The development of the three-component catalytic system for constructing isoindolinones from simple feedstocks is both significant and challenging.In this study,a unique tartrate-linked dimeric samarium-antimonotungst...The development of the three-component catalytic system for constructing isoindolinones from simple feedstocks is both significant and challenging.In this study,a unique tartrate-linked dimeric samarium-antimonotungstate[Sm_(2)(H_(2)O)_(6)(tar)(Sb_(2)W_(21)O_(72))]_(2)^(20-)(Sm_(4)tar_(2),H_(4)tar=tartaric acid)was synthesized via a one-step method at room temperature using an acetate buffer solution.The dimeric polyanion of Sm4tar2shows a centrosymmetric structure with a parallelogram-like arrangement and comprises two enantiomeric{Sm_(2)(H_(2)O)_(6)(Sb_(2)W_(21)O_(72))}moieties connected by two enantiomeric tar ligands.Sm_(4)tar_(2)demonstrates efficient catalytic activity in the three-component reaction involving 2-acylbenzoic acids,primary amines,and phosphine oxides to form 3,3-disubstituted isoindolinones.The advantages of this catalytic system include simple feedstocks,green and reusable catalyst,and operational simplicity with water as the sole by-product.This finding enables an effective molecular fragment assembly strategy for synthesizing isoindolinone drug precursor skeletons.展开更多
Introducing PT-symmetric generalized Scarf-Ⅱpotentials into the three-coupled nonlinear Gross-Pitaevskii equations offers a new way to seek stable soliton states in quasi-onedimensional spin-1 Bose-Einstein condensat...Introducing PT-symmetric generalized Scarf-Ⅱpotentials into the three-coupled nonlinear Gross-Pitaevskii equations offers a new way to seek stable soliton states in quasi-onedimensional spin-1 Bose-Einstein condensates.In scenarios where the spin-independent parameter c_(0)and the spin-dependent parameter c_(2)vary,we use both analytical and numerical methods to investigate the three-coupled nonlinear Gross-Pitaevskii equations with PT-symmetric generalized Scarf-Ⅱpotentials.We obtain analytical soliton states and find that simply modulating c_(2)may change the analytical soliton states from unstable to stable.Additionally,we obtain numerically stable double-hump soliton states propagating in the form of periodic oscillations,exhibiting distinct behavior in energy exchange.For further investigation,we discuss the interaction of numerical double-hump solitons with Gaussian solitons and observe the transfer of energy among the three components.These findings may contribute to a deeper understanding of solitons in Bose-Einstein condensates with PT-symmetric potentials and may hold significance for both theoretical understanding and experimental design in related physics experiments.展开更多
A H_(4)SiW_(12)O_(40)-catalyzed three-component tandem reaction of 2-acylbenzoic acids,primary amines and phosphine oxides to form 3,3-disubstituted isoindolinones was developed.By employing A H_(4)SiW_(12)O_(40)as th...A H_(4)SiW_(12)O_(40)-catalyzed three-component tandem reaction of 2-acylbenzoic acids,primary amines and phosphine oxides to form 3,3-disubstituted isoindolinones was developed.By employing A H_(4)SiW_(12)O_(40)as the catalyst and dimethyl carbonate(DMC)as the solvent,a diverse range of 2-acylbenzoic acid derivatives and primary amines worked well to give the C3-phosphinoyl-functionalized 3,3-disubstituted isoindolinones with the yield range of 61%-87%.Advantages of this transformation include green catalyst and solvent,available starting materials,broad substrate scope,high efficiency and operational simplicity with water as the sole by-product.The strategy achieved an efficient and green molecular fragment assembly to access isoindolinones,which would provide opportunities for the synthesis of potential biologically active molecules in a green manner.展开更多
