCIE CAS CSCD 2021年第2期487-492,共6页
In the present work,a two-parameter empirical formula is proposed,based on the Geiger-Nuttall law,to study two-proton( 2p )radioactivity.Using this formula,the calculated 2p radioactivity half-lives are in good agreem... In the present work,a two-parameter empirical formula is proposed,based on the Geiger-Nuttall law,to study two-proton( 2p )radioactivity.Using this formula,the calculated 2p radioactivity half-lives are in good agreement with the experimental data as well as with calculated results obtained by Goncalves et al.[Phys.Lett.B 774,14(2017)]using the effective liquid drop model(ELDM),Sreeja et al.[Eur.Phys.J.A 55,33(2019)]using a four-parameter empirical formula,and Cui et al.[Phys.Rev.C 101:014301(2020)]using a generalized liquid drop model(GLDM).In addition,this two-parameter empirical formula is extended to predict the half-lives of 22 possible 2p radioactivity candidates with 2p radioactivity released energy Q_(2p)>0 ,obtained from the latest evaluated atomic mass table AME2016.The predicted results are highly consistent with those obtained using other theoretical models such as the ELDM,GLDM and four-parameter empirical formula. 展开更多
关键词 two-proton radioactivity Geiger-Nuttall law empirical formula
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Two-proton radioactivity within Coulomb and proximity potential model
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作者 De-Xing Zhu Hong-Ming Liu +4 位作者 Yang-Yang Xu You-Tian Zou Xi-Jun Wu Peng-Cheng Chu Xiao-Hua Li 《Chinese Physics C》 SCIE CAS CSCD 2022年第4期150-155,共6页
Considering the preformation probability of the two emitted protons in the parent nucleus,we extend the Coulomb and proximity potential model(CPPM)to systematically study two-proton(2p)radioactivity half-lives of the ... Considering the preformation probability of the two emitted protons in the parent nucleus,we extend the Coulomb and proximity potential model(CPPM)to systematically study two-proton(2p)radioactivity half-lives of the nuclei close to proton drip line.The proximity potential chosen is Prox.81 proposed by Blocki et al.in 1981.Furthermore,we apply this model to predict the half-lives of possible 2p radioactive candidates whose 2p radioactivity is energetically allowed or observed but not yet quantified in the evaluated nuclear properties table NUBASE2016.The predicted results are in good agreement with those from other theoretical models and empirical formulas,namely the effective liquid drop model(ELDM),generalized liquid drop model(GLDM),Gamow-like model,Sreeja formula and Liu formula. 展开更多
关键词 two-proton radioactivity Coulomb and proximity potential model HALF-LIFE
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Structure and 2p decay mechanism of^(18)Mg
