As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and el...As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and electrochemical characteristics,MXenes have shown great potential in brain-inspired neuromorphic computing electronics,including neuromorphic gas sensors,pressure sensors and photodetectors.This paper provides a forward-looking review of the research progress regarding MXenes in the neuromorphic sensing domain and discussed the critical challenges that need to be resolved.Key bottlenecks such as insufficient long-term stability under environmental exposure,high costs,scalability limitations in large-scale production,and mechanical mismatch in wearable integration hinder their practical deployment.Furthermore,unresolved issues like interfacial compatibility in heterostructures and energy inefficiency in neu-romorphic signal conversion demand urgent attention.The review offers insights into future research directions enhance the fundamental understanding of MXene properties and promote further integration into neuromorphic computing applications through the convergence with various emerging technologies.展开更多
The proliferation of wearable biodevices has boosted the development of soft,innovative,and multifunctional materials for human health monitoring.The integration of wearable sensors with intelligent systems is an over...The proliferation of wearable biodevices has boosted the development of soft,innovative,and multifunctional materials for human health monitoring.The integration of wearable sensors with intelligent systems is an overwhelming tendency,providing powerful tools for remote health monitoring and personal health management.Among many candidates,two-dimensional(2D)materials stand out due to several exotic mechanical,electrical,optical,and chemical properties that can be efficiently integrated into atomic-thin films.While previous reviews on 2D materials for biodevices primarily focus on conventional configurations and materials like graphene,the rapid development of new 2D materials with exotic properties has opened up novel applications,particularly in smart interaction and integrated functionalities.This review aims to consolidate recent progress,highlight the unique advantages of 2D materials,and guide future research by discussing existing challenges and opportunities in applying 2D materials for smart wearable biodevices.We begin with an in-depth analysis of the advantages,sensing mechanisms,and potential applications of 2D materials in wearable biodevice fabrication.Following this,we systematically discuss state-of-the-art biodevices based on 2D materials for monitoring various physiological signals within the human body.Special attention is given to showcasing the integration of multi-functionality in 2D smart devices,mainly including self-power supply,integrated diagnosis/treatment,and human–machine interaction.Finally,the review concludes with a concise summary of existing challenges and prospective solutions concerning the utilization of2D materials for advanced biodevices.展开更多
A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface...A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface area of 427 m^(2)·g^(-1)and rich surface active sites,which help restrain polysulfides(LiPSs)through good physi-cal and chemical adsorption,while simultaneously accelerating the nucleation and dissolution kinetics of Li_(2)S,effec-tively suppressing the shuttle effect.The assembled lithium-sulfur batteries(LSBs)employing the PVS-based inter-layer delivered a high initial discharge capacity of 1386 mAh·g^(-1)at 0.1C(167.5 mAh·g^(-1)),long-term cycling stabil-ity,and good rate property.展开更多
The study aimed to develop a customized Data Governance Maturity Model (DGMM) for the Ministry of Defence (MoD) in Kenya to address data governance challenges in military settings. Current frameworks lack specific req...The study aimed to develop a customized Data Governance Maturity Model (DGMM) for the Ministry of Defence (MoD) in Kenya to address data governance challenges in military settings. Current frameworks lack specific requirements for the defence industry. The model uses Key Performance Indicators (KPIs) to enhance data governance procedures. Design Science Research guided the study, using qualitative and quantitative methods to gather data from MoD personnel. Major deficiencies were found in data integration, quality control, and adherence to data security regulations. The DGMM helps the MOD improve personnel, procedures, technology, and organizational elements related to data management. The model was tested against ISO/IEC 38500 and recommended for use in other government sectors with similar data governance issues. The DGMM has the potential to enhance data management efficiency, security, and compliance in the MOD and guide further research in military data governance.展开更多
This paper investigates ruin,capital injection,and dividends for a two-dimensional risk model.The model posits that surplus levels of insurance companies are governed by a perturbed composite Poisson risk model.This m...This paper investigates ruin,capital injection,and dividends for a two-dimensional risk model.The model posits that surplus levels of insurance companies are governed by a perturbed composite Poisson risk model.This model introduces a dependence between the two surplus levels,present in both the associated perturbations and the claims resulting from common shocks.Critical levels of capital injection and dividends are established for each of the two risks.The surplus levels are observed discretely at fixed intervals,guiding decisions on capital injection,dividends,and ruin at these junctures.This study employs a two-dimensional Fourier cosine series expansion method to approximate the finite time expected discounted operating cost until ruin.The ensuing approximation error is also quantified.The validity and accuracy of the method are corroborated through numerical examples.Furthermore,the research delves into the optimal capital allocation problem.展开更多
This study explores the relationship between corporate environmental,social,and governance(ESG)disagreements and corporate debt maturity.By examining panel samples from Chinese non-financial listed companies covering ...This study explores the relationship between corporate environmental,social,and governance(ESG)disagreements and corporate debt maturity.By examining panel samples from Chinese non-financial listed companies covering 2007 to 2020,we find that ESG disagreements negatively influence corporate debt maturity.Even after conducting a series of robustness tests and addressing endogeneity concerns,the adverse effects of ESG disagreements persisted.A heterogeneity analysis shows that this negative impact is more significant for non-state-owned enterprises,small enterprises,enterprises with high capital intensity,enterprises with low analyst attention,and enterprises in high-tech industries.Through a mechanism analysis,we discovered that ESG disagreements can lead to information asymmetry and heightened default risk,subsequently affecting the maturity of corporate debt.Further analysis confirms that the negative impact of ESG on the debt structure inhibits long-term investment and exacerbates the mismatch between investment and financing terms.展开更多