L-glutamic acid(LA)is a bio-based,non-toxic,environmentally friendly material derived from biomass.The present study reports the application of Passerini three-component polymerization(P-3CP)for the straightforward pr...L-glutamic acid(LA)is a bio-based,non-toxic,environmentally friendly material derived from biomass.The present study reports the application of Passerini three-component polymerization(P-3CP)for the straightforward preparation of LA-based light-responsive polyesters(PLTDs)under mild conditions.PLTDs with molar masses up to 8500 g/mol and high yields exceeding 90%are obtained.The chemical structures and light-responsive self-immolative behavior of PLTDs are comprehensively characterized by employing ultraviolet-visible(UV-Vis)spectroscopy,size exclusion chromatography(SEC),nuclear magnetic resonance(NMR)spectroscopy,and liquid chromatography mass spectrometry(LC-MS).Meanwhile,monodisperse PLTD-based doxorubicin-loaded nanoparticles(PLTD-DOX-NP)(size=193 nm,PDI=0.018)are formulated by nanoprecipitation method.Upon light-induced depolymerization,the PLTD-DOX-NP undergoes rapid decomposition,resulting in a burst release of 80%cargo within 13 s.Furthermore,according to biological toxicity tests,the PLTD-NP possesses adequate biosafety,both before and after irradiation.Overall,the incorporation of P-3CP with biorenewable LA-based monomer adheres to the principles of green chemistry,significantly simplifying the synthetic pathway of light-responsive polymers.展开更多
A copper-catalyzed three-component reaction involving cyclic carbonates,elemental sulfur,and H-phosphonates is presented.It proceeds with excellent yields and provides an attractive approach for the construction of va...A copper-catalyzed three-component reaction involving cyclic carbonates,elemental sulfur,and H-phosphonates is presented.It proceeds with excellent yields and provides an attractive approach for the construction of valuable trisubstituted allenyl phosphorothioates using a one-step strategy.Moreover,this method can be easily adapted to large-scale preparation.展开更多
A facile and environmentally friendly visible-light-induced three-component reaction of α-diazoesters,cyclic ethers and Na SCN to construct organic thiocyanates has been developed at room temperature. This reaction c...A facile and environmentally friendly visible-light-induced three-component reaction of α-diazoesters,cyclic ethers and Na SCN to construct organic thiocyanates has been developed at room temperature. This reaction could occur under photocatalyst-and additive-free conditions to afford a number of organic thiocyanates with moderate to good yield and favorable functional group tolerance.展开更多
We present a bidirectional reflection distribution function （BRDF） model for thermal coating surfaces based on a three-component reflection assumption, in which the specular reflection is given according to the micr...We present a bidirectional reflection distribution function （BRDF） model for thermal coating surfaces based on a three-component reflection assumption, in which the specular reflection is given according to the microfacet theory and Snell＇s law, the multiple reflection is considered Nth cosine distributed, and the volume scattering is uniformly distributed in reflection angles according to the experimental results. This model describes the reflection characteristics of thermal coating surfaces more completely and reasonably. Simulation and measurement results of two thermal coating samples SR107 and S781 are given to validate that this three-component model significantly improves the modeling accuracy for thermal coating surfaces compared with the existing BRDF models.展开更多
Transient electromagnetic method (TEM),as a non-seismic geophysical exploration mainstream electromagnetic method,is widely used in oil,gas,mineral and other underground resources exploration areas. The coil sensor is...Transient electromagnetic method (TEM),as a non-seismic geophysical exploration mainstream electromagnetic method,is widely used in oil,gas,mineral and other underground resources exploration areas. The coil sensor is generally used to collect data. In view of the problems of incomplete information of the abnormal body and the data loss in the existing TEM single-component coil sensor,a three-component TEM coil sensor is designed. By analyzing the relationship between sensor sensitivity and coil structure parameters,the coil structure and turns are designed. By analyzing the frequency response characteristics of the TEM magnetic field sensor,the signal distortion is reduced by using the under-damped matching mode. By analyzing the distribution of various noise sources of the magnetic sensor,the appropriate amplifier is selected to reduce the background noise. Finally,a three-component TEM induction magnetic field sensor is designed. The weight of the sensor is controlled at 3.2 kg and the working frequency is 10 mHz-10 kHz. The background noises of X and Y components probably keep in 1.5×10^-8 V/ Hz and sensitivities are 8.4 and 9.8 nT/s,respectively,the background noise of vertical component is 2.1× 10^-7 V/ Hz and sensitivity is 18.5 nT/s. Compared with the existing single-component TEM receiving magnetic field sensor,the designed sensor realizes the signal acquisition of three components. Without too much increase in volume and total weight,it improves the sensitivity of the sensor and reduces the background noise,thus the signal-to-noise ratio (SNR) of the signal is improved.展开更多