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作者 Long Zhou De-Qing Fang +1 位作者 Si-Min Wang Hui Hua 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第6期145-154,共10页
The recently discovered,extremely proton-rich nuclide 18 Mg exhibits ground-state decay via two sequential two-proton(2p)emissions through the intermediate nucleus,16Ne.This study investigates the structure and the in... The recently discovered,extremely proton-rich nuclide 18 Mg exhibits ground-state decay via two sequential two-proton(2p)emissions through the intermediate nucleus,16Ne.This study investigates the structure and the initial 2p decay mechanism of^(18)Mgby examining the density and correlations of the valence protons using a three-body Gamow coupled-channel method.The results show that the ground state of^(18)Mgis significantly influenced by the continuum,resulting in a significant s-wave component.However,based on the current framework,this does not lead to a significant deviation in mirror symmetry in either the structure or spectroscopy of the 18Mg-18C pair.Additionally,the time evolution analysis of the^(18)Mgground state suggests a simultaneous 2p emission during the first step of decay.The observed nucleon-nucleon correlations align with those of the light-mass 2p emitters,indicating a consistent decay behavior within this nuclear region. 展开更多
关键词 Structure of^(18)Mg two-proton decay Proton-proton correlation
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二维材料复合质子膜的制备及其氕氚分离性能研究 被引量:1
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作者 周勋 柳伟平 +1 位作者 丁文艺 李桃生 《现代化工》 CAS CSCD 北大核心 2024年第1期177-182,共6页
采用溶液浇铸法分别制备了Graphene-Nafion和hBN-Nafion 2种二维纳米复合质子交换膜,利用XRD、ATR-FT-IR和SEM对复合膜的结构及微观形貌进行表征,并对复合膜的离子交换容量、质子电导率、机械性能和热稳定性进行测试,结果表明,Graphene和hB... 采用溶液浇铸法分别制备了Graphene-Nafion和hBN-Nafion 2种二维纳米复合质子交换膜,利用XRD、ATR-FT-IR和SEM对复合膜的结构及微观形貌进行表征,并对复合膜的离子交换容量、质子电导率、机械性能和热稳定性进行测试,结果表明,Graphene和hBN纳米片均匀地分散于Nafion基体内部。相较于重铸Nafion膜(空白对照样品),复合膜的离子交换容量、质子电导率以及机械性能均有不同程度的提升,特别是在掺入质量分数为0.50%时,Graphene-Nafion和hBN-Nafion复合膜的质子传导性能约为重铸Nafion膜的1.25倍和1.14倍。通过对比Graphene-Nafion和hBN-Nafion 2种复合膜的氕氚分离性能发现,在初始氚水比活度为3.51×10^(7)Bq/L时,持续电解超过60 h,2种复合膜的氕氚分离系数分别为5.73和8.46,氚回收率分别为78.53%和85.35%,表明hBN-Nafion复合膜具有更好的氕氚分离性能。 展开更多
关键词 二维材料 复合质子交换膜 氕氚分离系数
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水自由基阳离子与苯及其衍生物反应的质谱研究
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作者 杨黄丽 高校飞 +3 位作者 谭国斌 张兴磊 周振 陈焕文 《质谱学报》 EI CAS CSCD 北大核心 2024年第4期482-491,I0002,共11页
研究水自由基阳离子的化学性质对阐释水相化学反应机理有着重要意义。本文研究了在线制备的(H_(2)O)_(2)^(+·)(m/z 36)与苯及其衍生物反应的特点。结果表明,当(H_(2)O)_(2)^(+·)与苯(C_(6)H_(6))、苯甲醚(C_(7)H_(8)O)、2,4-... 研究水自由基阳离子的化学性质对阐释水相化学反应机理有着重要意义。本文研究了在线制备的(H_(2)O)_(2)^(+·)(m/z 36)与苯及其衍生物反应的特点。结果表明,当(H_(2)O)_(2)^(+·)与苯(C_(6)H_(6))、苯甲醚(C_(7)H_(8)O)、2,4-二甲基苯胺(C_(8)H_(11)N)等没有吸电子基团的化合物反应时,除产生对应的电子转移反应产物(C_(6)H_(6))^(+·)(m/z 78)、(C_(7)H_(8)O)^(+·)(m/z108)或质子转移反应产物(C_(8)H_(11)N+H)+(m/z 122)外,还发现苯酚相关产物(C_(6)H_(5)OH)^(+·)(m/z 94)、(C_(7)H_(7)O-OH)^(+·)(m/z 124)以及(C_(8)H_(10)NOH+H)+(m/z 138)。