In addition to the organic matter type,abundance,thermal maturity,and shale reservoir space,the preservation conditions of source rocks play a key factor in affecting the quantity and quality of retained hydrocarbons ...In addition to the organic matter type,abundance,thermal maturity,and shale reservoir space,the preservation conditions of source rocks play a key factor in affecting the quantity and quality of retained hydrocarbons in source rocks of lacustrine shale,yet this aspect has received little attention.This paper,based on the case analysis,explores how preservation conditions influence the enrichment of mobile hydrocarbons in shale oil.Research showns that good preservation conditions play three key roles.(1)Ensure the retention of sufficient light hydrocarbons(C_(1)–C_(13)),medium hydrocarbons(C_(14)–C_(25))and small molecular aromatics(including 1–2 benzene rings)in the formation,which enhances the fluidity and flow of shale oil;(2)Maintain a high energy field(abnormally high pressure),thus facilitating the maximum outflow of shale oil;(3)Ensure that the retained hydrocarbons have the miscible flow condition of multi-component hydrocarbons(light hydrocarbons,medium hydrocarbons,heavy hydrocarbons,and heteroatomic compounds),so that the heavy hydrocarbons(C_(25+))and heavy components(non-hydrocarbons and asphaltenes)have improved fluidity and maximum flow capacity.In conclusion,in addition to the advantages of organic matter type,abundance,thermal maturity,and reservoir space,good preservation conditions of shale layers are essential for the formation of economically viable shale oil reservoirs,which should be incorporated into the evaluation criteria of shale oil-rich areas/segments and considered a necessary factor when selecting favorable exploration targets.展开更多
Lithium-sulfur(Li-S)batteries with high energy density and capacity have garnered significant research attention among various energy storage devices.However,the shuttle effect of polysulfides(LiPSs)remains a major ch...Lithium-sulfur(Li-S)batteries with high energy density and capacity have garnered significant research attention among various energy storage devices.However,the shuttle effect of polysulfides(LiPSs)remains a major challenge for their practical application.The design of battery separators has become a key aspect in addressing the challenge.MXenes,a promising two-dimensional(2D)material,offer exceptional conductivity,large surface area,high mechanical strength,and active sites for surface reactions.When assembled into layered films,MXenes form highly tunable two-dimensional channels ranging from a few angstroms to over 1 nm.These nanoconfined channels are instrumental in facilitating lithium-ion transport while effectively impeding the shuttle effect of LiPSs,which are essential for improving the specific capacity and cyclic stability of Li-S batteries.Substantial progress has been made in developing MXenes-based separators for Li-S batteries,yet there remains a research gap in summarizing advancements from the perspective of interlayer engineering.This entails maintaining the 2D nanochannels of layered MXenes-based separators while modulating the physicochemical environment within the MXenes interlayers through targeted modifications.This review highlights advancements in in situ modification of MXenes and their integration with 0D,1D,and 2D materials to construct laminated nanocomposite separators for Li-S batteries.The future development directions of MXenes-based materials in Li-S energy storage devices are also outlined,to drive further advancements in MXenes for Li-S battery separators.展开更多
Titanium dioxide(TiO_(2))has been an important protective ingredient in mineral-based sunscreens since the 1990s.However,traditional TiO_(2)nanoparticle formulations have seen little improvement over the past decades ...Titanium dioxide(TiO_(2))has been an important protective ingredient in mineral-based sunscreens since the 1990s.However,traditional TiO_(2)nanoparticle formulations have seen little improvement over the past decades and continue to face persistent challenges related to light transmission,biosafety,and visual appearance.Here,we report the discovery of two-dimensional(2D)TiO_(2),characterized by a micro-sized lateral dimension(~1.6μm)and atomic-scale thickness,which fundamentally resolves these long-standing issues.The 2D structure enables exceptional light management,achieving 80%visible light transparency—rendering it nearly invisible on the skin—while maintaining UV-blocking performance comparable to unmodified rutile TiO_(2)nanoparticles.Its larger lateral size results in a two-orders-of-magnitude reduction in skin penetration(0.96 w/w%),significantly enhancing biosafety.Moreover,the unique layered architecture inherently suppresses the generation of reactive oxygen species(ROS)under sunlight exposure,reducing the ROS generation rate by 50-fold compared to traditional TiO_(2)nanoparticles.Through precise metal element modulation,we further developed the first customizable sunscreen material capable of tuning UV protection ranges and automatically matching diverse skin tones.The 2D TiO_(2)offers a potentially transformative approach to modern sunscreen formulation,combining superior UV protection,enhanced safety and a natural appearance.展开更多
Light hydrocarbons(LHs)are key components of petroleum,and the carbon isotopes composition(δ^(13)C)of individual LHs contains a wealth of geochemical information.Forty-four oil samples from five different basins were...Light hydrocarbons(LHs)are key components of petroleum,and the carbon isotopes composition(δ^(13)C)of individual LHs contains a wealth of geochemical information.Forty-four oil samples from five different basins were analyzed using gas chromatography(GC),gas chromatography-mass spectrometry(GC–MS),and gas chromatography-isotope ratio mass spectrometry(GC-IRMS).Theδ^(13)C values of forty-three LHs were recognized and determined by comparing the GC and GC-IRMS methods.The results revealed significant differences inδ^(13)C distribution characteristics among different LH compounds.Theδ^(13)C variation of individual LHs in iso-paraffins showed the widest range,followed by cycloalkanes and aromatics,whereas theδ^(13)C variation in n-paraffins showed the narrowest range.Theδ^(13)C values of most individual LHs are primarily affected by the source facies and thermal evolution.Among them,c-1,3-dimethylcyclohexane(c-1,3DMCH)is mainly sourced from higher plants but may also form through abiotic mechanisms such as catalysis or cyclization.Theδ^(13)C values of c-1,3DMCH(δ^(13)Cc-1,3DMCH)primarily exhibit parental genetic characteristics,enabling effective distinction of oil from different source facies.Specifically,theδ^(13)Cc-1,3DMCH in marine oils,lacustrine oils,terrigenous oils,and coal-formed oils are<–22‰,from–22‰to−20.2‰,from−20.2‰to−18.4‰,and>−18.4‰,respectively.Moreover,maturity is the primary controlling factor forδ^(13)C values of 3MC7(δ^(13)C3MC7,3MC7:3-methylheptane),while the source facies serve as a secondary influence.The plot ofδ^(13)Cc-1,3DMCH andδ^(13)C3MC7 was introduced to classify source facies.Asδ^(13)Cc-1,3DMCH andδ^(13)C3MC7 increase,the source facies transits from marine to lacustrine,then terrigenous,and finally coal facies.Additionally,increasingδ^(13)C3MC7 indicates a relative increase in maturity.Therefore,theδ^(13)Cc-1,3DMCH vs.δ^(13)C3MC7 plot serves as an effective tool for distinguishing source facies and assessing relative maturity.展开更多