A series of new hexahydroimidazo[1,2-a]pyridine derivatives were synthesized via convenient and practical three-component reactions. Preliminary bioassays showed that majority of the target compounds exhibited moderat...A series of new hexahydroimidazo[1,2-a]pyridine derivatives were synthesized via convenient and practical three-component reactions. Preliminary bioassays showed that majority of the target compounds exhibited moderate to excellent insecticidal activity against cowpea aphids （Aphis craccivora）. Among them, compound 91 demonstrated significant activity with LCso value of 0.00918 mmol/L which was about 3.8-fold higher than that of imidacloprid （IMI）. Furthermore, the study of stereostructure-activity relationship of four isomers of 9k indicated that configuration played a key role in insecticidal activity of these compounds.展开更多
A facile and metal-free visible-light-enabled three-component reaction of quinoxalin-2(1 H)-ones,alkenes and CF_(3)SO_(2)Na has been developed under air at room temperature.This photocatalytic tandem reaction using 4 ...A facile and metal-free visible-light-enabled three-component reaction of quinoxalin-2(1 H)-ones,alkenes and CF_(3)SO_(2)Na has been developed under air at room temperature.This photocatalytic tandem reaction using 4 CzIPN as the photocatalyst and air as the green oxidant,provides a mild and environmentally friendly approach to access a series of 3-trifluoroalkylated quinoxalin-2(1 H)-ones.展开更多
The functionalized spiro[indoline-3,40-pyrano[3,2-h]quinolines] were efficiently prepared in high yields from three-component reaction of 8-hydroxyquinoline, isatins and malononitrile or ethyl cyanoacetate in ethanol ...The functionalized spiro[indoline-3,40-pyrano[3,2-h]quinolines] were efficiently prepared in high yields from three-component reaction of 8-hydroxyquinoline, isatins and malononitrile or ethyl cyanoacetate in ethanol at room temperature for about 12 h in the presence of piperidine.展开更多
Some theorems of compactly supported non-tensor product form two-dimension Daubechies wavelet were analysed carefully. Compactly supported non-tensor product form two-dimension wavelet was constructed, then non-tensor...Some theorems of compactly supported non-tensor product form two-dimension Daubechies wavelet were analysed carefully. Compactly supported non-tensor product form two-dimension wavelet was constructed, then non-tensor product form two dimension wavelet finite element was used to solve the deflection problem of elastic thin plate. The error order was researched. A numerical example was given at last.展开更多
The dispersion relation and electromagnetic polarization of the plasma waves are comprehensively studied in cold electron, proton, and heavy charged particle plasmas. Three modes are classified as the fast, intermedia...The dispersion relation and electromagnetic polarization of the plasma waves are comprehensively studied in cold electron, proton, and heavy charged particle plasmas. Three modes are classified as the fast, intermediate, and slow mode waves according to different phase velocities. When plasmas contain positively-charged particles, the fast and intermediate modes can interact at the small propagating angles, whereas the two modes are separate at the large propagating angles. The near-parallel intermediate and slow waves experience the linear polarization, circular polarization, and linear polarization again, with the increasing wave number. The wave number regime corresponding to the above circular polarization shrinks as the propagating angle increases. Moreover, the fast and intermediate modes cause the reverse change of the electromagnetic polarization at the special wave number. While the heavy particles carry the negative charges, the dispersion relations of the fast and intermediate modes are always separate, being independent of the propagating angles. Furthermore, this study gives new expressions of the three resonance frequencies corresponding to the highly-oblique propagation waves in the general three-component plasmas, and shows the dependence of the resonance frequencies on the propagating angle, the concentration of the heavy particle, and the mass ratio among different kinds of particles.展开更多
