Airless tires are essential for enhancing the safety,reliability,and convenience of maintenance of electric bicycles.Polyurethane(PU)is considered a promising candidate for such applications owing to its versatile pro...Airless tires are essential for enhancing the safety,reliability,and convenience of maintenance of electric bicycles.Polyurethane(PU)is considered a promising candidate for such applications owing to its versatile properties.However,their use is limited by insufficient heat resistance and excessive dynamic heat generation under cyclic loading.In this study,star-shaped trifunctional polypropylene glycerol(PPG3)was incorporated into conventional poly(tetramethylene glycol)(PTMG)and 4,4'-methylenediphenyl diisocyanate(MDI)-based systems to construct microporous star-shaped casting polyurethanes(SCPU),with water serving as a green foaming agent.Unlike conventional small-molecule trifunctional crosslinkers that create junctions within hard segment domains,PPG3 introduces long flexible arms between the hard segments,anchoring the crosslinking points at its molecular core.The large steric hindrance of PPG3 effectively suppresses soft segment crystallization and lowers the degree of microphase separation,whereas the crosslinked network restricts chain mobility,thereby reducing dynamic heat generation.These structural features also enhance the heat resistance,yielding a softening temperature of 183℃,which is 30.9%higher than that of polyurethane without PPG3.When applied to airless tires by casting SCPU into rubber treads,the fabricated hybrid airless tires achieved a rolling distance of over 3000 km under a load of 65 kg at 25km/h without structural failure,satisfying practical performance requirements.This strategy offers a simple,solvent-free,and environmentally friendly process,underscoring the potential of SCPU for scalable production of high-performance airless tires.展开更多
The spoke as a key component has a significant impact on the performance of the non-pneumatic tire(NPT).The current research has focused on adjusting spoke structures to improve the single performance of NPT.Few studi...The spoke as a key component has a significant impact on the performance of the non-pneumatic tire(NPT).The current research has focused on adjusting spoke structures to improve the single performance of NPT.Few studies have been conducted to synergistically improve multi-performance by optimizing the spoke structure.Inspired by the concept of functionally gradient structures,this paper introduces a functionally gradient honeycomb NPT and its optimization method.Firstly,this paper completes the parameterization of the honeycomb spoke structure and establishes the numerical models of honeycomb NPTs with seven different gradients.Subsequently,the accuracy of the numerical models is verified using experimental methods.Then,the static and dynamic characteristics of these gradient honeycomb NPTs are thoroughly examined by using the finite element method.The findings highlight that the gradient structure of NPT-3 has superior performance.Building upon this,the study investigates the effects of key parameters,such as honeycomb spoke thickness and length,on load-carrying capacity,honeycomb spoke stress and mass.Finally,a multi-objective optimization method is proposed that uses a response surface model(RSM)and the Nondominated Sorting Genetic Algorithm-II(NSGA-II)to further optimize the functional gradient honeycomb NPTs.The optimized NPT-OP shows a 23.48%reduction in radial stiffness,8.95%reduction in maximum spoke stress and 16.86%reduction in spoke mass compared to the initial NPT-1.The damping characteristics of the NPT-OP have also been improved.The results offer a theoretical foundation and technical methodology for the structural design and optimization of gradient honeycomb NPTs.展开更多
This study presents a fragility curve to assess explosively induced damage to military vehicle tires based on shock tube experiments.To replicate lateral damage scenarios that may occur in real battlefield environment...This study presents a fragility curve to assess explosively induced damage to military vehicle tires based on shock tube experiments.To replicate lateral damage scenarios that may occur in real battlefield environments involving missile or bomb detonations,extreme overpressure conditions were generated using a shock tube.The influence of explosive charge mass on tire damage was quantitatively evaluated.Experimental results identified two critical failure thresholds:for loss of pressure,the threshold was 354 kPa peak overpressure and 3052 kPa·ms impulse;for rupture,the values were 485 kPa and 4237 kPa-ms,respectively.The same damage profile was reproduced through finite element analysis(FEA),verifying the reliability of the simulation.A Single Degree of Freedom(SDOF)model and Kingery-Bulmash(K-B)chart were employed to generate pressure-impulse data as a function of standoff distance.These data were applied to a finite element tire model using the BLAST ENHANCED keyword in LS-DYNA.The applied peak overpressures were identical to the experimental values with a 24%-27%difference in impulse.The simulation also captured recurring bead rim separation phenomenon,leading to internal pressure loss consistent with high-speed camera observations from the experiments.The resulting fragility curve clearly defines the threshold conditions for tire damage and provides a standardized damage assessment model applicable to various explosive charge masses and stand-off distances.The proposed model offers a quantitative basis for evaluating tire vulnerability,providing foundational reference data for defense applications.Specifically,the findings are expected to serve as a reliable source for weapon effects analysis and target vulnerability assessments involving wheeled military vehicles.展开更多
Pyrolysis has the potential of transforming waste into valuable products. Pyrolytic carbon black (PCB) is one of the most important products resulting from the pyrolysis of used tires. One of the most significant appl...Pyrolysis has the potential of transforming waste into valuable products. Pyrolytic carbon black (PCB) is one of the most important products resulting from the pyrolysis of used tires. One of the most significant applica-tions of modified pyrolytic carbon black is its use as pigment for offset printing ink to obtain high added values. Inverse gas chromatography (IGC) results show that a large quantity of inorganic matters and carbonaceous deposit are removed by treating the pyrolytic carbon black with nitric acid solution. Plenty of active sites originally occu-pied by inorganic ash and coke are recovered. The surface energy of pyrolytic carbon black (TWPC)modified by titanate-coupling agent-especially the specific interaction γ sspdetermined by the specific probe molecule, tolu-ene-shows the strong interaction between the TWPC and the synthetic resins. The offset printing ink performance confirms the IGC prediction. And TWPC has the great potential of applications in printing ink industry as pigment.展开更多