In the era of global tourism and creative economies,digital technology maturity has emerged as a critical factor for the sustainable development of small and medium enterprises(SMEs)in Indonesia.This research is imple...In the era of global tourism and creative economies,digital technology maturity has emerged as a critical factor for the sustainable development of small and medium enterprises(SMEs)in Indonesia.This research is implemented to find out current digital technology maturity levels among SMEs in the subdistrict of Cangkringan,district of Sleman,Yogyakarta,Indonesia,highlighting their role in fostering sustainable tourism and creative economic growth.Using a mixed-method approach,the research combines qualitative insights from in-depth interviews with three local government representatives and Focus Group Discussion with 15 SMEs in the area.Additionally,a quantitative analysis of SMEs across various sectors,including crafts and culinary services,supports the study’s conclusions.The finding reveals a significant gap between government’s training programs and the digital literacy of SMEs as well as a lack of affordable technological resources which could impede the full realization of digital benefits.Strengthening digital technology maturity among SMEs is essential for enhancing their competitiveness and long-term sustainability,yielding both financial and non-financial benefits.This also contributes to find out digital literacy gaps,impact on competitiveness and sustainability,policy and stakeholder recommendations,and government action.These insights offer valuable guidance for policymakers and stakeholders striving to support the digital transformation of SMEs in similar settings.The study also sheds light on digital literacy gaps,their impact on competitiveness and offers policy recommendations for government and stakeholders to address these challenges such as through government and community collaboration.展开更多
Savannah,Ga.,May 20,2025-Gulfstream Aerospace Corp.today announced the 50th customer delivery of the Gulfstream G700.The aircraft was outfitted at Gulfstream's Savannah completions center.Since entering service in...Savannah,Ga.,May 20,2025-Gulfstream Aerospace Corp.today announced the 50th customer delivery of the Gulfstream G700.The aircraft was outfitted at Gulfstream's Savannah completions center.Since entering service in April 2024,the G700 operates globally,and the fleet has accumulated more than 11,700 flight hours.展开更多
Owing to their rolling friction,two-dimensional piston pumps are highly suitable as power components for electro-hydrostatic actuators(EHAs).These pumps are particularly advantageous for applications requiring high ef...Owing to their rolling friction,two-dimensional piston pumps are highly suitable as power components for electro-hydrostatic actuators(EHAs).These pumps are particularly advantageous for applications requiring high efficiency and reliability.However,the ambiguity surrounding the output flow characteristics of individual two-dimensional pumps poses a significant challenge in achieving precise closed-loop control of the EHA positions.To address this issue,this study established a comprehensive numerical model that included gap leakage to analyze the impact of leakage on the output flow characteristics of a two-dimensional piston pump.The validity of the numerical analysis was indirectly confirmed through meticulous measurements of the leakage and volumetric efficiency,ensuring robust results.The research findings indicated that,at lower pump speeds,leakage significantly affected the output flow rate,leading to potential inefficiencies in the system.Conversely,at higher rotational speeds,the impact of leakage was less pronounced,implying that the influence of leakage on the pump outlet flow must be carefully considered and managed for EHAs to perform position servo control.Additionally,the research demonstrates that two-dimensional motion does not have a unique or additional effect on pump leakage,thus simplifying the design considerations.Finally,the study concluded that maintaining an oil-filled leakage environment is beneficial because it helps reduce the impact of leakage and enhances the overall volumetric efficiency of the pump system.展开更多
Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of...Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of catalytical materials.In 2019,we discussed the development trend of this field,and wrote a roadmap on this topic in Chinese Chemical Letters(30(2019)2065-2088).Nowadays,we discuss it again from a new viewpoint along this road.In this paper,several subtopics are discussed,e.g.,photocatalysis based on titanium dioxide,violet phosphorus,graphitic carbon and covalent organic frameworks,electrocatalysts based on carbon,metal-and covalent-organic framework.Finally,we hope that this roadmap can enrich the development of two-dimensional materials in environmental catalysis with novel understanding,and give useful inspiration to explore new catalysts for practical applications.展开更多
It is a key challenge to prepare two-dimensional diamond(2D-diamond).Herein,we develop a method for synthesizing 2D-diamond by depositing monodisperse tantalum(Ta)atoms onto graphene substrates using a hot-filament ch...It is a key challenge to prepare two-dimensional diamond(2D-diamond).Herein,we develop a method for synthesizing 2D-diamond by depositing monodisperse tantalum(Ta)atoms onto graphene substrates using a hot-filament chemical vapor deposition setup,followed by annealing treatment under different temperatures at ambient pressure.The results indicate that when the annealing temperature increases from 700℃ to 1000℃,the size of the 2D-diamond found in the samples gradually increases from close to 20 nm to around 30 nm.Meanwhile,the size and number of amorphous carbon spheres and Ta-containing compounds between the graphene layers gradually increase.As the annealing temperature continues to rise to 1100℃,a significant aggregation of Ta-containing compounds is observed in the samples,with no diamond structure detected.This further confirms that monodisperse Ta atoms play a key role in graphene phase transition into 2D-diamond.This study provides a novel method for the ambient-pressure phase transition of graphene into 2D-diamond.展开更多
Electron-hole interactions play a crucial role in determining the optoelectronic properties of materials,and in lowdimensional systems this is especially true due to the decrease of screening.In this review,we focus o...Electron-hole interactions play a crucial role in determining the optoelectronic properties of materials,and in lowdimensional systems this is especially true due to the decrease of screening.In this review,we focus on one unique quantum phase induced by the electron-hole interaction in two-dimensional systems,known as“exciton insulators”(EIs).Although this phase of matter has been studied for more than half a century,suitable platforms for its stable realization remain scarce.We provide an overview of the strategies to realize EIs in accessible materials and structures,along with a discussion on some unique properties of EIs stemming from the band structures of these materials.Additionally,signatures in experiments to distinguish EIs are discussed.展开更多