A simple and metal-free method has been developed for the construction of quinoline-2,4-carboxylates under mild conditions via a molecular iodine-catalyzed three-component tandem reaction of arylamines, ethyl glyoxyla...A simple and metal-free method has been developed for the construction of quinoline-2,4-carboxylates under mild conditions via a molecular iodine-catalyzed three-component tandem reaction of arylamines, ethyl glyoxylate, and a-ketoesters. The present protocol provides a convenient and attractive approach to various quinoline-2,4-carboxylates in moderate to good yields with excellent functional group tolerance.展开更多
The adaptive mesh refinement （AMR） method is applied in the 2-D Euler multi-component elasticplastic hydrodynamics code （MEPH2Y）. It is applied on detonation. Firstly, the AMR method is described, including a cons...The adaptive mesh refinement （AMR） method is applied in the 2-D Euler multi-component elasticplastic hydrodynamics code （MEPH2Y）. It is applied on detonation. Firstly, the AMR method is described, including a conservative spatial interpolation, the time integration methodology with the adapitve time increment and an adaptive computational region method. The advantage of AMR technique is exhibited by numerical examples, including the 1-D C-J detonation and the 2-D implosion ignited from a single point. Results show that AMR can promote the computational efficiency, keeping the accuracy in interesting regions.展开更多
Potassium tert-butoxide has been found to be a highly efficient catalyst for one-pot,three-component reaction of aryl aldehydes, acetophenones,and thiols via Claisen-Schmidt/Michael addition reactions for the synthesi...Potassium tert-butoxide has been found to be a highly efficient catalyst for one-pot,three-component reaction of aryl aldehydes, acetophenones,and thiols via Claisen-Schmidt/Michael addition reactions for the synthesis of thia-Michael adducts in high yields. The reactions are best carried out in tert-butyl alcohol at room temperature.展开更多
We exhibit some new dark soliton phenomena on the general nonzero background for a defocusing three-component nonlinear Schrodinger equation. As the plane wave background undergoes unitary transformation SU(3), we obt...We exhibit some new dark soliton phenomena on the general nonzero background for a defocusing three-component nonlinear Schrodinger equation. As the plane wave background undergoes unitary transformation SU(3), we obtain the general nonzero background and study its modulational instability by the linear stability analysis. On the basis of this background, we study the dynamics of one-dark soliton and two-dark-soliton phenomena, which are different from the dark solitons studied before. Furthermore, we use the numerical method for checking the stability of the one-dark-soliton solution. These results further enrich the content in nonlinear Schrodinger systems, and require more in-depth studies in the future.展开更多
In this paper, the solution of Chebyshev equation with its argument being greater than 1 is obtained. The initial value of the derivative of the solution is the expression of magnetization, which is valid for any spin...In this paper, the solution of Chebyshev equation with its argument being greater than 1 is obtained. The initial value of the derivative of the solution is the expression of magnetization, which is valid for any spin quantum number S. The Chebyshev equation is transformed from an ordinary differential equation obtained when we dealt with Heisenberg model, in order to calculate all three components of magnetization, by many-body Green＇s function under random phase approximation. The Chebyshev functions with argument being greater than 1 are discussed. This paper shows that the Chebyshev polynomials with their argument being greater than 1 have their physical application.展开更多