Wear and mileage performance are the foremost performances for truck bus radial (TBR) tires. There are a lot of researches about the tire wear performance as well as the contact patch phenomenon by using finite elemen...Wear and mileage performance are the foremost performances for truck bus radial (TBR) tires. There are a lot of researches about the tire wear performance as well as the contact patch phenomenon by using finite element analysis (FEA) method or testing. But there is little published data on the correlations between the footprint geometry and the tread wear performance of tires. In this paper, an experiment on tire-ground performance of TBR tires is carried out by using Tekscan. The real-time changes of contact-area pressure distribution that occurred during the process of continuous load and unload are recorded. Three types of tires that act differently in behavior under normal usage are analyzed. A new method of researching in tire tread wear, which focuses on the geometrical characters of the footprint, is put forward. The experimental results of the three tires are described by using footprint geometrical characters. On the basis of studying the changing laws of footprint geometrical characters during the loading process and considering consumer survey and factory feedback information, the correlations between the geometrical character of footprints and tread destruction form are built. The analyzed results show that a greater contact area coefficient and a steady coefficient of contact result in a better wear performance for TBR tires. The footprint-shape coefficient changing laws in the process of loading are found to have a very good coincidence with the tread wear of the three types of tires. Tires with a smaller footprint-shape coefficient are likely to have an average tread wear while avoiding the shoulder wear first. The proposed research provides a new solution to predict tire-ground performance at the point of footprint and several useful references for improving tire design.展开更多
Scrapped tires from vehicles are produced in large quantities. Despite numerous existing uses of scrapped tires, alarge quantity ends up at the landfill sites, which contributes to environmental degradation. The devel...Scrapped tires from vehicles are produced in large quantities. Despite numerous existing uses of scrapped tires, alarge quantity ends up at the landfill sites, which contributes to environmental degradation. The development ofmore applications of scrapped tire usage can reduce the disposal of tires at landfill sites. This research proposes anovel use of scrapped tires by using the strips taken from scrapped tires in replacement of steel bars as reinforcement. Manhole covers were produced using scrapped tires by completely replacing the steel with scrapped tires.Four different samples of manhole covers were prepared and tested. The highest bearing capacity of 25.5 kN wasrecorded with a sample of 100 mm thickness made with cementitious composite, which is 2.25 times higher thanthe bearing capacity of a conventional reinforced-concrete manhole cover. The use of manhole covers made withscrapped tires can effectively address the theft issue of manhole covers. The lifecycle cost analysis shows that themanhole cover made with scrapped tires is 3.4 times more cost-effective in comparison with the conventionalmanhole cover. This research shows a new avenue of the potential use of scrapped tires as reinforcement in structures, which can improve sustainable construction practices.展开更多
Scrap vulcanized rubber is amongst a bigger waste polymers. It does not decompose easily owing to its cross linked structure. Modification of scrap tires powder by the grafting with 2-acrylamido-2-methylpropanesulfoni...Scrap vulcanized rubber is amongst a bigger waste polymers. It does not decompose easily owing to its cross linked structure. Modification of scrap tires powder by the grafting with 2-acrylamido-2-methylpropanesulfonic acid (AMPS) is described. The grafting is achieved through free radical initiation. The effects of different amount of monomer and initiator were examined. Also the influence of reaction time and temperature were investigated. The grafted waste rubber was characterized by FT/IR, SEM and DSC measurements. The proposed mechanism of the grafting reaction is discussed. From DSC and SEM studies of WR-g-AMPS compared with PAMPS and WR, the results show that the particle size and crystallinity were enhanced for the grafted copolymers. The obtained modified scraped tires will used as an ion exchanger for the future applications.展开更多
A series of basic nitrogen doped carbon hollow spheres(p-N-C) catalysts derived from waste tires were prepared by a green, facile and environmental “leavening” strategy for the catalytic oxidation of pentanethiol. C...A series of basic nitrogen doped carbon hollow spheres(p-N-C) catalysts derived from waste tires were prepared by a green, facile and environmental “leavening” strategy for the catalytic oxidation of pentanethiol. Compared to pristine carbon, the p-N-C has a higher surface curvature conducive to the enrichment of substrates, leading to an excellent catalytic performance. This increased surface curvature of p-N-C was fabricated on the synergistic effect of two foaming agents((NH4)2 C2 O4 and NaHCO3), and the released gas also endows the spherical shell of p-N-C with a hierarchical porous structure, promoting the accessibility of active sites with pentanethiol. Pyridine-like and pyrrolic-like nitrogen atoms were investigated as reactive sites on the p-N-C to accelerate the electron transfer from sulfur to active surface oxygen and enhance the adsorption/oxidation process. As a result, the optimal p-N-C catalyst exhibits superior adsorption and oxidation performance(99.9%) of pentanethiol, outperforming the “unleavened”catalyst(20.8%). This work offers a new avenue for the fabrication of highly efficient materials for the desulfurization of fuel.展开更多
The restriction width of carcass by the belts( RWCB) as an important parameter of radial tire design has been neglected for a long time. In order to improve the accuracy and efficiency of tire profile design,the calcu...The restriction width of carcass by the belts( RWCB) as an important parameter of radial tire design has been neglected for a long time. In order to improve the accuracy and efficiency of tire profile design,the calculating method of RWCB is proposed. The equilibrium profile is calculated by geometric model and variational approach,based on it,the predicted model of RWCB is developed for tire design. Finally,four different designs of 12R22.5 tires are investigated by experiment and finite element method,which is used to validate the accuracy of the theoretical method. Results indicate that experimental and finite element analysis results are found to be in good agreement with theoretical results; linear relationships are existed between the cord length and RWCB,and also existed between the position of belt and RWCB; tires designed by the methods have smaller and more uniform displacement,so the method can be used for tire optimized design.展开更多