Background Boars undergo physiological and biochemical changes in semen composition as they grow from puberty to sexual maturity.However,comprehensive metabolomic profiles of boar semen remain uncharacterised.Understa...Background Boars undergo physiological and biochemical changes in semen composition as they grow from puberty to sexual maturity.However,comprehensive metabolomic profiles of boar semen remain uncharacterised.Understanding metabolic alterations in semen during this period is important for optimising reproductive performance in breeding programs.The aim of this study was to characterise the semen metabolome as boars mature,utilising an untargeted metabolomic approach.Semen samples were collected from 15 Duroc boars at three developmental ages:~7 months,8.5 months,and 10 months.Sperm and seminal plasma were separated and analysed by hydrophilic interaction and reversed-phase liquid chromatography coupled with mass spectrometry to capture a wide range of metabolites.Results We identified a total of 4,491 features in boar semen,annotating 92 distinct metabolites.Amino acids,peptides and analogues constituted the most abundant components,followed by fatty acid esters.Principal component analysis(PCA)and partial least squares discriminant analysis(PLS-DA)showed a clear separation between metabolomic profiles by age groups.PERMANOVA analysis of PCA scores confirmed statistically significant differences(P<0.05)between younger(7 months)and more mature boars(8.5 months and 10 months).Pathway analysis identified porphyrin metabolism,taurine and hypotaurine metabolism,and glycerolipid metabolism as significantly enriched pathways in sperm,while glutathione and nitrogen metabolism were prominently enriched in seminal plasma.Using linear modelling,partial Spearman correlation and random forest analyses,we identified homoisovanillic acid as a key metabolite discriminating age groups in both sperm and seminal plasma.Additionally,L-glutamic acid,decanoyl-L-carnitine and N-(1,3-Thiazol-2-yl)benzenesulfonamide emerged as important sperm metabolites,while glyceric acid,myo-inositol,glycerophosphocholine,and several other compounds were identified as critical seminal plasma metabolites.Conclusion This study provides a detailed characterisation of metabolic changes in Duroc boar semen during the transition from puberty to sexual maturity.Our findings enhance the understanding of reproductive development and could inform strategies to assess sexual maturity in breeding programs.展开更多
The pursuit of sustainable hydrogen production has positioned water electrolysis as a cornerstone technology for global carbon neutrality.However,sluggish kinetics,catalyst scarcity,and system integration challenges h...The pursuit of sustainable hydrogen production has positioned water electrolysis as a cornerstone technology for global carbon neutrality.However,sluggish kinetics,catalyst scarcity,and system integration challenges hinder its widespread deployment.Ultrathin two-dimensional(2D)materials,with their atomically exposed surfaces,tunable electronic structures,and defect-engineering capabilities,present unique opportunities for next-generation electrocatalysts.This review provides an integrated overview of ultrathin 2D electrocatalysts,discussing their structural diversity,synthetic routes,structure-activity relationships,and mechanistic understanding in water electrolysis processes.Special focus is placed on the translation of 2D materials from laboratory research to practical device implementation,emphasizing challenges such as scalable fabrication,interfacial engineering,and operational durability in realistic electrolyzer environments.The role of advanced characterization techniques in capturing dynamic structural changes and active site evolution is discussed.Finally,we outline future research directions,emphasizing the synergy of machine learning-driven materials discovery,advanced operando characterization,and scalable system integration to accelerate the industrial translation of 2D electrocatalysts for green hydrogen production.展开更多
Vehicle electrification,an important method for reducing carbon emissions from road transport,has been promoted globally.In this study,we analyze how individuals adapt to this transition in transportation and its subs...Vehicle electrification,an important method for reducing carbon emissions from road transport,has been promoted globally.In this study,we analyze how individuals adapt to this transition in transportation and its subsequent impact on urban structure.Considering the varying travel costs associated with electric and fuel vehicles,we analyze the dynamic choices of households concerning house locations and vehicle types in a two-dimensional monocentric city.A spatial equilibrium is developed to model the interactions between urban density,vehicle age and vehicle type.An agent-based microeconomic residential choice model dynamically coupled with a house rent market is developed to analyze household choices of home locations and vehicle energy types,considering vehicle ages and competition for public charging piles.Key findings from our proposed models show that the proportion of electric vehicles(EVs)peaks at over 50%by the end of the first scrappage period,accompanied by more than a 40%increase in commuting distance and time compared to the scenario with only fuel vehicles.Simulation experiments on a theoretical grid indicate that heterogeneity-induced residential segregation can lead to urban sprawl and congestion.Furthermore,households with EVs tend to be located farther from the city center,and an increase in EV ownership contributes to urban expansion.Our study provides insights into how individuals adapt to EV transitions and the resulting impacts on home locations and land use changes.It offers a novel perspective on the dynamic interactions between EV adoption and urban development.展开更多
The diffusion trajectory of a Brownian particle passing over the saddle point of a two-dimensional quadratic potential energy surface is tracked in detail according to the deep learning strategies.Generative adversari...The diffusion trajectory of a Brownian particle passing over the saddle point of a two-dimensional quadratic potential energy surface is tracked in detail according to the deep learning strategies.Generative adversarial networks(GANs)emanating in the category of machine learning(ML)frameworks are used to generate and assess the rationality of the data.While their optimization is based on the long short-term memory(LSTM)strategies.In addition to drawing a heat map,the optimal path of two-dimensional(2D)diffusion is simultaneously demonstrated in a stereoscopic space.The results of our simulation are completely consistent with the previous theoretical predictions.展开更多
基金supported by the NSFC(12474071)Natural Science Foundation of Shandong Province(ZR2024YQ051,ZR2025QB50)+6 种基金Guangdong Basic and Applied Basic Research Foundation(2025A1515011191)the Shanghai Sailing Program(23YF1402200,23YF1402400)funded by Basic Research Program of Jiangsu(BK20240424)Open Research Fund of State Key Laboratory of Crystal Materials(KF2406)Taishan Scholar Foundation of Shandong Province(tsqn202408006,tsqn202507058)Young Talent of Lifting engineering for Science and Technology in Shandong,China(SDAST2024QTB002)the Qilu Young Scholar Program of Shandong University。
文摘As emerging two-dimensional(2D)materials,carbides and nitrides(MXenes)could be solid solutions or organized structures made up of multi-atomic layers.With remarkable and adjustable electrical,optical,mechanical,and electrochemical characteristics,MXenes have shown great potential in brain-inspired neuromorphic computing electronics,including neuromorphic gas sensors,pressure sensors and photodetectors.This paper provides a forward-looking review of the research progress regarding MXenes in the neuromorphic sensing domain and discussed the critical challenges that need to be resolved.Key bottlenecks such as insufficient long-term stability under environmental exposure,high costs,scalability limitations in large-scale production,and mechanical mismatch in wearable integration hinder their practical deployment.Furthermore,unresolved issues like interfacial compatibility in heterostructures and energy inefficiency in neu-romorphic signal conversion demand urgent attention.The review offers insights into future research directions enhance the fundamental understanding of MXene properties and promote further integration into neuromorphic computing applications through the convergence with various emerging technologies.