The three-component coupling reaction of ethyl propiolate (1), phthalimide (2), and aldehyde (3) catalyzed by tripheny- lphosphine, was developed. A solution of an equivalent amount of 1 and 2 in benzaldehyde (3a) in ...The three-component coupling reaction of ethyl propiolate (1), phthalimide (2), and aldehyde (3) catalyzed by tripheny- lphosphine, was developed. A solution of an equivalent amount of 1 and 2 in benzaldehyde (3a) in the presence of 30 mol% of PPh3 was heated at 100?C for 48 h to give N-(1-ethoxycarbonyl-3-oxo-3-phenylpropyl)phthalimide (4a) in 83% yield. This reaction was thought to proceed via vinylphosphonium salt formed from the reaction of ethyl propiolate (1) with triphenylphosphine in situ.展开更多
基金financially supported by the National Natural Science Foundation of China(No.22301033)Jiangxi Provincial Natural Science Foundation(No.20232ACB213005 and 20212BAB213001)。
文摘The development of the three-component catalytic system for constructing isoindolinones from simple feedstocks is both significant and challenging.In this study,a unique tartrate-linked dimeric samarium-antimonotungstate[Sm_(2)(H_(2)O)_(6)(tar)(Sb_(2)W_(21)O_(72))]_(2)^(20-)(Sm_(4)tar_(2),H_(4)tar=tartaric acid)was synthesized via a one-step method at room temperature using an acetate buffer solution.The dimeric polyanion of Sm4tar2shows a centrosymmetric structure with a parallelogram-like arrangement and comprises two enantiomeric{Sm_(2)(H_(2)O)_(6)(Sb_(2)W_(21)O_(72))}moieties connected by two enantiomeric tar ligands.Sm_(4)tar_(2)demonstrates efficient catalytic activity in the three-component reaction involving 2-acylbenzoic acids,primary amines,and phosphine oxides to form 3,3-disubstituted isoindolinones.The advantages of this catalytic system include simple feedstocks,green and reusable catalyst,and operational simplicity with water as the sole by-product.This finding enables an effective molecular fragment assembly strategy for synthesizing isoindolinone drug precursor skeletons.
基金supported by NSFC under Grant No.12272403Beijing Training Program of Innovation under Grant No.S202410019024。
文摘Introducing PT-symmetric generalized Scarf-Ⅱpotentials into the three-coupled nonlinear Gross-Pitaevskii equations offers a new way to seek stable soliton states in quasi-onedimensional spin-1 Bose-Einstein condensates.In scenarios where the spin-independent parameter c_(0)and the spin-dependent parameter c_(2)vary,we use both analytical and numerical methods to investigate the three-coupled nonlinear Gross-Pitaevskii equations with PT-symmetric generalized Scarf-Ⅱpotentials.We obtain analytical soliton states and find that simply modulating c_(2)may change the analytical soliton states from unstable to stable.Additionally,we obtain numerically stable double-hump soliton states propagating in the form of periodic oscillations,exhibiting distinct behavior in energy exchange.For further investigation,we discuss the interaction of numerical double-hump solitons with Gaussian solitons and observe the transfer of energy among the three components.These findings may contribute to a deeper understanding of solitons in Bose-Einstein condensates with PT-symmetric potentials and may hold significance for both theoretical understanding and experimental design in related physics experiments.
基金the National Natural Science Foundation of China(No.22001034)Jiangxi Provincial Natural Science Foundation(No.20212BAB213001).
文摘A H_(4)SiW_(12)O_(40)-catalyzed three-component tandem reaction of 2-acylbenzoic acids,primary amines and phosphine oxides to form 3,3-disubstituted isoindolinones was developed.By employing A H_(4)SiW_(12)O_(40)as the catalyst and dimethyl carbonate(DMC)as the solvent,a diverse range of 2-acylbenzoic acid derivatives and primary amines worked well to give the C3-phosphinoyl-functionalized 3,3-disubstituted isoindolinones with the yield range of 61%-87%.Advantages of this transformation include green catalyst and solvent,available starting materials,broad substrate scope,high efficiency and operational simplicity with water as the sole by-product.The strategy achieved an efficient and green molecular fragment assembly to access isoindolinones,which would provide opportunities for the synthesis of potential biologically active molecules in a green manner.