This experimental work investigates the impact of substituting part of the conventional aggregates with rubber aggregates on certain characteristics of the cement concretes. This incorporation of rubber aggregates res...This experimental work investigates the impact of substituting part of the conventional aggregates with rubber aggregates on certain characteristics of the cement concretes. This incorporation of rubber aggregates resulting from cutting worn tires in practical sizes decreases the mechanical resistances of the concretes while improving slightly the fluidity of the tested mixtures. The effect of these aggregates on the shrinkage of the concretes at an early age is appreciable and even very interesting for the concretes used, for example, in road construction. This technique of cutting worn tires without any further treatment makes it accessible to everyone which helps not only in saving the environment by getting rid of this cumbersome waste but also in saving traditional aggregates.展开更多
This paper outlines a mechanical transformation process for rubber recycling, demonstrating the development of a new material from used tires. With the crumbs obtained using a crusher-compactor, a novel material for t...This paper outlines a mechanical transformation process for rubber recycling, demonstrating the development of a new material from used tires. With the crumbs obtained using a crusher-compactor, a novel material for the manufacture of O-rings has been developed, with properties close to those found on the market. The process includes an experimental methodology of a sulfur vulcanization system choice and the quantification of ingredients, as well as the experimental determination of cure parameters. Mechanical tests on the samples completed the work by providing the mechanical characteristics of both unaged and aged (thermo-oxidative ageing) novel material. This process has a high potential for sustainable development and industrialization, making it a valuable contribution to the recycling of rubber in African developing countries.展开更多
Large amounts of used rubber tires are discarded annually. A long time is needed for them to degrade naturally. This poses two major problems: environmental pollution and wastage of valuable rubber. On the other hand,...Large amounts of used rubber tires are discarded annually. A long time is needed for them to degrade naturally. This poses two major problems: environmental pollution and wastage of valuable rubber. On the other hand, with the harm of vibration and noise widely recognized, desires to control them intensify. As an important means of vibration control, viscoelastic damping technology has advanced greatly. The need for cheap and high quality viscoelastic damping materials increases rapidly. This paper made a trial to use ground rubber tire (GRT) recovered from old tires to make damping materials. The GRT is treated specially first. Then it was pressed into slabs and vulcanized. Finally, the product was cut into test samples. An Oberst beam was used to determine the loss factor βand storage modulus E. Results show that the damping materials exhibit good damping α-bility.展开更多
Activated carbon derived from solid hazardous waste scrap tires was evaluated as a potential adsorbent for cationic dye removal. The adsorption process with respect to operating parameters was investigated to evaluate...Activated carbon derived from solid hazardous waste scrap tires was evaluated as a potential adsorbent for cationic dye removal. The adsorption process with respect to operating parameters was investigated to evaluate the adsorption characteristics of the activated pyrolytic tire char （APTC） for Rhodamine B （RhB）. Systematic research including equilibrium, kinetics and thermodynamic studies was performed. The results showed that APTC was a potential adsorbent for RhB with a higher adsorption capacity than most adsorbents. Solution pH and temperature exert significant influence while ionic strength showed little effect on the adsorption process. The adsorption equilibrium data obey Langmuir isotherm and the kinetic data were well described by the pseudo second-order kinetic model. The adsorption process followed intra-particle diffusion model with more than one process affecting the adsorption process. Thermodynamic study confirmed that the adsorption was a physisorption process with spontaneous, endothermic and random characteristics.展开更多
Scrap tires were pyrolyzed in a continuously stirred batch reactor in the presence and absence of catalysts. The maximum yield of derived oil was up to 55.65 wt%at the optimum temperature, 500 °C. The catalytic p...Scrap tires were pyrolyzed in a continuously stirred batch reactor in the presence and absence of catalysts. The maximum yield of derived oil was up to 55.65 wt%at the optimum temperature, 500 °C. The catalytic pyrolysis was performed using 1.0 wt%（on a scrap tire weight basis） of catalysts based on ZSM‐5, USY,β, SAPO‐11, and ZSM‐22. The oil products were characterized using simula‐tion distillation, elemental analysis, and gas chromatography‐mass spectrometry. The results show that using a catalyst can increase the conversion of scrap tires to gas and decrease char by‐products;the yield of derived oil remains unchanged or a little lower. The oils derived from catalytic pyrolysis had H/C ratios of 1.55–1.65 and contained approximately 70–75 wt%light oil, 0.3–0.58 wt%S and 0.78–1.0 wt%N. Catalysts with high acid strengths and appropriate pore sizes, such as ZSM‐5, USY,β, and SAPO‐11, increased the amount of single‐ring aromatics in the light‐middle‐fraction oil to 45 wt%. The derived oil can therefore be used as a petrochemical feedstock for producing high‐value‐added chemical products or fuel oil.展开更多
Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char(PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications ...Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char(PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications for pyrolytic char recovered is used for the removal of Cr(Ⅵ) in the wastewater effluent to control waste by waste. The surface chemistry properties of surface element distribution / concentration and chemical structure were examined for the pyrolytic char and the commercial activated carbon(CAC) respectively. The results showed that surfaces of PC possesses a large amount of ester and hydrocarbon graft, whereas there are mainly carbon functional components of C—OH, C O and COOH on the surface of CAC. Therefore the surface electronegativity of PC is lower than that of CAC in the water. The repulsive interactions between the surfaces of PC and the negatively charged Cr(Ⅵ) ion are weaker than that of CAC, which results in an intensification of the adsorption process by the utilization of PC. The adsorption isotherms of Cr(Ⅵ) ion on the two kinds of carbons were determined experimentally. The larger adsorption amount on the PC in the case of Cr(Ⅵ) may be attributed mainly to its special surface micro-chemical environment. The mechanism of the removal Cr(Ⅵ) from aqueous solution was assumed to be the integration of adsorption and redox reaction. The adsorption was the rate-controlled step for Cr(Ⅵ) removal. The adsorption of Cr(Ⅵ) was identified as pseudo-second-order kinetics. The rate constants of adsorption were evaluated.展开更多
With the rapid growth in the number of passenger cars(PCs)in China over the past decades,more than ten million tons of used tires have already become solid wastes and subsequently caused serious environmental issues.D...With the rapid growth in the number of passenger cars(PCs)in China over the past decades,more than ten million tons of used tires have already become solid wastes and subsequently caused serious environmental issues.Due to the presence of synthetic rubber in PC tires,waste PC tires cannot be disposed through rubber reclaiming technology.Thus,waste PC tires have become one of fastest growing solid wastes in China.First,the current disposal capacity of the pyrolysis method,regarded as a promising technology for the disposal of waste PC tires,is surveyed and compared with other disposal methods mentioned in previous papers.Second,this work establishes a model to predict the total number of waste PC tires in the next five years depending on the rate of PC growth and current waste tire disposal capacity.Moreover,pyrolysis is evaluated on 15 collected waste PC tires selected from the most representative tire brands in the Chinese market.The corresponding results imply that~68.5%of S was into oil and~44.3%N and large amount of heavy metals resided in solid carbon which severely limit further applications.Finally,a new pyrolysis technology is introduced that may represent a solution to the limits in the application of tire disposal methods and relief for the coming waste tire crisis.展开更多
The current research of tire aerodynamics mainly focus on the isolated and simplified tread tire.Compared with the real complex pattern tire,the tread pattern structure and deformed profile of a loaded tire has a grea...The current research of tire aerodynamics mainly focus on the isolated and simplified tread tire.Compared with the real complex pattern tire,the tread pattern structure and deformed profile of a loaded tire has a greatly influence on tire aerodynamic drag.However,the mechanisms of the isolated loaded tires with different tread patterns effects on the aerodynamic drag are subjects worthy of discussion.The purpose of this study is to experimentally and compu-tationally investigate the aerodynamic characteristics of three tires 185/65 R14 with different patterns under loaded.A wind tunnel test model was first established using three-dimensional(3D)printing with a ratio of 1:1,and the pres-sure coefficients C_(p) of the three tires with different patterns are measured.The paper then conducted computational fluid dynamics(CFD)simulations for analyzing the pressure and flow characteristics.The accuracy of CFD simulation is verified by comparing the simulation results with the test results of pressure coefficients C_(p),and they are of good consistency.While,the general analysis of pressure coefficients C_(p) results of the three tires indicates high-pressure area on the windward surface,and occurrence of low-pressure area on the leeward surface,the pressure coefficients C_(p) of all three tires decreased firstly and then increased along in the air flow direction.The authors finally analyzed the effect of tread patterns on the flow field around the tire and revealed the differences between flow characteristics and aerodynamic drag.The results show that,angle of tire lateral groove has great effect on the flow field characteristics such that;the more the angle of lateral groove agrees with the air flow direction,the less the flow separation and flow vortices,and a minimum observable aerodynamic drag.The research provides a guidance for the design of low aerodynamic drag tires,and helps to illustrate the impact of tire aerodynamics on the car body in the future.展开更多
In this research,the tire deformations due to rotation are divided into three parts:tread,belt and carcass.Tread deformation is obtained by using a rotating hollow cylinder model,belt expansion is calculated according...In this research,the tire deformations due to rotation are divided into three parts:tread,belt and carcass.Tread deformation is obtained by using a rotating hollow cylinder model,belt expansion is calculated according to the laminated composite shell theory,and a formula of dynamic equilibrium profile is built to investigate carcass deformation.Moreover,a simple method is used to predict the footprint changes caused by tire deformation.Results show that a large deformation is occurring at tire shoulder,a smaller one at tread centre,and the shoulder deformations are mostly caused by carcass.Length of footprint side edges increase with tire rolling speed increasing.The predicted tread,belt,carcass deformations and footprint changes are in good agreement with finite element analysis results.The proposed method and the results will offer a helpful guidance to tire and vehicle engineers.展开更多
Based on the Sanders thin shell theory and Reddy's higher order shell theory,a general refined shell theory is developed for the analysis of stresses and deformations ofpneumatic radial tires of composite construc...Based on the Sanders thin shell theory and Reddy's higher order shell theory,a general refined shell theory is developed for the analysis of stresses and deformations ofpneumatic radial tires of composite construction. For easy and efficient simulation of the tire apiecewise Rayleigh-Ritz technique is proposed and applied to get a numerical solution to thenonlinear structural problem. Bezier polynomials are used to approximate both the geometry of thesurface of reference and displacement fields of the tires. Stress distributions and deformations ofthe tires subjected to uniform inflation pressure are computed and discussed in details. Fromcomparison of the present results with the numerical predictions by 3D finite element method, it hasbeen shown that the present solution procedure is accurate and applicable to much complicatedtime-consuming nonlinear analysis for the high quality tire.展开更多