基金the support from the National Natural Science Foundation of China(22272004,62272041)the Fundamental Research Funds for the Central Universities(YWF-22-L-1256)+1 种基金the National Key R&D Program of China(2023YFC3402600)the Beijing Institute of Technology Research Fund Program for Young Scholars(No.1870011182126)。
文摘The proliferation of wearable biodevices has boosted the development of soft,innovative,and multifunctional materials for human health monitoring.The integration of wearable sensors with intelligent systems is an overwhelming tendency,providing powerful tools for remote health monitoring and personal health management.Among many candidates,two-dimensional(2D)materials stand out due to several exotic mechanical,electrical,optical,and chemical properties that can be efficiently integrated into atomic-thin films.While previous reviews on 2D materials for biodevices primarily focus on conventional configurations and materials like graphene,the rapid development of new 2D materials with exotic properties has opened up novel applications,particularly in smart interaction and integrated functionalities.This review aims to consolidate recent progress,highlight the unique advantages of 2D materials,and guide future research by discussing existing challenges and opportunities in applying 2D materials for smart wearable biodevices.We begin with an in-depth analysis of the advantages,sensing mechanisms,and potential applications of 2D materials in wearable biodevice fabrication.Following this,we systematically discuss state-of-the-art biodevices based on 2D materials for monitoring various physiological signals within the human body.Special attention is given to showcasing the integration of multi-functionality in 2D smart devices,mainly including self-power supply,integrated diagnosis/treatment,and human–machine interaction.Finally,the review concludes with a concise summary of existing challenges and prospective solutions concerning the utilization of2D materials for advanced biodevices.
文摘A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface area of 427 m^(2)·g^(-1)and rich surface active sites,which help restrain polysulfides(LiPSs)through good physi-cal and chemical adsorption,while simultaneously accelerating the nucleation and dissolution kinetics of Li_(2)S,effec-tively suppressing the shuttle effect.The assembled lithium-sulfur batteries(LSBs)employing the PVS-based inter-layer delivered a high initial discharge capacity of 1386 mAh·g^(-1)at 0.1C(167.5 mAh·g^(-1)),long-term cycling stabil-ity,and good rate property.
文摘The study aimed to develop a customized Data Governance Maturity Model (DGMM) for the Ministry of Defence (MoD) in Kenya to address data governance challenges in military settings. Current frameworks lack specific requirements for the defence industry. The model uses Key Performance Indicators (KPIs) to enhance data governance procedures. Design Science Research guided the study, using qualitative and quantitative methods to gather data from MoD personnel. Major deficiencies were found in data integration, quality control, and adherence to data security regulations. The DGMM helps the MOD improve personnel, procedures, technology, and organizational elements related to data management. The model was tested against ISO/IEC 38500 and recommended for use in other government sectors with similar data governance issues. The DGMM has the potential to enhance data management efficiency, security, and compliance in the MOD and guide further research in military data governance.
基金supported by the Shihezi University High-Level Talents Research Startup Project(Project No.RCZK202521)the National Natural Science Foundation of China(Grant Nos.12271066,11871121,12171405)+1 种基金the Chongqing Natural Science Foundation Joint Fund for Innovation and Development Project(Project No.CSTB2024NSCQLZX0085)the Chongqing Normal University Foundation(Grant No.23XLB018).
文摘This paper investigates ruin,capital injection,and dividends for a two-dimensional risk model.The model posits that surplus levels of insurance companies are governed by a perturbed composite Poisson risk model.This model introduces a dependence between the two surplus levels,present in both the associated perturbations and the claims resulting from common shocks.Critical levels of capital injection and dividends are established for each of the two risks.The surplus levels are observed discretely at fixed intervals,guiding decisions on capital injection,dividends,and ruin at these junctures.This study employs a two-dimensional Fourier cosine series expansion method to approximate the finite time expected discounted operating cost until ruin.The ensuing approximation error is also quantified.The validity and accuracy of the method are corroborated through numerical examples.Furthermore,the research delves into the optimal capital allocation problem.
基金STU Scientific Research Initiation Grant[Grant No.STF24004T]Natural Science Foundation of Guangdong Province of China[Grant No.2021B1515020103].
文摘This study explores the relationship between corporate environmental,social,and governance(ESG)disagreements and corporate debt maturity.By examining panel samples from Chinese non-financial listed companies covering 2007 to 2020,we find that ESG disagreements negatively influence corporate debt maturity.Even after conducting a series of robustness tests and addressing endogeneity concerns,the adverse effects of ESG disagreements persisted.A heterogeneity analysis shows that this negative impact is more significant for non-state-owned enterprises,small enterprises,enterprises with high capital intensity,enterprises with low analyst attention,and enterprises in high-tech industries.Through a mechanism analysis,we discovered that ESG disagreements can lead to information asymmetry and heightened default risk,subsequently affecting the maturity of corporate debt.Further analysis confirms that the negative impact of ESG on the debt structure inhibits long-term investment and exacerbates the mismatch between investment and financing terms.
基金Supported by the National Natural Science Foundation of China(U22B6004)Project of PetroChina Research Institute of Petroleum Exploration and Development(2022yjcq03)Core Technology Key Project of China Petroleum Changqing Oilfield Company(KJZX2023-01).