基金This work was financially supported by the International Science and Technology Assistance Program of the Ministry of Science and Technology(No.KY202001016)Shandong Provincial Natural Science Foundation Magnitude Fundamental Research,China(No.ZR2022ZD11)Qingdao New Energy Shandong Laboratory Open Project(No.QNESL OP202312).
文摘L-glutamic acid(LA)is a bio-based,non-toxic,environmentally friendly material derived from biomass.The present study reports the application of Passerini three-component polymerization(P-3CP)for the straightforward preparation of LA-based light-responsive polyesters(PLTDs)under mild conditions.PLTDs with molar masses up to 8500 g/mol and high yields exceeding 90%are obtained.The chemical structures and light-responsive self-immolative behavior of PLTDs are comprehensively characterized by employing ultraviolet-visible(UV-Vis)spectroscopy,size exclusion chromatography(SEC),nuclear magnetic resonance(NMR)spectroscopy,and liquid chromatography mass spectrometry(LC-MS).Meanwhile,monodisperse PLTD-based doxorubicin-loaded nanoparticles(PLTD-DOX-NP)(size=193 nm,PDI=0.018)are formulated by nanoprecipitation method.Upon light-induced depolymerization,the PLTD-DOX-NP undergoes rapid decomposition,resulting in a burst release of 80%cargo within 13 s.Furthermore,according to biological toxicity tests,the PLTD-NP possesses adequate biosafety,both before and after irradiation.Overall,the incorporation of P-3CP with biorenewable LA-based monomer adheres to the principles of green chemistry,significantly simplifying the synthetic pathway of light-responsive polymers.
基金supported by the Educational Foundation of Zhejiang University of Technology(No.KYY-HX-20220471)。
文摘A copper-catalyzed three-component reaction involving cyclic carbonates,elemental sulfur,and H-phosphonates is presented.It proceeds with excellent yields and provides an attractive approach for the construction of valuable trisubstituted allenyl phosphorothioates using a one-step strategy.Moreover,this method can be easily adapted to large-scale preparation.
基金supported by the program of Science and Technology International Cooperation Project of Qinghai Province (No. 2022-HZ-813)the Youth Innovation and Technology Project of High School in Shandong Province (No. 2019KJC021)+1 种基金the Natural Science Foundation of Shandong Province (No. ZR2021MB065)the National Natural Science Foundation of China (No. 31900298)。
文摘A facile and environmentally friendly visible-light-induced three-component reaction of α-diazoesters,cyclic ethers and Na SCN to construct organic thiocyanates has been developed at room temperature. This reaction could occur under photocatalyst-and additive-free conditions to afford a number of organic thiocyanates with moderate to good yield and favorable functional group tolerance.
文摘We present a bidirectional reflection distribution function （BRDF） model for thermal coating surfaces based on a three-component reflection assumption, in which the specular reflection is given according to the microfacet theory and Snell＇s law, the multiple reflection is considered Nth cosine distributed, and the volume scattering is uniformly distributed in reflection angles according to the experimental results. This model describes the reflection characteristics of thermal coating surfaces more completely and reasonably. Simulation and measurement results of two thermal coating samples SR107 and S781 are given to validate that this three-component model significantly improves the modeling accuracy for thermal coating surfaces compared with the existing BRDF models.