Tire wear is a very complicated phenomenon that is influenced by various factors such as tire material, structure, vehicle and road conditions. In order to evaluate tire wear, a method for measuring tire wear using th...Tire wear is a very complicated phenomenon that is influenced by various factors such as tire material, structure, vehicle and road conditions. In order to evaluate tire wear, a method for measuring tire wear using the intensity of reflected light was presented?[1]. It comprises applying a single layer of reflected paint to a tread surface by spraying, and then measuring the intensity of light reflected from a matrix of blocks on the unworn tire. In this paper, a numerical technique for predicting the uneven wear of passenger car tire is presented. The uneven tire wear produced in wheel alignment condition with vehicle speed, camber angle, and toe angle is predicted by the frictional dynamic rolling analysis of 3D patterned tire model. The proposed numerical technique is illustrated through the method of paint testing the wear on the tread surface of a tire.展开更多
基金financially supported by the National Natural Science Foundation of China(No.52303063)Hubei Provincial Department of Education Guided Scientific Research Project(No.B2024056)。
文摘Airless tires are essential for enhancing the safety,reliability,and convenience of maintenance of electric bicycles.Polyurethane(PU)is considered a promising candidate for such applications owing to its versatile properties.However,their use is limited by insufficient heat resistance and excessive dynamic heat generation under cyclic loading.In this study,star-shaped trifunctional polypropylene glycerol(PPG3)was incorporated into conventional poly(tetramethylene glycol)(PTMG)and 4,4'-methylenediphenyl diisocyanate(MDI)-based systems to construct microporous star-shaped casting polyurethanes(SCPU),with water serving as a green foaming agent.Unlike conventional small-molecule trifunctional crosslinkers that create junctions within hard segment domains,PPG3 introduces long flexible arms between the hard segments,anchoring the crosslinking points at its molecular core.The large steric hindrance of PPG3 effectively suppresses soft segment crystallization and lowers the degree of microphase separation,whereas the crosslinked network restricts chain mobility,thereby reducing dynamic heat generation.These structural features also enhance the heat resistance,yielding a softening temperature of 183℃,which is 30.9%higher than that of polyurethane without PPG3.When applied to airless tires by casting SCPU into rubber treads,the fabricated hybrid airless tires achieved a rolling distance of over 3000 km under a load of 65 kg at 25km/h without structural failure,satisfying practical performance requirements.This strategy offers a simple,solvent-free,and environmentally friendly process,underscoring the potential of SCPU for scalable production of high-performance airless tires.
基金Supported by National Natural Science Foundation of China(Grant Nos.52072156,52272366)Postdoctoral Foundation of China(Grant No.2020M682269).
文摘The spoke as a key component has a significant impact on the performance of the non-pneumatic tire(NPT).The current research has focused on adjusting spoke structures to improve the single performance of NPT.Few studies have been conducted to synergistically improve multi-performance by optimizing the spoke structure.Inspired by the concept of functionally gradient structures,this paper introduces a functionally gradient honeycomb NPT and its optimization method.Firstly,this paper completes the parameterization of the honeycomb spoke structure and establishes the numerical models of honeycomb NPTs with seven different gradients.Subsequently,the accuracy of the numerical models is verified using experimental methods.Then,the static and dynamic characteristics of these gradient honeycomb NPTs are thoroughly examined by using the finite element method.The findings highlight that the gradient structure of NPT-3 has superior performance.Building upon this,the study investigates the effects of key parameters,such as honeycomb spoke thickness and length,on load-carrying capacity,honeycomb spoke stress and mass.Finally,a multi-objective optimization method is proposed that uses a response surface model(RSM)and the Nondominated Sorting Genetic Algorithm-II(NSGA-II)to further optimize the functional gradient honeycomb NPTs.The optimized NPT-OP shows a 23.48%reduction in radial stiffness,8.95%reduction in maximum spoke stress and 16.86%reduction in spoke mass compared to the initial NPT-1.The damping characteristics of the NPT-OP have also been improved.The results offer a theoretical foundation and technical methodology for the structural design and optimization of gradient honeycomb NPTs.
基金part of the Agency for Defense Development(ADD)research project on Weapon lethality/effectiveness analysis technology for material targets and grant funded by the korean goverment(511225-912A03301)。
文摘This study presents a fragility curve to assess explosively induced damage to military vehicle tires based on shock tube experiments.To replicate lateral damage scenarios that may occur in real battlefield environments involving missile or bomb detonations,extreme overpressure conditions were generated using a shock tube.The influence of explosive charge mass on tire damage was quantitatively evaluated.Experimental results identified two critical failure thresholds:for loss of pressure,the threshold was 354 kPa peak overpressure and 3052 kPa·ms impulse;for rupture,the values were 485 kPa and 4237 kPa-ms,respectively.The same damage profile was reproduced through finite element analysis(FEA),verifying the reliability of the simulation.A Single Degree of Freedom(SDOF)model and Kingery-Bulmash(K-B)chart were employed to generate pressure-impulse data as a function of standoff distance.These data were applied to a finite element tire model using the BLAST ENHANCED keyword in LS-DYNA.The applied peak overpressures were identical to the experimental values with a 24%-27%difference in impulse.The simulation also captured recurring bead rim separation phenomenon,leading to internal pressure loss consistent with high-speed camera observations from the experiments.The resulting fragility curve clearly defines the threshold conditions for tire damage and provides a standardized damage assessment model applicable to various explosive charge masses and stand-off distances.The proposed model offers a quantitative basis for evaluating tire vulnerability,providing foundational reference data for defense applications.Specifically,the findings are expected to serve as a reliable source for weapon effects analysis and target vulnerability assessments involving wheeled military vehicles.
基金Supported by the National Natural Science Foundation of China (No.20176051) and the Key Natural Science Foundation ofChina (No.20490205).