文摘In addition to the organic matter type,abundance,thermal maturity,and shale reservoir space,the preservation conditions of source rocks play a key factor in affecting the quantity and quality of retained hydrocarbons in source rocks of lacustrine shale,yet this aspect has received little attention.This paper,based on the case analysis,explores how preservation conditions influence the enrichment of mobile hydrocarbons in shale oil.Research showns that good preservation conditions play three key roles.(1)Ensure the retention of sufficient light hydrocarbons(C_(1)–C_(13)),medium hydrocarbons(C_(14)–C_(25))and small molecular aromatics(including 1–2 benzene rings)in the formation,which enhances the fluidity and flow of shale oil;(2)Maintain a high energy field(abnormally high pressure),thus facilitating the maximum outflow of shale oil;(3)Ensure that the retained hydrocarbons have the miscible flow condition of multi-component hydrocarbons(light hydrocarbons,medium hydrocarbons,heavy hydrocarbons,and heteroatomic compounds),so that the heavy hydrocarbons(C_(25+))and heavy components(non-hydrocarbons and asphaltenes)have improved fluidity and maximum flow capacity.In conclusion,in addition to the advantages of organic matter type,abundance,thermal maturity,and reservoir space,good preservation conditions of shale layers are essential for the formation of economically viable shale oil reservoirs,which should be incorporated into the evaluation criteria of shale oil-rich areas/segments and considered a necessary factor when selecting favorable exploration targets.
基金supported by Beijing Natural Science Foundation(Nos.2232037 and 2242035)the National Natural Science Foundation of China(Nos.22005012,22105012 and 51803183)+1 种基金Chunhui Plan Cooperative Project of Ministry of Education(No.202201298)the China Postdoctoral Science Foundation Funded Project(No.2023M733520).
文摘Lithium-sulfur(Li-S)batteries with high energy density and capacity have garnered significant research attention among various energy storage devices.However,the shuttle effect of polysulfides(LiPSs)remains a major challenge for their practical application.The design of battery separators has become a key aspect in addressing the challenge.MXenes,a promising two-dimensional(2D)material,offer exceptional conductivity,large surface area,high mechanical strength,and active sites for surface reactions.When assembled into layered films,MXenes form highly tunable two-dimensional channels ranging from a few angstroms to over 1 nm.These nanoconfined channels are instrumental in facilitating lithium-ion transport while effectively impeding the shuttle effect of LiPSs,which are essential for improving the specific capacity and cyclic stability of Li-S batteries.Substantial progress has been made in developing MXenes-based separators for Li-S batteries,yet there remains a research gap in summarizing advancements from the perspective of interlayer engineering.This entails maintaining the 2D nanochannels of layered MXenes-based separators while modulating the physicochemical environment within the MXenes interlayers through targeted modifications.This review highlights advancements in in situ modification of MXenes and their integration with 0D,1D,and 2D materials to construct laminated nanocomposite separators for Li-S batteries.The future development directions of MXenes-based materials in Li-S energy storage devices are also outlined,to drive further advancements in MXenes for Li-S battery separators.
基金supported by the National Key Research and Development Project(No.2019YFA0705403)the National Natural Science Foundation of China(No.T2293693,52273311)+2 种基金the Guangdong Basic and Applied Basic Research Foundation(No.2020B0301030002)and the Shenzhen Basic Research Project(Nos.WDZC20200824091903001,JSGG20220831105402004,JCYJ20220818100806014)Shenzhen Major Science and Technology Projects(Nos.KCXFZ20240903094013018,KCXFZ20240903094203005)。
文摘Titanium dioxide(TiO_(2))has been an important protective ingredient in mineral-based sunscreens since the 1990s.However,traditional TiO_(2)nanoparticle formulations have seen little improvement over the past decades and continue to face persistent challenges related to light transmission,biosafety,and visual appearance.Here,we report the discovery of two-dimensional(2D)TiO_(2),characterized by a micro-sized lateral dimension(~1.6μm)and atomic-scale thickness,which fundamentally resolves these long-standing issues.The 2D structure enables exceptional light management,achieving 80%visible light transparency—rendering it nearly invisible on the skin—while maintaining UV-blocking performance comparable to unmodified rutile TiO_(2)nanoparticles.Its larger lateral size results in a two-orders-of-magnitude reduction in skin penetration(0.96 w/w%),significantly enhancing biosafety.Moreover,the unique layered architecture inherently suppresses the generation of reactive oxygen species(ROS)under sunlight exposure,reducing the ROS generation rate by 50-fold compared to traditional TiO_(2)nanoparticles.Through precise metal element modulation,we further developed the first customizable sunscreen material capable of tuning UV protection ranges and automatically matching diverse skin tones.The 2D TiO_(2)offers a potentially transformative approach to modern sunscreen formulation,combining superior UV protection,enhanced safety and a natural appearance.
基金funded by the National Natural Science Foundation of China(Grant No.42173054).
文摘Light hydrocarbons(LHs)are key components of petroleum,and the carbon isotopes composition(δ^(13)C)of individual LHs contains a wealth of geochemical information.Forty-four oil samples from five different basins were analyzed using gas chromatography(GC),gas chromatography-mass spectrometry(GC–MS),and gas chromatography-isotope ratio mass spectrometry(GC-IRMS).Theδ^(13)C values of forty-three LHs were recognized and determined by comparing the GC and GC-IRMS methods.The results revealed significant differences inδ^(13)C distribution characteristics among different LH compounds.Theδ^(13)C variation of individual LHs in iso-paraffins showed the widest range,followed by cycloalkanes and aromatics,whereas theδ^(13)C variation in n-paraffins showed the narrowest range.Theδ^(13)C values of most individual LHs are primarily affected by the source facies and thermal evolution.Among them,c-1,3-dimethylcyclohexane(c-1,3DMCH)is mainly sourced from higher plants but may also form through abiotic mechanisms such as catalysis or cyclization.Theδ^(13)C values of c-1,3DMCH(δ^(13)Cc-1,3DMCH)primarily exhibit parental genetic characteristics,enabling effective distinction of oil from different source facies.Specifically,theδ^(13)Cc-1,3DMCH in marine oils,lacustrine oils,terrigenous oils,and coal-formed oils are<–22‰,from–22‰to−20.2‰,from−20.2‰to−18.4‰,and>−18.4‰,respectively.Moreover,maturity is the primary controlling factor forδ^(13)C values of 3MC7(δ^(13)C3MC7,3MC7:3-methylheptane),while the source facies serve as a secondary influence.The plot ofδ^(13)Cc-1,3DMCH andδ^(13)C3MC7 was introduced to classify source facies.Asδ^(13)Cc-1,3DMCH andδ^(13)C3MC7 increase,the source facies transits from marine to lacustrine,then terrigenous,and finally coal facies.Additionally,increasingδ^(13)C3MC7 indicates a relative increase in maturity.Therefore,theδ^(13)Cc-1,3DMCH vs.δ^(13)C3MC7 plot serves as an effective tool for distinguishing source facies and assessing relative maturity.