文摘Transient electromagnetic method (TEM),as a non-seismic geophysical exploration mainstream electromagnetic method,is widely used in oil,gas,mineral and other underground resources exploration areas. The coil sensor is generally used to collect data. In view of the problems of incomplete information of the abnormal body and the data loss in the existing TEM single-component coil sensor,a three-component TEM coil sensor is designed. By analyzing the relationship between sensor sensitivity and coil structure parameters,the coil structure and turns are designed. By analyzing the frequency response characteristics of the TEM magnetic field sensor,the signal distortion is reduced by using the under-damped matching mode. By analyzing the distribution of various noise sources of the magnetic sensor,the appropriate amplifier is selected to reduce the background noise. Finally,a three-component TEM induction magnetic field sensor is designed. The weight of the sensor is controlled at 3.2 kg and the working frequency is 10 mHz-10 kHz. The background noises of X and Y components probably keep in 1.5×10^-8 V/ Hz and sensitivities are 8.4 and 9.8 nT/s,respectively,the background noise of vertical component is 2.1× 10^-7 V/ Hz and sensitivity is 18.5 nT/s. Compared with the existing single-component TEM receiving magnetic field sensor,the designed sensor realizes the signal acquisition of three components. Without too much increase in volume and total weight,it improves the sensitivity of the sensor and reduces the background noise,thus the signal-to-noise ratio (SNR) of the signal is improved.
基金supported by National Key Technology R&D Program of China(No.2011BAE06B01)
文摘A series of new hexahydroimidazo[1,2-a]pyridine derivatives were synthesized via convenient and practical three-component reactions. Preliminary bioassays showed that majority of the target compounds exhibited moderate to excellent insecticidal activity against cowpea aphids （Aphis craccivora）. Among them, compound 91 demonstrated significant activity with LCso value of 0.00918 mmol/L which was about 3.8-fold higher than that of imidacloprid （IMI）. Furthermore, the study of stereostructure-activity relationship of four isomers of 9k indicated that configuration played a key role in insecticidal activity of these compounds.
基金supported by Youth Innovation and Technology Project of Shandong Province(No.2019KJC021)the International Cooperation Project of Qinghai Province(No.2018-HZ-815)+2 种基金the Natural Science Foundation of Shandong Province(No.ZR2018MB009)the Qinghai key laboratory of Tibetan medicine research(No.2017-ZJ-Y11)CAS“Light of West China”Program 2018。
文摘A facile and metal-free visible-light-enabled three-component reaction of quinoxalin-2(1 H)-ones,alkenes and CF_(3)SO_(2)Na has been developed under air at room temperature.This photocatalytic tandem reaction using 4 CzIPN as the photocatalyst and air as the green oxidant,provides a mild and environmentally friendly approach to access a series of 3-trifluoroalkylated quinoxalin-2(1 H)-ones.
基金supported by the National Natural Science Foundation of China (Nos. 21172189, 21572196)the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘The functionalized spiro[indoline-3,40-pyrano[3,2-h]quinolines] were efficiently prepared in high yields from three-component reaction of 8-hydroxyquinoline, isatins and malononitrile or ethyl cyanoacetate in ethanol at room temperature for about 12 h in the presence of piperidine.
文摘Some theorems of compactly supported non-tensor product form two-dimension Daubechies wavelet were analysed carefully. Compactly supported non-tensor product form two-dimension wavelet was constructed, then non-tensor product form two dimension wavelet finite element was used to solve the deflection problem of elastic thin plate. The error order was researched. A numerical example was given at last.
基金supported by National Natural Science Foundation of China(Nos.11303099,41531071 and 41574158)the Youth Innovation Promotion Association CAS
文摘The dispersion relation and electromagnetic polarization of the plasma waves are comprehensively studied in cold electron, proton, and heavy charged particle plasmas. Three modes are classified as the fast, intermediate, and slow mode waves according to different phase velocities. When plasmas contain positively-charged particles, the fast and intermediate modes can interact at the small propagating angles, whereas the two modes are separate at the large propagating angles. The near-parallel intermediate and slow waves experience the linear polarization, circular polarization, and linear polarization again, with the increasing wave number. The wave number regime corresponding to the above circular polarization shrinks as the propagating angle increases. Moreover, the fast and intermediate modes cause the reverse change of the electromagnetic polarization at the special wave number. While the heavy particles carry the negative charges, the dispersion relations of the fast and intermediate modes are always separate, being independent of the propagating angles. Furthermore, this study gives new expressions of the three resonance frequencies corresponding to the highly-oblique propagation waves in the general three-component plasmas, and shows the dependence of the resonance frequencies on the propagating angle, the concentration of the heavy particle, and the mass ratio among different kinds of particles.
