The combined micro arc oxidation (MAO) and a hybrid beam deposition process was used to deposit duplex (Si:N)-DLC/MAO coatings on AZ80 magnesium alloy. The microstructure and composition of the duplex coatings we...The combined micro arc oxidation (MAO) and a hybrid beam deposition process was used to deposit duplex (Si:N)-DLC/MAO coatings on AZ80 magnesium alloy. The microstructure and composition of the duplex coatings were analyzed by Raman spectroscopy, X-ray photoelectron spectroscope (XPS), scanning electron microscope (SEM) and atomic force microscopy (AFM). Tribological behaviors of the coatings were studied by ball-on-disk friction test. It was found that the ID/IG ratio of the (Si:N)-DLC (diamond-like carbon) top films increases with decreasing C2H2/N2 ratio. The (Si:N)-DLC top film with SigN4 was formed on the MAO coated sample as the C2H2/N2 ratio was 10sccm:5sccm, which showed an increasing critical load compared with the pure DLC directly deposited on the Mg alloy substrate. As a result, the (Si:N)-DLC/MAO coating exhibited an advanced wear protection for the substrate.展开更多
MAX phase ceramics is a large family of nanolaminate carbides and nitrides,which integrates the advantages of both metals and ceramics,in general,the distinct chemical inertness of ceramics and excellent physical prop...MAX phase ceramics is a large family of nanolaminate carbides and nitrides,which integrates the advantages of both metals and ceramics,in general,the distinct chemical inertness of ceramics and excellent physical properties like metals.Meanwhile,the rich chemical and structural diversity of the MAXs endows them with broad space for property regulation.Especially,a much higher self-lubricity,as well as wear resistance,than that of traditional alloys and ceramics,has been observed in MAXs at elevated temperatures in recent decades,which manifests a great application potential and sparks tremendous research interest.Aiming at establishing a correlation among structure,chemical composition,working conditions,and the tribological behaviors of MAXs,this work overviews the recent progress in their high-temperature(HT)tribological properties,accompanied by advances in synthesis and structure analysis.HT tribological-specific behaviors,including the stress responses and damage mechanism,oxidation mechanism,and wear mechanism,are discussed.Whereafter,the tribological behaviors along with factors related to the tribological working conditions are discussed.Accordingly,outlooks of MAX phase ceramics for future HT solid lubricants are given based on the optimization of present mechanical properties and processing technologies.展开更多
It is worthy of studying the effect of water content in crude oil on tribological behavior of stator rubber,because the different water content would affect the swelling and wear of rubber.Compatibility of dewatered c...It is worthy of studying the effect of water content in crude oil on tribological behavior of stator rubber,because the different water content would affect the swelling and wear of rubber.Compatibility of dewatered crude oil and water was observed after mixture of dewatered crude oil and water(called oil-water mixture)was mechanical stirred and statically placed.Static etching experiment of samples in oil-water mixture was performed using hanging patch test.Wetting contact angle of oilwater mixture on rubber surface was measured by contact angle meter.Tribological behavior of samples in mixture was measured using a ring-on-block tester.The result shows that when the water content is less than 15%,water can blend with dewatered crude oil,and oil-water separation happens when water content was more than 15%.With the increasing of water content in crude oil,Wettability of mixture and swelling increment of samples decrease.The wear loss of sample increases after treated by swelling experiment,and FKM owns better wear resistance than NBR.展开更多
基金the financial support of the National Natural Science Foundation of China(Grant No.51201176)Industrialization Project of Education Department of Shaanxi Province(GrantNo.2012JC13)Zhejiang Provincial Natural Science Foundation of China(Grant No.Y2110401)
文摘The combined micro arc oxidation (MAO) and a hybrid beam deposition process was used to deposit duplex (Si:N)-DLC/MAO coatings on AZ80 magnesium alloy. The microstructure and composition of the duplex coatings were analyzed by Raman spectroscopy, X-ray photoelectron spectroscope (XPS), scanning electron microscope (SEM) and atomic force microscopy (AFM). Tribological behaviors of the coatings were studied by ball-on-disk friction test. It was found that the ID/IG ratio of the (Si:N)-DLC (diamond-like carbon) top films increases with decreasing C2H2/N2 ratio. The (Si:N)-DLC top film with SigN4 was formed on the MAO coated sample as the C2H2/N2 ratio was 10sccm:5sccm, which showed an increasing critical load compared with the pure DLC directly deposited on the Mg alloy substrate. As a result, the (Si:N)-DLC/MAO coating exhibited an advanced wear protection for the substrate.
基金National Natural Science Foundation ofChina,Grant/Award Number:52275212Fundamental Research Funds for theCentral Universities,Grant/Award Number:D5000230047the"Special Lubrication and Sealing forAerospace"Shaanxi Provincial Scienceand Technology Innovation Team,Grant/Award Number:2024RS-CXTD-63。
文摘MAX phase ceramics is a large family of nanolaminate carbides and nitrides,which integrates the advantages of both metals and ceramics,in general,the distinct chemical inertness of ceramics and excellent physical properties like metals.Meanwhile,the rich chemical and structural diversity of the MAXs endows them with broad space for property regulation.Especially,a much higher self-lubricity,as well as wear resistance,than that of traditional alloys and ceramics,has been observed in MAXs at elevated temperatures in recent decades,which manifests a great application potential and sparks tremendous research interest.Aiming at establishing a correlation among structure,chemical composition,working conditions,and the tribological behaviors of MAXs,this work overviews the recent progress in their high-temperature(HT)tribological properties,accompanied by advances in synthesis and structure analysis.HT tribological-specific behaviors,including the stress responses and damage mechanism,oxidation mechanism,and wear mechanism,are discussed.Whereafter,the tribological behaviors along with factors related to the tribological working conditions are discussed.Accordingly,outlooks of MAX phase ceramics for future HT solid lubricants are given based on the optimization of present mechanical properties and processing technologies.
基金supported by the National Natural Science Foundation of China (50878178)Liaoning Provincial Natural Science Foundation of China (2013020039)
文摘It is worthy of studying the effect of water content in crude oil on tribological behavior of stator rubber,because the different water content would affect the swelling and wear of rubber.Compatibility of dewatered crude oil and water was observed after mixture of dewatered crude oil and water(called oil-water mixture)was mechanical stirred and statically placed.Static etching experiment of samples in oil-water mixture was performed using hanging patch test.Wetting contact angle of oilwater mixture on rubber surface was measured by contact angle meter.Tribological behavior of samples in mixture was measured using a ring-on-block tester.The result shows that when the water content is less than 15%,water can blend with dewatered crude oil,and oil-water separation happens when water content was more than 15%.With the increasing of water content in crude oil,Wettability of mixture and swelling increment of samples decrease.The wear loss of sample increases after treated by swelling experiment,and FKM owns better wear resistance than NBR.