文摘In the era of global tourism and creative economies,digital technology maturity has emerged as a critical factor for the sustainable development of small and medium enterprises(SMEs)in Indonesia.This research is implemented to find out current digital technology maturity levels among SMEs in the subdistrict of Cangkringan,district of Sleman,Yogyakarta,Indonesia,highlighting their role in fostering sustainable tourism and creative economic growth.Using a mixed-method approach,the research combines qualitative insights from in-depth interviews with three local government representatives and Focus Group Discussion with 15 SMEs in the area.Additionally,a quantitative analysis of SMEs across various sectors,including crafts and culinary services,supports the study’s conclusions.The finding reveals a significant gap between government’s training programs and the digital literacy of SMEs as well as a lack of affordable technological resources which could impede the full realization of digital benefits.Strengthening digital technology maturity among SMEs is essential for enhancing their competitiveness and long-term sustainability,yielding both financial and non-financial benefits.This also contributes to find out digital literacy gaps,impact on competitiveness and sustainability,policy and stakeholder recommendations,and government action.These insights offer valuable guidance for policymakers and stakeholders striving to support the digital transformation of SMEs in similar settings.The study also sheds light on digital literacy gaps,their impact on competitiveness and offers policy recommendations for government and stakeholders to address these challenges such as through government and community collaboration.
文摘Savannah,Ga.,May 20,2025-Gulfstream Aerospace Corp.today announced the 50th customer delivery of the Gulfstream G700.The aircraft was outfitted at Gulfstream's Savannah completions center.Since entering service in April 2024,the G700 operates globally,and the fleet has accumulated more than 11,700 flight hours.
基金Supported by National Natural Science Foundation of China(Grant No.52205072).
文摘Owing to their rolling friction,two-dimensional piston pumps are highly suitable as power components for electro-hydrostatic actuators(EHAs).These pumps are particularly advantageous for applications requiring high efficiency and reliability.However,the ambiguity surrounding the output flow characteristics of individual two-dimensional pumps poses a significant challenge in achieving precise closed-loop control of the EHA positions.To address this issue,this study established a comprehensive numerical model that included gap leakage to analyze the impact of leakage on the output flow characteristics of a two-dimensional piston pump.The validity of the numerical analysis was indirectly confirmed through meticulous measurements of the leakage and volumetric efficiency,ensuring robust results.The research findings indicated that,at lower pump speeds,leakage significantly affected the output flow rate,leading to potential inefficiencies in the system.Conversely,at higher rotational speeds,the impact of leakage was less pronounced,implying that the influence of leakage on the pump outlet flow must be carefully considered and managed for EHAs to perform position servo control.Additionally,the research demonstrates that two-dimensional motion does not have a unique or additional effect on pump leakage,thus simplifying the design considerations.Finally,the study concluded that maintaining an oil-filled leakage environment is beneficial because it helps reduce the impact of leakage and enhances the overall volumetric efficiency of the pump system.
基金supported by the National Natural Science Foundation of China(Nos.52272290,21972030,52073119,and 52373210)the Natural Science Foundation of Jilin Province(No.20230101029JC)+1 种基金the Fundamental Research Program of Shanxi Province(No.202303021212159)the Monash University Malaysia–ASEAN grant(No.ASE-000010)。
文摘Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of catalytical materials.In 2019,we discussed the development trend of this field,and wrote a roadmap on this topic in Chinese Chemical Letters(30(2019)2065-2088).Nowadays,we discuss it again from a new viewpoint along this road.In this paper,several subtopics are discussed,e.g.,photocatalysis based on titanium dioxide,violet phosphorus,graphitic carbon and covalent organic frameworks,electrocatalysts based on carbon,metal-and covalent-organic framework.Finally,we hope that this roadmap can enrich the development of two-dimensional materials in environmental catalysis with novel understanding,and give useful inspiration to explore new catalysts for practical applications.
基金supported by the Key Project of the National Natural Science Foundation of China(Grant No.U1809210)the International Science Technology Cooperation Program of China(Grant No.2014DFR51160)+3 种基金the One Belt and One Road International Cooperation Project from the Key Research and Development Program of Zhejiang Province,China(Grant No.2018C04021)the National Natural Science Foundation of China(Grant Nos.50972129,50602039,and 52102052)the Fund from Institute of Wenzhou,Zhejiang University(Grant Nos.XMGL-CX-202305 and XMGLKJZX-202307)the Project from Tanghe Scientific&Technology Company(Grant No.KYY-HX-20230024).
文摘It is a key challenge to prepare two-dimensional diamond(2D-diamond).Herein,we develop a method for synthesizing 2D-diamond by depositing monodisperse tantalum(Ta)atoms onto graphene substrates using a hot-filament chemical vapor deposition setup,followed by annealing treatment under different temperatures at ambient pressure.The results indicate that when the annealing temperature increases from 700℃ to 1000℃,the size of the 2D-diamond found in the samples gradually increases from close to 20 nm to around 30 nm.Meanwhile,the size and number of amorphous carbon spheres and Ta-containing compounds between the graphene layers gradually increase.As the annealing temperature continues to rise to 1100℃,a significant aggregation of Ta-containing compounds is observed in the samples,with no diamond structure detected.This further confirms that monodisperse Ta atoms play a key role in graphene phase transition into 2D-diamond.This study provides a novel method for the ambient-pressure phase transition of graphene into 2D-diamond.