文摘Pyrolysis has the potential of transforming waste into valuable products. Pyrolytic carbon black (PCB) is one of the most important products resulting from the pyrolysis of used tires. One of the most significant applica-tions of modified pyrolytic carbon black is its use as pigment for offset printing ink to obtain high added values. Inverse gas chromatography (IGC) results show that a large quantity of inorganic matters and carbonaceous deposit are removed by treating the pyrolytic carbon black with nitric acid solution. Plenty of active sites originally occu-pied by inorganic ash and coke are recovered. The surface energy of pyrolytic carbon black (TWPC)modified by titanate-coupling agent-especially the specific interaction γ sspdetermined by the specific probe molecule, tolu-ene-shows the strong interaction between the TWPC and the synthetic resins. The offset printing ink performance confirms the IGC prediction. And TWPC has the great potential of applications in printing ink industry as pigment.
基金supported by Jiangsu Provincial Innovation Program of Graduate Student of China (Grant No. CXZZ11_0551 )
文摘Wear and mileage performance are the foremost performances for truck bus radial (TBR) tires. There are a lot of researches about the tire wear performance as well as the contact patch phenomenon by using finite element analysis (FEA) method or testing. But there is little published data on the correlations between the footprint geometry and the tread wear performance of tires. In this paper, an experiment on tire-ground performance of TBR tires is carried out by using Tekscan. The real-time changes of contact-area pressure distribution that occurred during the process of continuous load and unload are recorded. Three types of tires that act differently in behavior under normal usage are analyzed. A new method of researching in tire tread wear, which focuses on the geometrical characters of the footprint, is put forward. The experimental results of the three tires are described by using footprint geometrical characters. On the basis of studying the changing laws of footprint geometrical characters during the loading process and considering consumer survey and factory feedback information, the correlations between the geometrical character of footprints and tread destruction form are built. The analyzed results show that a greater contact area coefficient and a steady coefficient of contact result in a better wear performance for TBR tires. The footprint-shape coefficient changing laws in the process of loading are found to have a very good coincidence with the tread wear of the three types of tires. Tires with a smaller footprint-shape coefficient are likely to have an average tread wear while avoiding the shoulder wear first. The proposed research provides a new solution to predict tire-ground performance at the point of footprint and several useful references for improving tire design.
文摘Scrapped tires from vehicles are produced in large quantities. Despite numerous existing uses of scrapped tires, alarge quantity ends up at the landfill sites, which contributes to environmental degradation. The development ofmore applications of scrapped tire usage can reduce the disposal of tires at landfill sites. This research proposes anovel use of scrapped tires by using the strips taken from scrapped tires in replacement of steel bars as reinforcement. Manhole covers were produced using scrapped tires by completely replacing the steel with scrapped tires.Four different samples of manhole covers were prepared and tested. The highest bearing capacity of 25.5 kN wasrecorded with a sample of 100 mm thickness made with cementitious composite, which is 2.25 times higher thanthe bearing capacity of a conventional reinforced-concrete manhole cover. The use of manhole covers made withscrapped tires can effectively address the theft issue of manhole covers. The lifecycle cost analysis shows that themanhole cover made with scrapped tires is 3.4 times more cost-effective in comparison with the conventionalmanhole cover. This research shows a new avenue of the potential use of scrapped tires as reinforcement in structures, which can improve sustainable construction practices.
文摘Scrap vulcanized rubber is amongst a bigger waste polymers. It does not decompose easily owing to its cross linked structure. Modification of scrap tires powder by the grafting with 2-acrylamido-2-methylpropanesulfonic acid (AMPS) is described. The grafting is achieved through free radical initiation. The effects of different amount of monomer and initiator were examined. Also the influence of reaction time and temperature were investigated. The grafted waste rubber was characterized by FT/IR, SEM and DSC measurements. The proposed mechanism of the grafting reaction is discussed. From DSC and SEM studies of WR-g-AMPS compared with PAMPS and WR, the results show that the particle size and crystallinity were enhanced for the grafted copolymers. The obtained modified scraped tires will used as an ion exchanger for the future applications.
基金financially supported by the National Natural Science Foundation of China (Nos. 21722604, 21878133, and22002050)China Postdoctoral Science Foundation (No.2020M671365)Postgraduate Research&Practice Innovation Program of Jiangsu Province (No. KYCX20_3039)。
文摘A series of basic nitrogen doped carbon hollow spheres(p-N-C) catalysts derived from waste tires were prepared by a green, facile and environmental “leavening” strategy for the catalytic oxidation of pentanethiol. Compared to pristine carbon, the p-N-C has a higher surface curvature conducive to the enrichment of substrates, leading to an excellent catalytic performance. This increased surface curvature of p-N-C was fabricated on the synergistic effect of two foaming agents((NH4)2 C2 O4 and NaHCO3), and the released gas also endows the spherical shell of p-N-C with a hierarchical porous structure, promoting the accessibility of active sites with pentanethiol. Pyridine-like and pyrrolic-like nitrogen atoms were investigated as reactive sites on the p-N-C to accelerate the electron transfer from sulfur to active surface oxygen and enhance the adsorption/oxidation process. As a result, the optimal p-N-C catalyst exhibits superior adsorption and oxidation performance(99.9%) of pentanethiol, outperforming the “unleavened”catalyst(20.8%). This work offers a new avenue for the fabrication of highly efficient materials for the desulfurization of fuel.