基金supported by the Opening Project of Key Laboratory at Universities of Education Department of Xinjiang Uygur Autonomous Region (No. 2014YSHXZD01)
文摘A simple and metal-free method has been developed for the construction of quinoline-2,4-carboxylates under mild conditions via a molecular iodine-catalyzed three-component tandem reaction of arylamines, ethyl glyoxylate, and a-ketoesters. The present protocol provides a convenient and attractive approach to various quinoline-2,4-carboxylates in moderate to good yields with excellent functional group tolerance.
基金Sponsored by the National Natural Science Foundation of China(10676120)Laboratory of Computational Physics Foundation(9140C690101070C69)
文摘The adaptive mesh refinement （AMR） method is applied in the 2-D Euler multi-component elasticplastic hydrodynamics code （MEPH2Y）. It is applied on detonation. Firstly, the AMR method is described, including a conservative spatial interpolation, the time integration methodology with the adapitve time increment and an adaptive computational region method. The advantage of AMR technique is exhibited by numerical examples, including the 1-D C-J detonation and the 2-D implosion ignited from a single point. Results show that AMR can promote the computational efficiency, keeping the accuracy in interesting regions.
文摘Potassium tert-butoxide has been found to be a highly efficient catalyst for one-pot,three-component reaction of aryl aldehydes, acetophenones,and thiols via Claisen-Schmidt/Michael addition reactions for the synthesis of thia-Michael adducts in high yields. The reactions are best carried out in tert-butyl alcohol at room temperature.
基金Project supported by the National Natural Science Foundation of China(Grant No.11771151)the Guangdong Natural Science Foundation of China(Grant No.2017A030313008)+1 种基金the Guangzhou Science and Technology Program of China(Grant No.201904010362)the Fundamental Research Funds for the Central Universities of China(Grant No.2019MS110)
文摘We exhibit some new dark soliton phenomena on the general nonzero background for a defocusing three-component nonlinear Schrodinger equation. As the plane wave background undergoes unitary transformation SU(3), we obtain the general nonzero background and study its modulational instability by the linear stability analysis. On the basis of this background, we study the dynamics of one-dark soliton and two-dark-soliton phenomena, which are different from the dark solitons studied before. Furthermore, we use the numerical method for checking the stability of the one-dark-soliton solution. These results further enrich the content in nonlinear Schrodinger systems, and require more in-depth studies in the future.
基金The project supported by the State Key Project of Fundamental Research of China under Grant No. G2000067101
文摘In this paper, the solution of Chebyshev equation with its argument being greater than 1 is obtained. The initial value of the derivative of the solution is the expression of magnetization, which is valid for any spin quantum number S. The Chebyshev equation is transformed from an ordinary differential equation obtained when we dealt with Heisenberg model, in order to calculate all three components of magnetization, by many-body Green＇s function under random phase approximation. The Chebyshev functions with argument being greater than 1 are discussed. This paper shows that the Chebyshev polynomials with their argument being greater than 1 have their physical application.
文摘The three-component coupling reaction of ethyl propiolate (1), phthalimide (2), and aldehyde (3) catalyzed by tripheny- lphosphine, was developed. A solution of an equivalent amount of 1 and 2 in benzaldehyde (3a) in the presence of 30 mol% of PPh3 was heated at 100?C for 48 h to give N-(1-ethoxycarbonyl-3-oxo-3-phenylpropyl)phthalimide (4a) in 83% yield. This reaction was thought to proceed via vinylphosphonium salt formed from the reaction of ethyl propiolate (1) with triphenylphosphine in situ.