基金supported by the National Key Research&Development Program of China(Grant Nos.2022YFA1403500 and 2021YFA1400500)the National Science Foundation of China(Grant Nos.62321004,12234001,and 12474215)+1 种基金supported by New Cornerstone Science Foundationa fellowship and a CRF award from the Research Grants Council of the Hong Kong Special Administrative Region,China(Grant Nos.HKUST SRFS2324-6S01 and C7037-22GF)。
文摘Electron-hole interactions play a crucial role in determining the optoelectronic properties of materials,and in lowdimensional systems this is especially true due to the decrease of screening.In this review,we focus on one unique quantum phase induced by the electron-hole interaction in two-dimensional systems,known as“exciton insulators”(EIs).Although this phase of matter has been studied for more than half a century,suitable platforms for its stable realization remain scarce.We provide an overview of the strategies to realize EIs in accessible materials and structures,along with a discussion on some unique properties of EIs stemming from the band structures of these materials.Additionally,signatures in experiments to distinguish EIs are discussed.
基金Open access funding provided by University of Inland Norway The Research Council of Norway provided financial support(grant number 331878).
文摘Background Boars undergo physiological and biochemical changes in semen composition as they grow from puberty to sexual maturity.However,comprehensive metabolomic profiles of boar semen remain uncharacterised.Understanding metabolic alterations in semen during this period is important for optimising reproductive performance in breeding programs.The aim of this study was to characterise the semen metabolome as boars mature,utilising an untargeted metabolomic approach.Semen samples were collected from 15 Duroc boars at three developmental ages:~7 months,8.5 months,and 10 months.Sperm and seminal plasma were separated and analysed by hydrophilic interaction and reversed-phase liquid chromatography coupled with mass spectrometry to capture a wide range of metabolites.Results We identified a total of 4,491 features in boar semen,annotating 92 distinct metabolites.Amino acids,peptides and analogues constituted the most abundant components,followed by fatty acid esters.Principal component analysis(PCA)and partial least squares discriminant analysis(PLS-DA)showed a clear separation between metabolomic profiles by age groups.PERMANOVA analysis of PCA scores confirmed statistically significant differences(P<0.05)between younger(7 months)and more mature boars(8.5 months and 10 months).Pathway analysis identified porphyrin metabolism,taurine and hypotaurine metabolism,and glycerolipid metabolism as significantly enriched pathways in sperm,while glutathione and nitrogen metabolism were prominently enriched in seminal plasma.Using linear modelling,partial Spearman correlation and random forest analyses,we identified homoisovanillic acid as a key metabolite discriminating age groups in both sperm and seminal plasma.Additionally,L-glutamic acid,decanoyl-L-carnitine and N-(1,3-Thiazol-2-yl)benzenesulfonamide emerged as important sperm metabolites,while glyceric acid,myo-inositol,glycerophosphocholine,and several other compounds were identified as critical seminal plasma metabolites.Conclusion This study provides a detailed characterisation of metabolic changes in Duroc boar semen during the transition from puberty to sexual maturity.Our findings enhance the understanding of reproductive development and could inform strategies to assess sexual maturity in breeding programs.
文摘The pursuit of sustainable hydrogen production has positioned water electrolysis as a cornerstone technology for global carbon neutrality.However,sluggish kinetics,catalyst scarcity,and system integration challenges hinder its widespread deployment.Ultrathin two-dimensional(2D)materials,with their atomically exposed surfaces,tunable electronic structures,and defect-engineering capabilities,present unique opportunities for next-generation electrocatalysts.This review provides an integrated overview of ultrathin 2D electrocatalysts,discussing their structural diversity,synthetic routes,structure-activity relationships,and mechanistic understanding in water electrolysis processes.Special focus is placed on the translation of 2D materials from laboratory research to practical device implementation,emphasizing challenges such as scalable fabrication,interfacial engineering,and operational durability in realistic electrolyzer environments.The role of advanced characterization techniques in capturing dynamic structural changes and active site evolution is discussed.Finally,we outline future research directions,emphasizing the synergy of machine learning-driven materials discovery,advanced operando characterization,and scalable system integration to accelerate the industrial translation of 2D electrocatalysts for green hydrogen production.
基金supported by National Natural Science Foundation of China(72288101,72361137002,and 72101018)the Dutch Research Council(NWO Grant 482.22.01).
文摘Vehicle electrification,an important method for reducing carbon emissions from road transport,has been promoted globally.In this study,we analyze how individuals adapt to this transition in transportation and its subsequent impact on urban structure.Considering the varying travel costs associated with electric and fuel vehicles,we analyze the dynamic choices of households concerning house locations and vehicle types in a two-dimensional monocentric city.A spatial equilibrium is developed to model the interactions between urban density,vehicle age and vehicle type.An agent-based microeconomic residential choice model dynamically coupled with a house rent market is developed to analyze household choices of home locations and vehicle energy types,considering vehicle ages and competition for public charging piles.Key findings from our proposed models show that the proportion of electric vehicles(EVs)peaks at over 50%by the end of the first scrappage period,accompanied by more than a 40%increase in commuting distance and time compared to the scenario with only fuel vehicles.Simulation experiments on a theoretical grid indicate that heterogeneity-induced residential segregation can lead to urban sprawl and congestion.Furthermore,households with EVs tend to be located farther from the city center,and an increase in EV ownership contributes to urban expansion.Our study provides insights into how individuals adapt to EV transitions and the resulting impacts on home locations and land use changes.It offers a novel perspective on the dynamic interactions between EV adoption and urban development.
基金supported by the Natural Science Foundation of Shandong Province(Grant No.ZR2020MA092)the Innovation Project for Graduate Students of Ludong University(Grant No.IPGS2024-048).
文摘The diffusion trajectory of a Brownian particle passing over the saddle point of a two-dimensional quadratic potential energy surface is tracked in detail according to the deep learning strategies.Generative adversarial networks(GANs)emanating in the category of machine learning(ML)frameworks are used to generate and assess the rationality of the data.While their optimization is based on the long short-term memory(LSTM)strategies.In addition to drawing a heat map,the optimal path of two-dimensional(2D)diffusion is simultaneously demonstrated in a stereoscopic space.The results of our simulation are completely consistent with the previous theoretical predictions.