基金Sponsored by the National Natural Science Foundation of China(Grant No.11272105)the Joint Construction Project of HIT and Weihai(Grant No.2013DXGJ02)the Natural Scientific Research Innovation Foundation in Harbin Institute of Technology(Grant No.HIT.NSRIF.2015109)
文摘The restriction width of carcass by the belts( RWCB) as an important parameter of radial tire design has been neglected for a long time. In order to improve the accuracy and efficiency of tire profile design,the calculating method of RWCB is proposed. The equilibrium profile is calculated by geometric model and variational approach,based on it,the predicted model of RWCB is developed for tire design. Finally,four different designs of 12R22.5 tires are investigated by experiment and finite element method,which is used to validate the accuracy of the theoretical method. Results indicate that experimental and finite element analysis results are found to be in good agreement with theoretical results; linear relationships are existed between the cord length and RWCB,and also existed between the position of belt and RWCB; tires designed by the methods have smaller and more uniform displacement,so the method can be used for tire optimized design.
文摘This experimental work investigates the impact of substituting part of the conventional aggregates with rubber aggregates on certain characteristics of the cement concretes. This incorporation of rubber aggregates resulting from cutting worn tires in practical sizes decreases the mechanical resistances of the concretes while improving slightly the fluidity of the tested mixtures. The effect of these aggregates on the shrinkage of the concretes at an early age is appreciable and even very interesting for the concretes used, for example, in road construction. This technique of cutting worn tires without any further treatment makes it accessible to everyone which helps not only in saving the environment by getting rid of this cumbersome waste but also in saving traditional aggregates.
文摘This paper outlines a mechanical transformation process for rubber recycling, demonstrating the development of a new material from used tires. With the crumbs obtained using a crusher-compactor, a novel material for the manufacture of O-rings has been developed, with properties close to those found on the market. The process includes an experimental methodology of a sulfur vulcanization system choice and the quantification of ingredients, as well as the experimental determination of cure parameters. Mechanical tests on the samples completed the work by providing the mechanical characteristics of both unaged and aged (thermo-oxidative ageing) novel material. This process has a high potential for sustainable development and industrialization, making it a valuable contribution to the recycling of rubber in African developing countries.
文摘Large amounts of used rubber tires are discarded annually. A long time is needed for them to degrade naturally. This poses two major problems: environmental pollution and wastage of valuable rubber. On the other hand, with the harm of vibration and noise widely recognized, desires to control them intensify. As an important means of vibration control, viscoelastic damping technology has advanced greatly. The need for cheap and high quality viscoelastic damping materials increases rapidly. This paper made a trial to use ground rubber tire (GRT) recovered from old tires to make damping materials. The GRT is treated specially first. Then it was pressed into slabs and vulcanized. Finally, the product was cut into test samples. An Oberst beam was used to determine the loss factor βand storage modulus E. Results show that the damping materials exhibit good damping α-bility.
基金supported by the National Key Technologies R & D Program of China (No. 2006BAC02A12)the Key Technologies R & D Program of Tianjin, China (No.07ZCGYSH02000)the Natural Science Foundationof Tianjin, China (No. 08JCZDJC21400).
文摘Activated carbon derived from solid hazardous waste scrap tires was evaluated as a potential adsorbent for cationic dye removal. The adsorption process with respect to operating parameters was investigated to evaluate the adsorption characteristics of the activated pyrolytic tire char （APTC） for Rhodamine B （RhB）. Systematic research including equilibrium, kinetics and thermodynamic studies was performed. The results showed that APTC was a potential adsorbent for RhB with a higher adsorption capacity than most adsorbents. Solution pH and temperature exert significant influence while ionic strength showed little effect on the adsorption process. The adsorption equilibrium data obey Langmuir isotherm and the kinetic data were well described by the pseudo second-order kinetic model. The adsorption process followed intra-particle diffusion model with more than one process affecting the adsorption process. Thermodynamic study confirmed that the adsorption was a physisorption process with spontaneous, endothermic and random characteristics.
基金supported by the Basic Research Program of VCC Technology(ycsy2014ky-A-14)~~
文摘Scrap tires were pyrolyzed in a continuously stirred batch reactor in the presence and absence of catalysts. The maximum yield of derived oil was up to 55.65 wt%at the optimum temperature, 500 °C. The catalytic pyrolysis was performed using 1.0 wt%（on a scrap tire weight basis） of catalysts based on ZSM‐5, USY,β, SAPO‐11, and ZSM‐22. The oil products were characterized using simula‐tion distillation, elemental analysis, and gas chromatography‐mass spectrometry. The results show that using a catalyst can increase the conversion of scrap tires to gas and decrease char by‐products;the yield of derived oil remains unchanged or a little lower. The oils derived from catalytic pyrolysis had H/C ratios of 1.55–1.65 and contained approximately 70–75 wt%light oil, 0.3–0.58 wt%S and 0.78–1.0 wt%N. Catalysts with high acid strengths and appropriate pore sizes, such as ZSM‐5, USY,β, and SAPO‐11, increased the amount of single‐ring aromatics in the light‐middle‐fraction oil to 45 wt%. The derived oil can therefore be used as a petrochemical feedstock for producing high‐value‐added chemical products or fuel oil.
文摘Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char(PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications for pyrolytic char recovered is used for the removal of Cr(Ⅵ) in the wastewater effluent to control waste by waste. The surface chemistry properties of surface element distribution / concentration and chemical structure were examined for the pyrolytic char and the commercial activated carbon(CAC) respectively. The results showed that surfaces of PC possesses a large amount of ester and hydrocarbon graft, whereas there are mainly carbon functional components of C—OH, C O and COOH on the surface of CAC. Therefore the surface electronegativity of PC is lower than that of CAC in the water. The repulsive interactions between the surfaces of PC and the negatively charged Cr(Ⅵ) ion are weaker than that of CAC, which results in an intensification of the adsorption process by the utilization of PC. The adsorption isotherms of Cr(Ⅵ) ion on the two kinds of carbons were determined experimentally. The larger adsorption amount on the PC in the case of Cr(Ⅵ) may be attributed mainly to its special surface micro-chemical environment. The mechanism of the removal Cr(Ⅵ) from aqueous solution was assumed to be the integration of adsorption and redox reaction. The adsorption was the rate-controlled step for Cr(Ⅵ) removal. The adsorption of Cr(Ⅵ) was identified as pseudo-second-order kinetics. The rate constants of adsorption were evaluated.