同位素标记实验表明,苯酚相关产物中的OH来源于水自由基阳离子。然而,当(H_(2)O)_(2)^(+·)与苯甲腈(C_(6)H_(5)CN)或硝基苯(C_(6)H_(5)NO_(2))等有强吸电子基团的取代苯反应时,主要通过取代反应产生(C_(6)H_(5)CN+H_(2)O)^(+·)(m/z 121)和(C_(6)H_(5)NO_(2)+H_(2)O)^(+·)(m/z 141),并未发现羟基化产物。由以上结果可知,(H_(2)O)_(2)^(+·)与底物分子的反应可通过电子转移(底物自由基阳离子)、质子转移(质子化产物)、解离电子转移(羟基化产物)和取代等4个过程发生,这可能与(H_(2)O)_(2)^(+·)存在(H_(2)O)H^(+)-^(·)OH和[H_(2)O∴OH_(2)]^(+·)_(2)种互变结构有关。本研究推测,苯环上的吸电子基团有利于[H_(2)O∴OH_(2)]^(+·)结构的存在,从而发生取代反应,当苯环上没有吸电子基团时,苯环上的富电子体系有利于(H_(2)O)H^(+)-^(·)OH结构的存在,而质子转移结构中的羟基自由基可以将苯氧化成苯酚,该结果有助于阐明苯及其衍生物与(H_(2)O)_(2)^(+·)相关的化学反应过程。 展开更多
关键词 水自由基阳离子 苯及其衍生物 质子转移结构 两中心三电子结构 质谱
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质子交换膜燃料电池均温板散热特性的数值分析
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作者 葛志晶 郑东明 +1 位作者 裴东号 曹军 《太阳能学报》 EI CAS CSCD 北大核心 2024年第6期109-116,共8页
以面向质子交换膜燃料电池电堆散热的超薄均温板为研究对象,用多孔介质传热模型、层流模型和Brinkman方程构建三维稳态数值模型,通过质量守恒确定气液界面的相变传质,研究在吸液芯饱和充液的常规工况下均温板的稳态特性。结果表明:超薄... 以面向质子交换膜燃料电池电堆散热的超薄均温板为研究对象,用多孔介质传热模型、层流模型和Brinkman方程构建三维稳态数值模型,通过质量守恒确定气液界面的相变传质,研究在吸液芯饱和充液的常规工况下均温板的稳态特性。结果表明:超薄结构以及支撑柱的存在使内部压降较大;随着冷凝段对流换热系数的增大,均温性变差,内部压降也显著增大;随着热流密度的增大,温差先增大后减小,热阻持续下降;孔隙率的变化对平衡终态影响较小;渗透率的增大将极大的降低吸液芯内的液体压降,有利于相变循环。 展开更多
关键词 质子交换膜燃料电池 两相流 传热 超薄均温板 数值分析
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面向控制的一维非等温两相流燃料电池模型研究
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作者 刘佳奇 卢炽华 +1 位作者 刘志恩 周辉 《重庆大学学报》 CAS CSCD 北大核心 2024年第3期107-119,共13页
经验模型不能反映电池内部复杂的物理化学耦合过程及其导致的响应迟滞,这给燃料电池系统精确控制策略的开发带来了一定困难。针对此问题,建立了面向控制的一维非等温两相流模型,考虑了流道内气体瞬态效应、电池内部水相变,研究了电流密... 经验模型不能反映电池内部复杂的物理化学耦合过程及其导致的响应迟滞,这给燃料电池系统精确控制策略的开发带来了一定困难。针对此问题,建立了面向控制的一维非等温两相流模型,考虑了流道内气体瞬态效应、电池内部水相变,研究了电流密度对气体浓度以及水热分布特性的影响,分析了运行条件和模型参数对电池输出电压的影响,探究了电流阶跃下该模型相比于集总参数模型在输出性能方面的优势。结果表明,该模型具有更好的适用性,可为燃料电池系统层面的模型优化及控制策略设计提供可靠依据。 展开更多
关键词 质子交换膜燃料电池 非等温 两相流 一维模型 SIMULINK
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质子膜燃料电池耦合反应模型研究
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作者 李敏 李婷 +1 位作者 张媛 胡小勇 《东方电气评论》 2024年第2期1-7,共7页
本文提出了一种基于多孔介质两相流传质过程的质子交换膜燃料电池三维理论模型,通过流体力学、两相流传质、膜传输以及电化学反应等过程的多重耦合,研究多物理过程对于燃料电池性能影响的协同机制。研究结果表明,氢气空气同向流条件下,... 本文提出了一种基于多孔介质两相流传质过程的质子交换膜燃料电池三维理论模型,通过流体力学、两相流传质、膜传输以及电化学反应等过程的多重耦合,研究多物理过程对于燃料电池性能影响的协同机制。研究结果表明,氢气空气同向流条件下,燃料电池内部液态水主要产生于中部及出口端,且流道脊区域的多孔介质液态水含量远高于流道区域;由于质子膜内阻、阴极氧气浓度以及多孔电极液态水含量的综合作用,电流密度峰值位于反应区中部区域,达到进口处电流密度的两倍以上。 展开更多
关键词 质子交换膜燃料电池 两相流模型 局部性能分布
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PEM电解槽制氢多相传输及转化模型综述
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作者 张春雁 窦真兰 +2 位作者 徐桂芝 李根蒂 俎焱敏 《电池》 CAS 北大核心 2024年第4期569-573,共5页
质子交换膜(PEM)电解槽通过水解反应将电能转化为氢能。实际电解槽的水解过程是包含了热量、质量传递和电化学转化的复杂过程,构建理论模型可揭示各过程对性能的影响规律,指导电解槽的设计和优化。综述PEM电解槽电化学、物质传输和气液... 质子交换膜(PEM)电解槽通过水解反应将电能转化为氢能。实际电解槽的水解过程是包含了热量、质量传递和电化学转化的复杂过程,构建理论模型可揭示各过程对性能的影响规律,指导电解槽的设计和优化。综述PEM电解槽电化学、物质传输和气液两相等理论模型,讨论模型发展现状和当前存在气液流动和离子传递影响规律不清晰的问题,探讨后续模型构建中应着力解决计算复杂、精度不足等难点。 展开更多
关键词 质子交换膜(PEM)电解槽 模型 电化学 传质 两相流
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