基金support of the National Key R&D Program of China[Grant No.2018YFC1902601].
文摘With the rapid growth in the number of passenger cars(PCs)in China over the past decades,more than ten million tons of used tires have already become solid wastes and subsequently caused serious environmental issues.Due to the presence of synthetic rubber in PC tires,waste PC tires cannot be disposed through rubber reclaiming technology.Thus,waste PC tires have become one of fastest growing solid wastes in China.First,the current disposal capacity of the pyrolysis method,regarded as a promising technology for the disposal of waste PC tires,is surveyed and compared with other disposal methods mentioned in previous papers.Second,this work establishes a model to predict the total number of waste PC tires in the next five years depending on the rate of PC growth and current waste tire disposal capacity.Moreover,pyrolysis is evaluated on 15 collected waste PC tires selected from the most representative tire brands in the Chinese market.The corresponding results imply that~68.5%of S was into oil and~44.3%N and large amount of heavy metals resided in solid carbon which severely limit further applications.Finally,a new pyrolysis technology is introduced that may represent a solution to the limits in the application of tire disposal methods and relief for the coming waste tire crisis.
基金Supported by National Natural Science Foundation of China(Grant Nos.52072156,51675240)Jiangsu Provincial Youth Fund of China(Grant No.KB20160528)+1 种基金Jiangsu Provincial Six Talents Summit Program of China(Grant No.JXQC-011)Jiangsu University Senior Talents Startup Fund(Grant No.1291120046).
文摘The current research of tire aerodynamics mainly focus on the isolated and simplified tread tire.Compared with the real complex pattern tire,the tread pattern structure and deformed profile of a loaded tire has a greatly influence on tire aerodynamic drag.However,the mechanisms of the isolated loaded tires with different tread patterns effects on the aerodynamic drag are subjects worthy of discussion.The purpose of this study is to experimentally and compu-tationally investigate the aerodynamic characteristics of three tires 185/65 R14 with different patterns under loaded.A wind tunnel test model was first established using three-dimensional(3D)printing with a ratio of 1:1,and the pres-sure coefficients C_(p) of the three tires with different patterns are measured.The paper then conducted computational fluid dynamics(CFD)simulations for analyzing the pressure and flow characteristics.The accuracy of CFD simulation is verified by comparing the simulation results with the test results of pressure coefficients C_(p),and they are of good consistency.While,the general analysis of pressure coefficients C_(p) results of the three tires indicates high-pressure area on the windward surface,and occurrence of low-pressure area on the leeward surface,the pressure coefficients C_(p) of all three tires decreased firstly and then increased along in the air flow direction.The authors finally analyzed the effect of tread patterns on the flow field around the tire and revealed the differences between flow characteristics and aerodynamic drag.The results show that,angle of tire lateral groove has great effect on the flow field characteristics such that;the more the angle of lateral groove agrees with the air flow direction,the less the flow separation and flow vortices,and a minimum observable aerodynamic drag.The research provides a guidance for the design of low aerodynamic drag tires,and helps to illustrate the impact of tire aerodynamics on the car body in the future.
基金National Natural Science Founda tion of China Project(51790502)Open Grant of National Key Laboratory of Science and Technology on Advanced Composites in Special Environments(JCKYS2019603C016)。
文摘In this research,the tire deformations due to rotation are divided into three parts:tread,belt and carcass.Tread deformation is obtained by using a rotating hollow cylinder model,belt expansion is calculated according to the laminated composite shell theory,and a formula of dynamic equilibrium profile is built to investigate carcass deformation.Moreover,a simple method is used to predict the footprint changes caused by tire deformation.Results show that a large deformation is occurring at tire shoulder,a smaller one at tread centre,and the shoulder deformations are mostly caused by carcass.Length of footprint side edges increase with tire rolling speed increasing.The predicted tread,belt,carcass deformations and footprint changes are in good agreement with finite element analysis results.The proposed method and the results will offer a helpful guidance to tire and vehicle engineers.
文摘Based on the Sanders thin shell theory and Reddy's higher order shell theory,a general refined shell theory is developed for the analysis of stresses and deformations ofpneumatic radial tires of composite construction. For easy and efficient simulation of the tire apiecewise Rayleigh-Ritz technique is proposed and applied to get a numerical solution to thenonlinear structural problem. Bezier polynomials are used to approximate both the geometry of thesurface of reference and displacement fields of the tires. Stress distributions and deformations ofthe tires subjected to uniform inflation pressure are computed and discussed in details. Fromcomparison of the present results with the numerical predictions by 3D finite element method, it hasbeen shown that the present solution procedure is accurate and applicable to much complicatedtime-consuming nonlinear analysis for the high quality tire.
文摘Tire wear is a very complicated phenomenon that is influenced by various factors such as tire material, structure, vehicle and road conditions. In order to evaluate tire wear, a method for measuring tire wear using the intensity of reflected light was presented?[1]. It comprises applying a single layer of reflected paint to a tread surface by spraying, and then measuring the intensity of light reflected from a matrix of blocks on the unworn tire. In this paper, a numerical technique for predicting the uneven wear of passenger car tire is presented. The uneven tire wear produced in wheel alignment condition with vehicle speed, camber angle, and toe angle is predicted by the frictional dynamic rolling analysis of 3D patterned tire model. The proposed numerical technique is illustrated through the method of paint testing the wear on the tread surface of a tire.
